va Resonence Educating for better tomorrow TARGET : JEE (Main + Advanced) 2017 Course : VIKAAS (JA) Date : 31-08-2015 TEST INFORMATION DATE : 20.09.2015 PT - 3 (ADVANCED) Syllabus :Gaseous state-1and Chemical equilibrium (All ChemInfos and Handouts till date) This DPP is to be discussed in the week (31-08-2015 to 05-09-2015) DPP No. #31 (JEE-ADVANCED) Total Marks : 62 Max. Time : 42 min. Single choice Objective (‘-1" negative marking) Q.1 to Q.3, (3 marks, 2 min.) [09, 06] ‘Multiple choice objective ('-1" negative marking) 2.4 to 0.6 (4 marks, 2 min.) [12, 06] Comprehension ('-1" negative marking) Q.7 to .9 (B marks, 2 min.) __[09, 08] Single Integer type Questions ('-1" negative marking) @.10 to @.14 (4 marks 3 min.) [20, 15] Double Integer type Questions ('-1" negative marking) 2.15 (4 marks 3 min.) [04, 03] Match the column (no negative marking) 0.16 (8 marks 6 min.) [08, 06) Ques.No [1] 2][3]4]5[6|7] 8] 9] | | 12] 13/14] 16] 16] Toa Mark obtained 4. Expressthe average kinetic energy per mole of a monoatomic gas of molar mass M, al temperature T Kin terms of the mean speed of the molecules () : [Gaseous State] we wearenredta thy, fore Aree seri MB, a fe ate sthea afeor Gat wT TK ara oR ays & are an (g) 3 oe 8 Fmt aS aaa we aM a2 Ma (2M) (a2 . A) 3, (OF (B) 9g (8) ©| =) (er (56) 2. The correct relationship between average translational kinetic energy per mole (KE) and most probable speed (V,,.) for an ideal gasis : (M is molar mass of gas) [Gaseous State] ea ec Bw Fa te eee MT a AAT KE.) ee eH aT A (v,,) IH HE ie 1 Prt & : (M, ae or Ares RerIFT 2) eke [aK [axe [aE Ono ™ ant g* ip Me™ 9M OV.g= 3 ap M sol. Ke=SaT= My,» 3. The graph which will be representing all he equilibrium concentrations for the reaction N,0,6) > 2NO, (@) will be {the concentrations of N,O, (g) and of NO, which of the following graphs) ae cae fF APTA N,O,(g) <=> 2NO, (g) # fee, so TI FHT (equilibrium concentrations) #1 rafter et 8 ) for which the following reaction will be at equilibrium will lie on arpa Oi CS Tost A BER, Wat Gy Wa tay Roe Ra RESONSNCE rene rmaresmmeonT Educating for better tomorrow carrraeTaGO ZOD ZIGT TOD 255 SESS] CH USSISERIEOOTPT COTOSol. 4s Sol. (N,0, (8) 2H NO, ay A aren, ford Re siBoa ara ue eM, RAS were ster Gere) eB wen) A) INO] (84) INO © hl (0) NOY] ~~ NO] (Noy — Oj — INOJ Allthe equilibrium concentrations will satisfy the equation c= NOR = ttn aur parabolic raph 041 quired ps rapt of) area arse, ator aigte ae | 10)" kK nal y= kc oraers oa ote #1 If the wave number of 1* line of Balmer series of H-atom is x’ then then 08 x 1 (A) wave number of line of lyman series ofthe He* ion willbe = 368 (8) wave number of 1* line of lyman series of the He* ion will be =~ 5x (C*) the wave length of 2% ine of lyman series of H-atom is > 32x (0) the wave length of 2% line of lyman series of Heatom is = Hevea, are Sh oft er Rear ob Rg eee x 8 aa 108 2 am (At) Het ners a orgns Soft a ger ter & Ferg cen siee 5 36 (B) Hest ren oh et Nem fare en ao Seo (Ce) Herery a eget Sh a Ectra ber aH en wma axa (0) Hearne a arg Soh ah Rett ear at oe aE ay arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrowSol. The curves in the Fig. represents two different Maxwell-Boltmann velocity distributions for the same gas sample under two different conditions, A and 8. Which of the following statements about conditions A and B islare false? Condition A C. speed > (A) The temperature for B is greater than for A, (B*) The average kinetic energy for Ais greater than for B. (C*) The intermolecular attractive forces are greater for Athan for B. (0°) Aand B correspond to the same temperature but different volumes, wart tar a et RAG BS fog are et fh Aaee—diecart I freer ar ante Pera A efeher 8 fH 8 8 Or oT oem Rent AG BS fay wa a Rafe Ca A) Bo fay aT Ag siteT sta 81 HAS fey shore nfs Sat Bien aie B (COAG PGB A ster arava carton ae sia & OHASHI B.S eira aoa BAM & aH Ta ATE K, Which of the following reaction(s) is fare follow the relationship, log x —log RT =0 K, fre 8 8 oh afftra tog 2 —log RT = Oger wT OTe ea (A) PCL.(g) = PCL) + C1,@) ©) 280,@) + 0,0) = 280,9) (C*) 4NH,(g) + 50,(g) = 4NO(Q) + 6H,O(@) —_(D) N,(g) + 3H,(g) = 2NH.(9) Using (swan et EY K,= K, (RTP iS Ke so (ester), log so(eaity, Ane +4 n, log RT Comprehension (7 to 9) ogee The rate of chemical reaction at a particular temperature is proportional to the product of the molar concentration of reactants with each concentration term raised to the power equal to the number of molecules of the respective reactant taking part in the reaction. aA + bB —> products, rate of reaction o(AJ* [8] = k [Al [B)?, where kis the rate constant of the reaction EQUILIBRIUM CONSTANT (k) For a general reaction aA + bB <= oC + dD, forward rate r,= ky (AI? [B]°, backward rate r, = k, (CID), concentrations of reactants & products at equilibrium [cy [D1* TAP TBP Mereallthe concentrations are expressed in moltiter, Ky are related by = arpa Oi TCS Tost SH BER War Cy Wa Tava Rov Rae FTES Resonance} ducating for better tomorrow