Beruflich Dokumente
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CHEMISTRY (THEORY)
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10. a) Give one test to distinguish between ethanol and Isopropyl alcohol.
b) Illustrate Kolbe’s reaction with a suitable example.
13. What are depressants? How would you separate ZnS and PbS ores using
depressants?
18. Illustrate elevation in boiling point with the help of vapour pressure temperature
curve of a solution. Show that elevation in boiling point is a colligative property.
19. Niobium crystallizes in bcc. If density is 8.55gcm-3 calculate the atomic radius
of Niobium .Atomic mass of Niobium is 93ủ.
20. The rate constants of a reaction at 500K and 700K are 0.02s-1 and 0.07 s-1
respectively. Calculate the values of Ea and A.
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field.
b) Write the IUPAC name of the linkage isomer of [Cr(H2O)5SCN]2+
OR
a) Draw the structure of pyrophosphoric acid.
b) Account for the following observations:
(i) SF6 does not undergo hydrolysis.
(ii) H2S is acidic whereas H2O is neutral.
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30. a) How can chromate and dichromate be interconverted? Give chemical equation.
b) How do lanthanoids differ from actinoids in oxidation states?
c) 4d and 5d series of elements show more similarity in their properties compared
to 3d elements.Why?
OR
a) Out of CrO and Cr2O3, which is more basic?
b) How does potassium iodide react with KMnO4 in (i) acidic medium (ii) faintly
basic medium.
c) Account for the following observations about transition elements.
(i) They act as good catalysts.
(ii) They show variable oxidation states.
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