BIWEEKLY TEST – 3

DATE : 23/06/2018 TIME : 180 Min.

EAS : (PCM)

MATHEMATICS
1. The equation (cos p  1) x2 + (cos p) x + sin p = 0, where x is a variable, has real roots. Then the
interval of p may be any one of the followings
(A) (0, 2  ) (B) (  , 0) (C) (  /2,  /2) (D) (0,  )
2. If sinA = sinB, cosA = cosB, then the value of A in terms of B is
(A) n  + B (B) n  + (1)n B (C) 2n  + B (D) 2n   B

3. The number of roots of the equation x + 2 tan x = in the interval [0, 2  ] is
2
(A) 1 (B) 2 (C) 3 (D) infinite
4. Let [x] = the greatest integer less than or equal to x and let f (x) = sin x + cos x. Then the most
   
general solutions of f (x) =  f    are
  10  
 
(A) 2n  + , n  Z (B) n  , n  Z (C) 2n  + , n  Z (D) none of these
2 4
5. Number of values of x  R which satisfy the equation cos (  x  4) cos(  x ) = 1 is
(A) 1 (B) 0 (C) 2 (D) none of these
   
6. If tan  sin   = cot  cos   , then sin  + cos  is equal to
2  2 
(A) 0 (B) 1 (C) 1 (D) 1 or 1
7. The general solution of the equation sinx  3sin2x + sin3x = cosx  3cos2x + cos3x is
 n 
(A) n  ,n  I (B)  ,n  I
8 2 8
 n   3
(C) (1)n   + , n  I (D) 2n + cos1   ,n  I
 2  8 2

8. If  is a root of 25 cos2   5 cos   12  0,    , then sin 2 is equal to
2
24 24 13 13
(A) (B)  (C) (D) 
25 25 18 18
9. If tan   tan2  3 tan  tan2  3, then
(6n  1) (6n  1)
(A)   , n   (B)   , n  
18 9
(3n  1)
(C)   , n   (D) None of these
9
10. The number of values of x in the interval [0, 5] satisfying the equation 3 sin2x – 7sin x + 2 = 0 is
(A) 0 (B) 5 (C) 6 (D) 10
11. If cos   cos 2   cos 3   0, then the general value of  is
2  2 
(A)   2m  (B)   2m  (C)   m  ( 1)m (D)   m  ( 1)m
3 4 3 3
12. If 0  x < 2  , then the number of real values of x, which satisfy the equation
cos x + cos 2x + cos 3x + cos 4x = 0, is
(A) 5 (B) 7 (C) 9 (D) 3
13. If | sinx  cos x |  | sinx |  | cos x |, then x belongs to the quadrant
(A) I or III (B) II or IV (C) I or II (C) III or IV
14. The number of integral values of k for which the equation 7 cos x  5 sin x  2k  1 has a solution is
(A) 4 (B) 8 (C) 10 (D) 12
15. Number of solutions of 2sin(|x|) = 3|cosx| in [–  ,  ] is equal to
(A) 2 (B) 4 (C) 6 (D) none of these

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  2 3
16. The value of cos .cos .cos is
7 7 7
1 1 1 1
(A)  (B) (C) (D) 
8 8 16 32
17. The value of sin3 10  sin3 50  sin3 70 is equal to
3 3 3 3
(A)  (B) (C)  (D) 
2 4 4 8
 3 15 12
18. If     and    2 , sin   and tan    , then sin     is
2 2 17 5
21 21 7 71
(A)  (B) (C)  (D)
221 221 221 221
A
19. Let  1400 then the value of 1  sin A  1  sin A 
2
A A A A
(A) 2 sin (B) 2 cos (C) 2 sin (D) 2cos
2 2 2 2
20. If cos 25  sin25  K, then cos50 is equal to
0 0 0

