MUTS(JEE)–5/27-12-2015

1. Which of the following compounds can be best CH 3  CH  CO2K

prepared by Wurtz-reaction 5. |
electrolys
is
(Major)
CH 3  C H  CO2K    (A)
(a) Iso-butane (b) n-butane
Major product (A) of the above reaction
(c) n-pentane (d) Iso-pentane
2. Ethyl iodide and n-propyl iodide are allowed to (a) (b)
undergo Wurtz reaction. The alkane which
will not be obtained in this reaction is (c) (d)
(a) Butane (b) Propane
H possible
products Br / CCl
6.   2 
4
(y)
(c) Pentane (d) Hexane OH (x)
products

Cl (excess
) / hv
3. 2  The number of possible products for x and y
is
How many dichloro products are formed in
the above reaction (including stereoisomers) (a) 2, 4 (b) 3, 5
(c) 3, 6 (d) 3, 4
(a) 5 (b) 6
(c) 7 (d) 9
7.
4. Which of the following is a major product of the
(a) (b) (c) (d)
reaction shown below
CH 3 The correct order of heat of hydrogenation of
Br2 given molecules is
H 2O (a) d  c  a  b (b) d  c  b  a
(c) b  a  c  d (d) d  a  c  b

CH 3 CH 3 CH 3
|
Br OH C  C H2
(a) (b) 8. A
OH Br  HBr (Major)
H H
Product (A) is
Br
CH 3 CH 3 (a) Br (b)
Br OH Br
(c) (d) Br
H H
OH Br (c) (d)

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2 Chemistry

9. Decreasing order of rate of reaction of CH 3

molecules towards electrophilic addition (b) CH 3  CH 2  CH 2  CH 2  CH  C
CH 3
reaction is
CH 3  CH 2  CH 2  CH 2  C  C H 2
(c) |
CH  CH 2 CH  CH 2 CH  CH 2 CH  CH 2 CH 3
CH 3
|
(d) CH 3  CH 2  C H  CH 2  C  C H 2
|
NO2 OH CH 3 NH 2 CH 3
(a) (b) (c) (d)
(a) a  b  c  d (b) b  c  a  d O O
|| ||
(1)O3
(c) d  b  c  a (d) b  d  c  a  H  C  C  H 
12. (2) Zn
Glyoxal

10. For the following reactions the major products are

O O O O
shown || || || ||
CH 3  C C  CH 3  CH 3  C  C  H
HBr
H 2C  CH  CH  CH 2  H 2C  CH  C H  CH 3 2, 3- Butanedion
e Pyrualdehy
de
0ºC |
Br
What is the ratio of glyoxal to pyrualdehyde
25º C
  C H 2 CH  CHCH 3 obtained in the above reaction
|
Br (a) 1 : 3 (b) 3 : 1
(c) 3 : 2 (d) 2 : 3
These provide an example of 1 control at low
temperature and 2 control at higher
temperature OH
1 2 H 
( A)
13.  (major)

(a) Kinetic Thermodynamic
Product (A) is
(b) Thermodynamic Kinetic
(c) Kinetic Kinetic
(d) Thermodynamic Thermodynamic (a) (b)

CH 3
| 
H
11. CH 3  CH 2  CH 2  CH 2  C  CH 2  OH 
|
CH 3 (c) (d)

(A) 14. Which of the following is most likely to undergo

(major) ; product (A) is
a favorable hydride shift
CH 3  CH 2  CH 2  CH 2  C  C H  CH 3
(a) |
CH 3 (a) (b)
 
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 Chemistry 3

(c) (d)
 (c) (d)
Mg Hg Dil.H SO

2Ph  C  CH 3     2 

4

15. || H 2O product
O 18. Predict the product C obtained in the following
The main product is reaction of butyne–1
HI
CH 3CH 2— C  CH  HCl  B 
 C
Ph  C  C  Ph CH 3  C  C  CH 3
(a) || || (b) || ||
(a) I (b)
O O O O

