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XIIP IIT LJ(MAINS MODEL) Exam Date:01-10-2016
Time:3:00 Max Marks: 360
INSTRUCTIONS :
1) There are 3 sections in this paper, consisting Physics, Chemistry, Mathematics. There will be
objective type questions with four options having single correct answer. For each correct
answer 4 marks awarded. For each incorrect response one fourth (1/4) of the total marks
allotted to the question would be deducted. No deduction from the total score will, however, be
made if no response is indicated for an item in the answer sheet. The candidates are advised not
to attempt such item in the answer sheet if they are not sure of the correct response. More than
one answer indicated against a question will be deemed as incorrect response and will be
negatively marked. All objective type questions are required to be answered on OMR sheet
provided with the question paper.
PHYSICS
1. A marble going at a speed of 2 ms–1 hits another marble of equal mass at rest. If the
collision is perfectly elastic, then the velocity of the first marble after collision is
(1) 4 ms–1 (2) 0 ms–1 (3) 2 ms–1 (4) 3 ms–1
2. A body of mass m moving at a constant velocity v hits another body of the same mass
moving with a velocity v/2 but in the opposite direction and sticks to it. The common
velocity after collision is
(1) v (2) v/4 (3) 2v (4) v/s
3. An 8 gm bullet is fired horizontally into a 9 kg block of wood and sticks in it. The block
which is free to move, has a velocity of 40 cm/s after impact. The initial velocity of the
bullet is
(1) 450 m/s (2) 450 cm/s (3) 220 m/s (4) 220 cm/s
4. A ball is dropped onto a horizontal floor. It reaches a height of 144 cm on the first bounce
and 81 cm on the second bounce. The coefficient of restitution is
(1) 0 (2) 0.75 (3) 81/144 (4) 1
5. A stationary body explodes into two fragments of masses m1 and m2. If momentum of one
fragment is p, the energy of explosion is
p2 p2 p 2 m1 m 2 p2
(1) (2) (3) (4)
2 m1 m 2 2 m1m 2 2m1m 2 2 m1 m 2
6. A railway truck of mass 16000 kg moving with a velocity of 5 ms–1 strikes another truck of
mass 4000 kg at rest. If they move together after impact, their common velocity is
(1) 2 ms–1 (2) 4 ms–1 (3) 6 ms–1 (4) 8 ms–1
7. A particle falls from a height ‘h’ upon a fixed horizontal plane and rebounds. If ‘e’ is the
coefficient of restitution, then the total distance travelled before it comes to rest is
1 e2 1 e2 h 1 e2 h 1 e2
(1) h 2
(2) h 2
(3) (4)
1 e 1 e 2 1 e2 2 1 e2
8. Three identical particles moving with velocities v 0 ˆi, 3v0 ˆj and 5v 0 kˆ collide successively
with each other in such a way that they form a single particle. The velocity of resultant
particle in i, j, k form is
v v v
(1) v 0 ˆi 3jˆ 5kˆ
(2) 0 ˆi 3jˆ 5kˆ
3
(3) 0 ˆi 3jˆ 5kˆ
2
(4) 0 ˆi 3jˆ 5kˆ
3
9. In two separate collisions, the coefficient of restitutions e1 and e2 are in the ratio 3 : 1. In the
first collision the relative velocity of approach is twice the relative velocity of separation.
