Narayana IIT Academy

INDIA
Sec: Jr.IIT-IZ-CO-SPARK Date: 16-05-15
Time: 3Hrs Max.Marks: 360
IMPORTANT INSTRUCTIONS:
1. Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Point Pen. Use of
pencil is strictly prohibited.
2. The test is of 3 hours duration.
3. The Test Booklet consists of 90 questions. The maximum marks are 360.
4. There are three parts in the question paper A, B, C consisting of Physics,Chemistry and Mathematics having 30
questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct response.
5. Candidates will be awarded marks as stated above in instruction No. 4 for correct response of each question.
(1/4) (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from
the total score will be made if no response is indicated for an item in the answer sheet.
6. There is only one correct response for each question. Filling up more than one response in any question
will be treated as wrong response and marks for wrong response will be deducted accordingly as per
instruction 5 above
PHYSICS
  
1. If C  A B, then
   
1) C is always less than A 2) C may be greater than A
     
3) C is always greater than AB 4) C can never be equal to AB
 
2. If A and B are two vectors each of magnitude 5 units. If they are inclined with the x–
axis at angles of 30o and 90o respectively, their resultant will be
5 3 ˆ 5ˆ 5 3 ˆ 5ˆ 5 3 ˆ 15 ˆ 5ˆ 5 3 
1) i j 2) i j 3) i j 4) i 

 5  ˆj

2 2 2 2 2 2 2  2 

3. Magnitude of y–component of vector OA is
A y

5
o
60
O x

5 5 5 3 5
1) 2) 3) 4)
2 2 2 3

4. An room has length and width as 4m and 3m and is 5m high. If an insect flies from a
bottom corner of the room to the diagonally opposite corner on the top of the room, then
taking the bottom corner as origin and length as x–axis, width as y–axis and vertical
height as z–axis, the displacement vector of the insect will be
1) 5 ˆi  4 ˆj  3kˆ 2) 5 ˆi  4 ˆj  5kˆ 3) 4 ˆi  5 ˆj  3kˆ 4) 4 ˆi  3 ˆj  5kˆ
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5. Two vector have magnitude of 4 unit and 6 unit. If their resultant has a magnitude of 8
units, then angle between the two vectors is
 1 3  2
1) 60 o 2) cos1   3) cos1   4) cos1  
4 4 3

6. A man walks 4 km eastwards, then turns leftwards and walks 1 km and then makes a
right turn and runs 2 km and then stops. The displacement of the man will be
 1
1) 37 km at tan1   north of east 2) 6 km at north–east direction
6

 1  1
3) 37 km at tan 1   east of north 4) 37 km at tan1   north of east
3 2
   
7. Two vectors a and b are a  2 ˆi  ˆj  3k and b  ˆi  2ˆj  3k . The angle between the two vectors
will be
 5   5   4   2 
1) cos1   2) cos 1   3) cos1   4) cos 1  
 28   14   35   5 
 
8. If a  2 ˆi  4 ˆj, and b  K ˆi  6 ˆj are two vectors which are perpendicular to each other, then
value of K is
1) 8 2) –12 3) 24 4) –18
   
9. If a  4 ˆi  3ˆj, and b  5 ˆi  2ˆj then the magnitude of component of a along b will be
26 14 26 26
1) 2) 3) 4)
5 5 29 5 29
 
10. A vector A is pointing vertically downwards and B is pointing towards north. The cross
 
product A  B is
1) along east 2) along west
3) zero 4)vertically upwards

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11. A body of mass 10kg is suspended by a rope and it is pulled to a side by means of a
horizontal force so that the rope makes an angle of 600 with the vertical where the body
is at equilibrium. The horizontal force is.
1) 100 3 N 2) 10 3 N 3) 1000 3 N 4) 3 N
     
12. If a  4 ˆi  5ˆj and b  2 ˆi  3ˆj c  7kˆ then c  (a  b) will be
1) 2iˆ  ˆj  kˆ 2) 3iˆ  ˆj  5kˆ 3) zero 4) 5iˆ  2 ˆj  3kˆ

13. If two of the adjacent sides of a parallelogram are represented by vectors a  2 ˆi  3ˆj  kˆ


and b  ˆi  2ˆj  4kˆ . The area of the parallelogram will be

1) 392 2) 278 3) 92 4) 184

 
14. If two of the adjacent sides of a triangle are represented by vectors a  2i  ˆj and b  i  2ˆj .

Then area of triangle will be

1) 5 units 2) 25 units 3) 1.5 units 4) 9 units

  
15. Two vectors A and B lie in a plane, a third vector C lies outside this plane, then the
  
sum of these vectors A  B C :

