Dear Students,

As you are proceeding for Deepawali Vacations, you are looking forward to free time, fun and
frolic with family and friends. I, on the behalf of my department, wish you all the joy and
happiness in this festival period.

Deepawali is a festival of lights. We lighten lamps to drive away the darkness of moonless
night of Deepawali. Do not forget, it is also a very crucial period for you when you can pull out
some time for your revision. Devote your mornings and afternoons to academics (self-study)
while evening should be reserved for pure enjoyment. Do not plan any study in evening
duration, just enjoy freely and have a good time if you have studied properly in the morning.

As you lighten the lamps of Deepawali, also lighten the lamp of knowledge in your heart. I am
offering you unlighted deepaks in the form of Chemistry problems. Lighten them with the fire
of your mind, and solve them all to celebrate true deepawali.

May your interest in your subject intensify. May you learn to work hard with consistency. May
you always maintain your focus. May you be true to yourself. May Ma Saraswati bless you
with all that is desirable. This is a blessing from my heart.

With affection,

Shishir Mittal,
VP(SW) and HoD (Chemistry),
Resonance.
 ORGANIC CHEMISTRY
IUPAC NOMENCLATURE
Instruction :
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. ¼ [one fourth (–1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________________
Straight Objective Type
This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.
________________________________________________________________________________________
1. What is correct about methyl butane and 2-methyl pentane.
(1) Both have same empirical formula. (2) Both have same molecular formula.
(3) Both have same general formula. (4) Both have same number of carbon atoms
2. Which of the following has CnH2n general formula ?

(1) (2) (3) (4)

3. Degree of unsaturation of the following compound is :

(1) 6 (2) 7 (3) 5 (4) 8

4. Number of 3º and 2º carbon atoms in iso-octane is
(1) 2, 2 (2) 2, 3 (3) 1, 1 (4) 1, 2

5. N compound is :
H
(1) Unsaturated homocyclic (2) Aromatic heterocyclic
(3) Saturated heterocyclic (4) Unsaturated heterocylic

6. What is correct IUPAC name of .

(1) 4-Methyl-2,6-dibromo-2-chloro-5-fluoroheptane
(2) 4-Methyl-2-chloro-2,6-dibromo-5-fluoroheptane
(3) 2,6-Dibromo-2-chloro-5-fluoro-4-methylheptane
(4) 4-Methyl-6-chloro-2,6-dibromo-3-fluoroheptane
7. The correct IUPAC name of the following compound is :
H OCH3 NO2

Cl — C — C — C — Et
CH3 Br H
(1) 2-Bromo-1-chloro-3-ethyl-2-methoxy-1-methyl-3-nitropropane
(2) 3-Bromo-2-chloro-3-methoxy-4-nitrohexane
(3) 3-Bromo-2-chloro-4-ethyl-3-methoxy-4-nitrobutane
(4) 4-Bromo-5-chloro-4-methoxy-3-nitrohexane

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8. In the structure word root changes by replacing the value of R. What will be R.

(1) –CH3 (2) CH  CH3 (3) –CH=CH2 (4) –CH2–CH2–CH2–CH3

|
Cl

9. Select the strucuture with correct numbering in the chain :

NO2
4 3 2 1
(1) (2) H3C – C – CH2 – CH3

Br
7
6
2 4
3 6 5 1
(3) 1 (4) 3
5 4 2
10. Correct IUPAC name of the following compound is :
Br

(1) 4-Bromo-5-ethylidenehepta-1,3,6-triene (2) 4-Bromo-5-ethenylhepta-1,3,6-triene

(3) 4-Bromo-3-ethenylhepta-1,4,6-triene (4) 4-Bromo-3-ethylidenehepta-1,4,6-triene
11. What is the structure of 4-Methylhex-5-en-3-thiol.

