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Dear Students,
Pramod Maheshwari
[B.Tech. IIT-Delhi] Find a mentor who can be your role model and your friend !
A mentor is someone you admire and under whom you can study. Throughout
Cover Design history, the mentor-protege relationship has proven quite fruituful. Socrates was
one of the early mentors. Plato and Aristotle studied under him and later
Govind Saini emerged as great philosophers in their own right.
Layout Some basic rules to know mentors :
Rajaram Gocher • The best mentors are successful people in their own field. Their behaviors
are directly translatable to your life and will have more meaning to you.
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accountability functions.
• Encourage your mentor to make you an independent, competent, fully
Every effort has been made to avoid errors or functioning, productive individual. (In other words, give them full
omission in this publication. Inr spite of this, permission to be brutally honest about what you need to change.)
errors are possible. Any mistake, error or
discrepancy noted may be brought to our Getting benefited from a role-mode :
notice which shall be taken care of in the Acquiring good habits from others will accelerate you towards achieving your
forthcoming edition, hence any suggestion is goals. Ask yourself these questions to get the most out of your role
welcome. It is notified that neither the model/mentors :
publisher nor the author or seller will be • What would they do in my situation?
responsible for any damage or loss of action to • What do they do every day to encourage growth and to move closer to a
any one, of any kind, in any manner, there from. goal ?
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Owned & Published by Pramod Presenting forever positive ideas to your success.
Maheshwari, 112, Shakti Nagar,
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Editor : Pramod Maheshwari Pramod Maheshwari,
B.Tech., IIT Delhi
Study Time........
S DYNAMIC PHYSICS 18
8-Challenging Problems [Set # 11]
Success Tips for the Months Students’ Forum
Physics Fundamentals
• "All of us are born for a reason, but all of Calorimetry, K.T.G., Heat transfer
us don't discover why. Success in life has Atomic Structure, X-Ray & Radio Activity
nothing to do with what you gain in life or
accomplish for yourself. It's what you do CATALYSE CHEMISTRY 32
for others." Key Concept
Purification of Organic Compounds
• "Don't confuse fame with success. Boron Family & Carbon Family
Madonna is one; Helen Keller is the other." Metallurgy
Understanding : Inorganic Chemistry
• "Success is not the result of spontaneous
combustion. You must first set yourself on DICEY MATHS 39
fire." Mathematical Challenges
• "Success does not consist in never making Students’ Forum
mistakes but in never making the same one Key Concept
a second time." Definite Integrals & Area under curves
Probability
• "A strong, positive self-image is the best
possible preparation for success." Test Time ..........
• "Failure is success if we learn from it."
XTRAEDGE TEST SERIES 50
• "The first step toward success is taken Mock Test IIT-JEE Paper-1 & Paper-2
when you refuse to be a captive of the Mock Test AIEEE
environment in which you first find Mock Test BIT SAT
yourself."
SOLUTIONS 85
He holds a B.Tech Degree from IIT Delhi. He is a first offering quality academic courses is contingent upon
generation entrepreneur and the key founder member of recruiting and retaining experienced faculty members,
the company. Recently he has been awarded as the providing updated educational content and effective
'Star CEO' of the country. Pramod Maheshwari has over academic administration and control on content delivery.
15 years of experience in developing and implementing We retain faculty and instructors with relevant industry
training methodologies. He plays a major role in providing experience and appropriate academic credentials. Our
thought, leadership and strategic guidance, in addition to Research and Development Cell helps in reassessing and
supervising the functional heads. He is responsible for the updating our tutorial courses on a regular basis which also
overall operation and growth of the company. helps us in designing new academic courses. Regular
feedbacks from our students are also an inbuilt standard
Career Point was established in 1993, to impart quality
procedure for our content delivery.
education to students preparing for various competitive
examinations. With the sky-high ideals and commitment to Strong brands and geographic presence
excellence, now Career Point has taken a shape of vibrant, We believe that our training centres have established a
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Career Point stands apart and well above the rest on a students. We currently have presence across 13 states and
distinguished platform, as an epitome of success. Since providing our expert services to them. In our Kota centre
beginning Career Point’s objective is to enable each students from across the country and even from Singapore
aspirant to achieve success in different competitive and the Middle East are also there, which in turn reinforces
examinations. In the pursuit of which, Career Point has to the brand equity and our geographical reach.
its credit a team of outstanding faculty members including
IITians, NITians and Doctors, added with the complete & Qualified faculty team
finest study material, excellent coaching methodology and We believe that our qualified and experienced faculty
a stimulating academic environment. Career Point believes members contribute to our success. Our faculty members
that effective guidance is the primary need of every are graduates in engineering and science from Indian
student, which would create motivation and instill courage Institute of Technology, National Institute of Technology
and confidence to face all challenges. And that is exactly and other colleges in India. Our faculty members are well
what Career Point imparts in all its coaching programmes. equipped with subject knowledge guiding and tutoring
For every course, Career Point has a strategic & a well students. We also have an ongoing in-house faculty
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missile to unfailingly hit the target in the bull’s eye. and subject matter of relevant courses and to keep them
abreast of the changes in competitive entrance examination
Sir, can you tell us what the major competitive strength trends and changing student needs.
of Career Point are?
We believe the following competitive strengths contribute Experience management team
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Commitment to offering quality courses and student success years and over 13 years of average experience in the
We offer quality tutorial courses, and intend to improve education industry. We believe our management led by our
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What is ISEET - Indian Science-Engineering Eligibility What is the pattern of the ISEET 2013?
Test and when it will be in operation? • ISEET 2013 will be conducted twice in 2013, first in
• ISEET (Indian Science-Engineering eligibility Test) is the month of April or May and second in November or
the proposed Single National level entrance test. December and the ultimate aim is to conduct it thrice
• It is proposed to be conducted from year 2013 for all or four times in a year
students who seek admissions in central engineering • Results will be valid for two years while multiple
institutions i.e. IITs, NITs, IIITs and IISERs attempts are allowed for students to improve scores by
• As of now ISEET 2013 will replace IIT-JEE & AIEEE but getting multiple attempts
it is proposed that ISEET will gradually replace all State • ISEET 2013 will be a single day exam in two sessions
level exams like RPET, MH-CET, Karnataka CET, etc. o Morning Session – 10:00 AM to 01:00 PM (3
Hours)
Why has the pattern changed? o Afternoon Session – 02:00 PM to 05:00 PM (3
• ISEET 2013 has been proposed by the Ministry of Hours)
Human Resource Development, Government of India • ISEET 2013 will have two papers
to reduce the burden on aspirants due to multiple
o ISEET Main – Objective type aptitude test to be
entrance examinations conducted across India each
held in the morning session to access the abilities
year.
of comprehension, critical thinking, logical
• The burden in terms of time, money (examination & reasoning of students
Transit fee) and the stress caused in scheduling and
o ISEET Advance– Objective type test to be held in
preparing for each examination syllabus.
the afternoon session to access the problem
Is this change beneficial for students in general? solving abilities of a student in basic science
• Yes, it is definitely beneficial for students. Earlier they subjects i.e. Physics, Chemistry & Mathematics
had to prepare for many engineering entrance tests. What will be the admission process from 2013 for IITs?
• ISEET implementation will reduce mental and • Board Percentage of Class 12th will be given a
financial burden on the student/parent and save time as minimum of 40% weightage
well. • Different State Boards and Central Board results
• Students can concentrate on the single test. It will normalized on the basis of percentile formula.
improve the chances of getting admission in a good • ISEET will replace IITJEE and will come into place
college. from academic session 2012-13
• As ISEET will be conducted twice or more during a • ISEET Main and Advance will be compulsory.
year and the scores will be valid for two years, students • Main will have 30% to 60% weightage and Advance
will have multiple chances to improve their scores exam will have 0% to 30% weightage. The actual
What major changes come with the new pattern? weightage within this limit will be decided by the
• With emphasis on School Board marks a minimum board of directors if IITs.
40% weightage will be mandatorily given to School • Merit list for the admissions will be prepared by the
Board marks in the admission process across India admission committee for IITs
• ISEET Main (Objective Aptitude Test - • All other institutes who took admissions based on JEE
comprehension, critical thinking, logical reasoning) will also follow the same pattern
made a mandatory part of admission process with a What will be that admission process from 2013 for
minimum of 30% weightage institutes currently using AIEEE rank?
• ISEET Advance (Advanced to School Board • Board Percentage of class 12th will be given a
curriculum & in-between AIEEE and IIT-JEE pattern minimum 40% weightage.
basic science subject knowledge objective test) with a • Different State Boards and Central Board results
maximum of 30% weightage in admission process normalized on the basis of percentile formula.
made a mandatory part of for taking admissions into • ISEET will replace AIEEE and will come into place
IITs and NITs while it is optional for other central and from academic session 2012-13
state level institutions • ISEET Main and Advance will be compulsory.
mgR e – B0 a t
2 2
→
F3
∴ v(t) = 2 2 1 –
B0 a mR
Y
1.6m
0.8m →
F
or heights of water level are (3.6 – 0.4) m, B l C
(3.6 – 1.2) m (3.6 – 2.0) m and (3.6 – 2.8) m. (a) Find the magnitude of the horizontal force
Therefore heights of water level are 3.2 m, 2.4 m, exerted by the hinge on the body.
2.4 m, 1.6 m and 0.8 m. (b) At time T, when the side BC is parallel to the
Let A and a be the are of cross-sections of the pipe x-axis, a force F is applied on B along BC (as
and hole respectively. Then shown). Obtain the x-component and the
y-component of the force exerted by the hinge
A = π (2 × 10–2)2 = 1.26 × 10–3 m–2. on the body, immediately after time T.
and a = π(10–3)2 = 3.14 × 10–6 m2 Sol. The mass B is moving in a circular path centred at
Velocity of efflux, V = 2gH A. The centripetal force (mlω2) required for this
Continuity equation at 1 and 2 gives, circular motion is provided by F′. Therefore a force
– dH F′ acts on A (the hinge) which is equal to mlω2. The
a 2gH = A
dt same is the case for mass C. Therefore the net force
Therefore rate of fall of water level in the pipe, on the hinge is
9. An ideal gas having initial pressure P, volume V 10. An organic compound X, on analysis gives 24.24
and temperature T is allowed to expand percent carbon and 4.04 percent hydrogen. Further,
adiabatically until its volume becomes 5.66 V, sodium extract of 1.0 g of X gives 2.90 g of silver
while its temperature falls to T/2. chloride with acidified silver nitrate solution. The
(a) How many degrees of freedom do the gas compound X may be represented by two isomeric
molecules have ? structures, Y and Z. Y on treatment with aqueous
(b) Obtain the work done by the gas during the potassium hydroxide solution gives a dihydroxy
expansion as a function of the initial pressure P and compound, while Z on similar treatement gives
volume V. [IIT-1990] ethanal. Find out the molecular formula of X and
Sol. (a) According to adiabatic gas equation, give the structures of Y and Z. [IIT-1989]
TVγ–1 = constant Sol. C = 24.24%, H = 4.04%
35.5 2.90 g
or T1V1γ–1 = T2V2γ–1 Percentage of Cl = × × 100 = 71.74%
143.5 1g
Here, T1 = T ; T2 = T/2
V1 = V 24.24
Relative number of C atoms = = 2.02
and V2 = 5.66 V 12
T 4.04
Hence, TVγ–1 = × (5.66V)γ–1 Relative number of H atoms = = 4.04
2 1
71.74
T Relative number of Cl atoms = = 2.02
= × (5.66)γ–1 × Vγ–1 35.5
2
Atomic ratio = C : H : Cl = 2.02 : 4.04 : 2.02
or (5.66)γ–1 = 2 ...(1) = 1 : 2: 1
Taking log, Empirical formula of X = CH2Cl
(γ – 1)log 5.66 = log 2 It is given that isomer of Y of the compound X
log 2 0.3010 gives a dihydroxy compound on treatment with
or γ–1= = = 0.4 aqueous potassium hydroxide. Therefore, the given
log 5.66 0.7528 compound should contain two Cl atoms. Thus
or γ = 1.4 molecular formula of X = C2H4Cl2
If f, be the number of degrees of freedom, then The two isomers of X are :
H H
2 2 | |
γ=1+ or 1.4 = 1 +
f f Y = ClCH2CH2Cl → Cl − C − C − Cl
| |
2 H H
or = 1.4 – 1 = 0.4
f
This section is designed to give IIT JEE aspirants a thorough grinding & exposure to variety
of possible twists and turns of problems in physics, that would be very helpful in facing IIT
JEE. Each and every problem is well thought of in order to strengthen the concepts and we
hope that this section would prove a rich resource for practicing challenging problems and
enhancing the preparation level of IIT JEE aspirants.
