Solutions

1
AITS-CRT-III-(Paper-2)-PCM(Sol)-JEE(Advanced)/15
FIITJEE JEE(Advanced)-2015
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ANSWERS, HINTS & SOLUTIONS

CRT–III
(Paper-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICS
1. A D B
ALL INDIA TEST SERIES
2. C B A
3. D A A
4. A C B
5. B A B
6. B C C
7. B A B
8. C A D
9. B, C A, C, D B, C
10. A, B C, D B, C, D
11. C, D B, C, D A, B, C
12. A, C, D A, B, C, D A, D
13. C C A
14. C B C
15. A C A
16. A B A
17. D A B
18. C B C
1. 2 3 1
2. 1 4 1
3. 4 3 5
4. 2 3 2
5. 5 8 2
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2
Physics PART – I
SECTION – A
2
1.   X

2 
  4 
16 2

I  4I0 cos2  2I0
4
3
2. mV0R  mR 2 
2
2V0

3R
2V0
Vcm  R 
3
3. Electric field lines kill off on surface of conductor
4. Torque will be in clockwise sense.
5. Since maximum current passing through two circuits is same and equal to V/R1 in (b) and V/R2 in
(c) then R1 = R2
Current growth equation of L – R circuit is :

i  i0 1  e t /  
 tR
 
i  i0 1  eL

 
di i0R  tR/L
Now,  e
dt L
At t = 0 slope of I vs t curve:
di i0R

dt L
From graph (a) : slope of curve (b) > slope of curve (c)
R1 R2

L1 L 2
Since, R1 = R2
L1 < L2
6. Momentum conservation.
MV0  2MV
V
V 0
3
Angular momentum conservation about centre of mass,
2
1 2 4  MR 2 4  1  2 
MR  0  MV0R    M  R    2M R 2  2M  R 2   
2 3  2 3  2  3  
3 8 V0
 0 
25 25 R
3
For   0
8V0
0 
3R
The energy loss,
E  Ei  Ef
1 1  MR2  2 1 19
 MV0 2   2
     3M V  MV0 2
2 2 2  2 9
T
7. V1   10 2
1
T 10 2
V2  
2 3
Reflection coefficient
V  V1
R 2  2 3
V1  V2
Transmission coefficient,
2V2
T  3 1
V1  V2
8. Initially,
Pgas  P0 A  mg  112.5 kPa
x
w   Pgas A dx
0
x
  P0 A  mg  kx dx  56.5 J
0
Q  m u  w  118 J
9. When the switch ‘S’ is opened,

  RC  1.5 sec
Voltage across the capacitor,

Vc  10 1  e t /1.5 for t < T 
dQ dVc
The current, i  C
dt dt
200
3
 106 e t /1.5 for t < T  
Voltage drop across 100 k  resister,
20  t /1.5
V  iR  e for t < T
3
After t = T,
  100 k  10 F  1 sec
Voltage across capacitor,
Vc  Vo t
  t  T  / 

 10 1  e 
 T /1.5 
,e 
   t  T  /1
The charge on capacitor,

Q  Vc  C
The current through 100 k  resistor,
dV
i  C c  103 1  e T /1.5 1  e  
dt
  t  T /1
 
4
  V    V 
10. If     then E exists.
y  x  x  y 
o
11. For emission of photoelectrons, incident  5200 A .
12. m1V12  m2 V22  3KT

3RT 3PM
 
NA NA d
13. Angular momentum conservation about axel of stool.

