12th CRP Mains PDF

FIITJEE - JEE (Mains)
PHYSICS, CHEMISTRY & MATHEMATICS

SET - A
CTY – PHASE – 4 QP CODE - 110650
Time Allotted: 3 Hours Maximum Marks: 360
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4. The Test Booklet consists of 90 questions. The maximum marks are 360.
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Mathematics having 30 questions in each part of equal weightage. Each question is allotted 4
(four) marks for correct response.
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question. ¼ (one fourth) marks will be deducted for indicating incorrect response of each question.
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JEE MAINS
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SECTION - 1
PHYSICS
1. Three bulbs A, B and C are connected as shown in figure. The C bulb B

and C are identical. If the bulb C is fused.
(a) both A and B will glow more brightly than before
(b) Both A and B will glow less brightly than before A B
(c) A will glow less brightly

(d) none of the bulbs will glow
2. When a proton is released from rest in a room, it starts with an initial acceleration a0 towards west. When it
is projected towards north with a speed 0 , it moves with an initial acceleration 3a0 towards west. The
electric and magnetic fields in the room are :
ma0 2ma0 ma0 2ma0
(a) west, up (b) west, down
e e0 e e0
ma0 3ma0 ma0 3ma0
(c) east, up (d) east, down
e e0 e e0
3. Needles N1,N2 and N3 are made of a ferromagnetic, a paramagnetic and diamagnetic substance
respectively. A magnet, when brought close to them, will :
(a) attract N1 strongly, but repel N2 and N3 weakly
(b) attract all three of them
(c) attract N1 and N2 strongly but repel N3
(d) attract N1 strongly, N2 weakly and repel N3 weakly
4. Consider the cube shown. A point charge 8q is placed at a vertex G of the cube
and another charge 4q is placed at the centre of an edge AE of the cube. B
A
Electric flux through the cube is E
q 2q 4q F
(A) (B)
o o D C
12q H 8q G
(C) (D) Zero
o
5. Current shown in figure is

I
15V 2V 5V 10V 5V
2 3 5 5
(A) 7 A (B) 2 A
(C) 5 A (D) 3 A
6. In the circuit shown in figure if battery is ideal, then time after which
R3  2
1
current in R3 becomes time of maximum current through it, is
e
(A) 18 s (B) 12 s  R2  2
(C) 6 s (D) 2 s
6 F
R1  2
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7. A battery of emf o  12V is connected across a 4 m long

uniform wire having resistance 4 / m. The cell of small o R  4
emfs 1  2V and 2  4V having internal resistance
2 and 6 respectively are connected as shown in the figure. N
A B
If galvanometer shows no deflection at the point N, the distance 1 r1
of point N from the point
A is equal to r2 G
(A) 1/6 m (B) 1/3 m 2
(C) 3/2 (D) None
8. A charged sphere of mass m and charge – q starts sliding along the

x x x x x x
surface of a smooth hemispherical bowl, at position P. The region has a
transverse uniform magnetic field B. Normal force by the surface of bowl x P x
on the sphere at position Q is: x 
R B
(A) mg sin  + qB 2gRsin  (B) 3mg sin  + qB 2gRsin  x Q x
x x x x x x
(C) mg sin  - qB 2gRsin  (D) 3mg sin  - qB 2gRsin 
9. A particle of charge (+q) and mass m moving under the influence of

x x x x xY x
uniform electric field E  Eo ˆj and uniform magnetic field
x xv o 2 x
ˆ
B  Bok follows a trajectory from P to Q as shown in figure. The velocity x x x
45o
v
at P is v  v o ˆi  v o ˆj and velocity at Q is - o ˆj. The
x x
magnitude of a
2 x x x x x x
electric field is given by Q x x x x x x
X
mv 02 3mv 02 L
(A) (B)
8qo a 4qa
7mv 02 5mv 02
(C) (D)
8qa 8qa
10. A particle of mass m and charge q enters a region of magnetic field (as shown) with speed v. There is a
region in which the magnetic field is absent, as shown. The particle after entering the region collides
elastically with a rigid wall. Time after which the velocity of particle becomes antiparallel to its initial
velocity is
x xB
x x x
x x
x x x
q x x
x x x
x x
x x x
x x
x x x
mv mv
Wall
2qB 2qB
m m
(A)    4 (B)    2
2qB qB
m m
(C)    2 (D)  2  3 
4qB 4qB
JEE MAINS
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11. A magnetic field B  B0 ˆj exists in the region a < x < 2a and B  B0 ˆj in the region 2a < x < 3a, where B0 is
a positive constant.
z
B0
x
v0 a 2a 3a
B0
A positive point charge moving with a velocity v  v 0 ˆi where v0 is a positive constant, enters the magnetic
field at x = a. The trajectory of the charge in this region can be like:
z z z z
x 2a
a x x
2a 3a a 2a 3a a 3a
x
a 2a 3a
(A) (B) (C) (D)
12. A rod has a total charge Q uniformly distributed along its length L. If the rod rotates with angular velocity
 about its end, its magnetic moment is

