Synozol

K-HL dyes
Reactive dyes

Fastness as self shade

Oxidative
Light Washing Water
bleach damage
Dyeing
depth ISO 105-B02 AATCC 16E M&S C10A
ISO 105- AATCC
ISO 105-E01
(1/6 SD) 20AFU C06 C2S 61-2A
Ch Ch Ch Ch/CO Ch/CO Ch/CO

Yellow K-HL 0.67% 5 4-5 4-5 4-5/ 5 4-5 / 5 4-5 / 4-5

Red K-HL 1.00% 4 4 4-5 4-5 / 4 4-5 / 4-5 4-5 / 4-5

Exhaust
Blue K-HL 0.58% 4-5 4-5 4-5 4-5 / 4-5 4-5 / 4-5 4-5 / 4-5
dyeing
Violet K-HL 0.67% 4 4 4 4-5/5 4-5/5 4-5/4-5

Grey K-HL 1.00% 4-5 4-5 3-4 4-5/4-5 4-5/4-5 4-5/4-5

Yellow K-HL 6.67g/ 5 5 4-5 4-5/5 4-5/5 4-5/5

Red K-HL 6.67g/ 4 4-5 4-5 4-5/5 4-5/5 4-5/5

Continuous
Blue K-HL 6.67g/ 5 4-5 4-5 4-5/5 4-5/5 4-5/5
dyeing

Synozol K-HL dyes

Violet K-HL 7.50g/ 5 4-5 4-5 4-5/5 4-5/5 4-5/5

Grey K-HL 10.00g/ 5 4-5 4 4/5 4-5/5 4/5

*Material : Exhaust dyeing - Unmercerized cotton

Continuous dyeing - Mercerized cotton For Exhaust & Continuous dyeing

Kyung-In Synthetic Corporation

HEAD OFFICE 112-31 Yeomchang-Dong Kangseo-Gu, Seoul, 157-040, Korea

Tel: 82-2-3665-4001 Fax: 82-2-3660-8635
E-mail: kiscotech@kyungin.co.kr
URL: http: // www.kyungin.co.kr

Edition 2012
Kyung-In Synthetic Corporation
Copyright ⓒ 2012 Kyung-In Synthetic Corporation. All rights reserved.
Synozol K-HL dyes
NEW TO THE INDUST R Y

One trichromatic combination for multiple processes Superior technical advantages with low cost
Pale / Light shades with high light fastness
Extremely cost efficient Can be used as an alternative to Vat dyes for pale shades
Unique range of dyes - market exclusive
Tailing / Listing in Pad Application eliminated
Proven dyestuff chemistry using just 3 core elements
Perfect leveling in difficult shade area’s
Homogeneous Violet and Grey as supplementary products
 Synozol K-HL dyes EXHAUST DYEING

Synozol K-HL dyes are specially designed for pale shade dyeing,
giving improved benefits in terms of reproducibility and good light
fastness for both exhaust and continuous dyeing.
In the past, difficult shades (earth tones, greys, olives) gave problems of leveling and
light fastness in exhaust dyeing and tailing /listing issues when dyed continuously.
Vat dyes were invariantly the only alternative UNTIL NOW!
Shade (1/6 Standard Depth) in Exhaust dyeing

Unique alternative for pale shades with good light fastness

In Exhaust and Continuous dyeing Yellow K-HL Red K-HL Blue K-HL
0.67% 1.00% 0.58%

Excellent
Compatibility
Excellent Compatibility
Low Sensitivity

Exhaust dyeing
Easy to formulate
to various dyeing For Cotton For Rayon
Earth shades
parameters 100.0% 100.0%

Flexible Application methods 80.0% 80.0%

(Exhaust & Continuous dyeing )

60.0% 60.0%

Brown
40.0% 40.0%
Yellow K-HL 0.33%
YEL K-HL YEL K-HL Red K-HL 0.33%
20.0% 20.0%
Excellent Reproducibilty !! RED K-HL
BLU K-HL
RED K-HL
BLU K-HL
Blue K-HL 0.33%

Right First Time !! 0.0%

0 10 20 30 40 50 60
0.0%
0 10 20 30 40 50 60

Suitability min. min.

