CHEMISTRY

Syllabus : Basic concepts of chemistry : Concepts of atoms and molecules, Dalton’s atomic theory,
Chemical formulae, Concentration in terms of mole fraction, molarity, molality and normality

Section - I : Straight Objective Type

1. The element whose atom has mass of 10.86 × 10–26 kg is
(a) Boron (b) Calcium (c) Silver (d) Zinc
2. The sulphate of a metal M contains 9.87% of M. This sulphate is isomorphous with ZnSO 4. 7H2O. The atomic weight
of M is –
(a) 40.3 (b) 36.3 (c) 24.3 (d) 11.3
3. A gaseous hydrocarbon was mixed with 7.5 times its volume of oxygen and exploded. The residual gas occupied 5
times the volume of the hydrocarbon. On passing through KOH solution, there was further contraction of 4 times the
volume of the hydrocarbon. The simplest formula of the hydrocarbon is
(a) C4H10 (b) C4H8 (c) C4H6 (d) C4H4
4. Naturally occurring chlorine is 75.53% Cl35 which has an atomic mass of 34.969 amu and 24.47% Cl 37 which has a
mas of 36.966 amu. Calculate the average atomic mass of chlorine-
(a) 35.5 amu (b) 36.5 amu (c) 71 amu (d) 72 amu
5. The molarity of a solution is always related with molality as-
(a) Molarity is always greater then molality (b) Molarity is always less than molality
(c) Molarity is equal to molality (d) Molality can not be determined in every cases
6. 5 gm of a metal give 6.35 of its oxide. Calculate the equivalent weight of metal.
(a) 63.5 (b) 29.63 (c) 30.0 (d) 28.63
7. An atom of element ‘X’ is 1.02 times heavier than that of an atom of ‘Y’. An atom of ‘Y’ is 0.1809 times heavier than
that of an atom of oxygen. What is the atomic weight of ‘X’?
(a) 2.952 (b) 5.314 (c) 4.4 (d) 2.6
8. CH3COOH exists as dimer in benzene, 1.2 gm of the acid was dissolved and he volume was made up to one litre by
benzene, what is the formality :–
(a) 0.1F (b) 0.01F (c) 1F (d) 10F
9. An excess of NaOH was added to 100 mL of a ferric chloride solution. This caused the precipitation of 1.425 g of
Fe(OH)3. Calculate the normality of the ferric chloride solution
(a) 0.20 N (b) 0.50 N (c) 0.25 N (d) 0.40 N
10. 25 mL of a solution containing HCl and H2SO4 required 10mL of a 1 N NaOH solution for neutralization. 20 mL of
the same acid mixture on being treated with an excess of AgNO 3 gives 0.1435 g of AgCl. The normality of the HCl
and the normality of the H2SO4 are respectively
(a) 0.40 N and 0.05 N (b) 0.05 and 0.35 N (c) 0.50 N and 0.25 N (d) 0.40 N and 0.50 N
 Section - II : Multiple Correct Answer Type

11. A solution is made by mixing of 5.6 V & 11.2 V H 2O2

(a) 8.4 V (b) 1.5 N (c) 4.8 V (d) 1 N
12. A sample of H2O2 solution labeled as “28 volume” has density of 26.5 g/L. Mark the correct option(s) representing
concentration of same solution in other units:
w
(a) MH2O2  2.5 (b) %  17
v
(c) Mole fraction of H2O2 = 0.2 (d) MH2O2  13.88
13. A 100 ml mixture of CO and CO2 is passed through a tube containing red hot charcoal. The volume now becomes 160
ml. the volumes are measured under the same conditions of temperature and pressure. Amongst the following, select
the correct statement(s).
(a) Mole percent of CO2 in the mixture is 60. (b) Mole fraction of CO in the mixture is 0.40
(c) The mixture contains 40 ml of CO2 (d) The mixture contains 40 ml of CO
14. For the reaction, Fe0.95O (molar mass: M) x – Fe2O3. What is the eq. wt. of Fe0.95 O?
M M M
(a) (b) (c) (d) None of these
0.85 0.95 0.8075
15. Dichromate ion in acidic medium oxidizes stannous ion as:
xSn2+ + yCr2 O 72  + zH+ 
 aSn4+ + bCr3+ + cH2O
(a) the value of x : y is 1 : 3 (b) the value of x + y + z is 18
(c) a : b is 3 : 2 (d) the value of z – c is 7

