D19IA005EN H ClassifiedListofApplications

::: Multiwave PRO – Classified List of Applications
Introduction and General Hints
All methods in this list are conservative recommendations. Different samples of the same sample type may show a
different reaction behavior. As a consequence, modifications of reagent mixtures and/or programs (e.g. longer ramp
time to avoid spontaneous reactions, longer hold time to obtain appropriate results) may be required. It is the user's
responsibility to adapt the methods with respect to the sample material.
The 'Generic Methods' will serve as a good starting point, if no other suitable method can be found. Use the
appropriate method according to the sample characteristics ('reactive' or 'inert') and to the type and number of vessels.
Start preliminary experiments with the lower sample weight given in the table!
When digesting sample materials, which tend to react spontaneously (like many organic materials and even metals),
we recommend to increase the ramp time and to reduce the pressure increase rate to 0.3 bar/s.
If a vigorous reaction is observed after addition of reagents, wait for 10-15 min before closing the vessels. If the
samples do not react spontaneously during the preliminary runs, you may increase the sample weight stepwise up to
the max. recommended sample weight.
For sample materials which tend to float on the surface, we recommend to use the stirring option in order to improve
the contact between sample and acid.
When running a temperature profile with a higher number of vessels than given in the table, extend the ramp time for
another 5-10 minutes.
After a digestion with hydrofluoric acid a subsequent complexation run may be necessary to complex free fluorides.
Add 6 mL of a cold-saturated boric acid solution (approx. 5 % H3BO3) per mL used acid.
We recommend to use Rotor 8NXQ80 with quartz vessels for ultra-trace analysis of e.g. Hg, Se, As.
All used reagents must be of appropriate purity and following concentration:

HNO3: 65 % HCl: 30-32 % HF: 40-48 % H2SO4: 96 % H3PO4: 85 % HClO4: 70-72 % H2O2: 30 %
Before starting with any application carefully read the instruction manual!
D19IA005EN-H 1 www.anton-paar.com
Content / Categories
1 Cleaning 3
2 Generic Methods 6
3 Ceramics and Oxides 14
4 Coal 17
5 Complexation 19
6 Drying 20
7 Environment 21
8 Evaporation 27
9 Food and Feed 29
10 Geology 34
11 Materials 38
12 Metals 41
13 Performance 46
14 Petrochemistry 49
15 Pharmaceutical and Medical 51
16 Plastics 55
17 Extraction* 58
* Safety Module SOLV PRO required
1 Cleaning
Limits Program
Sample
Program
Sample Rotor Vessels Amount Reagents Stirrer Notes
Type Temp/
[mg] T/IR P p-rate Ramp Hold Fan
Power
900 W 5 15 1
4 mL HNO3 Occasionally heat the TFM-liners in a drying oven
Cleaning Power
8NXF100 4 900 70 °C 3 after the cleaning run .
NXF100-4 4 mL H2O (200 °C for 4 h or 250 °C for 2 h).
1300 W 5 15 1
Cleaning 4 mL HNO3 Occasionally heat the TFM-liners in a drying oven
8NXF100 8 1300 Power 70 °C 3 after the cleaning run .
NXF100-8
4 mL H2O (200 °C for 4 h or 250 °C for 2 h)
900 W 5 15 1
Cleaning 4 mL HNO3
8NXQ80 4 900 Power 70 °C 3
NXQ80-4
4 mL H2O
1300 W 5 15 1
Cleaning 4 mL HNO3
8NXQ80 8 1300 Power 70 °C 3
NXQ80-8
4 mL H2O
900 W 5 10 1
16MF100 8 900 Power 600 W 15 1 after the cleaning run .
MF100-8
70 °C 3
1300 W 5 15 1
16MF100 16 1300 Power 600 W 10 1 after the cleaning run .
MF100-16
70 °C 3
Cleaning
Limits Program
Sample
Program
Type Temp/
Power
950 W 5 10 1
16HF100 8 200 950 Power 550 W 15 1 after the cleaning run.
HF100-8
70 °C 3
1300 W 5 15 1
16HF100 16 200 Power 550 W 10 1 after the cleaning run.
HF100-16
70 °C 3
180 °C 5 10 1
Cleaning Occasionally heat the vessel body in a drying oven
4 mL HNO3 Temp -
24HVT50- 24HVT50 12 1000 70 °C 3 after the cleaning run.
AVG
12 4 mL H2O (200 °C for 4 h or 250 °C for 2 h)
180 °C 5 10 1
4 mL HNO3 Temp -
MAX
180 °C 5 10 1
4 mL HNO3 Temp -
AVG
Cleaning
Limits Program
Sample
Program
Type Temp/
Power
180 °C 5 10 1
4 mL HNO3 Temp -
MAX
950 W 5 15 1
Cleaning 4 mL HNO3 Occasionally heat the liners in a drying oven after the
48MF50 16 130 950 Power 60 °C 3 cleaning run.
48MF50-16
4 mL H2O (200 °C for 4 h)
1300 W 5 15 1
48MF50 24 130 1300 Power 60 °C 3 cleaning run.
48MF50-24
4 mL H2O (200 °C for 4 h)
1500 W 5 15 1
48MF50 48 130 Power 60 °C 3 cleaning run.
48MF50-48
4 mL H2O (200 °C for 4 h)
2 Generic Methods
Limits Program
Sample
Program
Type Temp/
Power
400 W 10 1
.Generic-
Reactive 48 5 mL HNO3
48MF50 24 100-300 90 0.3 Power 200 W 25 1 The use of a p/T-sensor is highly recommended.
MF 50-24 1 mL H2O
60 °C 3
550 W 20 1
.Generic-
Reactive 6 mL HNO3 The use of a p- or p/T-sensor is highly
16MF100 4 100-500 145 0.3 Power 300 W 15 1
MF100-4 1 mL H2O recommended.
70 °C 3
650 W 20 1
.Generic-
16MF100 8 100-500 145 0.3 Power 350 W 15 1
70 °C 3
1200 W 20 1
.Generic-
16MF100 16 100-500 145 0.3 Power 500 W 15 1
70 °C 3
600 W 20 1
.Generic-
16HF100 4 100-500 190 0.3 Power 400 W 20 1
HF100-4 1 mL H2O recommended.
70 °C 3
950 W 20 1
.Generic-
Reactive 950 6 mL HNO3 The use of a p- or p/T-sensor is highly
16HF100 8 100-500 190 0.3 Power 450 W 15 1
70 °C 3
Generic Methods
Limits Program
Sample
Program
Type Temp/
Power
1250 W 20 1
.Generic-
16HF100 16 100-500 190 1250 0.3 Power 450 W 20 1
70 °C 3
350 W 20 1
.Generic-
6 mL HNO3
Reactive 8NXF100 4 100-500 800 0.3 Power 800 W 15 15 1
NXF100-4 1 mL H2O
70 °C 3
500 W 20 1
.Generic-
6 mL HNO3
Reactive 8NXF100 8 100-500 1200 0.3 Power 1200 W 15 15 1
NXF100-8 1 mL H2O
70 °C 3
350 W 20 1
.Generic-
6 mL HNO3
Reactive 8NXQ80 4 100-500 800 0.3 Power 800 W 15 15 1
NXQ80-4 1 mL H2O
70 °C 3
500 W 20 1
.Generic- 6 mL HNO3
Reactive 8NXQ80 8 100-500 1200 0.3 Power 1200 W 15 15 1
NXQ80-8 1 mL H2O
70 °C 3
180 °C 20 10 1
.Generic- 6-10 mL HNO3
Temp -
Organic A 24HVT50 4 0.5-1 g 200 800 0-1 mL HCl 70 °C 3
AVG
24HVT50-4 0-1 mL H2O2
Generic Methods
Limits Program
Sample
Program
Type Temp/
Power
180 °C 20 10 1
Organic A Temp -
24HVT50 12 0.5-1 g 200 1000 0-1 mL HCl 70 °C 3
24HVT50- AVG
12 0-1 mL H2O2
180 °C 20 10 1
Organic A Temp -
24HVT50 24 0.5-1 g 200 1500 0-1 mL HCl 70 °C 3
24HVT50- AVG
24 0-1 mL H2O2
100 °C 10 10 1
Temp -
Organic B 24HVT50 4 0.5-1 g 200 800 0-1 mL HCl 180 °C 10 10 1
MAX
24HVT50-4 0-1 mL H2O2
70 °C 3
100 °C 10 10 1
Organic B Temp -
24HVT50 12 0.5-1 g 200 1000 0-1 mL HCl 180 °C 10 10 1
24HVT50- MAX
12 0-1 mL H2O2
70 °C 3
100 °C 10 10 1
Organic B Temp -
24HVT50 24 0.5-1 g 200 1500 0-1 mL HCl 180 °C 10 10 1
24HVT50- MAX
24 0-1 mL H2O2
70 °C 3
Generic Methods
Limits Program
Sample
Program
Type Temp/
Power
180 °C 20 10 1
Temp -
Organic A 24HVT80 4 0.5-1 g 200 800 0-1 mL HCl 70 °C 3
AVG
24HVT80-4 0-1 mL H2O2
.Generic- 180 °C 20 10 1
6-10 mL HNO3
Organic A Temp -
24HVT80 12 0.5-1 g 200 1000 0-1 mL HCl 70 °C 3
24HVT80- AVG
12 0-1 mL H2O2
.Generic- 180 °C 20 10 1
6-10 mL HNO3
Organic A Temp -
24HVT80 24 0.5-1 g 200 1500 0-1 mL HCl 70 °C 3
24HVT80- AVG
24 0-1 mL H2O2
100 °C 10 10 1
Temp -
Organic B 24HVT80 4 0.5-1 g 200 800 0-1 mL HCl 180 °C 10 10 1
MAX
24HVT80-4 0-1 mL H2O2
70 °C 3
100 °C 10 10 1
Organic B Temp -
24HVT80 12 0.5-1 g 200 1000 0-1 mL HCl 180 °C 10 10 1
24HVT80- MAX
12 0-1 mL H2O2
70 °C 3
100 °C 10 10 1
Organic B Temp -
24HVT80 24 0.5-1 g 200 1500 0-1 mL HCl 180 °C 10 10 1
24HVT80- MAX
24 0-1 mL H2O2
70 °C 3
Generic Methods
Limits Program
Sample
Program
Type Temp/
Power
165 °C 10 10 1
Temp -
Inorganic 24HVT50 4 0.5-2 g 180 800 0-1 mL HCl 70 °C 3
AVG
24HVT50-4 0-1 mL H2O2
.Generic- 165 °C 10 10 1
Inorganic 0-9 mL HCl Temp -
24HVT50 12 0.5-2 g 180 1000 70 °C 3
24HVT50- 0-12 mL HNO3 AVG
12
.Generic- 165 °C 10 10 1
24HVT50 24 0.5-2 g 180 1500 70 °C 3
24HVT50- 0-12 mL HNO3 MAX
24
165 °C 10 10 1
.Generic- 0-9 mL HCl Temp -
Inorganic 24HVT80 4 0.5-2 g 180 800 70 °C 3
0-12 mL HNO3 AVG
24HVT80-4
165 °C 10 10 1
.Generic-
24HVT80 12 0.5-2 g 180 1000 70 °C 3
24HVT80- 0-12 mL HNO3 AVG
12
165 °C 10 10 1
.Generic-
24HVT80 24 0.5-2 g 180 1500 70 °C 3
24HVT80- 0-12 mL HNO3 MAX
24
Generic Methods
Limits Program
Sample
Program
Type Temp/
Power
1500 W 5 1
.Generic-
4.5 mL HCl
Inert 48MF50 24 200-500 130 Power 400 W 25 1
48MF50-24 1.5 mL HNO3
60 °C 3
950 W 5 1
.Generic-
4.5 mL HCl
Inert 16MF100 4 200-600 950 Power 350 W 25 1
MF100-4 1.5 mL HNO3
70 °C 3
1200 W 5 1
.Generic-
4.5 mL HCl
Inert 16MF100 8 200-600 1200 Power 350 W 20 1
MF100-8 1.5 mL HNO3
70 °C 3
1500 W 5 5 1
.Generic-
4.5 mL HCl
Inert 16MF100 16 200-600 Power 450 W 20 1
MF100-16 1.5 mL HNO3
70 °C 3
1100 W 5 1
.Generic-
4.5 mL HCl
Inert 16HF100 4 200-600 200 1100 Power 300 W 25 1
HF100-4 1.5 mL HNO3
70 °C 3
1500 W 5 5 1
.Generic- 4.5 mL HCl
Inert 16HF100 8 200-600 200 1500 Power 400 W 20 1
HF100-8 1.5 mL HNO3
70 °C 3
Generic Methods
Limits Program
Sample
Program
Type Temp/
Power
1500 W 5 10 1
Inert 16HF100 16 200-600 200 1500 Power 450 W 15 1
HF100-16 1.5 mL HNO3
70 °C 3
900 W 5 35 1
Inert 8NXF100 4 200-600 900 0.8 Power 70 °C 3
NXF100-4 1.5 mL HNO3
1200 W 5 35 1
Inert 8NXF100 8 200-600 1200 0.8 Power 70 °C 3
NXF100-8 1.5 mL HNO3
900 W 5 35 1
Inert 8NXQ80 4 200-600 900 0.8 Power 70 °C 3
NXQ80-4 1.5 mL HNO3
1200 W 5 35 1
Inert 8NXQ80 8 200-600 1200 0.8 Power 70 °C 3
NXQ80-8 1.5 mL HNO3
900 W 30 1
2 mL HNO3 O2-
MIC-4
8NXQ80 4 900 0.8 Combus- 70 °C 3 Use 8 mL of diluted HNO3 (10 to 30%)
Initialization 6 mL H2O tion
Generic Methods
Limits Program
Sample
Program
Type Temp/
Power
1500 W 30 1
MIC-8 2 mL HNO3 O2- Use 8 mL of diluted HNO3 (10 to 30%)
8NXQ80 8 1500 0.8 70 °C 3
Initialization 6 mL H2O Combus-
tion
900 W 10 1 Perform an acidic cleaning run after combustion e.g.

