Beruflich Dokumente
Kultur Dokumente
Useful data
–1 –1 –2 –1 –1 –1
R = 8.314 JK mol or 8.206 10 L atm K mol ; 1 F = 96500 C mol
–34 –19
h = 6.626 10 Js; 1 eV = 1.602 10 J
–1
c = 3.0 10 ms ; NA = 6.022 10
8 23
(Atomic Masses in amu : H = 1 , He = 4, C = 12, N = 14, O = 16, Na = 23, Mg = 24, P = 31, S = 32, Cl = 35.5, K
= 39, Ca = 40, Fe = 56, Cu = 63.5)
NAME:
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PH-VII-2018-P(I)–PCM-2
PAPER–I
PART I: PHYSICS
SECTION – I: Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. A transformer (step up) with an 1: 8 turn ratio has 60 Hz, 120 V across the primary. The load in the
secondary is 104 . The current in the secondary is
(A) 1.2 A (B) 0.96 A (C) 12 mA (D) 96 mA
3. The potential difference across the resistance, capacitance and inductance are 80 V, 40 V and 100 V
respectively in an L – C–R circuit. The power factor of this circuit is
(A) 0.4 (B) 0.5 (C) 0.8 (D) 1.0
4. A sinusoidal voltage of peak value 283 V and angular frequency 320s1 is applied to a series LCR
circuit. Given that R 5,L 25mH and C 1000F . The total impedance, and phase difference
between the voltage across the source and the current will respectively be
5 8
(A) 10 and tan1 (B) 10 and tan1
3 3
5
(C) 7 and tan1 (D) 7 and 450
3
5. A tuning fork of frequency 340 Hz is vibrated just above the tube of 120 cm height. Water is poured
slowly in the tube. What is the minimum height of water necessary for the resonance (speed of sound
in the air = 340 m /sec)
(A) 15 cm (B) 25 cm (C) 30 cm (D) 45 cm
6. A tuning fork sounded together with a tuning fork of frequency 256 emits two beats. On loading the
tuning fork of frequency 256, the number of beats heard are 1 per second. The frequency of tuning
fork is
(A) 257 (B) 258 (C) 256 (D) 254
7. In the experiment for the determination of the speed of sound in air using the resonance column
method, the length of the air column that resonates in the fundamental mode, with a tuning fork is 0.1
m. when this length is changed to 0.35 m, the same tuning fork resonates with the first overtone.
Calculate the end correction.
(A) 0.012 m (B) 0.025 (C) 0.05 m (D) 0.024
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PH-VII-2018-P(I)–PCM-3
8. An observer moves towards a stationary source of sound, with a velocity one– fifth of the velocity of
sound. What is the percentage increase in the apparent frequency.
(A) 5 % (B) 20 % (C) zero (D) 0.5 %
1
9. The displacement due to a wave moving in the positive x –direction is given by y at time t=
1 x2
1
0 and by y at t= 2 seconds , where x and y are in metres. The velocity of the wave in
1 x 12
m/s is
(A) 0.5 (B) 1 (C) 2 (D) 4
10. A source of sound is travelling towards a stationary observer. The frequency of sound heard by the
observer is of three times the original frequency. The velocity of sound is v m /s. The speed of source
will be.
2 3
(A) v (B) v (C) v (D) 3 v
3 2
11. A driver in a stationary car blows a horn which produces monochromatic sound waves of frequency
1000 Hz normally towards a reflecting wall. The wall approaches the car with a speed of 3.3 ms1
(A) The frequency of sound reflected from wall and heard by the driver is 1020 Hz
(B) The frequency of sound reflected from wall and heard by the driver is 980 Hz
(C) The percentage increase in frequency of sound after reflected from wall is 2 %
(D) The percentage decrease in frequency of sound after reflected from wall is 2%
1
12. The equation of a wave is y 4 sin 2t x where y and x are in cm and t is in second
2 8
–1
(A) The amplitude, wavelength, velocity and frequency of wave are 4 cm, 16 cm, 32 cms and 1 Hz
respectively with wave propagating along +x direction
–1
(B) The amplitude, wavelength, velocity and frequency of wave are 4cm, 32 cm, 16 cms and 0.5 Hz
respectively with wave propagating along – x direction
(C) Two positions occupied by the particle at time interval of 0.4 have a phase difference of 0.4
radian
0
(D) Two positions occupied by the particle at separation of 12 cm have a phase difference of 135
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PH-VII-2018-P(I)–PCM-4
14. Consider a harmonic wave travelling on a string of mass per unit length . The wave has velocity v,
amplitude A and frequency f. The power transmitted by a harmonic wave on the string is proportional
to (take constant of proportionality as 22 )
(A)
2 2
(B) v (C) A (D) f
.
15 Standing wave can be produced
(A) in a string clamped at both the ends
(B) in a string clamped at one end and free at the other
(C) When incident wave gets reflected from the wall superimpose
(D) When two identical waves with a phase difference of are moving in the same direction
superimpose
SECTION – III: Integer Answer Type
This section contains 5 questions. The answer to each of the questions is a single–digit integer, ranging
from 0 to 9 (both inclusive).
16. A stationary source is emitting sound at a fixed frequency f0 , which is reflected by two cars
approaching the source. The difference between the frequencies of sound reflected from the cars is
1.2 % of f0 . The difference in speeds of cars (in km per hour) to the nearest integer is (The cars are
moving at constant speeds much smaller than speed of sound which is 330ms1 )
17. A 20 m long string having a mass 1.0 g is fixed at the both ends. The tension in the string is 0.5 N.
The string is set into vibration using an external vibrator of frequency 100 Hz. The separation (in cm)
between successive nodes on the string is
18. A stretched string of length ' ' is excited by plucking the string at right angles to its length at a point
which is a distance of from one end and stopping the vibration at the centre of the string with a
4
finger. Find the number of antinodes for the vibration
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PH-VII-2018-P(I)–PCM-5
19. At a distance of 20 m from a point source, the loudness is 30 dB. After a minimum distance of
x 50 10 metre the sound is inaudible. Value of x is
21. In a polymer sample, 30% of molecules have a molecular mass of 20, 000, 40% have 30, 000 and the
rest 60, 000. What is the weight average molecular mass of the polymer ?
(A) 40, 300 (B) 30, 600 (C) 43, 333 (D) 33, 353
22. The ratio between the number of carbon atoms and nitrogen atoms in melamine molecule is
(A) 1 : 2 (B) 2 : 1 (C) 2 : 3 (D) 3 : 2
1 ) K MnO4/ OH Polymerisation
B; A B B (polymer)
2 ) Hydrolysis
CH3
Here ‘C’ is
(A) Glyptal (B) Dacron (C) Nylon–6, 6 (D) Nylon 6
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PH-VII-2018-P(I)–PCM-6
24. Which of the following is least effective in causing flocculation of Fe(OH) 3 sol
(A) K3 Fe CN6 (B) K2CrO4
(C) KBr (D) K2SO4
25. The potential difference between the fixed charged layer and the diffused layer having opposite
charge is called
(A) Zeta potential (B) Streaming potential
(C) Doru potential (D) Colloidal potential
26. The coagulation of 10 ml of gold sol is just prevented on adding 1 ml of 10% NaCl in the presence of
0.025g of starch. The gold number of starch is
(A) 0.25 (B) 0.025 (C) 25 (D) 250
–5 –7 –9
27. Ka values for HA,a HB and HD are 10 , 10 and 10 respectively. Which of the following will be
correct for decimolar aqueous solutions of NaA, NaB and NaD at 25C ?
(A) pHNaA pHNaB (B) pHNaD pHNaB
(C) pHNaA pHNaD (D) pHNaB 7
28. The pH of HCl is 1. The amount of NaOH to be added to 100 ml of such a HCl solution to get pH of 7
is
(A) 4g (B) 0.4g (C) 4 mg (D) 0.4 mg
–16
29. At certain temperature the Kw of D2O is 10 M. Then the pD of pure D2O at that temperature is
(A) 7 (B) 16 (C) 8 (D) 6
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PH-VII-2018-P(I)–PCM-7
H OH H OH
HO H HO H
H OH HO H
H OH H OH
CH 2OH CH 2OH
D-Glucose D-Galactose
Which of the following statements are correct about these compounds?
(A) they are diastereomers (B) both are components of lactose
(C) they are C 4 epimers (D) both are optically active
33. Which of the following will give red ppt with Fehling’s solution?
(A) HCHO (B) HCOOH (C) glucose (D) fructose
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PH-VII-2018-P(I)–PCM-8
XeFn dissolves in HF according to the reaction XeF n + HF XeFn1 HF2 . What is the value of n
39.
?
– – –10
40. A certain buffer solution contains equal concentration of X and HX. Kb for X is 10 . Find the pH of
buffer.
