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as Resonence Educating for better tomorrow TARGET : JEE (Main + Advanced) 2016 Course : VIKAAS (JA) This DP is to be discussed in the week (13-07-2015 to 18-07-2015) DPP No. # 20 (JEE-MAIN) Total Marks : 76 Max. Time : 48 min. Single choice Objective ('-1" negative marking) Q.1 to 0.20 (3 marks, 2 min.) [60, 40} ChemINFO : 4 Questions ('-1" negative marking) Q.21(a) to @.24(d) (4 marks, 2 min.) —_[16, 08] Gues.vo 17] 2]3] 4] 5] 8|7] 2%] 2] | "| 2] 13] 4) 5] | 17] 16] 19 | 20] Toa Mark obtained 4. Aperson adds 1.71 gram of sugar (C,,H,,0,,) in orderto sweeten his tea, The number of carbon atoms Sol. added are : (Mol. mass of sugar = 342) (A%) 3.6 « 10 (8) 3 102" (C) 3.6 10 (0) 3 « 102 ew et a BY Ar BY FG 1.74 TTF I (CygHy 20, Pre 8 | Pra ay aT GRATIS yee fres 8 : (areas ar aE = 342) (A*) 3.6 = 1072 (8) 3 « 107" (C) 3.6 x 10% (0) 3 « 107 Statement-1 : One mole of C.H, contains tiple number of atoms present in one mole of N.. Statement-2 : Molecular weight of C,H, is same as Molecular weight of N, (A) Statemeni-1 is True, Statement-2 is True; Statement-2is a correct explanation for Statement-t (B*) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False (D) Statement-1 is False, Statement-2 is True AAA YH Atel CH, A Ce Hie NAA sey Re U2: CH, OT a] AR, NO To wT (A) Be ae &, Ber Ter 8-2, wet aT ae TOT 8 (Gt) BoA ea 8, Ba 2 wea, BO! 1 wT we eT ae 8 (C) wer Wea 8, Be-2 9B (0) wer—4 area 8, er-2w BI ‘One mole of any substance corresponds to 6,023 x 10* entities respective of (Mw) Mw of C,H, is (12x2+ 4x1) = 28, 28 gram gmM.W of N, = 28 gram Then MW of C,H, is same as MW of N, fret aro Tw He 6.023 x 10° TAT araRATT C,H, diet H om (12x24 4x 1) = 28, 28 OTF IN, 27574 im Te = 28 51 TCH, 31 ory aN, SATS Determine the de-Broglie wavelength associated with an electron in the 3° Bohr's orbit of He" ion Her oer a 3 ate wen Hi getagiier ener viata & strc rede a ore afore (A)10A (B)2A sa (IA i, = nr => so 2e 9 B * 63 pm)x > =5A ‘Hoar City Mal, Jhalawar Roed, Kola (Raj) 224005 Resonance fara ames 26 toner a6 gusting fr bets to morro | WH vw eeonan oT | Ema = SorieT@rosoaTo Th Sol. Sol. Sol. , : According to Bohr model, the angular momentum of revolving electron is directly proportional to the atomic number of H-ike species bearing the electron. S, :An orbital cannot accomodate more than 2 electrons, 851 Allorbitals have directional character. 8, 29h Hiss & orga, Tor at ay eg on ah a, Se Ha is Sey aia} TTT ten &, for garages after & | 8, 10H Bary H 2) a aio eagles aah ee wae BY Sq: ah ware Reamer gf cad @ (A) ETF (8) TRF (C)FFT (O) TTF aa (2) , :An orbital can only accomodate 2 electrons with opposite spin. 85 S-orbital is non-directional in nature, rst all orbitals are directional S, : Angular momentum = mv Angular momentum peta eter a fi h = (ae > (AE) = 25 = 20 > 6F4. oe: BH Gra A sear Rata A eto = er + 1) = 18. 