TUGAS

TERSTRUKTUR 5

Mata Kuliah : TEKNOLOGI MINYAK BUMI

Dosen : MUHAMMAD HANIF, S.T., M.T.

Disusun Oleh
RIDWAN SANTOSO
NPM. 1415041053

JURUSAN TEKNIK KIMIA FAKULTAS TEKNIK

UNIVERSITAS LAMPUNG
2018
Soal
1. Calculate the number of barrels of n-butane that have to be added to a mixture
of 1250 barrels of HSR gasoline,750 barrels of LSR gasoline, and 620 barrels of
𝐶5+ FCC gasoline to produce a 9 psi RVP. What are the RON and MON of the
blend?
Component Barrels RVP (psi) RON MON Olefin (%) Aromatics (%)
HSR gasoline 1250 1 62.3 58.7 0 7
LSR gasoline 750 11.11 66.4 61.6 0 5
𝐶5+ FCC 620 13.1 91 80.7 30.6 33.1
n-Butane X 51.5 93 92 0 0

Penyelesaian :

Mencari nilai BIRVPi = 𝑅𝑉𝑃𝑖1,25

Sehingga di peroleh data tabel berikut ini,

Component RVP (psi) BIRVPi
HSR gasoline 1 1
LSR gasoline 11.11 20.28348
𝐶5+ FCC 13.1 24.92236
n-Butane 51.5 137.9619

Setelah itu menentukan nilai dari barrels n-butane

121,25 (1250 + 750 +620 + X) – (1250)(1) – (750)( 20.28348) – (620)( 24.92236)

– (X)( 137.9619) = 0

121,25 (2620 + X ) – (1250) – (15212.61) – (15451.86) – 137,9619X = 0

58516.43 + 22.33X – 1250 – 15212,61 – 15451,86 – 137,9619X = 0

26601,96 = 115,6319X
26601.96
X = 115.6319 , X = 230 Barrels

Sekarang menghitung nilai dari Xvi dengan rumus berikut ini

𝑛𝑖𝑙𝑎𝑖 𝑠𝑎𝑡𝑢 𝑘𝑜𝑚𝑝𝑜𝑛𝑒𝑛
𝑗𝑢𝑚𝑙𝑎ℎ 𝑘𝑒𝑠𝑒𝑙𝑢𝑟𝑢ℎ𝑎𝑛 𝑛𝑖𝑙𝑎𝑖 𝑘𝑜𝑚𝑝𝑜𝑛𝑒𝑛
Component Barrels Xvi
HSR gasoline 1250 0.438596
LSR gasoline 750 0.263158
𝐶5+ FCC 620 0.217544
n-Butane 230 0.087786
 ̅ , 𝑆̅, ̅̅̅̅
Setelah itu didapatlah nilai dari 𝑅̅ , 𝑀 𝑅𝑆, ̅̅̅̅ ̅̅̅2 , ̅̅̅̅
𝑀𝑆, 𝐴̅, 𝑂̅, 𝐴 𝑂2
Component 𝑅̅ ̅
𝑀 𝑆̅ ̅̅̅̅
𝑅𝑆 ̅̅̅̅
𝑀𝑆 𝐴̅
HSR gasoline 27.32456 25.74561 1.578947 43.14404 40.65097 0
LSR gasoline 17.47368 16.21053 1.263158 22.07202 20.47645 0
𝐶5+ FCC 19.79649 17.55579 2.240702 44.35803 39.33729 6.656842
n-Butane 8.164122 8.076336 0.087786 0.716698 0.708991 0
Total 72.75886 67.58827 5.170593 110.2908 101.1737 6.656842

𝑂̅ ̅𝐴̅̅2̅ ̅̅̅̅
𝑂2
3.070175 0 9.425977
1.315789 0 1.731302
7.200702 44.31355 51.85011
0 0 0
11.58667 44.31355 63.00738

Dari persamaan 9.22 dan 9.23 diperoleh RON blend dan MON blend
̅̅̅̅2 - 𝑂̅ 2 )
̅̅̅̅ - 𝑅̅ x 𝑆̅ ) + 0,00085 (𝑂
RONblend = 𝑅̅ + 0.03324 (𝑅𝑆

