Success Achiever Chmeistry Organic Chemistry PDF

Organic Chemistry UNIT 2
Section - A : Straight Objective Type

1. Answer (1)
Fluorine cannot be detected due to its more electronegativity.
2. Answer (3)
32 WBaSO 4
%S = 233  W × 100
compound
32 6.48
... 18.5 =  × 100
233 W
 W = 4.81 gram
3. Answer (2)
32
%S = × 100  42%
76
4. Answer (2)

O2 + 2C  2CO
5 CO + I2O5  I2 + 5 CO2
5. Answer (1)
Nitrogen is detected by Duma and Kjeldahl method only.
6. Answer (4)
These substances cannot give NH3 gas.
6a. Answer (2) [JEE (Main)-2018]

Kjeldahl method is not applicable for compounds containing nitrogen in nitro, and azo groups and nitrogen
in ring, as N of these compounds does not change to ammonium sulphate under these conditions. Hence
only aniline can be used for estimation of nitrogen by Kjeldahl’s method.
7. Answer (3)
Na2S + Na2 [Fe(CN)5NO]  Na4 [Fe(CN)5 NOS]
8. Answer (3)
HCN and H2S are vapourised.
9. Answer (1)
PbCrO4 absorbs SO2 to form PbSO4.
10. Answer (3)
Boiling point decreases with decrease in vapour pressure.
11. Answer (4)
These are solid polar organic compounds.
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124 Organic Chemistry Success Achiever (Solutions)
12. Answer (2)
12 WCO2
%C =  × 100
44 Wcompound
2 WH2O
%H=  × 100
18 Wcompound
13. Answer (3)

14. Answer (1)
62 WMg2P2O7
%P = 222  W × 100
compound

As per question
Normality Volume
N
H2SO4 60 mL
5
N
NaOH 20 mL
10
(ngeq )H2SO4  (ngeq )NaOH  (ngeq )NH3
1 60 1 20
    (ngeq )NH3
5 1000 10 1000
6 1
  (ngeq )NH3
500 500
5 1
(ngeq )NH3  
500 100
1
(nmol )N  (nmol )NH3  (ngeq )NH3 
100
14
(Mass)N   0.14 g
100
0.14
Percentage of "N"   100 = 10%
1.4
14b. Answer (1) [JEE (Main)-2015]

Percentage of Br
Weight of AgBr Mol. mass of Br

= × × 100
Mol. mass of AgBr Weight of O.C.
141 80
= × × 100 = 24%
188 250
Success Achiever (Solutions) Organic Chemistry 125
15. Answer (1)
⎡ ⎤
⎢ Mass of Platinichloride  195 – 410 ⎥
⎢ Mass of platinum ⎥
Molar mass of base = ⎢ 2
⎥ × basicity
⎢⎣ ⎥⎦
16. Answer (2)
⎡ weight of silver salt ⎤ ⎡ 1 ⎤

Equivalent weight of acid = ⎢  108 – 107⎥ = ⎢  108 – 107 ⎥ = 45
⎣ weight of silver ⎦ ⎣ 0 .7 ⎦
Molar mass 90
basicity = = =2
Equivalent mass 45
17. Answer (4)
Duma’s method can be used in all nitrogen containing compounds.
18. Answer (1)
It can combine with all Cl, Br, I, P, S, N elements due to high reactivity.
19. Answer (4)
Information based.
20. Answer (4)
All can be converted to vapour state directly from solid state.
21. Answer (1)
Cryoscopic and ebullioscopic methods are for non-volatile solutes.
22. Answer (4)
Fe 2 (SO 4 )
NaOH
FeSO 4 ⎯⎯⎯→ Fe (OH)2 ⎯⎯⎯
NaCN
→ Na 4 ⎡⎢Fe (CN)6 ⎤⎥ ⎯⎯⎯⎯⎯ 3
→ Fe 4 ⎡⎢Fe (CN)6 ⎤⎥
⎣ ⎦ ⎣ ⎦3
green blue
23. Answer (1)
(NH ) MoO
P ⎯⎯
→ Na 3PO 4 ⎯⎯ 4 2
→ H3PO 4 ⎯⎯⎯⎯⎯→
HNO
4
(NH4 )3 PO 4 .12MoO3
3
24. Answer (4)

H S
Cd(OAc)2 ⎯⎯⎯
2
→ CdS 
(yellow ppt.)
25. Answer (2)
1 ⎡ mass of Pt salt ⎤
E= ⎢ ×195 − 410⎥
2 ⎢⎣ mass of Pt ⎥⎦
26. Answer (3)

⎛ 0.76 ⎞
Equivalent weight of acid = ⎜⎜⎝⎜ ×108⎟⎟⎟ − 107 = 45
0.54 ⎠
Molar mass of ester = (2 × 45) – 1 + 29 = 118
27. Answer (2)
2º 2º
4º
3º
2º 1º
28. Answer (3)
1 1
2 | 1
29. Answer (3)

It is aromatic
30. Answer (1)
It is aromatic
30a. Answer (2) (AIEEE 2009)
CCl3 > C6H5 CH2 > (CH3)2 CH > (CH3)3 C
31. Answer (3)

(1, 1) (1, 2) (1, 3) (1, 4) (1, 5) (2, 2) (2, 3) (2, 4) (3, 3) dihaloderivatives are possible.
32. Answer (1)
 
CH3  O  C H2  CH3  O  CH2
33. Answer (2)
Maximum electron density containing nitrogen.
34. Answer (3)
n-nonane > n-octane > n-heptane > n-hexane.
35. Answer (4)
Just attached elements contain lone pair of electrons.
36. Answer (3)
All given groups show +R effect.
37. Answer (4)
–
OH is weaker nucleophile than NH2–.
38. Answer (3)
More will be negative charge on less electronegative carbon atom, more will be basic character.
39. Answer (4)
There are only functional isomers.

H H
O S
Cl CN
(a) (b) (c) (d)

O H S H
Cl CN
=0 =0 0 0
40. Answer (2)
It contains 10 electrons.
41. Answer (3)
+ is formed as a most stable carbocation.

CH – CH2
42. Answer (2)

R – H + x•  R• + HX
43. Answer (3)
Butanone cannot form any other type of Ketone.
44. Answer (1)
Both have different carbon chain length.
45. Answer (2)
It can form most stable conjugate base.
46. Answer (2)
It forms most stable carbocation.
47. Answer (1)
In forms most stable carbocation.
48. Answer (3)
Property of SN1 mechanism.
49. Answer (2)
+
CH2
|
is most stable carbocation.
50. Answer (1)

It is antiaromatic

However, all molecules given in options are stabilised by resonance but compound given in option (2) is
least resonance stabilised (other three are aromatic)
O O–
51. Answer (1)

It is antielimination.
52. Answer (1)
Antielimination is not possible.
53. Answer (1)
Benzene is more reactive than iodobenzene towards SE reaction.
54. Answer (1)
Rate determining step is removal of H, D or T.
55. Answer (4)
Factual.
56. Answer (2)

Due to resonance, Cl is partially double bonded.
57. Answer (3)
•
CH3 – C – CH3
|
It can form most stable radical
58. Answer (4)

