Advanced Pattern Online Test-3 (Aont-3) Xii: Fnukad Le ?K.VK Egùke Vad

P26-16
® Code
0
ADVANCED PATTERN ONLINE TEST-3 (AONT-3) XII
TARGET : JEE (MAIN+ADVANCED) 2017
SUBJECT : CHEMISTRY
COURSE : VIJETA (JP), VISHWAAS (JF)
Date (fnukad) : 09-02-2017 Time: 1 Hour (le; : 1 ?k.Vk) Max. Marks (egÙke vad) : 80
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
Ñi;k bu funsZ'kksa dks /;ku ls i<+saA vkidks 5 feuV fo'ks"k :i ls bl dke ds fy, fn;s x;s gSaA
INSTRUCTIONS / funsZ'k :
A. General : A. lkekU; %
1. This booklet is your Question Paper. Do not break 1. ;g iqfLrdk vkidk iz'u&i=k gSA bldh eqgjsa rc rd u
the seals of this booklet before being instructed to do rksMsa tc rd fujh{kdksa ds }kjk bldk funsZ'k u fn;k tk;sA
so by the invigilators.
DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

2. Blank spaces and blank pages are provided in the 2. dPps dke ds fy;s [kkyh i`"B vkSj [kkyh txg bl
question paper for your rough work. No additional iqfLrdk esa gh gSA dPps dke ds fy, dksbZ vfrfjDr dkxt
sheets will be provided for rough work.
ugha fn;k tk;sxkA
3. Blank papers, clipboards, log tables, slide rules, 3. dksjs dkxt] fDyi cksMZ (CLIP BOARD)] ykWx rkfydk]
calculators, cameras, cellular phones, pagers and LykbM:y] dSYdqysVj] dSejk] lsyQksu] istj vkSj fdlh
electronic gadgets are NOT allowed inside the
examination hall. izdkj ds bysDVªkfud midj.k ijh{kk d{k esa vuqefr ugha
tc rd ifjos"kd funsZ'k ugha nsa rc rd iz'u i=k dh lhy dks ugha [kksaysA
gSA
4. Write you name and roll number in the space 4. bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke
provided on the back cover of this booklet. vkSj jksy uEcj fyf[k,A
5. Using a black ball point pen, darken the bubbles 5. Åijh ewy i`"B ds cqycqyksa (BUBBLES) dks dkys ckWy
on the upper original sheet. IokbaV dye ls dkyk djsaA
6. DO NOT TAMPER WITH/MUTILATE THE ORS OR 6. vks-vkj-,l- (ORS) ;k bl iqfLrdk esa gsj&Qsj@foÑfr u
THE BOOKLET. djsaA
7. On breaking the seals of the booklet check that it 7. bl iqfLrdk dh eqgjsa rksM+us ds i'pkr~ Ñi;k tk¡p ysa fd blesa
contains all the 20 questions and corresponding lHkh 20 iz'u vkSj muds mÙkj fodYi Bhd ls i<+s tk ldrs gSaA
answer choices are legible. Read carefully the
Instructions printed at the beginning of each section. lHkh [kaMksa ds izkjaHk esa fn;s gq, funsZ'kksa dks /;ku ls i<+saA
B. Filling the ORS B.
vks-vkj-,l (ORS) Hkjuk % ORS dks Hkjus ds fy, dsoy dkys
Use only Black ball point pen only for filling the ORS. ck¡y iSu dk mi;ksx dhft,A
8. Write your Roll no. in the boxes given at the top left 8. ORS ds lcls Åij cka;s dksus esa fn, x, ck¡Dl esa viuk
corner of your ORS with black ball point pen. Also, jksy uEcj dkys ck¡y ikbUV ls fyf[k, rFkk laxr xksys Hkh
darken the corresponding bubbles with Black ball
point pen only. Also fill your roll no on the back side of dsoy dkys isu ls Hkfj;sA ORS ds ihNs dh rjQ Hkh viuk
your ORS in the space provided (if the ORS is both side jksy uEcj fyf[k, (;fn ORS nksuksa rjQ Nih gqbZ gSA)
printed).
9. Fill your Paper Code as mentioned on the Test Paper and 9. ORS
ij viuk isij dksM fyf[k, rFkk laxr xksyksa dks dkys
darken the corresponding bubble with Black ball point pen. ck¡y isu ls dkys dhft,A
10. If student does not fill his/her roll no. and paper code 10. ;fn fo|kFkhZ viuk jksy uEcj rFkk isij dksM lgh vkSj
correctly and properly, then his/her marks will not be mfpr rjhds ugha Hkjrk gS rc mldk ifj.kke jksd fy;k
displayed and 5 marks will be deducted (paper wise)
from the total. tkosxk rFkk iz'u&i=k esa izkIrkad ls 5 vad dkV fy, tkosaxsaA
(Please read the last page of this booklet for rest of the instructions)
Ñi;k 'ks"k funsZ'kksa ds fy;s bl iqfLrdk ds vfUre i`"B dks i<+sA
Resonance Eduventures Ltd.
CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
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CHEMISTRY
CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION – 1 : (Maximum Marks : 40)
[kaM 1 : (vf/kdre vad : 40)
 This section contains TEN questions

