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Para el sistema propileno y etileno como gas estime, la fugacidad del componente 1 en la

mezcla si la temperatura es 150°C y a 30 bar ..para y i=0.35

FUGACIDAD(Ø) EN VAN DER WAALS


Tc (K) Pc(bar) Pc( atm)
etileno ..(1) 282.4 50.4 49.7398 a1 4.54817529
propileno ..(2) 369.4 42.5 41.9433 a2 9.22875673

y1 0.35 am= 7.40412548


y2 0.65 En la mezcla bm= 0.07904577

p (bar) T(K) hallando V= 1.02555


30 423 Z 0.87538081
p(atm)
29.607
lnØ1 -0.0514788 Ø1 0.94982384 f1
lnØ2 -0.1560781 Ø2 0.85549244 f2

FUGACIDAD REDLICH-KWONG
Tc (K) Pc(bar) Pc( atm)
etileno ..(1) 282.4 50.4 49.7398 a1 3.76557557
propileno ..(2) 369.4 42.5 41.9433 a2 8.73883361
y1 0.35 am 6.76352019
y2 0.65

V= 1.218 Zreal 1.0396519

lnØ1 -0.0820697 Ø1 0.92121001 f1 9.54599266


lnØ2 -0.1247396 Ø2 0.88273004 f2 16.9877424
FUGACIDAD PEN ROBINSON
Tc (K) Pc(bar) Pc( atm) w Tr α
etileno ..(1) 282.4 50.4 49.7398 0.087 1.49787535 0.78596196
propileno ..(2) 369.4 42.5 41.9433 0.14 1.14510016 0.9196362
y1 0.35
y2 0.65

v= 1.0162339 Z 0.86742878

lnØ1 -0.0483565 Ø1 0.95279541 f1 9.87329483


lnØ2 -0.1778174 Ø2 0.83709973 f2 16.1096075
a11 4.54817529
b1 0.05819489 a12 6.4787347
b2 0.09027317 a21 6.4787347
a22 9.22875673

am = y1*y1*a11+y1*y2*a12+y2*y1*a21+y2*y2*a22
bm= y1*b1+y2*b2
𝑃�^3−(𝑃𝑏+𝑅𝑇) �^2+𝑎�−𝑎𝑏=0

lnØ1= b1/
9.84250206
16.463567

a11 3.76557557
a12 5.73643952
b1 0.04033604 σ1 1.49231081 a21 5.73643952
b2 0.06257014 σ2 2.2733711 a22 8.73883361
bm 0.0547882

A* 0.1664404
B* 0.04676568

a11
a12
a1 3.87435263 b1 0.0362205 σ1 1.47977997 a21
a2 9.19855655 b2 0.05618602 σ2 2.28011848 a22
am 7.07725505 bm 0.04919809

A* 0.17416096
B* 0.04199411
3.87435263
5.96979496
5.96979496
9.19855655