By : Dev Sharma
So lutions will b e p ub lished in nex t issue Director Academics, Jodhpur Branch
1. A metallic conductor of irregular cross section is as (C) the speed of the missile when it was detected
shown in figure A constant potential difference is gx
is
applied across the ends (A) and (B). Then 2
x
A (D) the maximum height attained by the missile is
Q B 4
P
4. Figure shows a square loop being pulled out with a
constant speed out of region of uniform magnetic
(A) Electric current at cross section P is equal to field. The induced emf in the loop
that of cross section Q B
(B) Electric field intensity at P is less than that at Q × × × ×
× l × l
(C) The number of electrons crossing per unit area × × × × v
× × × ×
per unit time at cross section P is less than that × × × l
at Q × × × ×
(D) The rate of heat generating per unit time at Q is (A) first increases, then decreases
greater than that of P (B) first decreases, then increases
(C) has a maximum value Bvl 2
2. A circular ring of radius R with uniform positive
(D) has a maximum value 2Bvl
charge density λ per unit length is located in the y-z
plane with its centre at the origin O. A particle of 5. The variation of pressure versus volume is shown in
charge –q0 is released from x = 3R on x-axis at t the figure. The gas is diatomic and the molar
= 0 then kinetic energy of particle when it passes specific heat capacity for the process is found to be
through origin, is xR. Find the value of x.
P
λq 0 q 0λ
(A) (B)
2 ∈0 3 ∈0
q 0λ q 0λ V
(C) (D)
∈0 4 ∈0
6. Figure shows a parabolic reflector in x-y plane
3. Missile is fired for maximum range at your town given by y2 = 8x. A ray of light traveling along the
from a place in the enemy country at a distance ‘x’ line y = a is incident on the reflector. Find where the
from your town. The missile is first detected at its ray intersects the x-axis after reflection.
half-way point. Then y-axis y2=8x
(A) the velocity with which the missile was line y = a
P(0,a)
projected is gx incident ray
x-axis
x
(B) you have a warning time of
2g
As speed increases, objects can be in several places • Sally, without even looking at her marbles or her
at once.
label, was able to tell the scientist what color her
This is particularly true of tooth-and-claw fights, in
marbles were. Can you tell what color marbles
which a character's head may be glimpsed emerging
from the cloud of altercation at several places Sally had? Can you also tell what color marbles
simultaneously. This effect is common as well the others had, and what label was in each of
among bodies that are spinning or being throttled. their containers?
A `wacky' character has the option of self- replication
only at manic high speeds and may ricochet off walls
to achieve the velocity required.
φ = 3B 0 t × π12 − B 0 t (π 22 − π12 )
φ = 2B 0 t × π12 − B 0 t × πr22
dφ
= 2B 0 π12 − B 0 πr22
dt
When both are moving in same direction dφ
E × 2πr =
BLv dt
i= = 0.2mA
(9 + 1) As E = 0
dφ
=0 Q 4r12 = r22
dt
2
r1 1
=
r2 4
When both are moving in opposite direction equation
emf of battery = 0 ∴i = 0 8. Ans. Α→P,Q,R; B→P,Q,S; C→Q,T; D→P,Q,S
1. A triangular prism of mass M = 1.12 kg having base For vertical forces on cylinder,
angle 37º is placed on a smooth horizontal floor. A mg – N cos37º – F sin37º = m (0.2α . sin37º) ...(iii)
solid cylinder of radius R = 20 cm and mass m = 4 kg
is placed over the inclined surface of the prism. If Taking moments (about O) of forces acting on the
sufficient friction exists between the cylinder surface cylinder,
and the prism, so that cylinder does not slip, calculate FR = Iα ...(iv)
acceleration of prism when the system is released. 2
Calculate also, force of friction existing between the mR
where I= = 0.08 kg m2
cylinder and the prism. (g = 10 ms–2) 2
m From above equation N = 23 newton
α = 30 rad/sec2
a = 3.75 ms–2 Ans.
M
37º F = 12 newton Ans.
Sol. Let angular acceleration of cylinder be α clockwise
and acceleration of prism be a leftwards. 2. A cylindrical tank of base area A has a small orifice
Acceleration of cylinder axis (relative to prism) is of area a at the bottom. At time t = 0, a tap starts to
Rα = 0.2 α down the plane. supply water into the tank at a constant rate Q m3 s–1.
Calculate relation between height h of water in the
Its horizontal and vertical components are tank and time t.
0.2α .cos37º (rightwards) and 0.2αsin37º Sol. When water supply is started, water starts to
(downwards) respectively. But resultant acceleration accumulate in the tank. But leakage of water through
of cylinder axis is vector sum of Rα and a, therefore orifice at bottom also start simultaneously.
horizontal and vertical components of resultant
acceleration of cylinder axis become Let at instant t, height of water in the tank be y as
(0.2α cos37º – α) rightwards and (0.2α sin 37º) shown in figure
downwards respectively.
Considering free body di agrams (fig. (a) and Fig.
(b))
Mg
F N Iα y
m (0.2 α cos 37º – a)
O
M.g
37º
N F m (0.2 a sin 37º) Then flow velocity through orifice,
M.a
v v= 2gy
Fig. (a)
Fig. (b) ∴ Volume flowing out per second through orifice,
For horizontal forces acting on prism, q = a 2gy
N sin 37º – F cos 37º = Ma ...(i)
But rate of supply to the tank is Q. Therefore net of
For horizontal forces acting on cylinder, increase of volume in tank = (Q – q) m3s–1. Since,
N sin 37º – F cos 37º = m (0.2α cos 37 – a) ...(ii)
(Not : these is no significance of angle θ for Since air temperature is a powerful component of
calculation of number of α-particles striking the climate, there will be unavoidable climate changes
surface.) in the future. Some climate changes involve
Kinetic energy of each α-particle is E = 83.5 Ke V extreme weather disturbances such as more severe
hurricanes and longer droughts. There will be an
or E = (83.5 × 103) (1.6 × 10–19) J
increased precipitation of snow and rain during
1 winter. The faster melting of snow during the spring
But E = mv2 where m = 6.68 × 10–27kg
2 will result in flooding. All these climate changes are
∴ Velocity of α-particles is v = 2 × 106 ms–1. predicted based on the assumption that changes will
be relatively gradual.
It means a beam of length v = 2 × 106 m crosses a
section in one second. But number of α-particles
n=1
Limiting line of Lyman series
–13.6 eV [ Zm p + (A − Z)m n − M ]c 2
Lyman Series
=
A
(U.V. rays)
Energy of the excited sate Kinetic energy of the electron after third collision = 0
En = – 13.6 + 12.75 = – 0.85 eV Energy of the photon produced in the third collision ,
E3 = 12.5 – 0 = 12.5 keV
13.6
Now, we know that En = – This is same as E2. Therefore, wavelength of this
n2
photon, λ3 = λ2 = 0.99 Å
13.6 −13.6
or n2 = – = = 16
En − 0.85 5. In an experiment on two radioactive isotopes of an
or n = 4 elements (which do not decay into each other), their
The number of possible transition in going to the mass ratio at a given instant was found to be 3. The
ground state and hence the number of different rapidly decaying isotopes has larger mass and an
wavelengths in the spectrum will be six as shown in activity of 1.0 µCi initially. The half lives of the two
the figure. isotopes are known to be 12 hours and 16 hours.
What would be the activity of each isotope and their
n
4 mass ratio after two days ?
3 Sol. We have, after two days, i.e., 48 hours,
4
1
N1 = N10 = N10 /16
2 2
3
1
N2 = N 02 = N 02 /8
2
1
N1 N0 8 3× 8 3
The longest wavelength corresponds to minimum Mass ratio = = 10 . = =
N2 N 2 16 162 2
energy difference, i.e., for the transition 4 → 3.
13.6 Now, A10 = λ1 N10 = 1.0 µCi
Now E3 = – = – 1.51 eV
32 After two days,
hc A1 = λ1N1 = λ1 N10 /16 = A10 /16 = (1/16)µCi
= E4 – E3
λ max A2 = λ2N2 = λ2 N 02 /8
6.6 × 10 −34 × 3 × 108 λ2 T 12 3
or λmax = But = 1 = =
(1.51 − 0.85) × 1.6 × 10 −19 λ1 T2 16 4
= 18.75 × 10–7m = 18750 Å 3
or λ2 = λ1
4
4. X-rays are produced in an X-ray tube by electrons 3 1 1
A2 = λ1 × N10 ×
accelerated through a potential difference of 50.0 kV. 4 3 8
An electron makes three collisions in the target
before coming to rest and loses half its kinetic energy 1 1
= λ1 N10 = A10
in each of the first two collisions. Determine the 32 32
wavelengths of the resulting photons. Neglect the = (1/32) µCi
recoil of the heavy target atoms.
Organic PURIFICATION OF
Chemistry
Fundamentals ORGANIC CHEMISTRY
Qualitative Analysis : Preparation of Lassaigne's Extract (or sodium extract):
Qualitative analysis of an organic compound involves A small piece of sodium is gently heated in an
the detection of various elements present in it. The ignition tube till it melts. The ignition tube is
elements commonly present in organic compounds removed from the flame, about 50–60 mg of the
are carbon, hydrogen, oxygen, nitrogen, halogens, organic compound added and the tube heated
sulphur and sometimes phosphorus. strongly for 2–3 minutes to fuse the material inside it.
Detection of carbon and Hydrogen : After cooling , the tube is carefully broken in a china
Principle. Carbon and hydrogen are detected by dish containing about 20–30 mL of distilled water.
strongly heating the organic compound with cupric The fused material along with the pieces of ignition
oxide, (CuO). The carbon present in the organic tube are crushed with the help of a glass rod and the
compound is oxidised to carbon dioxide and contents of the china dish are boiled for a few
hydrogen is oxidised to water. Carbon dioxide is minutes. The sodium salts formed in the above
tested by lime water test, whereas water is tested by reactions (i.e., NaCN, Na2S, NaX or NaSCN)
anhydrous copper sulphate test. dissolve in water. Excess of sodium, if any, reacts
with water to give sodium hydroxide. This alkaline
Mixture of orgainc compoud
Guard tube solution is called Lassaigne's extract or sodium
and dry copper oxide (CuO)
containing sodalime
extract. The solution is then filtered to remove the
insoluble materials and the filtrate is used for making
the tests for nitrogen, sulphur and halogens.
Anhydrous Cotton plug
Reactions : An organic compound containing C, H,
copper sulphate
(white) N, S, halogens when fused with sodium metal gives
Lime water the following reactions.