Section - III : Matrix-Match Type

16. Match the following:

Column I Column II
A. 4.5 m solution of CaCO3 density 1.45 gm/ml p. mole fraction of solution is 0.2
B. 3 M 100 ml H2SO4 mixed with 1 M 300 ml H2SO4 q. mass of the solution is 360 gm
solution
C. 14.5 m solution of Ca r. molarity = 4.5
D. In 4M, 2 litre solution of NaOH, 40 gm NaOH is s. molarity = 1.5
added.
17. 90 gm of NaOH is dissolved in 180 g water to prepare a solution of density 2.7 g/ml. Then match column I with
column II.
Column I Column II
A. % w/w p. 90
B. Mole fraction of solvent q. 22.5
C. % w/v r. 33.33
D. Molarity s. 0.816
 Section – IV Linked Comprehension Type
Molality : It is defined as the moles of the solute present in 1 kg of the solvent. It is denoted by ‘m’.
Number of moles of solute
Molality (m) =
Number of kilograms of the solvent
Let wA grams of the solute of molecular mass mA be present wB grams of the solvent, then
wA
Molality (m) = 1000
mA  w B
Relation between mole fraction and Molality :
n N
XA  and X B 
Nn Nn
XA n Moles of solute w A  mB
  
X B N Moles of solvent w B  m A
X A 1000 w A 1000 X A 1000
  m or m
X B  mB w B  mA (1  X A )mB
1 1
18. If the ratio of the mole fraction of a solute is changed from to in the 800 g of solvent then the ratio of molality
3 2
will be :
(a) 1 : 3 (b) 3 : 1 (c) 4 : 3 (d) 1 : 2
19. The mole fraction of the solute in the 12 molal solution of Na2CO3 is :
(a) 0.822 (b) 0.177 (c) 1.77 (d) 0.0177
20. What is the quantity of water that should be added to 16 gm, methanol to make the mole fraction of methanol as 0.25–
(a) 27 gm. (b) 12 gm. (c) 18 gm. (d) 36 gm.

Section - V : Reasoning Type

DIRECTIONS for (Qs. 21 to 24) : Each of these questions contains two statements: Statement-1 (Assertion) and
Statement-2 (Reason). Each of these questions has four alternative choices, only one of which is the correct answer.
You have to select the correct choice.
(a) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(b) Statement -1 is True, Statement-2 is True; statement-2 is NOT a correct explanation for statement-1.
(c) Statement-1 is True, Statement-2 is False.
(d) Statement-1 is False, Statement-2 is True.
21. Statement-1 : Molarity decreases with increase in temperature.
Statement-2 : Volume of solution increase with temperature.
22. Statement-1 : One atomic mass unit (amu) is mass of an atom equal to exactly one-twelfth the mass of a
carbon -12 atom.
Statement-2 : Carbon - 12 isotope was selected as standard.
23. Statement-1 : 1 amu equals to 1.66 × 10–24 g.
1
Statement-2 : 1.66 × 10–24 g equals to th of mass of a C12 atom.
12
24. Statement-1 : 0.1 M H3PO3(aq) solution has normality equal to 0.3 N when completely reacted with NaOH.
Statement-2 : H3PO3 is a dibasic acid.
 Solution
1. (d) 1 atm has mass = 10.86 1026 kg  10.86 1023 gm
6.0231023 atoms has mass
 10.86 1023  6.023  65.40gm
This is the atomic weight of Zn.
2. (c) As the given sulphate is isomorphous with ZnSO4  7H2 O its formula would be MSO4  7H 2 O . If m is
the atomic weight of M, molecular weight of MSO4  7H2 O  m  32  64  126  m  222
m
Hence % of M  100  9.87 (given)
m  222
or 100 m = 9.87m + 222 × 9.87 or 90.13m = 222 × 9.87
222  9.87
or m   24.3
90.13
3. (a)  xCO2 ( H 2 O) given xV  4V
Cx H y (O 2 ) 
x4
V xV
Contraction in volume after explosion
 (V  7.5V)  5V  3.5V
i.e., (volume of CxHy) + (volume of reacting O2)
= (volume of CO2) = 3.5V
V + (volume of reacting O2)  4V = 3.5V
volume of reacting O2 = 6.5V
 1 molecule of C4 H y  6.5 molecules of O2
  4 molecules of CO2 + (?) molecules of H2O
No. of molecules of H2O = 5  y = 10
C x H y is C4 H10 .
4. (a) Average atomic mass
% of 1 isotope×its atoms mass
+ % of II isotope × its atomic mass

100
75.53  34.969  24.47  36.96
  35.5 amu
100
M  103
5. (d) m where M is morality,
(10 s  MM )
3

M is the mol. wt of solute and m is the molality

If 103 s  MM  , the value of m will be undefined, therefore molality cannot determined in every
cases.
6. (b) Weight of metal = 5 gm
Weight of oxide = 6.35 gm
weight of metal 5
 Equivalent weight of metal  8   8  29.63
weight of oxygen 1.35
So equivalent weight of metal is 29.63.
 wt. of an atom of X wt. of an atom of Y
7. (a) Atomic wt. of X = ×
wt. of an atom y 1
× wt. of an atom O
16
 1.02 16  0.1809  2.952

