MAINS CHEMISTRY QUESTION BANK

1. Which of the following compounds show geometrical isomerism

i) [Co( NH 3 )4 Cl2 ] ii) [Co(en) 2 Cl2 ] iii) [ Pt ( gly ) 2 ] iv) [Co(en)3 ]3

1) i,ii and iii 2) ii, iii and iv 3) i, iii and iv 4) i, ii,iii and iv

2. 25ml of H 2O 2 on treatment with excess of acidified KI solution liberates iodine.

Liberated iodine requires 40ml of 0.4N Na 2 S 2O3 solution. The volume strength of
H 2O 2 solution is

1) 1.344 2) 3.584 3) 0.64 4) 1.584

3. The osmotic pressure of 0.1M solution of MgCl2 at 300K is 4.92atm. The percentage
ionization of the salt is

1) 20% 2)39% 3)49% 4)69%

4. The Gibb’s Energy for the decomposition of Al2O3 at 5000C is as follows

2 4
Al2O3 
 Al  O2 ;  r G  965KJ / mole
3 3

The potential difference needed for electrolytic reduction of Al2O3 at 5000C is at least

1) 2.5V 2) 3V 3) 4.5V 4) 5.0V

5. An impure sample of NaCl weighing 2 grams was dissolved in water and excess of
AgNO3 solution was added. The weight of precipitate formed was 0.287g. The
percentage purity of the sample is

1) 11.7% 2) 5.85% 3) 25% 4) 2.85%

6. The density of an ionic crystal is 2.75g cm 3 and edge length of unit cell is 660 pm. The
formula weight of ionic compound is 119. The number of unit cells present in 23.8 g of
the ionic compound is

1) 1.2046 10 23 2) 3.01110 22 3) 6.023 10 22 4) 1.2046 10 22

7. An organic compound has 14% of nitrogen. It is subjected to kjeldahl’s method and the
ammonia evolved is absorbed in 100ml of normal sulphuric acid. About 400ml of water
 N
was added. And 20 ml of this new solution now required 16ml NaOH for complete
5
neutralization. Calculate the original weight of the organic compound taken.

1) 20 gm 2) 1.4 gm 3) 4 gm 4) 2 gm

8. The number of monochloro derivatives that the compound ‘D’ can give

H O , H  Ca drydistillation Zn  Hg , HCl
CH 3CN 
3  A  B 
 C  D

1) 3 2) 4 3) 2 4) 1

9. If H, D, He atoms are travelling with same velocity, the ratio of their deBroglie
wavelength is

1) 1: 1: 1 2) 1: 2: 4 3) 2: 1: 4 4) 4: 2: 1

10. For the decomposition of PCl 5  g  in a closed vessel, the degree of dissociation is ‘x’ at
a total pressure ‘P’.

PCl 5  g  PCl 3  g   Cl 2  g  ; Kp

Which among the following relations is correct?

Kp Kp  P 1
1) x  2) x  3) x  K p  P 4) x 
Kp  P Kp Kp  P

11. Observe the following statements

a) The almost identical radii of Zr and Hf is consequence of Lanthanide contraction

b) Eu 2 act as a strong reducing agent

c) An alloy of lanthanoid metal called misch metal is used in making bullets

d) Actinoid contraction is greater from element to element than lanthanide contraction.

The correct statements are

1) a, b, c 2) a, b, c, d 3) b, c, d 4) a, c, d

O2
12. Ore  CN   H 2O  Zn
 X  Y  metal . X and Y in this reaction is
  2 2 2
1) X   Ag  CN  2  ; Y   Zn  CN  4  2) X   Ag  CN  4  ; Y   Zn  CN  4 
       

 2
3) X   Au  CN  2  ; Y   Zn  CN  4  4) 1 and 3
   

13. In which of the following pair of compounds, the first compound have more
dipolemoment than the second one.

1) NF3 , NH3 2) m-dichloro benzene, o- dichloro benzene

3) H 2 S , H 2O 4) CH3Cl , CHCl3

14. The pH of a sample of KOH solution is 12.6990. The weight of solute required to
prepare 5 lit of the solution is

1) 14g 2) 56g 3) 28g 4) 11.2g

15. Which of the following fibre is of polyamides?

1) Dacron 2) Orlon 3)Nylon 4) Rayon

16. Which among the following are correct statements

a) Order of O  O bond length is O 2  AsF6   O 2  KO 2

 

b) Though Ethylalcohol and Dimethyl ether have same molecular weights, Dimethyl
ether is more volatile than Ethylalcohol.

c) The order of bond order is N 2  N 2  N 22

d) Ice has more density than water

1) a, b, d 2) a, b, c 3) a, c, d 4) a, b, c, d

17. The correct order of coagulation power of different ions is

1) Al 3  Ba 2  Na 

4
2) Cl   SO 4 2  PO 4 3   Fe  CN  6 
 

4
3)  Fe  CN  6   PO 4 3  SO 4 2  Cl 
 
 4) Al 3  Ba 2  Na 

18. A salt ‘X’ on heating liberate one coloured gas and another coloureless gas. Both the
gases are paramagnetic. The salt ‘X’may be

1) NaNO3 2) KNO3 3) Na2CO3 4) LiNO3

19. Compressibility factor for H 2 behaving as real gas is

 a   Pb  RTV
1) 1 2) 1  3) 1  4)
 RTV   RT  1  a 
20. In which of the following arrangements the order is not according to the property
indicated against it ?

1) O 2  F   Na   Mg 2  Al 3 (ionic radii)

2) F  Cl  Br  I (Electron gain enthalpy)

3) B  C  O  N (First ionization enthalpy)

4) SiO2  P2O5  SO3  Cl 2O7 (acidic nature)

21. The composition of a sample of Ion oxide is Fe0.93O1.0 . The percentage of iron present
in the form of Fe3 is

1) 85% 2)15% 3) 12% 4) 76%

22. 93.75% of a I order reaction is completed in 120 minutes. If initial concentration of the
reactant is 2 mole/lit, the rate of reaction at the end of 120 min is

1) 4.62 10 2 M min 1 2) 2.3110 3 M min 1

3) 2.88 10 3 M min 1 4) 6.93 10 4 M min 1

23. Which of the following is wrong statement.

1) I 2O5 is a very good oxidizing agent and is used in the estimation of carbon monoxide.

2) ClO 2 is used as bleaching agent for paper pulp and textiles.

 3) When HCl reacts with finely powdered iron, it forms ferrous chloride and not ferric
chloride.

4) The inter halogen compound XX 1 hydrolysis as follows.

XX 1  H 2O  HX  HOX 1 [when X = larger halogen]

24. Which of the following is wrong

1) H 3BO3 is monobasic and Lewis acid

2) H 3BO3 is tribasic and Lewis acid

3) In solid state of orthobenzoic acid, B(OH )3 units are hydrogen bonded together into
two dimentional sheets.

4) Aqueous solution of Borax acts as a Buffer solution.

