12th – JEE (Warm up test) Chemistry 31.12.

2018
MEEEGS, AKOLA.
Mock Test - 3
31. The structure of the major product formed in the 38. p-cresol reacts with chloroform in alkaline
following reaction is medium to give the compound A which adds
hydrogen cyanide to form the compound B. The
latter, on acidic hydrolysis gives chiral carboxylic
acid. The structure of the carboxylic acid is

(1) (2) (1) (2)

(3) (4) (3) (4)

32. Trans-2-phenyl-1-bromocyclopenta ne on
39. In which of the following ionisation processes, the
reaction with alcoholic KOH produces
bond order has increased and the magnetic
(1) 4-phenylyclclopentene
behaviour has changed?
(2) 2-phenylcyclopentene
(1) C2 C2+ (2) NONO+
(3) 1-phenylcyclopentene
(3) O2O2+ (4) N2N2+
(4) 3- phenylcyclopentene
40. Which of the following reactions represent a
33. Which one of the following is an amphoteric
heterogeneous equilibrium?
oxide?
(1) H 2(g)+I2(g) ⇌ 2HI9(g)
(1) ZnO (2) Na2O (3) SO2 (4) B2O3
(2)CaCO3(s) ⇌ CaO(s) + CO2(g)
34. The substance not likely to contain CaCO3, is
(3) N2O4(g) ⇌ 2NO2(g)
(1) A marble statue (2) Calcined gypsum
(4) 2O3(g)n ⇌ 3O2(g)
(3) Sea Shells (4) Dolomite
1
35. Which one of the following has largest number of 41. H 2 ( g ) O2 ( g )  H 2 O(1)
2
isomers? (R = alkyl group,en = ethylenediamine)
B.E. (H−H) = x1:B.E. (O=O) = x2; B.E. (O−H) = x3
(1) Ru( NH 3 ) 4 Cl2  (2) Co( NH 3 )5 CL2 