Then, the ratio between relative velocity of approach and relative velocity of separation in
the second collision is
(1) 1 : 6 (2) 2 : 3 (3) 3 : 2 (4) 6 : 1
10. A sphere of mass m moving with constant velocity u, collides with another stationary
sphere of same mass. If e is the coefficient of restitution, the ratio of the final velocities of
the first and second sphere is
1 e 1 e e 1 e
(1) (2) (3) (4)
1 e 1 e 1 e e
11. A ball of mass ‘m’ moving with a horizontal velocity ‘v’ strikes the bob of mass ‘m’ of a
pendulum at rest. During this collision, the ball sticks with the bob of the pendulum. The
height to which the combined mass raises is (g = acceleration due to gravity)
v2 v2 v2 v2
(1) (2) (3) (4)
4g 8g g 2g
12. A 3 kg sphere makes an inelastic collision with another sphere at rest and they stick after
th
1
the collision. If the composite mass moves with a speed of of the initial speed of 3 kg
4
sphere, the mass of second sphere is
(1) 12 kg (2) 9 kg (3) 6 kg (4) 3 kg
13. A moving sphere P collides another sphere Q at rest. If the collision takes place along the
line joining their centres of mass such that their total kinetic energy is conserved and the
8
fraction of K.E. transferred by the colliding particle is , then the mass of P and the mass
9
of Q bears a ratio
(1) 8 : 3 (2) 9 : 8 (3) 2 : 3 (4) 2 : 1
14. Two spheres A and B of equal masses lie on the smooth horizontal circular groove at
opposite ends of diameter and at the end of time ‘t’, ‘A’ impinges on ‘B’. If ‘e’ is the
coefficient of restitution, the second impinge will occur after a time
2t t t t
(1) (2) (3) (4)
e e e e
15. A sphere A of mass m moving with certain velocity hits another stationary sphere B of
V 1 e
different mass. If the ratio of velocities of the spheres after collision is A , where e
VB 1 e
is coefficient of restitution. The initial velocity of sphere A with which it strikes is
CHEMISTRY
31. When molecules of type A react with molecules of type B in one-step process to given AB2,
the rate law is
(1) rate = K[A]1 [B]2 (2) rate = K[A]2[B]1 (3) rate = K[2A] [B] (4) rate = K[A] [B]
32. The units of rate of reaction and rate constant are identical for a
(1) fraction-order reaction (2) zero-order reaction
(3) first-order reaction (4) second-order reaction
33. The decomposition of H2O2 is represented as
H2O2 H2O + O(slow)
(O) + (O) O2 (fast)
Then the order of the reaction is
(1) 1 (2) 2 (3) 0 (4) 3
34. For the reaction A B the rate law is, rate = K[A]. Which of the following statement is
incorrect?
(1) The reaction follows first order kinetics
(2) The t 1 of reaction depends upon initial concentration of reactants
2
(3) K is constant for the reaction at a constant temperature
(4) The rate law provides a simple way of predicting the concentration of reactants and
products at any time after the start of the reaction
35. The time for half change for a zero order reaction is ………..
(1) proportional to the initial concentration
(2) proportional to the square root of the initial concentration
(3) independent of initial concentration
(4) inversely proportional to the initial conc.
36. Which of the following statements regarding molecularity of the reaction is correct?
(1) Molecularity relates to mechanism of reaction
(2) It cannot be negative or fractional
(3) Molecularity of a complex reaction has two (or) more steps and each individual step has
its own molecularity.
