PART- I - PHYSICS

SECTION - I
Straight Objective Type
This section contains 10 multiple choice questions. Each question has choices (A), (B), (C), (D) and
(E) out of which ONLY ONE is correct.

1. A block of mass m is connected to a spring ( spring constant k ) . Initially the block is

at rest and the spring is in its natural length. Now the system is released in gravitational
field and a variable force F is applied on the upper end of the spring such that the
downward acceleration of the block is given as a = g –t, where t is time elapses and
 = 1 m/s3 , the velocity of the point of application of the force is :
m t 2 m t 2
(A)  gt  (B)  gt 
k 2 k 2
m t 2 m
(C)  gt  (D)  gt  t 2
k 2 k

2. A rod P of length 1m, is hinged at one end A and there is a ring attached to the other end. Another long rod
Q is hinged at B and it passes through the ring. The rod P is rotated about an axis which is perpendicular to
plane in which both rods are present and the variations between the angles  and are plotted as shown.The
distance between the hinges A and B is:

(A) 3m (B) 1m (C) 2 m (D) 3m

3. STATEMENT-1 : In photoelectric experiment the ejected electrons have same kinetic energy.
STATEMENT-2 : According to Einstein kinetic energy of every ejected electron is the difference in the energy
of a photon and the work function of the metal.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is False, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.


4. A force given by F  fx î  fy ĵ  fzk̂ acts on a particle which moves from (a,b,c) to (d,e,f) . The work done by
the force F is : (Here A1 , A2, A3 are magnitude of area bounded)

(A) A1 + A2 + A3 (B) A1 – A2 – A3 (C) –A1 + A2 – A3 (D) A1 – A2 + A3

 PHYSICS

5. In a box of liquid of density  , there is a fixed sphere of density 2. From

the point P the center of the sphere is 3m while the height of the box is 4m.
The mass of the liquid is 5 kg while that of the sphere is 2 kg. The height of
the center of mass of the liquid and the sphere system, with respect to the
point P is :
(A) 12/7 m (B) 15/7 m
(C) 16/7 m (D) None of these

6. A disc of mass m and radius R, is placed on a smooth fixed surface. Point A is the geometrical center of disc
while point B is the center of mass of the disc.The moment of inertia of the disc about an axis through its
center of mass and perpendicular to the plane of the figure is . A constant force F is applied on the top of the
disc. The acceleration of the center A of the disc at the instant B is below A (on same vertical line) will be :

F F 3FR 2 F FR 2 F 3FR 2
(A) (B)  (C)  (D) 
m m 4I m 4I m I

7. A trolley is moving with a velocity v. There is a smooth circular tube fixed in

the trolley having a small sphere resting at the bottom. Now the trolley is
uniformly decelerated until it comes to stop. During the deceleration the
sphere moves by an angle  and acquires sufficient speed so that it just
completes the vertical circle in the tube. The magnitude of the deceleration
of the trolley is :
g g
(A) (B)
sin  sin2 
2g 2g
(C) (D)
cos  sin 

8. A steel rod is projecting out of a rigid wall. The shearing strength of steel is
345 MN/m2.The dimensions AB = 5 cm , BC = BE = 2 cm . The maximum load that
can be put on the face ABCD is:(neglect bending of the rod) (g = 10 m/s2)
(A) 3450 Kg
A B
(B) 1380 Kg
D
C
(C) 13800Kg E
F
(D) None of these
 PHYSICS

9. 4 moles of H2 at 500 K is kept in an adiabatic rigid container. After some time it was found that 1 mole of the
gas dissociated into H atoms . The dissociation energy per mole of H2 gas is 2000 cal,Let the new temperature
of the gas be 100T. The integral value of T is : (Use R= 2cal/mole-K)
(A) 3 (B) 4 (C) 5 (D) 6

10. Electric field in a region is given as E  x î  2yĵ  3k̂ in this region point A(3,3,1) and point B (4,2,1) are
there.The magnitude of work done by the electric field, if 2 coulomb charge is moved from A to B. All values
given and asked are in SI units.
(A) 3 (B) 4 (C) 5 (D) 6

SECTION - II
Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, 2 multiple choice questions have to
be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 11 to 12

In the ac circuit shown, XL=7 ,R = 4  and XC= 4 .The reading of the ideal voltmeter V2 is 8 2.