Reactions : C + N + Na fusion
→ NaCN
C + 2CuO → CO2 + 2Cu in organic compound sodium cyanide
fusion
in the compound X(Cl, Br, I) + Na→ NaX(X=Cl,Br, I)
2H + CuO → H2O + Cu from organic compound sodium halide
in the compound S + 2Na fusion
→ Na2S
CO2 + Ca(OH)2 → CaCO3 + H2O from organic compound sodium sulphide
limewater milky
If nitrogen and sulphur both are present in any
5H2O + CuSO4 (anhyd) → CuSO4.5H2O organic compound, sodium thiocyanate (NaSCN) is
white blue formed during fusion which in the presence of excess
Process : The given organic compound is mixed with sodium, forms sodium cyanide and sodium sulphide.
dry cupric oxide (CuO) and heated in a hard glass
Na + C + N + S fusion
→ NaCNS
tube. The products of the reaction are passed over
(white) anhydrous copper sulphate and then bubbled in organic compound sodium thiocyanate
through limewater. The copper sulphate turns blue Detection of Nitrogen :
(due to the formation of CuSO4.5H2O) by water Take a small quantity of the sodium extract in a test
vapour, showing that the compound contains tube. If not alkaline, make it alkaline by adding 2–3
hydrogen. The limewater is turned milky by CO2, drops of sodium hydroxide (NaOH) solution. To this
showing that the compound contains carbon. solution, add 1 mL of freshly prepared solution of
Detection of Nitrogen, Sulphur and Halogens : ferrous sulphate. Heat the mixture of the two
Nitrogen, sulphur and halogens in any organic solutions to boiling and then acidify it with dilute
compound are detected by Lassaigne's test. sulphuric acid. The appearance of prussion blue or
green colouration or precipitate confirms the
presence of nitrogen in the given organic compound.
B F
B F
X Planar structure of X
F
boron trihalides
π
BF3 + : NH 3 → F3 B ← NH3
Lewis acid Lewis base Addition product Empty 2p-orbital
2p-orbital with lone pair
BF3 + : F− → BF4− pπ-pπ back bonding
Lewis acid Lewis base Fluoroborate ion
COOH COO It is confirmed by the fact that CaCl2 gives white ppt.
(a) into Ca CaC2O4(E) which decolourises MnO4–/H+
COOH COO
(b) H3PO4 into CaHPO4 ⇒ (A) is (NH4)2C2O4
(c) NH4Cl into NH3 Explanation :
(d) NaHCO3 into CaCO3 ∆
(NH4)2 C2O4 → 2NH3 + CO2 + CO + H2O
COOH
(A) (B) (C) (D)
Sol. (a) is a dibasic acid
COOH (B) is blue towards litmus (basic)
COOH COO (C) is red toward litmus (acidic)
+ Ca(OH)2 Ca
COOH COO (D) is neutral
1 mo l 1 mo l ∆
(NH4)2C2O4+2NaOH → Na2C2O4+ 2 NH 3 +2H2O
Ca(OH)2 required = 1 mol (B)
(b) H3PO4 + Ca(OH)2 → CaHPO4 + 2H2O Na2C2O4+ CaCl2 → CaC 2 O 4 ↓ + 2NaCl
1 mol of H3PO4 ≡ 2H+ neutralised by 1 mol of White ppt. (E )
Ca(OH)2
Ca(OH)2 required = 1 mol
CrCl3 + 3NaOH → Cr(OH)3 + 3NaCl (iv) (C) on decarboxylation gives acetone (D).
green ppt (B) ∆
CH 3COCH 2 COOH → CH 3COCH 3
(ii) In excess of sodium hydroxide, soluble NaCrO2 is − CO 2
(C) ( D)
formed
(v) (D) reacts with NaNH2 to form sodium salt (E),
Cr(OH)3 + NaOH → NaCrO2 + 2H2O which on heating with CH3I gives butanone (F).
(sod. chromite)
∆
(iii) Since Cr(OH)3 contains -OH group, so it will act CH 3COCH 3 + NaNH2 → CH 3COCH 2 Na
− NH 3
( D) (E)
as a base. On heating it will lose water to give Cr2O3
powder (C) CH I
3
– NaI
→ CH 3COCH 2 CH 3
2Cr(OH)3 → Cr2O3 + 3H2O ( F)
(C) ∆
(vi) CH 3COCH 2 CH 3 + 3I2 + 4NaOH →
(iv) On fusing Cr2O3 with an alkali in presence of ( F)
oxygen or oxidising agent, a yellow soluble chromate CHI3 + CH3CH2COONa + 3NaI + 3H2O
will be formed - ∆
(vii) CH 3COCH 3 + 3I2 + 4NaOH →
2Cr2O3 + 8NaOH + 3O2 → 4Na2CrO4 + 4H2O ( D)
yellow soln. (D)
CHI3 + CH3COONa + 3NaI + 3H2O
`tà{xÅtà|vtÄ V{tÄÄxÇzxá 11
This section is designed to give IIT JEE aspirants a thorough grinding & exposure to variety
of possible twists and turns of problems in mathematics that would be very helpful in facing
IIT JEE. Each and every problem is well thought of in order to strengthen the concepts and
we hope that this section would prove a rich resource for practicing challenging problems and
enhancing the preparation level of IIT JEE aspirants.
By : Shailendra Maheshwari
So lu t ion s wi l l b e p ub lished in nex t issue Joint Director Academics, Career Point, Kota
1
∫x tan −1 x dx , then expression In in terms
n
6. Let In =
0
of In–2.
2m
π2
|DE| = x12 + 1 |x1 – x2| = 2
− ∫
0
sin 2θ sec θdθ
1 + m2
a
f ( x) dx ≤ M(b – a)
Properties of Definite Integrals :
If the function φ(x) and ψ(x) are defined on [a, b] and
b
If f(x) ≥ 0 on the interval [a, b], then ∫ a
f ( x) dx ≥ 0 differentiable at a point x ∈ (a, b) and f(t) is
continuous for φ(a) ≤ t ≤ ψ(b), then
b b
d ψ( x)
∫ a
f ( x) dx = ∫a
f (t ) dt
dx ∫
φ( x )
f (t ) dt = f(ψ(x)) ψ´(x) – f(φ(x)) φ´(x)
a b
∫ ∫
b b
f ( x) dx = – f ( x) dx
b a ∫ a
f ( x) dx ≤ ∫ | f ( x) | dx
a
b c b
∫ ∫ ∫
2 2
f ( x) dx = f ( x) dx + f ( x) dx, a < c < b If f (x) and g (x) are integrable on [a, b], then
a a c
1/ 2 1/ 2
b b b
∫
a
f ( x) dx = ∫
a
f (a − x) dx ∫ a
f ( x) g ( x) dx ≤
∫ a
f 2 ( x) dx
∫ a
g 2 ( x) dx
0 0
b b
Change of variables : If the function f(x) is
or ∫a
f ( x ) dx = ∫ a
f (a + b − x) dx continuous on [a, b] and the function x = φ(t) is
continuously differentiable on the interval [t1, t2] and
b a = φ(t1), b = φ(t2), then
∫
a 2
f ( x) dx = ∫ f ( x ) dx if f(–x) = f(x)
b t2
∫ ∫
a
−a
0 if f(–x) = – f ( x ) f ( x) dx = f (φ(t )) φ´(t) dt
a t1
∫−∞
f ( x) dx = lim
a →−∞ a ∫ f ( x) dx and Summation of Series by Integration :
n −1
r 1 1
∫−∞
∞
f ( x) dx = ∫−∞
a
f ( x) dx + ∫a
∞
f ( x) dx lim
n →∞
∑ f n . n = ∫
r =0
0
f ( x) dx
1 1 1 1 π2
Γ(n + 1) = n Γ (n), Γ(1) = 1, Γ = π – + – .... =
2 12 22 32 12
If m and n are non-negative integers, then 1 1 1 π2
2
+ 2
+ 2
+ .... =
m +1 n +1 1 2 3 6
Γ Γ
π/ 2 2 2 Area under Curves :
∫ sin m x cos n x dx =
0 m+n+2 Area bounded by the curve y = f(x), the x-axis and the
2Γ ordinates x = a, x = b
2
b b
Reduction Formulae of some Define Integrals :
∞
= ∫
a
y dx = ∫a
f ( x) dx
a
∫0
e −ax cos bx dx =
a + b2 2 Y
y = f (x)
∞ b
∫0
e −ax sin bx dx =
a2 + b2 y x=b
∞ n!
∫0
e −ax xndx =
a n +1
O δx X
π/2
If In = ∫
0
sin n x dx , then Area bounded by the curve x = f(y), the y-axis and the
abscissae y = a, y = b
Y
D C X
O
B
A
If f(x) ≥ 0 for a ≤ x ≤ c and f(x) ≤ 0 for c ≤ x ≤ b, then
area bounded by y = f(x), x-axis and the ordinates Black holes are the most fuel-efficient engines in
x = a, x = b is given by the universe.
c b c b
= ∫ a
f ( x) dx + ∫ c
− f ( x) dx = ∫ a
f ( x) dx – ∫
c
f ( x ) dx The results were surprising because the types of black
holes studied were older, less powerful and generally
considered boring, scientists said. But they ended up
A being more efficient than originally thought, possibly
x=a
OH OH
CHEMISTRY (C) (D)
CH3
OH CH2–OH
II
I CH3 (A) (B)
CH3 OH
CH3 HO CH3
OH
OH
CH3
III IV
(C) (D)
(A) II > IV > I > III (B) I > IV > III > II O
(C) I > II > III > IV (D) IV > I > III > II OH CH3
CH3 CH3
O ⊕ 5. V1 mL of NaOH of normality X and V2 mL of
2. H major tautomer (enol Ba(OH)2 of normality Y are mixed together. the
mixture is completely neutralised by 100 mL of 0.1
form) among the following is - 1 X
N HCl. If V1 / V2 = and = 4, what fraction of
OH OH 4 Y
(A) (B) the acid is neutralized by Ba(OH)2 :
(A) 0.5 (B) 0.25 (C) 0.33 (D) 0.67
(B) PCO = PB2 H 6 > PCH 4 > PH 2 This section contains 2 paragraphs; passage- I has 2
multiple choice questions (No. 12 & 13) and passage- II
(C) PCO > PB2 H 6 = PH 2 > PCH 4 has 3 multiple (No. 14 to 16). Each question has 4
choices (A), (B), (C) and (D) out of which ONLY ONE
(D) PB2 H 6 > PH 2 > PCH 4 > PCO is correct. Mark your response in OMR sheet against
the question number of that question. +3 marks will be
given for each correct answer and –1 mark for each
7. The dipole moment of HBr is 2.6 × 10–30 c–m and
wrong answer.
the interatomic spacing is 1.41Å. The percentage of
ionic character in HBr is : Paragraph # 1 (Ques. 12 to 13)
(A) 10.5 (B) 11.5 (C) 12.5 (D) 13.5 De-Broglie proposed dual nature for electron by
h
putting his famous equation λ = . Later on
SECTION – II mu
Multiple Correct Answers Type Heisenburg proposed uncertainty principle as ∆p.∆x ³
Questions 8 to 11 are multiple choice questions. Each h h
h = . On the contrary particle nature of
question has four choices (A), (B), (C) and (D), out of 2 2π
which MULTIPLE (ONE OR MORE) is correct. Mark electron was established on the basis of photoelectric
your response in OMR sheet against the question effect. When a photon strikes the metal surface,, it
number of that question. + 4 marks will be given for gives up its energy to the electron. Part of this energy
each correct answer and no negative marks. (say W) is used by the electrons of escape from the
O metal and the remaining imparts the kinetic energy
(½ mu2) to the photoelectron. The potential applied
on the surface to reduce the velocity of photoelectron
8. The compound C H may be named as -
2 5 to zero is known as stopping potential.