Numbering will be started from –COOH. It is (2S, 3E) configuration
59. Answer (3)
* O
*
*
*
60. Answer (4)
In hetero cyclic aromatic compounds at least one atom of ring is different.
61. Answer (3)
Initially left ring is less reactive towards nitration due to –R effect but after first nitration on other ring it becomes
more reactive.
62. Answer (3)
After removal of 3rd H, it becomes aromatic
63. Answer (2)
CH3 CH3
| + (CH3 shifting) |
CH3 – C – CH2 CH3 – C – CH2 – CH3
| +
CH3
64. Answer (4)
Fullurenes are allotrope of carbon.
65. Answer (4)
NO2 has strongest electron withdrawing ability.
66. Answer (3)
Due to the presence of vacant d-orbital of appropriate energy in Si atom, it behaves as electron withdrawing
group through mesomerism.
67. Answer (3)
Because charge separated structure is most contributing where negative charge in five-membered ring and
positive charge in seven-membered ring.
68. Answer (2)
In III, aromatic ring is present, hence it has lowest enthalpy of combustion.
69. Answer (2)
70. Answer (2)
(2) is resonance stabilized where delocalization of positive charge is maximum due to resonance.
71. Answer (2)
Planar six-membered ring formation.
72. Answer (1)
Charge separated resonating structure has negligible contribution towards resonance hybrid in option (1).
73. Answer (4)
Structure (4) has maximum number of covalent bonds.
74. Answer (2)
Conjugate base is not stabilized by resonance.
H
O O O O
–H
Unstable
75. Answer (2)

Bond between sp3 – sp3 hybridised carbons
76. Answer (1)
It has sp3 hybridised carbon (25% S charater)
77. Answer (2)
In both SN1 and SN2 mechanism reactivity order of haloacids is same.

Formation of carbocation is rate determining step in SN1 reaction. Hence alkyl halide which gives more
stable carbocation is more reactive towards SN1 reaction
Me Me
> Me > Me Br
Br Br
decreasing order of SN1 reactivity
78. Answer (2)

Adsorption extent of ethyne on surface of catalyst is maximum.
79. Answer (3)
Due to rearrangement, conjugated diene is formed.
NBS/h
More stable
Br –H
O
NBS H2O/K2CO3
80. Answer (4)

It is S type optical isomer.
81. Answer (2)
I and II carbon atoms are of R and S configurations and it is symmetrical molecule.
CO2H
1
H OH
2
H Cl
CH3
At (1),
3 1
4 1 2 3
2 4
It is 'S' configurated.
At (2),
2 1
4 1 3 2
3 4
It is 'R' configurated.
82. Answer (4)

Acetaldehydeoxime shows and syn-anti isomerism.
83. Answer (1)
2n number of stereomers = 22 = 4
84. Answer (3)
H
CH3
CH3—C*—CH = C
H
C2H5
Two enantiomeric pairs for each cis and trans. So the combination gives 4-diastereomeric pairs.
85. Answer (4)
CH3
CH3
KOH
C2H5—C—Cl HO—C—C2H5
DMF
SN2 H
H
Inversion of
configuration
86. Answer (3)
87. Answer (2)
–
OH
CH3 CH3 CH3 CH3

aq. KOH
H5C2—C—Cl C Cl – C2H5—C—OH + HO—C—C2H5
SN1
C3H7 C2H5 C3H7 C3H7 C3H7
(A) (B)
The concentration of B > A
88. Answer (3)
Pairs are not enantiomers
89. Answer (2)
The similar groups are on the same side in the fischer projection formula.
90. Answer (1)
Number of double bond are 3 and the polyene contains different groups at the terminals. So geometrical isomer
= 23 = 8
91. Answer (4)
92. Answer (1)
Br
H
Cl (1, 2) axial-equatorial is cis in nature
H
93. Answer (3)
94. Answer (3)
95. Answer (2)
–NH – CH3 is maximum electron donating group among all given groups.
96. Answer (2)
(CH3)3COK is a bulky base and it gives Hoffmann elimination.
97. Answer (3)
Both have 6 valance electrons.
98. Answer (1)
D
CH3 C C2H5
H Chiral centre
Since it has chiral centre therefore it will show optical isomerism.
99. Answer (4)
¨
C2H5
+
MgBr + H O R C2H5 H + R O MgX
Conjugate Conjugate
acid of base of ROH
CH3 CH2
¨
Protonolysis due to proton transfer.
100. Answer (3)

Even number of carbon containing hydrocarbon has higher melting point.
101. Answer (1)
CH3 CH3 CH3 CH3

Pd / 
+ CH3 C C CH3 + CH3 CH CH CH3
102. Answer (2)

TPH  [Ph3SnH], TPH can reduce 1°, 2° and 3° RX while NaBH4 can reduce 2° and 3° RX only.
While Red–P and Zn–Hg/HCl can’t reduce alkyl chloride.
103. Answer (3)
Wolf Kishner reduction is used for the preparation of alkane by using hydrazine (NH2—NH2) + sodium alkoxide.
104. Answer (1)
 2Na + 2H2O  2NaOH + H2
RX – Soluble in ether, insoluble in water.
105. Answer (4)
Ether
CH3 Cl +2Na + C2H5 Cl CH3 CH3 + CH2 CH2
CH3 C2H5
C2H5 C2H5
106. Answer (3)

3° – Alkyl halide preferred dehydrohalogenation and form alkene.
107. Answer (4)
At anode
¨O
¨
2CH3COO 2e 2CH3 C
O
CH3 C O CH3 + CO2
(Free radical)
CH3 + CH3 C2H6 (Alkane)

108. Answer (1)
109. Answer (1)

1º-Alcohol follow E2 mechanism while 2° and 3°-alcohol follow E1 mechanism.

H H
OH CH3 O
CH3
H
CH2–CH–CH CH2–CH–CH
CH3 CH3
CH3
CH—CH– C
H (A) (B) H CH3
CH3
(A)
CH = CH–CH
CH3
Extension of conjugation
(More stable)
 Major product
CH3
(B)
CH2–CH = C
(Minor) CH3
110. Answer (2)

Due to intra molecular hydrogen bonding gauche is more stable in glycol.
111. Answer (3)
Birch reduction
Na/liq. NH3 CH3 H

CH3 – C  C – CH3 C=C
H CH3
Trans alkene
So, option (3) is correct.
112. Answer (3)

On increase in surface area of alkene boiling point increases and cis form is more polar hence cis-3-Hexene
has highest boiling point.
113. Answer (3)
CH3 CH CH3 CH CH2 Cl
OH
OH–  Nucleophile
Cl+  Electrophile
114. Answer (3)
H H
–
1% KMnO4/OH
Cold
OH OH
115. Answer (3)
4 1 3
3 2 2 1
Right way Wrong way
of numbering of numbering
116. Answer (1)
OsO4 is used to perform cis-dihydroxylation reaction on alkene.
117. Answer (2)
H3C
C = CH – CH3
H3C
Saytzev's product
118. Answer (4)
Br
Anti-Markonikoff's addition
(Peroxide effect)
119. Answer (2)