(1) (2) (3) (4)

12. Structural formula of 3–Ethynyl–1,4–pentanediol is :

(1) (2)

(3) (4) None of these

13. The IUPAC name of CH3CH2COCH(CH3)2 is :

(1) Isopropylethyl ketone (2) 2-Ethyl-3-pentanone
(3) 4-Ethylisopropyl ketone (4) 2-Methyl-3-pentanone
14. IUPAC name of CH3CH2CHO is
(1) Propionaldehyde (2) Ethyl aldehyde (3) Propanol (4) Propanal
15. IUPAC name of CH3  CH  COCl is :
|
CH2CH3
(1) Butan-2-yl chloride (2) 2-Methylbutanoyl chloride
(3) 3-Methyl butanyl chloride (4) 2-Ethylpropanoyl chloride
16. The IUPAC name of CH3  C  CH2  CONH2 is :
||
O
(1) 3-Oxobutanamide (2) 4-Oxobutanamide
(3) 2-Oxobutanamide (4) 2-Acetyl ethanamide

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17. Structure of the 2,2-Dimethylbutane dioic acid :

(1) (2) (3) (4)

18. The IUPAC name of is

(1) 4-Cyano-2-chlorocyclohex-5-enamide (2) 4-Cyano-2-chlorocyclohex-5-ene carboxamide

(3) 4-Cyano-6-chlorocyclohex-2-enamide (4) 4-Cyano-6-chlorocyclohex-2-ene carboxamide

19. What is the correct IUPAC name for CH3  CH  CH  CH  CH2  C N

|
CH3
(1) 5-Methylhex-3-enenitrile (2) 5-Cyanomethylpent-2-ene
(3) 4-Isopropylbut-3-enenitrile (4) None of above

20. IUPAC name of is

(1) Methyl 2-aminopropanoate (2) 2-aminomethylpropanoate
(3) 2-aminomethylethane carboxylate (4) Methyl 2-aminocyanoethane carboxylate

21. The IUPAC name of is :

(1) Ethyl 3-chlorocarbonyl-2, 3-dimethylpropanoate

(2) Ethyl 3-chlorocarbonyl-2-methylbutanoate
(3) Ethyl 2, 3-dimethyl-3-chlorocarbonylpropanoate
(4) Ethyl 2-methyl-3-chlorocarbonylbutanoate
22. IUPAC name of is

(1) Ethyl 3-Oxobutanoate (2) Ethyl 3-Formylbutanoate

(3) Ethyl 3-Carboxy-2-methylpropanal (4) Ethyl 2-Formylbutanoate

23. IUPAC name of is :

(1) 1-Ethanoyloxyethane-1-sulphonic acid (2) 1-Ethanoyloxypropane-1-sulphonic acid.
(3) 2-Ethanoyloxyethane-1-sulphonic acid (4) 3-Ethanoyloxy-1-sulphoethane

24. What is the correct IUPAC name for

(1) Cyclopentanoic anhydride (2) Cyclopentane carboxylic anhydride

(3) Dicyclopentanoic anhydride (4) Dicyclopentane carboxylic anhydride
25. Which is the correct structure of compound Propyl cyclobutane carboxylate
O O
(1) O–C–CH2–CH2–CH3 (2) C–O–CH2–CH2–CH3

O O
(3) C–O–CH2–CH2–CH3 (4) C–O–CH(CH3)2

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26. The IUPAC name of is :

(1) 3-Hydroxy-2-oxobutanedioic anhydride

(2) 2-Hydroxy-3-oxobutanedioic anhydride
(3) 2-Oxo-3-hydroxybutane dicarboxylic anhydride
(4) 2-Hydroxy-3-oxoethane dicarboxylic anhydride

27. What is the IUPAC name of

(1) 5-Chloro-3-hydroxybenzenecarboxylic acid.

(2) 3-Hydroxy-5-chlorobenzenecarboxylic acid.
(3) 3-Chloro-5-hydroxybenzenecarboxylic acid.
(4) 1-Carboxy-3-chlorobenzen-1-ol
28. Which is the correct IUPAC name of the following compound :

(1) 4-Methyl-5-bromonitrobenzene (2) 2-Bromo-1-methyl-4-nitrobenzene

(3) 3-Bromo-4-methyl-1-nitrobenzene (4) 1-Bromo-2-methyl-5-nitrobenzene
29. The correct IUPAC name of the compound :
CHO
NO2

OCH3

(1) 2-Formyl-5-methoxynitrobenzene (2) 4-Formyl-3-nitroanisole

(3) 4-Methoxy-2-nitrobenzaldehyde (4) 4-Methoxy-6-nitrobenzaldehyde
30. Which has correct IUPAC numbering :

