Regioselective Chemisorption: A Breakthrough Research in the Field of

Materials Science by Tomokazu from Oasis Publishers

New York, NY, December 29, 2018 --(PR.com)-- Tomokazu Kiyonaga's research paper is titled, “
Regioselective chemisorption-induced separate deposition of two types of metal nanoparticles on TiO2.”

A current topic in the field of catalysis is the discovery that gold, dispersed as nanoparticles on
metal-oxide supports, such as TiO2, exhibits high thermal and visible photo-catalytic activities, even
though it is inactive in the bulk state. It was also observed that recently the separate deposition of Au NPs
and other metal NPs on TiO2 was developed. The separate deposition were achieved by the colloid
photo-deposition with a hole scavenger (CPH) method using TiO2 photocatalysis, and this was done so as
an effective method to enhance the visible photocatalysis of Au nanoparticles. Furthemore, Au and Pd
nanoparticles have been separately deposited to develop highly active and selective thermal catalysts
based on a hydrogen spillover. Thus, it is becoming clear that the separate deposition of metal
nanoparticles is important for the development of new photocatalysts and thermal catalysts.

Tomokazu gained his inspiration that there may be limited to the kinds of support that can be used.
Additionally, there were little known about the mechanism of separate deposition in these cases.

The objective of his research was to report a new method, which would involve the chemisorption and the
subsequent NaBH4 reduction of Au(III) complex ions on TiO2-Pt (TiO2-Pt: Pt nanoparticles deposited
TiO2).

The deposition states of the nanoparticles were observed by transmission electron microscopy (TEM). Au
and Pt nanoparticles in Au/TiO2-Pt were recognized by the particle size, and the TEM analysis indicated
that 10 nm-Pt nanoparticles and 2.4 nm-Au nanoparticles were individually loaded on the TiO2 surface.

Tomokazu has used X-ray photoelectron spectroscopy (XPS) to provide strong evidence for the separate
deposition of Au and Pt nanoparticles. The XPS analysis results were also consistent with the TEM
results.

Tomokazu has explained the separate deposition of Au and Pt nanoparticles. The adsorption isotherms of
Au (III) complex ions (AuC) in the samples (TiO2, TiO2-Pt and bulk metallic Pt foil) were measured.
Since no adsorption was observed on the surface of the bulk metallic Pt foil, Tomokazu found out that the
result revealed that AuC was regioselectively chemisorbed on the surface of TiO2. On further analysis,
the chemisorption patterns of AuC indicated a mechanism in which Au and Pt nanoparticles were
individually deposited on the surface of TiO2.

Furthermore, Tomokazu also observed that the in situ NaBH4 reductions of the regioselectively
chemisorbed AuC probably led to the separate deposition of Au and Pt nanoparticles.

Thus, the experimental work by Tomokazu established a new method for the separate deposition of the
small Au and Pt nanoparticles on TiO2. Additionally, the mechanism of the separate deposition was

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clarified. The regioselective chemisorption of Au (III) complex ions, which were present on the surface of
TiO2 enabled Au and Pt nanoparticles to be deposited separately.

There are great expectations from this method. It may be useful for specifying the locations at which the
small Au nanoparticles and various other metal nanoparticles are deposited.

On the other hand, Tomokazu compared this method with CPH method. It caused the particle size of the
deposited colloid Au nanoparticles to increase or decrease in the CPH method. According to Tomokazu,
this happened due to the TiO2 photocatalyzed dissolution and redeposition of Au nanoparticles.

Tomokazu also noticed that, in contrast to the CPH method, the new method provided small Au
nanoparticles within a narrow size and similar distribution in Au/ TiO2-Pt and Au/TiO2. The fact that the
visible photocatalytic activity of Au nanoparticles increases as the size of these nanoparticles decreases
has been reported. Therefore, the deposition of small Au NPs with a narrow size distribution would
increase the visible photocatalytic activity. Furthermore, the similar distributions of the Au nanoparticles
would be helpful to compare the catalytic activities such as those of Au/TiO2-Pt and Au/TiO2.

Additionally, the application of the chemisorption of AuC to SrTiO3, ZnO, In2O3, Al2O3, and so on, has
been reported. Therefore, Tomokazu concluded that this new method would be helpful in designing the
deposition locations of the small Au nanoparticles and other nanoparticles of various metals such as Pt
nanoparticles on various support materials. It was also seen that this attempt might assist in the
development of Au catalysts.

Tomokazu has mentioned that the future application of regioselective chemisorption to achieve the
separate deposition of metal nanoparticles may aid in the development of new photocatalysts and thermal
catalysts.

Tomokazu's brilliant research has set a precedent in the area of materials science. Many young
researchers can take help of this study and make further advances in this subject area. Tomokazu's
research paper shows his deep interest in this field and his relentless effort in arriving at the desired
conclusion.

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Contact Information:
Oasis Publishers
Tomokazu kiyonaga
+1-646-751-8810
Contact via Email
www.oasispub.org

Online Version of Press Release:

You can read the online version of this press release at: https://www.pr.com/press-release/773224

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