Ph
|
(c) Ph  C  C  CH 3 (d) (c) (d)
| ||
CH 3 O
19. In the following reactions,
Ph (1)
|
Ph  C  C  CH 3
|| |
O CH 3
16. CH 3 — CH  CH 2  NOCl  P . Identify the
adduct (2)

(a) (b) The major products (A) and (C) are

respectively

(a)
(c) (d)

(b)
17. In the following reaction :

[CBSE PMT (Pre.) 2012]

(c)

(d)
The major product is
20. Acetylene on passing into excess of HOCl
(a) (b) solution forms
(a) Ethylene chlorohydrin (b)
Acetaldehyde
(c) Dichloroacetaldehyde
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4 Chemistry

(d) Methyl chloride

21. Products of the following reaction The major product is
CH 3 C  CCH 2CH 3 (2)(1) O3 …….. are
(a) CH 3CHO  CH 3Hydrolysis
CH 2CHO (a) (b)
(b) CH 3 COOH  CH 3 CH 2CHO
(c) CH 3COOH  HOOCCH 2CH 3
(c) (d)
(d) CH 3COOH  CH 2
22. The number of   bonds
in the product H H
formed by passing acetylene through dilute 26. C C + Br2
sulphuric acid containing mercuric sulphate CH 3 CH 3
is
CCl4
(a) Zero (b) One
P
(c) Two (d) Three
(Major)
23. H 2C  CH  C  CH  HCl  X;' X ' is

Cl P should be
(a) |
CH 3
H 3C  C H  C  CH CH 3
Br
(a) H only (b) H Br only
H 2C  CH  C  CH 2 H Br Br
(b) | H
Cl CH 3 CH 3
Cl
(c) |
CH 3  C H  C  CH CH 3
Br H
Cl
| (c) H Br only
(d) CH 3  C H  C  CH 2 CH 3
|
Cl (d) A mixture of (b) and (c)
24. The order of reactivity of following alcohols
toward HCl is :

CH 3  C  CH 2
| H P
F OH F
OH OH
Ph OH
4
27.
CH 3 MeOH
1 2 3
(a) 1 > 2 > 3 > 4 (b) 1 > 3 > 2 > 4 P should be
(c) 4 > 3 > 2 > 1 (d) 4 > 3 > 1 > 2
CH 3  C H  CH 2  OCH 3
(a) |
CH 3
Conc.H 2SO4
25. OH
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 Chemistry 5

O CH 3
|
(b) CH 3  C  CH 3
|
CH 3

(c) Both of these

(d) None of thse

28. Ph  C  C  CH 3

1.
2. CH 3
|
(c) CH 3  C  C H C H2
| | |
P CH 3 OH Cl
P should be
O CH 3
(a) || (b) |
Ph  C  CH 2  CH 3
(d) CH 3  C  C H C H2
| | |
O CH 3 Cl OH
||
Ph  CH 2  C H 3
(c) Both in equal proportion HBr / H 2O
30. C6 H 5  CH 2  CH  CH 2    
(d) None of these Major product

C6H 5  CH 2  C H  CH 3
CH 3 (a) |
| Br
HOCl
29. CH 3  C  CH  CH 2  

|
CH 3
(b) C6H 5  CH 2  CH 2  CH 2  Br

CH 3
|
(a) CH 3  C  C H 2  CH 2  Cl C6 H 5  C H  CH 2  CH 3
|
(c) |
OH OH

(d) C6H 5  CH 2  CH 2  CH 2  OH
CH 3
|
(b) CH 3  C  C H 2  OH
|
Cl

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6 Chemistry

ANSWERSHEET
1 2 3 4 5 6 7 8 9 10
b b c d c b c a c a
11 12 13 14 15 16 17 18 19 20
b c b a c a a d c c
21 22 23 24 25 26 27 28 29 30
c b b c c d b a c c

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