(1) (2)

(3) (4) None of these

OBJECTIVE RESPONSE SHEET (ORS)

17
Page # 17
 ISOMERISM STRUCTURAL & PRACTICAL ORGANIC CHEMISTRY

Instruction :
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. ¼ [one fourth (–1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________________
Straight Objective Type
This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.
________________________________________________________________________________________
1. In position isomers :
(1) Nature of Functional group changed (2) Length of parent or side chain changed
(3) Position of multiple bond changed (4) None of these
2. The structures (CH3)2CHCH2Br and CH3(CH2)3Br shows :
(1) position isomers (2) chain isomerism
(3) functional isomerism (4) None of these
3. Which of the following are chain isomer :
(1) Hexane and Heptane (2) 1,1-Dichloroethane and 1,2-Dichloroethane
(3) 2-Methyl pentane and 3-Methyl pentane (4) Pentane and neopentane
4. 1,1-Dimethylcyclopropane and 1,2-Dimethylcyclopropane are :
(1) Positional isomer (2) Metamer
(3) Functional isomer (4) Chain isomer
5. Diethylether and Methylpropyl ether are
(1) Positional isomers (2) Functional isomers
(3) Metamers (4) Chain isomers
6. The isomerism exhibited by alkyl cyanide and alkyl isocyanide is :
(1) Functional isomerism (2) Positional isomerism
(3) Chain isomerism (4) Metamerism

7. Methyl propanoate and ethyl ethanoate are :

(1) Functional isomers (2) Metamers
(3) Chain isomers (4) Homologues.
8. Which of the following pairs are not isomeric compounds :
(1) Ethyl ethanoate and Methyl propanoate (2) Butanone and Butanal
(3) Ethoxy propane and Propoxy ethane (4) Methoxy methane and Ethanol
9. The number of possible alcoholic isomers for C4H10O are :
(1) 4 (2) 2 (3) 3 (4) 5
10. How many structural isomeric cycloalkene can give methylcyclobutane on hydrogenation :
(1) 2 (2) 3 (3) 4 (4) 1

11. How many cyclic alcohols are possible with molecular formula C4H8O.

(1) 1 (2) 2 (3) 3 (4) 4

12. Which can give only 3 monochloro structure isomers on reaction with chlorine in presence of light ?
(1) 2-Methyl propane (2) 2-Methyl butane
(3) 3-Methyl pentane (4) 3-Ethyl pentane

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13. The total number of monochloro products (structural) formed.

Cl2 / h
 

(1) 2 (2) 3 (3) 4 (4) 1

14. A dichloroderivative of propane ‘X’ (C3H6Cl2) gives three types of trichloroderivative on further
chlorination. The correct structure of ‘X’ is .

(1) (2) (3) (4)

15. The alkene which on ozonolysis yields acetone is

(1) CH2 =CH2 (2) CH3–CH=CH2 (3) (CH3)2C=C(CH3)2 (4) CH3–CH=CH–CH3

16. product

Product of the above reaction gives black precipitate with :

(1) Cu2Cl2 + NH4OH (2) Dil cold KMnO4 (3) AgNO3 + NH4OH (4) 2, 4-DNP

17. Ozonolysis of which unsaturated hydrocarbon of the following will give aldehyde and ketone both ?
(1) 2, 3-Dimethyl but-2-ene (2) 1, 2, 3, 4-Tetramethylcyclopenta-1,3-diene
(3) But-2-yne (4) 2-Methylbut-2-ene
O
18. CH2=CH–CH=CH–CH3 3
Zn,H O
 Products.
2

Which product is not obtained in the above reaction ?

(1) CH2=O (2) CH3–CH=O (3) OHC–CHO (4) CH3–COOH

19. An organic compound C8H12 adds two moles of H2 per mole of hydrocarbon. It undergoes reductive
ozonolysis to give Butane-1,4-dial only. What is the structure of hydrocarbon ?
(1) (2)

(3) (4)

20. A hydrocarbon C9H16 consumes only mole of H2 in the presence of nickel as catalyst. On ozonolysis,
the hydrocarbon produces cyclohexanone and acetone. The hydrocarbon is
CH3 CH2 CH3
CH3
C C
CH2 CH3 CH3
(1) (2) (3) (4)
CH3 CH2CH3