 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases
 bl [kaM esa nl iz'u gSaA

 izR;sd iz'u dk mÙkj 0 ls 9 rd, nksuksa 'kkfey] ds chp dk ,d ,dy vadh; iw.kk±d gSA
 izR;sd iz'u esa] vks- vkj- ,l- ij lgh iw.kk±d ds vuq:i cqycqys dks dkyk djsaA
 vadu ;kstuk :
+4 ;fn mÙkj ds vuq:i cqycqys dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
–1 vU; lHkh voLFkkvksa esa
Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
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CJP/JFAONT3090217C0-1
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029
CHEMISTRY
1. 0.2 gm of a solution of mixture of NaOH and Na2CO3 and inert impurity was first titrated with HPh
and N/10 HCl, 17.5 mL of HCl was required at the end point. After it MeOH was added and 2.5 mL
CHEMISTRY
of same HCl was again required for next end point. Determine percentage by weight of NaOH in
the original mixture. Give your answer after dividing by 10.
NaOH o Na2CO3 rFkk vfØ; v'kqf) ds 0.2gm feJ.k ds foy;u dks loZizFke HPh rFkk N/10 HCl ds lkFk
vuqekfur fd;k x;k] vfUre fcUnq ij 17.5 mL HCl dh vko';drk gksrh gSA blds i'pkr~ MeOH dks feyk;k
x;k o vxys vfUre fcUnq ds fy, mlh HCl ds 2.5 mL dh vko';drk gqbZA okLrfod feJ.k esa Hkkj ds vuqlkj
NaOH dk izfr'kr Kkr dhft;sA viuk mÙkj 10 ls Hkkx yxkus ds i'pkr~ nhft;s A
2. During dissolution of lead (II) sulphide into dilute nitric acid solution, the ratio of instantaneous rate
of disappearance of HNO3 to instantaneous rate of appearance of NO(gas) is :
ruq ukbfVªd vEy foy;u esa ysM (II) lYQkbM ds ?kqyus ds izØe esa HNO3 ds foyqIr gksus o NO(xSl) ds izdV
gksus dh rkR{kf.kd nj dk vuqikr gS&
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CHEMISTRY
3. How many of the following statements is/are true ?
(1) Silica gel absorbs water molecule from moist air.
CHEMISTRY
(2) The entropy of gas decreases when it gets adsorbed on charcoal.
(3) Heterogeneous catalysts like Ni(s) in the hydrogenation of vegetable oil function by
chemisorption.
(4) The enthalpy of physisorption is smaller in magnitude than enthalpy of chemisorption.
(5) As temperature increase, the extent of physisorption decrease but it can get converted to
chemisorption at higher temperature.
(6)
Graph A represent chemisorption and graph B represent physisorption.

fuEu esa ls fdrus dFku lgh gS@gSa \
(1) flfydk tSy vknz ok;q ls ty v.kq vo'kksf"kr djrk gSA
(2) xSl dh ,UVªksih ?kVrh gS tc ;g pkjdksy ij vf/k'kksf"kr gksrh gSA
(3) ouLifr rsy ds gkbMªkstuhdj.k esa Ni(s) tSls fo"kekaxh mRizsjd jklk;fud vf/k'kks"k.k }kjk dk;Z djrs gSA
(4) HkkSfrd vf/k'kks"k.k dh ,UFkSYih ifjek.k esa] jklk;fud ,UFkSYih ls de gksrh gSA
(5) tSls gh rkieku esa o`f) gksrh gS HkkSfrd vf/k'kks"k.k dh ek=kk ?kVrh gS ysfdu bls mPp rkieku ij
jklk;fud vf/k'kks"k.k esa ifjofrZr fd;k tk ldrk gSA
A B
fLFkfrt Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