O2 Initialization
O2- 70 °C 3
MIC-4 10 mL Use wet ( 0.050mL NH4NO3 50% ) ash free filter
8NXQ80 4 100-500 900 0.8 Combus-
Combustion (NH4)2CO3 paper to ignite sample.
tion
Use 10mL of a 50mM to 200mM (NH4)2CO3 solution
for absorption.
1500 W 10 1
O2-
MIC-8 10 mL Perform an acidic cleaning run after combustion e.g.
8NXQ80 8 100-500 1500 0.8 Combus- 70 °C 3
Combustion (NH4)2CO3 O2 Initialization
tion
3 Ceramics and Oxides

Limits Program
Sample
Program
Type Temp/
Power
3 mL H2SO4 1500 W 5 50 1
Al2O3 with 3 mL H3PO4 Subsequent complexation run with saturated boric
8NXF100 8 200 1500 0.8 Power 70 °C 3
SiO2 4 mL H2O acid solution required.
2 mL HF
4 mL HNO3 1500 W 5 60 1
4 mL HF Subsequent complexation run with saturated boric
Al2O3 8NXF100 8 200 1500 0.8 Power 70 °C 3
2 mL HClO4 acid solution required.
4 mL H2SO4
850 W 5 40 1
2 mL HCl
Antimony
8NXF100 4 100-200 3 mL H3PO4 Power 70 °C 3
trioxide
2 mL HClO4
Catalyst, 850 W 10 90 1
8 mL H2SO4
spent Subsequent complexation run with saturated boric
8NXF100 4 100 5 mL HF Power 70 °C 3
(PGM acid solution required.
loaded) 4 mL HCl
1300 W 10 20 1
Co oxide 16HF100 8 500 1300 10 mL HCl Power 70 °C 3
3 mL H2SO4 240 °C 15 25 1
3 mL H3PO4
70 °C 3 Subsequent complexation run with saturated boric
Cr oxide-1 16HF100 8 200-400 1500 1 mL HF Temp
acid solution required.
1 mL H2O
1 mL HClO4
Ceramics and Oxides