25. An organic compound (A ) with molecular formula C8 H8O forms an orange-red

precipitate with 2,4  DNP and gives yellow precipitate on heating with iodine in
presence of NaOH . It neither reduces tollen’s or Fehling’s reagent nor does it
decolourise bromine water or Bayer’s reagent. On drastic oxidation with chromic acid it
gives carboxylic acid having molecular formula C7 H 6O2 . Then A and B are

1) C6 H5COCH3 , C6 H5COOCH3

2) C6 H5CH 2CHO, C6 H5COOH

3) C6 H5CH 2CHO, C6 H 4CH 2OH

4) C6 H5COCH3 , C6 H5COOH

26. An aldehyde, (P) which does not undergo self aldol condensation gives benzaldehyde and
two moles of (Q) on ozonolysis. Compound ( Q), on oxidation with silver ions gives
oxalic acid. The structure of ( P) is given as

CH  CH  CH  CH  CH 2CHO CH  CH  CH  CH  CHO

1) 2)
 O
C  C  CHO
CH  CH  C  CHO
3) 4)

27. The product of the following I and II sequence are related as

(i) H2/Pd/CaCO3 (ii) Br2/CCl4

?
(I)
CH3 C C CH3
(II) (i) Br2(1 eq.)/ CCl4 (ii) H2 / Pd
?
1) Diastereomers 2)Identical
3) Enantiomers 4) Geometrical isomers

28. Which of the following sequence of reagent is the good means to furnish the conversion ?

R  CH 2OH 
 R  CH 2 NH 2

(a) KMnO 4 , SOCl 2 , NH 3, , NaOBr

(b) SOCl 2 , NaCN , H 2 / Ni

(c) CrO 3 in dilute acetone, NH 3, H 2 , Ni

(d) Cu,300 0 C, NH 3, LiAlH 4

1) a, b, c, d 2) a, b, c 3) b, c, d 4) c, d

29. Consider the following statements:

a) Keratin & Myosin are fibrous proteins

b) Deficiency of vitamin C causes disease bleeding gums (scurvy)

c) D-glucose and D- mannose are C-2 epimers.

d) Fructose does not reduse fehling solution

Which of the given statements are correct

1) a, c. d 2) a, b, d 3) a, b, c 4) a, b, c, d
30. The correct order of stability of following carbanions

I .CH 3 II .C6 H 5CH 2 III .CCl3 IV . CH 3 3 C

1) II > I > III > IV 2) II > III > I > IV

3) III > II > IV > I 4) III > II > I > IV

31. In an experiment 50 mL of 0.1 M solution of a salt reacted with 25 mL of 0.1 M solution

of sodium sulphite. The half equation for the oxidation of sulphite ion is
SO32  aq   H2 O  l  
SO42  aq   2H  aq   2e . If the oxidation number of metal in the
salt was 3, what would be the new oxidation number of the metal?
1) Zero 2) 1 3) 2 4) 4

32. A and B are two allotropes of an element. One gram of A will differ from one gram of B
in
1) oxidation number 2) chemical composition
3) total number of atoms 4) atomic arrangement

33. Which one of the following will most readily be dehydrated in acidic conditions?
O
O

O OH OH

1) 2) 3) OH 4) OH

34. Molecular size of ICl and Br2 is nearly same, but boiling point of ICl is about 40°C
higher than that of Br2 . This might be due to
1) I Cl bond is stronger than Br Br bond
2) ionisation energy of I< ionization energy of Br
3) ICl is polar whereas Br2 is non-polar
4) The size of I > size of Br

35. A mixture of Al  OH 3 and Fe  OH 3 can be separated easily by treating it with

1) HCl 2) NH 4 OH 3) HNO3 4) NaOH

36. What is the end product of the following sequence of operations?

CaC2 
H2 O
 A 
DilH2SO4
Hg2
 B 
Ni
H2
C
1) Methyl alcohol 2) Acetaldehyde
3) Ethyl alcohol 4) Ethylene
37. Two isotopes P and Q of atomic weights 10 and 20, respectively are mixed in equal
amounts by weight. After 20 days, their weight ratio is found to be 1 : 4. Isotope P has a
half – life of 10 days. The half-life of isotope Q is
1) zero 2) 5 days 3) 20 days 4) infinite

38. The crystals of ferrous sulphate on heating give

1) FeO  SO2  H 2 O 2) Fe2 O3  SO3  H 2 O
3) Fe2 O3  SO2  SO3  H 2 O 4) FeO  SO3  H 2SO 4  H 2 O

39. A compound A of formula C3 H 6 Cl2 on reaction with alkali can give B of formula C3 H 6 O
or C of formula C3 H 4 . B , on oxidation gives a compound of the formula C3 H 6 O 2 . C with
dilute H 2SO 4 containing Hg2 ion gives D of formula C3 H 6 O, which with bromine and
NaOH gives the sodium salt of C2 H 4 O 2 . Then A is
1) CH3CH 2 CHCl2 2) CH 2 CCl2 CH3 3) CH 2 ClCH 2 CH 2 Cl 4) CH3CHClCH 2 Cl

40. A substance will be deliquescent if its vapour pressure is

1) equal to the atmospheric pressure
2) equal to that of water vapour in the air
3) greater than that of water vapour in their air
4) lesser than that of water vapour in the air

41. When PCl5 reacts with sulphuric acid, sulphuryl chloride SO2 Cl2  is formed as the final
product. This shows that sulphuric acid
1) is a dibasic acid 2) has great affinity for water
3) has two hydroxyl groups in its structure.
4) is a derivative of sulphur dioxide
 3
Identify X in the sequence, X   C5 H12O   C5 H10
i CH MgCl Cu
42.  ii  H O / H  375 K
2

1) CH 3  C  CH 2CH 3 2) CH3CH 2 CH 2 CH 2 CHO

||
O
3)  CH3 2 CHCHO 4) CH3CH 2CH 2CH 2OH

43. Peptization is a process of

1) precipitating colloidal particles
2) Converting a sol into a gel
3) dispersing a precipitate into colloidal state
4) Removal of impurities of true solution state from a colloid

44. The solubility of noble gases in water shows the order

1) He  Ar  Kr  Ne  Xe 2) He  Ne  Ar  Ar  Xe
 3) Xe  Kr  Ar  Ne  He 4) None of the above

45. The correct order of decreasing acid strength of trichloroaceticacid (A), trifluoroacetic
acid (B), acetic acid (C) and formic acid (D), is
1) A  B  C  D 2) A  C  B  D 3) B  A  D  C 4) B  D  C  A

1
46. For the reaction, N2O5 
 2NO2  O2
2
d  N 2 O5  d  NO2  d O2 
Given,   k1  N 2 O 5   k 2  N 2 O5  ; and  k 3  N 2 O5 
dt ; dt dt
The relation between k1 , k 2 and k 3 , is
1) 2k1  k 2  4k 3 2) k1  k 2  k 3 3) 2k1  4k 2  k 3 4) k1  2k 2  4k 3

1 rd
47. Which one is the most likely structure of CrCl3  6H 2 O , if of total chlorine of the
3
compound is precipitated by adding AgNO3 to its aqueous solution?
1) CrCl3  6H 2 O 2) Cr  H2O 3 Cl3    H2O 3
3) CrCl2  H2 O 4   Cl  2H2O 4) CrCl  H2O 5  Cl2  H2O

48. The product formed in the given reaction is

OCH2CH=CH2


 
CH2CH=CH2 OH
CH2CH=CH2

1) 2)
CH2CH=CH2 OCH2CH=CH2
OH

3) 4)