1) can be zero 2) Can never be zero

   
3) Lies in a plane containing AB 4) Lies in a plane containing A  B

16. Resultant of which of the following may be zero?

1) 10N, 10 N, 30N 2) 10N, 20N, 30N, 40N

3) 5N, 10N, 20N, 60N 4) All of these

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17. A vector having magnitude 30 unit makes equal angles with each of X- ,Y- & Z- axes.
The components of vector along each of X-,Y-,& Z- axes are
1) 103 unit 2) 303 unit 3) 153 unit 4) 203 unit
  
18. The resultant of three vectors OA, OB, OC as shown in the figure is …. If the radius of the
circle is R
C
B
45
45
O A

R
1) R (1  2 ) 2) (1  2) 3) 2R 4) (1  2 )R
2
4 3
19. The resultant of the three vectors shown in the figure is …. (If cos 37  , sin 37  )
5 5

2m
5m 3m
37

1) 6.8m 2) 7.5m 3) 8.6m 4) 9.2m

20. F1, 10N and 10N are in equilibrium. F2, 20N and 10N are in equilibrium. The resultant
of F1 and F2 is ….. When they are acting at angle 1200.

20N
10N
1200
1200
10N
10N

F2
F1

1) 10( 4  5 )N 2) 10( 5  3 )N 3) 10( 4  3 )N 4) None of these

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  
21. The vector A = 2 i + 3 j and the sum A + B is 4m long directed at 120o to the +x axis in

the xy plane. What is B ?
1) 3i  (2 3  4) j 2) 4i  (2 3  3) j 3) 2i  (2 3  3) j 4) 2i  (4 3  3) j

22. A force F = (4 î  5 ĵ + 3 k̂ )N is acting at a point having a position vector

r1 =( î +2 ˆj + 3 k̂ ). The torque acting about a point having a position vector
   
r2 = (3 î  2 ˆj  3 k̂ ), is (if   r x F )

1) 42 î + 30 ˆj  6 k̂ 2) 42 î + 30 ˆj + 6 k̂ 3) 42 î  30 ˆj + 6 k̂ 4) zero
     
23. Given that A + B + C =0. Out of three vectors A , B and C two are equal in magnitude and
the magnitude of the third vector is 2 times that of either vector having equal
magnitudes. Then the angle between the vectors is
1) 30, 60, 90 2) 45, 45, 90 3) 45, 60, 90 4)90, 135, 135
24. A Vector perpendicular to the vector (i  2 j ) and having magnitude 3 5 units is

1) 3i  6 j 2) 6i  3 j 3) 4i  2 j 4) i  2 j

25. The vector sum of N coplanar forces, each of magnitude F, when each force is making

an angle of 2/N with the preceding one is

  
1) NF 2) NF 2 3) F2 4) zero
    
26. Angle between P and Q is . What is the value of 
P. Q  P ?

1) P2Q cos  2) zero 3) P2Q sin  cos  4) P2Q sin 

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   
27. If a1 and a2 are two non collinear unit vectors and if a1  a2  3 , then the value of
   
(a1  a2 )(2a1  a2 ) is

1) 2 2) 3/2 3) 1/2 4) 1
28. The sum of magnitudes of two forces acting at a point is 16N. If their resultant is normal
to the smaller force and has a magnitude of 8 N. Then the forces are
1) 6 N, 10 N 2) 8 N, 8 N 3) 4 N, 12 N 4) 2 N, 14 N
  
29. The angle between two vectors A and B is . Vector R is the resultant of the two
  
vectors. If R makes an angle with A then
2
B
(1) A  2 B (2) A  (3) A = B (4) AB = 1
2
30. Minimum number of forces having equal magnitudes, which can give a resultant zero, is
1) 2 2) 4 3) 3 4) 1
CHEMISTRY
31. Correct set of four quantum numbers for the outermost electron of Rubidium (Z = 37) is

1) 5, 0, 0, + 1/2 2) 5, 1, 0, + 1/2 3) 5, 1, 1, + 1/2 4) 6, 0, 0, + ½

32. The number of radial nodes present in 3p orbital is

1) 0 2) 1 3) 2 4) 3
33. Choose the correct options :
1) Number of electrons having magnetic quantum number equal to zero are 11 in Fe3+
2) Orbital angular momentum of 2p- and 3p orbitals is the same
3) Sum of radial and angular nodes in 4d – orbital is 2
4) Both A & B