Limits Program
Sample
Program
Type Temp/
Power
4 mL HNO3 1200 W 15 90 1
Cr oxide-2 8NXF100 8 200-400 Power 70 °C 3
2mL HClO4 acid solution required.
4 mL H2SO4
4 mL HCl 1500 W 5 25 1
2 mL HNO3 Subsequent complexation run with saturated boric
Fe oxide 16HF100 16 500 1500 Power 70 °C 3
2 mL HF acid solution required.
2 mL H2O
240 °C 10 15 1
Hf oxide 16HF100 8 0.5-1 g 1500 Temp 70 °C 3
7 mL HCl acid solution required.
850 W 10 40 1
Mn(II)O 8NXF100 4 400-600 Power 70 °C 3
1000 W 5 25 1
3 mL HNO3
Subsequent complexation run with saturated boric
Porcelain 16HF100 8 100-300 1000 2 mL HF Power 70 °C 3
2 mL H2SO4
850 W 5 85 1
5 mL H3PO4
Refractory Subsequent complexation run with saturated boric
8NXF100 4 200-400 3 mL HF Power 70 °C 3
oxides acid solution required.
2 mL HClO4
Ceramics and Oxides

Limits Program
Sample
Program
Type Temp/
Power
220 °C 15 30 1
16HF100 4 mL HNO3 Subsequent complexation run with saturated boric
Ta oxide 8 200-400 200 1500 Temp 70 °C 3
1500 W 10 20 1
Ti oxide 8NXF100 8 300-600 1500 Power 70 °C 3
3 mL H2O acid solution required.
850 W 15 45 1
5 mL HNO3
8NXF100
W oxide 4 200-400 0.3 5 mL H2O Power 70 °C 3 Dissolve NH4F in water before adding HNO3.
2 g NH4F
240 °C 15 20 1
2 mL HNO3
Zn oxide 16HF100 8 200-600 1500 2 mL H2O Temp 70 °C 3
2 mL H3PO4
850 W 5 70 1
Zr oxide-1 4 mL HNO3
8NXF100 4 Complexation with additional 4 mL HNO3 + 12 mL
(ZrO2, 100-300 2 mL HF Power 70 °C 3
H3BO3.
Zirconia) 4 mL H2SO4
4 mL HCl 1500 W 5 30 1
Zr oxide-2 2 mL HF Subsequent complexation run with saturated boric
(ZrO2, 16HF100 16 100-300 Power 70 °C 3
Zirconia)
4 mL H2SO4
4 Coal
Limits Program
Sample
Program
Type Temp/
Power
1500 W 15 20 1
6 mL HNO3
Activated low
8NXF100 8 250 1500 1 mL HCl Power 70 °C 3
carbon
1 mL H2O
850 W 10 60 1
5 mL HNO3 low Subsequent complexation run with saturated boric
Ash-1 8NXF100 4 100 850 Power 70 °C 3
850 W 15 45 1
3 mL HNO3
70 °C 3 Subsequent complexation run with saturated boric
3 mL HCl
Ash-2 8NXF100 4 200-300 0.3 Power acid solution required.
2 mL HF Add 4 mL HNO3 to the subsequent complexation run.
2 mL HClO4
850 W 15 40 1
Carbon 6 mL HNO3
8NXF100 4 200 850 Power 70 °C 3 low
fiber 2 mL H2O2
240 °C 10 30 1
8 mL HNO3
Charcoal 16HF100 8 200-400 200 1500 Temp 70 °C 3
2 mL H2O2
850 W 10 50 1
4 mL HNO3
Coal-1 8NXF100 4 250 850 2 mL HF Power 70 °C 3 low
2 mL H2O2
Coal
Limits Program
Sample
Program
Type Temp/
Power
850 W 5 55 1
7 mL HNO3
Coal-2 8NXF100 4 200-400 0.3 2 mL HF Power 70 °C 3 acid solution required.
2 mL HClO4
850 W 15 45 1
7.5 mL HNO3
Coal-3 8NXQ80 4 300-500 0.3 Power 70 °C 3
0.5 mL H2O2
750 W 20 45 1
5 mL HNO3
Coke-1 8NXQ80 4 500 0.3 2 mL HClO4 Power 70 °C 3
5 mL H2SO4
850 W 10 45 1
6 mL HNO3
Coke-2 8NXF100 4 100 850 2 mL H2O2 Power 70 °C 3 low
2 mL HF
650 W 10 50 1
2 mL HNO3
Graphite 8NXF100 4 200-400 0.3 3 mL H2SO4 Power 70 °C 3
2 mL HClO4
5 Complexation
Limits Program
Sample
Program
Type Temp/
Power
950 W 5 15 1
Complex-
Add 6 mL saturated boric acid solution for each mL
ation 16MF100 8 950 H3BO3 Power 70 °C 3
used HF, to complex free fluorides.
MF100-8
1500 W 5 15 1
Complex-
ation 16MF100 16 1500 H3BO3 Power 70 °C 3
MF100-16
950 W 5 15 1
Complex-
ation 16HF100 8 950 H3BO3 Power 70 °C 3
HF100-8
1500 W 5 15 1
Complex-
ation 16HF100 16 1500 H3BO3 Power 70 °C 3
HF100-16
950 W 5 15 1
Complex-
ation 8NXF100 4 950 H3BO3 Power 70 °C 3
NXF100-4
1500 W 5 15 1
Complex-
ation 8NXF100 8 1500 H3BO3 Power 70 °C 3
NXF100-8
6 Drying
Limits Program
Sample
Program
Type Temp/
Power
100 W 1 1
Use dishes to place samples in the rotor!
Food DRY 1 10g Power 270 W 20 10 1 For powdered material cover the dish with a watch
glass
0W 15 2
100 W 1 1
Use dishes to place samples in the rotor!
Sludge DRY 1 50g Power 270 W 10 30 1 Depending on the water content, extend the second
program step.
0W 15 2
300 W 1 1
Place sample in large evaporation dishes!
Soil DRY 1 500g Power 700 W 20 10 1 Depending on the water content, extend the second
program step.
0W 15 2
100 W 1 1
Starch DRY 1 10g Power 160 W 30 10 1 Use dishes to place samples in the rotor!
0W 15 2
7 Environment
Limits Program
Sample
Program
Type Temp/
Power
240 °C 15 45 1
4 mL HNO3
1500
Clay 16HF100 8 100-300 4 mL H3PO4 Temp 70 °C 3
2 mL HClO4
170 °C 20 10 1
ASTM Water, aqueous samples.
3 mL HNO3 Temp -
D4309 - 24HVT80 8 50 mL 200 1200 70 °C 3 For GFAAS, use 5 mL HNO3 instead.
2 mL HCl AVG
8 vessels Refer to ASTM D4309 for more details.
160 °C 15 1
3 mL HNO3 Temp -
D4309 - 24HVT80 16 50 mL 200 1500 165 °C 5 10 1 For GFAAS, use 5 mL HNO3 instead.
2 mL HCl AVG
70 °C 3
160 °C 5 1
3 mL HNO3 Temp -
D4309 - 24HVT80 24 50 mL 200 1500 165 °C 15 10 1 For GFAAS, use 5 mL HNO3 instead.
2 mL HCl AVG
70 °C 3
165 °C 10 0
EPA Water, aqueous samples.
3015A - 16MF100 8 45mL 1500 0.8 5 mL HNO3 Temp 170 °C 10 1 For 4 and 8 vessels.
8 vessels Refer to EPA 3015A for more details.
70 °C 3
165 °C 00:10 09:50 0

EPA Water, aqueous samples.
3015A - 16MF100 16 45mL 1500 0.8 5 mL HNO3 Temp 170 °C 10 1 For 16 vessels.
16 vessels Refer to EPA 3015A for more details.
70 °C 3
Environment
Limits Program
Sample
Program
Type Temp/
Power
170 °C 10 10 1
EPA 3015A 2.5/2 mL HNO3 Water, aqueous samples.
Temp -
-HVT50 24HVT50 24 22.5 mL 200 1500 70 °C 3
0/0.5 mL HCl AVG Refer to EPA 3015A for more details.
half-scale
170 °C 10 10 1
EPA 3015A 5/4 mL HNO3 Temp - Water, aqueous samples.
24HVT80 20 45 mL 200 1500 70 °C 3
-HVT80 0/1 mL HCl AVG Refer to EPA 3015A for more details.
170 °C 05:30 0 Sediments, soil, sludge, contaminated soil and oils