= 72.75886+ 0.03324 (110.2908 - 67.58827 x 5.170593) + 0,00085

(63.00738 − 11.586672 )

= 63.85927
̅̅̅̅ 2
̅̅̅̅2 - 𝑂̅2 ) - (𝐴 − 𝐴̅ )
2
̅̅̅̅ - 𝑅̅x𝑆̅) + 0.00066 (𝑂
̅ + 0.04285 (𝑀𝑆
MONblend = 𝑀 100

= 67.58827 + 0,04285 (101.1737 - 72.75886 x 5.170593) + 0.00066

2
44.31355− 6.6568422
(63.00738 − 11.586672 ) - ( )
100

= 56.90169
Soal
2. A blend is performed for LSR gasoline, hydrocracker gasoline, FCC gasoline and
n-butane. Calculate the amount of each component that must be added to
produce gasoline blend of maximum octane number and 10 psi RVP using the
Linear Programming (LP) technique. The properties of each cut are shown in
the table below. The olefin contents in each cut can be assumed to be zero. The
maximum blend storage capacity is 10000 barrels.

Component Barrels RVP (psi) RON MON

LSR gasoline X1 12.1 91 81
Hydrocracker gasoline X2 15.5 89.5 85.5
FCC gasoline X3 4.8 97 96
n-Butane X4 51.6 93 92
Blend X5 10 Max

Penyelesaian :
̅̅̅̅ - 𝑅̅ x 𝑆̅ )……………………………………………………………………….. 1
RONblend =(𝑅̅ + 0.03324 (𝑅𝑆

𝑿 𝑿 𝑿 𝑿
𝑅̅ = 𝟏 (91) + 𝟐 (89,5) + 𝟑 (97) + 𝟑 (93)
𝑿𝑻 𝑿𝑻 𝑿𝑻 𝑿𝑻

𝑋1 𝑋2 𝑋3 𝑋4
𝑆̅ = (91-81) + (89.5-85.5) + (97-96) + (93-92)
𝑋𝑇 𝑋𝑇 𝑋𝑇 𝑋𝑇

𝑿𝟏 𝑿𝟐 𝑿𝟑 𝑿𝟒
= (10) + (4) + +
𝑿𝑻 𝑿𝑻 𝑿𝑻 𝑿𝑻

̅̅̅̅ = 𝑋1 91(91-81) +
𝑅𝑆
𝑋2
89,5(89.5-85.5) +
𝑋3
97(97-96) +
𝑋4
93(93-92)
𝑋 𝑇 𝑋𝑇 𝑋𝑇 𝑋𝑇

𝑿 𝑿𝟐 𝑿𝟑 𝑿𝟒
= 𝑿𝟏 (910) + 𝑿𝑻
(358) + 𝑿𝑻
(97)+ 𝑿𝑻
(93)
𝑻

Dimana,
X1 ≥ 0, X2 ≥ 0, X3 ≥ 0, dan X4 ≥ 0…………………………………………………………………………. 2

Sehingga diperoleh,
X1 + X2 + X3 + X4 < 10000 barrels………………………………………………………………………… 3

Component Barrels RVP (psi) BIrvp

LSR gasoline X1 12.1 22.5674097
Hydrocracker gasoline X2 15.5 30.7549215
FCC gasoline X3 4.8 7.10479492
n-Butane X4 51.6 138.296799
Blend X5 10 17.7827941
Didapatlah,
22.56 X1 + 30.75 X2 + 7,10 X3 + 138,3 X4 + 17.78 X5 = 0………………………………………………… 4

Dari persamaan 2,3, dan 4 diperolehlah persamaan berikut

22.56 X1 + 30.75 X2 + 7,10 X3 + 138,3 X4 + 17.78 X5 = 10000………………………………………… 5