L
++ + + + + + ++ +
Total charge = Q
QL2 QL2
(A) (B)
2 4
QL2 QL2
(C) (D)
8 6
13. An electric dipole AB is placed along the x-axis with its charges placed at distance x1 and x2 from a very long
thin wire having a uniform linear positive charge density  as shown in figure. Choose the correct option:
The force experienced by the dipole is

q  1 1  q  1 1 
(A)    along –ve x-direction (B)    along +ve x-direction
20  x1 x 2  40  x1 x 2 
q q
(C) (x 2  x1 ) along +ve x-direction (D) (x 2  x1 ) along –ve x-direction
20 20
14. The electric potential V (in volt) varies with x (in metre) according to the relation
V = 5 + 4x2
The force experienced by a negative charge of 2 × 10-6 C located at x = 0.5 m is
(A) 2 × 10-6 N (B) 4 × 10-6 N (C) 6 × 10-6 N (D) 8 × 10-6 N
JEE MAINS
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15. A positive charge (+q) is located at the centre of a circle as shown in figure. W 1 is the work done in taking a
unit positive charge from A to B and W 2 is the work done in taking the same charge from A to C, then
(A) W 1 > W 2 (B) W 1 < W 2 (C) 2W 1 = W 2 (D) W 1 = W 2 =0
16. Two wires AB and BC, each of length L/2 are made of the same material. The radius of wire AB is 2r and of
wire BC is r. The current I flows through the composite wire. Choose the correct statement from the
following:
(A) Potential difference across BC is twice that across AB

(B) Power dissipated in BC is four times the power dissipated in AB
(C) Current densities in AB and BC are equal
(D) Electric fields in AB and BC are equal
17. A steady current flows in a metallic conductor of non-uniform cross-section. The quantity/quantities that
remains/remain constant along the length of the conductor is/are
(A) current, electric field and drift speed (B) drift speed only
(C) current and drift speed (D) current only
18. An electron is shot in steady electric and magnetic fields such that its velocity v, electric field E and magnetic
field B are mutually perpendicular. The magnitude of E is 1 volt/cm and that of B is 2 T. Now it happens that
the magnetic force cancels with the electrostatic force on the electron; then the velocity of the electron is:
(A) 50 m/s (B) 2 cm/s (C) 0.5 cm/s (D) 200 m/s
19. A parallel plate capacitor of 3F is charged with charge of -200 C +100 C
-200 C at plate A and +100 C at plate B. Find the
potential difference vA – vB between the plates.
A B
(A) – 20 volt (B) -70 volt (C) -50 volt (D) 0 volt
20. Charge on plate B of capacitor (at steady state)is

(A) 3c (B) 3c
(C) 1.5c (D) 1.5c
21. Heat generated in the circuit when switch is shifted from 1 to 2 is

(A) 32J
(B) 16J
(C) 48J
(D) 64J
JEE MAINS
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22. Two large parallel sheets having linear current densities J and Jo as J
shown in figure, then magnetic field in region b is
 J b
(A) zero (B) o
2
(C)  o J (D) None of these      J
23. An electric field given by E  4iˆ  3(y2  2)jˆ pierces Gaussian cube of side 1m placed at origin such that its
three sides represents x, y and z axes. The net charge enclosed within the cube is
(a) 40 (b) 30 (c) 50 (d) zero
24. A dipole of dipole moment p is kept at the centre of a ring of radius R and charge q. The dipole moment
has direction along the axis of the ring. The resultant force on the ring due to the dipole is
pq
(a) zero (b)
40R3
pq pq
(c) (d) only if the charge is uniformly distributed on the ring.
20R3 40R3
25. A conductor in the form of a right angle ABC with AB = 3 cm and BC = 4 cm carries a current of 10 A.
There is a uniform magnetic field of 5 T perpendicular to the plane of the conductor. The force on the
conductor will be
(a) 1.5 N (b) 2.0 N (c) 2.5 N (d) 3.5 N
26. A parallel plate square capacitor of capacitance C = 2F (without dielectrics) is filled by dielectric slabs as
shown in figure. Then the new capacitance of the capacitor is :
(a) 12 F (b) 3.9 F K3  6 d

(c) 2.4 F (d) 3 F
K1  2 K3  4 d
w w
27. A long straight wire, carrying current I, is bent at its midpoint to form an angle of 45°. Magnetic field at point
P, distance R from point of bending is equal to :
P
( 2  1)0I ( 2  1)0I
(a) (b) R 45° I
4R 4R
I
( 2  1)0I ( 2  1)0I
(c) (d)
4 2R 2 2R
28. Half part of ring is uniformly positively charged and other half is E0
– – ++
uniformly negatively charged. Ring is in equilibrium in uniform
electric field as shown and free to rotate about an axis passing – +
through its centre and perpendicular to plane. The equilibrium is – +
– +
(a) stable (b) unstable – +
(c) neutral (d) can be stable or unstable –
–– + +
JEE MAINS
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29. In figure, two positive charge q2 and q3 fixed along the Y-axis, exert a net electric force in the +X direction
on a charge q1 fixed along the X-axis. If a positive charge Q is added at (x,0) , the force on q1 :
Y q2
q2
Q
X q1 O X
q1 O (x,0)
q3 q3
(a) (b)
(a) shall increase along the positive X-axis

(b) shall decrease along the positive X-axis
(c) shall point along the negative X-axis
(d) Shall increase but the direction changes because of the intersection of Q with q2 and q3 .
30. Find the equivalent resistance across AB. A

(a) 1Ω 2Ω
(b) 2 Ω 2Ω
2Ω
(c) 3Ω 2Ω
(d) 4Ω 2Ω
JEE MAINS
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SECTION – 2
CHEMISTRY
1. Which of the following polymer is not synthesized from acidic monomer
(a) Dacron (b) Nylon 6,6 (c) Bakelite (d) Teflon
2. Liebermann test is given by which of the following

COOH OH
CH3
(a) H3C C OH (b) CH3  CH2  COOH (c) (d)
3. Which is stronger base ?
NH
H3C C
(a) NH2 (b) (CH3 )3 N (c) Et 3N (d) Et 2NH
4. The major product (X) in the following reaction