(6) Å t kZ lrg lsnw
jh
vkjs[k A jklk;fud vf/k'kks"k.k o vkjs[k B HkkSfrd vf/k'kks"k.k dks iznf'kZr djrk gSA
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CHEMISTRY
4. After complete hydrolysis of XeF6 the oxidation number of Xe in the product is x then find x.
CHEMISTRY
XeF6 ds iw.kZ tyvi?kVu ds i'pkr~ mRikn esa Xe dh vkWDlhdj.k la[;k x gS] rc x crkb,A
5. NH3 is oxidized to NO by O2 in basic medium. Number of equivalents of NH3 oxidized by 1 mole O2
is :
{kkjh; ek/;e esa NH3,O2 }kjk NO es vkWDlhÑr gksrk gSA 1 eksy O2 }kjk vkWDlhÑr NH3 ds rqY;kad dh
la[;k gksxh&
2 3
6. If for a reaction A  products the concentration of A are Co, aCo, a Co, a Co …… after time interval
0, t, 2t, 3t …. where a is constant 0 < a < 1. The order of reaction is :
;fn vfHkfØ;k A  mRikn ds fy, A dh lkUnzrk le;vUrjky 0, t, 2t, 3t …. ds i'pkr~ Co, aCo, a2Co,
3
a Co …… gSA tgk¡ a fu;rkad gS 0 < a < 1. vfHkfØ;k dh dksfV gS &
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CHEMISTRY
7. Out of following polymers, how many are addition polymer as well as homopolymer (both) :
fuEufyf[kr esa ls fdrus cgqyd ;ksxkRed rFkk lecgqyd cgqyd ¼nksuksa½ gSa&
CHEMISTRY
Nylon 6, 6 (uk;ykWu 6,6)
Terylene (Vsjhyhu)
Polystyerene (ikWyhLVkbfju)
PVC
Glyptal (fXyiVy)
Polyacrylonitrile (ikWyh,ØkbyksukbVªkby)
Teflon (Vs¶yku)
Nylon -6 (uk;ykWu-6)
Neoprene (fu;ksçhu)
Bakelite (csdsykbV)
Buna-s (C;wuk -S)
Polythene (ikWyhFkhu)
8. Total number of aldol products formed in the following reaction is (all major and minor products
including stereoisomers)
fuEu vfHkfØ;k esa cuus okys ,YMksy mRiknksa ¼f=kfoe leko;oh lfgr lHkh eq[; o vYi mRikn½ dh dqy la[;k
gS &
NaOH
CH3CH=O +  

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CHEMISTRY
9. How many of these amino acid are negatively charged at pH = 7.0 ?
Alanine Lysine Glumatic acid
CHEMISTRY
Glycine Leucine Aspartic acid Arginine
fuEu esa ls fdrus ,ehuksa vEy pH = 7.0 ij _.kkosf'kr gksrs gS \
,ysuhu ykblhu XywesfVd vEy
Xyk;lhu Y;wlhu ,LikfVZd vEy vktsZuhu
O
COOH

10. COOH  X moles of CO2
HO2C CO2H
O

Y(-Keto acid)  Ph
y = possible structure of -Keto acid (including stereoisomers).
Value of (X + Y) will be :
O
COOH

COOH  CO2ds X eksy
HO2C CO2H
O

Y(-dhVksvEy)  Ph
y = - dhVks vEy dh lEHko lajpuk (f=kfoe leko;oh lfgr)
(X + Y) dk eku gksxk &
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CHEMISTRY
SECTION – 2 : (Maximum Marks : 40)
 This section contains TEN questions
CHEMISTRY
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
–1 In all other cases
[kaM 2 : (vf/kdre vad : 40)
 bl [kaM esa nl iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u esa] lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks vks- vkj- ,l- esa dkyk djsaA
 vadu ;kstuk :
+4 ;fn flQZ lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
–1 vU; lHkh voLFkkvksa esa
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CHEMISTRY
11. For a certain reaction A  P, the half life for different initial concentration of A is mentioned
below.
CHEMISTRY
[A0] 0.1 0.025
t1/2 (s) 100 50
Which of the following option(s) is / are incorrect.
(A) The order is 1 (B) The order is 0.5
(C) For [A0] = 1M, t1/2 = 100 10 sec. (D) For [A0] = 1M t1/2 = 100 sec.
,d fuf'pr vfHkfØ;k A  P ds fy,] A dh fofHkUu izkjfEHkd lkUnzrk ds fy, v)Z vk;q uhps mYysf[kr gSA
[A0] 0.1 0.025
t1/2 (s) 100 50
fuEu esa ls dkSulk@dkSuls fodYi xyr gS@gSa \
(A) dksfV 1 gSA (B) dksfV 0.5 gSA
(C) [A0] = 1M ds fy, t1/2 = 100 10 sec. (D) [A0] = 1M ds fy, t1/2 = 100 sec.
12. Cl2 + NH3(excess)  A + B

