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® Code

P32-17
0
ADVANCED PATTERN PART TEST-3(APT-3)
TARGET : JEE (MAIN+ADVANCED) 2018
REVISION PLAN-2 COURSE : VIJETA (JP), VISHWAAS (JF), VIJAY (JR)
Date : 01-05-2018 Time: 3 Hours Maximum Marks : 186
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.
6. After the open booklet, verify that the booklet contains all the 54 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :
7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.
8. Each section as detailed in the following table :
Category-wise Marks for Each Question Maximum
Number of
Section Question Type Marks of the
Questions Negative
Full Marks Partial Marks Zero Marks Section
Marks
+4 0
–1
One or More Correct If only the bubble(s) If none of
1 8 – In all other 32
Option(s) corresponding to all the correct the bubbles
cases
option(s) is(are) darkened is darkened
+3
0 –1
Matching Type If only the bubbles
2 6 – if not In all other 18
(SCQ) corresponding to the correct
attempted cases
answer is darkened
+3
0 –1
If only the bubbles
3 Single digit Integer (0-9) 4 – if not In all other 12
corresponding to the correct
attempted cases
answer is darkened

OPTICAL RESPONSE SHEET :


9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :
13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.

NAME OF THE CANDIDATE : ………………………………………………………………..………………………

ROLL NO. : ………………………..………………………


I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.

------------------------- -------------------------
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MATHEMATICS
PART : I MATHEMATICS

MATHEMATICS
SECTION – 1 : (Maximum Marks : 32)

 This section contains EIGHT questions


 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+4 If the bubbles corresponding to the answers are darkened
0 If none of the bubbles is darkened
–1 In all other cases

1. If A, A1, A2, A3 are the areas of the incircle and three excircles respectively of a  ABC, then

(A) A 1  A 2  A 3   r1  r2  r3 

1 1 1 1
(B)   
A1 A2 A3 A

1 1 1 s2
(C)   
A1 A2 A3  r 1 r2 r3

1 1 1
(D)      4R  r 
A1 A2 A3

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MATHEMATICS

 2 17  

MATHEMATICS
2. Consider the equation sin–1  x – 6x  –1
 + cos k = , then
 2  2
(A) the largest value of k for which equation has 2 distinct solution is 1

 1 
(B) the equation must have real root if k   – ,1
 2 
 1
(C) the equation must have real root if k   –1, 
 2
1
(D) the equation has unique solution if k = –
2

  
3. If the vectors a , b , c are non  coplanar and l , m , n are distinct scalars, then
  
  a  mb  nc

   
   b  mc  na   c  ma  nb   = 0 implies :

(A) lm + m n + nl = 0 (B) l + m + n = 0
2 2 2 3 3 3
(C) l + m + n = 0 (D) l + m + n = 3l mn

   1  
4. If f  x     oge  x     , where [] represents greatest integer function
 
   x  

1  1 
(A) Domain of f(x) is  ,0    n  N (B) Domain of f(x) is  , n  Z, n  0 
 n   n 
(C) Range of f(x) is {n(n) , n  N} (D) Range of f(x) contains exactly one integer

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MATHEMATICS
5. Let f(x) = |x –1| ([x] – [–x]), then which of the following statement(s) is/are correct. (where [.]

MATHEMATICS
denotes greatest integer function.)
(A) f (x) is continuous at x = 1 (B) f (x) is derivable at x = 1
(C) f (x) is non-derivable at x = 1 (D) f (x) is discontinuous x = 1

x  2 x 1
6. Let f(x) = .x, then
x 11
(A) domain of f (x) is x  1 (B) domain of f(x) is [1, ) – {2}
3
(C) f ' 10   1 (D) f '    1
2

7. If f(x) is differentiable function on R and g(x)  2 x f x.2 x        R  , then


(A) g'  0   g  0   n2  f '    (B) g'  0   g  0   n 2   f '   

 
(C) 2x g  x  '  0    f '     
(D) 2x g  x  ' 0   f '   

8. If a, b, c are different real numbers and a ˆi  b ˆj  c kˆ , b ˆi  c ˆj  akˆ & c ˆi  a ˆj  bkˆ are position
vectors of three non-collinear points A, B & C then :
abc ˆ ˆ ˆ
(A) centroid of triangle ABC is
3

i  jk 
(B) ˆi  ˆj  kˆ is equally inclined to the given three position vectors of A,B and C.
(C) perpendicular from the origin to the plane of triangle ABC meets at centroid of ABC
(D) triangle ABC is an equilateral triangle.