CH3
(A) 3– ethyl, 2-methyl oxirane 12. With what velocity must an electron travel so that its
(B) 1, 2 – epoxy – 2 – methyl butane momentum is equal to that of photon of wavelength
(C) 1, 2 – oxa pentane of λ = 5200 Å :
(D) 2 – methyl –1, 2– butoxide (A) 800 m s–1 (B) 1400 m s–1
(C) 400 m s–1 (D) 200 m s–1
9. In which of the following reactions 3º alcohol will
be obtained as a product -
⊕ 13. The wavelength of helium atom whose speed is equal
H
(A) MgBr + HCOCl → to its rms speed at 27ºC :
(A) 7.29 × 10–11 m (B) 4.28 × 10–10 m
(excess) –11
(C) 5.31 × 10 m (D) 6.28 × 10–11 m
O
⊕
H Paragraph # 2 (Ques. 14 to 16)
(B) Ph–Mg–Br + CH3—C—Cl → →
(excess) From following sets of compounds give answer of
⊕
O CH3 Ge
Set – C
O (vii) D C CH3 (viii)
I II Ph H
C2H5 CH3
O O 14
O 18. In the following reaction double bond equivalent of
D is –
OH OH
O
III IV
dil.HNO3 (1) Sn / HCl
14. Correct statement regarding set A - A + B (2)NaNO / HCl C (mild-basic) D
2
(A) I is stronger acid than III More Less condition
volatile volatile
(B) II is stronger acid then I
(C) III & IV are equal acidic strength
(D) IV is weaker acidic then I 19. How many groups are o/p director in electrophilic
aromatic substitution reaction –
15. Correct statement regarding set B - (i) — NH2 (ii) — CHO
(A) I & II compound show both resonance and (iii) — COOH (iv) —OMe
hyperconjugation (v) —O—C—Me (iv) — Et
(B) III compound show five hyperconjugation O
structure (vii) —C—NH—Me (viii) – SO3H
(C) IV is more stable than II
(D) II is more stable than I O
(ix) —N = O (x) —N = NH
16. Correct statement regarding set C -
(A) II is stronger acid than I 20. How many compound which is given below is
(B) I is stronger acid than IV isomer of D-glucose.
(C) II and III are equal acidic D-Mannose, D – Fructose, D-Idose,
(D) In IV acid anion is not stablises by resonance D-Galactose, D-Arabinose, D-Ribose
21. What is oxidation state of sulphur in Caro's acid?
(i) ⊕
N (ii) ⊕ which ONLY ONE is correct. Mark your response in
N
H T Ph C2H5 OMR sheet against the question number of that
D CH2 =CH–CH2 question. + 3 marks will be given for each correct
O answer and – 1 mark for each wrong answer.
CH3O H
(iii) (iv) CH3 S CH3
x 1 1
1. Let f (x) = sin πx 2 x 2 1 , f (x) be an odd function
H x3 3x 4 1
O
Si and its odd value is equal to g(x), then
(v) P (vi) f (1) g(1) is -
H D H (A) –1 (B) – 4 (C) – 5 (D) 1
T CH3
D
3. If x1, x2, x3, x4 are roots of the equation 11. If u = a 2 cos 2 θ + b 2 sin 2 θ +
x4 – x3 sin 2β + x2 cos 2β – x cos β – sin β = 0, then
4 a 2 sin 2 θ + b 2 cos 2 θ , then
∑ tan
i =1
−1
xi is equal to (A) max. u2 = a2 + b2
(A) π – β (B) π – 2β (B) max. u2 = 2 a 2 + b 2
(C) π/2 – β (D) π/2 – 2β (C) min. u2 = 2(a + b)2
(D) min u2 = (a + b)2
4. Lim− [1 + (cos x)cos x]2 is equal to
π
x→
2 SECTION – III
(A) Does not exist (B) 1 Comprehension Type
(C) e (D) 4 This section contains 2 paragraphs; passage- I has 3
multiple choice questions (No. 12 to 14) and passage- II
5. If f (x) = logx (ln (x)), then f '(x) at x = e is has 2 multiple (No. 15 & 16). Each question has 4
(A) 0 (B) 1 choices (A), (B), (C) and (D) out of which ONLY ONE
(C) e (D) 1/e is correct. Mark your response in OMR sheet against
the question number of that question. +3 marks will be
6. If the function f (x) = |x2 + a |x| + b| has exactly three given for each correct answer and –1 mark for each
points of non-differentiability, then which of the wrong answer.
following may hold
(A) b = 0, a < 0 (B) b < 0, a ∈ R Passage # 1 (Ques. 12 to 14)
(C) b > 0, a ∈ R (D) b < 0, a ∈ R–
f (x) = sin {cot–1 (x + 1)} – cos (tan–1 x)
7. The inequality log2(x) < sin–1 (sin(5)) holds if x ∈
a = cos tan–1 sin cot–1 x
(A) (0, 25–2π) (B) (25–2π, ∞)
2π–5 b = cos (2 cos–1 x + sin–1 x)
(C) (2 , ∞) (D) (0, 22π–5)
SECTION – II 12. The value of x for which f (x) = 0 is -
Multiple Correct Answers Type (A) – 1/2 (B) 0
Questions 8 to 11 are multiple choice questions. Each (C) 1/2 (D) 1
question has four choices (A), (B), (C) and (D), out of
which MULTIPLE (ONE OR MORE) is correct. Mark 13. If f (x) = 0, then a2 is equal to -
your response in OMR sheet against the question (A) 1/2 (B) 2/3
number of that question. + 4 marks will be given for (C) 5/9 (D) 9/5
each correct answer and no negative marks.
8. 2 tan–1(–3) is equal to 14. If a2 = 26/51, then b2 is equal to -
(A) – cos–1(–4/5) (B) – π + cos–1 (4/5) (A) 1/25 (B) 24/25
(C) – π/2 + tan–1(–4/3) (D) cot–1 (4/3) (C) 25/26 (D) 50/51
9. Let [x] denotes the greatest integer less than or equal Passage # 2 (Ques. 15 & 16)
to x. If f (x) = [x sin πx], then f (x) is v( x) dy
(A) continuous at x = 0
(B) continuous in (–1, 0)
If y = ∫ u ( x)
f (t ) dt, let us define
dx
in different
(C) differentiable at x = 1 dy
(D) differentiable at (–1, 1) manner = v'(x) f (v(x)) – u'(x) f (u(x)) and the
dx
x2 equation of tangent at (a, b) is.
10. Let f be the function f (x) = cos x – 1 − , then
2 dy
(y – b ) = (x – a )
(A) f (x) is an increasing function in (0, π/2) dx ( a ,b )
(B) f (x) is a decreasing function in (–∞, ∞)
19. The number of polynomials of the form 2. Two smooth, identical billiard balls A and B collide
x3 + ax2 + bx + c which are divisible by x2 + 1, where with B at rest and A in motion as shown. If speed of
a, b, c ∈ {1, 2, 3, ….. 10} must be 2k. Value of k will A is 'v' before collision and coefficient of restitution
be. for the collision is 'e', the speed of B after collision
will be-
d2y
20. If ey + xy = e, then at x = 0 is e–λ, then v A
dx 2
numerical quantity λ should be equal to………. B θ
(A) 70 N (B) 25 N
(C) 40 N (D) 35 N (A) Electric current at cross section P is equal to that
5. A tunnel is dug across the diameter of Earth. A ball of cross section Q
is released from the surface of Earth into the tunnel. (B) Electric field intensity at P is less than that at Q
The velocity of ball when it is at a distance R/2 from (C) The number of electrons crossing per unit area
centre of Earth is (where R = radius of earth and M = per unit time at cross section P is less than that at
mass of Earth) Q
3GM 2GM (D) The rate of heat generating per unit time at Q is
(A) (B) greater than that of P
4R 3R
GM 2GM 10. The horizontal distance x and the vertical height y of
(C) (D)
2R R a projectile at time t are given by
x = at and y = bt2 + ct, where a, b and c are constant.
6. The work done to break a spherical drop of radius R in Then-
n drops of equal size is proportional to- (A) the speed of the projectile 1 second after it is
1 1 fired is (a2 + b2 + c2)1/2
(A) 2 / 3 − 1 (B) 1/ 3 − 1
n n (B) the angle with the horizontal at which the
(C) n1/3 –1 (D) n4/3 – 1 c
projectile is fired is tan–1
a
7. A rod of length L kept on a smooth horizontal
(C) the acceleration due to gravity is –2b
surface is pulled along its length by a force F. The
area of cross-section is A and Young's modulus is Y. (D) the initial speed of the projectile is
The extension in the rod is- (a2 + c2)1/2
F
11. A block having mass m and charge q is connected by
FL 2FL FL spring of force constant k. The block lies on a
(A) (B) (C) (D) zero
AY AY 2AY frictionless horizontal track and a uniform electric
field E acts on system as shown. The block is
SECTION – II released from rest when spring is unstretched (at x =
Multiple Correct Answers Type 0). Then-
Questions 8 to 11 are multiple choice questions. Each
question has four choices (A), (B), (C) and (D), out of E
which MULTIPLE (ONE OR MORE) is correct. Mark
your response in OMR sheet against the question q,m
number of that question. + 4 marks will be given for
each correct answer and no negative marks. 2qE
(A) maximum elongation in the spring is
k
8. Under the action of a force, 2 kg body moves such
that its position x as a function of time is given by x qE
(B) at equilibrium position, elongation in the spring is
t3 k
= , x is in meter and t in second-
3 qE
(C) amplitude of oscillation of block is
(A) body is acted by constant force k
(B) body is acted by a force which is proportional to 2qE
time (D) amplitude of oscillation of block is
k
(C) body is acted by a force which is proportional to
square of time
(D) work done by the force in first 2 second is 16 J
10µF 1µF
V
12V
20. Three identical rods are joined at point O as shown in
12. Equivalent capacitance of the circuit between A and the figure. In the steady state, find the ratio of
B is- thermal current through rod AO and OC.
(A) 10 µF (B) 7.5 µF C
20ºC
(C) 5 µF (D) 14 µF
100ºC
13. Charge stored by 5 µF capacitor is-
(A) 20 µC (B) 70 µC A O
(C) 10 µC (D) zero
0ºC
14. Energy stored by 10 µF capacitor is- 21. A rod of length 20 cm is placed along the optical axis
(A) 20 µJ (B) 40 µC of a concave mirror of focal length 30 cm. One end
(C) 400 µJ (D) 245 µF of the rod is at the centre of curvature and other end
lies between F and C. Calculate the linear
magnification of the rod.
Passage # 2 (Ques. 15 & 16)
22. Figure shows a parabolic reflector in x-y plane given
Potential energy of particle is given by
by y2 = 8x. A ray of light traveling along the line y =
U = 5 + (x – 1)2. Particle have kinetic energy at x =
a is incident on the reflector. Find where the ray
2m is 10 J. Then
intersects the x-axis after reflection.
15. Total mechanical energy is- y-axis y2 =8x
(A) 16 J (B) 26 J (C) 6 J (D) 5 J line y = a
P(0,a)
incident ray
16. Minimum potential energy is- x-axis
(A) 5 J (B) 10 J (C) 6 J (D) 9 J
Hb 6.
