PERODIC PROPERTICS Page # 41

ANSWER-KEY

Exercise-I

1. D 2. C 3. D 4. D 5. 72

6. (a) d block, (b) d block, (c) p block, (e) f block

7. 101 102 103 104 105 106 107 108 109

Unu Unb Unt Unq Unp Unh Uns Uno Une

8. A 9. C 10. C 11. C 12. C 13. A

14. C 15. A 16. C 17. B 18. A 19. B

20. Zeff & half filled config. 21. O

22. N3– > O2– > F– > Na+ > Mg2+ 23. Isolelectronic Ca+2 (higher) 24. Fe3+, CO2+

25. difference in 1E1 & 1E2 is less than 10ev.

26. (a) F (b) O (c) Cl– 27. half filled and fully filled orbitals.

28. (i) Cl (ii) Cs (iii) Al (iv) F (v) Xe

29. Increases  a, b, e, g, h Decrease  c,d Same  f

30. half filled & fully filled orbitals

31. Cs > Na > Mg > Si > Cl 32. rk > 1.34 Å > rF 33. No 34. ICl

35. (a) P – Cl (b) S – O, (C) N – F 36. He < Ne < Ar < Kr < Xe < Rn

37. 3.03 (Pauling) 38. 3.8752 39. 3.2

40. IE2 = 1825 kJ/mole, IE3 = 2737.5 kJ/mol

41. 1.686 × 1023 atom 42. 3.476 eV 43. EN1 > EN2

44. 1.21 Å 45. 4.64 Å ; b = 3.28 Å

46. F = 37.81%, Cl = 62.19 %

47. (a) Al+3 > Mg+2 > Na+, (b) Al+3 > Mg+2 > Na+, (c) Al+3 > Mg+2 > Na+, (d) Na+ > Mg+2 > Al+3,

(e) Na+ > Mg+2 > Al+3

48. Li2O < BeO < B2O3

basic amphoteric acidic

49. BaO 50. False

51. (a) basic (b) acidic (c) basic (d) acidic (e) basic (f) acidic

58. –185 kcal/mole 59. +73.2 kcal/mole

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053 www.motioniitjee.com, email-info@motioniitjee.com
Page # 41 PERODIC PROPERTICS

Exercise-II
1. B 2. A 3. C 4. C 5. A 6. A

7. C 8. A,C 9. Zeff = 4.3

10. (a) IE1 of A = 350 kJ/mol, (b) IE2 = 600 kJ/mol, (c) EG H of A = –450 kJ/mol,

(d) ME H of (A2+) = –250 kJ/mol.

11. –780, –420, AB > CD 12. D 13. C

14. (a) 5.919 Å, (b) CaO < CO < CO2 < N2O5 < SO3

15. (a) Acids : HBO, HDO and order of acidic strength HDO > HBO

(b) Bases : AOH, COH and order of basic strength AOH < COH

(c) % Ionic character = 16 |XA – XB| + 3.5 (XA – XB)2

for CD = 16(1.2) + 3.5 (1.2)2 = 24.24 %  colourless

AB = 16 × 0.8 + 3.5 (0.8)2 = 15.07 % coloured

16. (i) –230 kJ, (ii) –40, (iii) 90, (iv) 110, (v) –20 kJ

Exercise-III
1. A 2. C 3. C 4. A 5. D 6. A

7. D 8. A 9. B 10. A,D 11. Al+3 < Mg2+ < Li+ < K+

12. Ionic 13. A,B,C 14. C 15. C 16. B 17. A

18. True 19. B 20. B 21. A

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053 www.motioniitjee.com, email-info@motioniitjee.com