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MATHEMATICS

MATHEMATICS
SECTION – 2 : (Maximum Marks : 18)
 This section contains SIX questions of matching type.
 This section contains TWO tables (each having 3 columns and 4 rows).
 Based on each table, there are THREE questions
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.

Answer Q.09, Q.10, Q.11 by appropriately matching the information given in the three
columns of following table.
Column – I Column – II Column - III
Polygon Circum radius (R) In radius (r)
I. Triangle i. a   (p) a  13 
cosec   cot  
2 5 2  12 
II. Hexagon ii. a   (q) a  
cosec   tan  
2 3 2 3
III. Pentagon iii. a   (r) a  
cosec   cot  
2 6 2 5
IV. Dodecagon iv. a   (s) a  
cosec   tan  
2  12  2 6

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MATHEMATICS
9. If sum of internal angles of a regular polygon is 4 then correct combination of column is

MATHEMATICS
(A) (II) (i) (p) (B) (II) (ii) (q) (C) (II) (iii) (q) (D) (IV) (iv) (s)

r 1
10. If value of is then which combination is correct?
R 5 1
(A) (III) (iii) (r) (B) (II) (i) (q) (C) (II) (ii) (Q) (D) (III) (i) (r)

11. tan   2  3 is valid for which of the following where   sin1  r 


R
(A) (III) (iii) (r) (B) (IV) (iv) (p) (C) (IV) (iv) (s) (D) (I) (i) (s)

Answer Q.12, Q.13, Q.14 by appropriately matching the information given in the three
columns of following table.
Column – I Column – II Column - III
Function Number of Points Number of Points of
of discontinuity non differentiability
I. Even i. 0 (p) 1
II. Odd ii. 1 (q) 2
III. Neither even nor odd iii. 2 (r) 3
IV. Both even & odd iv. 3 (s) 0

12. Correct the combination for f(x)  x  2  x  2


(A) (I) (i) (p) (B) (I) (i) (q) (C) (II) (i) (r) (D) (II) (ii) (p)

13. Correct combination for f(x) = sgn(x) where sgn represents signum function
(A) (I) (i) (p) (B) (I) (i) (s) (C) (II) (ii) (p) (D) (IV) (iv) (s)

14. Correct combination for f  x   x3 x is?


(A) (II) (i) (s) (B) (II) (ii) (q) (C) (I) (i) (r) (D) (III) (ii) (q)

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MATHEMATICS

SECTION – 3 : (Maximum Marks : 12)

MATHEMATICS
 This section contains FOUR questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

15. The number of planes that are equidistant from four non-coplanar points is:

  
16. In a quadrilateral ABCD , A C is the bisector of the angle between A B and A D . It is given that
  2        2
AB ^ AD = and 15 | A C | = 3 | AB | = 5 | AD | If cos  B A ^ CD  is then value of k is
3   k

17. A plane passing through (1,1,1) cuts positive direction of coordinate axes at A, B and C, and the
minimum volume of tetrahedron OABC is k then the value of 2k is

y z
18. The lines L : x = y = z and R: x   and third line passing through (1, 1,1) form triangle of area
2 3

6 units, if point of intersection of third line with second line R is (a, b, c) then the value of |a + b|
will be-

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PHYSICS
PART - II : PHYSICS

PHYSICS
SECTION – 1 : (Maximum Marks : 32)
 This section contains EIGHT questions
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+4 If the bubbles corresponding to the answers are darkened
0 If none of the bubbles is darkened
–1 In all other cases

19. A particle moving with constant speed u inside a fixed smooth hemispherical bowl of radius
a
a describes a horizontal circle at a distance below its centre. Then
2

a 3
(A) The radius of the circular motion is
2

3ag
(B) The value of u is
2
mg
(C) The normal reaction of the spherical surface on the particle is
2
(D) The magnitude of the resultant force acting on the particle is zero, in an inertial frame.