11. The reading of the ideal ammeter will be:

1
(A)1 A (B)2A (C) 2 A (D) A
2
12. The reading of idea voltmeter V1 will be :
(A) 20 volt (B) 7 volt (C) 8 volt (D) 10 volt

Paragraph for Question Nos. 13 to 14

See the adjoining circuit .Mark the correct options.

13. The current through the cell just after closing the switch S is :
 2  
(A) (B) (C) (D)
R R 3R 2R
14. The current through the cell long after closing the switch S is :
3  3 
(A) (B) (C) (D)
5R 5R R R
 PHYSICS

Paragraph for Question Nos. 15 to 16

Two coherent point sound sources S1 and S2 are placed as shown in the figure. Both are emitting sound of
frequency 165 Hz. S1 is ahead of S2 in phase by -radian. (Speed of sound is 330 m/s)

15. How many times maximum sound can be observed on line AB :

(A) 7 (B) 6 (C) 5 (D) 11

16. If power of sources are same and equal to 7200  watt. Resultant intensity (in watt/m2) at point B will be :
(A) ( 50  18 )2 (B) ( 30  18 )2 (C) ( 50  18 )2 (D) None of these

SECTION - III
Integer Answer Type

This section contains 6 questions. The answer to each of the questions is

a single digit integer, ranging from 0 to 9. The appropriate bubble below the
respective question number in the ORS have to be darkened.

17. An electric dipole (dipole moment = p) is placed in a uniform electric field in stable equilibrium position at
rest. Now it is rotated by a small angle and released . The time after which it comes to the equilibrium
t 2 pE
position again (for first time) is t. If the moment of inertia of the dipole about the axis of rotation is x ,
2
then find the value of x.

18. Monochromatic light of wavelengthpasses through a pair of slits S1 and S2 ,separated by a distance equal

to fringe width . There is a screen placed at a distance D in which two parallel slits S 1 ’ and S 2  are cut at

the positions of 3rd and 4th maxima. Again there is a screen at a distance D. P is a point at a distance of
2
from the central line of the first pair of slits S1 and S2 ,, while Q is on the central line of the second pair of slits
 
S1 ’ and S 2 . All slits are of same widths.If the intensity of light at the point P is  and the intensity at Q is

x
, then find the value of x.
4
 PHYSICS

19. A scale (=10-3/0C ) gives correct reading at 00C. It is used at a different temperature 150C.The scale is used
to measure length of 1m. If the value of the difference in the measured length and the actual length is 3x mm
then calculate x.

20. m gm of steam at 1000C is mixed with 31.50 gm ice at –200C.Take sice= ssteam= 0.5 cal/gm 0C ,
s water= 1cal/gm0C and the latent heat of fusion and vaporization as 80cal/gm and 540 cal/gm respectively.The
final temperature is found to be 100C . Find the value of m.

21. A 1kg ball is suspended in a uniform electric field with the help of a string fixed to a point.The ball is given a
charge 5 coulomb and the string makes an angle 370 with the vertical in equilibrium position.In the equilibrium
position the tension is double the weight of the ball. Find the magnitude of the electric field in N/Coul.

22. A sphere P(emissivity = 1) of radius 2R and and another sphere Q(emissivity = 1/2) of radius R are placed in
vacuum at some distance.There are no other objects. The temperature of the sphere Q is maintained at
200 K by the means of a heater. A fraction 1/32 of the power emitted by the sphere Q falls on the sphere P.
If the equilibrium temperature of the sphere P is 10 T, find the value of T.

Space for Rough Work

 PART II : CHEMISTRY

SECTION - I
Straight Objective Type
This section contains 10 questions. Each question has 5 choices (A), (B), (C), (D) and (E) for its answer, out
of which ONLY ONE is correct.

