DPS-MIS, DOHA, QATAR

CLASS XI-CHEMISTRY -HOLIDAY ASSIGNMENT ; DATE OF SUBMISSION:09.08.2018

CHAPTER:2-STRUCTURE OF ATOM

What is meant by Zeeman effect and Stark effect?

Write the electronic configuration of Cu,Cr&Zn

State Aufbau principle.Which of the following is possible?

Explain Hund's rule taking nitrogen as an example

Why are Bohr's orbits called stationary states?

What are emission and absorption spectra?How do they differ?

Out of the following sets ,which are not possible and why?

a.Calculate the wavelength and frequency of a photon emitted when an electron of

hydrogen jump from n=5 to n=2
b.Calculate the ionisation energy required to remove an electron from n=3 of H-atom
a.Explain Heisenberg's uncertainity principle? b.What is the uncertainity in position of
an electron moving with a velocity 600m/s with an accuracy of 0.05%
5
a.What are the informations conveyed by principal and azimuthal quantum numbers?
b.Calculate the angular momentum of an electron in 3p subshell
c.Using s,p,d,f notations describe the following quantum numbers
 CHAPTER:3-CLASSIFICATION OF ELEMENTS

1 MARK QUESTIONS

Q1 - Why electron gain enthalpy of noble gases are positive?

Q2 - Write the formula of compound which might be formed by the pair of aluminium and sulphur.

2 MARK QUESTIONS

Q3- Write the IUPAC name of the following elements with atomic number:
(i) 103 (ii)110
Q4 - Define
(i) van der Waals radius (ii) Metallic radius.
Q5 -Arrange the following species in decreasing order of size. Give reasons also.
O2- , F -, Mg2+, Na+, N 3-

Q6 - Define the term ionisation enthalpy.Name the factors influencing it.

Q7 - Predict the position of elements with atomic numbers 57 and 27 in the periodic table

3 MARK QUESTIONS

Q8 - a.What is periodicity?What is its reason?Explain using an example

b.Give the group number and period of element X(z=59)
Q9 - a.What do you mean by the term"electronegativity"?What are the factors deciding it?
b.Why noble gases have + ve electron gain enthalpy?

5 MARK QUESTION
Q10 - a.Write a short note on blocks in the periodic table.
b.Explain diagonal relationship with its reason.
 CHAPTER:4-CHEMICAL BONDING AND MOLECULAR STRUCTURE

ONE MARK QUESTIONS

1 HF has a higher boiling point than HCl.why?

2 Define resonance
3 Define the term bond length. Arrange the following in the increasing order of
their bond lengths: Ethane, ethene, ethyne

TWO MARKS QUESTIONS

1 Define the term bond angle. Arrange the following in the increasing order of
their bond angle: Water, ammonia, methane, carbon dioxide.

2 Which hybrid orbitals are used by the carbon atoms in the following molecules?

a. CH3-CH=CH2
b. CH3-CH2-OH
c. CH3CHO
d. CH3COOH
3 What do you understand by formal charge of a molecule? Calculate the
formal charge of central atom in the following molecule
HClO4
4 Justify the following
a) Bonds in ozone are equivalent.
b) Acetic acid forms dimer.

THREE
____ MARKS QUESTIONS

1 a.Explain the formation of PCl5 on the basis of hybridization.

-
b.IFind the hybridisation of central atom in a.XeOF3 and I3

2 a.Write the molecular orbital electronic configuration for O-2 and O+2 , Calculate
the bond order & comment on their stabilities.
b.How bond strength is related with bond order?
fF IVE MARKS QUESTION
____

1. a.Explain why
a) Para nitro phenol has higher boiling point than ortho nitro phenol.
b) BF3 is non-polar while NF3 is polar.
c) px orbital does not overlap with py orbital.
b.Calculate the formal charge of N in HNO 3
 CHAPTER:6-THERMODYNAMICS

1 Marks questions

1. What is a thermodynamic state function?

.2 .. For the reaction 2Cl (g) → Cl2(g) , What will be the sign of ΔH and ΔS?

.3 .. State Hess’s Law for constant heat summation?