EPA 3051A (oil <0.25g!).
16MF100 8 250-500 1500 0.8 10 mL HNO3 Temp 175 °C 04:30 1
-8 vessels For 4 and 8 vessels.
70 °C 3 Refer to EPA 3051A for more details.
170 °C 00:10 05:20 0 Sediments, soil, sludge, contaminated soil and oils
EPA 3051A (oil <0.25g!).
16MF100 16 250-500 1500 0.8 10 mL HNO3 Temp 175 °C 04:30 1
-16 vessels For 16 vessels.
70 °C 3 Refer to EPA 3051A for more details.
175 °C 5:30 4:30 1

EPA 3051A 10/9 mL HNO3 Temp - For sediments, soil, sludge, oils (oil <0,25g!).
24HVT50 20 250-500 200 1500 70 °C 3
-HVT50 0/3 mL HCl AVG Refer to EPA 3051A for more details.
175 °C 5:30 4:30 1

For sediments, soil, sludge, oils (oil <0,25g!). For
EPA 3051A 10/9 mL HNO3 Temp -
24HVT80 20 250-500 200 1500 70 °C 3 sediments, soil, sludge, oils (oil <0,25g!).
-HVT80 0/3 mL HCl AVG
Refer to EPA 3051A for more details.
Environment
Limits Program
Sample
Program
Type Temp/
Power
180 °C 05:30 0 Siliceous and organically based matrices for 8

vessels.
EPA 3052 - 0.1g - 180 °C 09:30 1
16MF100 8 1500 0.8 9 mL HNO3 Temp Digest reactive samples with a longer heating ramp!
8 vessels 1.0g
Reagent optimization: add 0-5mL HF, 0-4mL HCl or
70 °C 3 0-2mL H2O2
180 °C 10 0 Siliceous and organically based matrices for 16

vessels.
EPA 3052 - 0.1g - 180 °C 09:30 1
16MF100 16 1500 0.8 9 mL HNO3 Temp Digest reactive samples with a longer heating ramp!
16 vessels 1.0g
Reagent optimization: add 0-5mL HF, 0-4mL HCl or
70 °C 3 0-2mL H2O2
180 °C 10 9:30 1
6-10 mL HNO3
EPA 3052 - 0.1g - Temp - For siliceous and organically based matrices.
24HVT50 24 200 1500 0-1 mL HCl 70 °C 3
HVT50 1.0g AVG Refer to EPA 3052 for more details.
0-1 mL HF
180 °C 10 9:30 1
6-10 mL HNO3
EPA 3052 - 0.1g - Temp - For siliceous and organically based matrices.
24HVT80 24 200 1500 0-1 mL HCl 70 °C 3
HVT80 1.0g AVG Refer to EPA 3052 for more details.
0-1 mL HF
1400 W 10 30 1
Filter, 4 mL HNO3
cellulose 8NXF100 8 500 1400 0.3 1 mL HCl Power 70 °C 3
nitrate 2 mL H2O
1500 W 10 30 1
5 mL HNO3 The use of a p or p/T-sensor is highly recommended.
Filter, glass
16HF100 16 500 200 0.3 1 mL HCl Power 70 °C 3 Subsequent complexation run with saturated boric
fiber
Environment
Limits Program
Sample
Program
Type Temp/
Power
1500 W 5 25 1
6 mL HNO3
low Subsequent complexation run with saturated boric
Fly ash 16MF100 16 300 1500 1 mL HCl Power 70 °C 3
2 mL HF
240 °C 20 20 1
6 mL HNO3
Grass, total 16HF100 8 200-600 200 1500 0.3 1 mL HCl Temp 70 °C 3
0.5 mL HF
190 °C 10 20 1
Leaves 16MF100 8 200-500 1500 0.3 Temp 70 °C 3
220 °C 20 10 1
Leaves,
16HF100 8 0.5-1g 190 1500 0.3 10 mL HNO3 Temp 70 °C 3
vine
240 °C 15 20 1
6 mL HNO3
Peat 16HF100 8 100-250 1500 0.3 Temp 70 °C 3
1 mL HCl
1500 W 5 30 1
Sediment, 2 mL HNO3
For samples with high inorganic content.
inorganic, 16HF100 16 250 5 mL HCl Power 70 °C 3
total Subsequent complexation run with saturated boric
1 mL HF
Environment
Limits Program
Sample
Program
Type Temp/
Power
1500 W 5 30 1 The use of a p or p/T-sensor is highly recommended.

5 mL HNO3
Sediment, For samples with high organic content.
16HF100 16 250 200 2 mL HCl Power 70 °C 3
organic, Subsequent complexation run with saturated boric
total 1 mL HF
190 °C 20 10 1
Sewage 16MF100 8 200-500 1500 0.3 8 mL HNO3 Temp 70 °C 3 Program also applicable for sludge samples.
100 °C 00:10 04:50 1

5 mL HNO3
Slag-1 16HF100 8 300 1500 1 mL HClO4 Temp 240 °C 10 40 1
2 mL HF
70 °C 3
850 W 10 60 1
6 mL HCl
Slag-2 8NXF100 4 100-300 0.3 2 mL HNO3 Power 70 °C 3
2 mL HF
850 W 10 45 1
4 mL HNO3
Black ground material.
Slag-3 8NXF100 4 100-400 0.3 4 mL H2SO4 Power 70 °C 3
950 W 5 25 1
Sludge,
16MF100 8 250 950 0.3 2 mL HCl Power 70 °C 3 Subsequent complexation run with saturated boric
total-1
Environment
Limits Program
Sample
Program
Type Temp/
Power
950 W 10 35 1
Sludge,
16HF100 8 500 950 0.3 950 2 mL HCl Power 70 °C 3 Subsequent complexation run with saturated boric
total-2
1300 W 5 35 1
Soil, acid solution required.
16HF100 8 500 1300 1300 6 mL HCl Power 70 °C 3
tot.carbon
3 mL HF Calcareous soil, low organic content.
1300 W 5 35 1 The use of a p or p/T-sensor is highly recommended.

6 mL HNO3
Soil, Subsequent complexation run with saturated boric
16HF100 8 500 1300 0.3 1300 2 mL HCl Power 70 °C 3
tot.humus acid solution required.
3 mL HF
Humus soil, high organic content.
190 °C 10 20 1
5 mL HNO3
Waste
16MF100 8 0.5-5 mL 1500 0.3 1500 1 mL HCl Temp 70 °C 3
water
1 mL H2O2
850 W 5 40 1
8 mL HNO3
Wood chips 8NXF100 4 300-600 0.3 Power 70 °C 3
0.5 mL HF
8 Evaporation
Limits Program
Sample
Program
Type Temp/
Power
850 W 10 10 1
Remove acids from previous digestion
HF
8EVAP 8 8mL 150 850 n/a Power 55 °C 3 (typically 6 to 10 mL acid will be reduced to 1-2 mL)
evaporation
step 1 Continue with method 'Fume off HF-2' if necessary
850 W 10 15 1
HF Add reagent and continue HF removal.
8EVAP 8 150 850 n/a 3 mL HNO3 Power 55 °C 3
evaporation Repeat this step if necessary.
step 2
200 W 10 1
HNO3 Evaporation with 4 vessels, fill the unoccupied
8EVAP 4 n/a 5 mL HNO3 Power 450 W 10 1
evaporation positions with empty vessels.
55 °C 3
450 W 35 1
Removal of 5 mL HNO3 Evaporation with 4 vessels, fill the unoccupied
8EVAP 4 400 n/a Power 55 °C 3
Si (after 10 mL HF positions with empty vessels.
digestion)
950 W 2 11 1
Water 50mL Evaporation with 4 vessels, fill the unoccupied
8EVAP 4 50mL 950 n/a 0.1 mL HNO3 Power 55 °C 3
to 1mL positions with empty vessels.
Reduction of 50 mL solution to 1 mL.
950 W 2 5 1
Evaporation with 4 vessels, fill the unoccupied
Water 50mL positions with empty vessels.
to 25mL
Evaporation
Limits Program
Sample
Program
Type Temp/
Power
950 W 2 5 1
Water 25mL Evaporation with 4 vessels, fill the unoccupied
to 1mL positions with empty vessels.
1300 W 2 15 1
Water 50mL Evaporation with 8 vessels.
to 1mL Reduction of 50 mL solution to 1 mL.
1300 W 2 8 1
1300 W 2 8 1
9 Food and Feed