Br
Br

C2H5 ONa
C2H5 OH
P , P is
NO 2
OC2H5 Br OC 2H 5 Br
Br OC 2H 5 OC 2H 5 Br
(a) (b) (c) (d)
NO 2 NO 2 NO 2 OC 2 H 5
5. The complementary strand of DNA for following single stranded DNA sequence 5’-A-T-C-A-T-G-C-3’ is
(a) 5’-A-T-C-A-T-G-C-3’ (b) 5’-T-A-G-T-A-C-G-3’ (c) 5’-G-C-A-T-G-A-T-3’ (d) 5’-C-G-T-A-C-T-A-3’
6. Molisch’s test given by -

(a) Carbohydrates (b) Amino acid (c) Lipids (d) none of these
7. 
dil KOH

(A) Product (A) is
O OH
O O
OH
(a) (b) (c) (d)

OH
JEE MAINS
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8. In the following reaction
CH3
CH C C CH3 
(i)KOCl

 (A)
(ii)H
O
What is A?
CH3
O O
|| ||
(a) Ph CH C COOH (b) PhCOOH  CH3  C C CH3
(c) Ph  COOH  CH3COOH (d) none of these
9. The correct order of acidity of the following compound

O O O O O
|| || || || ||
(a) CH3  C OEt  CH3  C H  CH3  C CH3  CH3  C CH2  C OEt  CH2 (COOEt)2
O O
|| ||
(b) CH3  C CH2  C OEt  CH3COCH3  CH3CHO  CH3COOEt  CH2 (COOEt)2
O
||
(c) CH3  C CH2COOEt  CH2 (COOEt)2  CH3COCH3  CH3CHO  CH3COOEt
O
||
(d) CH3  C OEt  CH3CHO  CH2 (COOEt)2  CH3COCH2COOEt  CH3COCH3
O
|| 
10. CH3  C OH 
NH3
(A) 
Al2 O3
(B) 
H3 O
(D)
‘D’ is
(a) CH3NH2 (b) CH3COOH (c) CH3CH2COOH (d) CH3CH2NH2
OH
 (A).
CHCl
3
NaOH
11.
A is
OH
CHO CHO
(a) (b) (c) No Reaction (d) none of these
NO 2
NaNO2 HCl
12. 
Fe HCl
(A) 
0C
(B) 
H2 O

(C)
OH Cl
JEE MAINS
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(a) (b) (c) (d) none of these
13. Thermosetting polymer is/are

(a) Bakelite (b) Terylene (c) Nylon 66 (d) All of these
14. Artificial sweeting agent is

(a) Terpineol (b) Bithionol (c) Penciline (d) Aspartame
15. Free energy profile for given reaction is

HO  CH3  Br 
HO  CH3  Br
Free Free
(a) Energy (b) Energy
Reaction co-ordinate Reaction co-ordinate
(c) Free (d) Free

Energy Energy
Reaction co-ordinate Reaction co-ordinate

16. In which of the following reaction pair of diastereomers will form ?

OH 
(a) 
H

(b) 
H

OH

(c) 
H

(d) All of these
OH

17. CH3  CH  CH  CH2Br 
KCN
(A) 
NaOH
(B) 
Basic hydrolysis
(C) 
H
(D)
‘D’ is :
(a) CH2  CH  CH  CH  COOH (b) CH3  CH  CH  CH2  COOH

(c) CH3  CH2  CH  CH  COOH (d) none of these
18. In the following reaction, which of the following step is wrong?
JEE MAINS
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NO 2 NO 2 NO 2
CH3COCl Zn Hg / HCl
conc. HNO3
AlCl3 C CH3 Me
+ conc. H2SO4
O
Step 1 Step 2 Step 3
(A) Step 1 (B) Step 2
(C) Step 1 & 3 Both (D) Step 1 & 2 both
19. Which of the following halides will be most reactive in SN2 reaction & SN1 reaction, respectively?
Br
Me
Br II. Me Me III.
I. Me
Me
Br
(A) I, II (B) II, I
(C) I, III (D) III, I
20. Arrange the following in increasing order of SN1 reactivity -
I. CH3CH2Br II. CH2 CH CH CH3 III. CH2 CH Br IV. CH3 CH CH3

Br Br
(A) IV > II > I > III (B) II > IV > I > III
(C) II > III > IV > I (D) II > I > IV > III
21. Which one of the following compounds undergoes bromination of it’s aromatic ring (electrophilic aromatic
substitution) at fastest rate
(A) (B)
N
H
(C) (D) NH
NH
O
JEE MAINS
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22. Which of the following belong to the class of natural polymers?

(A) Proteins (B) Cellulose
(C) Rubber (D) All of the above
23. In the following reactions :
Br
I. Alc. KOH
Ph Me Ph + HBr
Br
II. Alc. KOH
Ph CD 3 Ph CD 2 + DBr
The rate of reaction of (I) is faster than of (II). Both reactions proceed by which mechanism?
(A) E1 (B) E2
(C) SN2 (D)  -elimination
24. Which is the correct order of dipole moment of following compounds?
Cl Cl Cl Cl
Cl Cl
(I) (II) (III)
(A) I > II > III (B) I > III > II
(C) I < II < III (D) III > I > II
25. The product formed in following reaction B2H6 H2O2

sequence will be
OH-
CH2
H H
H H
(A) (B)
H H C OH OH CH3
2
JEE MAINS
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H OH
(C) (D) None of these
H CH3
26. The energy of activation is lowest for which reaction?
   
