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A n I S O 9 0 0 1 : 2015 C e r t i f i e d Organisation
CLASS - 11 (PCB)
Question Paper Code : UN444
KEY
1. A 2. C 3. A 4. D 5. B 6. A 7. A 8. D 9. C 10. C
11. D 12. C 13. C 14. B 15. A 16. C 17. C 18. C 19. A 20. A
21. B 22. A 23. B 24. A 25. B 26. B 27. C 28. B 29. A 30. B
31. D 32. C 33. D 34. D 35. C 36. A 37. A 38. C 39. C 40. A
41. C 42. B 43. A 44. D 45. C 46. B 47. C 48. B 49. D 50. C
51. D 52. B 53. D 54. B 55. C 56. C 57. A 58. D 59. C 60. D
SOLUTIONS
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9. (C) Sinusoids are small blood vessels, 23. (B) Sargassum is the genus of a large
somewhat larger than capillaries lined brown alga floating on the sea surface.
with Kupffer cells in liver. It has a diploid plant body and gametic
10. (C) Blood in the right ventricles is relatively meiosis.
deoxygenated after returning from the 24. (A) Citrus (lemon and oranges) develops
tissues. hesperidium fruit in which juicy
11. (D) Gaseous exchange in the booklungs placental hairs contain glucose
takes place with the help of lamellae (monosaccharide) with vitamin-C
arranged one over another like the (ascorbic acid) and citric acid.
leaves of a book. 25. (B) Heterophylly occurs in attached
12. (C) Thomas Addison, a London physician, in emergent hydrophytes such as
1855 reported a life threatening disease Limnophilla heterophylla, Ranunculus
caused by partial or complete failure of aquatilis or sagittaria sagittifolia. They
adrenocortical function. Some authors produce two types of leaves, those
consider W.H.Bayliss and E.H. Starling submerged iin water are deeply lobed
as the founders of endocrinology and but those produced above the level of
birth date of endocrinology as a science water are well developed with entire or
is usually given as 1902. serrate margins.
2
22(1.22)2 38. (C) The average temperature of 94 °C and
31. (D) Area = π r2 = = 4.6778 sq m. 86 °C is 90 °C, which is 70 °C above the
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room temperature. Under these
= 4.68 m2, having three significant digits. conditions the pan cools to 8 °C in 2
32. (C) Let the origin be at the C atom. Then: minutes.
Change in temperature
12 × 0 + 16 × 0.12 nm = K∆ T
Rcm = ≅ 0.07 nm Time
12 + 16
8 °C
33. (D) [Frequency] = T1 = K (70°C )
2 min
[Angular frequency] = T1 The average of 69 °C and 71 °C is 70 °C,
[Angular velocity] = T 1 which is 50 °C above room temperature.
K is the same for this situation as for
[Velocity gradient] = T1
the original.
ML2 T −2 2 °C
[Potential energy gradient] = = K (50°C )
L Time
= MLT2 = [force] When we divide above two equations,
34. (D) F = YAl/L = 90 × 109 × 106 × 1 / 2 we get
= 45000 N. 8 °C / 2 min K (70 °C )
=
35. (C) For the first 30 minutes, distance 2 °C / time K ( 50 °C )
travelled = 15 × 1800 = 27000 m Time = 0.7 min = 42 s
For the next 20 minutes, distance 39. (C) Resultant of three forces represented
travelled = 25 × 1200 = 30000 m completely by three sides of a triangle
Total distance travelled = 27000 + 30000 taken in the same order is zero.
= 57000 m Therefore, velocity of particle remains
unaffected.
The total time taken = 1800 + 1200 +
40. (A) As the ball rises, the initial kinetic
120 = 3120 s
energy is converted into potential
Average speed energy. Also, the potential energy is
Total dis tance travelled directly proportional to the height.
= When kinetic energy is reduced to 70%,
Total time taken
the potential energy is 30%. It will
57000 happen at a height of 30 m.
= = 18.3 m / s
3120
CHEMISTRY
36. (A) Forces are represented by vectors and
can be added and subtracted. 41. (C) As there are three electrons in the
Therefore, an 8 N force to the left added valence shell of group 13 elements they
to a 20 N force to the right yields a net show + 3 oxidation state. Also in case of
force of 20 8 = 12 N to the right. Then heavier members, due to inert pair
Newtons second law gives a = Fnet/m = effect, + 1 oxidation state is most
(12 N to the right) / (4kg) = 3 m/s2 to the stable.
right.