23. If enthalpy of formation of CH3–CH3 (g), CH3–CH2–CH3 (g) and CH3–CH2–CH2–CH3 (g) are –20 kcal / mole,
–25 kcal / mol and –30 kcal/mol respectively, then enthalpy of formation of CH3–CH2–CH2––CH2–CH2–CH3
(g) is:
(A) – 50 kcal/mol (B) – 40 kcal/mol
(C) – 45 kcal/mol (D) – 35 kcal/mol

24. Which is incorrect order of basic strength ?

(A) NH2– > PH2– (B) H2O > H2S

(C) CH3– > (D) >

25. S1 : The intercept of a graph of PVm along Y-axis vs P along X-axis is equal to 1 for any real gas.
S2 : Equal volumes of real gases contain equal number of molecules under a given condtion of temperature
and pressure.
4
S3 : The rate of diffusion of CH4 is times rate of diffusion of CD4 under identical conditions.
5
Which of the following is Correct ?
(A) FFF (B) FTF (C) TFF (D) TTT

26. When 12g of carbon reacted with oxygen to form CO and CO2 at 25C and constant pressure, 77.5 Kcal of
heat was liberated and no carbon was left. Calculate the mass of oxygen which reacted.
fH (CO) = –25 Kcal/mol.
fH (CO2) = –95 Kcal/mol.
(A) 32g (B) 2g (C) 24g (D) 28g

27. A current of 19.3 mA is passed for 9375 sec. through 500 ml of 2 mM ZnSO4 solution. If final molarity of Zn2+
is 0.5 mM, then the current efficiency of the source is : (Assume volume remains constant during this
process).
(A) 80% (B) 75% (C) 72% (D) 65%

28. On the basis of following reactions, identify the correct matching

heat
A(aq) + Al   (B)(gas). (Colorless combustible gas which is lightest)
heat
A(aq) + C   PH3(gas).
A(aq) + NH4Cl  heat
 (D)(gas) . (turns red litmus blue)
(A) A = NaOH, C = P4 (B) A = CH3COOH, B = CH4
(C) A = KOH, D = NH3, C = H3PO4 (D) A = HCl, B - H2, C = H3PO4


H
29. (CH3 )3 C – CH – C  C – H     Pr oduct
| isomerisat ion
OH (II)
(I)

The correct statement is :

(A) (I) and (II) give positive tests with Tollen's reagent.
(B) (I) and (II) give positive tests with Fehling solution.
(C) (I) and (II) both react with Lucas reagent.
(D) (I) and (II) both liberate H2 gas with sodium metal.
 CHEMISTRY
30. Diasteromers are possible for structural formula :

(A) C3FClBrI (alkynes) (B) C2FClBrI (C) (D)

31. Which of the following is a disacchharide which is ;

(I) not a reducing sugar
(II) having -(1,2) glycosidic linkage.

(A) (B)

(C)
(D)

32. The following benzyl alcohols are reacted with HBr. The least reactive and the most reactive are respectively:

(A) 1, 4 (B) 2, 3 (C) 2, 4 (D) 1, 3

 SECTION - II
Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, there are 2 questions. Each question has
4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 33 to 34

dqrev
dS =  dqrev = TdS
T
qrev =  TdS
Hence q is the area under the curve in S vs T diagram projected on S axis.

33.

Consider the cyclic process ABCDEFGA. The area of the two circles are equal. The net work done during
ABCDEFGA is :
(A) positive
(B) negative
(C) Zero
(D) work cannot be determined in a cyclic process from S vs T diagram.

34.

Which of the following is correct regarding the cycle ABCD ?

(A) Ssurr > 0 along process BC and DA
(B) The process AB is isothermal expansion
(C) The process BC is adiabatic expansion
(D) Ssurr < 0 in the complete cyclic process ABCDA.
 CHEMISTRY

Paragraph for Question Nos. 35 to 36

An ore found in nature contain two elements A and B from 4th period of periodic table. Also both of these
elements belong to the same group in the list of basic radicals analysis.
An orange compound of element A on reacting with KCl and concentrated H2SO4 produce deep red vapors.
These deep red vapors on passing through aqueous H2SO4 solution acquire orange color. If Barium chloride
is added to this solution along with Baryta water, a yellow ppt is obtained.
On the basis of this information, answer the following questions.