n 4 dy 4
41. The real value of n for which the substitution y = u will transform the differential equation 2x y +y
dx
6
= 4x into a homogeneous equation is
1 3
(A) (B) 1 (C) (D) 2
2 2
2
42. If the distance of two points P and Q on the parabola y = 4ax from the focus of a parabola are 4 and
9 respectively then the distance of the point of intersection of tangents at P and Q from the focus is
(A) 8 (B) 6 (C) 3.5 (D) 13
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PH-VII-2018-P(I)–PCM-9
2
43. The tangents at P and Q on the parabola y = 4x meet in T. S is the focus such that, SP, ST and SQ
2
are equal to a, b and c, respectively. Then the roots of the equation ax + 2bx + c = 0 are
(A) real and different (B) real and equal (C) complex numbers (D) irrational
x 4 y 3
2 2
2 2
45. If the reflection of the ellipse = 1 in the mirror x – y – 2 = 0 is k1x + k2y – 160x –
16 9
k1 k 2
36y + 292 = 0, then is equal to
5
(A) 4 (B) 5 (C) 6 (D) 7
x2 y2
46. Maximum length of chord of the ellipse = 1, such that eccentric angles of its extremities differ
8 4
by is
2
(A) 4 (B) 2 2 (C) 16 (D) 8
47. The area of the parallelogram formed by the tangents at the points whose eccentric angles are ,
3 x2 y2
, + , on the ellipse 2 2 = 1 is
2 2 a b
(A) ab (B) 4ab (C) 3ab (D) 2ab
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PH-VII-2018-P(I)–PCM-10
x2 y2
48. The maximum distance of the centre of the ellipse = 1 from the chord of contact of mutually
16 9
perpendicular tangents of the ellipse is
144 9 16 8
(A) (B) (C) (D)
5 5 5 5
x2 y2
2 = 1 at P forms a triangle of area 3a square units, with
2
49. A tangent drawn to hyperbola
6
2
a b
coordinate axes, then the square of its eccentricity is equal to
(A) 15 (B) 16 (C) 17 (D) 18
x2 y2
50. If e is the eccentricity of the hyperbola = 1 and is the angle between the asymptotes, then
a2 b2
cos is equal to
2
1 e 2 1 2
(A) (B) e (C) (D)
e e e e
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PH-VII-2018-P(I)–PCM-11
x2 y2
2
52. If x – 2y + 4 = 0 is a common tangent to y = 4x and = 1, then the value of ‘b’ and the other
4 b2
common tangent are given by
(A) b = 3 (B) b = 3 (C) x + 2y + 4 = 0 (D) x – 2y – 4 = 0
1 1 k
54. In X–Y plane, the path defined by the equation = 0 is
xm ym x y n
1
(A) a parabola if m = , k = –1, n = 0 (B) a hyperbola if m = 1, k = –1, n = 0
2
(C) a pair of lines if m = k = n = 1 (D) a pair of lines if m = k = –1, n = 1
x2 y2
2 = 1 be reciprocal to that of the ellipse x + 4y = 4. If the
2 2
55. Let the eccentricity of the hyperbola 2
a b
hyperbola passes through a focus of the ellipse, then
x2 y2
(A) the equation of the hyperbola is = 1 (B) a focus of the hyperbola is (2, 0)
3 2
2 2 2
(C) the eccentricity of the hyperbola is (D) the equation of the hyperbola is x – 3y = 3
3
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PH-VII-2018-P(I)–PCM-12
x2 y2
2 2
59. A tangent of slope 2 of the ellipse = 1 (a > b) is normal to the circle x + y + 4x + 10y + 1 = 0.
a2 b2
1 1
If a , , then minimum value of latus rectum of ellipse is
8 4
x2 y2
60. The line 2x + y = 1 is tangent to the hyperbola = 1. If this line passes through the point of
a2 b2
intersection of the nearest directrix and the x-axis, then the eccentricity of the hyperbola is
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PH-VII-2018-P(I)–PCM-13
CHEMISTRY
21. C 22. A 23. B 24. C
25. A 26. C 27. C 28. B
29. C 30. D 31. B, C 32. A, B, C, D
33. A, B, C, D 34. B, C, D 35. A, C, D 36. 5
37. 2 38. 4 39. 6 40. 4
MATHEMATICS
41. C 42. B 43. B 44. C
45. B 46. A 47. B 48. C
49. C 50. BONUS 51. AB 52. AC
53. ABCD 54. CD 55. BCD 56. 5
57. 7 58. 6 59. 6 60. 2
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PH-VII-2018-P(I)–PCM-14
Useful data
–1 –1 –2 –1 –1 –1
R = 8.314 JK mol or 8.206 10 L atm K mol ; 1 F = 96500 C mol
–34 –19
h = 6.626 10 Js; 1 eV = 1.602 10 J
–1
c = 3.0 10 ms ; NA = 6.022 10
8 23
(Atomic Masses in amu : H = 1 , He = 4, C = 12, N = 14, O = 16, Na = 23, Mg = 24, P = 31, S = 32, Cl = 35.5, K
= 39, Ca = 40, Fe = 56, Cu = 63.5)
NAME:
ENROLLMENT NO.:
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PH-VII-2018-P(I)–PCM-15
PAPER–I
PART I: PHYSICS
SECTION – I: Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. A tuning fork sounded together with a tuning fork of frequency 256 emits two beats. On loading the
tuning fork of frequency 256, the number of beats heard are 1 per second. The frequency of tuning
fork is
(A) 254 (B) 258 (C) 256 (D) 257
2. In the experiment for the determination of the speed of sound in air using the resonance column
method, the length of the air column that resonates in the fundamental mode, with a tuning fork is 0.1
m. when this length is changed to 0.35 m, the same tuning fork resonates with the first overtone.
Calculate the end correction.
(A) 0.012 m (B) 0.024 (C) 0.05 m (D) 0.025
3. A transformer (step up) with an 1: 8 turn ratio has 60 Hz, 120 V across the primary. The load in the
secondary is 104 . The current in the secondary is
(A) 96 mA (B) 0.96 A (C) 12 mA (D) 1.2 A
5. The potential difference across the resistance, capacitance and inductance are 80 V, 40 V and 100 V
respectively in an L – C–R circuit. The power factor of this circuit is
(A) 0.8 (B) 0.5 (C) 0.4 (D) 1.0
6. An observer moves towards a stationary source of sound, with a velocity one– fifth of the velocity of
sound. What is the percentage increase in the apparent frequency.
(A) 20 % (B) 5 % (C) zero (D) 0.5 %
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PH-VII-2018-P(I)–PCM-16
1
7. The displacement due to a wave moving in the positive x –direction is given by y at time t=
1 x
2
1
0 and by y at t= 2 seconds , where x and y are in metres. The velocity of the wave in
1 x 12
m/s is
(A) 0.5 (B) 1 (C) 2 (D) 4
8. A source of sound is travelling towards a stationary observer. The frequency of sound heard by the
observer is of three times the original frequency. The velocity of sound is v m /s. The speed of source
will be.
3 2
(A) v (B) v (C) v (D) 3 v
2 3
9. A sinusoidal voltage of peak value 283 V and angular frequency 320s1 is applied to a series LCR
circuit. Given that R 5,L 25mH and C 1000F . The total impedance, and phase difference
between the voltage across the source and the current will respectively be
5
(A) 10 and tan1 (B) 7 and 450
3
5 8
(C) 7 and tan1 (D) 10 and tan1
3 3
10. A tuning fork of frequency 340 Hz is vibrated just above the tube of 120 cm height. Water is poured
slowly in the tube. What is the minimum height of water necessary for the resonance (speed of sound
in the air = 340 m /sec)
(A) 45 cm (B) 25 cm (C) 30 cm (D) 15 cm
11. A driver in a stationary car blows a horn which produces monochromatic sound waves of frequency
1000 Hz normally towards a reflecting wall. The wall approaches the car with a speed of 3.3 ms1
(A) The frequency of sound reflected from wall and heard by the driver is 1020 Hz
(B) The frequency of sound reflected from wall and heard by the driver is 980 Hz
(C) The percentage decrease in frequency of sound after reflected from wall is 2%
(D) The percentage increase in frequency of sound after reflected from wall is 2 %
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PH-VII-2018-P(I)–PCM-17
1
12. The equation of a wave is y 4 sin 2t x where y and x are in cm and t is in second
2 8
–1
(A) The amplitude, wavelength, velocity and frequency of wave are 4cm, 32 cm, 16 cms and 0.5 Hz
respectively with wave propagating along – x direction
–1
(B) The amplitude, wavelength, velocity and frequency of wave are 4 cm, 16 cm, 32 cms and 1 Hz
respectively with wave propagating along +x direction
(C) Two positions occupied by the particle at time interval of 0.4 have a phase difference of 0.4
radian
0
(D) Two positions occupied by the particle at separation of 12 cm have a phase difference of 135
14. Consider a harmonic wave travelling on a string of mass per unit length . The wave has velocity v,
amplitude A and frequency f. The power transmitted by a harmonic wave on the string is proportional
to (take constant of proportionality as 22 )
(A)
2 2
(B) v (C) A (D) f
.
15 Standing wave can be produced
(A) in a string clamped at one end and free at the other
(B) in a string clamped at both the ends
(C) When incident wave gets reflected from the wall superimpose
(D) When two identical waves with a phase difference of are moving in the same direction
superimpose
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16. A stationary source is emitting sound at a fixed frequency f0 , which is reflected by two cars
approaching the source. The difference between the frequencies of sound reflected from the cars is
1.2 % of f0 . The difference in speeds of cars (in km per hour) to the nearest integer is (The cars are
moving at constant speeds much smaller than speed of sound which is 330ms1 )
17. A 20 m long string having a mass 1.0 g is fixed at the both ends. The tension in the string is 0.5 N.
The string is set into vibration using an external vibrator of frequency 100 Hz. The separation (in cm)
between successive nodes on the string is
18. A stretched string of length ' ' is excited by plucking the string at right angles to its length at a point
which is a distance of from one end and stopping the vibration at the centre of the string with a
4
finger. Find the number of antinodes for the vibration
18. At a distance of 20 m from a point source, the loudness is 30 dB. After a minimum distance of
x 50 10 metre the sound is inaudible. Value of x is
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21. The coagulation of 10 ml of gold sol is just prevented on adding 1 ml of 10% NaCl in the presence of
0.025g of starch. The gold number of starch is
(A) 25 (B) 0.025 (C) 0.25 (D) 250
–5 –7 –9
22. Ka values for HA,a HB and HD are 10 , 10 and 10 respectively. Which of the following will be
correct for decimolar aqueous solutions of NaA, NaB and NaD at 25C ?
(A) pHNaA pHNaD (B) pHNaD pHNaB
(C) pHNaA pHNaB (D) pHNaB 7
23. In a polymer sample, 30% of molecules have a molecular mass of 20, 000, 40% have 30, 000 and the
rest 60, 000. What is the weight average molecular mass of the polymer ?
(A) 40, 300 (B) 30, 600 (C) 33, 353 (D) 43, 333
24. The ratio between the number of carbon atoms and nitrogen atoms in melamine molecule is
(A) 3 : 2 (B) 2 : 1 (C) 2 : 3 (D) 1 : 2
1 ) K MnO4/ OH Polymerisation
B; A B B (polymer)
2 ) Hydrolysis
CH3
Here ‘C’ is
(A) Glyptal (B) Nylon 6 (C) Nylon–6, 6 (D) Dacron
26. The pH of HCl is 1. The amount of NaOH to be added to 100 ml of such a HCl solution to get pH of 7
is
(A) 4g (B) 0.4 mg (C) 4 mg (D) 0.4 g
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–16
27. At certain temperature the Kw of D2O is 10 M. Then the pD of pure D2O at that temperature is
(A) 7 (B) 16 (C) 8 (D) 6
29. Which of the following is least effective in causing flocculation of Fe(OH) 3 sol
(A) K3 Fe CN6 (B) K2CrO4
(C) K2SO4 (D) KBr
30. The potential difference between the fixed charged layer and the diffused layer having opposite
charge is called
(A) Colloidal potential (B) Streaming potential
(C) Doru potential (D) Zeta potential
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H OH H OH
HO H HO H
H OH HO H
H OH H OH
CH 2OH CH 2OH
D-Glucose D-Galactose
Which of the following statements are correct about these compounds?