49. The decomposition of N 2 O 4 to NO 2 is carried out at 280 K in chloroform. When

equilibrium has been established, 0.2 mole of N 2 O 4 and 2  103 mole of NO 2 are present
in a 2 L solution. The equilibrium constant for the reaction, N2O4 2NO2 , is
 1) 1102 2) 2  103 3) 1105 4) 2  105

50. Tests on an aqueous solution of a sodium salt having an anion X n  gave the following
results
K 2 Cr2 O7  H 2SO4 Pb NO   aq 
Anion, X n     Green solution; X n  
3 2

 Black precipitate
Which one of the following could be X n  ?
1) I 2) NO2 3) S2  4) SO24

51. The major products (P&Q) in the given reaction sequence are

  2, i O 
Cl.CH 2CH 2CH 3 
AlCl3
 P 
 ii  H 2O Q  phenol

1) , and CH 3CHO 2) , and CH 3COCH 3

3) , and CH 3COCH 3 4) , and CH3CH 2CH

52. A weak acid HX  K a  1105  on reaction with NaOH gives NaX. For 0.1 M aqueous
solution of NaX, the per cent hydrolysis is
1) 0.001% 2) 0.01% 3) 0.15% 4) 1%

Pt  H 2  || H  1M  H  1M  |  H 2  Pt
53. The given cell is . The cell reaction will be
p1  atm  p 2  atm 
spontaneous if
1) p1  p 2 2) p1  p 2 3) p 2  p1 4) p1  1atm

54. Glucose gives many reactions of aldehyde because

1) it is hydrolysed to acetaldehyde
2) it is a polyhydroxy ketone
3) it is a cyclic aldehyde
4) it is a hemiacetal in equilibrium with its aldehyde form in solution

55. For a reversible process at T = 300 K, the volume of 2 moles of an ideal gas is increased
from 1 L to 10 L. The H for isothermal change is
1) 11.47 kJ 2) 4.98 kJ 3) 0 4) 11.47 Kj
56. The molecular formula of diphenyl methane CH2

is C13 H12 . How many structural isomers are possible when one of the hydrogens is
replaced by a chlorine atom?
1) 6 2) 4 3) 8 4) 7

57. Bases common to DNA and RNA are

1) adenine, cytosine, uracil 2) guanine, adenine, cytosine
3) guanine, uracil, thymine 4) adenine, thymine, guanine

58. Na  ion is smaller in size than Na atom .Correct statement among the following is
1) nucleus in each case contains different nucleons
2) sodium atom has an electron less than the sodium ion
3) sodium atom has 11 electrons while sodium ion has 10 electrons with same nuclear
positive charge
4) the force of attraction is less in Na  ion than in Na atom

59. The optically active tartaric acid is named as D     tartaric acid because it is
1) dextro rotatory and derived from D-glucose
2) dextro rotatory and so it has D-configuration
3) dextro rotatory and derived from D     glyceraldehyde
4) dextro rotatory when substituted by deuterium

60. Of the following which is a step-growth polymer?

1) Bakelite 2) Polyethylene 3) Teflon 4) PVC

61. A tetra atomic molecule (A) on reaction with nitrogen(I)oxide, produces two substances
(B) and (C). (B) is a dehydrating agent. While substance (C) is a diatomic gas which
shows almost inert behaviour. The substances (A) and (B) and (C) respectively will be
1) P4, P4O10, N2 2) P4, N2O5, N2 3) P4, P2O3, Ar 4) P4, P2O3, H2

62. The IUPAC name of the compound

Cl CH 2CH 3
C C
H 3C I
is

1) E-2-choloro-3-iodopent-2-ene

2) Z-2- choloro-3-iodopent-2-ene
 3) E-3-iodo-4-chloropent-3-ene

4) Z-3-iodo-4-choropent-3-ene

63. A real gas is supposed to abey the gas equation P  v  b   nRT at STP if one mole of a
gas occupies 25 dm3 volume at STP, calculate diameter of each gas molecule.

1) 1.27 108 cm 2) 1.27 106 cm 3) 4.56 108 cm 4) 4.56 106 cm

64. The enthalpies of hydration of Ca 2 , Mn2 and Zn2 follow the order

1) Mn2  Ca 2  Zn2 2) Zn2  Ca2  Mn2

3) Mn2  Zn2  Ca 2 4) Zn2  Mn2  Ca 2

65. The absolute configuration of

HO2C CO2 H

HO OH
H H
is

1) S,R 2) S,S 3) R,R 4) R,S

66. A stationary He  ion emitted a photon corresponding to the first line  H  of the lyman
series. That photon liberated a photon electron from a stationary H-atom in ground state.
What is the kinetic energy of that electron?

1) 2.36 1018 Joul 2) 4.36 1018 Joul

3) 4.36 1016 Joul 4) 2.36 1016 Joul

67. If a mixture of NaCl, conc. H 2 SO4 and K 2Cr2O7 is heated in a dry test tube. A red
vapour(P) is formed. This vapour(P) dissolves in aqueous NaOH to form a yellow
solution.Which upon treatment with AgNO3 forms a red solid (Q). P and Q are
respectively .

1) CrO2Cl2 and Ag2Cr2O7 2) Na2 [CrOCl5 ] and Ag2CrO4

3) Na2 [CrOCl5 ] and Ag2Cr2O7 4) CrO2Cl2 and Ag2CrO4

68. Amongst the following compounds

 O
O OH
CHO
CHOH
O CH 2OH CHO
(I ) ( II ) ( III ) ( IV )

1) I,III,IV are stereoisomers 2) I,II are tautomers

3) III,IV are positional isomers 4) I,IV are tautomers

69. Rate of diffusion of ozonized oxygen is 0.4 5 times that of pure oxygen what is
percentage of degree of association of oxygen assuming pure O2 in the sample initially

1) 20 2) 40 3) 60 4) none of these

70. Number of anti bonding electrons in N2 is

1) 4 2) 10 3) 12 4) 14

71. Which of the following compound is most reactive towards catalytic hydrogenation?

1) H 2C  CH 2 2) H3C  CH  CH 2

H 3C CH 3 H 3C CH 3

C C C C
H H H 3C CH 3
3) 4)

72. For a first order homogeneous gaseous reaction A  2B  C of the total pressure after
time ‘t’ was Pt and after long time t   was P then k in terms of Pt , P , and ' t ' is

2.303  P  2.303  2 P 
1) k  log   2) k  log  
t  p  pt  t  p  pt 

2.303  2 P  2.303 2 P
3) k  log   4) k  log
t  3  p  pt   t 2 p  pt

73. Among the following donors the one that forms most stable adduct with the Lewis acid
B(CH 3 )3 is

1) 4-methyl pyridine 2) 2,6-dimethyl pyridine

3) 4- nitro pyridine 4) 2,6-di-tert-butyl pyridine

74. In the following carbocation, H/CH3 that is most likely to migrate to the positively
charged carbon is

H H
1 + 5
CH 3 2C 3C  C  CH 3
4
HO H CH 3

1) CH3 at C-4 2) H at C-4 3) CH3 at C-2 4) H at C-2

75. The P H of the resultant solution of 20 mL of 0.1 M H3 PO4 and 20 mL 0.1 M Na3 PO4 is

P ka1  P ka2
1) P ka1  log 2 2) P ka1 3) Pka2 4)
2

76. The correct order of tri positive ionic radius of Ce, Sm, Tb, Lu is
1) Ce>Sm>Tb>Lu 2) Lu>Tb>Sm>Ce
3) Tb>Lu>Sm>Ce 4) Sm>Tb>Lu>Ce

