Material Safety Data Sheet

Henkel
Revision Number: 004.1 Issue date: 09/18/2009

Product name: ALODINE 1000 RTU IDH number: 598168

Product type: Coating
Region: United States
Company address: Contact i n f o r m a t i o n :
Henkel Corporation Teiephone: 248.583.9300
32100 Stephenson Highway For Chemical Emergency Call CHEMTREC at 800.424.9300
Madison Heights. Mi 48071 internet: www.henkelna com

EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: '2
Color: Orange FLAMMABILITY: 0
Odor: Odorless PHYSICAL HAZARD: 0
Personal Protection: See MSDS Section 8
WARNING: CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
POSSIBLE CANCER HAZARD.
Relevant routes of e x p o s u r e : Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: Prolonged or repeated breathing may cause ulceration of nasal membranes.

Skin contact: Product contains chromium, which may cause an allergic skin sensitization reaction. Liquid or
vapor can cause fluoride-type irritation or burns which may not be immediately painful or
visible. Prolonged or widespread contact may result in the absorption of potentially hannful
amounts of material.
Eye contact: This product may be severely irritating to the eyes.
Ingestion: Acute ingestion may result in mild gastrointestinal distress.

Existing conditions aggravated by Eye, skin and respiratory disorders.

exposure:

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910 1200).

See Section 11 for additional toxicological Information.

Hazardous c o m p o n e n t s CAS NUMBER %

Chromic a d d 7738-94-5 0.1-1
Dipotassium tiexafiuorozirconate 16923-95-8 0.1-1

fURE! m:^^_s2
Inhalation: If mist or vapor of this product is inhaled, remove person immediately to fresh
air. Seek medical attention if symptoms develop or persist.

IDH number: 598168 Product name: ALODINE 1000 RTU

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 Skln contact: Remove contaminated clothing and footwear. For skin contact, flush with large
amounts ofwater. Seek immediate medical attention. Discard any shoes or
clothing items that cannot be decontaminated.

Eye contact: In case of contact with the eyes, rinse immediately wilh plenty of water for 15
minutes, and seek immediate medical attention.

Ingestion: Get immediate medical attention. Do nol induce vomiting. Give one lo two
glasses of water or milk. Never give anything by mouth to a victim who is
unconscious or is having convulsions.

Notes to p h y s i c i a n : Treat symptomatically and supportiveiy.

5. FIRE FIGHTING M E A ^ i f ^
Flash point: Not applicable

A u t o i g n i t i o n temperature: Not applicable

Flammable/Explosive limits • lower: Not applicable

Flammable/Explosive limits - upper: Not applicable

Extinguishing media: Use media appropriate for surrounding material.

Special firefighting procedures: Wear full protective clothing. Wear self-contained breathing apparatus.

Unusual fire or explosion hazards: This product is an aqueous mixture which will not burn.

Hazardous c o m b u s t i o n p r o d u c t s : Irritating and toxic gases or fumes may be released during a fire.

Use personal protection recommended In Section 8, isolate the hazard area and deny entry t o unnecessary and unprotected
personnel.

Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate
protective equipment and clothing during clean-up.

Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for
disposal. Dispose of according to Federal, Stale and local governmental
regulations.

Tlf^W^. L\HQ AND ST01

Handling: Avoid contact with eyes, skin and clothing. Wash thoroughly afler handling.

Storage: For safe storage, store at or above 40 ' F (4.4 °C)

Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

Employers s h o u l d complete an assessment of all workplaces to determine the need for, a n d selection of, proper exposure
controls and protective equipment for each task performed.

IDH number: 598168 Product name: ALODINE 1000 RTU

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Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER
0.1 mg/m3 Ceiling
0.005 mg/m3 TWA
Chromic acid 0,05 mg/m3 TWA (SKIN)
None None
(as Cr) 0.0025 mg/m3
OSHA ACT
29 CFR 1910.1026
5 mg/m3 TWA (as 5 mg/m3 TWA (as
Zr) Zr)
Dipotassium hexafluorozirconate 10mg/m3STEL 2.5 mg/m3 TWA
(as Zr) None None
Dust.
2.5 mg/m3 TWA 2.5 mg/m3 TWA
(asF) (asF)

Engineering c o n t r o l s : Provide local and general exhaust ventilation to effectively remove and
prevent buildup of any vapors or mists generated from the handling of this
product.

Respiratory p r o t e c t i o n : If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or

vapors, appropriate NIOSH/MSHA respiratory protection must be provided.

Eye/face protection: Wear chemical goggles; face shield (if splashing is possible).

Skin protection: Chemical resistant, impermeable gloves. Use of impervious apron and boots
are recommended.