Hg2+, H3O+
H–CC–H H2C = CH
O
H
Tautomerization
O
H3C – C – H
120. Answer (3)
Fact.
121. Answer (2)
Most substituted alkene will have lowest molar heat of hydrogenation.
122. Answer (4)
Oxidation produces diols.
123. Answer (3)
Br
Br2
Br
124. Answer (1)
h
Initiation : R – O – O – R R – O
Propagation :
R – O + H – Br R – OH + Br
125. Answer (4)
Presence of electron withdrawing group in -complex increases potential energy of the system.
126. Answer (4)
Five double bonds, one triple bond and cyclopropyl ring will absorb H2 at higher temperature.
127. Answer (2)
H
CH3 CH CH3 CH2 CH2 B
(Electrophile) H
128. Answer (4)
HgSO4
CH CH CH3 CHO
H2SO4
LiAlH4
CH3 CH2 OH
129. Answer (2)
(i) B2H6 CHO
CH CH
(ii) H2O2/NaOH CHO
The alkynes which has terminal hydrogen always gives aldehyde. While non-terminal alkynes gives ketone.
130. Answer (2)
(i) O3 CHO
CH2 CH CH CH CH CH2 2HCHO + 2
(ii) Zn/H2O CHO
131. Answer (1)
No. of geomaterical isomer is = 2n where n = No. of double bond. When both end are non identical.
132. Answer (3)

CH2 CH2
OsO4 O O NaHSO3 CH2 CH2
CH2 CH2
Os OH OH
O O
133. Answer (4)
O
NaNH 2 Hg 2 hv (1) NaIO
CH3  CBr2  CH3   CH3  C  CH   CH3 – C – CH3 H2O/H
+ CH3COOH
134. Answer (2)
O OH ONa
Tautomerism NaNH2
CH3 C CH3 CH3 C CH2 C CH2
CH3
(A)
Addn CH CH
ONa
CH3 C CH3
C CH
(B)
135. Answer (1)
Ether
CH C CH 2Br + Mg CH C CH2MgBr
(A) (B)
Since compound B has acidic (terminal) H, hence it reacts further with (A) and forming propyne
CH C CH2 MgBr + CH C CH2Br CH C CH3 + BrMgC C CH2Br
136. Answer (4)

C2H6, CH2 = CH2, CH CH
sp3(25%) sp2(33.33%) sp(50%)
Greater the s.character more will be bond dissociation energy (C – H)
137. Answer (1)
Greater the number of terminal hydrogen more will be acidic character.
138. Answer (3)
A pair of electron is easily available for protonation.

Θ
R  COO  HC  CΘ  NH2  R

increasing basic strength
As sp3 C is less electronegative than sp3 N alkyl carbanion  R  is more basic than NH2 . However
Θ
Θ Θ
sp hybridized carbon is more electronegative than sp3 N. Hence NH2 is more basic than HC  C
139. Answer (3)

R C C H + R' MgBr R C C MgBr + R'H
This reaction of terminal alkynes with Grignard reagent is extremely rapid and goes to completion and example
of transmetallation.
Transmetallation  A reaction in which a metal is transferred from one carbon to another.
140. Answer (3)
KMnO4 hydroxylate C C bond and C C bond.
141. Answer (2)
hot Fe
3CH CH Tube
Benzene
142. Answer (3)
Na/C2H5OH CH3 H
CH3 C C CH3 C C
H CH3
D2/Pt
H D
CH3 C C CH3
D H
(Recemic mixture)
143. Answer (1)
(2  carbon  2)  hydrogen
Degree of unsaturation =
2
(2  7  2)  12
 D.U. 
2
D.U. = 2
144. Answer (4)
C2H5
AlCl3/HCl
+ CH2 CH2
368 K
145. Answer (4)

All of these are example of stereospecific reaction only particular isomer is formed.
146. Answer (1)
Nucelophilic substitution is not possible in benzene nucleus under ordinary condition, but under high
temperature and pressure SN reaction is made possible.
147. Answer (1)
Cl Cl
CH3 H CH3 CH3
+
¨NH ¨ + Cl
–
¨
Benzyne
148. Answer (1)
Due to more prominent +R effect of F .
149. Answer (2)
CH3 CH3
Cl

CH3 CH3 CH3 CH3

resonance
stable
carbocation
 It will be faster towards SN1 mechanism
150. Answer (1)
It is aromatic because it is planner, conjugated and contains 6 electrons.
151. Answer (4)
In –NH2 lone pair of electron is easily available for delocalisation because it is planar and –NR2 is non–plannar
152. Answer (2)
It is example of anti-elimination
153. Answer (4)
O O O
|| || ||
Reductive ozonolysis of all can form H− C − C − C − H

5-keto-2-methylhexanal is
O O
O3 Zn
O O
+
H
H
154. Answer (3)

Cl
CH2Cl
Cl2
Cl
155. Answer (4)
+
CH2 CH3
+
is more stable, is aromatic
156. Answer (1)
There is no H-atom at anti-position.
157. Answer (3)
Natural polymer is degradable.
158. Answer (4)
SO3 is not primary pollutant.
159. Answer (1)
Exosphere is the uppermost region of atmosphere.
160. Answer (1)
Statosphere.
161. Answer (2)
Fact.
162. Answer (1)
BOD5 means dissolved oxygen consumed in 5 days.
163. Answer (1)
Ozone layer is destroyed by chlorofloro carbon.
164. Answer (1)
Los Angels smog is photochemical smog.
165. Answer (4)
MIC gas released in Bhopal gas tragedy.
166. Answer (4)
Due to very decrease in temperature.
167. Answer (2)
Due to hole in ozone layer, U.V. rays reaches on earth which cause skin cancer.
168. Answer (4)
CO is primary pollutant.
169. Answer (3)
PAN is a secondary pollutant.
170. Answer (2)
Chlorination of water is done to kill germ.

F– ions make the teeth enamel harder by converting
[3Ca3 (PO4 )2 .Ca(OH)2 ] to [3Ca3 (PO4 )2 .CaF2 ]
Hydroxyapatite Fluorapatite
171. Answer (1)

Fact.
172. Answer (4)
NO2.
173. Answer (1)
N2 is not an air pollutant.
174. Answer (3)
SO3 is not dissociated in smog formation
175. Answer (4)
Seconal is tranquilliger

Phenelzine is not antacid, it is anti-depressant.
176. Answer (3)

Reaction of alcohol with SOCl2 in presence of dry ether is an example of SNi. In this reaction retention of
structure take place.
177. Answer (1)
Br
OH
H SO NBS
2 
4
 
170 C
CH3 CH3 CH3
178. Answer (1)
Nucleophilic substitution by SN2 mechanism on a stereogenic centre give only one product that may be
dextrorotatory or leveorotatory.
179. Answer (1)
Et 2O
Br CH2—CH2—CH2—Br + Mg  
180. Answer (3)
Covalent character in AgCN due to high polarising power of Ag+ due to its Pseudo noble electronic configuration
so C of CN– is not allowed to attack and hence N of CN– act as nucleophile.
181. Answer (2)
Alkyl fluoride always give alkene that is less substituted which is governed by Hoffman rule.
182. Answer (1)
Function of Red P is to remove I2 as PI3 otherwise I2 react again with C2H6 to form C2H5I.
183. Answer (4)
Stronger base favour elimination while weaker base favour substitution.
The order of basic strength is
R—O– > OH– > C6H5O– > CH3—COO–
184. Answer (4)
Better will be leaving group faster will be rate of reaction.
Leaving group is in order I > Br > Cl > F.
185. Answer (1)
 – 
CH3—CH CH—COOH + HBr CH3—CH—CH2—COOH
Br
CH3—CH—CH2—COOH
Br

NO2 in a strong electron withdrawing so, CH3 — CH2 — C H— NO 2 is highly unstable.