21. Zingiberene is the oil of ginger having structure as below :

Which is not true about this compound

(1) Its DU = 4
(2) After hydrogenation its chlorination gives 12 monochloro products.
(3) For hydrogenation it requires 3 mol of H2
(4) On ozonolysis it gives ketone only
22. Benzoic acid can be distinguished from ethyl benzoate by
(1) NaHCO3 (2) Fehling solution
(3) Carbylamine test (4) Action with dil. HCl

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Page # 19
23. Benzaldehyde and acetone can be distinguished by
(1) Mulliken Baker test (2) Fehling solution
(3) Iodoform test (4) Ninhydrin test
24. Phenol and Benzoic acid can be distinguished by
(1) FeCl3 test (2) Mollisch test (3) Hinsberg test (4) Tollen's test

25. Acetaldehyde and benzaldehyde can be distinguished by

(1) Tollen's test (2) Fehling solution (3) FeCl3 test (4) NaHCO3 test

26. Propanal and propanone can not be distinguished by

(1) Iodoform test (2) Fehling solution
(3) Tollen's test (4) 2,4- DNP test
27. Formic acid and acetic acid can be distinguished by
(1) Iodoform test (2) NaOH solution (3) Tollen's test (4) NaHCO3 test

NaHCO
28. 3
  X gas

NaHCO
Ph-CH2-SO3H  3
 Y gas

X and Y are respectively
14 14
(1) CO 2 , SO2 (2) CO2, CO 2 (3) CO2, SO2 (4) CO2, SO3

29. PhCONH2 and PhCOOH can be distinguished by :

(1) NaOI,  (2) NaHCO3 (3) 2, 4-DNP (4) AgNO3

30. Which compound can not give Prussian blue colour in lassaigne test ?
(1) CH3–NH–CH3 (2) Pyridine (3) NH2–NH2 (4) Aniline

OBJECTIVE RESPONSE SHEET (ORS)

20
Page # 20
 ELECTRONIC EFFECT & APPLICATION (GOC)

Instruction :
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. ¼ [one fourth (–1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________
Straight Objective Type
This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.
________________________________________________________________________________
1. Which of the following groups has the highest + effect.
(1) –COO (2) CH3 CH2 – (3) (CH3 )2 CH– (4) (CH3 )3 C–
2. In which of the following correct stability order is shown :
(1) < (2) <

(3) > (4) <

3. Which of the following has the maximum number of resonating structures ?

(1) Benzene (2) Naphthalene (3) Anthracene (4) Phenanthrene
4. The bonding in ozone is best described in terms of :
(1) (2)
(3) O O O (4) ¯O O O+ O+ O O¯
5. Which of the resonating structures are not acceptable in the given groups
+ +
(1) CH2 =CH–OCH3 (2) (3) CH CH OCH
2 3 (4) CH2 CH OCH 3

6. Which of the following resonating structure is more stable ?

(1) (2) (3) (4)

7. Which of the following orders is correct for heat of hydrogenation of these compounds ?

(X) (Y) (Z)

(1) X > Y > Z (2) Z > Y > X (3) Y > Z > X (4) Z > X > Y
8. Find out number of benzylic hydrogen in following compound :

(1) 4 (2) 5 (3) 6 (4) 7

9. S 1 : Protonated pyrrole has resonance stabilised positive charge.
S 2 : CH2=C=O exhibits resonance.
S 3 : 1,3-Butadiene shows resonance and hyperconjugation effect.
S 4 : Carbon-oxygen bonds are of equal length in acetic acid.
(1) T F F F (2) F T F F (3) F F F T (4) F F F F

21
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10. Arrange the following in increasing order of stability
, ,

(1) III < II < I (2) I < II < III (3) III < I < II (4) II < I < III
11. Which is the most stable resonating structure.
(1) (2) (3) (4)

12. Which of the following group has (+m) effect :

O
C–H NH–CH 3 CH3
(1) (2) (3) (4)

13. For Cyclooctatetraene following is incorrect.

(1) There are two types of C–C bond.
(2) Structure is non planar and resonance is not observed in molecule.
(3) Extensive resonance is found with in the molecule and all bonds are of same type.
(4) Its heat of hydrogenation is equal to that of 4 bonds hydrogenated.
14. Pair of aromatic compound is/are-