Limits Program
Sample
Program
Type Temp/
Power
1500 W 10 20 1
8 mL HNO3
Animal feed 16HF100 16 500 200 0.3 Power 70 °C 3 The use of a p or p/T-sensor is highly recommended.
1 mL HCl
1500 W 10 20 1
Animal feed 4 mL HNO3 The use of a p or p/T-sensor is highly recommended.
16HF100 16 300 200 0.4 Power 70 °C 3
mineral 2 mL HF Subsequent complexation run with saturated boric
1300 W 15 10 1
Bouillon,
16HF100 16 500 200 1300 0.3 10 mL HNO3 Power 70 °C 3 The use of a p or p/T-sensor is highly recommended.
powder
230 °C 20 15 1
8 mL HNO3
Bread 16HF100 8 0.5-1g 190 1500 0.3 1 mL HCl Temp 70 °C 3
2 mL H2O
230 °C 15 20 1
Bread
16HF100 8 250-500 1500 0.3 6 mL HNO3 Temp 70 °C 3
additives
230 °C 15 20 1
5 mL HNO3
Casein 16HF100 8 350 200 1500 0.3 Temp 70 °C 3
2 mL H2O2
Food and Feed

Limits Program
Sample
Program
Type Temp/
Power
230 °C 15 20 1
Chilli paste 16HF100 8 250-500 1500 0.3 6 mL HNO3 Temp 70 °C 3
1400 W 15 20 1
Chocolate 16HF100 16 500 190 0.3 6 mL HNO3 Power 70 °C 3 The use of a p or p/T-sensor is highly recommended.
1400 W 15 15 1
4 mL HNO3
Cocoa 16HF100 16 500 190 0.3 2 mL H2O2 Power 70 °C 3 The use of a p or p/T-sensor is highly recommended.
1 mL HCl
350 W 20 1
Edible oil 8NXQ80 8 600 1400 0.3 8 mL HNO3 Power 800 W 10 20 1
70 °C 3
350 W 20 1
Fat 8NXQ80 4 500 1300 0.3 8 mL HNO3 Power 800 W 10 20 1
70 °C 3
230 °C 20 15 1
4 mL HNO3
Fish-1 16HF100 8 200-400 1500 0.3 0.5 mL HCl Temp 70 °C 3
2 mL H2O
Food and Feed

Limits Program
Sample
Program
Type Temp/
Power
650 W 5 10 1
6 mL HNO3
Fish-2 8NXQ80 8 500 1400 0.3 Power 1400 W 10 10 1
1 mL HCl
70 °C 3
350 W 25 1
Fish oil 8NXF100 4 200-500 0.3 7 mL HNO3 Power 750 W 15 5 1
70 °C 3
110 °C 5 5 1
6 mL HNO3
Grain-1 16HF100 8 300-600 1500 0.3 Temp 220 °C 5 20 1
1 mL HCl
70 °C 3
850 W 10 20 1
Grain-2 8NXF100 4 300-500 0.3 Power 70 °C 3
220 °C 10 30 1
6 mL HNO3
Lactose 16HF100 8 500 190 1500 0.3 Temp 70 °C 3
1 mL HCl
1500 W 10 30 1
6 mL HNO3
Liver 8NXF100 8 300 1500 0.3 Power 70 °C 3
1 mL HCl
Food and Feed

Limits Program
Sample
Program
Type Temp/
Power
1500 W 10 20 1
5 mL HNO3
Meat 16HF100 16 500 0.3 Power 70 °C 3
1 mL HCl
230 °C 15 20 1
Milkpowder 16HF100 8 200-600 1500 0.3 6 mL HNO3 Temp 70 °C 3 Sample weight strongly depends on fat content.
Nuts 220 °C 20 20 1
(e.g.
16HF100 8 200-500 1500 0.3 6 mL HNO3 Temp 70 °C 3
cashew,
hazelnut)
Poly- 1000 W 10 40 1
saccharide Subsequent complexation run with saturated boric
8NXF100 8 600 0.3 7 mL HNO3 Power 70 °C 3
(e.g. acid solution required.
alginate,…)
350 W 25 1
6 mL HNO3
Rape seed
8NXF100 4 200-500 0.3 1 mL H2O Power 550 W 5 35 1
oil
1 mL H2O2
70 °C 3
190 °C 15 15 1
Rice 16MF100 8 200-500 1500 0.3 8 mL HNO3 Temp 70 °C 3
Food and Feed

