Jee Main Revise

Sri Chaitanya IIT Academy., India.
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Jr. Super60-I Date: 10-06-17
Time: 07:30 AM to 10:30 AM WTM-7 Max.Marks:360
Name of the Student: ______________ I.D.NO:

IMPORTANT INSTRUCTIONS: Determination of enthalpy of hydration of
1) Immediately fill in the particulars on this page of the
CuSO4, Resonance energy, Limitations of
Test Booklet with Blue/Black Ball Point Pen. Use of
pencil is strictly prohibited. first law of thermodynamics; Second law of
2) The test is of 3 hours duration. Thermodynamics; Carnot cycle, efficiency of
3) The Test Booklet consists of 90 questions. The thermodynamic system ,Entropy - physical
maximum marks are 360.
significance, expressions in all types of
4) There are three parts in the question paper A, B, C
consisting of Mathematics, Chemistry and Physics processes ,Gibb's free energy - physical
having 30 questions in each part of equal weight age. significance, spontaneity of processes(70%)
Each question is allotted 4 (four) marks for correct Thermodynamics: Terms involved in
response.
5) Candidates will be awarded marks as stated above in
thermodynamics - System & Surrounding,
instruction No. 4 for correct response of each Extensive and Intensive Properties, Path and
question. (1/4) (one fourth) marks will be deducted State function, types of processes, First law
for indicating incorrect response of each question.
of thermodynamics , Reversible and
No deduction from the total score will be made if no
response is indicated for an item in the answer sheet. irreversible processes; Work - expressions
6) There is only one correct response for each question. for reversible, irreversible isothermal and
Filling up more than one response in any question adiabatic processes, Heat and Heat capacity,
will be treated as wrong response and marks for
Thermo chemistry: Enthalpy(30%)
wrong response will be deducted accordingly as per
instruction 5 above. PHYSICS:
Non - uniform accelerated motion in 1D &
SYLLABUS
MATHS: related graphs, Motion in 2D, Projectile
Transformation formulae, Conditional motion (Excluding projection on inclined

Identities, Graphs of Trigonometric planes) (70%)
Functions, Periodicity and extreme values Kinematics: Motion in 1D, Uniform motion,
(30%); Trigonometric Equations (70%) uniform accelerated motion, motion under
CHEMISTRY: gravity and related graphs (30%)
Enthalpy of reaction - different types of Cumulative syllabus covered till now (10%)
enthalpies, Hess's law, Effect of temperature
on enthalpy of reaction - Kirchhoff’s
equation, Hess’s law and its applications,
Sri Chaitanya IIT Academy 10-06-17_Jr.Super60-I_Jee-Main_WTM-7_Q.P
MATHS 5. Total no of solutions of the equation,
1. If sin(sin x cos x) cos(cos x sin x) 1
f ( x) Max sin x,cos x in
then the largest possible value of sin x 2
is x ( 2 ,5 )
1 1) 3 2) 5
1) 2) 1
2 3) 7 4) 9
2
16 6. The total number of values of x in
3) 4)
4 4
( 2 , 2 ) satisfying
2. Sum of the common solutions of the
log cos x sin x log sin x cos x 2
simultaneous equations
cos 2 x sin 2 x cot x 1) 2 2) 4
,x ,
2cos 2 x cos2 2 x 1 3) 6 4) 8
2
1) 2) 0 7. If Tan( A B ) 1 , and Sec( A B) ,
2 3
3 and A and B are the smallest positive

3) 4)
2 values satisfying both the equations
3. No of solutions of A+B=
sin x sin y sin( x y ) and x y 1 11 13
1) 2)
1) 2 2) 4 6 6
17 3
3) 6 4) 0 3) 4)
6 6
4. The number of values of y in 2 ,2
8. Number of solutions of
satisfying the equations cos( sinx) sin(cos x) , x 2 ,2
sin 2 x cos 2 x sin y is 1) 0 2) 2
1) 1 2) 2 3) 1 4) 4
3) 3 4) 4
Jr. Super60-I space for rough work Page 2
9. The smallest positive values of x and x1 solutions if C 2 8 and has x2
y satisfying x y , cot x cot y 2 solutions if C 2 8 ,the ordered pair

4
( x1 , x2 ) is
5 7
1) , 2) ,
12 6 12 3 1) (4,2) 2) (2,4)
9 5 3) (3,3) 4) (3,5)
3) , 4) ,
7 4 12 4
14. If x (0, 2 ) and y ( , 2 ) , the number
10. The number of real solutions of the
of solutions of the system of equations
x x x 2 x 2
equation sin(e ).cos(e ) 2 2
1 3
sin x sin y ,cos( x y) cos( x y)
1) 0 2) 1 4 2
3) 2 4) infinite 1) 3 2) 4
11. The number of points of intersection of 3) 5 4) 6
15. If sin x cos x tan x cot x sec x cos ecx 7
the y cos x , y sin 3 x in x
2 2 and sin 2 x a b 7 ,then the ordered
1) 3 2) 4 pair ( a, b ) can be
3) 5 4) 6 1) (6,2) 2) (8,3)
12. The smallest positive root of the 3) (22,8) 4) (11,4)
equation sin(1 x) cos x is 16. The number of solutions of the equation
1 7 1 3 Tan 2 x Sec10 x 1 0 in (0,10) is
1) 2)
2 4 2 4 1) 3 2) 6
3 1 5 3) 10 4) 0
3) 4)
4 4 2 4 17. If denotes the greatest integer
13. In 0 , 2 , the equation function then number of solutions of
sin x 1 sin x 1 cos x in 2 , 2
Sec Co sec C has is
1) 0 2) 1
3) 2 4) 4
18. The number of solutions of 22. If a cos2 3 b cos4 16cos6 9 cos2 is
( , ) satisfying identity, then