(A) One of the product is also obtained by decomposition of (NH4)2Cr2O7.
(B) Bond order in one of the products is 3.
(C) Both products contain chlorine.
(D) If Br2 is used instead of Cl2, one of the products remain same.
Cl2 + NH3(vkf/kD;)  A + B.
(A) ,d mRikn dks (NH4)2Cr2O7 ds fo?kVu }kjk Hkh izkIr fd;k tkrk gSA
(B) ,d mRikn esa cU/k Øe 3 gSA
(C) nksuksa mRikn Dyksjhu j[krs gSA
(D) ;fn Cl2 ds LFkku ij Br2 dk iz;ksx djrs gS] rks ,d mRikn leku jgrk gSA
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CHEMISTRY
The correct statement(s) about MnO4 & Cr2O72– is/are :
–
13.
(A) All the bond lengths are identical in both anions separately.
CHEMISTRY
(B) Both the anions are colourless & diamagnetic.
(C) Both the anions are coloured & diamagnetic.
(D) Both KMnO4 & K2C2O7 on heating produce same colourless paramagnetic gas.
– 2–
MnO4 rFkk Cr2O7 ds ckjs esa lgh dFku gS@gSa&
(A) i`Fkd&i`Fkd :i ls nksuksa _.kk;uksa esa lHkh ca/k yEckbZ;k¡ leku gksrh gSaA
(B) nksuksa _.kk;u jaxghu rFkk izfrpqEcdh; gksrs gSaA
(C) nksuksa _.kk;u jaxhu rFkk izfrpqEcdh; gksrs gSaA
(D) nksuksa KMnO4 rFkk K2C2O7 xeZ djus ij leku jaxghu vuqpqEcdh; xSls mRiUu djrs gSaA
14. Select the incorrect statement(s) related with colloids :

(A) Muddy water can be coagulated more effectively by Alums as compared to NaCl.
(B) Surface tension of lyophilic colloids is less than that of dispersion medium.
(C) When excess of AgNO3 is added in aqueous KI solution and the sol is subjected to
electrophoresis coagulations occur near the anode.
(D) A colloidal solution is a heterogeneous two phase system.
dksykWbMks ls lEcfU/kr xyr dFku@dFkuksa dk p;u dhft,&
(A) dhpM+ ;qDr ty dks NaCl dh rqyuk esa fQVdjh }kjk vf/kd izHkkoh :i ls Ldafnr dj ldrs gSA
(B) nzoLusgh dksykWbMks dk i`"B ruko ifj{ksi.k ek/;e dh vis{kk de gksrk gSA
(C) tc AgNO3 ds vkf/kD; dks tyh; KI foy;u esa feykrs gS] rks lksy oS|qrd.k lapyu ls lEcfU/kr gksrk gSA
Ldanu ,uksM+ ds lehi izkIr gksrk gSA
(D) ,d dksykWbMy foy;u] ,d fo"kekaxh nks izkoLFkk ra=k gSA
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CHEMISTRY
k
15. For a first order reaction A  B
–kt
(A) The degree of dissociation is equal to (1 – e )
CHEMISTRY
(B) A plot of reciprocal of concentration of the reactant v/s time give a straight line.
(C) The time taken for the completion of 75% reaction is twice the t½ of the reaction.
–1
(D) The pre exponential factor in the Arrhenius equation has the dimension of time .
k
,d izFke dksfV vfHkfØ;k A  B ds fy,
–kt
(A) fo;kstu dh ek=kk (1 – e ) ds cjkcj gksrh gSA
(B) vfHkdkjd lkUnzrk dk O;qRØe rFkk le; dk vkys[k ljy js[kk nsrk gSA
(C) 75% vfHkfØ;k iw.kZ gksus esa fy;k x;k le; vfHkfØ;k ds t½ dk nqxquk gksrk gSA
–1
(D) vkjsfu;l lehdj.k esa iwoZ pj ?kkrkadh xq.kkad le; dh foek j[krk gSA
16. An amount of 0.01 mol of SO2Cl2 is hydrolysed completely in sufficient water (no gas is allowed to
escape out) and the solution is diluted to 200 mL. Which of the following statement is/are correct ?
(A) The solution is 0.05 M in H2SO4.
(B) The solution is 0.1 M in HCl.
(C) A volume of 20 mL of the solution exactly requires 20 mL 0.2 M NaOH solution for complete
neutralization.
(D) When 100 mL of solution is treated with excess of AgNO3 solution 1.435 g of AgCl will
precipitate out.
0.01 eksy SO2Cl2 dh ek=kk dks i;kZIr ty (dksbZ Hkh xSl fu"dkflr ugaha gksus nsrs gS) esa iw.kZr% tyvi?kfVr
djrs gS rFkk foy;u dks 200mL rd ruq fd;k tkrk gSA fuEu esa ls dkSulk @dkSuls dFku lgh gS@gSa \
(A) foy;u H2SO4 esa 0.05 M gSA
(B) foy;u HCl esa 0.1 M gSA
(C) ,d foy;u ds 20mL vk;ru dks iw.kZ mnklhuhdj.k ds fy, 20mL, 0.2M NaOH foy;u dh iw.kZr%
vko';drk gksrh gSSpace
A for Rough Work ¼d Ppsd k;Zd sfy , LFkku½
(D) tc 100mL foy;u dks AgNO3 foy;u ds vkf/kD; ds lkFk mipkfjr djrs gS] rks 1.435g AgCl vo{ksfir
gksxkA
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CHEMISTRY
17. Which reaction is/are possible ?
dkSulh vfHkfØ;k@vfHkfØ;k,¡ lEHko gS@gSa\
CHEMISTRY
(A) MgCl2 + NaNO3   (B) BaSO4 + HCl 
(C) ZnSO4 + BaS    (D) BaCO3 + CH3COOH 
18. The correct statement(s) about 'X' is/are :