Ha
H
Hcc (A) Fused with Na2CO3 (B) (H2SO4 + H2O) (C)
Evaporisation
Green solid Yellow Orange
(A) Ha (B) Hb (C) Hc (D) Hd
solution
(CH3COO)2Pb
2. The no. of position isomers for
CH3—CH—CH2—C≡CH are (give answer (D) Yellow
CH3 Here, A, B, C and D are respectively :
including this structure) : A B C D
(A) 1 (B) 2 (C) 0 (D) 3 (A) FeSO4 FeCO3 Fe(OH)3 PbCO3
(B) Cr2O3 Na2CrO4Na2Cr2O7 PbCrO4
3. Rank the following alkyl halides in order of (C) FeCl2 FeSO4 PbSO4 Fe(OH)3
increasing SN2 reactivity: (D) FeSO4 FeCl3 Fe(OH)3 PbCl2
Br Br
Br 7. The negative charge on As2S3 sol is due to absorption
of :
I II III (A) H¯ (B) OH¯
(A) I < III < II (B) III < I < II (C) O2– (D) S2–
(C) II < I < III (D) I < II < III
10. Which of the following function are defined for all x x 3 − 2 x, x<0 (Q) Discontinuous
(B) f (x) = 2
(A) sin[x] + cos [x] ([x] denotes greatest integer ≤ x) x − 2 sin( x), x≥0
(B) sec–1 (1 + sin2 x) (R) Differentiable
4 − x 2 , x<0
(C) tan (log x) (C) f (x) = 2
5− x , x≥0
9
(D) + cos x + cos 2 x 3 − 2 x , x <1 (S)Non- differentiable
8 (D) f (x) = (T) continuous &
7 − 6 x, x ≥1
differentiable
11. If x + |y| = 2y, then y as a function of x is
(A) defined for all real x 14. Match the column
(B) continuous at x = 0 Column –I Column-II
(C) differentiable for all x (A) If x2 + y2 = 1, then minimum (P) – 3
(D) such that dy/dx = 1/3 for x < 0 value of x + y is
(B) If maximum value of (Q) − 2
12. Two villages A and B are on the same side of a 1
y = acos(x) – cos (3x)
straight river. A pump set is to be installed by the 3
river side at a point P. Then if the villages are
π
situated at a distance c, then occurs, when x = , then
6
(where a =distance of village A from river side,
value of 'a' is
b = distance of village B from river side,
(C) If f (x) = x – 2sin(x), 0 ≤ x ≤ (R) 3
c = distance between villages.)
2π is increasing in interval
(A) minimum value of PA + PB is c 2 + 2ab (aπ, bπ) then, (a + b) is
(D) If equation of tangent to the (S) 2
(B) minimum value of PA + PB is c 2 + 4ab curve y = – e–x/2, where it (T) 1
crosses the y-axis is
(C) minimum value of PA + PB is c 2 + ab x/p + y/q = 1, then p – q is
(D) The required location must lie on the imaginary
line joining village A and image of village B in SECTION – IV
the river. Numerical Response Type
This section contains 6 questions (Q.15 to 20). The
SECTION – III answer to each of the questions is a Single-digit integer,
Matrix Match Type ranging from 0 to 9. The bubble corresponding to the
correct answer is to be darkened in the OMR. +4
This section contains 2 questions. Each question has marks will be given for each correct answer and no
four statements (A, B, C and D) given in Column-I and negative marking for each wrong answer.
five statements (P, Q, R, S and T) in Column-II. Any
given statement in Column–I can have correct 15. An urn containing '14' green and '6' pink ball.
matching with One or More statement(s) given in K (< 14, 6) balls are drawn and laid a side, their
Column II. For example, if for a given question, colour being ignored. Then one more ball is drawn.
statement B matches with the statements given in Q Let P(E) be the probability that it is a green ball, then
and R, then for the particular question, against 10 P(E) = ..............
statement B, darken the bubbles corresponding to Q
16. Two lines zi – z i + 2 = 0 and z(1+i) + z (1–i) + 2 = 0
and R in the OMR. +8 marks will be given for each
intersect at a point P. Find the sum of minimum and
correct answer (i.e. +2 marks for each correct row) and
maximum modulus of complex number of a point on
no negative marking for each wrong answer.
second line which is at a distance of 2 units from
point P.
19. If the solution of differential equation 4. A particle is moving in parabolic path y = x2 with
2
d y dy constant speed 'u'. Then acceleration of the particle
x2 2 + 2x = 12y is y = Axm + Bx–n then find the
dx dx when it crosses origin, is-
value of m + n, if m & n ∈ N. (A) u2 (B) 2u2
u2
1 (C) zero (D)
20. If f(x) = x + ∫ 0
(xy2 + x2y) f (y) dy, then 2
O T/2 T
SECTION – II t
Multiple Correct Answers Type
Questions 9 to 12 are multiple choice questions. Each 2i 0 i0
question has four choices (A), (B), (C) and (D), out of (A) im = (B) im =
π 2
which MULTIPLE (ONE OR MORE) may be correct.
Mark your response in OMR sheet against the question i0 i0
(C) irms = (D) irms =
number of that question. +4 marks will be given for 3 2
each correct answer and no negative marks for wrong
answer. SECTION – III
9. Missile is fired for maximum range at your town Matrix Match Type
from a place in the enemy country at a distance 'x' This section contains 2 questions. Each question has
from your town. The missile is first detected at its four statements (A, B, C and D) given in Column-I and
half-way point. Then- five statements (P, Q, R, S and T) in Column-II. Any
(A) the velocity with which the missile was projected given statement in Column–I can have correct
matching with One or More statement(s) given in
is gx Column II. For example, if for a given question,
x statement B matches with the statements given in Q
(B) you have a warning time of and R, then for the particular question, against
2g statement B, darken the bubbles corresponding to Q
and R in the OMR. +8 marks will be given for each
gx correct answer (i.e. +2 marks for each correct row) and
(C) the speed of the missile when it was detected is
2 no negative marking for each wrong answer.
x 13. Consider the circuit showing in figure. There are
(D) the maximum height attained by the missile is
4 three switches S1, S2, S3. Match the columns.
C
10. A particle A of mass 'm' and charge Q moves directly S1
3r
towards a fixed particle B, which has charge Q. The r
speed of A is 'v' when it is far away from B. The S3
minimum separation between the particles is S2
proportional to- 2r
(A) Q2 (B) 1/v2
(C) 1/v (D) 1/m
V
Instructions :
• There are three parts in question paper A, B, C consisting of chemistry, Physics & Mathematics having
30 questions in each part of equal weightage. Each question is allotted four marks for each correct response.
• 1/4 (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from the
total score will be made if no response is indicated for an item in the answer sheet.
26. The correct order of acidic strength of following acid n(n − 1) n(n + 1)
(1) (2)
is - 2 2
COOH COOH COOH COOH n(n + 2)
(3) (4) none of these
OH HO OH CH3 2
k
2π 2π
(II) (III) OH cos − sin
(I)
(IV) 34. If
7 7 = 1 0 , Then the least
0 1
sin 2π cos 2π
(1) II > I > III > IV (2) I > II > III > IV 7
7
(3) II > I > IV > III (4) II > IV > I > III
positive integral value of k is -
27. In the phenomenon of osmosis, the semipermeable (1) 6 (2) 7 (3) 3 (4) 4
membrane allows the passage of
(1) solute particles 35. The number of 2 digit numbers , which are of the
(2) solvent molecules only form xy with y < x are given by
(3) both solute and solvent (1) 45 (2) 55 (3) 17 (4) None
(4) none
36. Let A, B, C be three independent events such that
28. What is the contribution of the atom present at the 1 1 1
P(A) = , P(B) = , P(C) = . Then probability of
edge centre to the cubic unit cell ? 3 2 4
(1) 1/2 (2) 1/4 exactly two events occuring out of three events is -
(3) 1/8 (4) 1 (1) 1/2 (2) 1/3
(3) 1/4 (4) none of these
29. In the cell, Zn | Zn2+ | | Cu2+ | Cu, the negative
terminal is - 37. If a variable x takes values xi such that a ≤ xi ≤ b, for
(1) Cu (2) Cu2+ i = 1, 2, ---- n, then -
(3) Zn (4) Zn2+ (1) a ≤ Var (x) ≤ b (2) a2 ≤ Var (x) ≤ b2
a2
30. Assign double bond configuration of the following - (3) ≤ Var (x) (4) (b – a)2 ≥ Var (x)
4
COOH
CH2OH 38. A variable line has it's intercepts on the coordinate
NC e e'
axes e, e' where , are eccentricies of
H2N–H2C CN 2 2
(1) E, Z (2) Z, Z hyperbola and it's conjugate hyperbola then the line
always touches the circle x2 + y2 = r2, where r = ?
(3) E, E (4) Z, E
(1) 1 (2) 2
(3) 3 (4) cannot be decided
MATHEMATICS (Part-B) 39. If it is possible to draw a line which belongs to all the
given family of lines y – 2x + 1 + λ1 (2y – x – 1) = 0, 3y
– x– 6 + λ2 (y – 3x + 6) = 0 and
31. f(x) = log x2
25 and g(x) = logx 5 then f(x) = g(x)
ax + y – 2 + λ3 (6x + ay – a) = 0 , then -
holds for x belonging to - (1) a = 4 (2) a = 3
(1) R (2) (0, 1)∪ (1, ∞) (3) a = – 2 (4) a = 2
(3) φ (4) none
40. If (α, 0) is an interior point of ∆ABC formed by the
32. The area enclosed by the parabola y2 = 4ax between lines x – y = 0, 4x + 3y – 12 = 0 and y + 2 = 0 then
the ordinates x = a and x = 9a is - integral values of α are
a2 a2 (1) 1 (2) 2
(1) 8a2 (2) 108 (3) 208 (4) a2
3 3 (3) 4 (4) 8
+σ –λ
Θ
72. When both light bulbs are screwed in, the current
RS through the battery is -
⊕
(3) RL
(1) 1.2 ampere (2) 2 ampere
(3) 4 ampere (4) 6 ampere
Θ
RS 73. String 1 has twice the length, twice the radius, twice
⊕ the tension and twice the density of another string 2.
(4) RL The relation between the fundamental frequencies of
1 and 2 is :
Θ (1) f1 = 2f2 (2) f1 = 4f2
(3) f2 = 4f1 (4) f1 = f2
Instructions :
• This question paper contains 150 questions in Physics (40) Chemistry (40), Mathematics (45), Logical
Reasoning (10) & English (15). There is Negative Marking
• Each question has four option & out of them, ONLY ONE is the correct answer. There is – ve marking.
• +3 Marks for each correct & – 1 Mark for the incorrect answer.
27. In a magnetic field of 0.05 T area of coil changes 34. A transverse sinusoidal wave moves along a string in
from 101 cm2 to 100 cm2 without changing the the positive x-direction at a speed of 10 cm/ s. The
resistance which is 2Ω. The amount of charge that wavelength of the wave is 0.5 m and its amplitude is
flow during this period is 10 cm. At a particular time t, the snap-shot of the
(A) 2.5 × 10–6 C (B) 2 × 10–6 C wave is shown in the figure. The velocity of point P
–6
(C) 10 C (D) 8 × 10–6 C when its displacement is 5 cm, is -
Rate
CH2CH=CH2+ NBS → A
(C) (D)
Rate
Rate
Compound formed A is -
(A)2 (A)2
(A) CHCH=CH2
13. For an elementary process Br
2X + Y —® Z + W
(A) 2 (B) 1 (B) CH = CHCH2Br
(C) 3 (D) unpredictable.
(C) (D)
H3C CH3
21. Grignard reagent reacts with HCHO to produce:
(A) 3,5-dimethylcyclohexene
(A) secondary alcohol
(B) 3,5-dimethyl -1-cyclohexene
(B) anhydride
(C) 1,5-dimethyl-5-cyclohexene
(C) and acid
(D) 1,3-dimethyl-5-cyclohexene
(D) primary alcohol
30. The ions O2–, F–, Na+, Mg2+ and Al3+ are
22. Cyanohydrin of which of the following forms lactic
isoelectronic. Their ionic radii show.
acid :
(A) A decrease from O2– to F– and then increase from
(A) HCHO (B) CH3CHO
Na+ to Al3+
(C) CH3CH2CHO (D) CH3COCH3
(B) A significant increase from O2– to Al3+
23. Isopropyl bromide on Wurtz reaction gives : (C) A significant decrease from O2– to Al3+
(A) hexane (D) An increase from O2– to F– and then decrease
(B) propane from Na+ to Al3+
(C) 2, 3-dimethylbutane
(D) neo-hexane 31. Which of the following values in electron volt per
atom represent the first ionisation energies of oxygen
24. On heating with oxalic acid at 110°C, glycerine gives:
and nitrogen atom, respectively ?