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34. Assertion (A) : The angular nodes of a particular orbital is given by azimuthal quantum
number
Reason (R) : The angular nodes for p - orbital and d - orbitals are one and two
respectively.
The correct answer is
1) (A) is not true but (R) is true 2) (A) is true but (R) is not true
3) Both (A) and (R) are true and (R) is the correct explanation of (A).
4) Both (A) and (R) are true and (R) is not the correct explanation of (A)
35. The electron density of Px orbital in yz plane is
1) 95% 2) 50% 3) 33.33% 4) zero
36. The radial probability curve drawn here represents the orbital

RP

1) 3s 2) 3 p 3) 3d 4) 4g
37. Consider the following plots for 2s-orbital :

(1) (2) (3)

x,y and z are respectively.
1) R, R 2 and 4r 2 R 2 2) R2, R and 4p r 2 R 2 3) 4p r 2 R 2 and R2, R 4) R2, 4p r 2 R 2 and R

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38. If n and l are principal and azimuthal quantum numbers respectively, then the expression
for calculating the total number of electrons in any energy level is:
l n l n n l  n 1
1)  2  2  1
l 0
2)  2  2  1
l 1
3)   2  1
 0
4)  2  2l  1
l 0

39. The quantum numbers +1/2 and -1/2 for the electron spin represent
1) rotation of the electron in clockwise and anticlockwise direction respectively
2) rotation of the electron in anticlockwise and clockwise direction respectively
3) magnetic moment of the electron pointing up and down respectively
4) two quantum mechanical spin states which have no classical analogue
40. The Schrodinger wave equation for hydrogen atom is
3/2
1  1  r0  r0 /a0
 2s    2  e
4 2  a0   a0 

Where a0 is Bohr’s radius. If the radial node in 2s be at r0, then

1) r0 = 2a0 2) r0 = 4a0 3) 2r0 = a0 4) r0 = a0
41. The ground state energy in J, of hydrogen atom is –X. The minimum energy in J,
required to promote an electron from n = 1 to n = 2 in He+ is
4X 3X X
1) 2) 3) 4) 3X
3 4 3
5R 3R 21R 1
42. Hydrogen spectrum gave a series of lines at , and cm
36 16 100

(R=Rydberg constant in cm-1). These lines belong to

1) Balmer series 2) Lyman series 3) Pfund series 4) Paschen series

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43. The temperature of a sample of gas is raised from 127 o C at 527 o C . The fraction of gas

escaped is

1 1 3 1
1) 2) 3) 4)
4 2 4 3

44. The radiation with maximum frequency is

1) X-rays 2) Radio waves 3) UV rays 4) IR rays
45. The volume of 1 mole gas measured at STP is
1) 22.4 lit 2) 11.2 lit 3) 22.7 lit 4) 11.4 lit
46. The orbital with maximum no. of spacial orientations is

1) S 2) d 3) f 4) p

47. The angular wave function of orbital depends on quantum numbers

1) n 2) l 3) ml 4) ms

48. The correct Schrodinger’s wave equation for electron with E as total energy and V as
potential is

 2   2   2  8 m  2   2   2  8 2
1) 2  2  2  2  E  V    0 2) 2  2  2  2  E  V    0
x y z h x y z mh

 2   2   2  8 2 m  2   2   2  8 m2
3)   2  2  E V    0 4)     E V    0
x 2 y 2 z h x 2 y 2 z 2 h

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49.
List – A List – B
An orbital can have maximum two
i) a) Heisenber’s uncertainty
electrons with opposite spins
Orbitals are filled in order of increasing Pauli’s exclusion
ii) b)
energy principle
Degenerate orbitals are first singly
iii) c) Aufbau principle
occupied

iv) It is impossible to determine

simultaneously the exact position and d) Hund’s rule
velocity of a microscopic particle

1) i–b, ii–a, iii–d, iv–c 2) i–b, ii–d, iii–c, iv–a

3) i–b, ii – c, iii – d, iv – a 4) i – a, ii – c, iii – d, iv – b
50. What is the orbit angular momentum and orbital angular momentum