(A) K 2  K 2 (B)  2  K 2 (C) 2  K 2 (D)  K 2  2

 3 5 7 9 11 13 
21. The value of sin .sin .sin sin .sin .sin .sin
14 14 14 14 14 14 14
1 1 1
(A) (B) (C) (D) None of these
64 32 16
x y z
22. If   , then x + y + z is equal to
cos   2   2 
cos     cos    
 3   3 
(A) 1 (B) 1 (C) 0 (D) none of these
  3      
23. The expression 3 sin4      sin4  3      2 sin6      sin6  5    is equal to
  2    2  
(A) 0 (B) –1 (C) 1 (D) 3
tan A cot A
24. The expression  can be written as
1  cot A 1  tan A
(A) sinA cosA + 1 (B) secA cosecA + 1 (C) tanA + cotA (D) secA + cosecA
3 sin A  cos A
25. If tan A  and A lies in third quadrant then is equal to
4 cot A
20 21 20 21
(A) (B) (C) (D)
21 20 21 20
4 5 
26. Let cos       and let sin       , where 0  ,   . Then tan 2 
5 13 4
56 19 20 25
(A) (B) (C) (D)
33 12 7 16
4 cos 59o cos1o cos 61o
27. 
cos 3o
(A) 1 (B) 2 (C) 3 (D) 0

28. The value of 5 cos   3 cos(  )  3 lies between
3
(A) –4 and 4 (B) –4 and 6 (C) –4 and 8 (D) –4 and 10
29. A person observes the angle of deviation of a building as 30o . The person proceeds towards the
building with a speed of 25( 3  1)m / hour . After 2 hours, he observes the angle of elevation as
45o . The height of the building (in metres) is
(A) 100 (B) 50 (C) 50( 3  1) (D) 50( 3  1)

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 pq  
30. If cosec  , then cot 2    
pq  4 2
p q
(A) (B) (C) pq (D) pq
q p

PHYSICS
dy
31. y = x3 + 2x2 + 7x + 8 then will be
dx
(A) 3x2 + 2x + 15 (B) 3x2 + 4x + 7 (C) x3 + 2x2 + 15 (D) x3 + 4x + 7
dy
32. If y = x2 sin x, then will be
dx
(A) x2 cos x + 2x sin x (B) 2x sin x
2
(C) x cos x (D) 2 x cos x
33. Double differentiation of displacement w.r.t. time is :
(A) acceleration (B) velocity (C) force (D) none of these
2
d y
34. If y = x3 then is
dx 2
(A) 6x2 (B) 6x (C) 3x2 (D) 3x
 x dx is equal to
3
35.
x4 x4
(A) 3x2 (B) C (C) (D) 4x3
4 4
36. The displacement of a body at any time t after starting is given by s = 15t – 0.4t2. The velocity of the
body will be 7 ms–1 after time
(A) 20 s (B) 15 s (C) 10 s (D) 5 s
37. A stone thrown upwards from ground level, has its equation of height h = 490 t – 4.9 t2 where ‘h’ is
in metres and t is in seconds respectively. What is the maximum height reached by it ?
(A) 10250 m (B) 12250 m (C) 22250 m (D) 14250 m
38. ˆ
The unit vector along A  2i  3 j isˆ
2iˆ  3ˆj 2iˆ  3ˆj 2iˆ  3ˆj
(A) 2iˆ  3ˆj (B) (C) (D)
2 3 13
39. For the figure shown
(A) A  B  C (B) B  C  A
(C) C  A  B (D) A  B  C  0
40. Parallelogram law of vectors is applicable to the addition of
(A) Any two vectors (B) Two scalars
(C) A vector and a scalar (D) Two vectors representing same physical quantity
41. ˆ ˆ ˆ ˆ ˆ ˆ
Vectors A  i  j  2k and B  3i  3 j  6k are
(A) Parallel (B) Antiparallel
(C) Perpendicular (D) at acute angle with each other
42. The displacement of a body from a reference point is given by, x  2t  3, where ‘x’ is in metres
and it is non negative number, t in seconds. Select the wrong option
(A) is at rest at t = 3/2 (B) is speeding up for t > 3/2
(C) is retarded for t < 3/2 (D) is in uniform motion
43. A ball is thrown vertically upwards from the ground. It crosses a point at the height of 25 m twice at
an interval of 4 secs. The ball was thrown with the velocity of
(A) 20 m/sec. (B) 25 m/sec. (C) 30 m/sec. (D) 35 m/sec.
44. The distance travelled by a freely falling body is proportional to
(A) the mass of the body (B) the square of the acceleration due to gravity
(C) the square of the time of fall (D) the time of fall