(A) glyceryl trioxalate (B) formic acid
(A) 14.6, 13.6 (B) 13.6, 14.6
(C) glyceryl dioxalate (D) none of the above
(C) 13.6, 13.6 (D) 14.6, 14.6
25. The compound, whose stereo-chemical formula is
32. Which of the following is not involved in any
written below, exhibits x geometrical isomers and y
diagonal relationship ?
optical isomers.
(A) C (B) B (C) Al (D) Si
CH3 H OH
C=C 33. A metal M readily forms water soluble sulphate
H CH2–CH2–C–CH3 MSO4, water insoluble hydroxide M(OH)2 and oxide
H MO which becomes insert on heating. The hydroxide
is soluble in NaOH. The M is -
The values of x and y are :
(A) Be (B) Mg
(A) 4 and 4 (B) 2 and 2
(C) Ca (D) Sr
(C) 2 and 4 (D) 4 and 2
34. Plaster of paris is -
26. Which one of the following product is formed when (A) CaSO4 (B) CaSO4.H2O
calcium salt of adipic acid is heated ? (C) 2CaSO4.H2O (D) CaSO4.2H2O
CH2–CH2
(A) O 35. In diborane -
CH2–CH2
(A) 4-bridged hydrogens and two terminal hydrogens
CH2–CH2 are present
(B) C=O (B) 2-bridged hydrogens and four terminal
CH2–CH2
hydrogens are present
CH2CH2CO (C) 3-bridged hydrogens and three terminal
(C) C=O
CH2CH2CO hydrogens are present
(D) None of these
CH2CH2COOH
(D)
CH2CH2COOH
r 2 – b2 a2 – r 2
1. The point on the line 3x + 4y = 5 which is equidistant (C) (D)
from (1, 2) and (3, 4) is a2 – r 2 r 2 – b2
(A) (7, – 4) (B) (15, – 10)
10. If f : R → R and g : R → R are defined by f(x) = | x |
(C) (1/7, 8/7) (D) (0, 5/4)
and g (x) = [x – 3] for x ∈ R, then
2. The transformed equation of 3x2 + 3y2 + 2xy = 2 8 8
when the coordinate axes are rotated through an g ( f ( x)) : – < x < is equal to -
5 5
angle of 45º, is
(A) {0, 1} (B) {1, 2}
(A) x2 + 2y2 = 1 (B) 2x2 + y2 = 1
2 2
(C) {–3, –2} (D) {2, 3}
(C) x + y = 1 (D) x2 + 3y2 = 1
11. If f : R → R is defined by
3. The length of the common chord of the ellipse
cos 3x – cos x
( x – 1) 2 ( y – 2) 2 , for x ≠ 0
+ = 1 and the circle (x – 1)2 + (y–2 )2 = 1 f (x) = x2
9 4 λ , for x = 0
is
and if f is continuous at x = 0, then λ is equal to -
(A) 0 (B) 3
(A) – 2 (B) – 4 (C) – 6 (D) – 8
(C) 4 (D) 5
2x – 1 1 1 1 1
4 3 + 3 + 2 + ..... + (n + 1) n + n + 2 ,
15. x ∈ R : 3 ∈ R equals
ω ω ω ω
x + 4 x 2 + 3x
(A) R – {0} (B) R – {0, 1, 3} where ω is an imaginary cube root of unity, is
1 n(n 2 + 2) n(n 2 – 2)
(C) R – {0, –1, – 3} (D) R – 0, – 1, – 3, + (A) (B)
2 3 3
n 2 (n + 1) 2 + 4n
(C) (D) None of these
d –1 x – 1 1 4
16.
dx a tan x + b log x + 1 = 4
x – 1 a2 a3 a +a a –a
24. If = 2 3 = 3 2 3 , then a1, a2, a3, a4
⇒ a – 2b is equal to - a1a4 a1 + a4 a1 – a4
(A) 1 (B) – 1 (C) 0 (D) 2 are in
(A) A.P. (B) G.P.
17. The function f (x) = x3 + ax2 + bx + c, a2 ≤ 3b has (C) H.P. (D) None of these
(A) one maximum value
(B) one minimum value x2 – 1
25. If f (x) = for every real number x then the
(C) no extreme value x2 +1
minimum value of f
(D) one maximum and one minimum value
(A) does not exist because f is unbounded
18. Area of the region satisfying x ≤ 2, y ≤ | x | and x ≥ 0 is (B) is not attained even though f is bounded
(A) 4 sq. unit (B) 1 sq. unit (C) is equal to 1
(D) is equal to – 1
(C) 2 sq. unit (D) None of these
26. If x + y and y + 3x are two factors of the expression
1 1 2
λx3 – µx2y + xy2 + y3, then the third factor is
∫ ∫ ∫
x2 x3 x2
19. If I1 = 2 dx , I2 = 2 dx , I3 = 2 dx and
0 0 1 (A) y + 3x (B) y – 3x
2 (C) y – x (D) None of these
∫
3
I4 = 2 x dx , then
1
27. The number of ways in which 30 marks can be
(A) I3 > I4 (B) I3 = I4 allotted to 8 questions if each question carries at least
(C) I1 > I2 (D) I2 > I1 2 marks, is
(A) 115280 (B) 117280
20. Let A = [–1, 1] and f : A → A be defined as (C) 116280 (D) None of these
f (x) = x | x | for all x ∈ A, then f (x) is -
28. The numerically largest term in the binomial
(A) many-one into function 2
expansion of (4 – 3x)7, when x = is -
(B) one-one into function 3
(C) many-one onto function (A) 46016 (B) 66016
(D) one-one onto function (C) 86016 (D) None of these
LOGICAL REASONING
8. Directions : The questions that follow contain a set
1. Fill in the blank spaces of three figure X, Y and Z showing a sequence of
folding of piece of paper. Fig. (Z) shows the manner
6, 13, 28, . ?. . .
in which the folded paper has been cut. These three
(A) 56 (B) 57 (C) 58 (D) 59 figure are followed by four answer figure from which
2. Choose the best alternative you have to choose a figure which would most
Car : Petrol : : T.V. : ? closely resemble the unfolded form of figure. (Z)
(A) Electricity (B) Transmission
(C) Entertainment (D) Antenna
3. Pick the odd one out – X Y Z
(A) Titan (B) Mercury
(C) Earth (D) Jupiter
(A) (B) (C) (D)
4. Direction : In questions, find out which of the
figures (A), (B), (C) and (D) can be formed from the A B C D
pieces given in (x).
9. Direction : In following questions, complete the
missing portion of the given pattern by selecting from
the given alternatives (A), (B), (C) and (D).
(x)
?
(A) (B) (C) (D)
(X)
5. Directions : In question, choose the set of figures
which follows the given rule.
(A) (B) (C) (D)
Rule : Closed figures become more and more open
and open figures more and more closed.
(A) Wicked (B) Impolite (A) Meatless days (B) have been made
(C) Cowardly (D) Foolish (C) into a film (D) No Error
6. Choose the word which is closest to the 'opposite' in
13. Which part of the following sentence has an error ? If
meaning of the underlined word
the sentence is correct, the answer will be 'No Error".
Many snakes are 'innocuous' :
Looking forward / to / meet you here / No Error
(A) Deadly (B) Ferocious (a ) (b) ( c) (d )
(C) Poisonous (D) Harmful (A) looking forward (B) to
7. Choose the one which can be substituted for the (C) meet you here (D) No error
given words/sentences :
Giving undue favours to one's kith and kin' 14. Choose the one which best expresses the meaning of
(A) Corruption (B) Worldliness the given Idiom/Proverb :
(C) Favouritism (D) Nepotism The 'pros and cons'
(A) Good and Evil
8. Find out which one of the words given below the (B) Former and Latter
sentence can most appropriately replace the group of (C) For and Against a thing
words underlined in the sentence :
(D) Foul and Fair
The bus has to "go back and forth" every six hours.
(A) Cross (B) Shuttle 15. Replace the underlined word with one of the given
(C) Travel (D) Run options :
9. Read both the sentences carefully and decide on their The Second World War started in 1939.
correctness on the basis of the underlined words : (A) Broke out (B) Set out
1. I am out of practise these days (C) Took out (D) Went out
2. I practice law
(A) Only 1 is correct
(B) Only 2 is correct
(C) Both the sentences 1 & 2 are correct
(D) Both the sentences 1 & 2 are incorrect
(excess)
1. [A] CH3
1 ⊕
HOC ∝ H
stability CH3–Mg – Br + Cl–C–OC2H5 →
(excess)
So II > IV > I > III
O
2. [B] OH
In acidic médium enol form depend on stability of
CH3—C—CH3
alkene
CH3
3. [C] Both double are E, E isomer
10. [B,C]
CH2–OH
O Cr3+ → 3, Mn2+ → 5, Fe3+ → 5, Cu2+ → 1
⊕
H / H2O 11. [B,C,D]
4. [B]
Fe, Cr, Al have protected film
3. [C] We have
f (| x |) = x2 + a |x| + b
S1 = Σ x1 = sin 2β
S2 = Σ x1x2 = cos 2β
S3 = Σ x1x2x3 = cos β
S4 = x1x2x3x4 = – sin β
4
S1 − S3
so that ∑ tan
i =1
−1
xi = tan–1
1 − S2 + S4 | f |x|| = | x2 + a |x| + b|
sin 2β − cos β
= tan–1
1 − cos 2β − sin β
cos β(2 sin β − 1)
= tan–1
sin β(2 sin β − 1)
= tan cot β = tan–1 (tan (π/2 – β)) Exactly at three points function is not differentiable.
= π/2 – β
5
⇒ 2 tan (–3) = – cos–1 (– 4/5)
–1 13. [C] a = cos tan–1 sin cot–1 x = cos tan–1 sin α, where x
= cot α
Again –π < 2α < 0
1
⇒ 0 < 2α + π < π = cos tan–1 = cos β where
4 1 + x2
So cos (π + 2α) = – cos 2α =
5 1 1 x2 + 1
4 tan β = = =
⇒ π + 2α = cos–1 1 + x2 1 x2 + 2
5 1+
1 + x2
4
⇒ 2 tan–1 (–3) = – π + cos–1 x2 + 1 5
5 ⇒ a2 = = for x = – 1/2
x2 + 2 9
Finally – π < 2 α < 0
⇒ –π/2 < 2α + π/2 < π/2 14. [B] Now a2 = 26/51 ⇒ x = ± 1/5
−1 and b = cos (2 cos–1 x + sin–1 x)
So tan (π/2 + 2α) = – cot 2α =
tan 2α = cos (cos–1x + π/2)
2 1
and x will change at every integral multiple of = e 1−1 / 2 = e2 = eS ⇒ S = 2 ⇒ 0002
3
3/2 19. [5] x2 + 1 = (x + i) (x – i)
They would change all together at every multiple of The cubic polynomial must vanish
LCM of {1, 1/2, 1/3, 1/4, 1/5, 3/2} = 3
for x = i , x = – i
No. of total points at which f (x) will changes its value
– i – a + bi + c = 0, i – a – bi + c = 0
in the interval [0, 3] will depend on the total number of
different terms in the following cases – – a + c = 0, –1+b=0
[x] = 0, 1, 2 – a + c = 0, 1–b=0
[2x] = 0, 1/2, 2/2, 3/2, 4/2, 5/2 b = 1, a = c ⇒ b is fixed
[3x] = 0, 1/3, 2/3, 3/3, 4/3, 5/3, 6/3, 7/3, 8/3 Now a can be chosen in 10 ways and c = a,
c can be chosen in 1 way only
[4x] = 0, 1/4, 2/4, 3/4, 4/4, 5/4, 6/4, 7/4, 8/4, 9/4,
10/4 ⇒ Number of ways of choosing
[5x] = 0, 1/5, 2/5, 3/5, 4/5, 5/5, 6/5, 7/5, 8/5, 9/5, a, b, c = 10 ⇒ 10 = 2k ⇒ k = 5
10/5, 11/5, 12/5, 13/5, 14/5
20. [ 2] ey + xy = e
2
3 x = 0, 3/2, 6/2 on putting x = 0, we get ey = e
y = 1 when x = 0
∴ f (x) will change its values in the intervals on differentiating the relation (i) we get
14 dy dy
0 ≤ x < 1/5, 1/5 ≤ x < 1/4, 1/4 ≤ x < 1/3,........... ≤ + 1.y + x. =0
5 dx dx
x<3
on putting x = 0, y = 1 we get
Total no. of different terms in above equation
= 30. dy dy −1
ey + 1= 0 ⇒ =
So, no. of terms in the range of dx dx e
f (x) for 0 ≤ x < 3 is 30 ⇒ m +21 = 30 ⇒ m =9 on differentiating solution (ii) we get
2
dy d2y dy dy d2y
h e + ey
y
+ + + x =0
−h2 1 1 dx dx 2 dx dx dx 2
18. [2] Lim h (h + 1) h + ..... h + h −1 dy −1
h →∞ 2 2
on putting x = 0, y = 1, = we get
h dx e
1 1
(h + 1) h + ....... h + h −1 d2y 1
= 2 = e–2 ⇒ λ = 2
2 2
= Lim dx 2 e
h →∞ hh
21. [1] Circle (x – 2)2 + (y – 3)2 + λ (x + y – 5) = 0
it passes through (1, 2)
h h
1 1 1 + 1 + λ (1 + 2 – 5) = 0 ⇒ λ = 1
h h+ h + h −1
h +1 2 ......... 2 x2 – 4x + 4 + y2 – 6y + 9 + x + y – 5 = 0
= Lim
h →∞ h h h (x – 3/2)2 + (y – 5/2)2 = 1/2
So, number of circle is 1.