CH3 CH3
HBr
CH3 – CH = C – CH2 – CH3 R2O2 CH3 – *CH –*C – CH2 – CH3
3-methyl pent-2-ene
Br H
Product (X)
Since product (X) contains two chiral centres and it is unsymmetrical.
So, its total stereoisomers = 22 = 4.
186. Answer (1)
—CH—CH3 HBr —CH—CH3

| |
OH 
O—H
|
H
CH3
* —CH—CH3
 ring 
expansion
CH3
Br *
187. Answer (4)

At high temperature, Cl show allylic substitution.
188. Answer (2)
(i) CaOCl2 + H2O  Ca(OH)2 + Cl2 – Hydrolysis
(ii) CH3CH2OH + Cl2  CH3CHO + 2HCL – Oxidation
(iii) CH3CHO + 3Cl2  CCl3CHO + 3HCl – Halogenation
(iv) 2CCl3CHO + Ca(OH)2  2CHCl3 + (HCOO)2Ca – Alkaline hydrolysis
189. Answer (4)
Wiliamson synthesis is a nucleophilic substitution and R'—O– act as nucleophile.
190. Answer (4)
– CH3

C2H5—O H H H CH3
– E2
C2H5O + CH3CHBrCH3 C C C=C + C2H5OH

H Br H H


H –

NaI gives nucleophilic substitution
Br NaI I
191. Answer (2)

CH3O– is a strong base and strong nucleophile, so favourable condition is SN2/E2.
Given alkyl halide is 2° and C's are 4° and 2°, so sufficiently hindered, therefore, E2 dominates over
SN2.
Also, polarity of CH3OH (solvent) is not as high as H2O, so E1 is also dominated by E2.
4°
 Br
 CH3O–
E2
 H
(Major product)
(2°)
192. Answer (1)

Fact.
193. Answer (3)
194. Answer (3)

Br Br
CH3  CH3 Br CH3 Br
 SN2
CH—OH + P—Br CH—O—P CH—Br + HO—P
CH3 Br CH3 Br CH3 Br
H
195. Answer (1)
–
Br H
CH3—CH2—C—CH3
O
O=S=O
H O Br
SN2
CH3CH2—C—OH + Cl—S CH3 CH3—CH2—C—CH3
–(OTs–)
CH3 O H
CH3
196. Answer (3)

Ethylene
LiAlH4
CH3COOH CH3CH2OH 'A'
PCl5
CH3CH2Cl 'B'
Alc. KOH
CH2 = CH2 'C'
197. Answer (4)

1 2 3 4 5
CH3—CH—CH2—CH—CH3
5 4 3 2 1
CH3 CH3
Only three different position available
198. Answer (2)
Here the order of base strength is also the order of rate.
199. Answer (1)
200. Answer (3)
OD
– –
DCCl2–CF3 CCl2—CF2 CCl2 = CF2
D2O –F–
–
OH/HOH F
–
CCl2—CF3
HOH
HCCl2—CF3
201. Answer (1)

CH3 O is a strong base and good nucleophile and the substrate is 1° alkyl halide so SN2
202. Answer (4)
More stable will be carbocation, higher will be chance to show SN1 reaction.

Rate of SN1 reaction  stability of carbocation
I. CH3 – CH – CH2 – CH3 CH3 – CH – CH2 – CH3
Cl
II. CH3 – CH2 – CH2 – Cl CH3 – CH2 – CH2
CH2 – Cl CH2
III.
OCH3 OCH3
So, II < I < III
Increase stability of carbocation and hence increase reactivity of halides.
203. Answer (2)

204. Answer (4)
This is Ullmann reaction.
205. Answer (2)
O OH
|| |
To give iodoform test, compound should have either CH3 — C — or CH3 — CH— as general formula.
206. Answer (2)
Benzyne is the intermediate of this reaction
207. Answer (3)
More will NO2 group more stable will be intermediate and easy will be aromatic substitution.
208. Answer (4)
All form azodyes.
209. Answer (1)
This is Sand Mayer reaction.
210. Answer (1)
Fact.
211. Answer (3)
CH3
CH3
Cl
CH3
+ – CH3
Na O C CH3
O O O C CH3
CH3
Br CH3
(Product)
The above product does not have any C = C or C  C bond, so, it will not give Br2-water test.
211b. Answer (4) [JEE (Main)-2017]

Br
H t-BuOK
C6H5 C6H5

C6H5 (E-2) C6H5
(+)
212. Answer (4)

213. Answer (1)
Cl
214. Answer (3)

Benzene is more reactive than chlorobenzene.
NH2 NH3 NH3 NH3 NH3

NO2
H+ NO2
+ +
NO2
(51%) (2%)
NO2
(47%)
215. Answer (4)

Br– is weaker nucleophile than I–.
216. Answer (1)

Cl
Cl Cl
Cl Cl
Cl
Cl
Cl Cl
Cl2/Fe
Cl Cl
Cl
217. Answer (2)
CH3 CH3
CH3 |
| |
CH—C—CH Re arrangemen t
3       CH — C—CH—CH
CH2 CH—C—CH3 + H2O —— CH3— 3
| |
3
| | |
CH3 OH CH3 OH CH3
(more stable)
218. Answer (1)
ONa OH
OH
COOH
4 – 7 atm
COONa
 CO2   
H / H2 O
125C  
Salicylic acid
O O
O H
–
—C—O
+C O
(E)

OH OH
COOH
CO2
NaOH
Salicylic acid
219. Answer (2)
RNH2  HONO  ROH  N2  H2O

–
2HNO2—— N O  H2 O NO 2
(Electrophi le )
220. Answer (1)

( CH COO ) Hg / H O NaBH
CH3 — CH  CH2  
3
2

2
 CH3 — CH— CH2  

4
 CH3 — CH— CH3
THF | | OH |
OH HgOOCCH OH
( 2  Alcohol) 3
221. Answer (2)
222. Answer (1)
(i) O
CH3 — CH — CH  CH — CH3   3
 CH3 — CH — CHO  CH3 CHO
| (ii)Zn / H2O |
Oxidation
CH3 CH3
CH3 CH — COOH  CH3 COOH

|
CH
3

(i) O3
CH3 CH CH CH3 CH3 CHO
(ii) Zn-H2O
44 amu
223. Answer (1)
HOCl  OH  Cl 

(Nu )
– – +1
CH 3—CH CH 2 + OH CH3—CH—CH2 + Cl
|
OH
 CH3 — CH— CH2Cl
|
OH
224. Answer (2)
Cl –
623 K OH
300 atm
H Benzyne
OH
(Intermediate)
225. Answer (1)
OH OH
OK
CHO
CHO
343 K
 KOH  CHCl3    
dil HCl
(major)
226. Answer (4)
O
||
The compound which has CH3 — C — or CH3 — CH— group gives iodoform test.
|
OH
227. Answer (1)
O—CH2—CH CH2 CH2 CH—CH2

