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What is HYDRATES?
Hydrate is a crystalline solid; is building blocks consists of a Gas
molecules surrounded by a cage of water molecules.
The formation of gas hydrates in natural gas pipe lines depends primarily up
on the pressure, temperature and composition of gas-water vapour mixture.
Gas dehydration is the most commonly used method for hydrate prevention.
What Is Gas Dehydration?
1. Absorption
Using Liquid agents
2. Adsorption
Using Solid agents
Adsorption is usually carried out solid desiccant like Silica gel or
Alumina
Properties of TEG
Tri Ethylene Glycol is called TEG
Chemical formula: C6H14O4
Sp gravity: 1.1274 @15 °C
Boiling Point: 285 °C
Degradation start point: 206 °C
Introduction of Gas Dehydration
The Wet gas from Separator is being processed in Dehydration unit
Dehydration is carried out by contacting the wet gas stream with Lean TEG.
When the water content is removed from gas, Dew point temp of gas out
from Contactor moves with in the limit of dry gas specification.
Lean TEG
Water vapour
Dehydrated gas further is being utilized for Gas exporting or Gas Injection.
Lean TEG (99.8 %) is injected to the Dehydration system to absorb water
from Gas
Rich TEG (which contains 4.0 % absorbed water) from Contactor passes to
the TEG regeneration system.
Rich TEG is heated up in Regeneration system, up to 200 C and boiled
water vapors taken off from the system.
Regenerated Lean TEG, further circulated through Gas Dehydration System.
How to determine dehydrated gas are with in the spec?
By monitoring DEW POINT of Dehydrated gas (< 2.5 lbs/mmscfd or Dew point
temp -54 C @ Atmos)
The dew point is the temperature (at a given pressure) at which the first
drop of water is foamed.
Note: Dew point can either be expressed in temperature or lbs water (content)/mmscf of gas.
8.0
Indicates, Dew point
7.0 temp will vary
6.0 corresponding to
different pressure,
5.0
while water content is
4.0 constant.
3.0
Dew point Limit
Dew point
2.0
In means of water content
Target
1.0 2.5 lbs/mmscf
-15
-5
-55
-50
-45
-40
-35
-30
-25
-20
-10
10
15
20
-60
Stripper
Flashing gas 200 C
Rich TEG N2 to LP Flare
make-up
Lean TEG
Carbon filter
Flash drum
Water Vapour
Stripping gas
Heavy hydrocarbon condensate
Rich TEG
Surge drum
Rich TEG for Regeneration
Water vapour
198 C
Cartridge 160 C
filters
Rich/ Lean TEG
Exchanger
58 C
48 C
Gas/ TEG 85 C
Exchanger
Lean TEG
Contactor
83 C
Gas to LP
TEG Circulation Flare
Pump
Vent
Vent condenser
35 C condenser
Rich
scrubber
Water/ condensate
drum
TEG to drain
Inlet
exchanger
In Contactor, wet particle regeneration system.
from the gas is being
attracted by Lean TEG. Water
Regegeration
Rich TEG (TEG+Water)
accumulated at the
bottom of Contactor Gas to
TEG
Contactor
Inlet
Gas from
scrubber
Separator Rich TEG from Contactor is being processed in
Regeneration system absorbed water in Rich TEG will
Liquid evaporated by high temp provided by steam or Heater.
TIPS FOR THE BETTER OPERATION OF GAS DEHYDRATION UNIT (GDU)
When the water content is removed from gas, Dew point temp
(Hydrate formation temp) moves to lower side.
TEG out
Absorbed water
Skimmed
condensate out
TEG/ Gas Exchanger
85 0C Lean TEG
in to Exch
In Exchanger, Lean TEG is
cooled down to 50°C by the out Contactor
going gas from Contactor, prior Gas out
to enter in to Contactor.
Feed gas
Dry Gas from Gas Dehydration Column is @ 45 C
used as a cooling medium for Lean TEG.
Amount of water which is removed out from gas in the contactor depends
mainly on:
In the Glycol Flash Drum the dissolved hydrocarbons are separated from the TEG. Then
the gas is sent to LP flare header under back pressure control valve.
A fuel gas blanket line with PCV arrangement is provided to supplement the gas
flow if necessary to maintain the vessel pressure.
4.0 Barg
5.5 barg
Blanketing gas
To LP Flare Rich TEG in
Condensate out
Rich TEG To Filters
PARTLCLE FILTER Rich TEG to C L/R exch.
Removing solid impurities over 5 dim from Rich TEG. These Rich TEG from Cont
particles will damage the Glycol Circulation Pump, liquid 97C
trims, plug, Glycol Still Column packing and cause foaming in
the Gas Dehydration Column..
Reboiler
Carbon Filter
Rich TEG being filtered for Aromatic hydrocarbons and 200 C
canister shall be replaced every 3 months or according to
differential pressure across the filter. H L/R EXGR
PDI
Stripper
Heater
202 C or steam
The TEG flows downward across the
packing (of Still Column) and TEG partially Stripping gas
regenerated in the Glycol Still Column to preheating
Lean TEG
through contact with rising vapors
generated by the Glycol Reboiler.
Rich TEG
Stripping Column
Gas to
Stripper
Stripping
Stripping gas
gas
to preheating
to preheating
GLYCOL STRIPPING COLUMN
Surge Drum
Lean/Rich Exchanger
Reboiler
Rich/ Lean exchanger can a plate type cross exchanger or
Shell and tube type depends up on the offshore installations.
Gas to Stripper
200 C Lean TEG
Surge Drum
circulation line)
exchanger will be bypassed from TEG circulation
Warm up (Cold
Surge Vessel
and flow will be diverted through warm up line to
Reflux Condenser. Restricted Orifice also provided Recirculation
on Warm up line. valve
Pump RO