42. (B) Mass of one mole of the oxide
37. (A) The work done on the crate by the mover
is W = Fd = (300 N) (6 m) = 1,800 J. If 100
= × 14 g
this much work is done in 20 s, then the 30.4
power delivered is P = W/t = (1,800 J) ∴Density of the oxide relative to O2
/ (20 s) = 90 W.
(100 / 30.4) × 14
= = 1.44
32
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43. (A) Hydrogen has ionization enthalpy value 49. (D) The reaction in which change in
which is too high as compared to alkali oxidation numbers of some of the
metals and too low as compared to atoms takes place is termed as a redox
halogens and thus cannot be placed in reaction.
any of these two groups.
(a) +2+62 4+1 +2 31 +62
44. (D) Average kinetic energy of methane CuSO" + 4NH! → [Cu(NH!)"]SO"
3 RT No change in oxidation number of any
molecule = ×
2 NA of the atoms.
(b) +1 +62 +21 +2+62 +21
3 8.314 J K −1 mol−1 × 300 K
= × Na SO" + BaCl → BaSO" + 2NaCl
2 6.023 × 1023 molecule mol−1
No change in oxidation number of any
εk = 6.21 × 1021 J molecule1 one of the atoms.
Total kinetic energy of 32 g methane (c) +42 +22 +1+42
SO2 + H2O → H2SO3
3 w 3
=n× RT = × RT No change in oxidation number of any
2 M 2
one of the atoms.
32 g 3 (d) +2 +62 +11 +11 +1 +62 0
= × × 8.314 J K −1 mol−1 × 300 K 2CuSO" + 4KI → Cu I + 2K SO" + I
16 g / mol 2
Oxidation number of Cu decreases from
= 7482.6 J +2 to+1 and oxidation number of iodine
45. (C) In (iii), H2O donates a proton and in (iv), increases from 1 to 0.
H2O accepts proton. Thus, out of the above four reactions,
46. (B) The electronic configurations of these the reaction given in option (D) is a
elements are redox reaction.
V : 1s2 2s2 2p6 3s2 3p6 3d3 4s2 50. (C) The process given in option (C) cannot
go by itself after initiation.
Cr : 1s2 2s2 2p6 3s2 3p6 3d5 4s1
51. (D) Dipole moment corresponding to 100%
Mn : 1s2 2s2 2p6 3s2 3p6 3d5 4s2 ionic character of KCl
Fe : 1s2 2p2 2p6 3s2 3p6 3d6 4s2 = 1 unit charge × Interionic distance
In the case of chromium, the second between K+ and Cl
electron has to be removed from the = (1.602 × 1019 C) (2.6 × 1010 m)
half-filled d-shell which is more stable. = 4.1652 × 1029 C m
47. (C) The weights of oxygen which combine Actual dipole moment of KCl = 3.336
with the fixed weight of nitrogen (= 28 ×1029 C m
g) in N2O, NO, N2O3, N2O4 and N2O5 are
Percentage of ionic character
16, 32, 48, 64 and 80 g respectively.
They are in the ratio 1 : 2 : 3 : 4 : 5. This 3.336 × 10−29 C m
= × 100 = 80.1
proves the law of multiple proportions. 4.1652 × 10 −29 Cm
48. (B) The anion is HCO 3 which gives the Thus, the percentage of ionic character
reaction as follows: in KCl is 80.1
2NaHCO3− + MgCl2 → Mg(HCO3 )2 + 2NaCl 13.6
52. (B) En = − eV, ∆E = E2 − E1
∆ n2
Mg(HCO3 )2 → MgCO3 + CO2 + H2O
White ppt.
⎛1 1⎞ 3
= −13.6 ⎜ 2 − 2 ⎟ = 13.6 × = 10.2 eV
⎝2 1 ⎠ 4
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53. (D) Higher the values of a higher is the 58. (D) Closing the schools for a week and the
critical temperature. parents withdrawing their wards from
54. (B) pH of buffer remains almost constant. the local schools are independent
issues, which must have been triggered
55. (C) Mg burns in air to form Mg3N2 which
by different individual causes.
then reacts with H2O to form NH3.
THE END
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