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Definition Halogen + Hydrogen Halide salts + Conc. H2SO4 : NaCl + H2SO4 ...............................
Electronegativity:........................................................... X2(g) + H2(g) 2HX(g) Depends on how easily the halide
...................................................................................... Polar bonds ions is oxidised (reducing ability)
1stI.E:.............................................................................. H F* Reactivity NaBr + H2SO4 ...............................
....................................................................................... H Cl Thermal F- Reducing ability of
1st Electron affinity:....................................................... H Br stability halide ions ...........................................................
....................................................................................... H I Acidic Cl- Explanation:
Bond enthalpy:............................................................. strength .............................................
..................................................................................... * = Hydrogen bond b.p.* Br- .............................................NaI + H2SO4 .................................
1 9 .............................................
I- ........................................................................................................
Test for Halide ions with AgNO3(aq) : .............................................
Disproportionation reactions Ion Ppt Formula dil. conc. ...........................................................
NH3(aq) NH3(aq)
.............................................
(species is simultaneously oxidised and reduced)
Cl2 + H2O Cl- ........................................................................................................
0 .............................................
Br- 8 11
For (iii) uses of Group VII elements, students are encouraged to do their own research.
The order of use is indicated by the NUMBERED CIRCLES (make it easier for students to follow). This can be changed to suit your style of teaching.
Use arrows to indicate increase or decrease in trends (all trends are down the group as indicated by the huge black arrow next to the elements or ions).
e.g. Atomic radius
Reactivity
Everything in RED relates to chemical properties.
Show the states and discuss the colours of chlorine, bromine and iodine.
Opportunity to discuss uses
Demonstrate sublimation and recrystallisation of iodine.
Demonstrate displacement reaction.
Demonstrate test for halide ions.
Discuss thermal stability of hydrogen halides using suitable data (the ones below might be useful).
BOILING POINTS OF HYDRIDES
100 H2O
BOILING POINT / C°
HF
0 Mr
50 100 140
NH3
GROUP IV
GROUP V
GROUP VI
GROUP VII
Source: www.Chemguide.co.uk -160
Just an observation: Students appreciate Large A3 size coloured printout of this mind map!