2) ( ) , l (l +1) 3) ( ) , l ( l +1)
nh h n +1 h h n- 1 h h n2 h h
1) , l (l +1) 4) , l ( l +1)
2p 2p 2p 2p 2p 2p 2p 2p
51. Suppose a particle has four quantum numbers such that permitted values are n : 1, 2, 3
1 1
………. l : (n – 1), (n – 3), (n – 5) ……….. but no negative number j :  l   or  l   ,
2 2
   
the latter is not negative m : - j in integral steps to + j. What are other permitted values
for n = 1
l j m l j m
1 1 1 1 1 1
1) 0  , 2) 1  ,
2 2 2 2 2 2
1 1 1 1 1 1
3) 2  , 4) 0 -  ,
2 2 2 2 2 2
52. Hund’s rule deals with the distribution of electrons in :
1) a quantum shell 2) an orbit 3) an orbital 4) Degenerate orbitals

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53. The radial distribution curve of 2s sublevel consists of ‘x’ nodes, ‘x’ is
1) 1 2) 3 3) 2 4) 0
54. Match List – I with List – II and select the correct answer

List – I
(‘l’ and ‘m’ are respectively the azimuthal List – II
and magnetic quantum numbers)
Number of values of (l) for an energy
A 1 0, 1, 2 …….. (n – 1)
level

+l, ……… +2, +1, 0, -

B Actual values of (l) for an energy level 2
1, -2, ……… -l

Number of ‘m’ values for a particular

C 3 (2l + 1)
type of subshel
Actual values of ‘m’ for a particular
D 4 n
type of orbital

A B C D A B C D
1) 4 1 2 3 2) 4 1 3 2
3) 1 4 2 3 4) 1 4 3 2
55. Which of the following radial distribution graphs correspond to n=3, l= 2 for the H
atom

1) 2)

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3) 4)
56. The wave function for a hydrogen atom with its electron in the 2p state varies with
directions as well as distance from the nucleus. What is the probability of a 2p electron
for which ml  0 existing in xy plane

1) 0 2) 1 3) 2a0 4) a0

57. The orbital angular momentum for s-electron is

h h h
1) 2) 2 3) 4) zero
2 2 2
58. The number of electrons with the azimuthal quantum number l  1 and l  2 in ground
state of 24 Cr is respectively
1) 16 and 5 2) 12 and 5 3) 16 and 4 4) 12 and 4
59. The number of radial nodes of 3s and 2p orbitals are respectively
1) 2, 0 2) 0, 2 3) 1, 2 4) 2, 1
60. Which of the following sets of quantum numbers represent the highest energy of an
atom?
1 1
1) n  3 l  1 m 1 s   2) n  3 l  2 m 1 s  
2 2
1 1
3) n  4 l  0 m0 s 4) n  3 l  0 m0 s
2 2

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MATHEMATICS
61. If the roots of ax 2  bx  c  0 and px 2  qx  r  0 differ by the same quantity, then
b 2  4ac

q 2  4 pr
2 2 2 2
p c a p
1)   2)   3)   4)  
a    p p  c
 

62. If one root of the equation ax 2  bx  c  0 is equal to the nth power of the other, then
1/ n 1 1/ n 1
a cn
  ac n  b

1) 0 2) 1 3) -1 4) 2
63. If  and  ,     , are the roots of the equation x 2  bx  c  0 , where c<0<b, then
1) 0     2)   0     3)     0 4)   0    
64. The value of ‘a’ for which one root of the quadratic equation
a 2
 5a  3 x 2   3a  1 x  2  0 is twice as large as other is

1) -2/3 2) 1/3 3)-1/3 4) 2/3

65. If ,  are the roots of 4x 2  16x  c  0, c  0 such that 1    2    3, then the

number of integral values of c is

1) 2 2) 3 3) 4 4) 5

66. The equation e sin x  e  sin x  4  0 has

1) Infinite number of real roots 2) no real roots

3) Exactly one real roots 4) exactly four real roots

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2 2
67. If the equations ax  2bx  3c  0 and 3 x  8 x  15  0 have a common root where a,b,c are

the length of the sides of ABC then sin 2 A  sin 2 B  sin 2 C is equal to

3
1) 1 2) 3) 2 4) 2
2

68. If x satisfies x  1  x  2  x  3  6 then

1) 0  x  4 2) x  2  or  x  4 3) x  0 or  x  3 4) R

69. The least value of expression x 2  4 y 2  9 z 2  2 x  8 y  27 z  15 is

41
1) 15 2) 5 3) 0 4)
4

1
70. If y  2  then
1
4
1
4
4  ....