(A) RCH2 O H2 
 R C H2 (B) R 2CH O H2 
R2 C H

(C)  R 3C 
R 3C  O H 2  (D) All have the same energy of activation
27. When iodoform is heated with silver powder, the gaseous product formed is -
(A) Ethene (B) Ethyne
(C) Ethane (D) Silver iodate
28. CH3  CH  O  CH2  CH  CH3
CH3 CH3
Which of the following isomers of above compound has the highest boiling point?
(A) Chain isomer (B) Position isomer
(C) Functional isomer (D) Metamer
29. Hg  OAc 2 ,H2O BH3 ,THF

 Y       X
NaBH4 NaOH,H2O2
The products (X) and (Y) of above reaction exhibit
(A) chain isomerism (B) position isomerism
(C) functional isomerism (D) ring-chain isomerism
30. COOH 46% NaOH

2 A + B. A & B will be :
CHO
COOH COOH COONa COONa
(A) (B)
CH 2OH , CHO CH 2OH , COONa
COONa COONa (D) COOH COOH

(C)
CH 2OH , COOH COOH , COOH
JEE MAINS
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SECTION – 3
MATHS

 4)(x  4)(x  10)

1
(2 tan x
1. Set of values of x satisfying  0 is
x! (x  1)!
(a)  (b) {2, 3} (c) {5, 6, … 9} (d) none of these
2. Number of solution of the equation tan x = 2x in the interval [,2]

(a) 3 (b) 4 (c) 5 (d) 6
3sin x  4cos x  3
3. Range of the function f(x)  is equal to :
2 8  2 8  2 8   2  8 
(a)  ,  (b)  ,  (c)  ,    ,  (d)  ,    , 
3 7   3 7  3  7   3  7 
4. Which of the following function are non-identical ?

(a) f(x) = sin-1 (sin x) and g(x) = sin (sin-1 x) ; 0  x  1
(b) f(x) = sgn (x) and g(x) = sgn (sgn (x)) where sgn(x) represents signum function
sin4 2x
(c) f(x)  sin4 x  cos4 x and g(x)  1 
2
(d) f(x)  {x} and g(x)  { x}
5. Let f(x)  sin [a]x (where [ ] denotes the greatest integer function). If f is periodic with fundamental period
 , then a belongs to :
(a) [2, 3) (b) {4, 5} (c) [4, 5] (d) [4, 5)
x
 2 tan1 x  L
6. lim   equals e , then L is equal to :
x   
2 2
(a) (b)  (c)  (d) 1
 
(tan({x}  1))sin{x}
7. The value of lim where {x} denotes the fractional part function :
x 0 {x}({x}  1)
(a) is 1 (b) is tan 1 (c) is sin 1 (d) is non existent
8. Number of points of discontinuity of f(x) = [2x3 - 5] in [1, 2), is equal to : (where [x] denotes greatest integer
less than or equal to x)
(a) 14 (b) 13 (c) 10 (d) 8
  a  x  x 
sin  2  tan  2a  for x  a
  
9. f(x)     x  
cos   
   2a  
 for x  a
 ax
Where [x] is the greatest integer function of x and a > 0, then :
(a) f(a )  0 (b) f has a removable discontinuity at x = a
(c) f has an irremovable discontinuity at x = 0 (d) f(a+) < 0
10. Let f : [a,b]  R be any function which is such that f(x) is rational for irrational x and that f(x) is irrational for
rational x, then in [a, b] :
(a) f is discontinuous everywhere [a, b]
(b) f is continuous only at x = 0 and discontinuous everywhere
(c) f is continuous for all irrational x and discontinuous for rational x
JEE MAINS
15
(d) f is continuous for rational x and discontinuous for irrational x

11. The function f(x)  ex  x, being differentiable and bijective, has a differentiable inverse f 1(x) . The value
d 1
of (f ) at the point f(ln2) is :
dx
1 1 1
(a) (b) (c) (d) none of these
ln 2 3 4
12. The ends A and B of a rod of length 5 are sliding along the curve y  2x 2 . Let xA and xB be the x-
dxB
coordinate of the ends. At the moment when A is at (0, 0) and B is at (1, 2) the derivative has the
dx A
value(s) equal to :
1 1 1 1
(a) (b) (c) (d)
3 5 8 9
13. Suppose the function f(x)  f(2x) has the derivative 5 at x = 1 and derivative 7 at x = 2. The derivative of
the function f(x) – f(4x) at x = 1, has the value equal to :
(a) 19 (b) 9 (c) 17 (d) 14
14.  x   {sin1(ln x)  cos1(ln x)}dx is

 e
(a) (x  )3 / 2 (sin1(ln x))  C (b) (x  )3 / 2 (cos1(ln x))  C
5 

(c) (x   )3 / 2  C (d) does not exist
3
f '(x)
15. f(x)   (1  cos x)sin xdx, lim is finite non-zero, then value of n is :
x 0 xn
(a) 0 (b) 1 (c) 2 (d) 3
e3x  ex
16.  e4x  e2x  1dx 
1
(A) log(e4x  e2x  1)  C (B) tan1(ex  e x )  C
4
(C) tan1(ex  e x )  C (D) tan1(e x  ex )  C
17. For and natural number m,