OH
475 K
228. Answer (2)

Due to sp2 hybridisation of bonded carbon atoms.
229. Answer (4)
Conc . H2SO 4 Br excess of Alc KOH
C 3H7 OH    CH3 — CH  CH2 
2
 CH3 — CH — CH2      CH3 — C  CH
160  180 C | | ( Alkene)
OH OH (Z )
230. Answer (4)

For the preparation of Di-tertiarybutylether, tert-butylether is required which undergoes elimination reaction and
form alkene.
231. Answer (1)
CH3 — O — CH(CH3 )2  HI  CH3I  CH3 — CH — OH
|
CH3
( 2  Alcohol & more stable )
O HI I
Heat
+ I
O OH
+
OH
Hence, option (4) is correct.
232. Answer (3)

In phenol, phenoxide ion is resonance stable compound.
233. Answer (4)
Due to + R effect of benzene, C6H5COOH is less acidic than HCOOH.
234. Answer (2)
It is an example of SNi mechanism in which 100% retention takes place.
235. Answer (3)
In Claisen rearrangement, if ortho positions are blocked, allyl group migration para position with same carbon.
236. Answer (4)
It forms most resonance stabilised aromatic carbocation.
237. Answer (2)
CH3 O O
|
Cu
CH3 O3
||
NaNH2
||
CH3 − C − OH ⎯⎯⎯
573K
→ CH2 = C ⎯⎯⎯⎯
Zn−H2O
→ HCHO + CH3 − C − CH3 ⎯⎯⎯⎯
→ CH3 − C− CH2Na
|
CH3 (C) (B)
CH3
238. Answer (1)
First ester (A) will form ketone which will further reacts with grignard reagent and form 3°–Alcohol which reacts
faster with Lucas reagent.
239. Answer (1)
O
|
HCOOC2H5 + CH3MgBr —— H—C—O—C2H5
|
CH3
O OMgBr OH
|| | 
|
H / H O
H — C — CH3  C 2H5 OMgBr     CH3—C—CH3  2 CH3 — CH— CH3
CH3MgBr
Acetaldehy de | 2 propanol
H
240. Answer (3)
This method is used for the preparation of aldehyde (expect formaldehyde) only.
241. Answer (4)
Fact.
242. Answer (1)
243. Answer (3)
3º allyl radical is formed
244. Answer (3)
OH
is formed
OH
245. Answer (1)
246. Answer (1)

O
is formed by H2SO4
O
247. Answer (2)
OH OCOONa OH OH
COONa +
COOH
(i) NaOH H
(ii) CO2
248. Answer (1)

Attack of BH3 fellows Markovnikov’s addition.
249. Answer (1)
3º cation is formed.
250. Answer (2)
It gives alkene
251. Answer (2)
HO CH COONa
HO CH COOK
252. Answer (4)
Both give same test
252a. Answer (2, 4) (AIEEE 2011)

Both formaldehyde and acetaldehyde will give this test

[ Ag(NH3 )2 ]
HCHO   Ag   Organic compound
Silver mirror

[ Ag(NH3 )2 ]
CH3 – CHO   Ag   Organic Compound
Silver mirror
253. Answer (1)

By using strong oxidising such as conc. HNO3, ketones gives carboxylic acids
254. Answer (2)
255. Answer (2)
CuO (Cupric oxide) (blue colour) of Fehling solution converted into cuprous oxide (red colour) on the the
reaction with aldehyde.
256. Answer (2)
O OH
|| |
H
CH3 — C  HCN 
 CH3 — C — CH3
| |
CH3 CN
Cyanohydrine
257. Answer (1)

O
|
In Cannizzaro’s reaction due to transfer of hydride ion D — C — OH (Alcohol) is formed.
|
D
258. Answer (3)
Only ‘C’ has - carbon
259. Answer (4)
All of these do not have  hydrogen

Cl Cl Cl
NaOH
Cl–C–CHO Cl–C–COONa + Cl–C–CH2–OH
Cannizaros reaction
2 1
Cl Cl Cl
2, 2, 2-trichloroethanol
260. Answer (1)

(i) CO2
Br
CH3MgBr 
  CH3 COOH  Mg
(ii) H /H2O
Acetic acid OH
261. Answer (4)
This is laboratory method of preparation of formic acid.
262. Answer (2)
COOH
CH2 O C C C O
COOH
263. Answer (3)
(A) is carboxylic acid and (B) is anhydride
264. Answer (3)
It is Schimdt reaction
265. Answer (4)
C2H5 C2H5
CH3 CH3
and cannot give HCHO
266. Answer (1)

LiAlH4 can be kept in alcohol due to its greater reducing power.
267. Answer (4)
Five membered product is more stable then seven membered.
268. Answer (2)
HI/P
HO COOH
CH3
269. Answer (2)
According to alphabetic order
270. Answer (4)
All can form benzaldehyde
271. Answer (1)
O
CH3 CH3
C CH C CH C
CH3 CH3
272. Answer (3)
– NO2 is EWG and – OCH3 is ERG.
273. Answer (4)
— CHO is deactivating group and –OH and –NH2 have acidic H
274. Answer (3)
Cl OH
I I
H O
CH3 — C — Cl  (aq) NaOH  CH3 — C — OH 2 CH3 COOH
| | ( Carboxylic acid)
Cl OH
( unstable )
275. Answer (3)

Due to greater acidic character.
276. Answer (4)
Conc. H SO
HCOOH   
2

4
 CO  H2O

277. Answer (4)

Tollen’s reagent gives silver mirror with formic acid.
278. Answer (2)

Due to greater +I-effect

O
CH3—CH2—CH—C—OH
Cl
Presence of electron withdrawing group nearest to the carboxylic group increase the acidic strength to
maximum extent.
279. Answer (2)

The value of van’t Hoff factor (i) can be determined on dimerisation of benzoic acid and ‘i’ gives information
about molecular mass.
280. Answer (3)
Sequence of acetic strength = II > III > I.
So pKa sequence will be opposite.
281. Answer (1)
It is Wittig reaction
282. Answer (2)
It is aldol condensation reaction.
283. Answer (2)
CH3 COCl  (CH3 )2 Cd  CH3 — COCH3  CdCl2
284. Answer (1)

The carbonyl carbon of HCHO has greater positive charge.
285. Answer (2)
2 
Hg / H LiAlH P / Br
CH  CH    CH3 CHO  
4
 CH3 — CH2 — OH  
2
 CH3 — CH2 — Br
H2O (A) (B ) (C)

CHCl /KOH
R – CH2 – NH2 
3
C2H5OH R– CH2 – NC
286. Answer (1)

This is iodoform test
287. Answer (1)
Fact
288. Answer (3)
Phenyl ethanal does not have –CHO group directly attached to phenyl group, therefore it is not a aromatic
aldehyde.
289. Answer (4)
COONa COOH
633 K HCl
Na  CO 2    + NaCl
COONa COOH
290. Answer (1)
CN HCl COOH
| + H2O |
CN COOH
(A) cyanogen
291. Answer (1)

