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No Donor Acceptor linker Kenapa Journal

1 Tidak ada Design of NIR-


Absorbing Simple
Asymmetric
Squaraine Dyes
Carrying Indoline
Moieties for
Use in Dye-
Sensitized Solar
Cells
with Pt-Free
Electrodes

doi ;
Penggunaan senyawa sq dapat meningkatkan penyerapan foton 10.1021/ol300054a
hingga 750 nm
2 Organic Dye
Bearing Asymmetric
Double Donor-π-
Acceptor Chains
for Dye-Sensitized
nonconjugated n-hexane chain Solar Cells
Difenilamin
10.1021/jo201057b
linker ini menghasilkan 2
pemanen cahaya yang terpisah Difenilamin: berkontribusi untuk menekan agregasi pewarna
, berguna untuk meningkatkan pada permukaan TiO2 untuk meningkatkan masa hidup
intensitas absorbs dan elektron karena perlindungan permukaan yang lebih baik, yang
memperluas jangkauan akan meningkatkan kinerja keseluruhan dari DSSCs
phenoxazine penyerapan cahaya (
absorption overlap and phenoxazine : pemanen cahaya yang baik pada zona visible
complement of both the donors
and p-spaces) pada waktu yang the overall conversion efficiency reaches 6.06% for DC-
bersamaan sensitized solar cells as a result of its longer electron lifetime
and higher incident monochromatic photon-to-current
conversion efficiency
3. Performance of dye-
sensitized solar cells
based on novel
sensitizers bearing
cyanoacrylic asymmetric double
nonconjugated n-hexane chain D_p_A chains with
Difenilamin acid
arylamines as donors
linker ini menghasilkan 2
pemanen cahaya yang terpisah 10.1016/j.dyepig.2
, berguna untuk meningkatkan 012.02.011
Carbazole intensitas absorbs dan
memperluas jangkauan Difenilamin: berkontribusi untuk menekan agregasi pewarna
penyerapan cahaya ( pada permukaan TiO2 untuk meningkatkan masa hidup
absorption overlap and elektron karena perlindungan permukaan yang lebih baik, yang
complement of both the donors akan meningkatkan kinerja keseluruhan dari DSSCs
phenothiazine
and p-spaces) pada waktu yang
bersamaan
DC3 exhibited the best overall light to electricity conversion
efficiency of 5.19% (Jsc ¼ 10.79 mA cm_2, Voc ¼ 687 mV,
FF ¼ 0.70) under standard global AM 1.5 solar light irradiation
(100 mW cm_2). Compared to DC2, DC1 and SC, the cell
based on DC3 had the higher h because of its relatively higher
Jsc.
4. SQ CA Near-Infrared
PA Asymmetrical
Squaraine
Sensitizers for
Highly Efficient
Dye Sensitized Solar
Cells: The Effect of π
‑Bridges and
Anchoring
Groups on Solar Cell
Performance

10.1021/cm504594
6

Efisiensi CA lebih baik daripada PA (Anchoring group)

This is due to high short circuit currents (JSC) and increased


open circuit voltages (VOC). Dyes with PA anchoring groups
exhibited lower JSC resulting from decreased charge injection
efficiency, as determined by femtosecond transient absorption
spectroscopy. This study suggests that out-ofplane bulky
substituents may increase DSSC performance not only by
increasing JSC through decreased aggregation but also by
increasing VOC through decreased TiO2/electrolyte
recombination.
5 zn tBu Highly Asymmetric
Tribenzonaphtho-
nBuO Condensed
Porphyrazinatozinc
Complex: An
Efficient Near-
Infrared
Sensitizer for Dye-
Sensitized Solar
Phthalocyanine Cells
intense absorption in the UV/ 10.1002/cplu.201200219.
blue (Soret band) and the
red/near-IR (Q-band) spectral
regions for efficient photon
harvesting Zn-tri-PcNc-2b displays 60.7% of the maximum incident
monochromatic photon-to-current conversion efficiency (IPCE)
in the red/near-IR region, which is much higher than that of
Zntri- PcNc-3b (22.9 %), thus highlighting the potential of Zn-tri-
PcNc-2b as a DSSC component
6 Carbazole-bridged
double D–A dye for
efficient dye-
sensitized solar cell

http://dx.doi.org/10.1016/j.
jphoto- chem.2014.09.007.
The double donor–acceptor dye CBZ-3 is linked by a carbazole
unit as a secondary donor which increases the donor–acceptor
strength of the dye and proved to increase the h and Jsc values
of the photovoltaic cell compared to the corresponding mono-
anchoring system CBZ-2 and the monodonor dye CBZ-1

With the non-planar structure of the arylamino group and the


alkyl chains which efficiently prevent the formation of the dye
aggregates, the dye exhibited a high open-circuit photovoltage
(Voc) of 650 mV, a short-circuit photocurrent density (Jsc) of
7.20 mA cm_2 and the solar energy-to-electricity conversion
efficiency (h) of 3.23%.
7 Carbazole - R= butyl / octyl Asymmetric
Phenothiazine double donor-p-
acceptor dyes
based on
phenothiazine
and carbazole
donors for dye-
sensitized solar
Carbazole rhodanine R= butyl / octyl cells
Phenothiazine acetic acid
https://doi.org/10.
1016/j.tet.2017.09.
018

Carbazole cyanoacetic R= butyl / octyl


Phenthiazine acid

CPR-series dyes shows


larger maximum absorption wavelength and broader absorption.
spectra than CPC-series dyes with cyanoacetic acid acceptor,
indicating their better light-harvesting capability. However, the
disjointed carboxylic group with the whole conjugation system in
CPR-series dyes deteriorates the electron injection efficiency and
leads to inferior IPCE and VOC. Compared with short butyl chain,
8 carbazole phosphonic - Carbazole dye with
acid phosphonic acid
anchoring groups
for long-termheat
stability of dye-
sensitized solar cell

10.1016/j.electacta.
2013.12.013

we found that the phosphonic acid group as ananchor in the


organic dye was effective in increasing the long-termheat
stability of the DSSC. The combination of a strong acceptor and
a phosphonic acid will produce robust and highly efficient dyes.