I w s  Isp w f  I  w f  w s   md2 wf
3
wf  ws
8
14. Linear impulse  p  mv cm  0

3
 mdw s
8
15. Slope will be now different such that

200 2
sin   
500 5
21
So, cos  
25
2u sin30o
Hence, T =
gcos 
16. For minimum slope, line will be PQ, i.e. a horizontal line
2u sin30o
Hence, time = = 1 sec.
g
17. 72  52  74
18. Snell’s law

For minimum time it will follow a path which could have been
followed by a light ray under refraction, but not the previous 5
one. Definitely time taken would be less than what could have
been over straight path.
3 4
SECTION – C
1. 4T . cos  . dl  2T . dl
1 
cos  
2

  60o c1 d c2
d R 2
So,  R cos 60 
2 2
c 1c 2 = d = R = 2 m
5
1 v
2. fn   n
2rn 2rn
vn
2.18  106
f1 = sec 1
2  3.14  0.529  1010
= 6.56  1015 sec 1
P = 6.56
2P
 1 approximately.
13
Q  x 2B
3. dQ  2xdx. 2
, Ex 
R 2 t
R x 2B Q
L    dt  IW =  . 2xdx dt
0 2 t R2
MR2 QBR 2 QB
  4
2 2 M
v1  v 2 t M
4. Vavg = Since variation is linear, t = 2
2 Vavg R
R  T1  T2 
=  
M  2 

1 1
5.   30 , f = 60
f f
1 1 1 1 1 1
   v1  30 ,  
v1 20 60 v 30 60
I v 60
m  2
0 v 1 30
I
  2  I  10
5
y coordinate = 5
6
Chemistry PART – II
SECTION – A
1. Normally not possible to F2 because it is highly exothermic with I2 reversible reaction takes place
due to more E.N of Cl2 compare to Br2. It does not give e  pair to carbocation.
2.
H O KOH
 
H 
CH3
O O
3. II, III are unstable because of their rigid frame work, to stabilize themselves by collapsing to the
stable intermediate planer state. II is more stable than III because the greater rigidity about bridge
head carbon with a one-carbon than with a two – carbon bridge.
5e  Mn7   Mn2

4.
P 3
4
 4P5   8e
100  5  1000
Meq. Of KMnO4 =  3164.56
158
100  8  1000
Meq. Of P4O6 =  3638.02
219.9
Meq. Of P4O6 in excess = 473.46
w  8  1000
  473.46 WP4O6 in excess  13.01g
219.9


NH4CN  s  
 NH3  g   HCN  g 
5.
P P
At eq.
 Total pressure = 2P = 0.298 atm
p = 0.149
1 1
Also KP = PNH3
 PHCN  0.149  0.149  0.022 atm 2
Now PNH3  0.25 atm


NH4 CN  s  
 NH3  g   HCN  g 
Initial 0.25 0
1
At eq 0.25  P P1
1 1
KP = P (0.25 + P )
1
P = 0.0694 atm
6. 

AgBr  s  
 Ag  aq.  Br  aq.
 
K1  K sp


Ag  aq   2S2 O32   aq. 
3
 Ag  S2O3  2  aq. K2  Kf


AgBr  2S2 O32  aq. 
3
 Ag  S 2O3  2  Br

K  K sp  K f  25
7
x2 x2
K 2
 2
 25
 0.1  2x   0.1  2x 
 x  0.045 M .
8. M  M  e 
M  e   x  y  NH3  M NH3  x   e NH3  y 

 
solvated metal solvated e
on s tand
M  NH2
11. V. B.T does not explain colour, Cu2+, Pt2+, Pd2+ square planar geometries with proper reason.
14. CH3
hydrolysis NaI Cu / 
CaC2 
 CH  CH 
CH Cl
 H3C C C H  
3
H3C CH3
Hot KMnO4
CH3  COOH  CO2
15. W = –P.V = –nRT = – 2  8.314  600 = – 9.97 kJ
16. HTotal  HAB  HBC

 nCp,m T  0
7
 2  R   800  200 
2
= 4200 R
17. Due to high electronegativity of ‘F’ bp–bp repulsion is minimum in OSF2. Steric effect may also be
the explanation.
18. Among P, As and Sb, P is most electronegative and so it exerts the strongest pull on shared
electrons causing more bp–bp repulsion.
SECTION – C
1. H3C C C H  CH3MgBr  H3C C C MgBr  CH4

(A ) (C)
(B)
H3C C N
/ Excess of H2O
OH
o CH3MgBr / H2O
Cu / 300 C H3C C C C O
 H3C C C C CH3 
CH3 CH3
D 
H3C C C C CH2
CH3
8
2.
o NBS / h
Cu / 300 C
    AlCl
3

KMnO
4
  No reaction
OH Br
Due to absence of Benzoic hydrogens.