Limits Program
Sample
Program
Type Temp/
Power
550 W 15 1
7 mL HNO3
Sausage 8NXF100 4 400-600 0.3 Power 750 W 5 20 1
1 mL H2O
70 °C 2
800 W 20 10 1
Sugar 8NXF100 8 500 1300 0.3 8 mL HNO3 Power 1300 W 10 10 1
70 °C 3
850 W 15 20 1
Vegetable 8 mL HNO3 low
8NXF100 4 500 850 0.3 Power 70 °C 3
oil 1 mL HCl
10 Geology
Limits Program
Sample
Program
Type Temp/
Power
1500 W 5 25 1
1 mL HNO3
Al-silicate 16HF100 16 300 1500 0.8 1 mL HCl Power 70 °C 3
4 mL HF
4 mL H2SO4 900 W 5 45 1
4 mL H3PO4 Subsequent complexation run with saturated boric
Bauxite 8NXF100 4 200 900 0.8 Power 70 °C 3
2 mL H2O
850 W 45 1
Diorite 2 mL HF Subsequent complexation run with saturated boric
8NXF100 4 100-300 Power 70 °C 3
(geo- 6 mL HCl acid solution required.
standard)
1500 W 10 30 1
2 mL HNO3
Feldspar 16HF100 16 200 1 mL HClO4 Power 70 °C 3
4 mL HF
220 °C 15 20 1
Fertilizer 2 mL HNO3
16HF100 8 100-300 1500 0.3 Temp 70 °C 3
(e.g. 6 mL HCl
Ca(H2PO4)2)
1500 W 5 30 1
Hematite 16HF100 16 200 6 mL HCl Power 70 °C 3
Geology
Limits Program
Sample
Program
Type Temp/
Power
1500 W 5 20 1
Iron ore, 4 mL HNO3
16HF100 16 200 Power 70 °C 3
leaching 3 mL HCl
1500 W 5 25 1
Kaolin-1 16HF100 16 300 Power 70 °C 3
3 mL H2SO4 acid solution required.
750 W 50 1
Kaolin-2 8NXF100 4 100-300 Power 70 °C 3
15 mL HF 850 W 15 45 1
13 mL H3PO4
70 °C 3 low Subsequent complexation run with saturated boric
Kimberlite 8NXF100 4 5-10g 0.3 13 mL H2SO4 Power
3 mL HClO4
3 mL H2O
850 W 15 60 1
Limestone 8NXF100 4 200-400 Power 70 °C 3
4 mL HNO3 acid solution required.
1500 W 10 10 1
2 mL HNO3
Magnetite 16HF100 16 500 6 mL HCl Power 70 °C 3
1 mL HF
Geology
Limits Program
Sample
Program
Type Temp/
Power
4 mL HNO3 240 °C 15 45 1
2 mL H2O
Mica 16HF100 8 100-300 1500 Temp 70 °C 3 Subsequent complexation run with saturated boric
2 mL HF
4 mL H2SO4
240 °C 10 35 1
Quartz 10 mL HF Subsequent complexation run with saturated boric
16HF100 16 2g 1500 Temp 70 °C 3
sand-1 5 mL H2O acid solution required.
190 °C 5 25 1
Quartz 10 mL HF Subsequent complexation run with saturated boric
48MF50 8 2g 1500 Temp 70 °C 3
sand-2 5 mL H2O acid solution required.
1500 W 5 30 1
Rock, 6 mL HNO3 Subsequent complexation run with saturated boric
16HF100 16 250 Power 70 °C 3
basaltic 2 mL HF acid solution required.
1300 W 5 15 1
Rock, 6 mL HCl Subsequent complexation run with saturated boric
16HF100 8 250 1300 Power 70 °C 3
calcite 1 mL HF acid solution required.
1300 W 5 15 1
3 mL HNO3
Rock, Subsequent complexation run with saturated boric
16HF100 8 250 1300 6 mL HCl Power 70 °C 3
dolomite acid solution required.
3 mL HF
Geology
Limits Program
Sample
Program
Type Temp/
Power
900 W 5 45 1
3 mL HNO3
Rock, Subsequent complexation run with saturated boric
8NXF100 4 250 900 0.8 1 mL HCl Power 70 °C 3
granite acid solution required.
3 mL HF
1500 W 5 30 1
2 mL HNO3
Rutile Ore 8NXF100 8 250 1500 4 mL HF Power 70 °C 3
2 mL H3PO4
240 °C 15 30 1
4 mL HNO3
Talcum 16HF100 4 400 1500 2 mL HCl Temp 70 °C 3
2 mL HF
2 mL HCl 850 W 10 90 1
Tantalum 2 mL HF Subsequent complexation run with saturated boric
8NXF100 4 100-300 Power 70 °C 3
ore 2 mL H2SO4 acid solution required.
2 mL HNO3
11 Materials
Limits Program
Sample
Program
Type Temp/
Power
750 W 15 60 1
5 mL H3BO3
AlF3 8NXF100 4 150-500 saturated Power 70 °C 3
5 mL HNO3
1500 W 5 90 1
7 mL HNO3
B carbide 8NXF100 8 50 1500 0.8 7 mL HF Power 70 °C 3
3 mL H2SO4
Continue with method 'B carbide complexation'.
1500 W 5 50 1
B carbide 6 mL HNO3
8NXF100 8 50 1500 0.8 Power 70 °C 3
complex- 25 mL H3BO3
ation
850 W 5 30 1
3 mL HNO3
B nitride 8NXF100 4 500 850 0.8 2 mL H2SO4 Power 70 °C 3
3 mL HF
1500 W 5 30 1
1 mL HNO3
Borosilicate Subsequent complexation run with saturated boric
16HF100 16 500 1 mL HCl Power 70 °C 3
glass acid solution required.
4 mL HF
1300 W 15 20 1
4 mL HNO3
Cellulose
8NXF100 8 500 1300 0.3 2 mL H2O2 Power 70 °C 3
fibers
1 mL H2O
Materials
Limits Program
Sample
Program
Type Temp/
Power
3 mL HNO3 900 W 5 40 1
Cement 1 mL HCl Power
8NXF100 4 200 900 70 °C 3
(Ca-Al) 4 mL H3PO4
2 mL HClO4
230 °C 20 40 1
Crayon 16HF100 8 100-200 200 1500 Temp 70 °C 3
850 W 10 50 1
2 mL HNO3
Electronic e.g. printed circuit boards . Subsequent complexation
8NXF100 4 200-500 6 mL HCl Power 70 °C 3
waste run with saturated boric acid solution required.
2 mL HF
1400 W 10 20 1
5 mL HNO3
Hair 8NXF100 8 500 1400 0.3 1 mL HCl Power 70 °C 3
2 mL H2O2
5 mL HNO3 220 °C 10 25 1
1 mL HCl Subsequent complexation run with saturated boric
Leather 16HF100 4 300 200 1500 0.3 Temp 70 °C 3
1 mL H2O2 acid solution required.
2 mL HF
950 W 15 25 1
6 mL HNO3 low
Paper 16HF100 8 500 200 950 0.3 Power 70 °C 3 The use of a p or p/T-sensor is highly recommended.
2 mL H2O2
Materials
Limits Program
Sample
Program
Type Temp/
Power
4 mL HNO3 240 °C 15 45 1
2 mL H2O low Subsequent complexation run with saturated boric
Pearl 16HF100 8 200-300 1500 0.3 Temp 70 °C 3
4 mL H2SO4
850 W 45 1
Si3N4 8NXF100 4 100-200 Power 70 °C 3
1500 W 5 90 1
7 mL HNO3
Si carbide 8NXF100 8 50 1500 7 mL HF Power 70 °C 3
3 mL H2SO4
850 W 10 35 1
3 mL H2O Subsequent complexation run with saturated boric
Silicon 8NXF100 4 0.5-1g Power 70 °C 3
850 W 5 35 1
Zeolite 8NXF100 4 300 850 Power 70 °C 3
12 Metals
Limits Program
Sample
Program
Type Temp/
Power
1300 W 5 30 1
1 mL HNO3
Al alloy Subsequent complexation run with saturated boric
16HF100 8 500 1300 6 mL HCl Power 70 °C 3
(with Si) acid solution required.
1 mL HF
1500 W 5 30 1
2 mL HNO3
Au-Cu alloy 16HF100 16 300 1500 Power 70 °C 3
5 mL HCl
1500 W 10 10 1
3 mL HNO3
Brass 16HF100 16 500 3 mL HCl Power 70 °C 3
5 mL H2O
2 mL HClO4 900 W 10 50 1
Cast iron 8NXF100 4 200-500 Power 70 °C 3
4 mL H2SO4 acid solution required.
4 mL H3PO4
900 W 30 1
2 mL HNO3
Cr-Si, Cr- Subsequent complexation run with saturated boric
8NXF100 4 500 900 0.8 1 mL HF Power 70 °C 3
Mo alloy acid solution required.
6 mL HCl
1500 W 5 25 1
6 mL HNO3
Cu alloy 16MF100 16 500 Power 70 °C 3
2 mL HCl
Metals
Limits Program
Sample
Program
Type Temp/
Power
220 °C 15 25 1
3 mL HNO3
Fe 16HF100 8 0.5-1g 195 1500 Temp 70 °C 3
9 mL HCl
240 °C 15 45 1
2 mL HNO3
Fe-Cr alloy- Subsequent complexation run with saturated boric
16HF100 8 0.2-1 g 1500 6 mL HCl Temp 70 °C 3
1 acid solution required.
2 mL HF
900 W 10 30 1
5 mL HCl
Fe-Cr alloy- Subsequent complexation run with saturated boric
8NXF100 4 200-800 5 mL H2O Power 70 °C 3
2 acid solution required.
3 mL HF
5 mL HNO3 900 W 5 60 1
Fe-Mn alloy 8NXF100 4 500 900 0.8 Power 70 °C 3
4 mL H2O
900 W 5 40 1
3 mL H2O
Fe-Si alloy 8NXF100 4 200-400 1 mL HF Power 70 °C 3 Subsequent complexation run with saturated boric
3 mL HCl acid solution required.
900 W 10 50 1
2 mL HNO3
Ge 8NXF100 4 200-400 1 mL HF Power 70 °C 3
6 mL HCl
Metals
Limits Program
Sample
Program
Type Temp/
Power
550 W 5 10 1
4 mL HNO3
Mo sulfide 8NXQ80 8 300 1500 Power 1500 W 10 10 1
3 mL HCl
70 °C 3
900 W 15 45 1
4 mL H3PO4
Ni 8NXF100 4 100-300 4 mL HNO3 Power 70 °C 3
2 mL HF
900 W 5 40 1
6 mL HCl
Ni-Co alloy 8NXF100 4 300-500 2 mL HNO3 Power 70 °C 3
2 mL HF
1500 W 5 30 1
2 mL HNO3
Ni-Cr alloy 16HF100 16 500 1500 Power 70 °C 3
5 mL HCl
1300 W 5 40 1
Pb 8NXF100 8 500 1300 0.8 8 mL HNO3 Power 70 °C 3
1500 W 5 30 1
Pb alloy 16HF100 16 500 Power 70 °C 3
Metals
Limits Program
Sample
Program
Type Temp/
Power
900 W 120 1
9 mL HCl
Pt-Pd alloy 8NXF100 4 250 900 0.8 Power 70 °C 3
3 mL HNO3
900 W 10 120 1
10 mL HCl
Rh powder 8NXF100 4 50-100 Power 70 °C 3
2 mL H2O2
900 W 5 35 1
6 mL HCl
Steel 16HF100 8 500 900 Power 70 °C 3
2 mL HNO3
900 W 5 30 1
Ti 16HF100 8 250 900 Power 70 °C 3
1300 W 5 120 1
5 mL HNO3
Ti nitride 8NXF100 8 500 1300 0.8 2 mL HCl Power 70 °C 3
2 mL H2SO4
1300 W 5 35 1
W 16HF100 8 500 1300 Power 70 °C 3
Metals
Limits Program
Sample
Program
Type Temp/
Power
900 W 5 45 1
3 mL HNO3
Zn alloy 8NXF100 4 100 900 0.8 Power 70 °C 3
6 mL HCl
900 W 5 120 1
4 mL HCl
Zr powder 8NXF100 4 500 900 0.8 5 mL HF Power 70 °C 3
8 mL H2SO4
13 Performance
Limits Program
Sample
Program
Type Temp/
Power
1500 W 8 22 1
9.9 mL H2O
PQ MF50 48MF50 16 n/a 140 1500 0.5 Power 70 °C 3
0.1 mL HNO3
1500 W 8 15 1
9.9 mL H2O
PQ MF 16MF100 8 n/a 160 1500 0.5 Power 70 °C 3
0.1 mL HNO3
1500 W 8 20 1
9.9 mL H2O
PQ HF 16HF100 8 n/a 210 1500 0.5 Power 70 °C 3
0.1 mL HNO3
1500 W 8 20 1
9.9 mL H2O
PQ NXF 8NXF100 8 n/a 240 1500 0.8 Power 70 °C 3
0.1 mL HNO3
1500 W 8 30 1
9 mL H2O
PQ NXQ 8NXQ80 8 n/a 280 1500 0.8 Power 70 °C 3
1 mL HNO3
180 °C 5 10 1
PQ 9.9 mL H2O Temp -
24HVT50 12 n/a 200 1000 70 °C 3
24HVT50 0.1 mL HNO3 AVG
Performance
Limits Program
Sample
Program
Type Temp/
Power
180 °C 5 10 1
PQ 9.9 mL H2O Temp -
24HVT80 12 n/a 200 1000 70 °C 3
24HVT80 0.1 mL HNO3 AVG
1500 W 12 1
49.5 mL H2O
PQ EVAP 8EVAP 8 n/a 180 1500 Power 55 °C 3
0.5 mL HNO3
800 W 30 1
PQ DRY DRY 1 n/a 800 600 mL H2O Power 0W 10 3
850 W 15 1
1.98 mL H2O
PQ 64MG5 64MG5 16 n/a 160 850 Power 70 °C 3
0.02 mL HNO3
1500 W 15 1
PQ 4x48 4x48MC 4 n/a 180 1500 n/a Power 70 °C 3
1500 W 15 1
PQ 4x24 4x24MG5 4 n/a 180 1500 n/a Power 70 °C 3
Performance
Limits Program
Sample
Program
Type Temp/
Power
1500 W 15 1
PQ 4x20 4x20MGC 4 n/a 180 1500 n/a Power 70 °C 3
14 Petrochemistry
Limits Program
Sample
Program
Type Temp/
Power
230 °C 15 15 1
8 mL HNO3
Bitumen 16HF100 16 200 200 1500 0.3 1 mL HCl Temp 70 °C 3
2 mL H2O2
240 °C 15 30 1
6 mL HNO3 low
Candle wax 16HF100 8 500 200 1500 0.5 Temp 70 °C 3
2 mL H2O2
350 W 20 1
8 mL HNO3
Crude oil 8NXF100 4 200-500 0.5 Power 700 W 10 20 1
1 mL H2O2
70 °C 3
350 W 20 1
7 mL HNO3
Engine oil,
8NXF100 4 200-500 0.3 1 mL HCl Power 700 W 10 20 1
used
0.5 mL HF
70 °C 3
350 W 20 1
Hydro- 5 mL HNO3
8NXF100 4 200-500 0.3 Power 500 W 5 10 1
carbons 2 mL H2O
70 °C 3
1500 W 15 30 1
Lubrication 8 mL HNO3
16HF100 16 300 1500 0.3 Power 70 °C 3 The use of a p or p/T-sensor is highly recommended.
oil 1 mL HCl
Petrochemistry
Limits Program
Sample
Program
Type Temp/
Power
Diesel, Fuel 400 W 15 1