2 2
1) a 1,b 24 2) a 3, b 24
sec2 4 2
( 3) tan 2 tan is 3) a 4, b 2 4) a 7,b 18
1) 4 2) 2 23. If
3) 1 4) 3
f (x) sin 2 x sin 2 x cos x cos x
sec4 tan 4 1 3 3
19. If ,then
a b a b 5
and g 1, then gof
1) b a 2) a b 4 8
b 1) 5 2) 1
3) b a 4) 2 4
a
3) 2 4)
20. If sin x 2 cos x 3, x 0,2 24. If
where is the greatest integer un sin n secn ,vn cosn secn 1
v vn 1 1 u n
function ,then x then n is equal to
un 1 n vn
5 5 1) 0 2) tan
1) ,2 2) ,2
4 4
3) tan tan n 4) tan tan n
5 5 n n
3) , 4) ,
4 4 25. If K1 tan 27 tan and
21. T he number of solutions in x 0, 2 sin sin3 sin9 ,then
K2
cos3 cos9 cos27
for which
sin x cos x 3 sin x cos x
1) K1 2K 2 2) K1 K2 4
( is greatest integer function) 3) K1 K2 4) None of these
1) 0 2) 4 26. If , , , are the smallest positive angles
3) infinite 4) 1 in ascending order of magnitude which

have their sines equal to the positive 29. If a1 cos 1
a2 cos 2
..... an cos n 0
quantity k , then the value of
a1 cos( 1 ) a 2 cos( 2 )
and , then
4sin 3sin 2sin sin is equal ...a n cos( n ) 0( k )
2 2 2 2
to a1 cos( ) a 2 cos( ) ...
1 2
1) 2 1 k 2) 2 1 k a n cos( n )
3) 2 k 4) None of these 1) 0 2)
27. If tan x 2 x and
x2 x 1 3) 4)
1 ,0 then 30. If the mapping f (x) ax b,a 0 maps
tan 2
,
2x 2x 1 2
1,1 onto 0,2 , then for all values of
1) 2)
4 2 ,A cos2 sin 4 is such that
3) 4) 3 1) f 1
A f (0)
3 4 4
28. The value of sin 2 sin 4 sin 8 is 2) f (0) A f ( 2)

7 7 7
1) 1 2) 7 3) f 1 A f (0)
3
2
4) f ( 1) A f ( 2)
3) 3 3 4) 15
4 4

CHEMISTRY 33. The standard enthalpy of formation of
31. Assuming that water vapour is an ideal NH 3 is 46.0 kJ mol 1 . If the enthalpy of
gas, the internal energy U when 1
formation of H 2 from its atoms is
mol of water is vapourized at 1 bar 1
436 kJ mol and that of N 2 is
0
pressure and 100 C . (Given: Molar
712 kJ mol 1 , the average bond enthalpy
enthalpy of vapourization of water at 1
of N-H bond in NH 3 is
bar and 373K 41kJ mol 1 and
1 1
1 1
1) 1102 kJ mol 2) 964kJ mol
R 8.3 J mol K ) will be
1 1
1 1
3) 352 kJ mol 4) 1056 kJ mol
1) 4.1kJ mol 2) 3.7904 kJ mol
1 1
34. The lattice energy of NaCl is
3) 37.904 kJ mol 4) 41.0 kJ mol
780 kJ mol 1. The enthalpies of hydration
32. Oxidizing power of chlorine in
of Na g and Cl g ions are
aqueous solution can be determined by
1 1
the parameters indicated below: 406 kJ mol and 364 kJ mol
1 1
2 diss H
0
eg H
0
hyd H
0
. respectively. The enthalpy of solution of
Cl g Cl g Cl g Cl aq
2 2
NaCl(s) in water is
The energy involved in the conversion 1 1
1) 738 kJ mol 2) 10 kJ mol
1
of Cl2 g to Cl g (using the data, 1 1
2 3) 10 kJ mol 4) 822 kJ mol
diss H 0 Cl2 240kJ mol 1 , 35. The entropy change involved in the
eg H 0 Cl 349 kJ mol 1
H 0 Cl 381kJ mol 1 isothermal reversible expansion of 2 mol
hyd
of an ideal gas from a volume of 10 dm3 to

