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POWER POINT PRESENTATION
ON
B. Injection Grouts
Polymer Grouts
Gas Forming Grouts
Sulpho-Aluminate Grouts
C. Bonding Materials
Polymer Emulsion Type
Polymer Resin Type
D. Resurfacing Materials
E. Sealing Materials
F. Water Proofing Materials
CONCRETE REPAIR CHEMICALS:
EPOXIES
Epoxies belong to the epoxy group of organic chemicals. In case of
epoxies, the polymerization process takes place when two materials
Epoxy Resin
Curing Agent
Come in contact by thoroughly mixing in specified proportions.
EPOXY RESIN:
Epoxy resins are the substances of low viscosity and can be
injected into small cracks too. The higher viscosity can be used for
surface coating or filling of large cracks or holes.
EPOXY RESIN AND
HARDENER
PROPERTIES OF EPOXY
Good Mechanical Strength
Good Chemical Resistance
Good Workability
High Tensile Strength
Dis-Advantages of accelerators
1. The excess use of accelerators may lead to drying shrinkage and swelling.
2. The excess use may result into flash set of concrete.
3. The excess use of accelerators containing chloride result into corrosion of
concrete.
4. The excess use of admixtures reduce the resistance of concrete against
ADMIXTURE: RETARDERS
Retarders are added to the concrete to slow down the process
of hydration of cement to delay or prolong the setting of cement in
concrete. Retarders keep the concrete workable for a longer period.
Purpose of Retarders:
To overcome the accelerating effect of high temperature on setting
properties of concrete in hot weather concreting.
To delay setting. of cement. when concrete 15 to he placed in t
conditions.
When concrete is required to be transported for a long distance.
In grouting oil wells, where at a depth of about ()0le meter
temperature may be about 200°C and cement grout is required to be
in mobile condition for about 3 to 4 hours.
RETARDER
Commonly used retarders are:
Calcium sulphate (Gypsum).
Starches.
Sugars.
Cellulose products.
Acids or salts of acids like lingo, sulphonic acid, hydroxylated
carboxylic acid, mucic acid calcium acetate, tannic acid.
Calcium sulphate in the form of gypsum is generally added
during the manufacture of cement to retard the setting. Normally 2 to
3% gypsum is used. Calcium sulphate in the form of plaster of Paris
can also be used. Addition of excess amount of gypsum may cause
undesirable expansion and indefinite delay in the setting of concrete.
At normal temperature, 0.2% addition of sugar can delay the
final setting time to about 72 hours or more.
ADMIXTURE: PLASTICIZER
Workability is an important property of concrete. The optimum workability of
fresh concrete varies from situation to situation. A high degree of workability is
required in situations like deep beams, this walls with congested reinforcement. beam
column Junctions, tremie concreting, hot weather concreting, pumping of concrete etc.
The conventional methods adopted to obtain high workability are use of higher
percentage of fine aggregate, using good grading of aggregates, or by increasing
cement content. Sometimes, unengineered contractors use extra water to improve
workability of concrete.
Use of plasticizers for improving workability without using excess of water is
becoming popular practice all over the world.Calcium, sodium and ammonium lingo-
sulphonates are the most commonly mad plasticizers. They are used in the amount of
0.1% to 0.4% by weight of cement.
The action of plasticizers is to fluidify the mix and to improve the workability
of mix. Portland cement will have a tendency to flocculate in wet concrete. These
flocculation entraps certain amount of water used in the mix. When plasticizers are
added, they get absorbed on the cement particles. The absorption of charged polymer
PLASTICIZER
SUPER PLASTICIZER
Japan was the first country to develop super—plasticizers in 1960 and
subsequently Germany in 1970. The use of Super-plasticizers permit the reduction of
water to the extent of 30 percent without reducing workability of the mix. They are
also called high range water reducers. They are chemically different from the normal
plasticizers. They are more powerful as dispersing agents.