Passage : I λ
18. [3] Here l1 e = …(i)
4
Sol. for Q.No. 12.[B], 13.[D] & 14.[A] 3λ
The given circuit can be simplified as l2 + e = …(ii)
4
23µF from (i) & (ii)
7µF
l − 3l 1
A B e= 2
12µF 5µF
2
1µF
e=3
10µF 1µF 19. [3] For a polytropic process
PVn = constant
12V
R
C = CV –
OR n −1
35µF 7µF 5 R
= R−
A B 2 −1−1
(Q P ∝ V or PV–1 = constant)
C = 3R
10µF 12µF
20. [3] Temperature of junction
100 + 20 + 0
12V TC = = 40ºC
3
35 × 7 20 i1 100 − 40
Ceq = + = 7.5 µF = =3
35 + 7 12 i2 40 − 20
Charge on 5 µF = 0
21. [3]
20
Charge on 10 µF = 12 × = 20 µC 20cm
12
A B
20 × 20 O
U12µF = = 20 µJ C f
2 × 10 f = 30cm
60cm
H Br I H 14. [A → S; B → R; C → Q; D → T;]
H Cl D H
I Br 15. [2]
Both are enantiomers. ⊕
NH3–CH–CH2–CH2–COOH
5. [D] Insulin → Zinc (Zn); Haemoglobin → Fe
B12 → Co COO Θ
Two group present in above compound.
6. [B]
∆ H2O + H2SO4 16. [5]
Cr2O3 Na2CrO4 Na2CrO7
Na2CO3
Green (CH3COO)2 Pb Orange 17. [6]
3. [B] 7. [B]
f (θ) = cos2θ + sin4 θ f (x) = 2x3 + ax2 + bx – 3cos2x
f (θ) = cos2θ + (1 – cos2 θ)2 f '(x) = 6x2 + 2ax + b + 3 sin 2x > 0
f (θ) = (cos2 θ – 1/2)2 + 3/4 6x2 + 2ax + b – 3 > 0 as sin 2x ≥ – 1
(f (θ))min = 3/4. ∴ 4a2 – 4b(b – 3) < 0 ⇒ a2 – 6b + 18 < 0
14. A → Q, B → S, C → S, D → R –i
(A) x = sin θ & y = cos θ
x + y = sin θ + cos θ |z|max = |3i| = 3
|z|min = | –i| = 1
2 sin (θ + π/4) ⇒ min. value = – 2
=
sum = 4
(B) y = a cos x – 1/3 cos (3x)
9 3 − 2 3
y'(π/6) = 0 ⇒ – a sin π/6 + sin π/2 = – +1=0
2 17. [3] A = 2 1 − 1
⇒a=2 4 − 3 2
(C) f '(x) = 1 – 2 cosx
f '(x) > 0 ⇒ cos(x) < 1/2 ⇒ x ∈ (π/3, 5π/3) − 1 − 5 − 1
adj A = − 8 − 6 9 & |A| = – 17
⇒ a = 1/3, b = 5/3 ⇒ a + b = 2
(D) at x = 0, y = – e0 = – 1 − 10 1 7
y' = 1/2 e–x/2 = y' (0) = 1/2
3 0 3 x 8 2 y
Equation of tangent y + 1 = 1/2 (x – 0)
⇒ 2 1 0 y = 1 + z is equivalent to
x y
⇒ + ⇒ p = 2, q = – 1 4 0 2 z 4 3 y
2 −1
So, p – q = 3 3 − 2 3 x 8
2 1 − 1 y = 1
15. [7] Let Ei denote the event that out of the first k
4 − 3 2 z 4
balls drawn, i balls are green. Let A denote the event
that (k + 1)th ball drawn is also green. ∴ solution is given by
14
Ci × 6 C k −i x − 1 − 5 − 1 8 − 17
P(Ei) = 20
; 0≤i≤k y = 1 − 8 − 6 9 1 = − 1 − 34
Ck
− 17 17
14 − i z − 10 1 7 4 − 51
and P(A/Ei) =
20 − k ∴x = 1 , y = 2, z = 3
14 6
k
C j × Ck −i 14 − j
Now P(A) = ∑j =0
20
Ck
+
20 − k
18. [1] Given planes are
x – cy – bz = 0 ... (i)
Also (1 + x)14 – 1 (1 + x)6 cx – y + az = 0 ... (ii)
= (14–1C0 + 14–1C1x +.......+ 14 – 1C14 – 1 x14–1) bx + ay – z = 0 ... (iii)
(6C0 + 6C1x + .......+ 6C6x6) equation of plane passing through the line of
k intersection of plane (i) and (ii) may be taken as
⇒ ∑(
j=0
14−1
C j + 6 Ck − j ) = co-efficient of xk (x – cy –bz) + λ (cx – y + az) = 0
⇒ (1 + λc) x – y (c + λ) + z (aλ – b) = 0 ....(iv)
14 14 If plane (iii) and (iv) are same then
∴ P(E) = = ⇒ 10P(Ε) = 7
6 + 14 20
W = q dV T
warning time t =
λq 0 3 2
W= ln
2π ∈0 2 u x
t= =
g 2 2g
6. [D]
+ gx
+ +
+ R+ A at max. height, v = u cos 45º =
x 2
+ +
+ + x = 3R u2 u2 x
+ max. height H = (sin 45º)2 = =
Q=λ2πR 2g 4g 4
12. [B,C]
V
We have
no charge appear on capacitor.
T
1 1
iav =
T ∫
0
i dt = (Area of i – t curve)
T 14. A → S ; B → R ; C → P; D → Q
α = 90º – 60º = 30º
i0
im = 2u sin α 2 × 40 10
2 T= = × = 4 sec
g 10 2
T T/2
1 2 1
∫ ∫i
2
irms = i dt = ×2 dt u 2 sin 2α 40 × 40 3
T0 T R= = ×
0 g 10 2
we have
R = 80 3 m
2i T
i = 0 t for 0 ≤ t ≤ u 2 sin 2 α 40 × 40
T 2 H= = = 40 m
2g 2 × 10 × 4
We get
i
irms = 0 15. [4]
3 Electric field lines are perpendicular to equipotential
surfaces and electric potential decreases along
13. A→P; B→Q;C→S; D→T electric field.
When only S1 → closed then 80V 60V 40V 20V
C
3r B 90º
A 30º 30º
r
B
120º r
V E
Br C–––––C Cl
y2= 4ax
Cl x' O x
Br
At C1 : →
(3) F (4)
y'
(4) Cw
C1––CF(Cl)Br
Exchange C1––(3) 9a
Br (2) R-form
(1) ∴ The required area = 2 ∫ 4ax dx
Cl (1) a
(2) 9a
= 4 a
x x
=
3 / 2
8 a
3
27 a a − a a [ ]
At C2 : → a
F (3) 1 208a 2
(4) =
Exchange ACw 3
Br(Cl)FC––C Cl (2) (2)––C 4
S-form
1 1
Br (1) 3 33. [2] Sλ = 1 + + + ............ ∞
λ λ2
26. [1] Due to formation of Intramolecular H.B λ
= ⇒ λ = (λ – 1 )Sλ
Conjugated base if I and II is more stable. λ −1
Due to ortho effect III is more acidic than IV n n
n(n + 1)
=
27. [2] SPM allows only solvent molecules to pass 2
through 7
2π 2π
cos − sin
28. [2] Edge-centre atom is shared in 4 cubic unit cells. 34. [2]
7 7 = 1 0
2 π 2π 0 1
sin
7 cos
29. [3] In electrochemical cells, anode = –ve 7
here k = 7
r r r r 1 ˆ 1 1
= [a b d ]c = i – ĵ + k̂ {By (1)}
6 3 3 47. [1] x2 + y2 ≤ 4
1 ˆ R = {(–2, 0) , (–1, 0), (–1, 1) , (–1, –1), (0, 0), (0, 1),
= (i − 2 ˆj + 2kˆ) (0, 2), (0, –1), (0, –2), (0,0), (1, 1), (1, –1), (2, 0)}
6
⇒ DR = {–2, –1, 0 , 1, 2}
r iˆ − 2 ˆj + 2kˆ
= c=
3 48. [3]
(i) R1 is not a relation Q 4 ∉ A
x −1 y z
44. [3] L1 : = = ...(1) (ii) R2 is subset of A × B, ∴ it is a relation
1 −1 2
(iii) R3 is subset of A × B, ∴ it is relation
x +1 y z −3
L2 : = = ...(2) (iv) R4 is subset of A × B, ∴ it is relation
2 2 λ
Shortest distance between the lines (1) & (2) is
r r r r 49. [2] Area of ∆ formed by z, ωz, z + ωz
(a1 − a 2 ).(b1 × b2 )
⇒ r r =1 1
| b1 × b2 | = |z|2. sin 120º
2
⇒ λ=? 1 2 3
But it is given (z) sin (120º) =
2 100
45. [1] l+m+n=0 ...(1)
1
and lm = 0 ...(2) |z|2 =
25
⇒ l = 0 or m = 0
1
By (1) l = – m – n (3) |z | =
5
Case (I)
If m = 0 1 1 1
| z + ωz| = |z| | 1 +ω| = | –ω2| = × 1 =
5 5 5
By (3) ⇒ l = – n
∴ DR's of line (1) is (Q 1 + ω = –ω2)
50. [1] do your self
a1, b1, c1
⇒ − n, 0, n
− 1, 0, 1 51. [4]
Let g(x) = f(x) – x2 ⇒ [g(1) = 0 , g(2) = 0,
Case (II) g(3) = 0 as f (1) = 1, f (2) = 4, f (3) = 9]
If l = 0 From RT on g(x), g' (c1) = 0 for at least x ∈ (1, 2)
By (3) ⇒ m = – n ⇒ c1 ∈ (1, 2)
DR's of line (2) is RT on g (x), g' (c2) = 0 for at least x ∈ (2, 3)
a 2, b2, c2 ⇒ c2 ∈ (2, 3)
l, m, n
∴ Now g' (c1) = g' (c2) = 0
⇒
0, − n, n ⇒ so between x ∈ [c1, c2], g" (x) = 0
0, − 1, 1 ⇒ f" (x) –2 = 0 ⇒ f" (x) = 2
∫
= tan 2 x (1 + tan2x). sec2 xdx 58. [2] P(A∩ B ) = P(A) P( B )
tan x = t = P(A) ⋅ (1–P(B))
dy du
53. [3] y = um ⇒ = mum–1. 59. [4] Contra positive of compound statement
dx dx
~ (p ∧ q) → q ≡ ~ q → ~ (~( p ∧ q))
du
Hence, 2x4.um.m um–1. + u4m = 4x6 ~ (p ∧ q) → q ≡ ~ q → (p ∧ q)
dx
so, statement I is wrong.
du 4 x 6 − u 4m 3 but statement II is correct.