Synozol K-HL dyes Fixation time 2min 5min 10min 20min 45min 60min
Exhaust +++
Padding Cold Pad Batch +++ Cotton
Continuous PDPS +++
PDT ++
+++ : suitable
++ : suitable with limits E-control ++
+ : unsuitable Rayon
Cotton +++
Viscose rayon +++
PES/CO +++
PA/CO ++
LEVELING & REPRODUCIBILITY!
 Combination Synozol K-HL dyes CONTINUOUS DYEING

Brown Olive Grey Continuous and cold pad batch dyers major problems come from tailing and side/center
shade difference when pale shades are produced. Even when light fastness is achieved the
shade continuity remained an issue UNTIL NOW!

Recipe Yellow K-HL 0.33% Yellow K-HL 0.50% Yellow K-HL 0.25%
Shade (1/6 Standard Depth) in Continuous dyeing
Red K-HL 0.33% Red K-HL 0.25% Red K-HL 0.25%
Blue K-HL 0.33% Blue K-HL 0.25% Blue K-HL 0.50%

Fastness
Oxidative Yellow K-HL Red K-HL Blue K-HL
Light Washing Water 6.67g/ 6.67g/ 6.67g/
bleach damage
AATCC 16E
ISO 105-B02 M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01
20AFU
Ch Ch Ch Ch CO Ch CO Ch CO Low Sensitivity to Dyeing Factors in PDPS

Continuous dyeing
Brown 4 4 4 4-5 5 4-5 5 4-5 5
Exhaust dyeing

1.5
Olive 4 4 4 4-5 5 4-5 5 4-5 5 Soda(g/ ) / NaOH(ml/ )

Grey 4 4 4 4-5 5 4-5 5 4-5 5

redder
1 5
+5/5
0.5 -50 6

-1.5 -1 -0.5 0.5 1 1.5 2 1 3 Time(sec)

Low Sensitivity For Right First Time

DH
6 71 -30 +60
4
23
5
7 +50
Soda ash & Glauber’s salt Time & Temperature -0.5 -5/5
Salt(g/ )
4

greener
1 1 -1

1 standard condition Salt 200g/

-1.5 Soda ash 20g/
0.5 0.5 NaOH 10ml/
duller DC brighter
Time 60sec
17
4 6
-1 -0.5 6 2 89 0.5 1 -1 -0.5 0 14 0.5 1
5
Da 0
Da 18 13
3 4 11 12
10
1
16 15
-0.5 -0.5

2 3
-1 -1

Db Db

Soda ash(g/ ) 10 15 20 Time(min) 30 40 50

20 1 2 3 55 10 11 12
Glauber’s Salt Temperature 5 7
30 4 5(Std) 6 60 13 14(Std) 15
(g/ ) (C˚)
40 7 8 9 65 16 17 18
PERFECT CONSISTENCY & REPRODUCIBILITY!
 Combination
Homogeneous dyes
Synozol Violet K-HL and Synozol Grey K-HL were developed to achieve easily, critical Violet and Grey pale shades with
excellent light fastness properties, good reproducibility which are difficult to dye level with trichromatic combinations.
LT. Stone LT. Brown Steel Grey
Shade (1/6 Standard Depth)
Exhaust dyeing Continuous dyeing

Recipe Yellow K-HL 1.10g/ Yellow K-HL 4.05g/ Yellow K-HL 3.20g/
Red K-HL 0.90g/ Red K-HL 3.12g/ Red K-HL 2.50g/
Blue K-HL 0.78g/ Blue K-HL 2.40g/ Blue K-HL 4.00g/
Violet K-HL Grey K-HL Violet K-HL Grey K-HL
0.67% 1.00% 7.5g/ 10.0g/

Fastness Combination
Recipe1 Recipe2 Recipe3 Recipe4
Oxidative
Light Washing Water
bleach damage

Exhaust dyeing
AATCC 16E
ISO 105-B02 M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01
20AFU
Continuous dyeing

Ch Ch Ch Ch CO Ch CO Ch CO

LT. Stone 4 4-5 4-5 4-5 5 4-5 5 4-5 5

LT. Brown 4 4 4-5 4-5 5 4-5 5 4-5 5 Violet K-HL 0.10% Violet K-HL 0.10% Grey K-HL 0.10% Grey K-HL 0.10%
Yellow K-HL 0.02% Blue K-HL 0.02% Yellow K-HL 0.02% Violet K-HL 0.02%
Steel Grey 4 4 4 4-5 5 4-5 5 4-5 5