(1) (2)

N N
(3) (4) &
S N

15. Choose the non aromatic compound among the following :

H
B
(1) (2) (3) (4)

16. W hich of the following pairs of ions is more stable ?

(i) and

(ii) and

(iii) and

(1) (i) – II , (ii) – II , (iii) – II (2) (i) – II , (ii) – I , (iii) – II

(3) (i) – II , (ii) – I , (iii) – I (4) (i) – I , (ii) – II , (iii) – II

17. Which of the following carbanions is most stable ?

(1) (2) (3) (4)

18. The decreasing order of stability of following anion is :

(P) (Q) (R) (S)

(1) P > Q > R > S (2) Q > R > P > S (3) P > R > Q > S (4) S > R > Q > P
19. Which of the following carbocation would have greatest stability ?

(1) (2) (3) (4)

22
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20. Which of the following cations is most stable ?

(1) (2) (3) (4)

21. In which of the following carbocation rearrangement takes place most rapidly ?

(1) (2) (3) (4)

22.

How many number of sp2 hybridised nitrogen atoms in given structure.

(1) 3 (2) 5 (3) 2 (4) 4

23. Write basicity order of following :

CH3—CH2—NH2 (CH3)2NH
(P) (Q) (R) (S)
(1) P > S > R > Q (2) R > S > Q > P (3) P > R > Q > S (4) S > R > Q > P

24. The correct order of acidity in following compound is :

(P) (Q) (R) (S)

(1) P > S > R > Q (2) R > S > Q > P (3) Q > R > S > P (4) S > R > Q > P

25. Arrange the following in decreasing order of their acidic strength :

(P) (Q) (R) (S)

(1) S > P > Q > R (2) R > S > P > Q (3) S > Q > P > R (4) P > Q > R > S

26. Arrange the following in decreasing order of their acidic strength :

(P) (Q) (R) (S)

(1) P > Q > R > S (2) Q > P > S > R (3) S > R > Q > P (4) R > S > P > Q

27. The correct order of acidic strength of the following :

(P) (Q) (R)

(1) P > Q > R (2) R > P > Q (3) Q > R > P (4) P > R > Q

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28. Compare acidic strength of the following compound.

(P) (Q) (R)

(1) P > Q > R (2) Q > P > R (3) R > P > Q (4) R > P > Q
29. Which of the following will not react with Na metal ?

(1) (2) (3) (4)

30. Which of the following compound will not exhibit enolization ?

(1) (2)

(3) (4)

OBJECTIVE RESPONSE SHEET (ORS)

24
Page # 24
 STEREOISOMERS

Instruction :
1. The test is of 1 hour duration.
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
3. Each question is allotted 4 (four) marks for correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. ¼ [one fourth (–1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________
Straight Objective Type
This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, – 1) Marks.
________________________________________________________________________________
1. Types of geometrical isomerism shown at point X, Y and Z of the following compound respectively are :

X Y Z X Y Z
(1) cis cis trans (2) cis trans trans
(3) trans cis cis (4) cis trans cis
2. Which of the following compounds does not have any geometrical isomer ?

(1) (2) (3) (4)

3. Geometrical isomerism is possible in :

(1) (2) (3) (4)

4. A natural occurring substance has the constitution shown below. How many isomers may have this
constitution ?

(1) 2 (2) 8 (3) 16 (4) 64

5. Which is correct option for given character ?

fn;sx;sy {k.k d sfy ;slgh fod Yi gS\
(1)

(2) (water solubility)

(3) Maleic acid > Fumaric acid (Melting point)

(4) (Dipole moment)

6. Which of following statement is incorrect for the pair of geometrical isomers :

(1) Known as diastereomers.
(2) Mirror image of each other.
(3) Trans isomer is generally more stable than cis isomers but not always.
(4) Geometrical isomers have same connectivity of atoms.