'X' ds lanHkZ esa lgh dFku gS@gSa&
X=
(A) It is a non-reducing sugar.

(B) It exhibits mutarotation.
(C) It has (C1 – C4) glycosidic linkage.
(D) Its hydrolysis product is D-Galactose.
(A) ;g ,d vuvipk;d 'kdZjk gSA
(B) ;g E;wVkjksVs'ku (mutarotation) iznf'kZr djrk gSA
(C) blesa (C1 – C4) XykbdkslkbfMd ca/ku gSA
(D) blds tyvi?kVu dk mRikn D-xsysDVksl (Galactose) gSA
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CHEMISTRY
19. The correct statements about the following reaction sequence are :
fuEu vfHkfØ;k vuqØe ds lanHkZ esa lgh dFku gSa&
CHEMISTRY
KOH R– X
   
(1) (2)
R – NH2 +
(A) The hydrolysis reaction is step-3.

(B) The bimolecular nucleophilic substitution reaction (SN2) is step-2.
(C) Step–1 is an acid –base reaction.
(D) Aniline can be synthesised by this method.
(A) in-3 ty vi?kVu vfHkfØ;k gSA
(B) in-2 f}v.kqd ukfHkdLusgh izfrLFkkiu vfHkfØ;k (SN2) gSA
(C) in-1 vEy {kkj vfHkfØ;k gSA
(D) bl fof/k }kjk ,fufyu dks la'ysf"kr dj ldrs gSaA
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CHEMISTRY
O H
H O
CHEMISTRY
CH3MgBr CH3MgBr CH3MgBr
20. O  )
 (x)  )
 (y)  )
 (z) 3  (w)
(1eq (1eq (1eq
Which of the following is/are correct ?
fuEufyf[kr esa ls dkSulk@dkSuls fodYi lgh gS@gSa \
O H O CH3
OMgBr
(A) x = O (B) z =
CH3
MgBr MgBr
BrMgO CH3 HO CH3
OH
(C) y = O (D) w =
CH3
MgBr
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ADVANCED PATTERN ONLINE TEST-3 Code
P26-16
(AONT-3) XII 0
TARGET : JEE (MAIN+ADVANCED) 2017
COURSE : VIJETA (JP), VISHWAAS (JF)
11. Since it is not possible to erase and correct pen filled 11. pawfd isu ls Hkjs x, xksys feVkuk vkSj lq/kkjuk laHko ugha gS
bubble, you are advised to be extremely careful while
blfy, vki lko/kkuh iwoZd vius mÙkj ds xksyksa dks HkjsaA
darken the bubble corresponding to your answer.
12. Neither try to erase / rub / scratch the option nor 12. fodYi dks u feVk,a@u LØsp djsa vkSj u gh xyr (X) fpUg
make the Cross (X) mark on the option once filled.
dks HkjsaA ORS dks dkVs u gh QkMs u gh xUnk ugha djsa rFkk
Do not scribble, smudge, cut, tear, or wrinkle the
ORS. Do not put any stray marks or whitener
dksbZ Hkh fu'kku ;k lQsnh ORS ij ugha yxk;sA
anywhere on the ORS.
13. If there is any discrepancy between the written data 13. ;fn ORS esa fdlh izdkj dh fy[ks x, vkadMksa rFkk xksys
and the bubbled data in your ORS, the bubbled data
fd, vkadMksa esa fojks/kkHkkl gS] rks xksys fd, vkadMksa dks gh
will be taken as final.
lgh ekuk tkosxkA
C. Question Paper Format C. iz'u&i=k dk izk:i
The question paper consists of one part. This part bl iz'u&i=k esa ,d Hkkx gSaA bl Hkkx esa nks [kaM gSaA