1 1
1) 152kJ mol 2) 610kJ mol a volume of 100 dm3 at 270 C is
1 1 1) 35.8J mol 1K 1
2) 32.3J mol 1 K 1
3) 850kJ mol 4) 120kJ mol
3) 42.3J mol 1K 1
4) 38.3J mol 1 K 1

36. Standard entropies of X 2 , Y2 and XY3 40. Which one of the following statements is
1 1
are 60, 40 and 50 JK mol , false?
respectively. For the reaction, 1) Work is a state function
1 3
X2 Y2 XY3 ; H 30 kJ to be at 2) Temperature is a state function
2 2
equilibrium, the temperature will be 3) Work appears at the boundary of the
1) 1250 K 2) 500 K
system
3) 750 K 4) 1000 K
4) Change in the state is completely
37. What is the sign of G for the process
defined when the initial and final states
of melting of ice at 280 K?
are specified.
1) G 0 2) G 0
41. Calculate the work, in joules, done by a
3) G 0 4) None of these gas as it expands at constant temperature
38. For a reversible isothermal expansion from a volume of 3.00 L and a pressure
of 5.00 atm to a volume of 8.00 L. The
of an ideal gas
external pressure against which the gas
1) S sys Ssurr positive expands is 1.00 atm. (1 atm = 101,325
2) S sys S surr pa.)
1) 405J 2) 532J
3) S sys S surr negative
3) 458J 4) 507J
4) S sys S surr 0 42. Which one of the following equations
39. Among mass, volume, density and does not correctly represent the first law
specific volume of a gas, the intensive of thermodynamics for the given process?
properties are 1) Isothermal process: q = - w
1) density and specific volume 2) Cyclic process: q = - w
2) volume and density 3) Isochoric process: U q
3) specific volume and mass 4) Adiabatic process: U w
4) density only
43. The enthalpy of neutralization of HCl 45. For which change H U?
by NaOH is 55.9 kJ mol 1. If the
1) H 2 g I2 g 2 HI g
enthalpy of neutralization of HCN by
NaOH is 12.1 kJ mol 1 , the enthalpy of 2) HCl aq NaOH aq NaCl aq H 2O l
dissociation of HCN is 3) C s O2 g 2CO2 g
1) 43.8 kJ 2) -43.8 kJ 4) N 2 g 3H 2 g 2 NH 3 g
3) 68 kJ 4) -68 kJ 46. If water kept in an insulated vessel at

10 0 C suddenly freezes, the entropy
44. In a fuel cell, methanol is used as fuel
change of the system
and oxygen gas is used as an oxidizer.
1) decreases
The reaction is
2) increases
3
CH 3OH l O2 g CO2 g 2 H 2O l
2 3) is zero
. At 298K, standard Gibbs energies of 4) equals to that of the surroundings
formation for 47. Estimate the average S F bond energy
CH 3OH l , H 2O l and CO2 g are in SF6 . The standard heat of formation
166.2 kJ mol 1 , 237.2 kJ mol 1
and values of SF6 g , S g and F g are: - 1100,
394.4 kJ mol 1 , respectively. If the
275 and 80 kJ mol 1 respectively.
standard enthalpy of combustion of 1) 309.17 kJ 2) 212.5 kJ
methanol is 726 kJ mol 1 , efficiency of 3) 126.2 kJ 4) 182.5 kJ
the fuel cell will be 48. When one mole anhydrous CuSO4 is
1) 90% 2) 97%
dissolved in excess of water, 66.4 kJ
3) 80% 4) 87% heat is evolved. When one mole of
CuSO4 .5 H 2O is dissolved in water, the

heat change is +11.7 kJ. Calculate 51. Calculate the work done when 156g
enthalpy of hydration of CuSO4 anh. . potassium reacts with water in an open
1) -87.1 kJ 2) -78.1 kJ container of water at 300 K .

1) -2866.5 J 2) -4988.4 J
3) -44.2 kJ 4) -28.1 kJ
3) -1234.6 J 4) -862.5 J
49. H 0f values (i.e., enthalpy of
52. The enthalpy change for a reaction does
formation) for O3 , CaO, NH 3 and HI are
1
not depend upon
34.01, 151.9, 11.0 and 6.20 kcal mol
1) the physical states of reactants and
respectively. Arrange these in
products
decreasing order of stability with
2) use of different reactants for the same
respect to thermal decomposition.
product
1) CaO HI NH 3 O3
3) the nature of intermediate reaction
2) NH 3 HI CaO O3
steps
3) CaO NH 3 HI O3 4) the differences in initial or final
4) CaO HI O3 NH 3 temperatures of involved substances
50. Calculate the free energy change when 53. The direct conversion of A to B is
1 mole of NaCl is dissolved in water at difficult; hence it is carried out by the
250 C. Lattice energy of NaCl = 777.8 following shown path.
kJ mol 1; S for dissolution
1
0.043kJ mol and hydration energy of
1
NaCl 774.1 kJ mol
1 1
1) 9.114 kJ mol 2) 91.14 kJ mol
3) 911.4 kJ mol 1
4) 0.9114 kJ mol 1 Given

SA C
50 eu 3) the sum of standard molar enthalpies
SC 30 eu of formation of CO and O2
D
SB 20 eu 4) the standard molar enthalpy of

D
combustion of carbon (graphite).