(A) they are diastereomers (B) both are components of lactose
(C) they are C 4 epimers (D) both are optically active
33. Which of the following will give red ppt with Fehling’s solution?
(A) HCHO (B) HCOOH (C) glucose (D) fructose
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XeFn dissolves in HF according to the reaction XeF n + HF XeFn1 HF2 . What is the value of n
39.
?
– – –10
40. A certain buffer solution contains equal concentration of X and HX. Kb for X is 10 . Find the pH of
buffer.
x2 y2
41. Maximum length of chord of the ellipse = 1, such that eccentric angles of its extremities differ
8 4
by is
2
(A) 8 (B) 2 2 (C) 16 (D) 4
42. The area of the parallelogram formed by the tangents at the points whose eccentric angles are ,
3 x2 y2
, + , on the ellipse 2 2 = 1 is
2 2 a b
(A) 4ab (B) ab (C) 3ab (D) 2ab
n 4 dy 4
43. The real value of n for which the substitution y = u will transform the differential equation 2x y +y
dx
6
= 4x into a homogeneous equation is
3 1
(A) (B) 1 (C) (D) 2
2 2
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2
44. If the distance of two points P and Q on the parabola y = 4ax from the focus of a parabola are 4 and
9 respectively then the distance of the point of intersection of tangents at P and Q from the focus is
(A) 6 (B) 8 (C) 3.5 (D) 13
2
45. The tangents at P and Q on the parabola y = 4x meet in T. S is the focus such that, SP, ST and SQ
2
are equal to a, b and c, respectively. Then the roots of the equation ax + 2bx + c = 0 are
(A) real and equal (B) real and different (C) complex numbers (D) irrational
x2 y2
46. The maximum distance of the centre of the ellipse = 1 from the chord of contact of mutually
16 9
perpendicular tangents of the ellipse is
144 9 8 16
(A) (B) (C) (D)
5 5 5 5
x2 y2
47. A tangent drawn to hyperbola 2 = 1 at P forms a triangle of area 3a2 square units, with
6
2
a b
coordinate axes, then the square of its eccentricity is equal to
(A) 15 (B) 16 (C) 18 (D) 17
x2 y2
48. If e is the eccentricity of the hyperbola = 1 and is the angle between the asymptotes, then
a2 b2
cos is equal to
2
1 e 2 2 1
(A) (B) e (C) (D)
e e e e
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x 4 y 3
2 2
2 2
50. If the reflection of the ellipse = 1 in the mirror x – y – 2 = 0 is k1x + k2y – 160x –
16 9
k1 k 2
36y + 292 = 0, then is equal to
5
(A) 4 (B) 5 (C) 6 (D) 7
x2 y2
2
52. If x – 2y + 4 = 0 is a common tangent to y = 4x and = 1, then the value of ‘b’ and the other
4 b2
common tangent are given by
(A) b = 3 (B) b = 3 (C) x – 2y – 4 = 0 (D) x + 2y + 4 = 0
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1 1 k
54. In X–Y plane, the path defined by the equation m = 0 is
x y
m n
x y
1
(A) a parabola if m = , k = –1, n = 0 (B) a hyperbola if m = 1, k = –1, n = 0
2
(C) a pair of lines if m = k = n = 1 (D) a pair of lines if m = k = –1, n = 1
x2 y2
2 = 1 be reciprocal to that of the ellipse x + 4y = 4. If the
2 2
55. Let the eccentricity of the hyperbola 2
a b
hyperbola passes through a focus of the ellipse, then
x2 y2
(A) the equation of the hyperbola is = 1 (B) a focus of the hyperbola is (2, 0)
3 2
2 2 2
(C) the equation of the hyperbola is x – 3y = 3 (D) the eccentricity of the hyperbola is
3
x2 y2
2 2
59. A tangent of slope 2 of the ellipse = 1 (a > b) is normal to the circle x + y + 4x + 10y + 1 = 0.
a2 b2
1 1
If a , , then minimum value of latus rectum of ellipse is
8 4
x2 y2
60. The line 2x + y = 1 is tangent to the hyperbola = 1. If this line passes through the point of
a2 b2
intersection of the nearest directrix and the x-axis, then the eccentricity of the hyperbola is
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PH-VII-2018-P(I)–PCM-26
CHEMISTRY
21. A 22. A 23. D 24. D
25. D 26. D 27. C 28. B
29. D 30. D 31. B, D 32. A, B, C, D
33. A, B, C, D 34. B, C, D 35. B, C, D 36. 5
37. 2 38. 4 39. 6 40. 4
MATHEMATICS
41. D 42. A 43. A 44. A
45. A 46. D 47. D 48. BONUS
50. C 50. B 51. AC 52. AD
53. ABCD 54. CD 55. BCD 56. 5
57. 7 58. 6 59. 6 60. 2
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Useful data
–1 –1 –2 –1 –1 –1
R = 8.314 JK mol or 8.206 10 L atm K mol ; 1 F = 96500 C mol
–34 –19
h = 6.626 10 Js; 1 eV = 1.602 10 J
–1
c = 3.0 10 ms ; NA = 6.022 10
8 23
(Atomic Masses in amu : H = 1 , He = 4, C = 12, N = 14, O = 16, Na = 23, Mg = 24, P = 31, S = 32, Cl = 35.5, K
= 39, Ca = 40, Fe = 56, Cu = 63.5)
NAME:
ENROLLMENT NO.:
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PH-VII-2018-P(I)–PCM-28
PAPER–I
PART I: PHYSICS
SECTION – I: Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. An observer moves towards a stationary source of sound, with a velocity one– fifth of the velocity of
sound. What is the percentage increase in the apparent frequency.
(A) 5 % (B) 20 % (C) zero (D) 0.5 %
1
2. The displacement due to a wave moving in the positive x –direction is given by y at time t=
1 x2
1
0 and by y at t= 2 seconds , where x and y are in metres. The velocity of the wave in
1 x 12
m/s is
(A) 0.5 (B) 1 (C) 2 (D) 4
3. A source of sound is travelling towards a stationary observer. The frequency of sound heard by the
observer is of three times the original frequency. The velocity of sound is v m /s. The speed of source
will be.
2 3
(A) v (B) v (C) v (D) 3 v
3 2
4. A sinusoidal voltage of peak value 283 V and angular frequency 320s1 is applied to a series LCR
circuit. Given that R 5,L 25mH and C 1000F . The total impedance, and phase difference
between the voltage across the source and the current will respectively be
5 8
(A) 10 and tan1 (B) 10 and tan1
3 3
5
(C) 7 and tan1 (D) 7 and 450
3
5. A tuning fork of frequency 340 Hz is vibrated just above the tube of 120 cm height. Water is poured
slowly in the tube. What is the minimum height of water necessary for the resonance (speed of sound
in the air = 340 m /sec)
(A) 15 cm (B) 25 cm (C) 30 cm (D) 45 cm
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6. A tuning fork sounded together with a tuning fork of frequency 256 emits two beats. On loading the
tuning fork of frequency 256, the number of beats heard are 1 per second. The frequency of tuning
fork is
(A) 257 (B) 258 (C) 256 (D) 254
7. In the experiment for the determination of the speed of sound in air using the resonance column
method, the length of the air column that resonates in the fundamental mode, with a tuning fork is 0.1
m. when this length is changed to 0.35 m, the same tuning fork resonates with the first overtone.
Calculate the end correction.
(A) 0.012 m (B) 0.025 (C) 0.05 m (D) 0.024
8. A transformer (step up) with an 1: 8 turn ratio has 60 Hz, 120 V across the primary. The load in the
secondary is 104 . The current in the secondary is
(A) 1.2 A (B) 0.96 A (C) 12 mA (D) 96 mA
10. The potential difference across the resistance, capacitance and inductance are 80 V, 40 V and 100 V
respectively in an L – C–R circuit. The power factor of this circuit is
(A) 0.4 (B) 0.5 (C) 0.8 (D) 1.0
12. Consider a harmonic wave travelling on a string of mass per unit length . The wave has velocity v,
amplitude A and frequency f. The power transmitted by a harmonic wave on the string is proportional
to (take constant of proportionality as 22 )
(A)
2 2
(B) v (C) A (D) f
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.
13 Standing wave can be produced
(A) in a string clamped at both the ends
(B) in a string clamped at one end and free at the other
(C) When incident wave gets reflected from the wall superimpose
(D) When two identical waves with a phase difference of are moving in the same direction
superimpose
14. A driver in a stationary car blows a horn which produces monochromatic sound waves of frequency
1000 Hz normally towards a reflecting wall. The wall approaches the car with a speed of 3.3 ms1
(A) The frequency of sound reflected from wall and heard by the driver is 1020 Hz
(B) The frequency of sound reflected from wall and heard by the driver is 980 Hz
(C) The percentage increase in frequency of sound after reflected from wall is 2 %
(D) The percentage decrease in frequency of sound after reflected from wall is 2%
1
15. The equation of a wave is y 4 sin 2t x where y and x are in cm and t is in second
2 8
–1
(A) The amplitude, wavelength, velocity and frequency of wave are 4 cm, 16 cm, 32 cms and 1 Hz
respectively with wave propagating along +x direction
–1
(B) The amplitude, wavelength, velocity and frequency of wave are 4cm, 32 cm, 16 cms and 0.5 Hz
respectively with wave propagating along – x direction
(C) Two positions occupied by the particle at time interval of 0.4 have a phase difference of 0.4
radian
0
(D) Two positions occupied by the particle at separation of 12 cm have a phase difference of 135
16. A stretched string of length ' ' is excited by plucking the string at right angles to its length at a point
which is a distance of from one end and stopping the vibration at the centre of the string with a
4
finger. Find the number of antinodes for the vibration
17. At a distance of 20 m from a point source, the loudness is 30 dB. After a minimum distance of
x 50 10 metre the sound is inaudible. Value of x is
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19. A stationary source is emitting sound at a fixed frequency f0 , which is reflected by two cars
approaching the source. The difference between the frequencies of sound reflected from the cars is
1.2 % of f0 . The difference in speeds of cars (in km per hour) to the nearest integer is (The cars are
moving at constant speeds much smaller than speed of sound which is 330ms1 )
20. A 20 m long string having a mass 1.0 g is fixed at the both ends. The tension in the string is 0.5 N.
The string is set into vibration using an external vibrator of frequency 100 Hz. The separation (in cm)
between successive nodes on the string is
21. The pH of HCl is 1. The amount of NaOH to be added to 100 ml of such a HCl solution to get pH of 7
is
(A) 4g (B) 0.4g (C) 4 mg (D) 0.4 mg
–16
22. At certain temperature the Kw of D2O is 10 M. Then the pD of pure D2O at that temperature is
(A) 7 (B) 16 (C) 8 (D) 6
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24. Which of the following is least effective in causing flocculation of Fe(OH) 3 sol
(A) K3 Fe CN6 (B) K2CrO4
(C) KBr (D) K2SO4
25. The potential difference between the fixed charged layer and the diffused layer having opposite
charge is called
(A) Zeta potential (B) Streaming potential
(C) Doru potential (D) Colloidal potential
26. The coagulation of 10 ml of gold sol is just prevented on adding 1 ml of 10% NaCl in the presence of
0.025g of starch. The gold number of starch is
(A) 0.25 (B) 0.025 (C) 25 (D) 250
–5 –7 –9
27. Ka values for HA,a HB and HD are 10 , 10 and 10 respectively. Which of the following will be
correct for decimolar aqueous solutions of NaA, NaB and NaD at 25C ?