consists are two section.
14. Section 1 contains 10 questions. The answer to 14. [kaM 1 esa 10 iz'u gSaA izR;sd iz'u dk mÙkj 0 ls 9 rd ¼nksuksa
each question is a single-digit integer, ranging from 'kkfey½ ds chp ,d ,dy vadh; iw.kkZad gSA
0 to 9 (both inclusive).
15. Section 2 contains 10 multiple choice questions. 15. [kaM 2 esa 10 cgqfodYi iz'u gaSA gj iz'u esa pkj fodYi (A),
Each question has Four choices (A), (B), (C) and (D) (B), (C) vkSj (D) gSa ftuesa ls ,d ;k ,d ls vf/kd fodYi
out of which ONE OR MORE THAN ONE is correct. lgh gSaA
D. Marking Scheme D. vadu ;kstuk
16. For each question in Section 1, you will be awarded 16. [kaM 1 esa gj iz'u esa dsoy lgh mÙkj okys cqycqys(BUBBLES)
4 marks if you darken the bubble corresponding to
dks dkyk djus ij 4 vad vkSj dksbZ Hkh cqycwyk dkyk ughaa djus ij
only the correct answer and zero mark if no bubbles
(0) vad iznku fd, tk;saxsA vU; lHkh fLFkfr;ksa esa _.kkRed ,d
are darkened. In all other cases, minus one (–1) mark
will be awarded. (–1) vad iznku fd;k tk;sxkA
17. For each question in Section 2, you will be awarded 17. [kaM 2 esa gj iz'u esa dsoy lgh mÙkj okys cqycqys(BUBBLES)
4 marks if you darken the bubble corresponding to dks dkyk djus ij 4 vad vkSj dksbZ Hkh cqycwyk dkyk ughaa djus ij
only the correct answer and zero mark if no bubbles
(0) vad iznku fd, tk;saxsA vU; lHkh fLFkfr;ksa esa _.kkRed ,d
are darkened. In all other cases, minus one (–1) mark
(–1) vad iznku fd;k tk;sxkA
will be awarded.
Name of the Candidate (ijh{kkFkhZ dk uke) : Roll Number (jksy uEcj) :
I have read all the instructions and shall I have verified all the information filled by
abide by them the candidate.
eSaus lHkh funsZ'kksa dks i<+ fy;k gS vkSj eSa mudk ijh{kkFkhZ }kjk Hkjh xbZ lkjh tkudkjh dks eSusa
vo'; ikyu d:¡xk@d:¡xhA tk¡p fy;k gSA
...................................... ......................................
Signature of the Candidate Signature of the Invigilator
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj
Resonance Eduventures Ltd. P26-16
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(CHEMISTRY)  = nO2 × 4
1. 0.2 gm of a solution ……… NH3 d srq

Y;kad d h la[;k = 1 × 4 = 4
NaOH o Na2CO3 rFkk ………
6. If for a reaction A  products ………
Sol. NaOH + Na2CO3 + Impurity (v'kq
f) )
;fn vfHkfØ ;k A  mRikn ………
x y
1 2.303 Co
x  1  y  1  17.5  Sol. K1 = log
10 t aCo
1 2.303 Co
y  1  2.5   x = 1.5 mm, y = 0.25 mm K2 = log
10 2t a 2 Co
0.06 2.303 Co
%NaOH   100  30% K3 = log
0.2 3t a 3 Co
%Na 2CO3  13.25%
K1 = K2 = K3 = constant fu;r
2. During dissolution ………