= ⇒ 4m = 6 ⇒ m = and
dx 2mx 4u 2 m −1 2
3 60. [2] Both statements are correct and statement 2 is
2m – 1 = 2 ⇒ m =
2 correct explanation of statement 1
(1,2)
PHYSICS
61. [3] Statement 1 is true, statement 2 is false.
(t2, 2t)
54. [3]
62. [3] A halved, δ halved.
5
63. [1] Vfather =
60
5
For the daughter V = , after catches M = 21
Equation of tangent at (1, 2) 21
y . 2 = 2 (x + 1)
64. [3] dτ = (dq)E(2x sin θ)
x–y+1=0
image pt of (t2, 2t) about line x – y + 1 = 0 +λ
x −t2 y − 2t − 2(t 2 − 2t + 1) +
= =
1 −1 2
x = t2 – t2 + 2t – 1, y = 2t + t2 – 2t + 1
x = 2t – 1 y = t2 + 1
x +1 –λ
=t y – 1 = t2
2 σ
= λ(dx) (2x sin θ)
Eliminating 2ε 0
( x + 1) 2 σλx sin θ
y–1= ⇒ (x + 1)2 = 4 (y – 1) = dx
4 ε0
55. [1] f (x) = min ({x + 1}, {x –1}) = min ({x}, {x}) = {x} σλl 2 sin θ
τ=
4 1 2ε 0
so ∫ f ( x)dx = 9. ∫ x − [ x]dx
−5 0
65. [3]
According to Newton law of cooling rate of loss of
heat (T – T0), where T is the average temperature
56. [2] Statement I and Statement II both correct and
in the given time interval hence.
statement II is correct explanation of Statement I.
60 − 50 60 + 50
m n m
m−n
−
Even mC ∝ – 25
as h' (x) = x = .(x) odd 10 2
n n
(50 – T ) 50 + T
as h' (x) is undefined at x = 0 so h' (x) does not and mC ∝ 625
change. 10 2
sign in neighbour hood ⇒ No extreme Solving we get : T = 42.85ºC
1km
67. [4] Scooter ← → Bus dN
Relative distance = (time) (relative velocity) 75. [3] From – = λN
dt
(In uniform motion)
1000 = (100) vrel. n
n = λN or λ =
∴ 10 = (vs – vb) N
vs = 20 m/s
68. [3] Use, δm = (µ − 1) A 76. [2] Binding energy
Chemistry Joke 2:
86. [1] M ∝ k L1 L2
Q: What is the name of the molecule CH2O?
A: Seawater
87. [2]
Chemistry Joke 3:
88. [4] Q: What do you call a joke that is based on cobalt,
W1 = MB (cos 0º– cos 90º) radon, and yttrium?
A: CoRnY.
W2 = MB (cos 0º – cos 60º)
W1 = nW2
Chemistry Joke 4:
n=2 Q: If a mole of moles were digging a mole of holes,
what would you see?
89. [3] A: A mole of molasses.
Zener diode is always connected in RB and it act
as voltage regulator. Chemistry Joke 5:
Q: What does a teary-eyed, joyful Santa say about
90. [4] chemistry?
y A: HOH, HOH, HOH!
B1 i2 Chemistry Joke 6:
BR Susan was in chemistry. Susan is no more, for what
she thought was H2O was H2SO4.
x
30º ⇐ i1
Chemistry Joke 7:
B2 Q: Why is potassium a racist element?
Be A: Because, when you put three of them together,
you get KKK.
B2
tan 30º =
B1 Chemistry Joke 8:
B1 = 3 B2 An electron sitting in a prison asked a second
electron cellmate, "What are you in for?" To which
µ0i1 µi the latter replied, "For attempting a forbidden
= 3 02
2R 2R transition."
i1 1
i2 = = Amp. Chemistry Joke 9:
3 3
Q: What is the dullest element?
A: Bohrium
32. [D] r =
mV CHEMISTRY
qB
r1 V1 B2 1. [C]
= .
r2 V2 B1 Ca(OH)2 (aq.) + CO2(g) —→ CaCO3(s)
1 mol 100 g
ρ0
33. [B] ρ = given: 0.05 × 0.5 mol ?
1 + γ∆T
0.05 × 0.5 × 100
or 1(1 + γ × 4) = 0.998 = = 2.5 g
1
∴ γ = – 5 × 10–4/°C
Negative sign tells that for 0 – 4°C, water contracts n 1 w 1
2. [A] r= ∝ ⇒ ∝
on heating. t m M M
⇒ w∝ m
∂y
34. [A] From VP = – V ×
∂x 8 16
3. [D] No. of atoms per unit cell = + =4
∂y 8 2
At location of P, is – and V is along +ve
∂x 4 3 16 3
x-axis. Vol. of 4 atoms = 4 × πr = πr
3 3
So, VP is along +ve x-axis
h
4. [C] λ=
35. [C] Deviation should take place at each face. mv
Dispersion takes place at first face only.
h
5. [A] ∆x. ∆v =
36. [B] 1 atmosphere ≈ 10 Pa 5 4πm
Also, p = hρg 0.011
Here ∆v = 104 ×
= 10 × 1000 × 10 Pa = 105 Pa 100
So, total pressure is nearly 2 × 105 Pa
H 2O2
cis-alkene C2H5
OH
H OH
C2H5
19. [B]
CH2–CH=CH2 NBS
→ CH–CH=CH2
|
Br
[NBS. substitutes bromine at allylic position]
CH2
35. [B]
CH2
H
Ca(OH)2 H H Bridge H ⇒ 2
CH2 B B
H Terminal H ⇒ 4
COOH H
H
Adipic acid
O 36. [B] Order of Lewis Acid BCl3 < AlCl3
||
C–O
Ca 37. [C] Fact
C–O
||
O 38. [D] Brass ⇒ Cu + Zn
non metal ⇒ Cu + Sn + Zn
–CaCO3 dry distillation
German silver ⇒ Cu + Zn + Ni
x2 + y2 = 25 – 16
a tan–1 x + b [log (n – 1) – ln (x + 1)
⇒ x2 + y2 = 9
1 dx dx
9. [B] Eqn of tangent having slope 'm' to ellipse
= 2 ∫
2 x –1
– ∫
x 2 + 1
1 1 x –1 –1
y = mx + a 2m 2 + b 2 = ln – tan x
2 2 x +1
As it touch circle x2 + y2 = r2 then
a2m2 + b2 = r2 + r2m2 Compare
a = –1/2, b = + 1/4
r 2 – b2
⇒m= 1
a2 – r 2 a – 2b = – – 2 (+ 1/4) = – 1
2
O 2 a1 + a4 a +a
24. [C] = 2 3;
2 2 a1a4 a2 a3
A= ∫ 0
y dx = ∫ 0
x dx = 2
1 1 1 1 1 1 1 1
so, + = + or – = –
a4 a1 a3 a2 a4 a3 a2 a1
19. [C] 0<x<1 … (i)
⇒ x > x3 2
3(a2 – a3 ) a1 – a4
Also, = ;
2
2x > 2x
3
a2 a3 a1a4
1 1 1 1 1 1
∫ ∫ So, 3 – =
2 3
2 x dx > 2 x dx ⇒ I1> I2 – … (ii)
0 0 a3 a2 a4 a1
Clearly, (i) and (ii)
20. [D] 1 1 1 1 1 1
⇒ – = – = – ;
a2 a1 a3 a2 a4 a3
1 1 1 1
so, , , , are in A.P. or a1, a2, a3, a4 are
–1 a1 a2 a3 a4
1 in H.P.
25. [D]
One-one function x2 +1 – 2 2
Range = [–1, 1] = co domain f (x) = 2
=1– 2 ;
x +1 x +1
⇓ 2
f (x) is minimum when 2 is maximum or (x2
onto function x +1
+ 1) is minimum
21. [B] x5 – 2y4 = 0 i.e. x2 + 1 ≥ 1 for all x
dy 5 x 4 2
= Hence 2 =2
x + 1 max .
dx 8 y 3
2 2
dy 80 5 or f (x) = 1 – 2 is minimum, when 2 is
=– =– x +1 x +1
dx 2, 2 8×8 4 maximum
y 2 8 or f (x) = 1 – 2 = – 1
length = = =
y1 5/ 4 5
26. [B] As it is a third-degree homogeneous
expression in x, y, we have
22. [B] y3 + y2x – µ yx2 + λ + x3 =(y + x) (y + 3x)(y + mx)
dy dy / dθ a cos θ = y3 + (m + 3 + 1) y2x + (3 + m + 3m) yx2 + 3mx3
= =
dx dx / dθ 1 ⇒ 1 = m + 4, – µ = 3 + 4m, λ = 3m,
a – sin θ +
2 sin θ / 2 cos θ / 2 ⇒m=–3
∴ y – 3x is third factor
2 2 0 –2
–1
2 2 0 – 1/ 2 35. [D] Since, =6 (Q A.M. = 6)
= = 10
– 1/ 2 0
2 2 –2 0 2 2 10
–1 –1 10 ∑x i
=
–1 –1
⇒ ∑
i =1
xi = 60 and i =1
4
= 7.5
4 10
31. [D] Applying R1 → R1 – R2 and R2 → R2 – R3 ⇒ ∑
i =1
xi = 30, ∴ ∑x
i =5
i = 60 – 30 = 30
5 –5 0
f (x) = 0 5 –5 30
⇒ Mean of remaining items = =5
2 2
sin x cos x 5 + 4 sin 2 x 6
7. [B] The third figure in each row comprises of 4. [A] Lively : Correct synonym to 'sprightly' as both
parts which are not common to the first two means, 'someone dashing/energetic/enthusiastic'.
figure. Beautiful : (Irrelevant)
Sportive : (Irrelevant)
8. [A] Intelligent : (Irrelevant)
5. [D] Wicked : It is almost a synonym to 'Astute'
Impolite : Irrelevant because it is the antonym of
9. [C] 'polite'.
Cowardly : Irrelevant as it is the opposite of
'bravely'.
Foolish : (It's the correct antonym of 'Astute'
which itself means 'clever, shrewd'.
10. [A]
6. [D] Deadly : It means 'Fatal'.
Hence, this is not a proper antonym to 'innocuous'.
Ferocious : It means 'horrible'
Hence, irrelevant to the opposite of 'innocuous'.
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Every month get the XtraEdge Advantage at your door step.
✓ Magazine content is prepared by highly experienced faculty members on the latest trend of the IIT JEE.
✓ Predict future paper trends with XtraEdge Test Series every month to give students practice, practice & more practice.
✓ Take advantage of experts' articles on concepts development and problem solving skills
✓ Stay informed about latest exam dates, syllabus, new study techniques, time management skills and much more XtraFunda.
✓ Confidence building exercises with Self Tests and success stories of IITians
✓ Elevate you to the international arena with international Olympiad/ Contests problems and Challenging Questions.
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