AND CHEMICAL
physical state: Liquid
Color: Orange
Odor; Odoriess
Odor t h r e s h o l d : Not available
pH: 1.7-2.2
Vapor pressure: Not detemiined
Boiling point/range: >100°C(>212T)
Melting point/ range: 3 0 ° F ( - 1 . 1 °C)
Specific gravity: 1.00-1.02
Vapor density: Not determined
Flash point: Not applicable
Flammable/Explosive limits • lower: Not applicable
Flammable/Explosive limits • upper: Not applicable
A u t o i g n i t i o n temperature: Not applicable
Evaporation rate; Not determined
Solubility in water: Complete
Partition coefficient (n-octanol/water): Not determined
VOC content: Not applicable

Stability Stable at normal conditions.

Hazardous reactions: Will not occur.

Hazardous d e c o m p o s i t i o n p r o d u c t s : Upon decomposition, this product emits carbon monoxide, carbon dioxide
and/or low molecular weight hydrocarbons.

Incompatible materials: Avoid contact with organic materials, oils, greases, and any oxidizable
materials. Keep away from alkalis.

Conditions to a v o i d : Do not allow chemical to dry in the presence of organic materials.

IDH number: 598168 Product name: ALODINE 1000 RTU

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 OSHA Carcinogen
Hazardous c o m p o n e n t s NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Chromic acid Known carcinoqen. Group 1 Yes
Dipotassium he^fafluorozirconate No No No

Hazardous c o m p o n e n t s Health Effects/Target Organs

Allergen, Blood, Carcinogen, Central nervous system. Corrosive.
Chromic acid Developmental, Eyes, Gastrointestinal, Irritant. Kidney, Liver, Mutagen,
Reproductive, Respiratory
Allergen, Blood, Cardiac, Central nervous system. Corrosive, Gastrointestinal
Dipotassium he^^afluorozirconate tract. Irritant, Kidney, Lung, Metabolic, Muscle, Teeth, Less weight gain and
food intake.

Ecological i n f o r m a t i o n : Not available

13. fPISROSAL CONSIDEfWfU

Information provided is for unused p r o d u c t only.

Recommended method of d i s p o s a l : Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: This product contains chromium which is a hazardous waste (D007). This
producL if discarded, may be characterized as a RCRA corrosive waste,
D002.

The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging
as exceptions may apply. Refer to shipping documents for package specific transportation classification.

U.S. Department of Transportation Ground (49 CFR>

Proper s h i p p i n g name: Environmentally hazardous substances, liquid, n.o.s.
Hazard class or d i v i s i o n : 9
Identification number: UN 3062
Packing g r o u p : III
DOT Reportable quantity: Chromic acid

International Air Transportation nCAO/IATAl

Proper s h i p p i n g name: Environmentally hazardous substance, liquid, n.o.s.
Hazard class or d i v i s i o n : 9
Identification number: UN 3082
Packing g r o u p : 111

Water Transportation (IMO/IMDGl

Proper s h i p p i n g name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard class or d i v i s i o n : 9
Identification number: UN 3082
Packing g r o u p : III

United States Regulatorv Information

TSCA 8 (b) Inventory Status: All componenls are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12(b) Export Notification: Chromic acid (CAS# 7738-94-5).

CERCLA/SARA Section 302 EHS: None above reporting de minimus

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health

IDH number: 598168 Producl name: ALODINE 1000 RTU

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 CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 ofthe Emergency Planning and Community Right-To-Know Act of 1986(40
CFR 372). Chromic acid (CAS# 7738-94-5).
CERCLA Reportable quantity: Chromic acid (CAS# 7738-94-5) 10 lbs. (4.54 kg)

California Proposition 65: This product contains a chemical known in the Stata of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada ReQulatorv Information

CEPA D S U N D S L Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
WHMIS hazard class: D.2.A, D.2.B. E

This material safety data sheet contains changes f r o m the previous version in s e c t i o n s : New Material Safety Data Sheet
format.

Prepared b y : John DiCerbo. Regulalory Affairs Specialist

DISCLAIMER: The data contained herein are f u r n i s h e d for information only a n d are believed to be reliable. However,
Henkel Corporation does not assume responsibility for any results obtained by persons over w h o s e methods Henkel
Corporation has no c o n t r o l . It Is the user's responsibility t o determine the suitability of Henkel's products or any
p r o d u c t i o n methods mentioned herein for a particular purpose, and to adopt s u c h precautions as may be advisable for the
protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel
Corporation's p r o d u c t s . In light of the f o r e g o i n g , Henkel Corporation specifically disclaims all warranties, express or
implied, including warranties of merchantability a n d fitness for a particular purpose, arising f r o m sale or use of Henkel
Corporation's products. Henkel Corporation further disclaims any liability f o r consequential or incidental damages of any
k i n d . Including lost profits.

IDH number: 598168 Productname ALODINE 1000 RTU

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