7. Out of following polymers………
ruqukbfVªd vEy ……… fuEufy f[kr esalsfd rus………
Sol. 3PbS + 8HNO3 3Pb(NO3)2 + 2NO + 4H2O + 3S Sol. Polysterene, PVC, Polyacrylonitrile, Teflon, Neoprene,
Polythene, are addition polymer as well as homopolymer.
3. How many of the following ………
ikWy hLVkbfju, PVC, ikWy h,Ø kby ksukbVªkby , Vs¶y ku, fu;ksçhu rFkk
fuEu esalsfd rusd Fku ………
ikWy hFkhu ;ksxkRed o lecgqy d nksuksagSA
Sol. (1) Silica gel adsorbs moisture
(2) True
(3) True. (Bonds weaken on the surface) 8. Total number of aldol ………
(4) True fuEu vfHkfØ ;k esacuus………
(5) True (Chemisorption need activation energy. Sol.
(6) True, physisorption is due to weak attractive forces,
hence it occurs little farther from surface atoms in
comparison to chemisorption. Moreover the decrease in
potential energy is more in chemisorption than in
physisorption.
(1) flfy d k t Sy ueh vf/k'kksf"kr d jrk gSA
(2) lR;
(3) lR;A ¼lrg ij cU/k nq cZy gksrsgSA½
(4) lR;
(5) lR; ¼jklk;fud vf/k'kks "k.k d ks lfØ ;.k Å t kZ d h
vko';d rk gksrh gSA½
(6) lR;] HkkS frd vf/k'kks"k.k nqcZy vkd "kZ.k cy d sd kj.k gksrk
gSvr% ;g jklk;fud vf/k'kks"k.k d h rqy uk eslrg ijek.kql s
FkksM +h nwj gksrk gS fLFkfrt Å t kZ ft ruh d e gksxh jklk;fud
vf/k'kks"k.k] HkkSfrd vf/k'kks"k.k d h rqy uk esamruk gh vf/kd gksxkA
9. How many of these amino ………
4. After complete hydrolysis ……… fuEu esalsfd rus,ehuksa………
XeF6 d siw
.kZt y vi?kVu ……… Sol. Neutral amino acid & acidic amino acid are negatively charged
Sol. XeF6 + 3H2O  XeO3 + 6HF at pH = 7.0
Alanine , Glumatic acid , Glycine, Leucine , Aspartic acid
5. NH3 is oxidized to NO ……… mnklhu ,ehuksa vEy rFkk vEy h; ,ehuksa vEy pH = 7.0 ij
{kkjh; ek/;e esaNH3,O2 ……… _ .kkosf'kr gksrsgSA
Sol. 4NH3 + 5O2  4NO + 6H2O ,y suhu, Xy wesfVd vEy ]Xy k;lhu, Y;wl hu],LikfVZd vEy
v.f. = 5 v.f. = 4
Number of equiv. of NH3 = Number of equiv. of O2 O
 = nO2 × 4 COOH 
10. COOH
 ………
Number of equiv. of NH3 = 1 × 4 = 4
Sol. 4NH3 + 5O2  4NO + 6H2O
HO2C CO2H
v.f. = 5 v.f. = 4
Sol. x=3 y=3
NH3 d srq
Y;kad d h la[;k= O2 d srqY;kad d h la[;k x+y=6
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SOLJP/JFAONT3090217-5
O 16. An amount of 0.01 mol ………
0.01 eksy SO2Cl2 d h ek=kk ………
Final product is (three moles of CO2 evolved)
Sol. Hint: l a
d sr: SO2Cl2 + 2H2O  2HCl + H2SO4
COOH 17. Which reaction is/are ………