Latent heat of vaporization of water liquid into water
(3) Ir ( PR3 ) 2 H (CO) (4) Co(en) 2 Cl2 
2 
vapor = x4’ then Hf (heat of formation of liquid into
36. Which one of the following nitrates will leave water) is
behind a metal on strong heating? x x
(1) x1  2  x3  x4 (2) 2 x3  x1  2 x4
(1) Ferric nitrate (2) Copper nitrate 2 2
(3) Manganese nitrate (4) Silver nitrate x x
(3) x1  2  2 x3  x4 (4) x1 2  2 x3  x4
37. Consider the acidity of the carboxylic acids : 2 2
(i) PhCOOH (ii) o-NO2C6H4COOH 42. In both DNA and RNA, heterocyclic base and
(iii) p-NO2C6H4COOH (iv) m-NO2C6H4COOH phosphate ester linkages are at
Which of the following order is correct ? (1) C’5 and C’1 respectively of the sugar molecule
(1) (i) > (ii) > (iii) > (iv) (2) C’1 and C’5 respectively of the sugar molecule
(2) (ii) > (iv) > (iii) > (i) (3) C’2 and C’5 respectively of the sugar molecule
(3) (ii) > (iv) > (i) > (iii) (4) C’5 and C’2 respectively of the sugar molecule
(4) (ii) > (iii) > (iv) > (i) 43. Insulin production and its action in human body
are responsible for the level of diabetes. This
compound belongs to which of the following
categories?
(1) A coenzyme (2) A hormone
(3) An enzyme (4) An antibiotic
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12th – JEE (Warm up test) Chemistry 31.12.2018
44. The metallic sodium dissolves in liquid ammonia 52. A certain current liberated 0.504g of hydrogen in
to form a deep blue coloured solution. The deep blue 2 h. How many grams of copper can be liberated by
colour is due to the formation of the same current flowing for the same time in CuSO4
(1) Solvated electron e (NH3)x
- solution?
(2) Solvated atomic sodium,Na(NH3)y (1) 12.7 g (2) 15.9 g (3) 31.8 g (4) 63.5 g
53. A plot of log x/m versus log p for the adsorption
(3) (Na+ + Na-) (4) NaNH2 + H 2
of a gas on a solid gives a straight line with slope
45. Which one of the following processes will
equal to
produce hard water? 1
(1) Saturation of water with CaCO3 (1) –log K (2) n (3) (4) log K
n
(2) Saturation of water with MgCO3 54. The order of
(3) Saturation of water with CaSO4 stability of the
(4) Addition of Na2SO4 to water following
46. The half- life of a reaction is halved as the initial carbocation is
concentration of the reactant is doubled. The order of
reaction is (1) II > III > I (2) I > II > III
(1) 0.5 (2) 1 (3) 2 (4) 0 (3) III > I > II (4) III > II > I
47. The boiling point of an aqueous solution of a non- 55. The maximum tolerable limit of degree of
volatile solute is.100.150 C. What is the freezing point hardness in water required for our daily needs is,
approximately,
of an aqueous obtained by diluting the above
(1) 10-15ppm (2) 100-150ppm
solution with an equal volume of water? The values
(3) 103ppm (4) 700-800ppm
of kb and Kf for water 0.5120C kg m-1 and 1.860C kg 56. Find the calorific value of glucose
mol -1 respectively C6H12O6+6O2  6CO2 + 6H2O ; H = - 2900 kJ mol-1
(1) -0.5440C (2) -0.5120C (1) 15.34 kJ g-1 (2) 13.92 kJ g-1
(3) -0.272 C0 (4) -1.86 C0
(3) 18.50 kJ g -1 (4) 16.11 kJ g-1
48. The wave number of first line of Balmer series of 57. Heat of neutralization of oxalic acid is -53.35 kJ
hydrogen atom is 15200 cm . What is the wave
-1 mol-1 using NaOH. Hence H of H2C2O4 ⇌ C2O + 2H + is
number of first line of Balmer series of Li ion?
2+ (1) 5.88 kJ (2) -5.88 kJ (3) -13.7 kcal (4) 7.9 kJ
(1) 15200 cm-1 (2) 6080 cm-1 58. Y g of non-volatile organic substance of
(3) 76000 cm-1 (4) 1,36,800 cm-1 molecular mass M is dissolved in 250g benzene.
Molal elevation constant of benzene is kb. Elevation in
49. The molecular shapes of SF4 , CF4 and XeF4 are
its boiling point is given by
(1) Different with 1,0 and 2 lone pair of electrons on
M 4k Y Kb y Kb y
the central atom, respectively (1) (2) b (3) (4)
K bY M 4M M
(2) Different with 0,1 and 2 lone pair of electrons on
the central atom, respectively 59. The volume of colloidal particle , V c as compared
(3) The same with 1,1 and 1 lone pair of electrons on to the volume of a solute particle in a true solute
particle in a true solution Vs, could be
the central atom, respectively
V V
(4) The same with 2 ,0 and 1 lone pair of electrons on (1) C ≈ 103 (2) C ≈ 10-3
VS VS
the central atom, respectively
50. Equal volumes of 1 M each of KMnO4 and K2Cr2 V V
(3) C ≈ 1023 (4) C ≈ 1
are used to oxidize Fe (II) solution in acidic medium. VS VS
The amount of Fe oxidized will be 60. The disperse phase in colloidal iron (III)
(1) More with KMnO4 hydroxide and colloidal gold is positively and
(2) equal with both oxidizing agents negatively charged , respectively . Which of the
following statement is not correct ?
(3) More with K2 Cr2 O7
(1) Coagulation In both sols can be brought about by
(4) Cannot be determined
electrophoresis
51. Ammonium hydrogen sulphide dissociates (2) Mixing the sols has no effect
according to the equation, (3) Sodium sulphate solution causes coagulation in
NH4HS(s) ⇌ Nh3(g) + H2S(g).If the observed both sols
pressure of the mixture is 1.12 atm at 1060C. what is (4) Magnesium chloride solution coagulates the gold
the kp of the reaction? sol more readily than the iron (III) hydroxide sol
(1) 0.2136 (2) 0.3136 (3) 0.4136 (4) 0.5126
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