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PHYSICS
20. Two identical blocks A and B of mass m each are connected to each other by spring of spring

PHYSICS
constant k. Block B is initially shifted to a small distance x0 from natural length of spring to the left
and then released. Choose the correct statements for this problem, after the spring attains it's
natural lenth.
xo
A k B
m m

1 k
(A) Velocity of centre of mass of the system is x0
2 m
x0
(B) Maximum elongation in spring during the subsequent motion is
2
(C) Maximum elongation in spring during the subsequent motion is x0
K
(D) Maximum speed of block A during subsequent motion be x0
m

21. A cylinder and a variable mass M are arranged on a fixed wedge using a light string and a
massless pulley. There is enough friction between cylinder and the wedge to prevent any slipping.
Mass less pulley

Cylinder
M

Fixed Wedge

(A) Only one value of M is possible for which cylinder can remain in equilibrium.
(B) There is a range of value of M for which cylinder can remain in equilibrium.
(C) For a certain value of M, the cylinder starts to roll up the plane. In this situation, magnitude of
Space
friction force on the cylinder by the forwill
wedge Rough Work
be greater than tension in the string
(D) For a certain value of M, the cylinder starts to roll down the plane. In this situation, magnitude
of friction force on the cylinder by the wedge will be greater than tension in the string

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PHYSICS
22. A uniform disc of radius R lies in the x-y plane with its centre at origin. Its moment of inertia about

PHYSICS
z-axis is equal to its moment of inertia about an axis along the line y = K1x + K2 where K1 and K2
are constants. Then choose the option (s) having possible values of K1 and K2.
R
(A) K1 = 1, K2 = +
2
R
(B) K1= 1, K2 = –
2
R
(C) K1 = –1, K2 = +
2
R
(D) K1 = –1, K2 = –
2

23. Lower end of a capillary tube of radius 10–3 m is dipped vertically into a liquid. Surface tension of
liquid is 0.5 N/m and specific gravity of liquid is 5. Contact angle between liquid and material of
capillary tube is 120°. Choose the correct options (use g = 10m/s2)
(A) Maximum possible depression of liquid column in the capillary tube is 1 cm.
(B) Maximum possible depression of liquid column in the capillary tube is 2 cm.
(C) If the length of the capillary tube dipped inside liquid is half of the maximum possible
depression of liquid column in the capilary tube, angle made by the liquid surface at the end of the
 1
capillary tube with the vertical, is cos–1    .
 4
(D) If the length of the capillary tube dipped inside liquid is one third of the maximum possible
depression of liquid column in the capilary tube, angle made by the liquid surface at the end of the
 1
capillary tube with the vertical, is cos–1    .
 6

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PHYSICS
24. Length of arms are sufficient. Now tube is rotated with an angular velocity  with respect to ARM-2

PHYSICS
such that ARM-2 just becomes empty. Area of cross section of ARM-1 is A, ARM-2 is 2A and

ARM-3 is 3A. Choose the correct option(s). ( A   )

A 2A 3A

ARM-1 ARM-2 ARM-3

 2

(A) Liquid Level in ARM-1 will fall.

(B) Liquid Level in ARM-3 will rise

18h
(C) Difference of liquid level in ARM-3 and ARM-1 is
13

5h
(D) Difference of liquid level in ARM-3 and ARM-1 is
13

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PHYSICS
25. A uniform ring having mass m, radius R, cross section area of the wire A and young’s modulus Y is

PHYSICS
rotating with an angular speed  (is small) on a smooth horizontal surface. Which of the

following options is correct :

mR2
(A) Tension in the wire is
2

mR2 2
(B) Change in length of the wire is
2A.Y

mR2 2
(C) Change in radius of the ring is
2A.Y

1  m2 4R3 
(D) elastic potential energy stored is  
4  A.Y 

26. A block of density 2000 kg/m3 and mass 10 kg is suspended by a spring of stiffness 100 N/m. The

other end of the spring is attached to a fixed support. The block is completely submerged in a
liquid of density 1000 kg/m3 . If the block is in equilibrium position (g = 10m/s2).
(A) the elongation of the spring is 1 cm.
(B) the magnitude of buoyant force acting on the block is 50 N.
(C) the spring potential energy is 12.5 J.

(D) magnitude of spring force on the block is greater than the weight of the block.

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PHYSICS
SECTION – 2 : (Maximum Marks : 18)

PHYSICS
 This section contains SIX questions of matching type.

 This section contains TWO tables (each having 3 columns and 4 rows).

 Based on each table, there are THREE questions

 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is

correct.