4. Under what condition, the heat evolved/absorbed in a reaction is

equal to its free energy change?
2 Marks questions

5. Justify the following statements:

(i) An endothermic reaction is always thermodynamically spontaneous.
(ii) The entropy always increases on going from liquid to vapour
state at any temperature T.
6. What is bond energy? Why is it called enthalpy of atomization?
7. What do you understand by state function? Neither q nor w
is a state function but q + w is a state function? Explain.
3 Marks questions

8. a.For the reaction NH4 Cl (s) → NH 3(g) + HCl (g)at 25 0C enthalpy

-
change Δ H = 177KJ.mol-1 andΔS = 285J.K 1 mol -1. Calculate free energy
change ΔG at 25 0 C and predict whether the reaction is spontaneous or
not.
b.How bond enthalpy can be termed as enthalpy of atomisation?
9. a.From the data given below at 298K for the reaction:
CH 4(g)+ 2O 2(g) →CO2(g)+2H 2 O (l) Δ rH = - 890.5KJ, Calculate enthalpy of formation of
CH 4(g) at 298 K. Given enthalpy of formation of CO & H O are393.5 and
2 2
-286 KJ respectively.
b.Enthalpy of formation of graphite is zero while diamond is not zero.Why?

5 Marks question
10.a. Enthalpies of formation of CO(g), CO2(g), N 2 O (g)and N 2 O 4(g)are –110,
–393, 81 and 9.7 KJ mol-1 respectively. Find value ΔrH for the reaction
N2 O 4(g)+ 3CO (g) → N2O + CO2
b.Using Born-Haber cycle , calculate lattice enthalpy of NaCl
 CHAPTER:9-HYDROGEN

ONE MARK QUESTIONS

1 Name a hydride that can act as a) Lewis acid b) Lewis base.

2 How will you show that H2O2 is a powerful oxidizing agent?

3 Explain giving reasons

a. The dihedral angle in H2O2 decreases in the solid state.
b. Ionic hydrides are frequently used to remove traces of water from organic compounds.

TWO MARKS QUESTIONS

1 Complete & balance the following equations

a. CuO(s) + H2 (g) →
b. CO(g) + H2 (g) →
2 Describe the industrial applications of hydrogen dependent on:
a. The heat liberated when its atoms combine on the surface of the metal.
b. Effect on unsaturated organic systems in presence of a catalyst

3 Explain the following reactions with equations

a) Coal gasification b) Water gas shift reaction
4 Describe the permutit process for softening of hard water

THREE MARKS QUESTIONS

1 a.A binary compound of hydrogen is non

- conducting in the solid state. On electrolysis
of the molten compound, hydrogen was liberated at the anode. What class of
compound is this? Give an example. Give equation for its reaction with water.
b.What is hydride gap/?
2 a.Discuss the different types of hydrides with examples
b.What is heavy water?How it can be prepared?
3 What is hard water?What are the types of hardness?Explain its reason
 CHAPTER:8-REDOX REACTION

ONE MARK QUESTIONS

1 Define Redox couple.

2 Name a compound each in which hydrogen exists in i) +1 ii) -1
oxidation states

3 Find the oxidation state of undelined elements

a)Na3 VO4 b) CrO 5 C) H2--

SO5

TWO MARKS
QUESTIONS

1 Define
i) stock notation
i) Standard electrode potential

2 Explain the following by giving example

i) Displacement redox reaction.
ii) Disproportionation reactions

3 Identify the redox reactions and classify them.

a. 2Na + H2 → 2NaH

b. AgNO3 + NaCl → AgCl + NaNO3

c. CaCO3 → CaO + CO2
d. 2HCHO + NaOH → HCOONa + CH3 OH
THREE MARKS QUESTIONS
Balance the following equations:
1)By oxidation number method
1 MnO4 - + C2H2O4 → Mn2++ CO2 [acid]
2)By half reaction method
2 HNO2 + I- → NO + I2 [acid]
3 Fe(OH)2 + H2O2 → Fe(OH)3 + H2O [basic]
4 Dichromate ion in acid medium oxidises stannous to stannic and itself undergo
reduction to give Cr3+and water.Write the equation and identify
oxidant and reductant.