(A) pHNaA pHNaB (B) pHNaD pHNaB
(C) pHNaA pHNaD (D) pHNaB 7
28. In a polymer sample, 30% of molecules have a molecular mass of 20, 000, 40% have 30, 000 and the
rest 60, 000. What is the weight average molecular mass of the polymer ?
(A) 40, 300 (B) 30, 600 (C) 43, 333 (D) 33, 353
29. The ratio between the number of carbon atoms and nitrogen atoms in melamine molecule is
(A) 1 : 2 (B) 2 : 1 (C) 2 : 3 (D) 3 : 2
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1 ) K MnO4/ OH Polymerisation
B; A B B (polymer)
2 ) Hydrolysis
CH3
Here ‘C’ is
(A) Glyptal (B) Dacron (C) Nylon–6, 6 (D) Nylon 6
31. Which of the following will give red ppt with Fehling’s solution?
(A) HCHO (B) HCOOH (C) glucose (D) fructose
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H OH H OH
HO H HO H
H OH HO H
H OH H OH
CH 2OH CH 2OH
D-Glucose D-Galactose
Which of the following statements are correct about these compounds?
(A) they are diastereomers (B) both are components of lactose
(C) they are C 4 epimers (D) both are optically active
XeFn dissolves in HF according to the reaction XeF n + HF XeFn1 HF2 . What is the value of n
37.
?
– – –10
38. A certain buffer solution contains equal concentration of X and HX. Kb for X is 10 . Find the pH of
buffer.
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PH-VII-2018-P(I)–PCM-35
x2 y2
41. The maximum distance of the centre of the ellipse = 1 from the chord of contact of mutually
16 9
perpendicular tangents of the ellipse is
144 9 16 8
(A) (B) (C) (D)
5 5 5 5
x2 y2
42. A tangent drawn to hyperbola 2 = 1 at P forms a triangle of area 3a2 square units, with
6
2
a b
coordinate axes, then the square of its eccentricity is equal to
(A) 15 (B) 16 (C) 17 (D) 18
x2 y2
43. If e is the eccentricity of the hyperbola = 1 and is the angle between the asymptotes, then
a2 b2
cos is equal to
2
1 e 2 1 2
(A) (B) e (C) (D)
e e e e
x 4 y 3
2 2
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PH-VII-2018-P(I)–PCM-36
x2 y2
46. Maximum length of chord of the ellipse = 1, such that eccentric angles of its extremities differ
8 4
by is
2
(A) 4 (B) 2 2 (C) 16 (D) 8
47. The area of the parallelogram formed by the tangents at the points whose eccentric angles are ,
3 x2 y2
, + , on the ellipse 2 2 = 1 is
2 2 a b
(A) ab (B) 4ab (C) 3ab (D) 2ab
n 4 dy 4
48. The real value of n for which the substitution y = u will transform the differential equation 2x y +y
dx
6
= 4x into a homogeneous equation is
1 3
(A) (B) 1 (C) (D) 2
2 2
2
49. If the distance of two points P and Q on the parabola y = 4ax from the focus of a parabola are 4 and
9 respectively then the distance of the point of intersection of tangents at P and Q from the focus is
(A) 8 (B) 6 (C) 3.5 (D) 13
2
50. The tangents at P and Q on the parabola y = 4x meet in T. S is the focus such that, SP, ST and SQ
2
are equal to a, b and c, respectively. Then the roots of the equation ax + 2bx + c = 0 are
(A) real and different (B) real and equal (C) complex numbers (D) irrational
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1 1 k
52. In X–Y plane, the path defined by the equation = 0 is
xm ym x y n
1
(A) a parabola if m = , k = –1, n = 0 (B) a hyperbola if m = 1, k = –1, n = 0
2
(C) a pair of lines if m = k = n = 1 (D) a pair of lines if m = k = –1, n = 1
x2 y2
2 2
53. Let the eccentricity of the hyperbola = 1 be reciprocal to that of the ellipse x + 4y = 4. If the
a2 b2
hyperbola passes through a focus of the ellipse, then
x2 y2
(A) the equation of the hyperbola is = 1 (B) a focus of the hyperbola is (2, 0)
3 2
2 2 2
(C) the eccentricity of the hyperbola is (D) the equation of the hyperbola is x – 3y = 3
3
2
54. The point/points of contact of normal to the parabola y = 4ax (a > 0) such that the y-intercept of the
normal is double of the x-intercept, is
a a
(A) (4a, 4a) (B) (4a, –4a) (C) , (D) none of these
4 2
x2 y2
2
55. If x – 2y + 4 = 0 is a common tangent to y = 4x and = 1, then the value of ‘b’ and the other
4 b2
common tangent are given by
(A) b = 3 (B) b = 3 (C) x + 2y + 4 = 0 (D) x – 2y – 4 = 0
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PH-VII-2018-P(I)–PCM-38
x2 y2
2 = 1 (a > b) is normal to the circle x + y + 4x + 10y + 1 = 0.
2 2
57. A tangent of slope 2 of the ellipse 2
a b
1 1
If a , , then minimum value of latus rectum of ellipse is
8 4
x2 y2
58. The line 2x + y = 1 is tangent to the hyperbola = 1. If this line passes through the point of
a2 b2
intersection of the nearest directrix and the x-axis, then the eccentricity of the hyperbola is
2 2 2
59. The shortest distance between parabolas y = 4x and y = 2x – 6 is d, then d =
2 2
60. The line x + 2y + 4 = 0 is a common tangent to the parabola y = 4ax and x = 4by, then |b – a| is
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PH-VII-2018-P(I)–PCM-39
CHEMISTRY
21. B 22. C 23. D 24. C
25. A 26. C 27. C 28. C
29. A 30. B 31. A, B, C, D 32. B, C, D
33. A, C, D 34. B, C 35. A, B, C, D 36. 4
37. 6 38. 4 39. 5 40. 2
MATHEMATICS
41. C 42. C 43. C 44. C
45. B 46. BONUS 47. B 48. C
49. B 50. B 51. ABCD 52. CD
53. BCD 54. AB 55. AC 56. 6
57. 6 58. 2 59. 5 60. 7
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FIITJEE INTERNAL TEST
IIT – JEE 2018
PHASE – VII_PAPER – II_SET – A
Time: 3 hours Maximum Marks: 198
INSTRUCTIONS:
A. General
1. This booklet is your Question Paper containing 60 questions.
2. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and electronic
gadgets in any form are not allowed to be carried inside the examination hall.
3. Fill in the boxes provided for Name and Enrolment No.
4. The answer sheet, a machine-readable Objective Response (ORS), is provided separately.
5. DO NOT TAMPER WITH / MULTILATE THE ORS OR THE BOOKLET.
B. Filling in the OMR:
6. The instructions for the OMR sheet are given on the OMR itself.
C. Question paper format:
7. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists
of three sections.
8. Section I contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
9. Section II contains 6 multiple choice questions relating to three paragraphs with two questions on
each paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY one is
correct.
10. Section III contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE may be is correct.
D. Marking Scheme
11. For each question in Section I and Section II, you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer ONLY and zero (0) marks if no bubbles are darkened. In all
other cases, minus one (–1) mark will be awarded in these sections.
12. For each question in Section Ill, you will be awarded 4 marks if you darken ALL the bubble(s)
corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks will be awarded. No
negative marks will be awarded for incorrect answer(s) in this section.