1
 (x7m  x 2m  xm )(2x 6m  7xm  14)m dx (where x > 0) equals :

m 1 m 1
(7x7m  2x 2m  14xm ) m
(2x7m  14x 2m  7xm ) m
(a) C (b) C
14(m  1) 14(m  1)
m 1 m 1
(2x7m  7x 2m  14xm ) m (7x7m  2x 2m  xm ) m
(c) C (d) C
14(m  1) 14(m  1)
Where C is constant of integration.
(2x  1)
18.  (x 2  4x  1)3 / 2
dx is equal to :
x3 x x2 1
(a) C (b) C (c) C (d) C
(x 2  4x  1)1/ 2 (x  4x  1)1/ 2
2
(x 2  4x  1)1/ 2 (x  4x  1)1/ 2
2
JEE MAINS
16
/2 /4
19. If I   ln(sin x)dx then  ln(sin x  cos x) dx is :
0  / 4
I I I
(a) (b) (c) (d) I
2 4 2
/2
20. Value of  / 2
{tan x} dx where {.} denotes fractional part function, is :
 
(a) (b) (c)  (d) 2
4 2
/2
21. Value of  / 2
max(cosec 1 cosecx, sgn(x)) dx, (where sgn (x) is signum function), is
2  1  2 2
(a) 1   (b)  (c) 1 (d) 1 
8 2 2 2 8 8
73 
22. Value of 0
10
[cos x] dx is (where [.] denotes greatest integer function)
73 19 43
(a)  (b) 3 (c)  (d) 
10 5 10
    1
23. Let f(x) be an even function such that 0
f(x) dx 
2
, then the value of the definite integral 
0
f  x   dx
 x
is equal to
 3
(a)  (b) (c) (d) 2
2 2
24. The interval on which the function f(x)  log1/ 3 (x2  5x  6) is monotonic increasing is
 5 5 
(a)  2,   (3, ) (b) (3, ) (c) (,2) (d)  ,3
 2 2 
25. In [-2, 2], Langrange’s mean value theorem is not applicable to :

 sin(x  1)
 , x 1
(a) f(x)  (x  1) | x  1| (b) f(x)   (x  1)

1, x 1
  1 1
   
(c) f(x)   xe  |x| x  , x0 (d) f(x) | x  3 |  | x  3 |  | x  5 |

0, x0
x
26. Let f(x)   (sint  cos t)(et  2)(t  1)3 (t  2)5 dt (0 < x < 4). Then number of points, where f(x) assumes
0
local maximum value, is :

(a) one (b) two (c) three (d) none of these
27. If A(x1,y1 ) and B(x2 ,y2 ) are two points on curve y  e2|x| x (x1  0 and x2  0) such that tangents at points
A and B are perpendicular, then number of such pair of points A and B, is
(a) 0 (b) 1 (c) 2 (d) more than 2
3 x
28. Let g(x)  

3 x
t | f '(t) | dt, where f(x) does not behave like a constant function in any interval (a, b) and the
graph of f '(x) is symmetric about the line x = 3. Then :

(a) g(x) is increasing x R (b) g(x) is increasing only if x < 3
(c) g(x) is increasing only if f(x) is increasing (d) g(x) is decreasing x R
JEE MAINS
17
29. Let f(x) is an increasing function and f(x) > 0 for all x, then set of values of  for which major axis of ellipse
x2 y2
  1 is y-axis :
f(4  2) f( 2  5)
(a)   (1,3) (b)   (, 1)  (3, ) (c)   (,1)  (3, ) (d)   (1,3)
 
cos 2x x    
If f(x)    0, 2  ,   R ; then
30. 4 is continuous in
 0, 2  and differentiable in
(sin x  cos x) x   
 4
 
(a) f(x) is non-monotonic function in  0, 
 2
 
(b) there exist more than one c   0,  such that f '(c)  2
 2
  2( 2  1)
(c) there exist atleast one c   0,  such that f '(c) 
 2 
  2( 2  1)
(d) there cannot exist any c   0,  such that f '(c) 
 2 
JEE MAINS
18
ANSWERS IIT MAINS

SET - A
SR. PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE

NO
1. C P120218 D C121211 C M120316
2. B P120308 D C121205 B M120324
3. D Magnetic properties C M120317
of matter A C121208
4. B P120108 A C121202 D M120307
5. D P120113 C C121210 D M120322
6. A P120306 A C121209 B M113610
7. D P120114 B C121206 D M113602
8. B P120302 A C121207 B M120406
9. B P120113 C C121207 B M120402
10. A P120101 B C121207 A M120401
11. A P120215 B C121205 B M120503
12. D P120108 A C120208 D M120501
13. A P120113 A C121211 A M120501
14. D P120306 D C121210 D M120712
15. D P120114 B C121201 D M120712
16. B P120302 A C121203 B M120713
17. D P120113 C C121205 C M120701
18. A P120101 B C121408 B M120701
19. C P120215 C C124806 A M120802
20. B P120216 B C124802 B M120804
21. D P120110 B C114717 A M120804
22. C P120110 D C121704 C M120807
23. B P120108 B C114704 B M120813
24. B P120113 A C113610 C M120606
25. C P120306 A C114705 C M120614
26. A P120114 C C111303 C M120617
27. A P120302 B C114711 A M120601
28. A P120113 C C111401 A M120604
29. A P120101 B C114705 C M120604
30. A P120215 B C122813 C M120614
JEE MAINS
19
HINTS & SOLUTIONS (IIT MAINS)

PHYSICS :
1. C
2. B
3. D
4. B
8q
Due to 8q 
8 0
4q q q 2q
Due to 4q  Total   
40 0 0 0
5. D
6. A
i i2 2 
+q2
2 6F
q2
i1
2
i  i1  i2
  2i1  2i  0
q2
  2i2   2i  0
6
On solving differential equation is
 3dq2 q2
  0
2 dt 6
 q2 3dq2
 
2 6 dt
18dq2
 3  q2  
dt
q t
0 3  q2  18 0 dt  q2  3 1  e 
dq2 1  t /18
dq2   t /18
i2   e
dt 6
1
i2   imax 
e
then, e1  e t/18
 t  18 sec.
7. D
8. B
From energy conservation
From P + 0 Q
V  2gRsin 
Force, equation into radial direction
mv 2
N  qvB  mgsin  
R
N  3mgsin   qB 2gR 

