Volumen (L/mol) Presión (atm) a 300K Presión (atm) a 400K Presión (atm) a 500K

0.05 246.3522 880.5363 1514.7203

0.07 -97.9608 151.0522 400.0653
0.09 -46.4081 108.5135 263.4351
0.11 -4.8803 107.5562 219.9928
0.13 19.7154 107.9538 196.1923
0.15 33.8118 106.4232 179.0345
0.17 41.7899 103.4765 165.1631
0.19 46.1626 99.7819 153.4012
0.21 48.3652 95.7832 143.2013
0.23 49.2371 91.7395 134.2420

Gas a (Bar*L^2/mol^2) b (L/mol)

Amoniaco (NH3) 4.225 0.03707

Ejemplo de Cálculo

(𝑃+𝑎/(𝑣  ̂^2  ))(𝑣  ̂−𝑏)=𝑅�

P=𝑅�/((𝑣  ̂−𝑏) )
−𝑎/(𝑣  ̂^2  )

P=(0,082 (𝑎𝑡𝑚∗𝐿)/(𝐾∗𝑚𝑜𝑙)∗300𝐾)/
((0,05𝐿/𝑚𝑜𝑙−0,03707𝐿/𝑚𝑜𝑙) )−(4,1405 (𝑎𝑡𝑚∗𝐿^2)/ 〖𝑚𝑜𝑙〗
^(2 ) )/(0,05 𝐿^2/ 〖𝑚𝑜𝑙〗 ^2   )=246,3522𝑎𝑡𝑚
 Isotermas de Van der Waals para el Amoniaco
300K 400K 500K
1800
1600
1400
1200
1000
P(atm)

800
600
400
200
0
0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2 0.22 0.24
-200

V(L/mol)

plo de Cálculo

4,225 𝐵𝑎𝑟∗(0,98 𝑎𝑡𝑚)/(1 𝐵𝑎𝑟)=4,1405 𝑎𝑡𝑚

(𝑎𝑡𝑚∗𝐿^2)/ 〖𝑚𝑜𝑙〗
2𝑎𝑡𝑚
2 0.24
Volumen (L/mol) Presión (atm) a 500K Z
0.08 537.7321 1.0485938856
0.13 257.2255 0.8150959118
0.18 187.8688 0.824287158
0.23 151.0969 0.8470999926
0.28 127.0442 0.8670905365
0.33 109.7957 0.8831828756
0.38 96.7415 0.8960818499
0.43 86.4907 0.9065449986
0.48 78.2176 0.9151602411
0.53 71.3957 0.922358044
0.58 65.6720 0.9284519073
0.63 60.7999 0.9336724476
0.68 56.6019 0.9381918222
0.73 52.9470 0.9421405752
0.78 49.7359 0.9456192129
0.83 46.8924 0.9487062263
0.88 44.3566 0.951463725
0.93 42.0811 0.9539414521
0.98 40.0278 0.9561796888

Volumen (L/mol) Presión (atm) a 2000K Z

0.2 953.2306 1.1617679131
0.25 734.0198 1.1182507992
0.3 597.7914 1.09285457
0.35 504.6313 1.0763007224
0.4 436.7894 1.0646906973
0.45 385.1292 1.0561129314
0.5 344.4539 1.0495242453
0.55 311.5837 1.0443086424
0.6 284.4618 1.0400796427
0.65 261.6973 1.0365828177
0.7 242.3157 1.0336439908
0.75 225.6134 1.0311399932
0.8 211.0698 1.0289813125
0.85 198.2910 1.0271013593
0.9 186.9736 1.0254495867
0.95 176.8803 1.0239869439
1 167.8222 1.0226827902
1.05 159.6478 1.0215127505
1.1 152.2337 1.0204571948
 1.15 145.4782 1.0195001386
1.2 139.2974 1.0186284358
1.25 133.6209 1.0178311763
1.3 128.3892 1.0170992304
1.35 123.5521 1.0164249007
1.4 119.0665 1.0158016519
1.45 114.8953 1.0152239
1.5 111.0067 1.0146868449
1.55 107.3729 1.0141863384
1.6 103.9695 1.0137187768
1.65 100.7754 1.0132810146

Volumen (L/mol) Presión (atm) a 300K Z

0.062 338.9659 1.1016564542
0.112 68.6891 0.362769803
0.162 69.4073 0.5075490455
0.212 65.4454 0.6115145858
0.262 59.9002 0.6813753811
0.312 54.4934 0.7305634528
0.362 49.6726 0.7668331671
0.412 45.4864 0.7946035818
0.462 41.8720 0.816517041
0.512 38.7447 0.8342351339
0.562 36.0249 0.8488500986
0.612 33.6447 0.8611075503
0.662 31.5482 0.871533069
0.712 29.6900 0.8805074141
0.762 28.0331 0.8883130025
0.812 26.5475 0.8951636332
0.862 25.2087 0.9012240786
0.912 23.9963 0.9066233432
0.962 22.8936 0.9114638498
1.4

1.2

0.8

0.6

0.4

0.2

0
0.0000 200.0000 400.0000 600.0000 800.0000 1000.0000 1200.0000
1000.0000 1200.0000