Advantages of using Super—plasticizers :
Very high workability can be achieved. Hence, self levelling, self-compacting,
flowing concrete can be produced.
For the same workability, it has made possible to use w/c ratio as W 0.28 to obtain
strength of the order of 100 MPa.,
With low w/c ratio, it also permits a reduction of cement content.
The use of Super—plasticizers has made it possible to use fly ash. 513% “n silica
fume to make high performance concrete.
The Super—plasticizers produce a homogeneous, cohesive concrete general without
ADMIXTURE: WATER PROOFING
The leakage of roofs, bathrooms, toilets, walls, kitchens, water
tanks,basements etc. is still a headache for civil engineers. There are
various materials and methods available in our country for
waterproofing purposes. But most of them fail due to one or the other
reasons. The success of waterproofing depends upon the quality of
materials durability of materials, workmanship, environment etc.
A waterproof concrete has to fulfil two separate and distinct functions:
To be impervious to the water under pressure.
To resist the absorption of water.
Waterproofing admixtures amy be obtained in powder, paste or
liquid form. There are two types of materials available namely, pore
filling and water repellent materials.
The Pore filling materials are chemically active pore fillers. In
addition they also accelerate the setting time of concrete. Examples of
pore filling materials are silicate of soda, aluminium and zinc
WATER-PROOFING
The water repelling materials are soda, potash soaps, calcium
soaps vegetable oils, Waxes, fats and coal tar residues. Butyl stearate,
heavy mineral oil free from fatty or Vegetable oil may also be used as
waterproofing materials.
The chemical available for waterproofing concrete structures are :
Integral waterproofing compounds
Acrylic based polymer coatings.
Mineral based polymer coatings.
Silicon based water repellent materials.
Waterproofing adhesives for marble, granite and tiles.
EXPANSIVE CEMENT
Concrete shrinks while setting due to loss of free water. This is
known as drying shrinkage. The important property of expansive
cement is that it suffers no overall change in volume on drying. Such
type of cement is used by adding an expansive compound known as
Sulpho-aluminate in the form of clinker at the time of grounding
cement clinkers. Generally 8-20 parts of clinkers of Sulpho-aluminate
are added to 100 parts of Portland cement and 15 parts of the
stabilizer.
There are two types of Expansive Cement:
Shrinkage compensating cement
Self stressing cement
Uses of Expansive Cement
are:
PROCEDURE-B
In procedure ‘B’, the dried concrete specimen is placed in an
airtight container and subjected to vacuum pressure of 2 mm
mercury for two hours. After removing the vacuum, the specimens
are soaked in the molten Sulphur for half an hour. The specimens are
removed, wiped clean of Sulphur and cooled at room temperature.
APPLICATION
The commonly used glass fibers are E-Glass fibers and AR-Glass fibers. Glass
fibers are made from 2000 to 4000 filaments which are lightly bonded to make up a
strand. These strands can be chopped or combined to make cloth or mate.
PLASTIC FIBER REINFORCED
CONCRETE
Plastic fiber reinforced concrete uses plastic fibers such as
nylon, polypropylene, polyethylene to increase the tensile strength of
concrete. The nylon and polypropylene and nylon fibers are found to
increase the impact strength of concrete and thus reduce the tendency
of cracking and their propagation. Generally 0.25-1% of fibers by
volume are added to concrete.