 For each question, darken the bubble corresponding to the correct option in the ORS.

 For each question, marks will be awarded in one of the following categories :

Full Marks : +3 If only the bubble corresponding to the correct option is darkened.

Zero Marks : 0 If none of the bubbles is darkened.

Negative Marks : –1 In all other cases.

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PHYSICS
Answer Q.27. Q.28 and Q.29 by appropriately matching the information given in the three

PHYSICS
columns of the following table.
Column–I shows a system for which two numbers x and y are defined, column–II shows value of x
and column–III shows the value of y.
Column-I Column-II Column-III

(I) (i) 2 (P) 3


2R R/2

There is a small bubble inside a bigger bubble.


Surface tension of bigger bubble is S and of smaller
bubble is 2S. Inner bubble is uniformly charged with
surface charge density  Pressure inside bigger
bubble and smaller bubble is same. Pressure outside
bigger bubble is P0. Excess pressure (in addition to P0)
xS
inside smaller bubble =
R
2 0 S
Value of  = y
R
A2 A1



(II) (ii) 6 (Q) 4



A uniform solid cylinder of heightSpace


h and density
for Rough is floating
Work
in a liquid of density 3as shown. Cylinder is slightly
displaced and released. Time period of SHM of cylinder
2h
(if A1 = 3A2 ) = 2
xg
Time period of SHM of cylinder
h
(if if A1 >>>> A2 ) = 2
yg
P Q R
3F 2F
(III) (iii) 9 (R) 5
Rod PQR is of uniform linear mass density and cross
section A.
Young modulus of rod is 

In natural state PQ = QR =
2
xF
Elongation in part PQ =
8A
9F
Elongation in part QR =
yA

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PHYSICS

PHYSICS
A B
53°
(IV) S (iv) 11 (S) 8
37°

C D

We have a spherical bubble of radius R, made up by


liquid having surface tension S. AB and CD are two
parallel planes as shown in figure. Net force of surface
RS
tension on part ABCD due to rest of the part is .

There is no common factor in  and . x is defined as
3 
x= y is defined as y =
14 5

27. Which of the following is correctly matched :


(A) (IV) (ii) (R) (B) (IV) (ii) (S) (C) (I) (iii) (Q) (D) (III) (ii) (P)

28. Which of the following is correctly matched :


(A) (I) (iv) (P) (B) (I) (iii) (Q) (C) (II) (iii) (P) (D) (IV) (i) (S)

29. Which of the following is correctly matched :


(A) (I) (i) (Q) (B) (IV) (iii) (R) (C) (III) (ii) (S) (D) (I) (iii) (S)

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PHYSICS
Answer Q.30. Q.31 and Q.32 by appropriately matching the information given in the three

PHYSICS
columns of the following table.
Column–I shows a system for which two numbers x and y are defined, column–II shows value of x
and column–III shows the value of y.
Column-I Column-II Column-III

uniform ring
C mass m, radius R
A

53º 37º

(I) 53º 37º (i) 2 (P) 1




D B

Uniform ring of mass m and radius R is rotated with


constant angular velocity  in gravity free space as
shown. Net force on AB part of ring
xm2R
(by the rest of ring) = Net force on AC part of ring
5
ym 2R
(by the rest ring) =
2

(II) F m m 2F (ii) 3 (Q) 5

Initially (at t=0) the spring of spring constant k is at its

natural position and blocks are at rest.


Space for Rough Work
xF
Maximum elongation in the spring =
2k
kinetic energy of the system (w.r.t. ground) ,when
elongation in the spring becomes maximum for
2 F 2
first time =
yk
9V0
Uniform Ring
0 
R
V0
(III) (iii) 4 (R) 8

Rough ()
Uniform ring of radius R, released on rough horizontal
surface at t=0, as shown.
Velocity of ring after long time = xv0
y v0
Time after which velocity becomes constant =
g

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PHYSICS

(IV) (iv) 6 (S) 9

PHYSICS
R
O

Solid hemisphere density varying with radial distance


0 r
as  = .
R

xR
Distance between centre of mass and O =
5

Moment of inertia w.r.t. an axis passing through O and

20R5
lying in the plane of base of hemisphere =
y

30. Which of the following is correctly matched :


(A) (I) (ii) (P) (B) (IV) (iii) (S) (C) (I) (iii) (Q) (D) (III) (ii) (P)