3. NH4NO3  N2O 2H2 O
A
o
1300 C
N2 O   2NO N2
B   C
NO  FeSO4  FeSO4 .NO
 D
Brown Compound
Po  P n W
5.  
P N W N
850  844.9 2  76
= 
844.9 M  100
M  252
252
N= 8
32
9
Mathematics PART – III
SECTION – A
x
1.  
Consider f  x    1  cos8 x ax2  bx  c dx 
0
Obviously, f(x) is continuous in [1, 2] and differentiable in (1, 2). Also f(1) = f(2)
By Rolle’s theorem, there exist one point
k  (1, 2) such that f(k) = 0 ….. (1)
Now, f(k) = (1 + cos8 k)(ak2 + bk + c) = 0
 ak2 + bk + c = 0 (1 + cos8 k  0)
2
 x = k is root of ax + bx + c = 0 where k  (1, 2)
Here, atleast one root  (1, 2)
2.  2 cos 2x – 1 = 2(cos2 x – sin2 x) – (sin2 x + cos2 x) = cos2 x – 3 sin2 x

The given equation reduces to b sin x = b + sin x, then
b
sin x 
b 1
 1  sin x  1
b
 1  1
b 1
b
  1
b 1
b
and 1
b 1
1
 b
2
 1
 b   , 
 2 
3. The vectors representing forces are 2 × unit vector along (2iˆ  4ˆj  4k)
ˆ
and 3 × unit vector along (4iˆ  4 ˆj  2k)
ˆ
1 ˆ
i.e., ˆ and 1 (4iˆ  4ˆj  2k)
(2i  4ˆj  4k) ˆ
3 2
1
 The resultant is (8iˆ  2ˆj  7k)
ˆ
3
The displacement is given by the vector ˆi  2jˆ  kˆ
1 ˆ
Hence the work done  (8i  2ˆj  7k)
ˆ  (iˆ  2ˆj  2k)
ˆ  6 gm-cm
3
4. Let r be the common ration of the given G.P., then b = ar, c = ar2, and d = ar3
Then (a2 + b2 + c2)(b2 + c2 + d2)
= (a2 + a2r2 + a2r4)(a2r2 + a2r4) + a2r6
2 2 4 2 2 2 4
= a (1 + r + r ) a r (1 + r + r )
4 2 2 4 2
= a r (1 + r + r )
= (a2r + a2r3 + a2r5)2
= (a·ar + ar·ar2 + ar2·ar3)2
= (ab + bc + cd)2
10
8. M is mid point of BC and HT A(1, 2)

 BTCH is a parallelogram
 CH is perpendicular BA and CH is parallel BT
 BT is perpendicular AB
Similarly CT is perpendicular AC H
Now, a circle drawn taking AT as diameter will pass M
through B and C B C
i.e. points A, B, T, C are concyclic points x – 2y + 3 = 0 x+y+1=0
 5  2
 Required circle  x  1  x     y  2   y    0 T  5 2
 8  3  , 
 3 3
12. First use integrating by parts to show that

/2
n 1
un   cos
0
x sin x sinnx dx
/2 / 2
=  cosn1 x cos(n  1)x   cos
n
x cosnx dx (Use sin nx sin x = cos(n – 1)x – cos nx cos x)
0 0
= un – 1 – un
u 1
 n 
un1 2
 1  
We have, u1  , un  n1   n1
4 2 4 2
13.-14. Let  be the common root of the three equations are their other roots be , ,  respectively
  +  = –a,  = 12
 +  = –b,  = 15
 +  = –(a + b),  = 36
 ( + ) + ( + ) = –(a + b) =  + 
++= ….. (1)
Again ( +  + ) = 12 + 15 + 36 = 63
or (2 – ) = 63 by (1)
or 2 = 2 = 63 or 72 – 2 = 63
  = 36
 2 = 9;  = 3, –3
 = 3   = 4,  = 5,  = 12
 = –3   = –4,  = –5,  = –12
 a = –( + ) = 7, –7; b = –( + ) = 8, –8
2
15. Equation of any tangent to the parabola y2 = 8x is y  mx 
m
x2 y 2
Since, it touches  1 ( c2 = a2m2 + b2)
4 15
2
2 2 1
   4m  15  m  
m
  2
Hence, equations of tangent are x  2y + 8 = 0
1
16. When m  then slope of normal is –2 and equation of the normal to the parabola is
2
y = –2x – 2(2)(–2) – 2(–2)3 ( y = mx – 2am – am3)
 y = –2x + 8 + 16  2x + y = 24
11
SECTION – C
1.
cos x 1  4 cos2x 
  