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45. The acceleration–time graph of a particle moving on a straight line is
as shown in figure. The velocity of the particle at time t = 0 is 2m/s.
The velocity after 2 seconds will be
(A) 6 m/s (B) 4 m/s
(C) 2 m/s (D) 8 m/s

46. A parachutist drops freely from an aeroplane for 10 s before the parachute opens out. Then he
descends with a net retardation of 2.5 ms–2. If he bails out of the plane at a height of 2495 m and g
= 10 ms–2, his velocity on reaching the ground will be
(A) 2.5 ms–1 (B) 7.5 ms–1 (C) 5 ms–1 (D) 10 ms–1
47. The displacement of a body is given to be proportional to the cube of time elapsed. Acceleration of
the body is proportional to
(A) t4 (B) t3 (C) t2 (D) t
48. The graph shown in the figure shows the velocity v versus time t of a
body. Which of the graphs shown in figure represents the corresponding
acceleration versus time graphs?

(A) (B)

(C) (D)
49. A car starts from rest and moves with constant acceleration. The ratio of the distance covered in the
nth second to distance covered in n seconds is
2 1 2 1 2 1 2 1
(A) 2  (B) 2  (C)  2 (D)  2
n n n n n n n n
50. A particle moves through the origin of an xy-cordinate system at t = 0 with initial velocity u = 4i - 5 j
m/s. The particle moves in the xy plane with an acceleration a = 2i m/s 2. Speed of the particle at t =
4 second is
(A) 12 m/s (B) 8 2 m/s (C) 5 m/s (D) 13 m/s
51. The instantaneous velocity of a particle is equal to time derivative of its position vector and the
instantaneous acceleration is equal to time derivative of its velocity vector. Therefore:
(A) the instantaneous velocity depends on the instantaneous position vector
(B) instantaneous acceleration is independent of instantaneous position vector and instantaneous
velocity
(C) instantaneous acceleration is independent of instantaneous position vector but depends on the
instantaneous velocity
(D) instantaneous acceleration depends both on the instantaneous position vector and the
instantaneous velocity
52. Distance between a frog and an insect on a horizontal plane is 10 m. Frog can jump with a
maximum speed of 10 m/s. g =10 m/s2. Minimum number of jumps required by the frog to catch
the insect is
(A) 5 (B) 10 (C) 100 (D) 50
53. A ball A is projected with speed 50 ms–1 at an angle 37° with horizontal. At the same time, a second
ball B is projected in a direction shown in the figure with speed 60 ms–1 from a point 91 m from A.
Both ball collide in air. (Given, 3  1.7 )
The time when collision takes place is

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 –1
uA = 50ms uB

A 37°  B
91m
(A) 1 s (B) 2 s (C) 3 s (D) 4 s
–2
54. A particle A is moving towards North with an acceleration of 5 ms and particle B is moving North–
East direction with an acceleration of 5 2 m/s–2. Find relative acceleration of particle A with respect
to particle B
(A) 5 ms–2 towards East (B) 5 ms–2 towards West
(C) 5 ms–2 towards South (D) 5 2 ms–2 towards West
55. Two buses of equal 5 m lengths are moving with the same velocity in the same direction on a
highway. The first bus is 40 m ahead of the second bus. The driver of the second bus thinks to
overtake the first bus and gives an acceleration of 1ms–2 to the bus. After what time the second bus
just passes the first bus ?
(A) 5 s (B) 10 s (C) 15 s (D) 20 s
–2
56. A man starts from rest with an acceleration 1ms at t = 0. At t = 3 3 s, it appears to him that rain
falls with the velocity 3 ms–1 vertically downwards. The velocity of actual rain fall is
(A) 3 3 ms1 (B) 3 ms1 (C) 6ms1 (D) 6 3 ms1
57. A river is flowing from West to East at a speed of 5 m min –1. A man on the South bank of the river,
capable of swimming at 10 m min–1 in still water, wants to swim across the river in the shortest time.
He should swim in a direction
(A) due North (B) 30° East of North
(C) 30° West of North (D) 60° East of North
58. A boat which has a speed of 5 kmh–1 in still water, crosses a river of width 1 km along the shortest
possible path in 15 min. The velocity of the river water (in kmh–1) is
(A) 1 (B) 3 (C) 4 (D) 41
59. The wind is blowing towards East with a speed of 30 ms–1. The air speed of an aeroplane is
50 ms–1. The aeroplane has to go from city A to city B 1200 km away due North. Choose the correct
statement.
(A) The direction in which the pilot should head the aeroplane to reach the city B is 37° West of
North
(B) The time taken by the plane to fly from city A to city B is 500 sec.
(C) The time taken by plane to fly from city A to city B is 100 sec.
(D) none of the above
60. A ball A is projected with speed 50 ms–1 at an angle 37° with horizontal. At the same time, a second
ball B is projected in a direction shown in the figure with speed 60 ms–1 from a point 91 m from A.
Both ball collide in air. (Given, 3  1.7 )
The value of  is
–1
uA = 50ms uB