Where eu is entropy unit, then S A B
56. Boiling water in a closed steel tank is an
is
example of
1) 100 eu 2) 60 eu
1) Closed system
3) 100 eu 4) 60 eu
2) Insulated system
54. For a reaction at equilibrium,
3) Open system
1) G G0 0
4) Adiabatic system
2) G 0 but not G 0
57. In which of the following reactions the
3) G 0 0 but not G
entropy change is positive?
4) G G0 0
1
1) H 2 g O H 2O l
2 2g
55. Standard molar enthalpy of formation
2) Na g Cl g NaCl s
of CO2 is equal to
1) zero 3) NaCl g NaCl s
2) the standard molar enthalpy of 4) H 2O l H 2O g
combustion of gaseous carbon

58. Which of the following process is non- PHYSICS
spontaneous 61. A stone is dropped from a hill of height
1) Heat flow from hot end to cold end 180m. Two seconds later another a stone
2) Water flow from higher level to is dropped from a point P below the top
lower level of the hill. If the two stones reach the
3) Gas flow from lower pressure ground simultaneously, the height of P
region to higher pressure region from the ground is (g = 10 ms-2)
4) Gas flow from higher pressure 1) 100 m 2) 90 m
region to lower pressure region 3) 80 m 4) none of these
59. Human body requires 2370 K. cal of 62. Water drops fall from the roof of a
energy daily. If the heat of combustion building 20m high at regular time
of glucose is 790 K .cal / mole the interval. If the first drop strikes the floor
amount of glucose required for daily when the sixth drop begins the fall, the
consumption is height of the second drop from the
1) 650 g 2) 540 g ground at that instant is
3) 327 g 4) 490 g (g = 10 ms-2)
60. In an insulated container 1 mole of a 1) 3.2 m 2) 0.8 m
liquid. Molar volume 100 ml at 1 bar. 3) 7.2 m 4) none of these
Liquid is steeply taken to 100 bar, 63. A body freely falling from a height h
when volume of liquid decreases by describes 11h/36 in the last second of its
1 ml. Find H for the process. fall. The height h is (g = 10ms-2)
1) 7900 bar mL 2) 8900 bar Ml 1) 125 m 2) 180 m
3) 9900 bar mL 4) 10900 bar mL 3) 360 m 4) none of these

64. A ball dropped from a point P crosses distance of 24m away in the direction of
a point Q in t seconds. The time taken the kick starts running at that instant to
by it to travel from Q to R, if PQ = QR catch the ball. Before the ball hits the
1) t 2) 2t ground to catch it, the speed with which
3) 2t 4) ( 2 -1)t the second player has to run is
65. A boy throws a ball in air in such a (g = 10 m/s2)
manner that when a ball is at its 1) 4 ms-1 2) 4 2 ms-1
maximum height he throws another 3) 8 2 ms-1 4) none of these
ball. If the balls are thrown with the 68. From the top of a tower, a stone is thrown
time difference 1 second, the up and it reaches the ground in time t1 . A
maximum height attained by each ball second stone is thrown down with the
is same speed and it reaches the ground in
1) 9.8 m 2) 19.6 m time t2 . A third stone is released from
3) 4.9 m 4) none of these
rest and it reaches the ground in time t3
66. A body projected vertically up reaches
1
a maximum height h in time t. The 1) t3 t1 t 2 2) t3 t1t2
2
time taken to reach the half of the
1 1 1
maximum height may be 3) 4) t32 t12 t22
t3 t2 t1
1) t/2 2) t/4
69. A body starts with velocity V and moves
t 1
3) 4) t 1 on a straight path with constant
2 2
acceleration. When its velocity becomes
67. A player kicks a football obliquely at a
5V the acceleration is reversed in
speed of 20 m/s so that its range is
direction without change in magnitude.
maximum. Another player at a

When it returns to the starting point, its 72. A boy sees a ball go up and then down
velocity becomes through a window 2.45 m high. If the
1) -7 V 2) -3 V total time that the ball in is sight is 1s, the
3) 7 V 4) -5 V height above the window the ball rises is
70. A train length 200 m switches on its approximately.
headlight when it starts moving with 1) 2.45 m 2) 4.9 m
acceleration 0.5 m / s 2 . Sometime later, 3) 0.3 m 4) 0.49 m
its tail light is switched on. An 73. A ball thrown horizontally with velocity
observer on the ground notices that the V from the top of a tower of height h
two events occur at the same place. reaches the ground in t seconds. If
The time interval between the two another ball of double the mass is thrown
events is horizontally with velocity 3V from the
top of another tower of height 4h it
1) 10 2 s 2) 20 s
reaches the ground in (seconds)
3) 20 2 s 4) 40 s
1) 3t 2) t/2
71. The distance traveled by a body during 3) 4t 4) 2t
last second of its upward journey is d 74. A balloon starts rising from the ground
when the body is projected with with an acceleration of 1.25 m / s 2 . After