77. In the reaction

(C )
CH 3  CH  CH 3   ( A)    ( B ) 
Alc . KOH HBr NaI
Peroxide Acetone

Br , The compound C
is

CH 3  CH  CH 3 CH 3  CH  CH 2 I

1) CH3  CH 2  CH 2 I 2) I 3) I 4) CH3  CH  CHI

78. 108 g of fairly concentrate solution of AgNO3 is electrolyzed using 0.1 F of electricity
the weight of resulting solution is

1) 94 g 2) 11.6 gm 3) 96.4 gm 4) none of these

79. The reaction of ammonium chloride with BCl3 at 1400 C followed NaBH 4 gives product
X. Which of the following statements is/are true for X?
(i) X is not isoelectronic with benzene.
(ii) X undergoes addition reactionwith HCl
(iii) X is isostructural with Graphite
(iv) X undergoes polymerization at 900 C .
1)(i) and (ii) 2) (ii) only 3) (ii) and (iii) 4) (i) and (iv)

80. Which one of the following will most readily be dehydrated in basic condition?
 O OH OH

1) 2)

O O

3) OH 4) OH

81. When 36.0 gm of a solute having the empirical formula CH 2O is dissolved in 1.20 kg of
water the solution freezes at 0.930 C what is the molecular formula of the solute
K f  1.860 C kg / mol 

1) C2 H 4O 2) C2 H 2O2 3) C2 H 4O3 4) C2 H 4O2

82. The structures of the complexes Cu  NH 3 4  (ClO4 )2 and Cu  NH 3 4  (ClO4 ) in the
solution respectively are

1)Square planar and tetrahedral

2) Octa hedral and square pyramidal
3)Octahedral and trigonal bipyramidal

4) Tetra hedral and square planar

83. O on reaction with methanol in presence of acidic medium gives majorly

OCH 3
OCH 3
OCH 3

CH 3 OCH 3
1) O 2) O 3) O 4) O

84. The percentage of oxalate ion in a given sample of oxalate salt of which 0.3 g dissolved
N
in 100 ml of water required 90 ml of KMnO4 solution for complete oxidation.
20

1) 66 2) 19.8 3) 6.6 4) 1.98

85. The ionic conductivity of aqueous alkali metal cations at a given concentration follow the
following order
1) Li   Na   K   Rb  2) Li   Na   K   Rb 
 3) Li   Na   K   Rb  4) Li   Na   K   Rb 


CH 2 NH 2
 A 
NaOH

B
86.

‘A’ and ‘B’ in the above reaction are respectively

O O
O
CH 3

, ,
1) 2)
O
O O

, O

,
3) 4)

87. Graph between log  x / m and log p is a straight line at angle 450 with intercept OA as
shown in figure. Then  x / m  at a pressure of 2 atm is

A 450

x
log  
m log 2

O log p

1) 2 2) 4 3) 8 4) 1

88. In the froth flotation process, pine oil

1) increases the surface tension of the solution.

2) decreases the surface tension of the solution.

3) does not affect the surface tension of the solution.

4) acts as a depresent.
 
C4 H 6O4   C3 H 6O2 
soda lim e

 C2 H 6
89.  A  B

The compound  A is

CH 2 COOH

CH3  CH  COOH 2 CH 2 COOH

2)
1)

3) Both are correct 4) none is correct

90. The acid ionization (hydrolysis) constant of Zn2 is 1109 then calculate pH of
103 M ZnCl2 solution.

1) 6 2) 5 3) 4 4) 5.5

91. The volume strength of 1.5N H2O2 solution is

1) 4.8 2) 8.4 3) 3.0 4) 8.0

Br

Mg CO H O

 A 
2  B 
2 C
92. . What is C in the above conversion

CONH 2 COOH CHO

1) 2) 3) 4)
93. How many electrons in an atom with atomic number 105 can have (n + l ) =8

1) 30 2) 17 3) 15 4) 20

94. The hybridisation of the central atoms in the following species is

 2
 PtCl4 2 ,  Ni CN 4  3
,  Fe(CN )6  ,  NiCl4 
2

1) dsp2, sp3, dsp3, dsp2 2) sp3, sp3, dsp2, d2sp3

3) dsp2, dsp2, d2sp3, sp3 4) dsp2, d2sp3, dsp2, sp3

95.

CH 3

Br2 Sn / HCl NaNO2 / HCl H 2O K M nO

  A   B   C  D   

4 E
273 278 K H 3 PO2 OH

NO2

What is E ?

1) 2-bromobenzoic acid 2) 1- bromobenzoic acid

3) 4 -bromobenzoic acid 4) 3 -bromobenzoic acid

96. What transition in the hydrogen spectrum would have the same wavelength as the Balmer

transition n =4 to n = 2 of He+ spectrum ?

1) n1=1 to n2=2 2) n1=2 to n2=4 3) n1=1 to n2=3 4) n1=2 to n2=3

97.

OH
( NH 3 )4 Co Co ( NH 3 )2 Cl2 SO4
OH and
OH
Cl ( NH 3 )3 Co Co ( NH 3 )3 Cl SO4
OH

1) Ligand isomers 2) Coordinate position isomers

3) Ionsation isomers 4) Coordinate isomers

98. Which of the following is / are aromatic in character ?
 +

+
(I) (II) (III) (IV)
1) II only 2) I and II 3) III and IV 4) I, II, III and IV
99. The vander wall's equation for CH4 at low pressure is

a a
1) PV=RT - Pb 2) PV  RT  3) PV = RT+ 4) PV = RT +Pb
V V
100. An ideal gas is taken around the cycle ABCA shown in the P - V diagram below. The net
work done by the gas during the cycle is equal to

B
4P1
P
P1 C
A

V1 3V1
V

1) 12 P1V1 2) 6 P1V1 3) 3 P1V1 4) P1V1

101. Decreasing - I power of given groups is

a) CN b) NO2 c) - NH2 d) F

1) b > a > d > c 2) b > c > d > a 3) c > b > d > a 4) c > b > a > d


102. In the formation of N 2 from N2 the electron is removed from

3)  orbital 4)  orbital
* *
1)  orbital 2)  -orbital
103. For an ideal gas reaction 2A + B C + D the value, of Kp will be

n n V n n V
1) K p  C D . 2) K p  C D .
n2AnB RT 2 n 2AnB RT

n n RT nC nD V
3) K p  C D . 4) K p  .
n 2AnB V 4n2AnB RT
104. The volume of 0.3M NH4OH that should be mixed with 30 ml of 0.2 M solution of

NH4Cl to give buffer solution of pH 8.65 ( P kb  4.75 )

1) 10 ml 2) 20 ml 3) 5 ml 4) 15 ml
105. Which of the following combinations is correctly matched ?