JEE MAINS
20
9. B
A work energy theorem,
Work done by electric field = Change in kinetic energy
2
1 v  1
q  E0 a   m  0   m v 0 2  
2
2  2  2
3mv 02
E
4qa
3mv 02
magnitude of E 
4qa
10. A
x x x
x x
x
  45o x
x x
O x
x x
t1 t2

 4 m
t1   
 qB 4qB
m
mv
2qB m
t2  
v qB
2
 m 2m 
T  2  t1  t 2     
 2qB qB 
m
=    4
2qB
11. A
12. D

dl
l
++ + + + + + ++ +
dq  dl
We can visualize the rod to consist of differential elements dQ, which constitute a series of concentric
Q
current loops. the charge per unit length of the rod   .
L
So the charge on a differential element of length dl.
JEE MAINS
21
dq   dl
The current dI due to rotation of this charge is given by
dq  
dI =  dq  dl
 2 /  2 2
The magnetic moment of this differential current loop.
    2
 
d  dI l 2    dl 2   l 2 
 2  2
l dl
 2  L3 Q L2
L
2 0
Total magnetic moment is   l dl  
6 6
 Q   Q  1 2   QL2  
Again,   l =  2m  3 mL     
 2m      6 
13. Electric field due to in infinite wire


E=
2  r
q q
Fdipole = 
2x1 22h
q  1 1
F=   
2   x1 x 2 
v
14. E=   8x
x
at x = 0.5
E = - 4 V/m
F = qE = 8 × 10-6 N
16. Current flowing through both the bars is equal. Now, the heat produced is given by
HAB RAB
H = I2Rt or H  R or 
HBC BBC
1/ 2r 
2
 1 1
  as R  A  2 
1/ r   r 
2
1
= or HBC = 4HAB
4
P4 1
or 
P5 5
P5 10
 P4 =   2 cal / s
5 5
 Correct option is (B)
19. C -(200 +q) +(100 + q)

+q q
Writing electric field at point P
-(200 + q) – q + q – (100 + q) = 0 P
q = - 150 C. A B
150C
vA – vB = - = -50 volt.
3F
20. (B)
21. (D)
u in capacitor = 0
Work by battery = qE = 64 J
JEE MAINS
22
 Heat  64J
  J
22. Bb  B1 B2  2   o 
 2 
23. Net flux in x-direction = 0
y
Net flux in y-direction
 A[3(1)2  2]  A[3(0)  2]
 v  v cos60iˆ  v sin60jˆ
 q  3 0 A  3 0 , (as A  1m2 ) x
 (b)
z
p
24. The electric field due to the dipole on the circumference of the ring E  and it is directed normal to
40R3
the plane of charged ring.
pq
Hence force on the charged ring F  qE 
40R3
 (b)
25. Force on the conductor ABC A A
= Force on the conductor AC  10A 
= 5 × 10 × (5 × 10–2) = 2.5 N 10A × B × B
 (c) 3cm 3cm 
F
B 4cm C B 4cm C
26. (A)
27. (A)
28. Assuming ring as dipole, then dipole moment P and E are in same direction, so potential energy U = –PE
 (A)
29. A
30. A
SOLUTIONS (CHEMISTRY) :
2. (d) Only phenol gives Liebermann reaction. When phenol is dissolved in concentrated H2SO4 & few drops
of aq.NaNO2 added, red colour is obtained which turns blue on addition of NaOH(aq.) .
4. (a) In arylhalide the halogen, ortho or para to electron withdrawing group is removed.
7. (b) Aldol condensation

10. (b) CH3COONH4 
Al2 O3
 CH3 CONH2 
H3 O
 CH3 COOH
(A)
18. B
Since - NO2 is ring deactivating group therefore Friedal Crafts acylation will not take place.
19. C
3o alkyl halide will undergo SN1 where as 1o alkyl halide will give SN2 reaction.
20. B

SN1 reactions are favoured when stable carbocation is formed.  CH2  CH  CHCH3 is most stable and

CH2  CH is least stable carbocation out of 1o and 2o, 2o carbocation is more stable than 1o.
21. B
JEE MAINS
23
Lone pair on nitrogen is in conjugation with the ring hence will activate the ring towards substitution
reaction (alkylation).
22. D
Fact.
23. B
C – D bond is stronger than C – H bond. In E2 the RDS is step in which C–H or C–D bond is broken.
24. A
Dipole moment depends upon the angle between the vectors. In ortho substituted product the angle is
minimum hence  is maximum.

  2C lC l cos   , where C lC l is the vector moment and  is the angle between two vector
2
moments.
25. A
In Hydro boration oxidation the alcohol formed is according to anti markornikoff’s rule.
3 + B2H6 H
CH2 B
CH2 3
H2O2, OH-
H
CH2 OH
26. C
3o carbocation is most stable due to +I effect and hyper conjugation  has least activation energy to
form.
27. B
2CHI3  6Ag  6AgI  CH  CH.
28. C
Alcohols have high b.p due to H – bonding.
29. B
Hygroboration oxidation gives anti markownikoff’s product where are oxymercusation de mercuration
gives markownikoff’s product.
30. B
In Cannizaro’s reaction –CHO is oxidised to give –COOH and –CHO is reduced to form –CH2OH. In
presence of NaOH, –COOH group will turn into salt.
MATHS SOLUTIONS :
1. x! (x  1)!  0  x I  {I}