(4) All are correct
37. The rate of gaseous reaction is given by K[A] [B]. If the volume of reaction vessel is
1
reduced to of initial volume the reaction rate relative to the original rate is
4
1 1
(1) (2) (3) 8 (4) 16
16 8
38. For the reaction 4NH3 5O2 4NO 6H 2 O, the rate of reaction with respect to NH3 is
2 103 Ms1. Then the rate of the reaction with respect to oxygen in Ms–1
(1) 2 103 (2) 103 (3) 103 (4) 103
39. The rate of formation of SO3 in the reaction 2SO2 + O2 2SO3 is 100 g min–1. Hence rate
of disappearance of O2 is
(1) 50 g min–1 (2) 100 g min–1 (3) 20 g min–1 (4) 40 g min–1
40. The rate of a certain reaction at different times is as follows
Time 0 10 20 30
2 2 2
Rate 10 10 10 102
The order of the reaction is
(1) 1 (2) zero (3) 2 (4) 3
41. Which of the following relation is correct for a first order reaction?
(K = rate constant; r = rate of reaction ; c = conc. of reactant)
c r
(1) K = r × c2 (2) K = r × c (3) K (4) K
r c
42. If the rate of reaction A B triples on increasing the concentration of A by 9 times, then
the order of reaction is
(1) 2 (2) 1 (3) 1/2 (4) 4
43. The initial rates for gaseous reaction A + 3B AB3 are given below
[A] (M) [B](M) Rate(M sec–1)
0.1 0.1 0.002
0.2 0.1 0.002
0.3 0.2 0.008
0.4 0.3 0.018
order of the reaction is
(1) zero (2) three (3) one (4) two
44. Half life of a zero order reaction is 250 sec. t 75%, t100% of the reaction respectively in sec. are
(1) 500, 375 (2) 375, 500 (3) 300, 575 (4) 575, 300
45. In the equilibrium A + B C + D, the activation energy for forward reaction is 25 k.
cal/mole and that of backward reaction is 15 k. cal/mole. Which one of the following
statement is correct
(1) It is an exothermic process (2) It is an endothermic process
(3) It is reaction for which H = 0 (4) It is a sublimation process
46. For a reversible reaction A B, which one of the following statements is wrong from the
given energy profile diagram
E
A
Reaction coordinate
(1) Activation energy of forward reaction is greater than backward reaction
(2) The forward reaction is endothermic
(3) The threshould energy is less than that of activation energy
(4) The energy of activation of forward reaction is equal to the sum of heat of reaction and
the energy of activation of backward reaction.
1
47. For a chemical reaction Y2 2Z Product, rate controlling step is Y Z Q. If then
2
the concentration of Z is doubled, the rate of reaction will
(1) Remain the same (2) Become four times
(3) Become 1.414 times (4) Become double
48. Observe the following reaction 2A + B C. The rate of formation of C is
d A
2.2 × 10–3 mol L–1 min–1. What is the value of (in mol L–1 min–1)?
dt
(1) 2.2 × 10–3 (2) 1.1 × 10–3 (3) 4.4 × 10–3 (4) 5.5 × 10–3
49. 2A + B D + E for this reaction proposed mechanism A + B C + D(slow), A + C
E(fast). The rate law expression for the reaction is
2 2
(1) r K A B (2) r K A B (3) r K A (4) r K A C
50. For a reaction A + 2B products, when B is taken in excess, then the rate law expression
can be written as
(1) Rate = K[A]1[B]0 (2) Rate = K[A]1[B]2 (3) Rate = K[A][B] (4) Rate =K[A]2[B]1
51. The unit of rate constant obeying the rate expression r = K[A]1[B]2/3 is
(1) mole–2/3 lit2/3time–1 (2) mole2/3 lit–2/3 time–1
–2/3 –2/3 –1
(3) mole lit time (4) mole2/3 lit2/3 time–1
52. For the reaction A + B products, it is found that order of A is 1 and order of B is ½.
When concentrations of both A & B are increased four times the rate will increase by a
factor
(1) 6 (2) 8 (3) 4 (4) 16
53. The product of half life (t1/2) and the square of initial concentration of the reactant (a) is
constant. Then the order of reaction is
(1) 2 (2) 3 (3) 0 (4) 1
54. 50% completion of a first order reaction takes place in 16 minutes, then the fraction that
would react in 32 minutes from the beginning
(1) 1/2 (2) 1/4 (3) 1/8 (4) 3/4
55. 75% of a first order process is completed in 30 min. The time required for 93.75%
completion of same process (in hr)?
(1) 1 (2) 120 (3) 2 (4) 0.25
56. The rate of the reaction CH3COOC2H5 + NaOH CH3COONa + C2H5OH is given as rate
= K[CH3COOC2H5] [NaOH]. If three times water is added to the reaction mixture, the rate
of the reaction compared to the original rate will be
1 1 1
(1) rd (2) th (3) th (4) 16 times
3 9 16
57. If doubling the concentration of the reactant A increases the rate by 4 times and tripling the
concentration of A increases the rate by 9 times, the rate is proportional to
(1) concentration of A (2) square of concentration of A
(3) under root of conc. of A (4) cube of concentration of A
58. Give the following data for the reaction:
X+YZ
[X] [Y] Rate × 10–1 ms–1
1.0 M 1.0 M 0.25
2.0 M 1.0 M 0.50
1.0 M 2.0 M 0.25
1.0 M 3.0 M 0.25
Which one is the rate law equation ?