Useful data
–1 –1 –2 –1 –1 –1
R = 8.314 JK mol or 8.206 10 L atm K mol ; 1 F = 96500 C mol
–34 –19
h = 6.626 10 Js; 1 eV = 1.602 10 J
–1
c = 3.0 10 ms ; NA = 6.022 10
8 23
(Atomic Masses in amu : H = 1 , He = 4, C = 12, N = 14, O = 16, Na = 23, Mg = 24, P = 31, S = 32,
Cl = 35.5, K = 39, Ca = 40, Fe = 56, Cu = 63.5)
NAME:
ENROLLMENT NO.:
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PH-VII-2018-P(II)-SET-A-PCM-2
PAPER–II
PART I: PHYSICS
SECTION – I: Single Correct Answer Type
The section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. The voltage time (V —t) graph for a triangular wave having peak value V0 is as shown in figure. The
rms value of V is:
V0 V0 V0 V0
(A) (B) (C) (D)
3 2 2 3
C
3. An inductor L, a capacitor C and ammeters A1, A2 and A3 are connected to an A1
oscillator in the circuit as shown in the adjoining figure. when the frequency of
the oscillator is increased, then at resonant frequency, the ammeter reading is L
A2
zero in the case of
(A) ammeter A1 (B) ammeter A2
~ A3
(C) ammeter A3 (D) all the three ammeters
4. An inductor coil joined to a 6V battery draws a steady current of 1.5A , but when this coil is
connected to a 20V , 50Hz AC source it draws a current of 4A . The reactance of this coil when it is
connected to a 30V , 100Hz AC source is
(A) 6 (B) 12 (C) 18 (D) 3
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Acceleration of point x = 2 m of a transverse wave is 5 ˆj m/s and the slope of waveform is given
2
5.
dy
5 sin x . Then the speed of the point at that instant is given in m/s as
dx 12
50 100 150 200
(A) (B) (C) (D)
3 3 3 3
1 1
6. The amplitude of a wave represented by displacement equation y sin t cos t will be
a b
ab a b a b ab
(A) (B) (C) (D)
ab ab ab ab
displacements at x 0 and x 3 m is
–5 –4 -4 –4
(A) 5 x 10 m (B) 2.5 x 10 m (C) 5 x 10 m (D) 10 m
8. A metallic wire with tension T and at temperature 30c vibrates with its fundamental frequency of 1
kHz. The same wire with the same tension but at 10C temperature vibrates with a fundamental
frequency of 1.001 kHz. The coefficient of linear expansion of the wire is
–4 –4 –4 –4
(A) 2 x 10 /C (B) 1.5 x 10 /C (C) 1 x 10 /C (D) 0.5 x 10 /C
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10. At some instant current in L-R1 circuit is 10 A. At the same instant current in C – R2 circuit will be :
(A) 5 A (B) 5 2A (C) 6 6A (D) 5 3A
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14. Keeping tension and amplitude in the given rope remaining the same, if a simple harmonic oscillator
of frequency 200 Hz is used instead of the earlier oscillator of frequency 100 Hz. Then
(A) Speed of transverse waves in the rope will not change, wavelength will not change and energy
density will become one fourth.
(B) Speed of transverse waves in the rope will become half; wavelength will become one-fourth and
energy density will become two times.
(C) Speed of transverse waves in the rope will become four times; wavelength will become doubled
and energy density will not change .
(D) Speed of transverse waves in the rope will not change; wavelength will become half and energy
density will become four times.
16. If a string fastened at both ends has successive resonance with wavelength of 0.54m for the nth
th
harmonic and 0.48m for the (n + 1) harmonic then (with a given frequency)
(A) the value of n is 8
(B) the length of the string is 2.16m
(C) the wavelength of the fundamental frequency is 4.32m
(D) fundamental frequency is 18Hz
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17. The vibration of a string fixed at both ends are described by Y = 2 sin (x) sin(100t) where Y is in
mm, x is in cm, t in sec then
1
(A) maximum displacement of the particle at x cm would be 1 mm
6
1 1
(B) velocity of the particle at x cm at time t = sec will be 157 3 mm/s
6 600
(C) if the length of the string be 10 cm, number of loop in it would be 5
(D) none of these
The equation of a stationary wave in a string is y =(4 mm) sin[(3.14m ) x] cos t.
-1
18.
Select the correct alternative(s)
(A) The amplitude of component waves is 2 mm
(B) The amplitude of component waves is 4 mm
(C) The smallest possible length of string is 0.5 m
(D) The smallest possible length of string is 1.0 m
19. Velocity of sound in air is 320 m/s. A pipe closed at one end has a length of 1 m. Neglecting end
corrections, the air column in the pipe can resonate for sound of frequency:
(A) 80 Hz (B) 240 Hz (C) 320 Hz (D) 400 Hz
20. Two identical straight wires are stretched so as to produce 6 beats per second when vibrating
simultaneously. On changing the tension slightly in one of them, the beat frequency remains
unchanged. Denoting by T 1 and T2 the higher and the lower initial tension in the strings, then it could
be said that while making the above changes in tension :
(A) T2 was decreased (B) T2 was increased
(C) T1 was decreased (D) T1 was increased
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21. In the following reaction HC2O4 PO34 HPO24 C2O24 which are the two Bronsted base ?
(A) HC2O4 and PO34 (B) HPO24 and C2O24
(C) HC2O4 and HPO24 (D) PO34 and C2O24
22. What is the change in pH of water when 0.01 mole of NaOH are added in 10 litre water.
(A) 3 (B) 4 (C) 6 (D) 11
23. Which one of the following characteristics is not correct for physical adsorption?
(A) Adsorption on solids is reversible
(B) Adsorption decreases with increase in temperature
(C) Adsorption is non specific
(D) Both change in enthalpy and change in entropy of adsorption is positive
24. Buna-S is a
(A) condensation polymer formed by styrene and 1,3-butadiene
(B) addition polymer formed by styrene and 1,3-butadiene
(C) condensation polymer of hexamethylene diamine and adipic acid
(D) addition polymer of hexamethylene diamine and adipic acid
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28. 100 mL of 0.1 M NaOH is added to 100 mL of a 0.2 M CH3COOH solution. The pH of the resulting
–5
solution will be (Ka for CH3COOH = 1.8 x 10 )
(A) 4.74 (B) 5.74 (C) 3.74 (D) 7.00
Polymerization involves various mechanisms depending upon the initiator. If initiator generates free radical,
addition polymerization takes place through free radical mechanism.
+
If H is initiator and electron releasing group is present, cationic polymerization takes place. If electron
withdrawing group is present and strong base is initiator, anionic polymerization takes place
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A solution which remains in equilibrium with undissolved solute, is said to be saturated. The concentration of a
saturated solution at a given temperature is called solubility. The product of concentration of ions in a
saturated solution of an electrolyte at a given temperature, is called solubility product K sp . For the
electrolyte, AxBy with solubility S, A xBy s
xA y yBx . The solubility product K sp = x x y y sx y .
While calculating the solubility of a sparingly soluble salt in the presence of some strong electrolyte containing
a common ion, the common ion concentration is practically equal to that of strong electrolyte. If in a solution,
the ionic product of an electrolyte exceeds its Ksp value at a particular temperature, then precipitation occurs.
31. The solubility of PbSO4 in water is 0.303 g/l at 25C, its solubility product at that temperature is
–6 2 –4 2 –8 2 –8 2
(A) 10 M (B) 9.18 x 10 M (C) 10 M (D) 9.18 x 10 M
32.
The solubility of BaSO4 in 0.1 M BaCl2 solution is K sp of BaSO4 1.5 109
–9 –8 –16 –18
(A) 1.5 x 10 M (B) 1.5 x 10 M (C) 2.25 x 10 M (D) 2.25 x 10 M
33. A colloidal solution of ferric hydroxide sol is prepared by the hydrolysis of FeCl3. The colloidal particles
of ferric hydroxide are
(A) Positively charged (B) Negatively charged
(C) Neutral (D) Can not be predicted
34. Which of the following ion forms primary electrical double layer on the colloidal particle of As2S3 ?
3+ 2– + –
(A) As (B) S (C) H (D) OH
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35. Alanine, an -amino acid is existed in the following equilibrium at different pH values of the solution.
OH OH
CH3 CH COOH CH3 CH COO CH3 C H COO
| | |
NH3 NH3 NH2
pKa12.3 pKa2 9.7
(at pH0) (at pH14)
Identify the correct statements from the following:
(A) at pH=6.0 the solubility of alanine is minimum
(B) at pH=6.0 the concentration of anionic form dominating over the cationic form
(C) at pH=2.3, the concentration of dipolar ion is same as that of cationic form
(D) at pH=9.7, the concentration of dipolar ion is same as that of anionic form
36. Acetic acid and aq. NH3 are weak monobasic acid and weak monoacidic base respectively and Ka of
acetic acid is equal to Kb of aq. NH3. Which of the following statements are correct ?
(A) All the above mixing would result in neutral solution having pH = 7 at 25C
(B) If aq. NH3 is exactly half neutralized by HCl, then pOH of resulting solution is equal to pK b
(C) If acetic acid is exactly half neutralized by NaOH , the pH of resulting solution is equal to pKa
(D) If acetic acid is exactly neutralized by aq. NH 3 then pH of resulting solution is equal 1/ 2 pkw.
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39. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are)
(A) Adsorption is always exothermic
(B) Physisorption may transform into chemisorption at high temperature
(C) Physisorption increases with increasing temperature but chemisorption decreases with increasing
temperature.