O
||
CH2—CH2—COOH 573 K
+H2O + CO2
CH2—CH2—COOH (CH3CO)2O
Adipic acid (A)
292. Answer (1)

CHCOOH KMnO4 CH(OH)COOH
|| |
CHCOOH CH(OH)COOH
293. Answer (1)
H
|
C12H22O11  H2O  CH3 — C — COOH
Lactose |
OH
Lactic acid
294. Answer (2)

NaNO / HCl
RCONH2  2  RCOOH
295. Answer (4)
O N—OH NH2
NH2OH LiAlH HNO
   
4
  
2
 —CH2OH
296. Answer (3)
O O O
|| || || . . H O / H
R — C — Cl + N3H  R — C — N3  R — C — N :  R—NCO 2  R—NH2
Acylazide
297. Answer (2)

CH3 CH3
+
HCN/H3O
H3C C OH H3C C COOH
CH3 CH3
298. Answer (1)
O O
|| CH3 H O/H  ||
CH3—CH2— C— N 2  CH3—CH2— C—OH + CH3—NH—C2H5
C 2H 5
299. Answer (4)
P2 O5
COOH 
O = C = C = C = O + 2H2O
Carbon suboxide
CH2
COOH CaO/
CH2 = C = O + H2O + CO2
Ketene
300. Answer (3)

O OH COOH OH CH2OH O
O +
H
301. Answer (4)

O
(C2H5 O)3Al
CHO C O CH2
COOH + CH2OH
302. Answer (3)
Amide forms amine. Acetone and acetophenone give haloform test.
303. Answer (2)
O CH2
HOOC – (CH2)4 – COOH
304. Answer (2)

NO2 NO
Fe / H O
 2
305. Answer (2)

O
|| LiAlH4
CH3—CH2— C—NH2   CH3—CH2—CH2—NH2
306. Answer (4)

Due to maximum molecular mass.
307. Answer (3)
More is the +I effect, higher is the basicity of amine in gaseous phase.

Among C6H5NH2, CH3NH2, (CH3)2NH,
(CH3)3N . C6H5NH2 is least basic due to resonance.
+
NH2
+
NH2
+
NH2 NH2 NH2
Out of (CH3)3N, CH3NH2, (CH3)2NH . (CH3)2NH is most basic due to +I effect and hydrogen bonding in H2O.
+I effect
CH3
H3C H
+I effect
O
Hydrogen H H
bonding
308. Answer (1)
Due to maximum resonance stabilised nitrogen atom.
NH2 Protonation NH3

(a) 3
1° & sp
Protonation
NH NH2
(b) 2
sp
+
NH2 NH2 NH2
Protonation
+
NH NH2 NH2
(c)
[Equivalent resonance]
Protonation
(d) NHCH3 NH2–CH3

2° & sp3
 Correct order of basicity : b < a < d < c.
309. Answer (4)

Nitrobenzene does not respond to Friedel Craft acylation.
310. Answer (3)
More -hydrogen on alkyl group, more repelling power.
311. Answer (2)
CH3 CH3 CH3
KNH NH –
 
2
 
2

NH2
Cl
312. Answer (2)
Hofmann elimination (Least substituted alkene is formed).
313. Answer (1)
It is Gabriel synthesis used for preparation of primary amine only.
314. Answer (3)
Zn dust and NaOH are strong reducing agent.
315. Answer (2)
CH3 CH3
| HNO 2
|
CH3 — C — CH2 — NH2  
 CH3 — C — CH2 — CH3 (followed by rearrangement)
| |
CH3 OH
316. Answer (2)
NO
|
HNO 2 NaOH
R — CH — R   
 R — C — R   
 Blue colour
| |
NO 2 NO 2
317. Answer (3)

Dipole moment of alkyl cyanides are very high.
318. Answer (2)
It can form most stable carbocation.
319. Answer (1)
NaNO / HCl
HO3S NH2  2  NaO3S N2Cl
N(CH3) 2
NaO3S N=N N(CH3)2

Methyl orange
320. Answer (3)
NC NH2
H O / H
2  + HCOOH
321. Answer (2)
O–
|
H O2
CH3 — N — CH — CH3 2   CH3 — N — CH — CH3  CH3—CH = CH2 + (CH3)2N—OH
| | | |
CH3 CH3 CH3 CH3
322. Answer (2)

HNO 2
This test is only for secondary amines R2NH    R2N—NO.
323. Answer (3)
H SO
(C2H5)2 NH 2 
5
 (C2H5)2 N—OH
324. Answer (2)
Fact.
325. Answer (1)
It is Hinsberg test
O O O
|| || ||  
KOH
S — Cl + R—NH2  S — NH — R  S — NK — R
|| || ||
O O O
326. Answer (3)
NaOH
N2Cl 
327. Answer (2)
OH O
HO OH
CH2 — OH
328. Answer (3)

Approximately 52% p-nitro aniline.
329. Answer (3)
Migration of CH 3O is easier than

OCH3
330. Answer (4)
N2Cl NH2
+ N N NH2
(yellow dye)
331. Answer (3)

Due to maximum e– density on N.
332. Answer (2)
Cl > —OCOC2H5 > —OC2H5 > —NH2
333. Answer (1)
O
CH3
H C N is formed
CH3
334. Answer (4)

Migration of CH3 on N takes place
335. Answer (1)
N(CH3)2
CH (Malachite)
N(CH3)2
336. Answer (4)

All form complexes
337. Answer (1)
Hg(NHC2H5)2 is formed.
338. Answer (2)
C 8H18 − cannot migrate due to Bulkier group.
339. Answer (4)

NH2
NO2 W.A
S.B.
H2N NH2
Benzidine
340. Answer (4)
It is due to polar protic medium.
341. Answer (1)
CH3 − CN ⎯⎯
→ CH3 − COOH + NH3 , CH3 − NC ⎯⎯
→ CH3 − NH2 + HCOOH
HCOOH reduces tollen’s reagent while CH3COOH does not reduce tollen’s reagent.
342. Answer (2)
Diazo salt is an electrophile & Phenoxide is more reactive than phenol towards SE reaction.
343. Answer (2)
344. Answer (4)
345. Answer (4)
R O R O
H2N — C — C — OH + H — NH — C — C — OH
H H
– H2O
R O R
H2N — C — C — NH — C — OH
H H
Peptide linkage
346. Answer (1)
O R O
R
CH — C CH — C
H — HN OH 
HN NH
– H2O
HO NH — H
C — CH CH — CH
O R O R
347. Answer (3)
348. Answer (1)
349. Answer (3)
350. Answer (4)
351. Answer (4)
352. Answer (3)
353. Answer (2)
354. Answer (3)

DNA contains ATGC bases
A – Adenine
T – Thymine
G – Guanine
C – Cytocine
So quinoline is not present.
355. Answer (3)

The typical elastomeric properties of natural rubber are attributed to its almost complete cis configuration and
nature of gutta percha is attributable to its trans structure.
356. Answer (3)
Nylon-66 is fibres, in which the interparticles forces are strongest these forces are either H-bonds or dipole -
dipole attractions.
357. Answer (4)
Buna-S is copolymer of butadiene and styrene.
358. Answer (4)
In condensation polymerisation a large number of monomers combine together usually with the loss of simple
molecules like water, alcohol etc. and they are also called step growth polymers, monomers of terylene are
ethylene glycol and terephthalic acid.
359. Answer (4)
Zeigler Natta catalyst is TiCl4 + (C2H5)3 Al.
360. Answer (2)
Polyamide and polyester are examples of condensation polymers.
361. Answer (3)
NH2 NH2 N —NH N

N NH2 NH2OH NH2—CH2—
Polymerisation
+ HCHO
N N N N N N
NH2 NH2 NH n
Melamine Resin intermediate |
Melamine polymer
362. Answer (1)
Formaldehyde is used in the formation of Bakelite (phenol + formaldehyde) and melamine resin.
363. Answer (2)

Thermoplastic polymers softon and melt on heating PVC is an example of thermoplastic.