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7. Which of the following compounds having E-configuration –
CH3
CH3O CH 2–Br CH
C C CH3
(1) OHC CH2 –NO2 (2) C=C=C=C
CH2–CH2–CH3

HS–CH2 NO2 CH3 CH 2–COOH

(3) CH –C–H C C C (4) H3 C–H2C C C
3 2 CH2–NH2 CH 2–CONH 2
O

8. Find out number of stereogenic centers present in following compound ‘simvastatin’.

(1) 5 (2) 7 (3) 8 (4) 6

9. Number of functional groups present in the following compound is :

(1) 5 (2) 7 (3) 6 (4) 8

10. The observed rotation of 2.0 g of a compound in 10 mL solution in a 25 cm long polarimeter tube is +
13.4º. The specific rotation of compound is :
(1) + 30.2º (2) –26.8º (3) + 26.8º (4) + 40.2º
11. If a mixture of 2-bromobutane has enantiomeric excess of 50% of (+) -2-bromobutane, the stereo
isomeric composition of the mixture with respect to (+) and (–) enantiomer respectively is :
(1) 75% (+) and 25% (–) (2) 70% (+) and 30% (–)
(3) 80% (+) and 20% (–) (4) 25% (+) and 75% (–)
12. Increasing order of stability among the three main conformations (i.e. eclipse, anti, gauche) of 3-
hydroxypropanoic acid is :
(1) eclipse, gauche, anti (2) gauche, eclipse, anti
(3) eclipse, anti, gauche (4) anti, gauche, esclipse
13. Find the correct statements regarding following molecules.

I II III IV
(1) I, II and III are meso compounds (2) II and III are enantiomers
(3) I, III and IV are enantiomer (4) III and IV are identical
14. Which of the following compound is meso isomers ?

(1) (2) (3) (4)

15. The following compounds differ in respect of :

(1)Their chemical and physical properties

(2) The direction in which they rotate plane of polarized ligth
(3) Their interaction with molecule (4) None of these

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16. Which of the following statements about the relationships of the structure (P), (Q) , (R) and (S) is
incorrect ?

(P) (Q) (R) (S)

(1) P and R are enantiomers (2) P and R are identical
(3) Q and S are identical (4) P and Q are enantiomers
17. Which of the following pairs of compounds are functional isomers ?

(1) and (2) and

(3) and (4) and

18. Which of the following properties are different for (R)-2-bromo butane and (S)-2-bromobutane
(1) Boiling point (2) Melting point (3) Density (4) Configuration
19. Which of the following compounds do not have the plane of symmetry ?

(1) (2) (3) (4)

20. Which of the following statements are INCORRECT about these molecules ?

(1) I and II are a pair of enantiomers (2) III is metamer of I and II

(3) I and II are optically active compound (4) III is not stereoisomer of I and II
21. Calculate no. of stereogenic center in following molecule.

(1) 8 (2) 7 (3) 10 (4) 9

22. The number of alkynes possible with molecular formula C5H8 is :
(1) 2 (2) 3 (3) 4 (4) 5

23. Identify R isomer in the following compound :

CH3
COOH COOH
H OH CH 3 H3C CH3
(1) OH CH 3 (2) (3) (4) HOOC
H
CH 3 C2 H5
H H3 C H H HO H

24. Number of stereocenter and stereoisomer of the given compound :

(1) 1 and 2 (2) 2 and 4 (3) 3 and 8 (4) 3 and 6

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25. Metamer of compound B is :

B:

(1) (2) (3) (4)

26. In the structure the configurations at chiral centers are :

(1) 2R , 3R (2) 2S , 3R (3) 2R , 3S (4) 2S , 3S

27. Which of the following compound is chiral ?

(1) (2) (3) (4)

28. Which of the following compounds is/are can be optically active ?

(a) (b) (c)

Select correct answer using the codes given :

(1) a and c (2) a and b (3) b and c (4) a, b and c
29. Which of the following compound on reaction with NH2OH shows Geometrical isomerism.
O O O Me Me

(1) (2) (3) O (4) All of these

30. Which of the following molecule can show geometrical isomerism ?

CH3
H Cl H H
(1) Cl H (2) (3) (4)
CH3 HOOC COOH

OBJECTIVE RESPONSE SHEET (ORS)

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 ANSWER KEY

PHYSICAL CHEMISTRY

MOLE CONCEPT
1. (3) 2. (1) 3. (1) 4. (3) 5. (3)
6. (4) 7. (3) 8. (1) 9. (2) 10. (3)
11. (1) 12. (3) 13. (3) 14. (3) 15. (2)