H
|
1) H 3C  C  Cl , SN walden inversion
2
|
D

H
|
2) H 3C  C  Cl , SN walden inversion
1
|
D

C2 H5
|
3) C6 H 5  C  Cl , SN 1 , only retention
|
CH3

C2 H5
|
4) C6 H 5  C  Cl , SN 1 , only inversion
|
CH3

106. With which of the following diborane liberates dihydrogen gas ?

 I = H2O II = NH3 at 120° III = CO IV=NH3 at above

200°c

1) II, III only 2) II, III, IV only 3) I, IV only 4) II, IV only

107. The solubility A2B3 is x mol dm-3. Its Ksp is

1) 6x4 2) 64x4 3) 36x5 4) 108x5

108. The number of unit cells in 1 gram of NaCl are

1) 1.28  10 21 2) 2.56 1023 3) 2.56 1021 4) 1.28 1023

109. IUPAC name of the compound

CH 3  CH 2  CH 2  CH  CH 2  CH 2  CH  CH 3
| |
CH CH3 CH 3
|
CH3

1) 2-methyl -5-isoprophyl octane 2) 2, 6 -dimethyl -3- propylheptane

3) 5- methyl -2- isoropyl octane 4) 5- isopropyl -2-methyloctane

110. The van't Hoff factor for 0.1 M Al2(SO4)3 solution is 4.2. The degree of dissociation is

1) 80% 2) 90% 3) 78% 4) 83%

111. Coal gasification involves

1) production of 'syngas' from sewage

2) Synthesis of methanol from water gas

3) Producing 'syngas' from coal

4) Producing dihydrogen by the water gas shift reaction

112. Equimolal solutions A and B show depression in freezing point in the ratio 2:1. A

remains in the normal state in solution. B will be

1) Normal in solution 2) Dissociated in solution

3) Associated in solution 4) Hydrolysed in solution

113. Denaturation of protein doesnot disturb ___ structure

1) Quaternary 2) Secondary 3) Primary 4) Tertiary

E  0.44V ; E  0.77V
114. Given that Fe2  / Fe Fe2  / Fe3 . If Fe2+, Fe3+ and

Fe solid are kept together, then

1) Fe3+conc increases

2) Fe3+conc decreases

3) Fe2+, Fe3+ conc remain unchanged

4) Fe2+ conc decreases

115. When electricity is passed through a solution of AlCl3 and 13.5g of Al is deposited, the

number of faraday must be

1) 0.5 2) 1.0 3) 1.5 4) 2.0

116. The non-essential amino acid among the following is

1) Valine 2) Leucine 3) Histidine 4) Glutamic acid

117. Rate law for 2A  B  C  D from following data :

S.NO. [A] (M) Rate (M/s) Rate (M/s)

 1 0.01 0.01 2.5

2 0.01 0.02 5

3 0.03 0.02 45

1) r  K  A  B 2) r  K  A B  3) r  K  A  B  4) r  K  A  B
1/3 1/3 2 2/3 1/3

118. 'x' and 'y' are monomers used in the preparation of biodegradable polymer of Nylon-2-
Nylon - 6. What are 'x' and y ?

1) Caprolactam, hexamethylene diamine

2) Glycine,  -hydroxy valeric acid

3) Ethylene glycol, pthalic acid

4) Glycine, aminocaproic acid

119. In a first order reaction, the concentration of the reactants is reduced to 25% in one hour.
The half life period of the reaction is

1 1
1) 2 hr 2) 4 hr 3) hr 4) hr
2 4

120. 0.25 g of an organic compound gave 22.4 ml of N2 at STP by Duma's method. The

percentage of nitrogen in the compound is

1) 15% 2) 28% 3) 11.2% 4) 14%

121. A mixture of NaOH and Na 2CO3 required 25 ml of 0.1M HCl using phenophthalein as
the indicator. However the same amount of the mixture required 30 ml of 0.1 M HCl
when methyl orange was used as indicator. The molar ratio of NaOH and Na 2CO3 in the
mixture was

1) 2 : 1 2) 1 : 2 3) 4 : 1 4) 1 : 4

122. An electron in a hydrogen atom in its ground state absorbs 1.5 times as much energy as
the minimum required for it to escape from the atom. What is the velocity of emitted
electon ?

1) 1.54´ 106 m / s 2) 1.54´ 108 m / s 3) 1.54´ 103 m / s 4) 1.54´ 104 m / s

123. Tautomerism is not exhibited by

1) 2) 3) 4)

124. Under identical conditions of pressure and temperature, 4 litres of gaseous mixture
 H2 and CH4  effuses through a hole in 5 minutes where as 4 litres of a gas 'X' of
molecular mass 36 takes to 10 minutes to effuse through the same hole. The mole ratio
of H 2 :CH 4 in the mixture is

1) 1 : 2 2) 2 : 1 3) 2 : 3 4) 1 : 1

125. CsBr has bcc type structure with edge length 4.3 pm. The shortest inter ionic distance in
–
between Cs and Br is

1) 3.72 pm 2) 1.86 pm 3) 7.44 pm 4) 4.3 pm

126. Which of the following is least stable

CH 2

1) Me O CH 2 2) CH 2 3) PhCH 2 4)
OMe

127.On adding AgNO3 solution into KI solution a negatively charged colloidal sol is obtained
where they are in

1) 50 ml of 0.1M AgNO3 + 50 ml of 0.1M KI

2) 50 ml of 0.1M AgNO3 + 50 ml of 0.2M KI

3) 50 ml of 0.2M AgNO3 + 50 ml of 0.1M KI

4) None
128. In the following reactions, which of the following step is wrong?
NO2 NO2
NO2

Con.HNO3 CH 3COC
NaOH+I2
Con.H2SO4 AC 3 +CHI3
C CH3
COONa
Step-I Step-II O Step-III

1) Step I 2) Step II 3) Step III4) Step I and II

129. The ground state electronic configuration of the elements A, B, C, D and E (symbols
have no chemical significance) are as follows.

A – 1s 2  2s 2  2p6 3s 2 3p5   B – 1s 2  2s 2  2p6 3s1

C – 1s 2  2s 2  2p6  3s2  3p6 4s1 D – 1s 2  2s 2  2p6  3s 2  3p 6  3d 5  4s 2

E – 1s2
Determine which sequence of elements satisfy the following statements ?

i) Element forms a carbonate which is not decomposed by heating.

ii) Element is most likely to form coloured ionic compounds.

iii) Element has largest atomic radius.

iv) Element forms acidic oxide.

1) B, C, E, A 2) B, D, E, C 3) B, C, E, D 4) B, D, C, A

MgBr
130. ¾ 1)¾CH ¾ ¾ ® (A) ¾ HBr
3 - CHO
2) H O+
¾ ® (B) . The compounds (A) and (B) are
3

Me Me
Me Me
1) Br 2) Br
OH OH

Me Me
Me Me
3) 4)
OH OH Br
OH

131. N 2 and O 2 are converted to mono cations N2 and O2 respectively, which is wrong
statement ?
 1) In , N2 the N – N bond weakens

2) In , O2 the O – O bond order increases

3) In , O2 the paramagnetism decreases

4) N2 becomes diamagnetic

132. The freezing point of a solution containing 0.2 gr of acetic acid in 20 grams of benzene
is lowered by 0.450C . Calculate the degree of dimerisation of acetic acid in benzene.
K f for benzene is 5.12 K mol –1 Kg .