 4 as tan1 x 
1
2 tan x
.
2
(x  4)(x  10)
 0
(x  1)!(x  1)
 x  {5,6,...,9}
JEE MAINS
24
2. There are 4 intersection points
3sin x  4cos x  3 3sin x  4cos x  2  1

3. y 
3sin x  4cos x  2 3sin x  4cos x  2
1
 1
5  3sinx  4cos x  5
3  3sinx  4cos x  2  7
1  1  1 
 ,     , 
3sin x  4cos x  2  3  7 
1  2 8 
1   ,    , 
3sin x  4cos x  2  3  7 
4. (a) f(x)  g(x)  x when 0  x  1
1; x  0
 1; x  0

(b) f(x)  1; x  0 sgn(sgn(x))  0 ; x  0
0 ; x  0
 1; x  0

sin2 2x sin2 2x
(c) g(x)  1  and f(x)  1 
2 2
(d) Domain of f(x) and g(x) are not identical
2
5. p  ,
[a]
Hence, [a]  2  [a]  4
 4a5
 2 tan1 x 
lim x  1
  
le
x
6.  eL
 2 tan1 x   
Where, L  lim x  
x   
  
2     cot 1 x  
  2 
L  lim x
x  
 1
tan1  
2.x.cot x 1
2  x 2
 lim   lim  
x   x    1 
 x 
(tan{x}  1))sin{x}
7. lim  lim f(x)
x 0 {x}({x}  1) x 0
tan(h  1).sin h tan( 1)

 lim   tan1
x 0 h(h  1) 1
tan(1  h)  1).sin(1  h) sin 1
 lim   sin1
x 0 (1  h)(1  h  1) 1
JEE MAINS
25
Hence, lim f(x) does not exist.

x 0
8. f(x)  [2x3  5]  [2x3 ]  5

Let 2x3  t
 g(t)  [t]
Where t  [2,16)
g is continuous at t = 2 and discontinuous at
t = 3, 4, …., 15 = 13 points.
9. x=a–h
    h 
cos 2a (a  h) sin 2a 
f(a )  lim  0;
h 0 h h
x=a+h
sinh   h 
f(a )  lim tan     0;
h 0 2 2 2 
Hence, f(a )  f(a )
10. f(x)  rational if x  Q in [a,b]

irrational if x  in [a, b]
Let c  Q
f(c) = irrational
f(c + h) = rational
lim through irrational
h 0
 f is discontinuous for x  Q in [a,b]
dx
11. y  ex  x, differentiate w.r.t. y, 1 = (ex +1) ;
dy
dx 1 dx  1 1
 x    ln2 
dy e  1 dy  x ln2 e  1 3
12. We have y = 2x2

(AB)2  (xB  x A )2  (2xB2  2x2A )2  5
Or (xB  x A )2  4(xB2  x2A )  5
dxB
Differentiating w.r.t. xA and denoting D
dx A
2(xB  x A )(D  1)  8(xB2  x2A )(2xBD  2x A )  0
Put x A  0; xB  1
2(1  0)(D  1)  8(1  0)(2D  0)  0
1
2D  2  16D  0  D 
9
13. y  f(x)  f(2x)
y'  f '(x)  2f '(2x)
y'(1)  f '(1)  2f '(2)  5 …(i)
and y'(2)  f '(2)  2f '(4)  7 …(ii)
Now, let y  f(x)  f(4x)
y'  f '(x)  4f '(4x)
y'(1)  f '(1)  4f '(4) …(iii)
Substituting the value of f '(2)  7  2f '(4) in eqn. (i),
JEE MAINS
26
f '(1)  2[7  2f '(4)]  5

f '(1)  4f '(4)  19
14. Hence x   is defined only for x   but sin-1 (ln x) is not defined, so no common domain so integral
does not exist.
15. f '(x)  (1  cos x)sinx

(1  cos x)sin x
lim is finite non-zero then n = 3
x 0 xn
e3x  ex
16.  e4x  e2x  1dx
e2x (ex  e x )
=  e2x (e2x  1 e2x ) dx
(ex  e x )
=  (ex  e x )2  1dx
= tan1(ex  e x )  C
17. We have I   (x7m1  x2m1  xm1 )(27m  7x2m  14xm )1/ m dx

Now put 2x7m  7x2m  14xm  tm
14m(x7m1  x2m1  xm1 )dx  mtm1dt
1 t m 1
 I
14  tm1(tm )1/ m dt 
14(m  1)
C
m 1
(2x7m  7x 2m  14xm ) m

14(m  1)
2x  1 2x  1
18.  (x  4x  1)3 / 2
2
dx  
 4 1
3/2
dx
x 1   2 
3
 x x 
2x 2  x 3
 3/2
dx
 4 1
 1  x  2 
x
1 4
Now put 2   1  t 2
x x
/4 /4
19. I1   ln(sin x  cos x)dx   ln (cos x  sin x) dx (using property)
 / 4  / 4
/4 /4 /2
 2I1   ln cos2xdx  2 ln (cos2x) dx   ln (cos t) dt
 / 4 0 0
Where 2x = t
/2
 0
ln(sin t)dt  I  I1  I/ 2
/2
20. I {tan x} dx …(i)
 / 2
/2
Using property 2I   {tan x}  { tan x} dx
 / 2
Adding eqns. (i) and (ii),

/2
2I   ({tan x}  { tan x}) dx
 / 2
JEE MAINS
27
/2
 2I   1 dx [ {x}  {x}  1 for x I]
 / 2