1 efi ait gtagte] ar apt s=-— eT Which of the following nuclear emission will generate an isotope (A) peemission (B*) neutron emission (C) protonemission _(D) positron emission fre 8 & aera cafett ere eens a Prank (A psa GAR weit Oster wea (0) ag wrets Bx MK 4 bn Resonance fara ames 26 toner a6 ‘Hoar City Mal, Jhalawar Roed, Kola (Raj) 224005 gusting fr bets to morro | WH vw eeonan oT | Ema = SorieT@rosoaTo Th a Fre £0 POD ZS [ DD DE SESE] CO USSSA OOTP TOOEOES Sol. Sol. Sol. 10. Sol. ‘Sum of significant figures which are present in () 0.0025. (i) 5005 and (i) 126,000 ata seam} (0.0025 (i) 5008 aeH (i) 126,000 & fore eke sia ar ate rm] Ay14 9 (©) 12 ©)7 w2 (i4 Gi) 3 sample of CaCO, has Ca = 40%, C = 12% and O = 48% by mass. Ithe law of constant proportions is true, then the mass of Cain 59 of CaCO, obtained from another source will be: (A) 0.29 (B29 (C)0.6g9 (0) Cannot be determined CaCO, UH A H oe a Ca= 40%, C= 12% TIT O= 40% 8) BPE Re orga aT Fram ai 8, at aT atta are §g CaCO, # Cast aR Fr ae (@)029 @)29 (089 (©) sa i Pr oH ra eine Mass of Ca = 5 * oq = 29. c: =5x 0 2 (Cami war)=5 x 55 =2 ‘An organic compound on analysis was found to contain 0.032% of sulphur by mass. The molecular mass of the compound, ifits one molecule contains two sulphur atoms, is fre aren ohana ame ARB FAR O.O2% HL TN Me | A TT CH He, I TR AI vam @, at atte or anita ger fe er (4) 100000 u (8) 10000u (©)20000u (© 200000 u Mass of sulphur ‘Mol mass of compound * 100 = % of sulphur (22) «1008 iy} * 100 = 0.032 M=2,00,000 Wem weal Wie a craw ganar * 100= % Tee : M=2,00,000 Ratio of weight of oxygen in Fe,0, and FeO for the same amount af ron is Fe.0, at FeO, ares ars Hat & Pay stants & aera a sigara sta aE (A322 (B)1:3 (C)2:3 (03:4 In order to have the same amount of Fe the molar ratio of Fe.O, & FeO should be 1:2 So molar ratio of oxygen will be 3 2 Fe #} art Hrar & (Sy Fe,0, ae FeO ay Hex Sigua 1:28 et aifagtiort ar Fra orgarer 3: 280 | le aaa 8 bata = 2 Ho da = 5 _ 3 Fed sta = 5x2=2 Fe oI aR =2*56=112g 112 fren arg Fe ar ster = 17 100 = 80% Resonance fara ames 26 toner a6 Educating for better tomorrow nalawat Road, Kola (Raj) 324005 De FV TOSI 41. Which of the following is not a chemical reaction ? far 8 a ww erate sittin ataeh adh 2? (ac #0, —> Co, (© 2Al+ 3cl, —> 2alcl, (CHO) —> 00 (©) Na(s) + 2H,O() —> NaOH(aq) +H.(0) 42, Copper metal reacts with nitric acid, Assume that the reaction is 3Cu(s) + BHNO,(aq) —> 3Cu(NO,), (aq) + 2NO(G) + 4H,0(0) 1118.75 g Cu(NO), is eventually obtained, then how many grams of nitric oxide, NO, would have also formed according to the preceeding equation (A)29 (B)4.59 (C) 1.4669, (0)3.3g aptae eg sretiea ores fiver ae Ba Fe seo ‘3Cu(s) + 8HNO,(aq) ——> 3Cu(NO), (aq) + 2NO(g) + 4H,0(4) cafe gar fran & Cu(NO,), 3 18.75 gq sre rer ar &, ra ge A ng Eh ore fry a ree sits (NO) fra ay2g 459 (©) 1.4669 (0)339 Sol. 3Cu(s) + 8HNO, (aq) —> 3Cu(NO,), (aq) + 2NO(@) + 4H,0(/) 18.75 Mol of Cu(NO,),* 77 Mole of NO = [Mole of Cu(NO,),] « 02 +. Mass of NO = =x 30= 2g Fa: 3Cu(s)+8HNO, (aq) —> 3Cu(NO,), (aq) + 2NO@) + 4H,0(0) ena 18.75) Cu (NO), a= Fg7g = 0.1 NO® a 02 2. NO a ganar = x 30= 2g 43, Inwhich Clhas +3 oxidation number— fre 4 8 feel Cl apr +3 sifaettarenr sia 8 (A)HCIO (B)HCIO, ()HCIO, ()HCIO, 44, Which of the following is not a redox reaction Farr} gate sarge efara) sen al 8? (A) Mg +N, —> Mg.N, (MnO, +C,07 —+ Mn +0, (©) CuSO, + KI —> 2Cul +1, +K,SO, (0°) AgCl+ NH, —> [Ag(NH,).ICI Sol. Those reaction in which oxidation number of any element do not change not a redox reaction AgCI+NH, —+ [Ag(NH,).JCl 48. Which of the following can