Continuous dyeing
No Tailing & Listing
Light Olive Violet K-HL 1.0g/ Violet K-HL 1.0g/ Grey K-HL 1.0g/ Grey K-HL 1.0g/
Synozol Yellow K-HL 2.62g/ Yellow K-HL 0.2g/ Blue K-HL 0.2g/ Yellow K-HL 0.2g/ Violet K-HL 0.2g/
Synozol Red K-HL 2.89g/
Synozol Blue K-HL 3.19g/
Oxidative
Light Washing Water
bleach damage
Tailing Property Listing Property ISO 105- AATCC
M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01
B02 16E 20AFU
Ch Ch Ch Ch CO Ch CO Ch CO

Start Recipe1 4 4 4 4-5 5 4-5 5 4-5 5

100% (STD)
Exhaust

Recipe2 4 4 4 4-5 5 4-5 5 4-5 5

dyeing

CMC DE= 0.0

Recipe3 4-5 4-5 4 4-5 5 4-5 5 4-5 5
Recipe4 4 4-5 4 4-5 5 4-5 5 4-5 5
End Left Center Right Recipe1 4 3-4 4 4-5 5 4-5 5 4-5 5
Continuous

97%
102% 100% (STD) 98% Recipe2 4 4 4-5 4-5 5 4-5 5 4-5 5
dyeing

CMC DE= 0.3

CMC DE= 0.2 CMC DE= 0.0 CMC DE= 0.2
Recipe3 4-5 4-5 3-4 4 5 4-5 5 4-5 5
Recipe4 4 4-5 3-4 4 5 4-5 5 4-5 5
 EXHAUST DYEING CONTINUOUS DYEING
Trichromatic Combination Trichromatic Combination

Yellow K-HL Yellow K-HL

1.0%o.w.f 10.0g/

Y+R Y+R+B Y+B Y+R Y+R+B Y+B

0.67+0.33%o.w.f 0.67+0.17+0.17%o.w.f 0.67+0.33%o.w.f 6.7+3.3g/ 6.7+1.7+1.7g/ 6.7+3.3g/

Continuous dyeing
Y+R Y+R+B Y+R+B Y+R+B Y+B Y+R Y+R+B Y+R+B Y+R+B Y+B
Exhaust dyeing

0.33+0.67%o.w.f 0.33+0.50+0.17%o.w.f 0.33+0.33+0.33%o.w.f 0.33+0.17+0.50%o.w.f 0.33+0.67%o.w.f 3.3+6.7g/ 3.3+5.0+1.7g/ 3.3+3.3+3.3g/ 3.3+1.7+5.0g/ 3.3+6.7g/

Red K-HL R+B R+B R+B R+B R+B Blue K-HL Red K-HL R+B R+B R+B R+B R+B Blue K-HL
1.0%o.w.f 0.83+0.17%o.w.f 0.67+0.33%o.w.f 0.50+0.50%o.w.f 0.33+0.67%o.w.f 0.17+0.83%o.w.f 1.0%o.w.f 10.0g/ 8.3+1.7g/ 6.7+3.3g/ 5.0+5.0g/ 3.3+6.7g/ 1.7+8.3g/ 10.0g/

Recommended dyeing process Recommended dyeing process Chemical Amount

Synozol Dyes Xg/
Migration Inhibitor 10g/
Wetting Agent 1g/
, , , , , , Padding
10 30 30 30 30 40 Reduction Inhibitor 1g/
60˚C
Liquor Temperature 25˚C
Liquor Pick up 60%
Auxiliary Dye Glauber's salt addition Soda ash addition Washing
off Temperature 120˚C
Pad Dry Pad Steam Washing off Drying
Time 1min
Soda ash 20g/
Caustic soda(38˚Be) 10m /
Unmercerized Cotton Alkali
* Applicable in : Padding Glauber’s salt 200g/
Dye(%o.w.f) <0.1% 0.1-0.5% 0.5-1.0% - Cold Pad Batch Liquor Temperature 25˚C

Glauber’s salt g/ 20 30 40
(minimum 24hours batching time for Grey K-HL) Liquor Pick up 80%
- Pad-dry-thermofix Steaming Temperature 102˚C
Soda ash g/ 10 15 15 - E-control (Fixation) Time 1min