certain velocity vertically up. If the 8 s, a stone is released from the balloon.
velocity of projection is doubled, the The stone will
distance traveled by the body during 1) Cover a distance of 40 m
last second of its upward journey is 2) have a displacement of 50 m
3) reach the ground in 4 s
1) 2d 2) 4d
4) begin to move down after being
3) d/2 4) d
released.
75. A ball rolls of the top of a stair way elevation is . If the velocity of
with a horizontal velocity u m/s. If the projection is same in all the cases, the
steps are h metre high and b metres proper elevation is
wide, the ball with hit the edge of the 1 a sin 2 b sin 2
1
1) sin
n th step, if 2 a b
1) n 2 h u / g b2 1 1 a sin 2 b sin 2
2) sin .
2) n 2
2 hu / g b 2 2 a b
3) n 2 h u2 / g b 1 1 a sin 2 b sin 2
3) sin
2 a b
4) n h u 2 / g b 2
1 1 a sin 2 b sin 2
76. A ball is thrown with velocity u 4) sin
2 a b
making an angle with the horizontal.
78. Velocity of the body on reaching the
Its velocity vector is normal to initial
ground is same in magnitude in the
velocity (u) vector after a time interval
following cases
of
A) a body projected vertically from the
u sin u
1) 2) top of tower of height ‘h’ with velocity
g g cos
‘V’
u u cos
3) 4) b) a body thrown downwards with
g sin g
velocity ‘V’ from the top of tower of
77. A projectile aimed at a mark which is
height ‘h’
in the horizontal plane through the
c) a body projected horizontally with a
point of projection falls “ a ” distance
velocity ‘V’ from the top of tower of
short of it when the elevation is and
height ‘h’
goes “ b ” distance too far when the

d) a body dropped from the top tower Y
of height ‘h’
V
1) a, b, c & d are correct
2) a b & c are correct
H
3) a & d are correct
30
2 v
4) d only correct 1
X
O A
79. A cannon ball has a horizontal range R
on a horizontal plane. If h and h ' are 3 2
1) 2)
2 3
the greatest heights in the two paths for
which this possible, then: 5 7
3) 4)
7 5
4h
1) R 4 hh' 2) R 81. A stone is dropped from a height of 10cm
h'
above the top of a window 80cm high.
3) R 4h h ' 4) R hh'
The time taken by the stone to cross the
80. A particle 1 is projected with speed V
window is
from a point O making an angle of
1)1/7 s 2) 2/7 s
30 with the vertical. At the same
3) 3/7 s 4) 4/7 s
instant, a second particle 2 is thrown
82. A projectile is thrown at an angle 30o
vertically upwards from a point A. The
with a velocity of 10 m/s. The change in
two particles reach H, the highest point
velocity during the time interval in which
on the parabolic path of particle 1
it reaches the highest point is
simultaneously. What is the ratio of
1) 10 m/s 2) 5 m/s
V / v?
3) 5 3 m/s 4) 10 3 m/s

83. A body is projected with velocity V so 3) 40 cm 4) 20 cm
that the maximum height is thrice the 86. Let two bodies be projected horizontally
horizontal range. Then the maximum in opposite directions with velocities
height is u1 and u2 from certain height. The time
72V 2 6 V2 instant from the start at which
1) 2)
145g 145 g
displacement vectors perpendicular to
V2
3) 4) none of these each other is
2g
2u1u2 u1u2
84. The range of a projectile, when 1) 2)
g g
launched at an angle of 15o with the
horizontal in 1.5km. The additional 2 u1u2 u1u2
3) 4)
g g
horizontal distance the projectile
would cover when projected with same 87. The horizontal and vertical displacement
velocity at 45o is of a projectile are given by x = 12t and y
1) 3 km 2) 4.5 km = 16t – 5t2, all the quantities being
3) 1.5 km 4) 2.5 km measured in S.I system. The maximum
85. A boy aims a gun at a bird from a height of the projectile is (g = 10 m/s2)
point, at a horizontal distance of 100 1) 25.6 m 2) 12.8 m
m. If the gun can impart a velocity of 3) 64 m 4) none of these
500 m/sec to the bullet, at what height 88. A ball is projected from the bottom of a
above the bird must he aim his gun in tower and is found to go above the tower
order to hit it? and is caught by the thrower at the