35. The element B can be :

(A) Ca (B) Fe (C) Hg (D) Al

36. The element B in its stable high oxidation state gives blue color with excess of :
(A) NH3 (B) K3 [Fe(CN)6] (C) K4 [Fe(CN)6] (D) NaSCN

Paragraph for Question Nos. 37 to 38

37. Compound (P) may be :

(A) (B) (C) (D)

38. Which is not correct statement ?

(A) Q is the recemic mixture.
(B) Total four stereoisomers are possible with (R).
(C) S will reacts with cold dil. KMnO4 & decolourises pink colour solution.

(D) LiAlH4 reacts with S to give

 CHEMISTRY

SECTION - III
Integer Answer Type

This section contains 6 questions. The answer to each of the questions is

a single digit integer, ranging from 0 to 9. The appropriate bubble below the
respective question number in the ORS have to be darkened.

39. Coordination number of underlined or mentioned atom is greater than or equal to 4 in how many of the
following ?
(i) Na2 SiF6
(ii) Silica (Silicon)
(iii) CaSiO3 (where the silicate unit is cyclic trisilicate)
(iv) Silicon
(v) [Ag(S2O3)2]3–
(vi) SO32–
(vii) H3PO3
(viii) N2O5
(ix) B2H6
(x) PH4Cl

40. How many of the following oxides are anhydrides of dibasic oxy-acid ?
(i) SO2 (ii) P4O10 (iii) NO2
(iv) CO2 (v) Li2O (vi) CO
(vii) ClO2 (viii) Cl2O (ix) I2O5

41. 2 moles of a mixture of O2 and O3 is reacted with excess of acidified solution of KI. The iodine liberated
x
require 1L of 2M hypo solution for complete reaction. The weight % of O3 in the initial sample is x. Find .
10

42. The number of completely filled orbitals in 29Cu which have atleast two nodes is/are :

43. C4H8 (unsaturated hydrocarbons) Total number of products formed :

44. An aromatic hydrocarbon has molecular formula C10H14, on oxidation with boiling alkaline KMnO4 followed by
acidification yields benzene dicarboxylic acid. Calculate total isomers for C10H14.
 PART- III - MATHEMATICS

SECTION - I
Straight Objective Type
This section contains 10 questions. Each question has 5 choices (A), (B), (C), (D) and (E) for its answer, out
of which ONLY ONE is correct.

2
 sec A cos ecA 
45. If A = 5º then the value of  2
 2
 is

 (1 – 4 sin A ) ( 4 cos A – 1) 
(A) 6 (B) 8 (C) 16 (D) 24
10
r –1
46. The value of  2
r 1

 8r – 3 is equal to

(A) 1343 (B) 1234 (C) 1334 (D) 1433

47. How many perfect squares are divisors of the product 1! . 2! . 3! ....9! ?
(A) 504 (B) 672 (C) 864 (D) 936
 x3 x 
48. The area of the smaller region in which the curve y     , where [.] denotes the greatest integer
 100 50 
2 2
function, divides the circle  x  2   y  1  4, is equal to

2  3 3 3 3 
(A) sq. units (B) sq. units
3 3

4  3 3 5  3 3
(C) sq. units (D) sq. units
3 3

/6 /2
cos x cos x
49. Let I =  dx, J   dx . Which of the following is CORRECT ?
x x
0 /3

       
(A) I < , J< (B) I > , J< (C) I < , J> (D) I > , J>
6 6 6 6 6 6 6 6

       
50. Vectors 3a  5b and 2a  b are mutually perpendicular. If a  4b and b  a are also mutually perpendicular,,
 
then cosine of the angle between a and b is equal to

19 19 19 19
(A) (B) (C) (D)
5 43 3 43 2 45 6 43

51. Mr. A and Mr. B have a competition. Initially, each player has one attempt at hitting a target. If one player hits
the target and other does not then the successful player wins. If both players hits the target, or if both players
miss the target, then each has another attempt, with same rules applying. If the probability of Mr. A hitting the
4 2
target is always and the probability of Mr. B hitting the target is always , then the probability Mr. A wins
5 3
the competition is
4 4 4 2
(A) (B) (C) (D)
15 11 13 3