A 37°  B
91m
(A) 30° (B) 60° (C) 53° (D) 45°

CHEMISTRY
61. According to Bohr's Model of hydrogen atom
(A) total energy of the electron is quantized
h
(B) angular momentum of the electron is quantized and given as l(l  1) ·
2
(C) both (A) and (B)
(D) none of these
62. The ratio of radii of first orbits of H, He+ and Li2+ is
(A) 1 : 2 : 3 (B) 6 : 3 : 2 (C) 1 : 4 : 9 (D) 9 : 4 : 1
63. The ratio of (E2 – E1) to (E4 – E3) for the hydrogen atom is approximately equal to
(A) 11 (B) 12 (C) 15 (D) 10

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64. How many electrons will have m (magnetic quantum number) = 0 in Fe3+ ion?
(A) 12 (B) 13 (C) 11 (D) 14
65. The radius of second stationary orbit in Bohr’s atom is R. The radius of the third orbit will be
9
(A) 3 R (B) 9 R (C) R (D) 4 R
4
66. The work function for a metal is 4 eV. To emit a photo-electron of zero velocity from the surface of
the metal, the wavelength of incident light should be
(A) 2700 Å (B) 1700 Å (C) 5900 Å (D) 3100 Å
67. The wave number of the first emission line in the H–atom spectrum in the Balmer series in terms of
Rydberg’s constant (RH) is given by
5RH 3RH 7RH 9RH 1
(A) cm1 (B) cm1 (C) cm1 (D) m
36 4 144 400
68. Which one of the following set of quantum numbers is not permitted?
1 1
(A) n = 3, l = 3, m = 0, s = + (B) n = 3, l = 2, m = + 2, s = –
2 2
1 1
(C) n = 3, l = 1, m = – 1, s = – (D) n = 3, l = 0, m = 0, s = + .
2 2
–1
69. Assuming Rydberg’s constant (RH) to be 109670 cm , the longest wavelength line in the Lyman
series of the hydrogen spectrum is
(A) 1215.8 Å (B) 1025.8 Å (C) 972.6 Å (D) 949.8 Å
70. The orbital diagram in which the Aufbau principle is violated is
2s 2p 2s 2p
(A) (B)

2s 2p 2s 2p
(C) (D)
71. The maximum value of m for an electron in fourth energy level is
(A) +4 (B) +3 (C) +5 (D) +9
72. In Mn2+ ion, the number of unpaired electrons is
(A) 2 (B) 3 (C) 4 (D) 5
73. If the speed of electron in the Bohr’s first orbit of hydrogen atom be x, then the speed of the electron
in third Bohr orbit is
(A) x/9 (B) x/3 (C) 3x (D) 9x
74. In which orbit of hydrogen atom is the angular momentum h/?
(A) 1 (B) 2 (C) 3 (D) not possible
75. Bohr’s theory is not valid for the species
(A) H atom (B) He+ ion (C) Li+ ion (D) Li2+ ion
th +
76. If electrons are excited to 4 shell in He ion, the number of wavelengths emitted by electrons
during deexcitation are
(A) 4 (B) 5 (C) 6 (D) 7
77. The first excitation energy for hydrogen atom would be
(A) 13.6 eV (B) 13.6 eV (C) 3.4 eV (D) 10.2 eV
78. Assuming their velocity to be same, which subatomic particle possesses smallest deBroglie
wavelength?
(A) an electron (B) a proton (C) an alphaparticle (D) all have same 
79. The ratio of wavelength of the limiting line of Paschen and Balmer series of hydrogen atom is
9 4 3 2
(A) (B) (C) (D)
4 9 2 3
80. Ultra violet light of 6.2 eV falls on aluminium surface (work function = 4.2 eV). The kinetic (in Joule)
of the fastest electron emitted is approximately
(A) 3.2  1021 (B) 3.2  1019 (C) 3.2  1017 (D) 3.2  1015