1) 0.527 2) 0.80 3) 0.945 4) None

Me
O excess of
Me Me HI
A B

133. Me The products (A) and (B) are

Me
Me
I
OH
1) Me Me
and

Me
Me
2) HO
I
Me and Me

CH3
|
3) I and CH 3 CH 2 C I
Me |
CH3

4) All

134. The magnetic moments (spin only) of complexes given below are in the correct order.
2- 2+
I) éêNi (CN)4 ù IV) éêNi (H 2O)6 ù
2-
ú II) [NiCl 4 ] III) Ni (CO)4 ú
ë û ë û
 1) I > II > III > IV 2) I < II < III < IV

3) IV = II > I = III 4) IV < II < I < III

135. Equivalent conductivity of BaCl2 , H 2SO4 and HCl are x1 , x 2 and x3 S cm2 equ –1  at
infinite dilution. If conductivity of saturated BaSO4 solution is x S cm–1 , then K sp of
BaSO4 is

500 x 106 x 2
1) 2) 3
(x1 + x 2 - 2x 3 ) (x1 + x 2 - 2x 3 )

2.5´ 105 x 2 0.25 x 2

3) 2
4) 2
(x1 + x 2 - x 3 ) (x1 + x 2 - x 3 )
136. On treatement of acetone with dilute Ba  OH 2 , the product formed is

1) 4-hydroxy 2-pentanone

2) Phorone

3) Propionaldehyde

4) 4 – hydroxy – 4 – methyl – 2 – pentanone

137. In the extraction of copper, metal is formed in the Bassemer converter due to the reaction

1) Cu 2S + 2Cu 2O ® 6Cu + SO2 2) Cu 2S ® 2Cu + S

3) Fe + Cu 2O ® 2Cu + FeO 4) 2Cu 2O ® 4Cu + O2

138. To avoid the precipitation of hydroxides of Ni 2 , Co2 , Zn 2 and Mn 2  along with

3 3 3
those of Fe , Al , Cr the third group solution (in qualitative analysis) should be

1) Heated with few drops of concentrated HNO3

2) Treated with excess of NH4Cl

3) Concentrated

4) Made alkaline
139. K p has the value of 10–6 atm3 and 10–4 atm3 at 298 K and 323 K respectively for the
reaction , CuSO4 .3H2O(s) ƒ CuSO4(s) + 3H 2O(g) D r H0 for the reaction is

1) 7.7 KJ/mol 2) – 147.41 KJ/mol 3) 147.41 KJ/mol 4) – 32.5 KJ/mole\

-
2( )
SOCl or
140. PhMe ¾ KMnO
¾D ¾ ¾¾
4 /OH
+ ® (B)¾ ¾PC¾
l5
¾® (C)¾ PhCOONa
¾¾¾ ® (D) Compound (D) is
, H3O

1) PhCOCl 2) PhCONH 2 3) PhCOOH 4)  PhCO 2 O

141. Metal M + air ¾ D¾® A ¾ H¾¾

2O
® B ¾ HC
¾ l¾
® white fumes. Metal 'M' can be
1) Li, Mg (or) Al 2) Li, Al (or) K

3) Na, K (or) Mg 4) Li, Na (or) K

142. The units of rate of reaction and rate constant are same for a

1) Zero order reaction 2) First order reaction

3) Second order reaction 4) Third order reaction

143. A compound (X) has the molecular formula C7 H 7 NO on treatment with Br2 and KOH,
(X) gives an amine (Y), (Y) gives carbylamine test. (Y) upon diazotization and coupling
with phenol gives azodye (Z). then 'X' is

1) PhCONH 2 2) PhCONHCOCH3

3) PhNH 2 4) PhCOONH4

144. Na 2 B 4O7 .10H2O ¾ Heat

¾¾ ® X + NaBO2 + H2O

X + Cr2O3 ¾ D¾® Y (green coloured)

X and Y are

1) Na 3BO3 and Cr(BO2 )3 2) Na 2 B4O4 and Cr(BO2 )3

3) B2O3 and Cr(BO2 )3 4) B2O3 and CrBO3

145. What is the molar solubility of Fe  OH 2 (Ksp = 8´ 10- 16 )at pH  13.0

1) 8´ 10- 18 2) 8´ 10- 15 3) 8´ 10- 17 4) 8´ 10- 14

146. The monomers of melamine polymer are

1) 2, 4, 6 - triamino -1, 3, 5, -triazine and HCHO

2) 2, 4, 6 - diamino 1, 3, 5 - triazine and CH3  – CHO

3) 2, 4 - diamino 1, 3, 5 - triazine and HCHO

4) 2, 4 - diamino 1, 3, 5 - triazine and CH3  – CHO

147. Which of the following species is / are formed when concentrated HNO3 is added to
concentrated sulphuric acid.

I) NO-3 II) NO+2 III) NO-2 IV) HSO-4

1) I, II 2) II, IV 3) III, IV 4) II, III

148. Suppose that a reaction has D H = - 40KJ and D S = - 50J / K . At what temperature
range will it change from spontaneous to non spontaneous?

1) 0.8 K to 1 K 2) 799 K to 800 K

3) 800 K to 801 K 4) 799 K to 801 K

149. Which statements are correct about lactose

1) (C1 - b)(OH)of glucose is linked with (C4 - OH)of galactose

2) (C1 - b)(OH)of galactose linked with  C4  – OH  of glucose

3) It is hydrolysed by both by amyalase and lactase

4) It is a non reducing sugar.

150. The transition metals exhibit higher enthalpies of atomisation due to

1) Their ability to show variable oxidation states

2) The presence of incompletely filled d – sub shell

3) Their ability to exist in the solid state with electron pairs

4) Strong interatomic interactions arise because of having large number of unpaired

electrons in their atoms

151. Arrange the following compounds in order of their increasing boiling points
 (I) Ethanol (II) Propan – 1 – ol

(III) Butan – 1 – ol (IV) Pentan– 1 – ol

1) IV < III < II < I 2) II > III > IV > I

3) I < II < III < IV 4) III > II > IV > I

152. Select the appropriate reaction to prepare the following ether

CH 3
CH3 C OC2H5
CH3

CH 3 CH 3
1) CH3 C Br C 2H 5 O 2) CH3 C O C 2H 5 Br
CH3 CH3

CH3 CH CH2 Br C2H5 O

3) 4) Both (1) and (2)
CH3

153. Choose the correct reaction given below

O
CrO 3 H 2 SO 4
1) CH 3 CH 2 CH 2 CH 2 OH CH 3 CH 2 CH 2 C H

O OH
COCH3 C

2) (i )KMnO 4 /KOH
(ii )H 2 SO 4 (dil )

CH3 CH3

KMnO 4 COOH
3) Heat
COOH
 CH2 OH CH2 Br CH 2 NC

4) HBr KCN

154. Which of the following is incorrect?

1) Monomers of Bakelite are phenol and formaldehyde

2) Monomers of Melamine polymer are Melamine and Formaldehyde

3) Monomers of Buna – N are 1, 3–Butadiene & Acrylonitrile

4) Monomer of neoprene is isoprene

155. Which of the following compounds will show Cis-trans isomerism.

1) (CH3 )2 C = CH - C2H5 2) CH2 = CHBr

3) C6H5 - CH = CH - CH3 4) CH3CH = C (Cl)2

156. When HCl reacts with finely powdered iron, it forms ferrous chloride and not ferric
chloride. Why?

1) Liberation of hydrogen prevents the formation of ferric chloride.