CARBON FIBER REINFORCED
CONCRETE
Carbon fibers possess high tensile strength and high youngs
modulus. The modulus of rupture of an aligned carbon reinforced
concrete cement composite with 8% fiber volume can be as high as
1623 N/mm2.
ASBESTOS FIBER
REINFORCED CONCRETE
Asbestos is a mineral fiber and has proved to be the most successful
fiber, which can be mixed with OPC. The minimum length of asbestos
is 10cm. The asbestos fiber reinforced concrete has high flexural
strength. Tensile strength of asbestos fiber is 500-980 N/mm2
CORROSION PROTECTION OF
REINFORCEMENT
Methods used are:
Use of corrosion resistant steel
Coating to reinforcement
Cathodic protection
Hot dip galvanizing
Electrochemical chloride removal
Improving the cover to reinforcement
USE OF CORROSION RESISTANT
STEEL
Stainless steel is the name given to a family of corrosion
resistant steels containing a minimum of 12% chromium. On contact
with air, the chromium forms a thin oxide layer on the surface of
steel. This layer is inert and resists corrosion.
The use of corrosion resistant steel is done where humidity is
more and where the concrete is subjected to chemical attacks.
COATING TO REINFORCEMENT:
CEMENT SLURRY
The purpose of coating of steel bar is to provide a sufficiently durable
barrier to aggressive materials such as chloride.
This method was developed by CECRI, Karaikudi, Tamilnadu. It
consists of application of two coats of cement slurry to rebars.
The entire process of coating is :
De—rusting : Removal of rust, dirt and oil from steel surface.
Phosphating : Phosphatization of steel surface by phosphating jelly offers
temporary protection during time lag between de—rusting and application of
first coat of inhibited cement slurry.
Cement slurry : Two coats of cement slurry made by OPC cement and
inhibitor solution to protect steel surface from the attack of sulphate and
chloride ions and to keep the steel surface in high pH environment. (
Sealing : Two coats of sealing solution to increase the adhesion between
steel and cement coating and to seal the surface. Sealing coat is applied
after each application of slurry coat.
COATING TO REINFORCEMENT:
EPOXY COATING
The Fusion Bonded Epoxy Coating (FBEC) is a process where epoxy powder is
applied by electrostatic spray on hot steel at pre-set temperature level The powder,
when in contact with the hot bar, melts, flows, gels, cures, cools and produces a well
adhered continuous corrosion resistant protective coating. The coating thickness
typically varies from 130 micron to 300 micron
Advantages :
As the technique is factory based, it gives uniform thickness and better quality
control.
It has excellent adhesive property.
The coating is flexible not broken due to bending of bars during fabrication.
Disadvantages:
There is reduction in bond strength between coated rebars and concrete.
Patching may not always be effective.
Even the smallest damage in coating can initiate corrosion in severe environment.
EPOXY COATED BARS
CORROSION INHIBITORS
A corrosion inhibitor is defined as a chemical substance that
reduces the corrosion of metals without a reduction in the
concentration of corrosion agents, i.e. chlorides.
Corrosion inhibitors work by reducing the rate of the anodic
and/or Cathodic reactions thereby Suppressing the overall corrosion
rate.
The examples of corrosion inhibiters are
The addition of calcium nitrate extends the time of corrosion
initiation, and also reduces the rate of corrosion once started.
Organic corrosion inhibitors such as amino-alcohols are believed to
suppress corrosion by primarily being absorbed on to the steel
surface thereby displacing corrosive ions such as chlorides.
CATHODIC PROTECTION
Cathodic protection is a technique by which the electrical
potential of the steel is decreased to level at which corrosion cannot
take place. It is widely used for concrete offshore structure and steel
structures, while on land it has been used for the protection of
pipelines.
Two methods are used:
Impressed current method
Sacrificial anode system
CATHODIC PROTECTION:
IMPRESSED CURRENT
The Cathodic protection comprises of application of impressed
current from an external power source to an electrode laid on the
concrete above steel reinforcement. This electrode serves as anode
and the steel reinforcement which is connected to the negative
terminal of a DC source acts as a cathode. In this process the external
anode is subjected to corrosion and the Cathodic reinforcement is
protected against corrosion and hence the name ‘Cathodic Protection’
.
In this process the negative chloride ions which are responsible
for the damage to “it passivating layer are drawn away from the
vicinity of steel towards the anode where they are oxidized to form
chlorine gas. The environment around the steel reinforcement reverts
back to alkaline condition which protects the steel.