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81. In Bohr’s hydrogen atom, the electronic transition emitting light of longest wavelength is
(A) n = 5 to n = 4 (B) n = 4 to n = 3 (C) n = 3 to n = 2 (D) n = 2 to n = 4
82. The ionization potential of hydrogen atom is 13.6 eV. The energy required to remove an electron
from the n = 2 state of hydrogen atom is
(A) 27.2 eV (B) 13.6 eV (C) 6.8 eV (D) 3.4 eV
83. The wavelength associated with a golf ball weighing 200 g and moving at a speed of 5 m/h is of the
order
(A) 1010 m (B) 1020 m (C) 1030 m (D) 1040 m
84. If the radius of first Bohr orbit is x, then de Broglie wavelength of electron in 4th orbit is nearly
(A) 8x (B) 6x (C) 4x (D) 2x
85. 3 mol of a mixture of FeSO4 and Fe2(SO4)3 required 100 ml of 2 M KMnO4 solution in acidic
medium. Hence the mole fraction of FeSO4 in the mixture is
(A) 1/3 (B) 2/3 (C) 2/5 (D) 3/5
86. How many ml of aqueous solution of KMnO4 containing 158 g litre1 must be used for complete
conversion of 83 g of KI to I2 in the presence of H2SO4?
(A) 90.36 ml (B) 100 ml (C) 85.09 ml (D) 65.05 ml
87. The anion nitrate can be converted into ammonium ion. The equivalent weight of NO 3 ion in this
reaction would be
(A) 6.20 (B) 7.75 (C) 10.5 (D) 21.0
88. When the equation Cr2O72 + H + I  Cr + I2 is balanced, the correct coefficient for I(aq) is
+  3+

(A) 8 (B) 6 (C) 10 (D) 3

89. 0.126 g of an acid requires 20 ml of 0.1 N NaOH for complete neutralization. Equivalent weight of
the acid is
(A) 45 (B) 53 (C) 40 (D) 63
90. Which of the following set of quantum numbers belong to highest energy?
1 1
(A) n = 2, l = 1, m = 0, s = + (B) n = 3, l = 0, m = 0, s = +
2 2
1 1
(C) n = 4, l = 0, m = 1, s = + (D) n = 4, l = 1, m = 1, s = +
2 2

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 ANSWERS

MATHEMATICS
1. D,
For the quadratic equation to have real roots, we must have
cos2p  4 sinp (cos p  1)  0
 (cos p  2 sinp) 2  4 sin2p + 4 sinp  0
 (cos p  2 sinp)2 + 4 sin p (1  sin p)  0
Now, 0 < p < ,  4sin p (1  sin p) > 0
and, (cos p  2sin p)2  0
Thus, (cos p  2 sin p)2 + 4 sin p(1  sin p)  0 for 0 < p < .
Hence, the equation has real roots for 0 < p < .
2. C,
sin A = sin B, cos A = cos B  A = 2n + B, clearly this satisfies both the relations for all n  Z.
3. C,
We have
  x
x + 2tan x =  tan x = 
2 4 2
 x
It can be easily seen from the graphs of the curves y = tan x and y =  , in the interval [0, 2],
4 2
that they intersect at three points. The abscissa of these three points are roots of the equation.
4. A,
  
f   = sin 18° + cos 18° = 2sin (45° + 18°) = 2sin 63°.
 10 
1   
As sin 63° > sin 45° = and sin 63° < 1, we get 1 < f   < 2
2  10 
   
  f    = 1. So, the equation is sin x + cos x = 1.
  10  
  1  
 cos  x    or x = 2n 
 4 2 4 4
5. A,
cos (  x  4)cos(  x )  1
 {cos(  x  4  1 and cos ( x ) = 1}
or {cos(  x  4)  1 and cos (  x )  1}
( If one of the factors is numerically less than 1, then the other is numerically greater than 1 ;
which is not possible as |cos|  1 for all )
 either both x  4 and x are even integers or both x  4 and x are odd integers.
 x = 4 is the only solution.
6. D,
   