bottom of the tower after a time interval
(take g 10 m / sec 2 )
t1. An observer at the top of the tower
1) 100 cm 2) 50 cm
sees the same ball go up above him and
then come back it his level in a time hits the screen A, penetrates through it
interval t2. The height of the tower is and finally emerges out from B making
1)
1
gt1t2 2) g
t1 t 2 holes in A & B. If the resistance of air
2 8
and wood are negligible, the difference of
g 2 2 g 2
3) t1 -t 2 4) t1 -t 2 heights of the holes in A & B is
8 2
89. Two bodies are projected at angle 30o 1) 5m
49
and 60o to the horizontal from the 2) m
90
ground such then the maximum
7
3) m
heights reached by them are equal. 90
Then 4) none of the above
1) their times of flight are equal
2) their horizontal ranges are equal
3) the ratio of their initial speeds of
projection is 3 : 1
4) both take same time to reach the
maximum height
Mark the answer as
1) If a, b, c & d are correct
2) If only a, b & c are correct
3) If only a & c are correct
4) If a, c & d are correct
90. Two thin wood screens A & B are
separated by 200m. A bullet traveling
horizontally at a speed of 600 m/s
Sri Chaitanya IIT Academy., India.
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Jr. Super60-I Date: 10-06-17
Time: 07:30AM to10:30AM WTM-07 Max. Marks: 360
KEY SHEET
MATHS
1 4 2 2 3 3 4 4 5 3 6 4
7 1 8 1 9 1 10 1 11 1 12 1
13 2 14 2 15 3 16 1 17 1 18 2
19 1 20 3 21 1 22 1 23 2 24 3
25 1 26 2 27 1 28 2 29 1 30 1
CHEMISTRY
31 3 32 2 33 3 34 2 35 4 36 3
37 1 38 2 39 1 40 1 41 4 42 4
43 1 44 2 45 4 46 3 47 1 48 2
49 3 50 1 51 2 52 3 53 2 54 2
55 4 56 1 57 4 58 3 59 2 60 3
PHYSICS
61 3 62 3 63 2 64 4 65 3 66 4
67 2 68 2 69 1 70 3 71 4 72 3
73 4 74 3 75 2 76 3 77 2 78 2
79 1 80 2 81 1 82 2 83 1 84 1
85 4 86 3 87 2 88 3 89 1 90 2
Sri Chaitanya IIT Academy 10-06-17_Jr. Super60-I_JEE-MAIN_WTM-7_Key&Sol’s
SOLUTIONS:
MATHS
1. cos(cos x sin x) cos( (sin x cos x)
2
Taking +ve sign, cos x n

4
Taking -ve sign, sin x

4
2. Expressing both the equations in terms of Tanx ,we get Tan 2 x 1 ,x n ,For n=-2,0,-1,1,+2,
4
sum=0
3. using transformations for sin x sin y sin(x y) ,we get 6 solution
4. The Max value of sin y 1 ,while min of L.H.S is 1
3
sin y 1, y ,
2 2
1
5. f(x) is a periodic function with period 2 and y f (x) and y meet 2 times in 0, 2
2
3 5 7
6. sin x 1, cos x 1, Tanx 1 x , , , . 8values
4 4 4 4
3 3
7. Tan(A B) 1, A B ,
,
4 4 4
2
sec(A B) ,A B
3 6
19 25
A ,B
24 24
8. From the graph , analise that L.H.S always greater than R.H.S
1
9. sin(x y) cos(x y)
2
5
x ,y
12 6
1 x
10. The given equation is 2sin(e x ).cos(e x ) 2 2 x
2
RHS 1and LHS 1
For a solution sin(2.e x ) 1
x 0 , but sin 2 1
No solution
11. sin 3x sin( x)

2
3x n ( 1)n ( x)
2
considering even and odd cases

Jr. Super60-I -Main Page 2
3
x , ,
8 4 8
12. Consistant with cos x 0 and sin(1 x) 0
after solving 1 x n ( 1) n ( x)
2
1 4m 1
x ( ) ,m I
2 4
13. Draw the graph of sec cos ec
1 5 7 11
14. If 0 x , cos(x y) and cos(x y) 1: (x1 , y1 ) ( , ), ( , ) as the 2 solutions . Similarly,
2 6 6 6 6
7 7 11 11
for x ( ,2 ) there are 2 solutions ( , )and( )
6 6 6 6
2 2
15. Re-write the equation as (sin x cos x)(1 ) (7 )
sin 2x sin 2x
where , sin 3 2x 44sin 2 2x 36sin 2x 0 , sin 2x 22 8 7
16. sin 2 x 10 sec x10
1 Tan 3 x sex10 x Tan 2 x sec 2 x 1
sec x 1, cos x 1
17. sin x sin x 2 cos x 1
which is not possible

18. put sec 2 t
t
( 3) (t 2 1)(t 2 1)
2
t 2
sec4 tan 4 sec 2 tan 2

19.
a b a b
b
sec 2 1
a
20. we must have sin x 1, 2 cos x 2
21. LHS 1 , RHS 1
sin x 1, cos x 1
which is not possible

22. Given a cos 2 3 bc0s 4 16cos6 9cos 2
9 cos 2 16 cos6 a(4cos3 3cos ) 2 b cos 4
a(16cos 6 9 cos 2 24 cos 4 ) b cos 4 9a cos 2 (b 24a) cos 4 16a cos6
comparing ,we get 9a 0 a 1, b 24a 0 b 24a 24
1 1 2 1
23. f (x) (1 cos 2x) 1 cos(2x ) cos(2x ) cos
2 2 3 2 3 3