Dacron is polyester formed by condensation polymerisation of terephthalic acid and ethylene glycol.
HOOC COOH + HO—CH2—CH2—OH —CO CH2—CH2—O—

n
Dacron
Acrylonitrile, Neoprene and Teflon are addition polymers of acrylonitrile, isoprene and tetrafluoro ethylene
respectively.
364. Answer (3)

Bakelite is condensation polymer of phenol + formaldehyde, glyptal is condensation polymer of ethylene glycol
+ phthalic acid, caprolactum is monomer of nylon-6, Buna-S is co-polymer of butadiene + styrene.

Acrylonitrile + 1, 3-butadiene  Buna-N
(Bu = Butadiene, na  Sodium, a polymerising agent, N = Nitrile)
365. Answer (1)

(PAN)  Polyacrylonitrite
nCH2= CH  
Peroxide
| |
CN CN n
(PAN)
366. Answer (4)

367. Answer (1)
368. Answer (4)
369. Answer (1)
370. Answer (1)
371. Answer (3)
372. Answer (2)
373. Answer (1)
374. Answer (2)
375. Answer (3)
376. Answer (4)
377. Answer (2)
378. Answer (2)
Kelvar is an polyamide which is obtained by condensation of terephathalic acid and P-phenylenediamine.
379. Answer (4)
Free radical of the compound C6H5CH=CH2 is most stable amongst the given compound therefore it will give free
radical polymerisation with ease.

Caprolactam is hydrolysed to produce caproic acid which undergoes condensation to produce Nylon-6.
O O
NH H3O +
C
HO (CH2)5 – NH2
(Caprolactam) (Caproic acid)
380. Answer (4)

The cation of the compound CH3–C=CH2 is most stable amongst the given compound.
CH3
381. Answer (2)
CN
HCN Polymerisation
CH CH Ba(CN)2
CH2=CH–CN Peroxide
–CH2–CH–
n
Orlon
(Polyacrylonitrite)
(PAN)
382. Answer (2)
H O
O NOH N C
O
NH2OH H2SO4 CH2 CH2 260-270°C –
Beckmann's –H2O
–C–NH–(CH2)5
rearrangement
CH2 CH2
CH2 Nylon-6
Cyclohexanone
oxime Caprolactum
383. Answer (4)
PTFE, polyethylene and PVC are homopolymers so their molecular mass is a whole number multiple of mol.
mass of monomer but terylene is condensation polymer.
384. Answer (1)
Polymethyl methylacrylate (PMMA) is known as plexiglass.
385. Answer (3)
Vulcanisation is a process of heating of rubber with 3-5% sulphur. It introduces cross links of sulphur atoms
between the polymeric chains thereby increasing the elasticity, tensile strength etc.
386. Answer (1)
387. Answer (3)
O N–OH
[O] NH2OH (i) PCl5
Nylon-6
(ii) Polymerisation
388. Answer (3)

389. Answer (4)
Neoprene is not a biopolymer and it is thermoplastic polymer and is a synthetic rubber.
390. Answer (4)
Neoprene, PVC and Polyethylene are the addition homopolymers.
391. Answer (2)

In condensation polymerisation a series of condensation reactions between the (generally two) monomers
containing at least two functional group each occur with loss of a small molecule such as H2O, CH3OH or HX,
Terylene is a condensation polymer of ethylene glycol and Terephthalic acid. It is also called step growth polymer.
392. Answer (4)
Because it contains alcoholic group in its side chain HOCH2–CH2NH2–COOH.

(– SH) Thiol group is present in cysteine.
HS – CH2 – CH – COOH
NH2
393. Answer (2)

In Greek, tyros means cheese.
394. Answer (2)
Amylose
CH2OH CH2OH
O O
H H H H
H H
–O OH H O OH H OH
, 1, 4
H OH H OH
395. Answer (1)
Cellulose
CH2OH CH2OH
O O
H H
O H H O
O
OH H OH H H
H
, 1, 4
H OH H OH
396. Answer (4)
A - Adenine pairs with T (Thymine)
G - Guanine pairs with C (Cytosine)
397. Answer (3)
Tertiary structure aims at giving more stability to the structure of protein as compared to other 2 hence variety
of bonds.
398. Answer (3)
CHO
HI, 
(CH–OH)4 CH3–CH2–CH2–CH2–CH2–CH3
n-Hexane
CH2–OH
399. Answer (3)
Raw fish contains thiaminase an antienzyme for Vit. B1 or Thiamine.
400. Answer (1)
Vit. A, C, E prevent formation of free radicals hence antioxidising.
Vit. D prevents rachitis hence antirachitic vitamin.
Vit. B1 prevents neuritis hence antineuritic vitamin.
Vit. E prevents ageing hence beauty vitamin.
401. Answer (2)
402. Answer (2)
Deptite-2 amino acids linked by a peptide bond.
403. Answer (4)
Fact.
404. Answer (2)
Fact.
405. Answer (1)
Fact.
406. Answer (1)
Fact.
407. Answer (2)
Amino group attached to -carbon.
408. Answer (1)
Fact.
409. Answer (1)
In sucrose carbonyl group glucopyranose and fructo-furanose are used in glycosidic linkage hence loss of
reducing property.
410. Answer (1)
pK a  pK b 2.34  4.40
Isoelectric point =   3.37
2 2
411. Answer (2)
Only aldose decolourises the Br2-water.
412. Answer (2)
Glycogen is stored sugar of animal body as starch in plants.
413. Answer (2)
The sugar present in D.N.A. is 2-deoxy D(–) ribose.
414. Answer (3)

B2 is soluble in H2O but insoluble in fat
Vitamin H is insoluble in H2O and fat both
Vitamin A is soluble only in fat
Vitamin C is soluble in H2O

Vitamin C is water soluble vitamin.
415. Answer (1)
⎡ ⎤
⎢ ⎥
−⎢⎢ NH − CH2 − C − NH − (CH2 ) − C −
⎥
⎥
|| 5 ||
⎢ ⎥
⎢⎣ O O ⎥⎦ n
Nylon-2-Nylon-6
(Step growth polymer)
416. Answer (4)
N
and are aromatic
N N
417. Answer (2)
→ CH2 = CH − C ≡ CH
HC ≡ CH ⎯⎯
↓
CH2 = CH − C = CH2
|
Cl
↓
−⎛ CH2 − CH = C − CH2 −⎟⎟⎞
⎜⎜ |
⎜⎜⎝ ⎟
Cl ⎠⎟n
Neoprene
418. Answer (3)