(1) Rate = K[X][Y] (2) Rate = K [X]0[Y]1 (3) Rate = K[X][Y]0 (4) Rate = K[X][Y]2
59. For the reaction system: 2NO(g) + O2(g) 2NO2(g) volume is suddenly reduced to half of its
value by increasing the pressure on it. If the reaction is of first order with respect to O2 and
second order with respect to NO, the rate of reaction will
(1) diminish to one-eight of its initial value (2) increase to eight times of its initial value
(3) increase to four times of its initial value (4) diminish to one fourth of its initial value
60. For N 2O5 2NO2 1/ 2O 2 , it is found that
d d d
N 2O5 K1 N2 O5 , NO2 K 2 N2O5 ; O2 K3 N 2O5 then
dt dt dt
(1) K1 = 2K2 = 3K3 (2) 2K1 = 4K2 = K3 (3) 2K1 = K2 = 4K3 (4) K1 = K2 = K3
MATHEMATICS
1
61. If the points (a, 1), (2, –1) and , 2 are collinear, then a is equal to
2
1
(1) 1 (2) 0 (3) 2 (4)
4
62. If Points A(x1, y1), B(x2, y2) and C(x3, y3) are such that x1, x2, x3 and y1, y2, y3 are in A.P.,
then
(1) A, B and C are concylic points (2) A, B and C are collinear points
(3) A, B and C are vertices of an equilateral triangle
(4) none of the above
63. If Points A(x1, y1), B(x2, y2) and C (x3, y3) are such that x1, x2, x3 and y1, y2, y3 are in G.P.
with same common ratio, then
(1) A, B and C are concylic points (2) A, B and C are collinear points
(3) A, B and C are vertices of an equilateral triangle
(4) none of the above
64. If 3a + 4b + c = 0, then the lines ax + by + c = 0 always passing through:
(1) (3, 4) (2) (4, 3) (3) (3, 3) (4) none of these
65. Set of lines (x – 2y + 1) + (x + y) = 0 (where is a parameter) passing through a fixed
point:
1 1
(1) , (2) , (3) 1,1 (4) none of these
3 3 3 3
66. The equation of line equidistant from the lines 2x + 3y + 5 = 0 and 4x + 6y = 11 is :
(1) 2x + 3y – 1 = 0 (2) 4x + 6y – 1 = 0 (3) 8x + 12 y – 1 = 0 (4) none of these
67. A ray of light along x 3y 3 gets reflected upon reaching x-axis, the equation of
reflected ray is :
(1) y = x + 1 (2) 3y x 3 (3) y 3x 3 (4) none of these
68. If orthocenter and circumcentre of triangle are respectively (1, 1) and (3, 2) then the co-
ordinates of its centroid are :
7 5 5 7
(1) , (2) , (3) (7, 5) (4) none of these
3 3 3 3
69. The angle bisector of two intersecting lines L1 = 0 and L2 = 0
(1) are always perpendicular (2) are at 60o
(3) are perpendicular if L1 = 0 and L2 = 0 are perpendicular
(4) make equal angle as is the angle between L1 = and L2 = 0
70. Obtuse angled bisector of lines 3x + 4y = 5 and 5x + 12y = 5 is
(1) 37x + 56y = 45 (2) 7x + 4y = 20 (3) 7x – 4y = 20 (4) 37x + 56y = 49
71. If a point P(4, 3) is rotated through an angle 45 o in anticlockwise direction about origin,
then co-ordinates of P in new position are
1 7 7 1 1 7 1 7
(1) , (2) , (3) , (4) ,
2 2 2 2 2 2 2 2
72. If a point P(4, 3) is shifted by a distance 2 units parallel to the line y = x, then co-
ordiantes of P in new position are:
(1) (5, 4) (2) (5 + 2 , 4 + 2 ) (3) (5 – 2 , 4 – 2 ) (4) none of these
73. The orthocenter of a triangle formed by the lines 2x + y = 2, x – 2y = 1 and x + y = 1 is
1 2 2 1
(1) , (2) (0, 1) (3) , (4) (1, 0)
3 3 3 3
74. The point (4, 1) undergoes the following three transformations successively
(i) reflection about the line y = x.