O d kSulh vfHkfØ ;k@vfHkfØ ;k,¡………
MgCl2 + 2NaNO3  2Na+ + Mg2+ + 2Cl– + 2 NO3 (N.R.)
–
Sol.
Kkr mRikn gS (CO2 d srhu eksy fu"d kflr gksrsgS)
BaSO4 + HCl  N.R.
ZnSO4 + BaS
COOH
 ZnS  ZnS  + BaSO 4  BaSO4 
O white 'osr white 'osr
Ph BaCO3+2CH3COOH  Ba2++2CH3COO– + CO2 + H2O
*
y= (2)
COOH 18. The correct statement(s) ………
(±) 'X' d slanHkZesalgh d Fku ………
O Sol. It is non-reducing sugar because it lacks hemiacetal linkage. Its
Ph (1) hydrolysis product is -D-Glucose.
;g ,d vuvipk;d 'kd Zjk gS D;ksafd blesa gseh,lhVy ca/ku
COOH
mifLFkr ughagSA bld st y vi?kVu d k mRikn -D-Xy wd kst gSA
11. For a certain reaction ………
19. The correct statements about ………
,d fuf'pr vfHkfØ ;k ………
fuEu vfHkfØ ;k vuqØ e ………
Sol. t1/2  [A0]1–n
100  [0.1]1–n ......(1)
50  [0.025]1–n ......(2)
KOH KOH
Dividing (1) by (2) Sol.    
acid base vEy {kkj
(1) d ks(2) lsfoHkkft r d jusij reaction vfHkfØ ; k
1–n
2=4   n = 1/2
When t c [A0] = 1M
t1/2  [1](1 – 1/2) R– X
 
and rFkk100  [0.1]1/2
SN2
1/ 2
t  1 
 1/ 2 =    t1/2 = 100 10 seconds.
100  0.1 
12. Cl2 + NH3(excess) ………

Cl2 + NH3(vkf/kD;) ………
t y vi?kVu
Sol. 3X2 + 8NH3 N2 + 6NH4X
(X : Cl, Br)
13. The correct statement(s) ………

R–NH2 (1° – amine ,ehu ) +
MnO4– rFkkCr2O72–
d s………
Sol. MnO4 purple t keq
–
uh
Cr2O72– Orange ukja
xh
 O H
2KMnO4   K2MnO4 + MnO2 + O2
2K2Cr2O7

  2K2CrO4 + Cr2O3 + 3 O2 20. O
CH3MgBr
  ………
2 )(1eq
15. For a first order reaction ……… O H O H

,d izFke d ksfV vfHkfØ ;k ………
Sol. (A) A  Product (mRikn) CH MgBr
Sol. O (13 
mol )
O
t=0 a 0
a(1–)
a(1–) = a e–k.t MgBr
 = 1 – e–k.t
(C) Correct. lgh
(D) Correct. lgh
BrMgO CH3
CH3MgBr
  
(1 mol ) O
MgBr
HO CH3
H3O  OH
CH3MgBr
   
(1 mol ) CH3
CHEMISTRY
1. (3) 2. (4) 3. (5) 4. (6) 5. (4) 6. (1) 7. (6)
8. (6) 9. (5) 10. (6) 11. (AD) 12. (ABD) 13. (CD) 14. (C)
15. (ACD) 16. (ABCD) 17. (CD) 18. (AC) 19. (ABC) 20. (ACD)
SOLJPSCTSTREAM-A170416-13

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P26-16

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

 This section contains TEN questions

 bl [kaM esa nl iz'u gSaA

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

the original mixture. Give your answer after dividing by 10.

of disappearance of HNO3 to instantaneous rate of appearance of NO(gas) is :

gksus dh rkR{kf.kd nj dk vuqikr gS&

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

Graph A represent chemisorption and graph B represent physisorption.

fLFkfrt Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

5. NH3 is oxidized to NO by O2 in basic medium. Number of equivalents of NH3 oxidized by 1 mole O2

0, t, 2t, 3t …. where a is constant 0 < a < 1. The order of reaction is :

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

12. Cl2 + NH3(excess)  A + B

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

14. Select the incorrect statement(s) related with colloids :

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

18. The correct statement(s) about 'X' is/are :

(A) It is a non-reducing sugar.

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

(A) The hydrolysis reaction is step-3.

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

Which of the following is/are correct ?

fuEufyf[kr esa ls dkSulk@dkSuls fodYi lgh gS@gSa \

BrMgO CH3 HO CH3

Space for Rough Work ¼d Ppsd k;Zd sfy , LFkku½

Name of the Candidate (ijh{kkFkhZ dk uke) : Roll Number (jksy uEcj) :

Resonance Eduventures Ltd. P26-16

1. 0.2 gm of a solution ……… NH3 d srq

2. During dissolution ………

COOH 17. Which reaction is/are ………

12. Cl2 + NH3(excess) ………

13. The correct statement(s) ………

15. For a first order reaction ……… O H O H

1. (3) 2. (4) 3. (5) 4. (6) 5. (4) 6. (1) 7. (6)

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