Oil, 7 mL HNO3
Kerosene, 8NXF100 4 200-500 0.5 Power 600 W 10 25 1
1 mL H2O
Naphtha,
Wax 70 °C 3
1300 W 15 40 1
Petroleum 6 mL HNO3
8NXQ80 8 250 1300 0.3 Power 70 °C 3
coke 2 mL H2O2
400 W 10 1
Residual
6 mL HNO3
Fuel Oil, 8NXF100 4 200-600 0.5 Power 900 W 40 1 Continue with Step 2, if required
Pitch, Tar 2 mL H2O2
60°C 3
Residual 1100 W 10 30 1
Fuel Oil, 2 mL HNO3
8NXF100 4 0.5 Power 70 °C 3
Pitch, Tar - 2 mL H2O2
Step 2
15 Pharmaceutical and Medical

Limits Program
Sample
Program
Type Temp/
Power
800 W 15 10 1
8 mL HNO3
Blood 8NXQ80 8 500 1300 0.3 Power 1300 W 10 10 1
1 mL H2O2
70 °C 3
1500 W 15 15 1
5 mL HNO3
Bone 16HF100 16 500 3 mL H2O2 Power 70 °C 3
1 mL HCl
300 W 15 1
4 mL HNO3 350 W 10 1
Capsule,
8NXF100 4 1.5g 0.3 Power Repeat step with additional 3 mL HNO3 + 1 mL H2O2.
filled with oil 4 mL H2O 400 W 15 1
70 °C 3
Chinese 230 °C 15 15 1
medicine
sample 16HF100 8 600 200 1500 0.3 6 mL HNO3 Temp 70 °C 3
(plant
material)
190 °C 15 20 1
Cough
16HF100 8 300 180 1500 0.3 6 mL HNO3 Temp 70 °C 3
syrup
240 °C 15 25 1
3 mL HNO3
Creme-1 16HF100 8 400 200 1500 0.3 2 mL HF Temp 70 °C 3
3 mL H2SO4
Pharmaceutical and Medical

Limits Program
Sample
Program
Type Temp/
Power
850 W 5 25 1
Creme-2 8NXF100 4 800 850 0.3 Power 70 °C 3
550 W 20 1
6 mL HNO3 800 W 5 5 1
Glycerol 8NXF100 8 400 1200 0.3 Power
1 mL H2O 1200 W 5 15 1
70 °C 3
1300 W 15 30 1
4 mL HNO3
Glycine 8NXQ80 8 300 1300 0.3 Power 70 °C 3
2 mL H2O2
350 W 15 1
7 mL HNO3
Haloperidol 8NXQ80 4 200 0.3 Power 800 W 10 20 1
1 mL H2SO4
70 °C 3
850 W 10 30 1
6 mL HNO3 low Subsequent complexation run with saturated boric
Lipstick 8NXF100 4 300 850 0.3 Power 70 °C 3
400 W 20 1
Methane- 2 mL H2O2
Program also applicable for Thiourea and Tin-
sulfonic 8NXF100 4 500 850 0.3 4 mL HCl Power 850 W 10 20 1
methane-sulfonate.
acid 2 mL H2O
70 °C 3

Limits Program
Sample
Program
Type Temp/
Power
240 °C 5 30 1
6 mL HNO3
Mg stearate 16HF100 8 300 1500 0.3 Temp 70 °C 3
2 mL HCl
900 W 15 1
Use 6 mL of diluted HNO3 (20%)
MIC-4 O2-
8NXQ80 4 500 900 0.8 6 mL HNO3 70 °C 3 Wet ash-free filter paper with 50 µL NH4NO3 (50%) to
Aspirin Combus-
tion ignite sample.
1200 W 15 30 1
Nicotinic 4 mL HNO3
8NXQ80 8 400 0.3 Power 70 °C 3 Very toxic acid!
acid 2 mL H2O2
1400 W 15 30 1
Phenyl- 4 mL HNO3
8NXQ80 8 400 1400 0.3 Power 70 °C 3
alanine 2 mL H2O2
400 W 20 1
8 mL HNO3
Soap 8NXF100 4 200-400 0.3 Power 750 W 10 15 1
2 mL H2O2
70 °C 3
750 W 10 40 1
Stearic
acid, 8NXF100 4 600 0.3 8 mL HNO3 Power 70 °C 3
Stearin