8. (b) Molecular weight of CH3COOH = 60

Formula weight of the associated molecule of the acid = 2 × 60 = 120
Weight of CH3COOH = 1.2 gm
Volume of solution = 1 litre.
1.2 1
Formality =   .01F
120 1
9. (d) 3NaOH  FeCl3 
 Fe(OH)3  3NaCl
milli equivalents of NaOH = milli equivalents of Fe(OH)3
W  mol.wt 
100  N  1000  E Fe(OH3 )  
E  3 
1.425  10  3
N  0.399  0.4N
107
10. (b) Let normality of HCl is N1 and H2SO4 is N2.
 milli equivalents of HCl + milli equivalents of H2SO4 = milli equivalents of NaOH
25  N1  25  N2  10 1
N1  N 2  0.4
By atom conservation
Moles of Cl = moles of AgCl
20  N1 0.1435
  103
1000 143.5
11. (a,b) 5.6V H2 O2  N1  1N
11.2V H2 O2  N 2  2N
1 1  2  1
Normality of H2O2 mixture   1.5N
11
12. (a,c,d) Vstrength  56
28
 M  2.5
11.2
 1 L contain 2.5 moles of H2O2
or 2.5 × 34 = 85 g H2O2
wt. of 1 litre solution = 265 g ( d  265 g / L)
 w H2O  180g or moles of H2O = 10
2.5
x H 2 O2   0.2
2.5  10
w 2.5  34
%   100  8.5
v 1000
2.5
m  1000  13.88
180
13. (a,b,d) CO 2(g)  C(s)  2CO(g) ; Volume of CO2  x ml, volume of CO  100  x
Final volume = 100  x  2x  160  x  60ml;
 Volume of CO = 100  60 = 40ml
40
Mol fraction of CO   0.4 ;
100
Mol % of CO2 = 60
n-factor =  3 
2 
14. (a)   0.95  0.85
 0.95 
M
 E
0.85
15. (b,c,d) 3Sn 2   14H   Cr2 O72  
 3Sn 3  2Cr 3  7H 2 O
16. A  r;B  s;C  p;D  q,r
A. 4.5 m, CaCO3 means 4.5 moles of CaCO3 is present in 1000 g solvent.
mass of solute = 4.5 × 100 = 450 g
 Given mass of solvent = 1000 gm
now given d = 14.5 gm/ml
mass of solution
 volume =
density of solution
1450

1.45
= 1000 ml
 volume of solution = 1000 ml
mass of solution = 1450 gm
Hence molarity = 4.5 M
3 100  1 300 3
B. Resultant molarity    1.5M
400 2
14.5
C. Mole fraction   0.2
14.5  55.5
D. Moles of NaOH in 2 ltr = 4 × 2 = 8 mole
40
Moles of NaOH added   1 mole
40
9
 Molarity   4.5 M
2
Mass of NaOH = 9 × 40 = 360 g
17. A  r;B  s;C  p;D  q
weight of solute
A. %w/w  100
weight of solute + weight of solution
90
  100  33.33%
90  180
90
B. moles of NaOH   2.5 ;
(n ) 40
180
moles of Water   10
(N) 18
N 10 10
Mole fraction of solvent     0.8
n  N 10  2.5 12.5
weight of solute
C. % w/v =  100
volume of solution
 Total mass of solution = 90 + 180 = 270
density of solution given = 2.7 g/ml
270
 Volume of solution =   100 ml
2.7
90
% w/v =  100  90
100
90 1000
D. Molarity    22.5
40 100
X A  1000
18. (d) molality 
(1  X A )m B
1
100
m1  3  1/16
 1
 1    800
 3
1
1000
1
m2  2 
 1 8
1    800
 2 
m1 1 1 1
 / 
m2 16 8 2
19. (b) mNa2CO3  12 , n Na2CO3  12
1000
n H2 O   55.55
18
12
x Na 2 CO3   0.177
12  55.55
20. (a) Let W water is added to 16 g CH3OH
10 1000 500
Molality = 
W  32 W
500 X A 1000 0.25 1000
   W  27 gm
W (1  X A )mB 0.75 18
mass of solute×1000
21. (a) Molarity 
molecular mass of solute× volume of solution in ml
22. (a) For universally accepted atomic mass unit in 1961, C-12 was selected as standard. However, the
new symbol used is ‘u’ (unified mass) in place of amu.
23. (a) 12g of C-12 contain 6.023 × 1023 atom
12
  1023  1.66  1024
6.023
24. (b) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.