ORGANIC CHEMISTRY Total Marks : 35 D P P DPP No. 8 Max. Time : 37 min. id and Basic Strength Type of Questions M.M., Min. Single choice Objective ('-1" negative marking) Q.1 to .9 (3 marks, 3 min) [27, 27] Match the Following (no negative marking) Q.10 (@ marks, 10 min.) [8,10] 1, Order of K, of following acids is @ HN —CH,-COOH NC-CH,-COOH —-H,C-CH,-CooH ~— 80c-cH,- coo 0 wm ay wo (> U> > IV BS T>M> IV (O)I>M>M>1V_—DIVe >>I 2. The strongest acid among the following compounds is @CHEHCOOH ©) CH,-FH-COOH (6) GHH.COOH —(&) cHLEHCOOH No, a 3. The order of acidity of following acids is. Br | CH, -CF,-COOH CH; -CH-COOH a ocr ‘CF; -COOH b Br I i Mi Vv ()I>U>U> IV B)IV>M> >t ©) IV>1> > @)IV>M>1> 0 4. Which one ofthe following carboxylic acid is the strongest (A) o-methyl benzoic acid (©) m-methyl benzoic acid (C) p-methyl benzoic acid (©) Benzoic acid 5. Increasing value of dissociation constant K, ofthe following is (O)-c00n (Cocoee (yom o (ay SNO: am“ icici @uciH> i B)l>tvet>l — ]l>lvenl>m — O)ive> toatl PNResonence. PaperThe correct decreasing order of acid strength of following compounds is COOH COOH COOH OH OH. OH ®t (oy n> >t eyim> mst Oye tot COOH COOH COOH OOH Me 8 Me Me o ay ay ay Pha. 4.17 31 427 437 Mark True and False statements related to the variation of pka values given for the compounds mentioned. above. S, : Me is electron releasing group but (Il) is more acidic than (I) due to SIR. SS, :(V) is weaker acid than (III) due to + hyperconjugation effect in (IV). S,: Only 41 effect of Me is observed in (II, , : The conjugate base of (IV) is less stable than that of (). TTT (TFT (FTFT ()FFTT CooH COOH 9. j | COOH cH, i 00H 1 0 Ka,= 540010" Ka,= 140 10 The reason for higher Ka, value of oxalic acid (I) as compared to that of malonic acid (II) is (A) The anion formed after the removal of first H® of oxalic acid (1) is more stable due to stronger—I effect of -COOH present at close distance (8) The anion formed after the removal of first H° of oxalic acid (I) is less stable due to +1 effect of COOH group. (©) The anion formed on removal of first H° of malonic acid is more stable than that of oxalic acid due to =Meffect of other -COOH group. (0) Oxalic acid is more acidic than malonic acid due to its lesser molecular weight. 40. Match the acids with their K, values. Column4| (Acids) Columndil(k, values) (A) Benzoic acid (p) 10.3 x 10° (@) p-Toluic acid (3.3% 10" (©) p-methoxy benzoic acid (96.4% 10" (D) p-chlorobenzoic acid (s) 4.2« 10% DNSss0020¢§ — —# —_aggermgORGANIC CHEMISTRY Total Marks : 24 D P P DPP No. 9 Max. Time : 26 min. id and Basic Strength ‘Type of Questions M.M., Min. Single choice Objective ('-1" negative marking) Q.1 to Q.6 (3 marks, 3 min.) (18, 18) Subjective Questions ('-1' negative marking) Q.7 to Q.8 (4 marks, 5 min.) [8, 10) OH OH OH OH NO, 4 NO, No, 1 1 1 Vv Pka. 9.98 7.23 8.40 TAS Mark True and False statements related to the variation in pKa values given for the compounds mentioned above S, Ill is more acid than I due to-I effect of-NO, group eto H-bonding in its slightly lees acidic than IV. ue to presences of -M effect II & IV are more acidic than that of III. jesomeric effect of -NO, group is not operative in casei of I TTT (8) TFTF (©) FTFT () FFTT The correct decreasing order of acid strength of following compounds is OH OH H H, NO, 0 Uy iy (I> > 1 (I> >I ©yu> m1 @Oi>i>u Arrange basicity of the given compounds in decreasing order () CH.=CH.-NH, (i) CH_=CH-NH, (ii) CH=C-NH, i> iil (B)i> ii> (i> ii>i Opuru>t Which of the following reaction is possible ? @l \\+Kor ff \+H0 ° ° Il eee erence d d I I ONa ‘OH oy +CH,COOH ——> © + CH,COONa Resonsnce Escatng or beter tomorow PaaeEse