1) y=6 2) y=5 3) y  6 4) y  5
x2  2 x  4 1
71. Given that, for all real x, the expression 2
lies between and 3. The values
x  2x  4 3

9.32 x  6.3x  4
between which the expression lies are
9.32 x  6.3x  4
1) 1/3 and 3 2) -2 and 0 3) -1 and 1 4) 0 and 2

1 1
72. If  ,  are roots of 6 x 2  6 x  1  0 then
2
 a  b  c 2  d 3    a  b  c  2  d  3  
2

1) a+b+c+d 2) a+2b+3c+4d 3) a+(b/2)+(c/3)+(d/4) 4) 0

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73. Let f  x   x  2bx  2c and g  x    x  2cx  b then min  f  x   max g  x  holds for
2 2 2 2

1) 0  c  b 2 2) c  b 2

3) c  b 2 4) no real value of b and c

74. If a and b are distinct positive real numbers such that a , a1 , a2 , a3 , a4 , a5 , b are in A.P
; a, b1 , b2 , b3 , b4 , b5 , b are in GP; and a, c1 , c2 , c3 , c4 , c5 , b are in HP; Then the roots of
a3 x 2  b3 x  c3  0 are

1) real and distinct 2) real and equal 3) Non-real complex 4) rational

x 1 
75. The equation 2 cos 2 sin 2 x  x 2  2
, 0  x  has
2 x 2
1) one real solution 2) no real solution
3) More than on real solution 4) two real solution
76. For a  0 , the roots of the equation x 2  2a x  a  3a 2  0 are………….

1) 1  2  a,  1  6  a 2) 1  2  a,  1  6  a

3) 1  2  a,  1  6  a 4) 1  2  a,  1  6  a

77. If xy=2(x+y), x  y and x, y  N , then number of solutions of the equation

1) two 2) three
3) no solution 4) infinite many solution
78. If x, y, z are real such that x+y+z=4, x 2  y 2  z 2  6, then x 
2
1) (-1, 1) 2) [0, 2] 3) [2, 3] 4)  , 2
3 

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  
79. If  ,  are the roots of x 2  px  q  0 and x 2 n  p n x n  q  0    and if   ,   are the
    
n
roots of xn  1   x  1  0,  n  N  then ‘n’
1) must be an odd integer 2) may be an even integer
3) must be an even integer 4) cannot say anything

80. Let  ,  be the roots of the equation x 2  px  r  0 and , 2  be the roots of the
2
equation x 2  qx  r  0 . Then, the value of r is
2 2
1)  p  q  2q  p  2)  q  p  2 p  q 
9 9
2 2
3)  q  2 p  2 q  p  4)  2 p  q  2q  p 
9 9
81. If the equations x 2  2 x  3  0 and ax 2  bx  c  0 , a, b, c R , have a common root then
a:b:c is
1) 1:2:3 2) 3:2:1 3) 1:3:2 4) 3:1:2
82. Let f  x   x 2   x   cos x,  is positive integer  is a real number. The number of

ordered pairs   ,   for which f(x)=0 and f(f(x))=0 have same set of real roots.
1) 0 2) 1 3) 2 4) 3
k 1 k2
If the roots of ax 2  bx  c  0 a  0 are then a  b  c  
2
83. and
k k 1
1) b2  4ac 2) b2  2ac 3) 2b2  ac 4) b2  ac
84. Consider f  x   90 x 2  20 x  1 then sum of digits of f 111111 is
1) 11 2)12 3) 13 4) 14

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x 1
85. If  and  are real and distinct roots of x 2  1  satisfy  2   2  then belongs to
a a

1 1 1   1   1   1 
1)  , 0  U  0,  2)  , 0  U  0,  3)  , 0  U  0,  4) none
 2   2  2   5  5   5

86. If a, b, c are three distinct positive real numbers then the real roots of ax 2  2b x  c  0 is
1) 0 2) 4 3) 2 4) None of these
87. If roots of x 2   a  3  x  a  0 are such that at least one of them is greater than 2, then

1) a   7, 9  2) a   7,   3) a  9,   4) a  (7,9)

88. Total number of integral values of ‘ a ’ so that x 2   a  1 x  a  1  0 has integral roots is

equal to
1) 1 2) 2 3) 4 4) None of these
89. If the equation x2  bx  c  k , where b, c, k  R has four real roots, then

b2  4c 4c  b 2
1) b 2  4c  0 and 0  k  2) b 2  4c  0 and 0  k 
4 4
4c  b 2 4c  b 2
3) b 2  4c  0 and k  4) b 2  4c  0, k 
4 4

90. If the roots of a 2  b2  x 2  2 bc  ad  x  c2  d 2  0 are equal, then

a b a b
1) a  c 2)  0 3)  4) a  b  c  d
b d c d d c

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