Limits Program
Sample
Program
Type Temp/
Power
900 W 5 50 1
4 mL HNO3
Talcum 8NXF100 4 300 900 0.8 2 mL HCl Power 70 °C 3
2 mL HF
850 W 15 30 1
8 mL HNO3
Urea 8NXF100 4 600 850 Power 70 °C 3
2 mL HCl
350 W 20 1
7 mL HNO3
Vitamin
8NXF100 4 1g 900 2 mL H2O2 Power 750 W 10 15 1
capsule-1
1 mL H2O
70 °C 3
16 Plastics
Limits Program
Sample
Program
Type Temp/
Power
220 °C 20 40 1
Ion
16HF100 8 200-400 1500 0.3 8 mL HNO3 Temp 70 °C 3
exchange
resin
1300 W 15 15 1
8 mL HNO3
Nylon 66 8NXF100 8 500 1300 0.3 Power 70 °C 3 low
2 mL HCl
850 W 15 30 1
7 mL HNO3
Complexation with additional 4 mL HNO3 + 6 mL
PET 8NXF100 4 200-400 0.3 1 mL HF Power 70 °C 3 low
H3BO3.
1 mL HCl
750 W 30 1
Polyamide 8NXF100 4 300-500 0.3 Power 70 °C 3
600 W 5 10 1
5 mL HNO3
Polyester 8NXF100 8 500 1400 0.3 Power 1400 W 10 10 1 low
1 mL H2O2
70 °C 3
750 W 5 15 1
Poly- Subsequent complexation run with saturated boric
7 mL HNO3
ethylene, 8NXF100 4 200-400 0.3 Power 70 °C 3
filled 1 mL HF acid solution required.
Plastics
Limits Program
Sample
Program
Type Temp/
Power
850 W 15 45 1
4 mL HNO3
Polyimide Subsequent complexation run with saturated boric
8NXF100 4 250 850 0.3 2 mL HF Power 70 °C 3 low
film acid solution required.
4 mL H3PO4
1500 W 10 30 1
Polyisobu-
16HF100 16 300 200 1500 0.3 6 mL HNO3 Power 70 °C 3 low
tylene
850 W 5 45 1
Polymer 1 mL HF Subsequent complexation run with saturated boric
8NXF100 4 200-400 0.3 Power 70 °C 3
gloves 7 mL HNO3 acid solution required.
1500 W 10 20 1
6 mL HNO3
Poly- Subsequent complexation run with saturated boric
16HF100 16 300 200 1500 0.3 1 mL HCl Power 70 °C 3 low
propylene, acid solution required.
filled 1 mL HF
1400 W 15 20 1
Poly- 6 mL HNO3
8NXF100 8 500 1400 0.3 Power 70 °C 3 low
propylene 1 mL HCl
850 W 10 40 1
Polystyrene 8NXF100 4 100-300 0.3 8 mL HNO3 Power 70 °C 3
Plastics
Limits Program
Sample
Program
Type Temp/
Power
850 W 10 40 1
Poly-
8NXF100 4 100-300 0.3 8 mL HNO3 Power 70 °C 3 low
urethane
850 W 15 30 1
5 mL HNO3
PVC 8NXF100 4 200-400 0.3 1 mL HCl Power 70 °C 3
1 mL H2O2
850 W 15 45 1
5 mL HNO3
PVDF 8NXF100 4 100-500 0.3 1 mL H2O2 Power 70 °C 3 low
5 mL H2SO4
650 W 15 30 1
Rubber 8NXF100 4 300-600 0.3 Power 70 °C 3
350 W 20 1
6 mL HNO3
Silicone Subsequent complexation run with saturated boric
8NXF100 4 200-400 0.3 1 mL H2O2 Power 750 W 10 15 1
rubber acid solution required.
1 mL HF
70 °C 3
1400 W 10 15 1
Tire 16HF100 16 250 200 0.3 1 mL HF Power 70 °C 3 low acid solution required.
2 mL H2SO4 remove rim!
17 Extraction
Limits Program
Sample
Program
Type Temp/
Power
135 °C 15 10 1
PQ SOLV 16SOLV
8 n/a 135 1500 0.5 10 mL Acetone Temp 50 °C 3
MF MF100
135 °C 15 10 1
PQ SOLV 16SOLV
8 n/a 135 1500 0.5 10 mL Acetone Temp 50 °C 3
HF HF100
12.5 mL 110 °C 5 5 1
Cleaning 16SOLV Acetone
8 110 1500 Temp 50 °C 3 high
SOLV MF100 12.5 mL
MF100-8 n-Hexane
115 °C 5 15 1
Animal feed 12.5 mL
for organo- 16SOLV n-Hexane 50 °C 3
8 2g 110 1500 Temp high
chloride MF100 12.5 mL
pesticides Acetone
ASTM D 150 °C 30 15 1
5765
(total 15 mL Acetone 50 °C 3
16SOLV
petroleum 8 5g 150 1500 15 mL Temp high
MF100
hydro- n-Hexane
carbons
from soil)
Extraction
Limits Program
Sample
Program
Type Temp/
Power
ASTM D 115 °C 10 10 1
6010
15 mL Acetone
(organic 16SOLV 50 °C 3
8 5g 115 1500 15 mL Temp high
compounds MF100
n-Hexane
from solid
matrices)
12.5 mL 110 °C 5 15 1
16SOLV Acetone
EPA 3546 8 2g - 10g 110 1500 Temp 50 °C 3 high
MF100 12.5 mL
n-Hexane

D19IA005EN H ClassifiedListofApplications

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::: Multiwave PRO – Classified List of Applications

Introduction and General Hints

All used reagents must be of appropriate purity and following concentration:

* Safety Module SOLV PRO required

900 W 10 1 Perform an acidic cleaning run after combustion e.g.

3 Ceramics and Oxides

Co oxide 16HF100 8 500 1300 10 mL HCl Power 70 °C 3

Ceramics and Oxides

Ceramics and Oxides

165 °C 00:10 09:50 0

170 °C 05:30 0 Sediments, soil, sludge, contaminated soil and oils

175 °C 5:30 4:30 1

175 °C 5:30 4:30 1

180 °C 05:30 0 Siliceous and organically based matrices for 8

180 °C 10 0 Siliceous and organically based matrices for 16

1500 W 5 30 1 The use of a p or p/T-sensor is highly recommended.

100 °C 00:10 04:50 1

1300 W 5 35 1 The use of a p or p/T-sensor is highly recommended.

9 Food and Feed

Food and Feed

Chilli paste 16HF100 8 250-500 1500 0.3 6 mL HNO3 Temp 70 °C 3

Edible oil 8NXQ80 8 600 1400 0.3 8 mL HNO3 Power 800 W 10 20 1

Fat 8NXQ80 4 500 1300 0.3 8 mL HNO3 Power 800 W 10 20 1

Food and Feed

Fish oil 8NXF100 4 200-500 0.3 7 mL HNO3 Power 750 W 15 5 1

Food and Feed

Rice 16MF100 8 200-500 1500 0.3 8 mL HNO3 Temp 70 °C 3

Food and Feed

Sugar 8NXF100 8 500 1300 0.3 8 mL HNO3 Power 1300 W 10 10 1

Hematite 16HF100 16 200 6 mL HCl Power 70 °C 3

Pb 8NXF100 8 500 1300 0.8 8 mL HNO3 Power 70 °C 3

PQ DRY DRY 1 n/a 800 600 mL H2O Power 0W 10 3

PQ 4x48 4x48MC 4 n/a 180 1500 n/a Power 70 °C 3

PQ 4x24 4x24MG5 4 n/a 180 1500 n/a Power 70 °C 3

PQ 4x20 4x20MGC 4 n/a 180 1500 n/a Power 70 °C 3

Diesel, Fuel 400 W 15 1

15 Pharmaceutical and Medical

Pharmaceutical and Medical

Pharmaceutical and Medical

Pharmaceutical and Medical

Polystyrene 8NXF100 4 100-300 0.3 8 mL HNO3 Power 70 °C 3

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