cos x 1  4 1  2 sin2 x 
 =

cos x 5  8 sin2 x

cos x

4 sin x 
 2
sin x 1  4cos x  2
sin x 1  4  4 sin x  2
sin x 5  4 sin x  sin x 5  4 sin2 x   
Put t = sin x; dt = cos x dx
x2
2.  f  t  dt  x cos x
0
 
2x  f x2  cos x  x sin x
Put x = 2
4f(4) = 1
1
f 4 
4
f x
And f(x),  t 2 dt  x cos x

0
{f(x)2·f(x) = cos x – x sin x
Put x = 4
3. f(x) – 5f(x) + 6f(x)  0  f(x) – 2f(x)  3(f(x) – 2f(x))

 g(x)  3g(x); where g(x) = f(x) – 2f(x)
Multiply by e–3x and then we can write it as
d

dx
  –3x
g  x  e 3x  0  y = g(x)e is non decreasing
 x  0 (Given)
 g(x)e–3x  g(0) e–0  g(x) e–3x  – 2  g(x)  –2e3x
 g(x) = f(x) – 2f(x), g(0) = f(0) – 2f(0) = 0 – 2
 f(x) – 2f(x)  –2e3x
Multiply it by e–2x and than we can write it as
d

dx
  –2x x
f  x  e 2x  2e x  0  f(x) e + 2e  3
 x  0, ex  1 ….. (1)
 We have e–2x f(x) + 2ex  3
or f(x)  3e2x – 2e3x ….. (2)
f(x)  ah(bx) – bh(ax) ….. (3)
From equation (2) and (3), we get a = 3, b = 2
 (a + b) h(0) = (3 + 2) e0 = 5
dy
4.  y  4xe x sin 2x
dx
x
Integrating factor = e
 Equation becomes ye x  4  x sin 2xdx
 yex = (sin 2x – 2x cos 2x) + c
 f(0) = 0  c = 0
 y = f(x) = (sin 2x – 2x cos 2x)e–x
f(k) = e–k(0 – 2k(1))
f(k) = –2k e–k
n
2e
lim  f k   2 1 e  2e 2   3e3   ..... upto   = 2
n 
k 1
e 

1

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ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

3. Electric field lines kill off on surface of conductor

4. Torque will be in clockwise sense.

9. When the switch ‘S’ is opened,

The charge on capacitor,

12. m1V12  m2 V22  3KT

13. Angular momentum conservation about axel of stool.

14. Linear impulse  p  mv cm  0

15. Slope will be now different such that

18. Snell’s law

5e  Mn7   Mn2

M  e   x  y  NH3  M NH3  x   e NH3  y 

CH3  COOH  CO2

15. W = –P.V = –nRT = – 2  8.314  600 = – 9.97 kJ

16. HTotal  HAB  HBC

1. H3C C C H  CH3MgBr  H3C C C MgBr  CH4

Due to absence of Benzoic hydrogens.

Mathematics PART – III

2.  2 cos 2x – 1 = 2(cos2 x – sin2 x) – (sin2 x + cos2 x) = cos2 x – 3 sin2 x

8. M is mid point of BC and HT A(1, 2)

12. First use integrating by parts to show that

And f(x),  t 2 dt  x cos x

3. f(x) – 5f(x) + 6f(x)  0  f(x) – 2f(x)  3(f(x) – 2f(x))

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