5 1 2
cos 2x cos(2x ) cos(2x )
4 2 3 3
5 1 5
2 cos(2x ) cos cos(2x ) for all x
4 2 3 3 3 4
5 5
f( ) and therefore gof ( ) g( ) 1
8 4 8 4
un vn vn cos n secn cos(n 1) secn 1

24. we have tan n and 1
vn un 1 sin(n 1) sec n 1
n
cos n sec cos(n 1) cos n cos(n 1) cos
sin(n 1) cos sin(n 1)
cos(n 1) cos sin(n 1) sin cos(n 1) cos
tan
cos sin(n 1)
vn vn 1 1 un tan n
sothat tan 0
un 1 n vn n
25.
K1 Tan 27 tan (tan 27 tan 9 ) (tan 9 tan 3 ) (tan 3 tan )
sin 2 2sin
now, tan 3 tan
cos3 cos cos3
2sin 3 2sin 9
similarly, tan 9 tan 3 and tan 27 tan 9
cos9 cos 27
sin 9 sin 3 sin
K1 2 2K 2
cos 27 cos9 cos3
26. , , , and sin sin sin sin k
, 2 , sin k
so that the given expression is equal to

2 3
4 sin 3sin( ) 2 sin sin
2 2 2 2
= 4 sin 3cos 2sin cos 2(sin cos ) 2 1 2sin cos 2 1 k

2 2 2 2 2 2 2 2
a 1
tan tan a 1
2a 1 wherex 2
27. tan( ) x a
1 tan tan a
1
(a 1)(2a 1)
a 1 a 1
a 1 2a 1 a 1 2a 1 1
1 1 a 1
1
a 1 2a 1 a 1 2a 1
5
hence (note : can not be
4 4
2 4 8 2 4 8
28. let S sin sin sin and C cos sin sin
7 7 7 7 7 7
then

2 4
C iS (i)
2 2
cos i sin is complex 7th root of unity and
7 7
6 5 3 6
C iS (ii) , etc
add (i) and (ii)

7
2 3 6 7
2C ... 1( 1)
1
1 7
C also multiple (i) and (ii) , C 2 S2 2 S
2 2
a1 cos( 1 ) a 2 cos( 2 )...... a n cos( n ) 0
29.
(a1 cos 1 a 2 cos 2 ... a n cos n ) cos (a1 sin 1 sin 2 ... a n sin n )sin 0
a1 sin 1 a 2 sin 2 ... a n sin n 0 (sin ce sin 0)
and a1 cos 1 a 2 cos 2 .... a n cos n 0
now a1 cos( 1 ) a 2 cos( 2 ) .... a n cos( n )
(a1 cos 1 a 2 cos 2 ... a n cos n ) cos (a1 sin 1 a 2 sin 2 ... a n sin n ) sin 0
30. given f (x) ax b f (x) a
since a<0, f (x) is a decreasing function f ( 1) 2and f (1) 0
a b 2 and a b 0 a 1 and b 1. thus f (x) x 1
clearly
1 3 1 2
f (0) 1, f ( ) , f ( 2) 3, f ( )
4 4 3 3, f ( 1) 2
1 cos 2 1 cos 2 2
also, A ( )
2 2
1 1 1 1 1 3 1 1 cos 4 7 1
cos 2 cos 2 cos 2 2 ( ) cos 4
2 2 4 2 4 4 4 2 8 8
3 1
A 1 f ( ) A f (0)
4 4
CHEMISTRY
31. 3
The reaction involved is H 2 O l H 2O g , where ng 1 mol, vap H 41 kJ mol 1. Now,
U H ng RT
1
41 kJ mol 1 8.3 10 3 kJ K 1mol 1
373 K
1 1
41 3.096 kJ mol 37.904 kJ mol
32. Given that

1
Cl2 g Cl aq ; H ?
2
1
Cl2 2Cl ; H1 240kJ mol

1
Cl Cl ; H 2 349 kJ mol
Aqueous 1
Cl medium
Cl aq ; H 3 381 kJ mol
Therefore,
H1 240 1
H H2 H3 349 381 610 kJ mol
2 2
H0 H
33. NH 3 g N g 3H g N H
3
The value of H for this reaction can be obtained from summation of following equations.
H
2 NH 3 2N 6H N H H0
6
2 NH 3 N 2 3H 2 r H0 92
N2 2N r H0 712
3H 2 6H r H0 436 3
2 NH 3 2N 6H r H0 2112
2112
Thus, at this condition N H H0 352kJ mol 1
6
34. NaCl s Na g Cl g H 780 kJ Lattice energy
Na g H 2O l Na aq H 406 kJ Hydration
Cl g H 2O l Cl aq H 364kJ Hydration
The net reaction of dissolution of NaCl s is NaCl s 2 H 2O l Na aq Cl aq

1
sol H 780 406 364 10 kJ mol
35. For an ideal gas, for isothermal reversible process,