(D) Chemisorption is more exothermic than physisorption, however it is very slow due to higher
energy of activation
40. Consider the equilibrium equation ; CH3COOH + HF CH3COOH2 F
Which of the following statements are incorrect :
– –
(A) F is the conjugate base of HF (B) F is the conjugate base of CH3COOH
(C) CH3COOH2 is the conjugate base of CH3COOH
(D) CH3COOH is the conjugate base of CH3COOH2
41. If y = f(x) passing through (1, 2) satisfies the differential equation y(1 + xy)dx = x dy = 0, then
2x x 1 x 1 4x
(A) f(x) = (B) f(x) = 2 (C) f(x) = (D) f(x) =
2x 2
x 1 4x 2
1 2x 2
2
42. Slope of the chord of the tangent to parabola y = 4ax which passes through the point (–6a, 0) and
which subtends an angle of 45 at the vertex is
2 3 7 5
(A) (B) (C) (D)
7 8 2 6
2
43. If the parabola y = (a – b)x + (b – c)x + (c – a) touches the x-axis, then the line ax + by + c = 0
(A) always passes through a fixed point (B) represents the family of parallel lines
(C) is always perpendicular to x-axis (D) always has negative slope
2
44. The locus of centroid of triangle formed by a tangent to the parabola y = 36x with coordinate axes is
2 2 2 2
(A) y = –9x (B) y + 3x = 0 (C) y = 3x (D) y = 9x
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x2 y2
45. If the normal at the point P() to the ellipse = 1 intersects it again at the point Q(2), then cos
14 5
is equal to
2 2 3 3
(A) (B) (C) (D)
3 3 2 2
x2 y2 PM 2
46. If normal at any point P to the ellipse = 1, a > b meets the axes at M and N so that ,
a2 b2 PN 3
then value of eccentricity e is
(A) cos 45 (B) sin 30 (C) tan 30 (D) sin 60
2 2 2 2
47. If 4x + py = 45 and x – 4y = 5 cut orthogonally, then the value of p is
1 1
(A) (B) (C) 3 (D) 9
9 3
x2 y2
48. If P is any point common to the hyperbola = 1 and the circle having line segment joining its
16 25
foci as diameter, then sum of focal distances of point P is
(A) 6 2 (B) 2 66 (C) 16 (D) 8
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56. The major axis and minor axis of an ellipse are respectively x – 2y – 5 = 0 and 2x + y + 10 = 0. If one
end of latus rectum is (3, 4), then the foci are
(A) (5, 0) (B) (–7, –6) (C) (–11, –8) (D) (11, 3)
x2 y2 x2 y2
57. For the ellipse 2 2 1 and 2 2 = 1
a b b a
(A) The foci of each ellipse always lie within the order ellipse
(B) Their auxiliary circles are the same
(C) Their director circles are the same
(D) The ellipse encloses the same area
1 2 2
58. A hyperbola having the transverse axis of length and is confocal with the ellipse 3x + 4y = 12,
2
then
x2 y2 1
(A) equation of the hyperbola is
15 1 16
(B) Eccentricity of the hyperbola is 4
1
(C) Distance between the directrices of the hyperbola is units
8
15
(D) Length of latus rectum of the hyperbola is units
2
2
59. The equations of the chords of the parabola y = 4ax which pass through the point (–6a, 0) and which
subtends an angle of 45 at the vertex is/are
(A) 2x – 7y + 12a = 0 (B) 2x + 7y + 12a = 0 (C) 7x – 2y + 12a = 0 (D) 7x + 2y + 12a = 0
2
60. Two distinct chords passing through (a, 2a) of parabola y = 4ax are bisected by the line
x + y = 1. Then the length of latus rectum can be
(A) 1 (B) 2 (C) 3 (D) 4
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CHEMISTRY
21. D 22. B 23. D 24. B
25. B 26. B 27. D 28. A
29. A 30. C 31. A 32. B
33. A 34. B 35. A, C, D 36. A, B, C, D
37. B, C, D 38. A, B, C, D 39. A, B, D 40. B, C
MATHEMATICS
41. A 42. A 43. A 44. B
45. A 46. C 47. D 48. B
49. B 50. A 51. A 52. B
53. A 54. A 55. BCD 56. AC
57. BCD 58. BCD 59. AB 60. ABC
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PH-VII-2018-P(II)-SET-A-PCM-16
Useful data
–1 –1 –2 –1 –1 –1
R = 8.314 JK mol or 8.206 10 L atm K mol ; 1 F = 96500 C mol
–34 –19
h = 6.626 10 Js; 1 eV = 1.602 10 J
–1
c = 3.0 10 ms ; NA = 6.022 10
8 23
(Atomic Masses in amu : H = 1 , He = 4, C = 12, N = 14, O = 16, Na = 23, Mg = 24, P = 31, S = 32,
Cl = 35.5, K = 39, Ca = 40, Fe = 56, Cu = 63.5)
NAME:
ENROLLMENT NO.:
PAPER–II
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PH-VII-2018-P(II)-SET-A-PCM-17
PART I: PHYSICS
SECTION – I: Single Correct Answer Type
The section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
Acceleration of point x = 2 m of a transverse wave is 5 ˆj m/s and the slope of waveform is given
2
1.
dy
5 sin x . Then the speed of the point at that instant is given in m/s as
dx 12
50 150 100 200
(A) (B) (C) (D)
3 3 3 3
2. The voltage time (V —t) graph for a triangular wave having peak value V0 is as shown in figure. The
rms value of V is:
V0 V0 V0 V0
(A) (B) (C) (D)
3 2 3 2
C
4. An inductor L, a capacitor C and ammeters A1, A2 and A3 are connected to an A1
oscillator in the circuit as shown in the adjoining figure. when the frequency of
the oscillator is increased, then at resonant frequency, the ammeter reading is L
A2
zero in the case of
(A) ammeter A1 (B) ammeter A3
~ A3
(C) ammeter A2 (D) all the three ammeters
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1 1
5. The amplitude of a wave represented by displacement equation y sin t cos t will be
a b
a b ab a b ab
(A) (B) (C) (D)
ab ab ab ab
7. A metallic wire with tension T and at temperature 30c vibrates with its fundamental frequency of 1
kHz. The same wire with the same tension but at 10C temperature vibrates with a fundamental
frequency of 1.001 kHz. The coefficient of linear expansion of the wire is
–4 –4 –4 –4
(A) 0.5 x 10 /C (B) 1.5 x 10 /C (C) 1 x 10 /C (D) 2 x 10 /C
8. An inductor coil joined to a 6V battery draws a steady current of 1.5A , but when this coil is
connected to a 20V , 50Hz AC source it draws a current of 4A . The reactance of this coil when it is
connected to a 30V , 100Hz AC source is
(A) 3 (B) 12 (C) 18 (D) 6
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One end of a long rope is tied to a fixed vertical pole. The rope is stretched horizontally with a tension 8 N. Let
us consider the length of the rope to be along x-axis. A simple harmonic oscillator at x = 0 generates a
transverse wave of frequency 100 Hz and amplitude 2 cm along the rope. Mass per unit length of the rope is
20gm / m. . Ignoring the effect of gravity, answer the following questions.
12. Keeping tension and amplitude in the given rope remaining the same, if a simple harmonic oscillator
of frequency 200 Hz is used instead of the earlier oscillator of frequency 100 Hz. Then
(A) Speed of transverse waves in the rope will not change, wavelength will not change and energy
density will become one fourth.
(B) Speed of transverse waves in the rope will become half; wavelength will become one-fourth and
energy density will become two times.
(C) Speed of transverse waves in the rope will become four times; wavelength will become doubled
and energy density will not change .
(D) Speed of transverse waves in the rope will not change; wavelength will become half and energy
density will become four times.
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3 3
In the circuit shown in figure R1 = 10, L = H, R2 = 20 and C = F. Current in L – R1 circuit is I1 in
10 2
C – R2 circuit I2 and the main current is I.
The two circuits are in parallel. So, they r be treated separately.
14. At some instant current in L-R1 circuit is 10 A. At the same instant current in C – R2 circuit will be :
(A) 5 A (B) 5 2A (C) 5 3A (D) 6 6A
15. If a string fastened at both ends has successive resonance with wavelength of 0.54m for the nth
th
harmonic and 0.48m for the (n + 1) harmonic then (with a given frequency)
(A) the value of n is 8
(B) the length of the string is 2.16m
(C) fundamental frequency is 18Hz
(D) the wavelength of the fundamental frequency is 4.32m
16. The vibration of a string fixed at both ends are described by Y = 2 sin (x) sin(100t) where Y is in
mm, x is in cm, t in sec then
1
(A) maximum displacement of the particle at x cm would be 1 mm
6
(B) if the length of the string be 10 cm, number of loop in it would be 5
1 1
(C) velocity of the particle at x cm at time t = sec will be 157 3 mm/s
6 600
(D) none of these
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The equation of a stationary wave in a string is y =(4 mm) sin[(3.14m ) x] cos t.
-1
17.
Select the correct alternative(s)
(A) The amplitude of component waves is 2 mm
(B) The amplitude of component waves is 4 mm
(C) The smallest possible length of string is 1.0 m
(D) The smallest possible length of string is 0.5 m
18. Velocity of sound in air is 320 m/s. A pipe closed at one end has a length of 1 m. Neglecting end
corrections, the air column in the pipe can resonate for sound of frequency:
(A) 80 Hz (B) 240 Hz (C) 400 Hz (D) 320 Hz
19. Two identical straight wires are stretched so as to produce 6 beats per second when vibrating
simultaneously. On changing the tension slightly in one of them, the beat frequency remains
unchanged. Denoting by T 1 and T2 the higher and the lower initial tension in the strings, then it could
be said that while making the above changes in tension :
(A) T2 was decreased (B) T2 was increased
(C) T1 was increased (D) T1 was decreased
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22. In the following reaction HC2O4 PO34 HPO24 C2O24 which are the two Bronsted base ?
(A) HC2O4 and PO34 (B) PO34 and C2O24
(C) HC2O4 and HPO24 (D) HPO24 and C2O24
23. What is the change in pH of water when 0.01 mole of NaOH are added in 10 litre water.
(A) 3 (B) 4 (C) 6 (D) 11
24. Which one of the following characteristics is not correct for physical adsorption?
(A) Adsorption on solids is reversible
(B) Adsorption decreases with increase in temperature
(C) Both change in enthalpy and change in entropy of adsorption is positive
(D) Adsorption is non specific
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27. 100 mL of 0.1 M NaOH is added to 100 mL of a 0.2 M CH3COOH solution. The pH of the resulting
–5
solution will be (Ka for CH3COOH = 1.8 x 10 )
(A) 5.74 (B) 4.74 (C) 3.74 (D) 7.00
28. Buna-S is a
(A) addition polymer formed by styrene and 1,3-butadiene
(B) condensation polymer formed by styrene and 1,3-butadiene
(C) condensation polymer of hexamethylene diamine and adipic acid
(D) addition polymer of hexamethylene diamine and adipic acid
A solution which remains in equilibrium with undissolved solute, is said to be saturated. The concentration of a
saturated solution at a given temperature is called solubility. The product of concentration of ions in a
saturated solution of an electrolyte at a given temperature, is called solubility product K sp . For the
electrolyte, AxBy with solubility S, A xBy s xA y yBx . The solubility product K sp = x x y y sx y .
While calculating the solubility of a sparingly soluble salt in the presence of some strong electrolyte containing
a common ion, the common ion concentration is practically equal to that of strong electrolyte. If in a solution,
the ionic product of an electrolyte exceeds its Ksp value at a particular temperature, then precipitation occurs.
29. The solubility of PbSO4 in water is 0.303 g/l at 25C, its solubility product at that temperature is
–8 2 –4 2 –6 2 –8 2
(A) 10 M (B) 9.18 x 10 M (C) 10 M (D) 9.18 x 10 M
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30.
The solubility of BaSO4 in 0.1 M BaCl2 solution is K sp of BaSO4 1.5 109
–8 –9 –16 –18
(A) 1.5 x 10 M (B) 1.5 x 10 M (C) 2.25 x 10 M (D) 2.25 x 10 M
The charge on colloidal particle is due to the selective adsorption of ions present in the dispersion medium.
The adsorbed ion on the colloidal particles is responsible for the development of electric charge. For example,
+
the selective adsorption of H ions lead to the development of positive charge on the colloidal particles and
–
the selective adsorption of OH ions lead to the development of negative charge on the colloidal particles.
31. A colloidal solution of ferric hydroxide sol is prepared by the hydrolysis of FeCl3. The colloidal particles
of ferric hydroxide are
(A) Negatively charged (B) Positively charged
(C) Neutral (D) Can not be predicted
32. Which of the following ion forms primary electrical double layer on the colloidal particle of As2S3 ?
3+ – + 2–
(A) As (B) OH (C) H (D) S
Polymerization involves various mechanisms depending upon the initiator. If initiator generates free radical,
addition polymerization takes place through free radical mechanism.