31. Which of the following is correctly matched :


(A) (I) (iv) (R) (B) (I) (iii) (P) (C) (III) (iii) (Q) (D) (IV) (i) (Q)

32. Which of the following is correctly matched :


(A) (IV) (i) (S) (B) (IV) (iii) (P) (C) (III) (ii) (S) (D) (I) (iii) (S)

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PHYSICS

SECTION – 3 : (Maximum Marks : 12)

PHYSICS
 This section contains FOUR questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

33. An old record player of 10 cm radius turns at 10 rad/s while mounted on a 30° incline as shown in
the figure. A particle of mass m can be placed any where on the rotating record. If the least
possible coefficient of friction  that must exist for no slipping to occur any where is , find the
value of 2 3 .

30°

34. A uniform disc of mass m and radius r is released from a wedge of mass 2m as shown. ABC is
hemispherical position of radius R. Impulse imparted to the system consisting wedge and disc by
the vertical wall w1w2 till the time disc reaches at the bottom most position of spherical portion for
g (R  r)
the first time is m . Friction between wedge and horizontal surface is absent and

between disc and wedge friction is sufficient to avoid slipping between them. Here  and are
integer. Find minimum value of  + 

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PHYSICS
35. In the figure shown AB, BC and PQ are thin, smooth, rigid wires. AB and AC are joined at A and

PHYSICS
fixed in vertical plane. BAC = 2 = 90°and line AD is angle bisector of angle BAC. A liquid of
surface tension T = 0.025 N/m forms a thin film in the triangle formed by intersection of the wires
AB, AC and PQ. In the figure shown the uniform wire PQ of mass 1 gm is horizontal and in
equilibrium under the action of surface tension and gravitational force. Find the time period of SHM

of PQ in vertical plane for small displacement from its mean position, in the form s and fill value
X
of X.

36. A sphere of density  falls vertically downward through a fluid of density . At a certain instant its
velocity is u. The terminal velocity of the sphere is u0. Assuming that stokes’s law for viscous drag
   u 
is applicable, the instantaneous acceleration of the sphere is found to be   1    1   g . Here
   u0 
 is an integer . Find .

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CHEMISTRY

PART : III CHEMISTRY

CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Maximum Marks : 32)

 This section contains EIGHT questions


 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+4 If the bubbles corresponding to the answers are darkened
0 If none of the bubbles is darkened
–1 In all other cases

37. Sodium thiosulphate is prepared by :

(A) Boiling Na2SO3 solution with S in acidic medium.

(B) Boiling NaOH solution with S.

(C) Neutralising H2SO3 solution with NaOH.

(D) Boiling Na2SO3 with S in absence of air.

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CHEMISTRY
38. Select the correct statement(s) regarding the given reaction :

CHEMISTRY
ClO2 + NaOH 

(A) Disproportination takes place.

(B) Chloride (Cl–) is produced.

(C) Chlorate (ClO3 ) is produced.

(D) Chlorite (ClO2 ) is produced.

39. Which reagent does not give oxygen as one of the products during oxidation with ozone ?

(A) SO2 (B) SnCl2 + HCl

(C) H2S (D) PbS

40. PCl5 + SO2  A + B

Which of the following is/are hydrolysis product(s) of A & B ?

(A) HCl (B) H2SO4

(C) H3PO4 (D) H2SO3

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CHEMISTRY
I II
41.  MnO24  MnO 4 .
Pyrolusite is MnO2 used to prepare KMnO4. Steps are, MnO2 

CHEMISTRY
Steps I and II are respectively :

(A) fuse with KOH / air and electrolytic oxidation.

(B) fuse with KOH / KNO3 and electrolytic oxidation.

(C) fuse with conc. HNO3 / air and electrolytic reduction.

(D) dissolve in H2O and oxidation.

42. Which of the following sequence of reactions will synthesis biphenyl.

Br2 / Fe Na/ether
(A) C6H6   

HNO3  H2SO4 Sn  HCl C6H6


(B) C6H6       
NaOH

 HNO2

Cl2 / AlCl3 Ph–H


(C) C6H6     
AlCl3

CH3Cl Cl2 /h Ph–H


(D) C6H6     
AlCl3 1 eq AlCl3

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CHEMISTRY
43. In which reaction, major product formed is correct.