If tan  sin    cot  cos  
2  2 
    
 tan  sin    tan   cos  
2  2 2 
  
 sin   n   cos ,n  I
2 2 2
 sin + cos = 2n + 1, n  I
 sin + cos = 2n + 1, n  I; but  2  sin   cos   2, therefore, sin + cos = 1 or 1.
7. B,
The given equation can be written as
(sin3x + sinx)  3sin2x = (cos3x + cosx)  3cos2x
 2sin2x cosx  3sin2x = 2cos2x cosx  3cos2x
 2sin2x cosx  3sin2x  2cos2x cosx + 3cos2x = 0

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  (sin2x  cos2x) (2cosx  3) = 0
 sin2x  cos2x = 0 (cosx  3/2)

 tan2x = 1  2x = n + ,n  I.
4
8. B,
 is a root of 25cos2   5cos   12  0
 25cos2   5cos   12  0
4 3
 cos    ,
5 5

But    
2
4
 cos    ( cos   0)
5
3
 sin  
5
3 4 24
 sin 2  2 sin  cos   2    
5 5 25
9. C,
tan   tan 2  3 tan  tan 2  3  tan   tan2  3(1  tan  tan2)
tan   tan2   n  
  3  tan3  tan    3  n       (3n  1) .
1  tan  tan2 3 3 3 9 9
10. C,
3 sin2x – 7sin x + 2 = 0
(sin x – 2) (3 sin x – 1) = 0
1
sin x = 2 or sin x =
3
1
sin x = [ sin x  2]
3
 x will have 6 values between [0, 5].
11. A,
 cos   cos2  cos3  0  (cos   cos3)  cos2  0
 2cos2.cos   cos2  0  cos2 (2cos   1)  0
   1 2 2
 cos 2  0  cos  2  2m     m  or cos     cos    2m  .
2 2 4 2 3 3
12. B,
0  x < 2
cos x + cos 2x + cos 3x + cos 4x = 0
(cos x + cos 4x) + (cos 2x + cos 3x) = 0
5x 3x 5x x
2cos cos  2cos cos  0
2 2 2 2
5x  x
2cos 2cos x cos   0
2  2
5x x
cos 0 or cos x = 0 or cos  0
2 2

x
 2n  1  or x   2n  1

or x   2n  1 
5 2
  3 7 9  3 
x   , , , , , , 
5 5 5 5 2 2
Number of solution is 7
13. A,
| sinx  cos x || sinx |  | cos x |
In Ist & IIIrd quadrant sin x and cos x are of same sign.

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14. B,
We know that
  a2  b2  a cos   b sin   a2  b2
  74  7cosx  5sinx  74
  74  2k  1  74  8.6  2k  1  8.6
 4.8  k  3.8 (considering only integral values)
 k can take 8 integral values
15. B,
Figure clearly indicates the graph of
y = 3|cosx| and y = 2sin(|x|) meets
3
3|cosx|
2
2(sin|x|)
y=1

O
- -/2 /2 

four times in [–  ,  ], Hence there are four solution.

16. B,
 2 3
cos .cos .cos
7 7 7
8
sin
 2 4 7 1
  cos .cos .cos 
7 7 7  8
23 sin
7
17. D,
sin3 10  sin3 50  sin3 70
1
  3 sin10  sin30    3 sin50  sin150    3 sin70  sin 210 
4
1 3 1  3 3
 3  sin10  sin 50  sin 70     3  sin10  2 cos 60  sin10     
4 2 4  2 8
18. B,
12 5
sin    , cos  
13 13
8
cos   
17
 12 8   5 15  21
So, sin      sin .cos   cos .sin            
 13 17   13 17  221
19. C,
A A A A
cos  sin  cos  sin
2 2 2 2
 A A  A A
  cos  sin    cos  sin 
 2 2  2 2
20. A,
cos250  sin250  K
Squaring,
1  sin500  K2
sin500  K2  1
cos500  1  sin2 500