+
If H is initiator and electron releasing group is present, cationic polymerization takes place. If electron
withdrawing group is present and strong base is initiator, anionic polymerization takes place
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35. Acetic acid and aq. NH3 are weak monobasic acid and weak monoacidic base respectively and Ka of
acetic acid is equal to Kb of aq. NH3. Which of the following statements are correct ?
(A) All the above mixing would result in neutral solution having pH = 7 at 25C
(B) If aq. NH3 is exactly half neutralized by HCl, then pOH of resulting solution is equal to pK b
(C) If acetic acid is exactly half neutralized by NaOH , the pH of resulting solution is equal to pK a
(D) If acetic acid is exactly neutralized by aq. NH3 then pH of resulting solution is equal 1/ 2 pkw.
38. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are)
(A) Adsorption is always exothermic
(B) Physisorption may transform into chemisorption at high temperature
(C) Chemisorption is more exothermic than physisorption, however it is very slow due to higher
energy of activation
(D) Physisorption increases with increasing temperature but chemisorption decreases with increasing
temperature.
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40. Alanine, an -amino acid is existed in the following equilibrium at different pH values of the solution.
OH OH
CH3 CH COOH CH3 CH COO CH3 C H COO
| | |
NH3 NH3 NH2
pKa12.3 pKa2 9.7
(at pH0) (at pH14)
Identify the correct statements from the following:
(A) at pH=6.0 the solubility of alanine is minimum
(B) at pH=2.3, the concentration of dipolar ion is same as that of cationic form
(C) at pH=6.0 the concentration of anionic form dominating over the cationic form
(D) at pH=9.7, the concentration of dipolar ion is same as that of anionic form
x2 y2
41. If the normal at the point P() to the ellipse = 1 intersects it again at the point Q(2), then cos
14 5
is equal to
2 2 3 3
(A) (B) (C) (D)
3 3 2 2
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42. If y = f(x) passing through (1, 2) satisfies the differential equation y(1 + xy)dx = x dy = 0, then
x 1 2x x 1 4x
(A) f(x) = 2 (B) f(x) = (C) f(x) = (D) f(x) =
x 1 2x 2
4x 2
1 2x 2
2
43. Slope of the chord of the tangent to parabola y = 4ax which passes through the point (–6a, 0) and
which subtends an angle of 45 at the vertex is
3 2 7 5
(A) (B) (C) (D)
8 7 2 6
2
44. If the parabola y = (a – b)x + (b – c)x + (c – a) touches the x-axis, then the line ax + by + c = 0
(A) represents the family of parallel lines (B) always passes through a fixed point
(C) is always perpendicular to x-axis (D) always has negative slope
x2 y2 PM 2
45. If normal at any point P to the ellipse = 1, a > b meets the axes at M and N so that ,
a2 b2 PN 3
then value of eccentricity e is
(A) cos 45 (B) sin 30 (C) sin 60 (D) tan 30
2 2 2 2
46. If 4x + py = 45 and x – 4y = 5 cut orthogonally, then the value of p is
1 1
(A) (B) (C) 9 (D) 3
9 3
x2 y2
47. If P is any point common to the hyperbola = 1 and the circle having line segment joining its
16 25
foci as diameter, then sum of focal distances of point P is
(A) 2 66 (B) 6 2 (C) 16 (D) 8
2
48. The locus of centroid of triangle formed by a tangent to the parabola y = 36x with coordinate axes is
2 2 2 2
(A) y + 3x = 0 (B) y = –9x (C) y = 3x (D) y = 9x
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x2 y2
2 2
The circle x + y – 8x = 0 and hyperbola intersect at points A and B
9 4
53. The equation of a common tangent with positive slope to the circle as well as to the hyperbola is
(A) 2x – 5 y – 20 = 0 (B) 4x – 3y + 4 = 0 (C) 3x – 4y + 8 = 0 (D) 2x – 5 y + 4 = 0
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55. The major axis and minor axis of an ellipse are respectively x – 2y – 5 = 0 and 2x + y + 10 = 0. If one
end of latus rectum is (3, 4), then the foci are
(A) (5, 0) (B) (–7, –6) (C) (11, 3) (D) (–11, –8)
x2 y2 x2 y2
56. For the ellipse 2
2 1 and 2 2 = 1
a b b a
(A) Their auxiliary circles are the same
(B) The foci of each ellipse always lie within the order ellipse
(C) Their director circles are the same
(D) The ellipse encloses the same area
1 2 2
57. A hyperbola having the transverse axis of length and is confocal with the ellipse 3x + 4y = 12,
2
then
(A) Eccentricity of the hyperbola is 4
x2 y2 1
(B) equation of the hyperbola is
15 1 16
1
(C) Distance between the directrices of the hyperbola is units
8
15
(D) Length of latus rectum of the hyperbola is units
2
2
58. The equations of the chords of the parabola y = 4ax which pass through the point (–6a, 0) and which
subtends an angle of 45 at the vertex is/are
(A) 2x – 7y + 12a = 0 (B) 7x – 2y + 12a = 0 (C) 2x + 7y + 12a = 0 (D) 7x + 2y + 12a = 0
2
59. Two distinct chords passing through (a, 2a) of parabola y = 4ax are bisected by the line
x + y = 1. Then the length of latus rectum can be
(A) 1 (B) 2 (C) 3 (D) 4
2
60. Let y – 5y + 3x + k = 0 be a parabola, then
(A) its latus rectum is independent of k
(B) its latus rectum is least when k = 1
73
(C) the line y = 2x + 1 will touch the parabola if k =
16
5
(D) y = is the only normal to the parabola whose slope is zero.
2
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CHEMISTRY
21. A 22. B 23. B 24. C
25. C 26. B 27. B 28. A
29. C 30. A 31. B 32. D
33. D 34. A 35. A, B, C, D 36. A, C, D
37. A, B, C, D 38. A, B, C 39. A, C 40. A, B, D
MATHEMATICS
41. B 42. B 43. B 44. B
45. D 46. C 47. A 48. A
49. B 50. C 51. D 52. B
53. D 54. C 55. AD 56. ACD
57. ACD 58. AC 59. ABC 60. ACD
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Useful data
–1 –1 –2 –1 –1 –1
R = 8.314 JK mol or 8.206 10 L atm K mol ; 1 F = 96500 C mol
–34 –19
h = 6.626 10 Js; 1 eV = 1.602 10 J
–1
c = 3.0 10 ms ; NA = 6.022 10
8 23
(Atomic Masses in amu : H = 1 , He = 4, C = 12, N = 14, O = 16, Na = 23, Mg = 24, P = 31, S = 32,
Cl = 35.5, K = 39, Ca = 40, Fe = 56, Cu = 63.5)
NAME:
ENROLLMENT NO.:
PAPER–II
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PH-VII-2018-P(II)-SET-A-PCM-32
PART I: PHYSICS
SECTION – I: Single Correct Answer Type
The section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1 1
1. The amplitude of a wave represented by displacement equation y sin t cos t will be
a b
ab a b a b ab
(A) (B) (C) (D)
ab ab ab ab
3. A metallic wire with tension T and at temperature 30c vibrates with its fundamental frequency of 1
kHz. The same wire with the same tension but at 10C temperature vibrates with a fundamental
frequency of 1.001 kHz. The coefficient of linear expansion of the wire is
–4 –4 –4 –4
(A) 2 x 10 /C (B) 1.5 x 10 /C (C) 1 x 10 /C (D) 0.5 x 10 /C
4. An inductor coil joined to a 6V battery draws a steady current of 1.5A , but when this coil is
connected to a 20V , 50Hz AC source it draws a current of 4A . The reactance of this coil when it is
connected to a 30V , 100Hz AC source is
(A) 6 (B) 12 (C) 18 (D) 3
Acceleration of point x = 2 m of a transverse wave is 5 ˆj m/s and the slope of waveform is given
2
5.
dy
5 sin x . Then the speed of the point at that instant is given in m/s as
dx 12
50 100 150 200
(A) (B) (C) (D)
3 3 3 3
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6. The voltage time (V —t) graph for a triangular wave having peak value V0 is as shown in figure. The
rms value of V is:
V0 V0 V0 V0
(A) (B) (C) (D)
3 2 2 3
C
8. An inductor L, a capacitor C and ammeters A1, A2 and A3 are connected to an A1
oscillator in the circuit as shown in the adjoining figure. when the frequency of
the oscillator is increased, then at resonant frequency, the ammeter reading is L
A2
zero in the case of
(A) ammeter A1 (B) ammeter A2
~ A3
(C) ammeter A3 (D) all the three ammeters
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10. Keeping tension and amplitude in the given rope remaining the same, if a simple harmonic oscillator
of frequency 200 Hz is used instead of the earlier oscillator of frequency 100 Hz. Then
(A) Speed of transverse waves in the rope will not change, wavelength will not change and energy
density will become one fourth.
(B) Speed of transverse waves in the rope will become half; wavelength will become one-fourth and
energy density will become two times.
(C) Speed of transverse waves in the rope will become four times; wavelength will become doubled
and energy density will not change .
(D) Speed of transverse waves in the rope will not change; wavelength will become half and energy
density will become four times.
3 3
In the circuit shown in figure R1 = 10, L = H, R2 = 20 and C = F. Current in L – R1 circuit is I1 in
10 2
C – R2 circuit I2 and the main current is I.
The two circuits are in parallel. So, they r be treated separately.
12. At some instant current in L-R1 circuit is 10 A. At the same instant current in C – R2 circuit will be :
(A) 5 A (B) 5 2A (C) 6 6A (D) 5 3A
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The equation of a stationary wave in a string is y =(4 mm) sin[(3.14m ) x] cos t.
-1
15.