V2 100
S 2.303nR log 2.303 2 8.314 log 38.3 J mol 1 K 1
V1 10
1 3
36. For the reaction, X2 Y2 XY3
2 2
1 3 1
r S 50 60 40 40 Jmol
2 2
H 30
Since, G H T S and at equilibrium G 0, so, T 103 750K
S 40
37. Melting of ice at 280 K is a non-spontaneous process
38. Conceptual
39. Density is mass per unit volume and specific volume is volume per unit mass

40. Work is not a state function; instead it is dependent on the path of the reaction
41. w p V
V 8.00 L 3.00 L 5.00 L
w 1 atm 5.00 L 5.00 L atm
101.325 J
In joules: - 5.00 L atm 507 J
1L atm
42. According to the first law of thermodynamics, U q w
For isothermal process, U 0. Hence, q = -w.

For cyclic process, U 0. Hence q = -w.
For isochoric process, V 0. Hence, U q w p V 0 ,
For adiabatic process, q = 0. Hence U w.

1
43. HCl NaOHK NaCl H 2 O H1 55.9 kJ mol
1
HCl NaOHK NaCl H 2 O H 2 12.1 kJ mol
Enthalpy of dissociation of HCN H2 H1 12.1 55.9 43.8 kJ
44. Conceptual
45. Conceptual
46. As the system is insulated from the surroundings, no heat enters or leaves the system. Hence,
S q /T 0.
47. Conceptual
48. We have to calculate enthalpy of reaction for
CuSO4 5H 2O CuSO4 .5H 2O; H ?
Given that
CuSO4 anh. 5 H 2 O aq. CuSO4 .5 H 2O aq ; H1 66.4 kJ …(1)
And CuSO4 .5 H 2 O aq. CuSO4 .5 H 2O aq ; H 2 11.7 kJ
On the basis of two equations

49. A compound with more negative H 0f value will have less energy associated with it and so
more stable. On the basis of given data CaO NH 3 HI O3

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Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

Name of the Student: ______________ I.D.NO:

Transformation formulae, Conditional motion (Excluding projection on inclined

3 and A and B are the smallest positive

y satisfying x y , cot x cot y 2 solutions if C 2 8 ,the ordered pair

( , ) satisfying identity, then

( is greatest integer function) 3) K1 K2 4) None of these

1) 0 2) 4 26. If , , , are the smallest positive angles

3) infinite 4) 1 in ascending order of magnitude which

28. The value of sin 2 sin 4 sin 8 is 2) f (0) A f ( 2)

Jr. Super60-I space for rough work Page 5

of an ideal gas from a volume of 10 dm3 to

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dissociation of HCN is 3) C s O2 g 2CO2 g

3) 68 kJ 4) -68 kJ 46. If water kept in an insulated vessel at

Jr. Super60-I space for rough work Page 8

1) -87.1 kJ 2) -78.1 kJ container of water at 300 K .

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SB 20 eu 4) the standard molar enthalpy of

combustion of carbon (graphite).

1) zero 3) NaCl g NaCl s

2) the standard molar enthalpy of 4) H 2O l H 2O g

combustion of gaseous carbon

Jr. Super60-I space for rough work Page 10

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when the body is projected with with an acceleration of 1.25 m / s 2 . After

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velocity at 45o is of a projectile are given by x = 12t and y

1) 3 km 2) 4.5 km = 16t – 5t2, all the quantities being

3) 1.5 km 4) 2.5 km measured in S.I system. The maximum

point, at a horizontal distance of 100 1) 25.6 m 2) 12.8 m

m. If the gun can impart a velocity of 3) 64 m 4) none of these

order to hit it? and is caught by the thrower at the

Taking +ve sign, cos x n

Taking -ve sign, sin x

For a solution sin(2.e x ) 1

11. sin 3x sin( x)

considering even and odd cases

12. Consistant with cos x 0 and sin(1 x) 0

13. Draw the graph of sec cos ec

where , sin 3 2x 44sin 2 2x 36sin 2x 0 , sin 2x 22 8 7

16. sin 2 x 10 sec x10

1 Tan 3 x sex10 x Tan 2 x sec 2 x 1

17. sin x sin x 2 cos x 1

which is not possible

sec4 tan 4 sec 2 tan 2

20. we must have sin x 1, 2 cos x 2

21. LHS 1 , RHS 1

which is not possible

9 cos 2 16 cos6 a(4cos3 3cos ) 2 b cos 4

a(16cos 6 9 cos 2 24 cos 4 ) b cos 4 9a cos 2 (b 24a) cos 4 16a cos6

comparing ,we get 9a 0 a 1, b 24a 0 b 24a 24

Jr. Super60-I -Main Page 3

un vn vn cos n secn cos(n 1) secn 1

26. , , , and sin sin sin sin k

so that the given expression is equal to

= 4 sin 3cos 2sin cos 2(sin cos ) 2 1 2sin cos 2 1 k

Jr. Super60-I -Main Page 4

add (i) and (ii)