CATHODIC PROTECTION:
SACRIFICIAL ANODE
In this system the reinforcement is connected to anodes with a
more negative corrosion potential than steel, such as zinc and
aluminium. The external anode corrodes preferentially to the steel and
supplies electrons to the Cathodic steel surface. Sacrificial anode
system are more effective in submerged structures where the concrete
is wet and resistivity is low. Warm temperature i.e. above 20˚C is
generally required for this system.
DRY PACK
TECHNIQUE
In this technique , dry cement sand mix in proportion of 1:2.5 is
used and sufficient amount of water is added to it so as to form a
ball by hand. The ball should neither slump nor crumble.
DRY PACK PROCESS
Before actual operation the hole should be thoroughly cleaned and ensured
free from broken pieces of aggregates, washed and dried.
A thin layer of cement grout is applied on the surface. The mix for bonding
grout is the mixture of cement and fine sand in ratio of 1:1 to a consistency
like thick cream.
After this, the dry pack material is put into place before the bonding grout
has dried up. Packing material consists of the volume or by weight a mix of 1
part of cement to 2.5 parts of sand.
Water requirement for mix is such as to produce a mortar which, when
used, will stick together on being molded into a ball, and will not exude
water but will leave the hands damp. If less water is added, it will not make
sound solid pack. If more water is added excessive shrinkage will occur and
the material becomes loose.
Dry pack material is not to be filled at a time, but should be filled in
layers and properly compacted having compacted thickness of about
1 cm.
Each layer is scratched & finished to secure bond for succeeding
layer and is compacted over its entire surface by use of hardwood
stick and hammer. The size of such stick is about 20 to 30 cm in
length and not over 2.5 cm in diameter. Wooden sticks will not polish
the surface of each layer and thus better bonding surface is formed.
Last layer is finished to match the surroundings.
For better results and when water tightness is a requisite, the holes
should be sharp and square at the surface edges, but corners within
holes should be rounded. Holes for dry pack should have a minimum
depth of 2.5 cm
VACUUM CONCRETE
Higher water-cement ratio is damaging for concrete. We always try to
restrict the water-cement ratio in order to achieve higher strength. the
adopted water-cement ratio is much more than that mainly because of the
requirement of workability. Workability is also important for concrete, so it
can be placed in the formwork easily without honeycombing.
After the requirement of workability is over, this excess water will
eventually evaporate leaving capillary pores in the concrete. These pores
result into high permeability and less strength in the concrete. Therefore,
workability and high strength don’t go together as their requirements are
contradictory to each other.
Vacuum concrete is the effective technique used to overcome this
contradiction of opposite requirements of workability and high strength.
In this technique, the excess water after placement and compaction of
concrete is sucked out with the help of vacuum pumps. This technique
is effectively used in industrial floors, parking lots and deck slabs of
bridges etc. The magnitude of applied vacuum is usually about 0.08 MPa
and the water content is reduced by up to 20-25%. The reduction is effective
COMPONENTS REQUIRED FOR
VACUUM CONCRETING
Mainly, four components are required in vacuum dewatering of
concrete, which are given below:
Vacuum pump
Water separator
Filtering pad
Screed board vibrator
Vacuum Pump: Vacuum pump is a small but strong pump of 5 to 10
HP.
Water Extractor: Water is extracted by vacuum and stored in the
water separator.
Filtering Pad: Filtering pad consists of rigid backing sheet, expanded
metal, wire gauge or muslin cloth sheet. A rubber seal is also fitted
around the filtering pad. Filtering pad should have minimum
dimension of 90cm x 60cm. The mats are placed over fine filter pads,
which prevent the removal of cement with water.
Screed Board Vibrator: To force the excess water to get collected at
the top.
Effect of Vacuum
Concreting
ADVANTAGES OF VACUUM CONCRETING