2) FeCl2 acts as reducing agent

3) FeCl3 acts as reducing agent

4) HCl is strong acid

157. What is the magnetic moment of a divalent ion in aqueous solution if its atomic number
is 25.

1) 4.8BM 2) 3.9BM 3) 5.9BM 4) 1.7BM

158. What would be the IUPAC name and symbol for the element with atomic number 120?

1) unbinilium,ubn 2) unnilbium, unb

3) unbibium, ubb 4) unnilnilium , unn

159. Time required to decompose SO2Cl 2 to half of its initial amount is
36 minutes. If the decomposition is a first order reaction, the rate constant of the reaction
is

1) 1.925 10 4 / moles /Sec 2) 1.925  10 2 / min

3) 1.925  10 4 / min 4) 1.925  10 2 mole / sec

160. If 1010 wheat grains are distributed in each second. The time required to distribute one
Avogardro’s number of wheat grains is

1) 1010 sec 2) 6.02  1023 sec

3) 6.02  1033 sec 4) 6.02  1013 sec

161. Identify incorrect statement

1) PCl 3 hydrolyses in the presence of moisture giving fumes of PCl 3

2) Pt does not react with oxygen directly

3) Boric acid is polymeric due to the presence of hydrogen bonds

4) In electrolytic refining of copper Impure copper and Pure copper are anode and
cathode respectively

162. Hydrolysis of sucrose gives

Sucrose + H 2O Glucose + Fructose

Equilibrium constant KC of the reaction is 2  1013 at 300 K. Then G 0 of the

reaction at 300 K is

1) 7.64  104 J /mole 2) 7.54  103 J /mole

3) 7.64  104k.J / mole 4) Data insufficient

163. The ionization constant of HCN at 298 K is 4.8  109 . The ionization constant of its
conjugate base is

1) 4.8  109 2) 2.08  105 3) 2.08  106 4) 6

164. Vapour pressure of chloroform and dichloromethane at 298K are 200 mm Hg and 415
mm Hg respectively. Calculate the vapour pressure of the solution prepared by mixing
25.5 gm of CHCl3 and 40 gm of CH2Cl2 at 298K

1) 367 mm Hg 2) 348 mm Hg

3) 567 mm Hg 4) 448 mm Hg

165. Statement-I: D Vmix and D Smix for an ideal solution is zero

Statement-II: A ----B Interaction in an ideal solution are same as between A---A and B--
-B.

1) Both true and Statement – II is correct explanation of Statement – I

2) Both true and Statement – II is not correct explanation of Statement – I

3) Statement – I is false and Statement – II is true

4) Statement – I is true and Statement – II is false

166. A compound is formed by two elements M and N. The element N forms CCP and atoms
1
of M occupy rd of tetrahedral voids. The formula of the compound is
3

1) M 3N 2 2) M 2N 3 3) M 3N 3 4) M 4N 3

- 7
167. A photon of wavelength 4 ´ 10 m strikes on metal surface, the work function of the
metal being 2.13 ev. Then kinetic energy of emitted electron is

1) 3.093 ev 2) 0.56 ev 3) 2.97 ev 4) 0.97 ev

æ ö
çç p + a ÷÷v = RT . The
168. At low pressure Vander Waal’s equation is written as çè v ÷
2
ø
compressibility factor is then equal to

æ RTV ÷
ö æ a ÷ö æ a ÷ö æ RTV ÷
ö
1) çç1 - ÷ 2) çç1 - ÷ 3) çç1 + ÷ 4) çç1 + ÷
çè a ÷
ø çè RTV ÷
ø çè ÷
RTV ø çè ÷
a ø

169. Identify the correct statements

i) Dielectric constant: H 2O > D2O

ii) Dihedral angle: H 2O2 (s ) > H 2O2 (g )

 iii) KO2 is paramagnetic & K 2O2 is diamagnetic

1) i & ii only 2) ii & iii only 3) i & iii only 4) All

170. Which of the following exhibit geometrical and optical Isomerism?

1) éêCo (NH 3 )4 Cl 2 ù
úCl 2) éêCo (en )2 Cl 2 ù
úCl
ë û ë û

3) éêCo (en )3 ù
úCl 3 4) éêCo (NH 3 )3 Cl 3 ù
ú
ë û ë û

171. XeF6 on hydrolysis gives

1) XeO3 , XeOF4 , XeO2F2 and HF 2) XeO3 and HF

3) XeO3 ,O2 and HF 4) XeO3 , HOF and HF

1)AlH(i- Bu)
172.
CH3 - CH = CH - CH2 - CH2 - CN ¾ ¾ 2)H
¾ 2¾O
¾®
2
.The product formed
is

1) CH3 - CH2 - CH2 - CH2 - CH2 - CN

O
||
CH3 - CH2 - CH2 - CH2 - CH2 - C- H
2)

O
||
CH3 - CH = CH - CH2 - CH2 - C- H
3)

O
||
CH3 - CH = CH - CH2 - CH2 - C- OH
4)

173. Choose the correct acidity order for the following compounds.
O O
|| ||

i)
NO2 - CH2 - C- OH ii)
NC - CH2 - C- OH

CCl3COOH CF3COOH
iii) iv)

1) i > ii > iii > iv 2) iv > iii > i > ii

3) ii > iii > i > iv 4) iii > ii > i > iv

174.

O O
C H C H
C OH CH2 O H
O

Select the suitable option for the above conversion.

1) NaBH4 2) LiAlH4

3) H+/Etheleneglycol, LiAlH4, H3O+ 4) Pd/C

175. In formation of glucosazone number of moles of phenylhydrazine used are

1) 2 2) 3 3) 4 4) 1
excess HBr hydrolysis
176. CH3 - C º CH ¾ ¾ ¾ ¾¾ ® A¾¾ ¾ ¾¾ ® B the product ‘B’ is

1) propanol 2) propanal 3) Acetone 4) propanoic acid

OH
Br2
O Cs2
177. major product formed is

1) o-bromophenol 2) p-bromophenol

3) 2,4,6 trybromophenol 4) 2,4 dibromophenol

178. Which of the following is purine base

1) Guanine 2) Cytosine 3) Thymine 4) Uracil

179. Correct statements among the following

I) Freundlich adsorption isotherm curves always seem to approach saturation at low
pressures

II) Freundlich adsorption isotherm curves always seem to approach saturation at high
pressures