not show disproportionation reaction fe 8 ale POvaTga often aE eet Seren (A) ClO- (8) clo- (@cio> (cio; 46. Arsenic estimation can be done by Bettendorff's process. The reaction is given below (A) 2, 12,12 (B) 1,6, 12 (C) 2,3, 24 (0)1,6,6 Beso Bncelemnmn anere a mao St MO a Sa halavae Road, Kola (Raj) 324005 Ais A (Bettendorft's process) eer sieffee wr Frater ran ore & | foe AV A me AS,Q, + SnCl, + HCl —> As, + SnCl,+H,0 orftensiat or wet cerenitoerfAte Terie” (stoichiometric cofficient) wren: wag’ : (eT H FRA TH aH A) (A) 2,12, 12 (B)1,6,12 (C)2,3,24 (1.6.6 Sol. 12" +A5,0, + 12H" —>As, + 6H,O ‘Sn?* —> Snt* + 2e- 12H" + As,O, + 6Sn?* ——> 6Sn** + As, + 6H,O 17, Which ofthe following equations is a balanced one fr @ atereh oof sight &— (A) SBIO, + 22H" + Mn?" > SBi*" + 7H,O + MnO,” (6) 5810, + 14H" + 2Mn?” — 587°" + 7H, + 2Mno,- (©) 2Bi0, + 4H" + Mn* > 2Bi"" + 2H,0+ MnO,” (0) 6BiO, + 12H” + 3Mn** — 6Bi* + 6H, + 3MnO, 18. —_Inthehalf reaction C10, > Cl, aig aiftitpan : C10, —> Cl, (A) 5 electrons are gained (B) S electrons are liberated (C) 10 electrons are gained (0) 10 electrons are liberated (a) SxSagts sem a © Sedacta yaa aa (C*) 10 gdagis nem eit () 10 geragiet yar ei 19. Inthe reaction A+ xe A. xwill be- caffra = Act + xe A A x erm Ant ny )n,-n, Cn, Onn, 20, Match the following List-1 List- 11 For 1 mole of reactant placed in open container in each reaction P 2NH,(g) 2 N,(@) +3H,Q) 1 The ratio of molecules of gaseous products is 1:1 Q PCI, (g) 2, PCI, (g) + Cl, @) 2 11.2 litre gaseous product at STP R 2HBr(g) _*_, H, (@) + Br, (0) 3. mass of one of the product is 3.9 S NH,COONH, (s) 2, 2NH,(@)+CO,(@) 4 67.2 litre gaseous product at STP fre at gata wa ete a woke afifiran & fore ga wa A 1 ste siPtortes we Ten G1 P 2NH,() —_, N,(@) + 3H) 4 tia Gere H anys er arg 11 & Q PCI, (@) 4, PCI, (g) + Cl, @) 2 STP wR 11.2 ates fea sere R 2HBr(g) _*_, H, (g) + Br, (0) 3 feat we sere wR 3g @ S$ NH,COONH, (s) 4, 2NH,(@)+CO,(g) 4 STP 4 67.2 chex Heh Gee Code: (@rs) s 3 1 Today's Quote : “Strength does not come from physical capacity. t comes from an indomitable will” Mahi Gandhi Resonance nalawar Road, Kola (Raj) 324005 Educating for better tomorrow D ChemINFO-1.6 Estimation of Phosphorous| Daily Self-Study Dosage for mastering Chemistry Estimation of Phosphorous [Estimation of Phosphorous First method : A known mass of compound is heated with fuming HNO, which converts phosphorous to HPO, (phosphoric acid). itis precipitated as ammonium phospho molybdate [(NH,), PO, 12 MoO, | by adding NH, and !ammonium molybdate {(NH,), MoO.]. tis fitered, dried, and weighed, Percentage of P= Atomic mass of P ., Mass of ammonium phospho molybdate jo Molecular mass of ammonium phospho molybdate Mass of compound |Second Method : A known mass of compound is heated with funing HNO, which converts phosphorous to H.PO,, Magnesia mixture (MgCl, + NH,Cl) is then added, which gives the precipitate of magnesium ammonium phosphate (MgNH,.PO,) which on heating gives magnesium pyrophosphate (Mg,P.0,). which is weighed. Percentage of P 2x Atomic mass of P____ Mass of Mg2P207 ii ites tc cteaae «100 Molecular mass of Mg2P;07 Mass of compound [Memorize this theory as soon as you get the DP, Revise it regularly and master this concept