 I
2
1 0 1 /2
21.  / 2
(1) dx   xdx   1 dx  
1 0 1
x dx
2 
 1 
8 2
73  65  73 
6
22. 0
10
[cos x] dx   [cos x] dx  
0 6
10
[cos x] dx   6510 [cos x] dx
10
65x 73 
2
 3 [cos x] dx   2
0 dx   10
65  dx
0 6
10
8 19
 3  0  
10 5
  1
I   fx  …(i)
x 
23. dx
0 
1
Put x 
t
 1  dt
I   f   t 2
0 t  t
  1  dx
I   f x   2 …(ii)
0  x x
Adding eqns. (i) and (ii),
  1  1 1
2I   f  x   1  2  dx put x   t
0  x   x  x
 
  f(t) dt  2 f(x) dt  
 0

 I
2
24. f(x)  log1/ 3 (x2  5x  6) : Domain of f(x) is x < 2 or x > 3
ln(x 2  5x  6)
f(x) 
 ln3
1  (2x  5)  1 (2x  5)
f '(x)      .

ln3 x  5x  6
2
 ln3 (x  2)(x  3)
 f '(x)  0 for x  (,2)
25. LMVT is not applicable to

  1 1
   
f(x)   xe  |x| x  , x0

0, x0
  2x
 xe , x  0
f(x)   x, x0
0, x0

f(x) is continuous at x = 0 but not differentiable at x = 0
f '(01 )  1; f '(0 )  0
26. f '(x)  (sinx  cos x)(ex  2)(x  1)3 (x  2)5
JEE MAINS
28
 5
f '(x)  0  x  , ,log2,1,2
4 4
5
Clearly f has local maxima at ln2,1, .
4
dy
27. If x  0, y  e3x   3e3x1
dx
dy
x  0, y  e x
  e x2
dx
1
 3e3x1 .e x2  1  e3x1  x2 
3
Which is never possible for x1 > 0 and x2 > 0.
28. g'(x)  (3  x) | f '(3  x) | (3  x) | f '(3  x) |

| f '(3  x) | (6)
f '(3  x)  f '(3  x)
g'(x)  0x R
29. For major axis to be y-axis

f( 2  5)  f(4  2)
2  4  3  0
 
cos 2x x
30. f(x)   4

(sin x  cos x) x 
 4

Differentiable at x=
4
    
 2sin2      cos  sin      2
 4  4 4
 
cos 2x x
 f(x)   4

 2(cos x  sin x) x 
 4
 
Clearly, f '(x)  0x   0, 
 2
Hence, decreasing function.
 
Applying LMVT in  0, 
 2
 
f    f(0)
 2  2  1 2( 2  1)
f '(c)   
  
0
2 2
  
And f '    2 ; f '(x)  2 for unique value of x 
 4 4

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FIITJEE - JEE (Mains)

PHYSICS, CHEMISTRY & MATHEMATICS

3. The test is of 3 hours duration.

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

1. Three bulbs A, B and C are connected as shown in figure. The C bulb B

(c) A will glow less brightly

5. Current shown in figure is

7. A battery of emf o  12V is connected across a 4 m long

8. A charged sphere of mass m and charge – q starts sliding along the

9. A particle of charge (+q) and mass m moving under the influence of

(A) (B) (C) (D)

The force experienced by the dipole is

(A) W 1 > W 2 (B) W 1 < W 2 (C) 2W 1 = W 2 (D) W 1 = W 2 =0

(A) Potential difference across BC is twice that across AB

20. Charge on plate B of capacitor (at steady state)is

21. Heat generated in the circuit when switch is shifted from 1 to 2 is

(a) 12 F (b) 3.9 F K3  6 d

(a) shall increase along the positive X-axis

30. Find the equivalent resistance across AB. A

2. Liebermann test is given by which of the following

3. Which is stronger base ?

(a) NH2 (b) (CH3 )3 N (c) Et 3N (d) Et 2NH

4. The major product (X) in the following reaction

6. Molisch’s test given by -

(a) (b) (c) (d)

8. In the following reaction

9. The correct order of acidity of the following compound

(a) (b) (c) No Reaction (d) none of these

(a) (b) (c) (d) none of these

13. Thermosetting polymer is/are

14. Artificial sweeting agent is

15. Free energy profile for given reaction is

Reaction co-ordinate Reaction co-ordinate

(c) Free (d) Free

Reaction co-ordinate Reaction co-ordinate

(a) CH2  CH  CH  CH  COOH (b) CH3  CH  CH  CH2  COOH

18. In the following reaction, which of the following step is wrong?

(A) Step 1 (B) Step 2

(C) Step 1 & 3 Both (D) Step 1 & 2 both

(A) I, II (B) II, I

(C) I, III (D) III, I

20. Arrange the following in increasing order of SN1 reactivity -

I. CH3CH2Br II. CH2 CH CH CH3 III. CH2 CH Br IV. CH3 CH CH3

substitution) at fastest rate

22. Which of the following belong to the class of natural polymers?

23. In the following reactions :

(C) SN2 (D)  -elimination

24. Which is the correct order of dipole moment of following compounds?

(A) I > II > III (B) I > III > II

(C) I < II < III (D) III > I > II

25. The product formed in following reaction B2H6 H2O2

26. The energy of activation is lowest for which reaction?

(A) Ethene (B) Ethyne

(C) Ethane (D) Silver iodate

28. CH3  CH  O  CH2  CH  CH3

29. Hg  OAc 2 ,H2O BH3 ,THF

30. COOH 46% NaOH

COONa COONa (D) COOH COOH

 4)(x  4)(x  10)

2. Number of solution of the equation tan x = 2x in the interval [,2]

4. Which of the following function are non-identical ?

Batch : Date of Examination :