CHEMISTRY
 (A) + CHBr3 + CO2

CHCl / NaOH / 
3
 (B) 

2HNO
 (C)  
 

Br OH
1. Mg/Et 2 O
 (D)  
2.O2
3.H

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CHEMISTRY

H  O O H3O 
44. (P) + (Q)     (R)

CHEMISTRY
 
COOH

find correct statement(s) about above reaction sequence.

CH3
(A) P & Q must be CH3COOH and HO–CH2–CH2–C–CH2–COOH
OH

CH3
(B) P & Q must be CH3CHO and HO–CH2–CH2–C–CH2–COOH
OH

O
O
(C) R must be CH3
OH

O O O
(D) R must be CH3
OH

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CHEMISTRY

SECTION – 2 : (Maximum Marks : 18)

CHEMISTRY
 This section contains SIX questions of matching type.
 This section contains TWO tables (each having 3 columns and 4 rows).
 Based on each table, there are THREE questions
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.

Answer Q.45, Q.46 and Q.47 by appropriately matching the information given in the three columns
of the following table.

In Column–1 some compounds are given which are treated with the Column–2 compounds or are
heated then in column–3 corresponding observations are given.
Column-1 Column-2 Column-3
Any binary compound of
(I) (i) H2O (P) Liberation of O2 is possible
potassium & oxygen
Any alkaline earth metal
(II) (ii) HCl (Q) The resulting solution is alkaline
carbide
(III) Any alkaline earth metal A gaseous hydrocarbon is
(iii) NaOH (R)
carbonate liberated
A gaseous oxide of non Space for Rough Work A gaseous acidic oxide or acidic
(IV) (iv) heat (S)
metal in +4 state solution is formed

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CHEMISTRY
45. Select the incorrect option :
(A) (I) (i) (P) (B) (II) (i) (R) (C) (III) (iv) (S) (D) (IV) (iii) (P)

CHEMISTRY
46. Select the correct option :
(A) (I) (ii) (R) (B) (I) (i) (Q) (C) (IV) (iii) (S) (D) (II) (i) (S)

47. Select the correct option :


(A) (IV) (i) (S) (B) (III) (iv) (R) (C) (III) (iii) (S) (D) (III) (ii) (P)

Answer 48, 49 and 50 by appropriately matching the information given in the three Columns
of the following table.
Columns 1,2 and 3 contain reactants, reagents & products respectively.
Column-1 Column-2 Column-3
NH2
(i) CHCl3/alc.–KOH (P) Gattermann reaction
(I)

Ph N(CH3)2
(Q) Coupling reaction
(ii) pH=5–6
(II)

+ –
N2Cl
(iii) 1. CCl4/alc KOH
(R) Reimer Tiemann reaction
2. H3O+
(III)

OH
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(IV) (iv) Cu/HCN (S) Carbyl amine reaction

CH3

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CHEMISTRY
48. The only correct combination in which Azo dye is formed:

(A) (I) (ii) Q (B) (III) (ii) Q

CHEMISTRY
(C) (I) (i) S (D) (II) (iii) R

49. The only correct combination in which carboxylic acid is formed:.

(A) (II) (i) R (B) (II) (iii) P

(C) (IV) (iii) R (D) (III) (i) P

50. The only correct combination in which isocyanide is formed

(A) (I) (i) S (B) (III) (iv) P

(C) (III) (iv) Q (D) (I) (iv) P

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CHEMISTRY

SECTION – 3 : (Maximum Marks : 12)

CHEMISTRY
 This section contains FOUR questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

Complete hydrolysis
51. XeF6 
 (A) + HF

NaOH + (A)  (B)



OH
Anion of (B)   C + Gas (D) + Xe + H2O
oxoanion

H2O
(A) + Gas(D)

(C)
2+
Mn (A) + (E)
oxo anion
Determine sum of atomicity of (A), (B), (C), (D) and (E). Give your answer after dividing 5.

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CHEMISTRY
4–
52. Number of B–O bonds in diborate ion (B2O5) is :

CHEMISTRY
53. How many hydrogen bonded water molecule(s) is/are associated in CuSO4.5H2O ?

COOEt (1) CH MgBr (excess) M Conc. H SO


54. 
3
 
2 4
 N (Major product)

(2) H2O,H  
COOEt ethanol

Number of  bonds present in product 'N'

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