by practice, 21(a). Inthe quantitative estimation of phosphorous by using magnesia mixture, the formula used is, 62 wx 100 31 W100 (A) Pecentage of P = = (B) Pecentage of P = 222° W 222° w = 62 W100 31 wx100 (C*) Pecentage of P= 4 ()Pecentage of P = 355“ where Wis the mass of Mg,P,O, and w is the mass of the compound 24(b). Inthe quantitative estimation of phosphorous by using ammonium molybdate, the formula used is: (A) Percentage of P = 2, Wx 100 Percentage of p = 62, W100 ter? w 1877 31 wx 100 34 W100 Pe : ) oe (©) Percentage of P = =< ST (0") Percentage of P = 57> where W is the mass of ammonium phospho molybdate and wis the mass of the compound. 21(c). 0.12. gm of an organic compound containing phosphorus gave 0.22 gm of Mg,P,O, by the usual analysis. Calculate the percentage of phosphorous in the compound, (A) 51.20% (©) 722% (©)92.5% (0) 40.2% Sol. _ Percentage of phosphorous 62. Mass of MI2P07_ 4gq _ 62 0.22 = 222 “Mass of compound © ©” = 399“ 9.42 *100 = 51.20% 22(d). 0.62.gm of an organic compound containing phosphorus gave 0.3754 gm of ammonium phospho molybdate by the usual procedure. What is percentage of phosphorous in the compound. (A) 4.20% (B)9.2% (C4)1.0% (0) 10.0% Sol. Percentage of phosphorous 31__ Mass of ammonium phospho molybdate 49 31 0.3754 “4877 © Mass of compound > Fer7* "0.62 «100 = 1.00% nalawat Road, Kola (Raj) 324005 Resonance ducating for better tomarrow & ee one} Mg Dally Sell-Study Dosage for mastering Chemistry BRAN BT YAS STP repre ar Jone Sars i Be fotks va oe sear gears are ar ah dig HNO, er ani ard & oh ateaICIH,PO, 4 fafa A sre | ger NH, err srraH eae [(NH,), MoO] Part ae shes wreaAeBE (NH), PO, 12MoO,) aH sant aver ete & | get aha a ort ae, a ae ea gH ce gH aK AA Shed are wo a OT BI Pa reg ome solfian tee) site agi x 100 Sih Blew sede wi sepa =i erie Par afters = fae FRY: ra ew ora gerart are hPa ah iq HNO, @ ener wri wed B ah wlealeTH,PO, 4 aRala a fe ger are ger} Atma (MgC, + NH,CI) wr Rom fsa cron @1 Fare atone AR om gee (MaNH,.PO,) at sata set dar 8 ot we ae oe Ahram aewLRe (Ma,P,0,) Zen & FORE a A chert & ae ronan at och 8 | 2xP a1 Pa HIRI = Mg P50; 189 [Memorize this theory as soon as you get the DP. Revise it regularly and master this concept by practi 21a), Aehferen fram Maree wieoteT } yore siarer A fer aS a ar ar sett wet 8 62 wx100 31 W100 (AP an after = @ Pa vftera = Fo w<100 idl W= Mg,P,0, a7 are 8 cea Wahine a ae #1 21(b). seis afeese Pore Greer } qurcre steers A Pres 4 8 frst ys ar soe wed 8 62 wx100 62. W100 (a) Pam after = F579 yy (@) Pom after = Feo9 wy 34 wx100 31 Wx100 (0) Pa ART = Feary (0%) Pw after = Feo al W= sailor tel afte wr aR & cen w aire wT aR ey 2A(e), 0.12 9m a TH Ge BRAT Ba arate hr Ta FAT wy 0.22 gm Mg_P,O, fan # Ara A Rey after wets water & 2 (A) 51.20% (8) 722% (©) 925% (0) 40.2% Sol, vfeetea or sifted 62. Mg,P,0, 71 620.22 =x xt00 = £2,022 199 = 222” ais oT ae 7220.12 “100-51 20% 2A(d). 0.62.38 ae arent vem FRI ya orale ae THT FAA areI 0.3754 rH srehfAe FRY AIeBE Se | cafes % fiver? sft testes softer & 2 A) 4.20% ©) 9.2% (©)1.0% (0) 10.0% Sol, pfeptve a7 after 31 vit ote aieeke a1 oe 3103754 a 1077 iPr Te *100 = F577" 99g * 100 = 1.00% Resonance nalawar Road, Kola (Raj) 324005 Educating for better tomorrow D