Select the correct alternative(s)
(A) The amplitude of component waves is 2 mm
(B) The amplitude of component waves is 4 mm
(C) The smallest possible length of string is 0.5 m
(D) The smallest possible length of string is 1.0 m
16. Velocity of sound in air is 320 m/s. A pipe closed at one end has a length of 1 m. Neglecting end
corrections, the air column in the pipe can resonate for sound of frequency:
(A) 80 Hz (B) 240 Hz (C) 320 Hz (D) 400 Hz
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17. Two identical straight wires are stretched so as to produce 6 beats per second when vibrating
simultaneously. On changing the tension slightly in one of them, the beat frequency remains
unchanged. Denoting by T 1 and T2 the higher and the lower initial tension in the strings, then it could
be said that while making the above changes in tension :
(A) T2 was decreased (B) T2 was increased
(C) T1 was decreased (D) T1 was increased
19. If a string fastened at both ends has successive resonance with wavelength of 0.54m for the nth
th
harmonic and 0.48m for the (n + 1) harmonic then (with a given frequency)
(A) the value of n is 8
(B) the length of the string is 2.16m
(C) the wavelength of the fundamental frequency is 4.32m
(D) fundamental frequency is 18Hz
20. The vibration of a string fixed at both ends are described by Y = 2 sin (x) sin(100t) where Y is in
mm, x is in cm, t in sec then
1
(A) maximum displacement of the particle at x cm would be 1 mm
6
1 1
(B) velocity of the particle at x cm at time t = sec will be 157 3 mm/s
6 600
(C) if the length of the string be 10 cm, number of loop in it would be 5
(D) none of these
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23. 100 mL of 0.1 M NaOH is added to 100 mL of a 0.2 M CH3COOH solution. The pH of the resulting
–5
solution will be (Ka for CH3COOH = 1.8 x 10 )
(A) 4.74 (B) 5.74 (C) 3.74 (D) 7.00
24. Buna-S is a
(A) condensation polymer formed by styrene and 1,3-butadiene
(B) addition polymer formed by styrene and 1,3-butadiene
(C) condensation polymer of hexamethylene diamine and adipic acid
(D) addition polymer of hexamethylene diamine and adipic acid
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26. In the following reaction HC2O4 PO34 HPO24 C2O24 which are the two Bronsted base ?
(A) HC2O4 and PO34 (B) HPO24 and C2O24
(C) HC2O4 and HPO24 (D) PO34 and C2O24
27. What is the change in pH of water when 0.01 mole of NaOH are added in 10 litre water.
(A) 3 (B) 4 (C) 6 (D) 11
28. Which one of the following characteristics is not correct for physical adsorption?
(A) Adsorption on solids is reversible
(B) Adsorption decreases with increase in temperature
(C) Adsorption is non specific
(D) Both change in enthalpy and change in entropy of adsorption is positive
The charge on colloidal particle is due to the selective adsorption of ions present in the dispersion medium.
The adsorbed ion on the colloidal particles is responsible for the development of electric charge. For example,
+
the selective adsorption of H ions lead to the development of positive charge on the colloidal particles and
–
the selective adsorption of OH ions lead to the development of negative charge on the colloidal particles.
29. A colloidal solution of ferric hydroxide sol is prepared by the hydrolysis of FeCl 3. The colloidal particles
of ferric hydroxide are
(A) Positively charged (B) Negatively charged
(C) Neutral (D) Can not be predicted
30. Which of the following ion forms primary electrical double layer on the colloidal particle of As 2S3 ?
3+ 2– + –
(A) As (B) S (C) H (D) OH
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Polymerization involves various mechanisms depending upon the initiator. If initiator generates free radical,
addition polymerization takes place through free radical mechanism.
+
If H is initiator and electron releasing group is present, cationic polymerization takes place. If electron
withdrawing group is present and strong base is initiator, anionic polymerization takes place
A solution which remains in equilibrium with undissolved solute, is said to be saturated. The concentration of a
saturated solution at a given temperature is called solubility. The product of concentration of ions in a
saturated solution of an electrolyte at a given temperature, is called solubility product K sp . For the
electrolyte, AxBy with solubility S, A xBy s xA y yBx . The solubility product K sp = x x y y sx y .
While calculating the solubility of a sparingly soluble salt in the presence of some strong electrolyte containing
a common ion, the common ion concentration is practically equal to that of strong electrolyte. If in a solution,
the ionic product of an electrolyte exceeds its Ksp value at a particular temperature, then precipitation occurs.
33. The solubility of PbSO4 in water is 0.303 g/l at 25C, its solubility product at that temperature is
–6 2 –4 2 –8 2 –8 2
(A) 10 M (B) 9.18 x 10 M (C) 10 M (D) 9.18 x 10 M
34.
The solubility of BaSO4 in 0.1 M BaCl2 solution is K sp of BaSO4 1.5 109
–9 –8 –16 –18
(A) 1.5 x 10 M (B) 1.5 x 10 M (C) 2.25 x 10 M (D) 2.25 x 10 M
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36. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are)
(A) Adsorption is always exothermic
(B) Physisorption may transform into chemisorption at high temperature
(C) Physisorption increases with increasing temperature but chemisorption decreases with increasing
temperature.
(D) Chemisorption is more exothermic than physisorption, however it is very slow due to higher
energy of activation
38. Alanine, an -amino acid is existed in the following equilibrium at different pH values of the solution.
OH OH
CH3 CH COOH CH3 CH COO CH3 C H COO
| | |
NH3 NH3 NH2
pKa12.3 pKa2 9.7
(at pH0) (at pH14)
Identify the correct statements from the following:
(A) at pH=6.0 the solubility of alanine is minimum
(B) at pH=6.0 the concentration of anionic form dominating over the cationic form
(C) at pH=2.3, the concentration of dipolar ion is same as that of cationic form
(D) at pH=9.7, the concentration of dipolar ion is same as that of anionic form
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39. Acetic acid and aq. NH3 are weak monobasic acid and weak monoacidic base respectively and Ka of
acetic acid is equal to Kb of aq. NH3. Which of the following statements are correct ?
(A) All the above mixing would result in neutral solution having pH = 7 at 25C
(B) If aq. NH3 is exactly half neutralized by HCl, then pOH of resulting solution is equal to pKb
(C) If acetic acid is exactly half neutralized by NaOH , the pH of resulting solution is equal to pK a
(D) If acetic acid is exactly neutralized by aq. NH 3 then pH of resulting solution is equal 1/ 2 pkw.
x2 y2 PM 2
41. If normal at any point P to the ellipse = 1, a > b meets the axes at M and N so that ,
a2 b2 PN 3
then value of eccentricity e is
(A) cos 45 (B) sin 30 (C) tan 30 (D) sin 60
2 2 2 2
42. If 4x + py = 45 and x – 4y = 5 cut orthogonally, then the value of p is
1 1
(A) (B) (C) 3 (D) 9
9 3
x2 y2
43. If P is any point common to the hyperbola = 1 and the circle having line segment joining its
16 25
foci as diameter, then sum of focal distances of point P is
(A) 6 2 (B) 2 66 (C) 16 (D) 8
2
44. The locus of centroid of triangle formed by a tangent to the parabola y = 36x with coordinate axes is
2 2 2 2
(A) y = –9x (B) y + 3x = 0 (C) y = 3x (D) y = 9x
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x2 y2
45. If the normal at the point P() to the ellipse = 1 intersects it again at the point Q(2), then cos
14 5
is equal to
2 2 3 3
(A) (B) (C) (D)
3 3 2 2
46. If y = f(x) passing through (1, 2) satisfies the differential equation y(1 + xy)dx = x dy = 0, then
2x x 1 x 1 4x
(A) f(x) = (B) f(x) = 2 (C) f(x) = (D) f(x) =
2x 2
x 1 4x 2
1 2x 2
2
47. Slope of the chord of the tangent to parabola y = 4ax which passes through the point (–6a, 0) and
which subtends an angle of 45 at the vertex is
2 3 7 5
(A) (B) (C) (D)
7 8 2 6
2
48. If the parabola y = (a – b)x + (b – c)x + (c – a) touches the x-axis, then the line ax + by + c = 0
(A) always passes through a fixed point (B) represents the family of parallel lines
(C) is always perpendicular to x-axis (D) always has negative slope
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x2 y2
2 2
The circle x + y – 8x = 0 and hyperbola intersect at points A and B
9 4
51. The equation of a common tangent with positive slope to the circle as well as to the hyperbola is
(A) 2x – 5 y – 20 = 0 (B) 2x – 5 y + 4 = 0 (C) 3x – 4y + 8 = 0 (D) 4x – 3y + 4 = 0
1 2 2
55. A hyperbola having the transverse axis of length and is confocal with the ellipse 3x + 4y = 12,
2
then
x2 y2 1
(A) equation of the hyperbola is
15 1 16
(B) Eccentricity of the hyperbola is 4
1
(C) Distance between the directrices of the hyperbola is units
8
15
(D) Length of latus rectum of the hyperbola is units
2
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2
56. The equations of the chords of the parabola y = 4ax which pass through the point (–6a, 0) and which
subtends an angle of 45 at the vertex is/are
(A) 2x – 7y + 12a = 0 (B) 2x + 7y + 12a = 0 (C) 7x – 2y + 12a = 0 (D) 7x + 2y + 12a = 0
2
57. Two distinct chords passing through (a, 2a) of parabola y = 4ax are bisected by the line
x + y = 1. Then the length of latus rectum can be
(A) 1 (B) 2 (C) 3 (D) 4
2
58. Let y – 5y + 3x + k = 0 be a parabola, then
(A) its latus rectum is least when k = 1
(B) its latus rectum is independent of k
73
(C) the line y = 2x + 1 will touch the parabola if k =
16
5
(D) y = is the only normal to the parabola whose slope is zero.
2
59. The major axis and minor axis of an ellipse are respectively x – 2y – 5 = 0 and 2x + y + 10 = 0. If one
end of latus rectum is (3, 4), then the foci are
(A) (5, 0) (B) (–7, –6) (C) (–11, –8) (D) (11, 3)
x2 y2 x2 y2
60. For the ellipse 1 and =1
a2 b2 b2 a2
(A) The foci of each ellipse always lie within the order ellipse
(B) Their auxiliary circles are the same
(C) Their director circles are the same
(D) The ellipse encloses the same area
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CHEMISTRY
21. B 22. D 23. A 24. B
25. B 26. D 27. B 28. D
29. A 30. B 31. A 32. C
33. A 34. B 35. A, B, C, D 36. A, B, D
37. B, C 38. A, C, D 39. A, B, C, D 40. B, C, D
MATHEMATICS
41. C 42. D 43. B 44. B
45. A 46. A 47. A 48. A
49. A 50. A 51. B 52. A
53. A 54. B 55. BCD 56. AB
57. ABC 58. BCD 59. AC 60. BCD
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