52. The equation of the curve satisfying the differential equation y2 (x2 + 1) = 2xy1 passing through the point
(0, 1) and having slope of tangent at x = 0 is 3, is
(A) y = x2 + 3x + 2 (B) y2 = x2 + 3x + 1 (C) y = x3 + 3x + 1 (D) y = x3 – 3x + 1
 MATHEMATICS

53. The equation x + cosx = a has exactly one positive root. Complete set of values of 'a' is
(A) (0, 1) (B) (–, 1) (C) (–1, 1) (D) (1, )
10

54. If  is a imaginary cube root of unity then the value of cos  (r – )(r –  ) is
225 r 1

1 1
(A) –1 (B) – (C) (D) 1
2 2

SECTION - II
Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph, there are 2 questions. Each question has
4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 55 to 56

Consider a general equation of degree 2, as
x2 – 10xy + 12y2 + 5x – 16y – 3 = 0
55. The value of  for which the given equation represents a pair of straight lines is
(A) 1 (B) 2 (C) 3/2 (D) 3
56. For the value of  obtained in above question, if L1 = 0 and L2 = 0 are the lines denoted by the given equation,
then the product of the abscissa and ordinate of their point of intersection is
(A) 18 (B) 28 (C) 35 (D) 25

Paragraph for Question Nos. 57 to 58

Let f(n) denote the nth term of the sequence 3, 6, 11, 18, 27............. and g(n) denote the nth term of the
sequence 3, 7, 13, 21, .............. let F(n) and G(n) denote the sum of n-terms of the above sequences
respectively.
F(n)
57. lim
n  G (n)
(A) 2 (B) 1 (C) 0 (D) 
n n
 F(n)   f(n) 
58. lim    nlim   =
n  G(n)  g(n)
   
(A) e3/2 – e (B) e–3/2 – e–1 (C) e3/2 (D) e–1

Paragraph for Question Nos. 59 to 60

Let ABCDE be a regular pyramid with square base ABCD and sides
AB = BC = CD = AD = AE = BE = CE = DE = 2.

59. Shortest distance between line through AB and DE

2 2 2 2 2 2
(A) (B) (C) (D)
3 3 3 3

60. Acute angle between faces ADE and ABE is

 1  1 2 4
(A) cos–1   (B) cos–1   (C) cos–1   (D) cos–1  
4 3 3 5
 MATHEMATICS

SECTION - III
Integer Answer Type

This section contains 6 questions. The answer to each of the questions is

a single digit integer, ranging from 0 to 9. The appropriate bubble below the
respective question number in the ORS have to be darkened.

61. A line with positive direction cosines passes through the point P(2, –1, 2) and makes equal angles with the
coordinate axes. The line meets the plane 2x + y + z = 9 at point Q. If the length of the line segment
PQ is  , then value of  2 is

62. Consider a triangle ABC and let a, b and c denote the lengths of the sides opposite to vertices A,B and C
respectively. If a,b,c (in order) are in arithmetic progression such that x2 + 3x + 5 = 0 and 3x2 + ax + c = 0
have a common root, then find the radius of the incircle of triangle ABC.

63. If the co-efficients of three consecutive terms in the expansion of (1 + x)n, n  N are in the ratio 1 : 7 : 35, then
n–3
find .
4

64. Let f(x) be a non-constant thrice differentiable function defined on x  R such that f(x) = f(6 – x), x  R and
f (0) = f (2) = f (5) = 0. If p is the minimum number of zeros of (x) = (f(x))2 + f(x) f(x) in the interval
p
[0, 6], then the value of is
3

65. Find the number of ordered triplets (x – y, y – z, z –x), where x,y,z satisfy
x(x – 1) + 2yz = y(y – 1) + 2zx = z(z – 1) + 2xy.

66. If a0 is the value of a  (0, 1] for which the area bounded by the graph of the function y = x b + 3x c
(where b > 1, c > 1) and the lines x = 0, x = 1, y = ab + 3ac is greatest, then evaluate 7a0 .