 
2
 1 K2  1  2K 2  K 4  K 2  K 2
21. A,

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   13   3 11   5 9  7
sin 14 .sin 14  sin 14 sin 14  sin 14 sin 14  .sin 14
   
3
= sin2  .sin2 .sin2 5 
14 14 14
 3 5
Let y = sin sin sin
14 14 14
 2 4 1
or, y = sin cos cos =
14 14 14 8
22. C,
x y z
Given     (say)
cos   2   2 
cos    cos   
 3   3 
  2   2   2 
 x + y + z =  cos   cos     cos    =  cos   2 cos  cos   0
  3   3   3 
23. C,
3 cos4   sin4    2 cos6   sin6  

  


  
2 3
 3  cos2   sin2   2 sin2 .cos2    2  sin2   cos2   3 sin2 .cos2 . sin2   cos2  
   
 3 1  2 sin .cos    2 1  3 sin .cos   = 3  2  1
2 2 2 2

24. B,
tan2 A 1 1  2 1 
Expression =    tan A 
tan A  1 tan A  tan A tan A  1 
2
tan A 
tan2 A  tan A  1
  tan A  cot A  1
tan A
 sec A  cosec A  1
25. B,
3 3 4 4
tan A  , sin A   , cos A   and cot A 
4 5 5 3
3 4
 
sin A  cos A 7 3 21
now  5 5   
cot A 4 5 4 20
3
26. A,
3 5
tan(  )  and tan(  ) 
4 12
3 5

tan(  )  tan(  )
  4 12
1  tan(  ) tan(  ) 1  3 . 5
4 12
(9  5)4 14  4 56
  
48  15 33 33
27. A,
1 cos 3o
4 1
4 cos 3o
28. D,
  
5 cos   3 cos(  )  3 = 5cos   3[cos cos  sin .sin ]  3
3 3 3
3 3 3  13 3 3 
= [5 cos   cos   sin ]  3 =  cos   sin    3
2 2  2 2 
 

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 2 2
 13   3 3   13   13   3 3 
2 2
3 3
    
  cos   sin     2    2 
 2   2   2 2     
 13 3 3 
7   cos   sin    7
 2 2 
 13 3 3   13 3 3 
 7  3   cos   sin    3  7  3  4   cos   sin    3  10
 2 2   2 2 
   
So, the value lies between – 4 and 10.
29. B,
30°

30° 45°
R
S h Q
50(3–1)
PQ
In PQR,tan 30o 
QR
1 h
 
3 50( 3  1)  h
 3h  50( 3  1)  h
 ( 3  1)h  50( 3  1)  h  50 metre.
30. B,
pq 1 pq
Given, cosec    ,
pq sin  p  q
  
1  sin  p  q  p  q  cos 2  sin 2  p
Apply componendo and dividendo,   
1  sin  p  q  p  q  cos   sin   q
 2 2
2
 
1  tan 2  p   p   p
    tan2      cot 2    
 1  tan   q  4 2 q  4 2 q
 2

PHYSICS
31. B,
32. A,
y  x 2 sin x
dy d d  2
 x2 sin x  sin x x
dx dx dx
 x2 cos x  2x sin x
33. A,
dx d2 x
 v  2  acceleration
dt dt
34. B,
35. B,
x4
 x dx  4  C
2

36. C,
37. B,

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 dx
 490  9.8t  0
dt
490
t  50 sec .
9.8
Smax  490  50  4.9  2500  12250 m
38. D,
A  2iˆ  3ˆj
2iˆ  3ˆj 2iˆ  3ˆj
A 
49 13
39. C,
40. D,
41. A,
Since B  3A, so both are parallel.
42. D,
43. C,
44. C,
For a freely falling body
1
S  gt 2 S  t2.
2
45. A,
v(2) = v(0) + area under a – t graph from t = 0 to t = 2
1
 2   2   4   6m/s.
2
46. C,
47. D,
48. B,
49. C,
1  
SN 2 a 2n  1 2n 1
  2  2
S 1 2 n n
an
2
2 1
  2
n n
50. D,
51. B,
52. B,
For minimum number of jumps, range must be maximum.
u2  10 
2

maximum range    1 meter.