(ii) translation through a distance 2 units along the positive direction of x-axis.
(iii) rotation through an angle about the origin the anticlockwise direction.
4
(iv) The final position of the point is given by the co-ordinates.
1 7 1 7
(1)
2 2
,
(2) 2, 7 2 (3)
,
2 2
(4) 2, 7 2
75. Line L has intercepts a and b on the co-ordinate axes. When the axes are rotated through a
given angle keeping the origin fixed, the same line has intercepts p and q then :
1 1 1 1 1 1 1 1
(1) a2 + b2 = p2 + q2 (2) 2 2 2 2 (3) a 2 p 2 b 2 q 2 (4) 2 2 2 2
a b p q a p b q
76. P, Q R and S are the points on line joining the points P(a, x) and T(b, y) such that PQ = QR
5a 3b 5x 3y
= RS = ST, then , is the mid-point of :
8 8
(1) PQ (2) QR (3) RS (4) ST
77. The incentre of the triangle formed by lines x = 0, y = 0 and 3x + 4y = 12 is at:
1 1 1 1
(1) , (2) (1, 1) (3) 1, (4) ,1
2 2 2 2
78. Circumcentre of triangle whose vertices are (0, 0), (3, 0) and (0, 4) is :
3 3
(1) , 2 (2) 2, (3) (0, 0) (4) none of these
2 2
79. If origin is shifted to (7, –4), then point (4, 5) shifted to
(1) (–3, 9) (2) (3, 9) (3) (11, 1) (4) none of these
3 3 2 2
80. If the line y 3x cuts the curve x + y + 3xy + 5x + 3y + 4x + 5y – 1 = 0 at the points
A, B, C then OA. OB. OC is, (O is origin)
4 2
(1)
13
3 3 1 (2) 3 3 1 (3)
3
7 (4) none of these
81. If p and p ' be the perpendicular from the origin upon the straight lines
x sec + y cosec = a and x cos – y sin = a cos 2, then 4p2 + p '2 is equal to :
1 1
(1) a 2 (2) a 2 (3) a2 (4) none of these
2 4
x y
82. The incentre of the triangle formed by the axes and the line 1 is
a b
a b ab ab
(1) , (2) ,
2 2 a b ab a b ab
a b ab ab
(3) , (4) ,
3 3 2 2
a b a b a b a b
2 2
83. If a straight line passes through (x1, y1) and its segment between the axes is bisected at this
point, then its equation is given by:
x y
(1) 2 (2) 2 xy1 x1 y x 1 y1
x1 y1
(3) xy1 yx1 x1y1 (4) none of these
84. Equation of a line which passes through the point (–3, 8) and cut off positive intercepts on
the axes whose sum is 7 is
(1) 3x – 4y = 12 (2) 4x + 3y = 12 (3) 3x + 4y = 12 (4) 4x – 3y = 12
85. If the line (x – y + 1) + k(y – 2x + 4) = 0 makes equal intercept on the axes then the value of
k is
(1) 1/3 (2) 3/4 (3) 1/2 (4) 2/3
2
86. The distance between the parallel lines given by x 7y 4 2 x 7y 42 0 is
(1) 1 (2) 5 (3) 6 (4) 2
87. For all values of ‘a’ the set of straight lines (3a + 1) x – (2a + 3)y + 9 – a = 0 passes through
the point
(1) (3, 4) (2) (4, 2) (3) (3, 3) (4) (1, 2)
88. If 2x + 3y + 4 = 0 & x + ky + 2 = 0 are identical lines then 3 – 2k =
(1) 1 (2) 0 (3) –1 (4) 2
89. The distance between the parallel lines 8x + 6y + 5 = 0 and 4x + 3y – 25 = 0 is
(1) 7/2 (2) 9/2 (3) 11/2 (4) 5/4
90. If the point of intersection of kx + 4y + 2 = 0, x – 3y + 5 = 0 line on 2x + 7y – 3 = 0 then k
=
(1) 2 (2) 3 (3) –2 (4) –3