Tranquilizers  These medicines act on central nervous system and help in reducing anxiety and relieve tension
on the nerves.
419. Answer (1)
It is chloroxylenol and is a component of dettol.
420. Answer (2)
Indigo is blue dye while alizarin is red dye.
421. Answer (1)
Heroin is morphine diacetate and is a narcotic drug.
422. Answer (2)
The sweetness of glucose is about 75% of cane sugar.
75
 Sweetness of glucose = 100   75.
100
423. Answer (1)
Reserpine is obtained from this plant which lowers the blood pressure.
424. Answer (2)
The sodium salts of azo dyes containing sulphonic acid (–SO3H) and carboxylic acid (–CO2H) groups are called
acid dyes.
425. Answer (1)
SLV-3 is indian rocket in which composite solid propellant is used.
426. Answer (4)
Factual.
427. Answer (4)
The chemicals which are used to bring down the body temperature during high fever are called antipyretics.
428. Answer (1)
Aspirin used as both antipyretics and analgesic.
429. Answer (1)
430. Answer (4)
Bipropellants consists of two liquids one of which acts as a fuel while other acts as the oxidizer.
431. Answer (1)
Mordant dyes are applied to the fabric after treating them with a metal ion (mordant) which acts as a binding
agent between the dye and the fabric.
432. Answer (3)
Malachite green is an example of triphenyl methane dye C .
433. Answer (3)
OH
COOCH3
 Methyl salicylate.
434. Answer (4)
O
||
O–C–CH3
COOH
Aspirin
435. Answer (1)

Leibig’s method is used for the estimation of carbon and hydrogen.
436. Answer (2)
Na2S + (CH3COO)2 Pb  PbS + 2CH3—COONa
437. Answer (2)

All nitrogen is converted to NH3.
438. Answer (2)
Beilstein test is used for the detection of halogen in organic compound.
439. Answer (1)
Kjeldahl method cannot be used for those compound in which nitrogen is present in ring.
440. Answer (3)
Phenol is acidic and gives violet coloured complex with FeCl3.
441. Answer (3)
Molecular weight 60
n= = =2
Empirical weight 30
So, molecular formula = C2H4O2

442. Answer (2)
KOH is used to absorb CO2.
443. Answer (3)
PbS is insoluble in CH3COOH.
444. Answer (1)
Li is very less reactive while K is very highly reactive.
445. Answer (3)
Aldehyde gives positive test with Tollen reagent.
446. Answer (1)
If 42 g silver is present the weight of organic compound = 58
58
If 1 g silver is present the weight of organic compound =
42
58  108
If 108 g silver is present the organic compound = = 149.14
42
So molecular weight of organic compound = 149.14 + 1 = 150.14 ~ 150

447. Answer (2)
Blood red colour is due to CH3 — C — NO 2 .

||
N— ONa
448. Answer (1)
—COOH group gives brisk effervences with NaHCO3.
449. Answer (2)
In Hofmann method diethyl oxalate is used.
450. Answer (1)
In thin layer chromatography, stationary phase is solid.
451. Answer (3)
Complex is [Fe(H2O)5NO]SO4.
452. Answer (3)
Black ppt are of Hg + Hg(NH2)Cl.

Black ppt
453. Answer (4)

All these metal ions belong with IIA group (groups belong with qualitative classification).
454. Answer (1)
NiS is black coloured and soluble in aqua regia.
455. Answer (1)
Cu+2 is coloured due to d-d transition.
456. Answer (4)
Except Be and Mg, all s block elements give flame test.
457. Answer (3)
Sodium metal does not form nitride.
458. Answer (1)
As size of halogen increase, covalent character increase, so solubility decrease.
459. Answer (4)
MnS + 2HCl 
 MnCl2 + H2S
MnCl2 + 2NaOH 
 Mn(OH)2 + 2NaCl
Br2 + H2O 
 2HBr + (O)

Mn(OH)2 + O  MnO2 + H2O
Black ppt
460. Answer (2)
Al(OH)3 + NaOH 
 NaAlO 2 + H2O
gelatinous white ppt So luble
NaAlO2 + NH4Cl + H2O 

 Al(OH)3 + NaCl + NH3
461. Answer (4)
NO2 NH2 NH2 N2Cl N(CH3) 2
NaNO2/HCl
NaOH NaSO3 N=N N(CH3)2
SO3H SO3H
462. Answer (2)
O OH O OH
OH OH
O +
O O
Alizarin
463. Answer (1)

NHCOCH3 NH2
SO2NH2
Sulphonilamide
PCC is mild oxidising agent, it will convert R  CH2  OH 

 R  CHO


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Organic Chemistry UNIT 2

Section - A : Straight Objective Type

6a. Answer (2) [JEE (Main)-2018]

12. Answer (2)

13. Answer (3)

14a. Answer (2) [JEE (Main)-2014]

(ngeq )H2SO4  (ngeq )NaOH  (ngeq )NH3

14b. Answer (1) [JEE (Main)-2015]

Weight of AgBr Mol. mass of Br

16. Answer (2)

⎡ weight of silver salt ⎤ ⎡ 1 ⎤

24. Answer (4)

25. Answer (2)

26. Answer (3)

28. Answer (3)

29. Answer (3)

30a. Answer (2) (AIEEE 2009)

CCl3 > C6H5 CH2 > (CH3)2 CH > (CH3)3 C

31. Answer (3)

39a. Answer (4) [JEE (Main)-2014]

(a) (b) (c) (d)

+ is formed as a most stable carbocation.

42. Answer (2)

50. Answer (1)

50a. Answer (2) [JEE (Main)-2017]

51. Answer (1)

56. Answer (2)

58. Answer (4)

75. Answer (2)

77a. Answer (2) (AIEEE 2010)

decreasing order of SN1 reactivity

78. Answer (2)

79a. Answer (1) [JEE (Main)-2016]

80. Answer (4)

81a. Answer (1) [JEE (Main)-2016]

82. Answer (4)

86. Answer (3)

CH3 CH3 CH3 CH3

100. Answer (3)

CH3 CH3 CH3 CH3

102. Answer (2)

106. Answer (3)

CH3 + CH3 C2H6 (Alkane)

109. Answer (1)

109a. Answer (2) (AIEEE 2010)

110. Answer (2)

111a. Answer (3) [JEE (Main)-2018]

Na/liq. NH3 CH3 H

So, option (3) is correct.

112. Answer (3)

115. Answer (3)

118. Answer (4)

119. Answer (2)

131a. Answer (1) (AIEEE 2012)

132. Answer (3)

134. Answer (2)

136. Answer (4)

138a. Answer (1) (AIEEE 2010)

139. Answer (3)

145. Answer (4)

CH3 CH3 CH3 CH3

153a. Answer (2) [JEE (Main)-2015]

154. Answer (3)