g 10
53. A,
54. B,
55. B,
56. C,
57. A,
58. B,
59. A,
60. A,
CHEMISTRY
61. C,
According to Bohr's model of H-atom, both
(i) total energy of the electron is quantized and
h
(ii) angular momentum of the electron is quantized and is given as l(l  1) · and true.
2
62. B,

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 n2
r= × 0.529 Å
Z
1 1
rH : rHe : rLi2 = 1 : : =6:3:2
2 3
63. C,
 E  3E1 E E 7E1
E2  E1   1  E1   , E4  E3  1  1 
 4  4 16 9 16  9
E2  E1 3 144 108 108
   = ~ 15.
E4  E3 4 7 7 7
64. C,
Fe: 1s22s22p63s23p64s23d6
Fe3+: 1s22s22p63s23p63d5
Electron with m = 0 are 11.
65. C,
n2
rn = 0.529 Å
Z
4
r2 = 0.529 × = R (for n = 2)
Z
9 R
r3 = 0.529 × =9× (for n = 3)
Z 4
66. D,
hc 6.626  1034  3  108
 w 0 + KE (but KE = 0) ;  = 
= 3.1 × 10–7 m = 3100 Å.
 4  1.6  10 19

67. A,
1 1 1
 RZ2  2  2  n1 = 2, n2 = 3, Z = 1
  n1 n2 
1  1 1 1 5R
R    cm1
 4 9  36
68. A,
If n = 3, l  3
69. A,
1  1 1 1 1  3
 RHZ2  2  2   109670     (109670) cm1
 n  1 4  4
 1 n2 
 = 1215.8  10–8 cm i.e.,  = 1215.8 Å
70. B,
71. B,
m = (l) to (+l)
72. D,
73. B,
Z
Vn 
n
74. B,
75. C,
Li+ ion is not a monoelectronic system.
76. C,
n(n  1)
By n C formula ie. Total number of transitions = .
2 2
77. D,

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  13.6
E2  E1 =  13.6 = 10.2 eV.
4
78. C,
h
=
mV
m is maximum for alpha particle.
79. A,
1 1 1 
 RHZ2  2  2  …. (i)
P 3  
1 1 1 
 RHZ2  2  2  ….(ii)
B 2  
 Dividing (ii) by (i),
1
P 4 9
  .
B 1 4
9
80. B,
h =  + KE
6.2 = 4.2 + KE
KE = 2eV = 2  1.6  1019 J = 3.2  1019 J.
81. A,
Longest wavelength mean least energy. Energy difference in higher shell are less on compared to
energy difference between lower shells.
82. D,
13.6
E2 = = 3.4 eV.
22
Energy required to remove an electron from n = 2 state.
E = E – E2
13.6  (1)2
=0–
22
= 3.4 eV
83. C,
h 6.62  1034  60  60
= =
mu 200  103  5
= 23.8 × 10 = 2.38 × 1030 m.
31

84. A,
r1 = x
r4 = 16x ( r  n2)
h
also  = ……(i) (from de Broglie equation)
mv
nh
and mvr = ……(ii)
2
from (i) and (ii)
2r = n
2r
=
n
 Wavelength of electron in 3rd orbit.
2r3 2  16 x
3 = = = 8x.
n3 4

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85. A,
Equivalents of FeSO4 = Equivalents of KMnO4 = 100  103  2  5 = 1
 Moles of FeSO4 = 1 ( n FeSO 4  1 )
1
 Mole fraction of FeSO4 in the mixture = .
3
86. B,
Equivalents of KMnO4 = Equivalent of KI
V 158  5 83  1
 = (where V is the volume of KMnO4 used in ml)
1000 158 166
On solving, V = 100 ml.
87. B,
+5

NO3  NH4
(n = 8)
MNO 62
 Equivalent weight of = 3
= = 7.75.
8 8
88. B,
89. D,
No. of equivalent of acid = No. of equivalent of base
weight of acid
= 2 × 10–3 =
equivalent weight of acid
0.126
Equivalent weight of acid = = 63.
2  10 3
90. D,
For (D), the value of n + l = 3 + 2 = 5. In other cases the value of (n + l) is less than 5.
The orbital having higher (n + l) value has higher energy.

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