QUANTUM NUMBERS & ELECTORNIC CONFIGURATION

16. (3) 17. (3) 18. (3) 19. (3) 20. (3)
21. (3) 22. (4) 23. (4) 24. (2) 25. (1)

GASEOUS STATE (REAL GAS)

26. (4) 27. (2) 28. (1) 29. (3) 30. (1)
31. (4) 32. (2) 33. (4) 34. (3) 35. (3)

PERIODIC TABLE

36. (4) 37. (4) 38. (2) 39. (3) 40. (2)
41. (1) 42. (1) 43. (3) 44. (3) 45. (1)
CHEMICAL EQUILIBRIUM
46. (1) 47. (1) 48. (2) 49. (3) 50. (3)
51. (1) 52. (2) 53. (3) 54. (4) 55. (4)
56. (3) 57. (2) 58. (3) 59. (3) 60. (1)
61. (2) 62. (1) 63. (2) 64. (3) 65. (2)

IONIC EQUILIBRIUM-3
66. (1) 67. (2) 68. (2) 69. (4) 70. (3)

CHEMICAL BONDING

71. (2) 72. (4) 73. (4) 74. (2) 75. (2)
76. (1) 77. (1) 78. (3) 79. (3) 80. (3)
81. (2) 82. (3) 83. (4) 84. (3) 85. (3)

SOLUTION & COLLIGATIVE PROPERTIES

86. (4) 87. (3) 88. (4) 89. (1) 90. (3)
91. (4) 92. (3) 93. (2) 94. (1) 95. (3)
96. (2) 97. (2) 98. (1) 99. (3) 100. (3)

COORDINATION COMPOUNDS
101. (1) 102. (3) 103. (1) 104. (1) 105. (3)
106. (1) 107. (2) 108. (4) 109. (4) 110. (2)
111. (2) 112. (2) 113. (4) 114. (3) 115. (3)

s-BLOCK ELEMENTS
116. (4) 117. (2) 118. (2) 119. (3) 120. (4)

SURFACE CHEMISTRY
121. (4) 122. (1) 123. (4) 124. (2) 125. (2)
126. (2) 127. (2) 128. (1) 129. (1) 130. (2)

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 ORGANIC CHEMISTRY

IUPAC NOMENCLATURE
1. (3) 2. (3) 3. (2) 4. (3) 5. (4)
6. (3) 7. (2) 8. (4) 9. (3) 10. (2)
11. (2) 12. (3) 13. (4) 14. (4) 15. (2)
16. (1) 17. (1) 18. (4) 19. (1) 20. (1)
21. (2) 22. (2) 23. (3) 24. (2) 25. (3)
26. (2) 27. (3) 28. (2) 29. (3) 30. (3)

ISOMERISM STRUCTURAL & PRACTICAL ORGANIC CHEMISTRY

1. (3) 2. (2) 3. (4) 4. (1) 5. (3)

6. (1) 7. (2) 8. (3) 9. (1) 10. (2)
11. (4) 12. (4) 13. (2) 14. (3) 15. (3)
16. (3) 17. (4) 18. (4) 19. (3) 20. (3)
21. (4) 22. (1) 23. (3) 24. (1) 25. (2)
26. (4) 27. (3) 28. (2) 29. (2) 30. (3)

ELECTORNIC EFFECTS (GOC)

1. (1) 2. (3) 3. (4) 4. (2) 5. (4)

6. (2) 7. (1) 8. (2) 9. (2) 10. (2)
11. (2) 12. (3) 13. (3) 14. (4) 15. (3)
16. (3) 17. (3) 18. (3) 19. (2) 20. (3)
21. (1) 22. (2) 23. (3) 24. (3) 25. (3)
26. (1) 27. (2) 28. (2) 29. (3) 30. (3)

STEREOISOMERS

1. (1) 2. (4) 3. (4) 4. (4) 5. (2)

6. (2) 7. (4) 8. (2) 9. (3) 10. (3)
11. (1) 12. (3) 13. (1) 14. (2) 15. (2)
16. (1) 17. (2) 18. (4) 19. (3) 20. (1)
21. (4) 22. (2) 23. (1) 24. (3) 25. (4)
26. (2) 27. (2) 28. (3) 29. (4) 30. (3)

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