Beruflich Dokumente
Kultur Dokumente
H I GH L IG H T S G R A P H I C A L A B S T R A C T
A R T I C LE I N FO A B S T R A C T
Keywords: (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) with no free radical and non-volatile characteristic can be
Chemically regenerative redox fuel cell utilized as a liquid catalyst instead of O2 at the cathode in a chemical regenerative redox fuel cell with H2 as a
Cathode fuel at the anode. In this study, the electrochemical properties and performance of TEMPO dissolved in sulfuric
TEMPO acid solution are investigated using half and unit cells. In the half-cell, TEMPO shows an activation energy of
Redox reaction
1.27 kcal mol−1 K−1 for the reduction. A chemical regenerative redox fuel cell (CRRFC) using TEMPO as the
liquid catalyst exhibits an open circuit voltage of 0.7 V and a maximum power density of 90 mW cm−2 at 30 °C
with a low activation loss. The regeneration cycling test of the CRRFC is performed at a constant voltage of 0.4 V
under a flow rate of the oxygen-bubbled TEMPO solution. The performance of the CRRFC deteriorates, i.e., a
power density of zero measured at > 200 min. Thus, a highly efficient regeneration system needs to be devel-
oped for a high-performance CRRFC using TEMPO used as a liquid-type oxidant. Furthermore, stable liquid
oxidants with relatively high standard reduction potentials can be proposed through various organic compounds.
∗
Corresponding author.
E-mail address: kwpark@ssu.ac.kr (K.-W. Park).
https://doi.org/10.1016/j.jpowsour.2018.05.009
Received 5 January 2018; Received in revised form 30 April 2018; Accepted 2 May 2018
0378-7753/ © 2018 Elsevier B.V. All rights reserved.
S.-B. Han et al. Journal of Power Sources 393 (2018) 32–36
2. Experimental
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S.-B. Han et al. Journal of Power Sources 393 (2018) 32–36
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S.-B. Han et al. Journal of Power Sources 393 (2018) 32–36
Fig. 6. Polarization curve of the CRRFC measured using TEMPO+ as the oxi-
dant and H2 as the fuel at 30 °C. The humidified H2 and the solution containing
0.3 M TEMPO and 1 M H2SO4 were supplied at the anode and cathode in the
CRRFC, respectively.
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S.-B. Han et al. Journal of Power Sources 393 (2018) 32–36
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