III) Freundlich isotherm is an approximation on the behavior of adsorption

IV) Freundlich isotherm holds good over a limited range of pressure

1) I, II only 2) II, III only 3) II, III, IV only 4) All

180. Predict the order of reactivity of following compounds in SN1 path way

CH 3 C 6H5 CH 3
1) C 6H 5 C Br > C 6 H 5 C Br > C 6 H 5 C Br > C H
6 5 CH2 Br
C 6H5 H H

C 6H5 CH 3 CH 3
C 6H 5 C B r > C 6H 5 C Br > C 6 H 5 C Br > C H
2)
6 5 CH2 Br
H H
C 6H5

CH 3
C 6H5 CH 3
3) C6H5 CH2 Br > C 6 H 5 C Br > C H
6 5 C Br > C 6 H 5 C Br
C 6H5 H H

H C 6H5 CH 3
4) C 6H 5 C Br > C H C Br > C 6 H 5
6 5 C Br > C 6 H 5 CH2 Br
C 6H5 CH 3 H

181. Sulphur exists as S8 , S6 , S4 and S 2 under different conditions. Which of the following
statements is correct?

1)Mass of one mole of each of them is same

2)Number of molecules in one mole of each of them is same
3)Number of atoms in one mole of each them is same
4)All are correct statements
182. Uncertainty in position and momentum of a particle are equal. Then uncertainty in
velocity is given as

h h 1 h
1) 2) 3) 4)
p 2p 2m p

h
2p m
 é a ù
183. At low pressure, Vander Waal’s equation is reduced to êp + 2 úV = RT for a mole of a
êë V ú û
gas. Then the compressibility factor can be given as
a RTV a RTV
1) 1- 2) 1- 3) 1 + 4) 1 +
RTV a RTV a

184. Amongest LiCl, RbCl, BeCl2 and MgCl2 , the compounds with the highest & least ionic
character respectively are
1) LiCl , RbCl 2) RbCl , BeCl2 3) RbCl , MgCl2 4) MgCl2 , BeCl2

185. CsBr has b.c.c type structure with edge length 4.3pm. The shortest inter-ionic distance
between Cs + and Br - is
1)3.72pm 2)1.86pm 3)7.44pm 4)4.3pm

186. The species having diamagnetic nature and bond order 1.0 is
1) O2+ 2) O2 3) O2- 4) O2- 2

187. Which of the following represents the increasing order of ionic radii

1) Mg + 2 < F - < O- 2 < N - 3 2) N - 3 < O- 2 < F - < Mg + 2

3) F - < O- 2 < N - 3 < Mg + 2 4) O- 2 < F - < Mg + 2 < N - 3

188. Which one of the following has maximum heat of hydrogenation

1) CH 2 = CH 2 2) CH 3 - CH = CH 2

CH 3

CH 3
3) 4) CH3CH 2CH = CH - CH 3

189. The difference between heat of reaction at constant pressure and constant volume for the
reaction given below at 25°C in kJ is

2C6 H 6(l ) + 15O2(g ) ¾ ¾

® 12CO2(g ) + 6H 2O(l )

1)-7.43 2)+7.43 3)-3.72 4)+3.72

 CH 3 Br + Nu - ¾ ¾
® CH 3 - Nu + Br - . The decreasing order of the rate of the above
190.
reaction with nucleophiles (Nu - ) A to D is

A) PhO - B) AcO- C) OH - D)
CH 3O -

1)D>C>A>B 2)D>C>B>A 3)A>B>C>D 4)B>D>C>A

191. A solution has a 1:4 mole ratio of pentane to hexane. The vapour pressure of the pure
hydrocarbons at 20 0 C are 440 mm Hg for pentane and 120 mm Hg for hexane. The mole
fraction of pentane in the vapour phase would be
1) 0.7861 2)0.549 3)0.478 4)0.200

192. In a 0.2 molal aqueous solution of weak acid HX (the degree of dissociation=0.3) the
freezing point is (given K f = 1.85 K. molal - 1 )

1) - 0.260 C 2) + 480 C 3) - 0.480 C 4)

- 0.360 C

193. K C for A + B ‡ˆ ˆ †ˆ C + D is 10 at 25°C . If a container has 1,2,3,4 mol/L of A,B,C and

D respectively at 250 C , the reaction will proceed

1)from left to right 2)from right to left
3)for either direction 4)no change

194. Which of the following reaction will yield 2,2-Di bromo propane

1) CH 3 - C º CH + 2 HBr ¾ ¾
® 2) CH 3CH = CHBr + HBr ¾ ¾
®

3) CH º CH + 2 HBr ¾ ¾
® 4) CH 3 - CH = CH 2 + HBr ¾ ¾
®
195. Solid Ba (NO3 )2 is gradually dissolved in a 1.0´ 10- 4 M Na2CO3 solution. At what

concentration of Ba + 2 will a precipitate begin to form ( k sp of BaCO3 = 5.1´ 10- 9 )

1) 5.1´ 10- 5 M 2) 5.1´ 10- 6 3) 1.0´ 10- 5 4) 5.1´ 10- 13

196. The equivalent weight of (NH4 )2 Cr2O7 in the following reaction is (M=molecular

weight) (NH 4 )2 Cr2O7 ¾ ¾

® N2 + Cr2O3 + 4H 2O

M M M M
1) 2) 3) 4)
2 3 6 8

197. In the following sequence of reactions

CH 3CH 2OH ¾ PCl

¾¾ 3
® A ¾ dry
¾Mg ¾ ® B ¾ CH
ether
¾3CHO
¾¾ ® C ¾ H¾¾
2O
® D . The compound D is

1)Butanal 2)n-Butyl alcohol 3)Sec butyl alcohol 4)Butanone

0
EFe+2
/ Fe
0
and EFe+3
/ Fe+ 2
are -0.441V and 0.771V respectively. E 0 for the reaction
198.
Fe + 2 Fe+ 3 ¾ ¾
® 3Fe+ 2 will be
1)1.212V 2)0.111V 3)0.330V 4)1.653V

199. Which one of the following undergoes reaction with 50% sodium hydroxide solution to

give the corresponding alcohol and acid

1)Benzaldehyde 2)Benzonitrile 3)Butanal 4)Phenol

200. The rate constant for a zero order reaction is 2´ 10- 2 mol L-1 s-1. If the concentration of
the reactant after 25 sec is 0.5M the initial concentration must have been
1)0.5M 2)1.0M 3)1.25M 4)12.5M

201. Addition of dil solution of AgNO3(aq) to excess of dil KI(aq) gives

1)AgI solution 2)+ve sol of AgI

3)-ve sol of Ag I 4)Neutral sol of AgI

202. Which one of the following is the strongest base in aqueous solution?
 1)Trimethylamine 2)Aniline 3)Dimethylamine 4)Methyl aniline

203. Extraction of zinc from zinc blende is achieved by

1)Electrolytic reduction
2)Roasting followed by reduction with carbon
3)Roasting followed by reduction with Mg
4)Roasting followed by self reduction

204. The pyrimidine bases present in DNA are

1)cytosine and adenine 2)cytosine and guanine

3)cytosine and thymine 4)cytosine and uracil

205. Which one of the following is a correct statement?

1) B2 H 6 .2 NH 3 is known as inorganic benzene

2)Boric acid is a protonic acid
3)Be exhibits coordination number of six
4)Chlorides of Be & Al have bridged chloride structure in solid state

206. Which of the following can be used as analgesic without causing addiction

1)paracetamol 2)morphine 3)thebaine 4)diazepam

207. In which of the following arrangements, the sequence is not strictly according to the
property written against it

1) HF < HCl < HBr < HI : Acid strength

2) NH3 < PH3 < AsH3 < SbH3 :Basic strength

3) B < C < O < N : Ionisation enthalpy

4) CO2 < SiO2 < SnO2 < PbO2 :Oxidising power

208. Nylon threads are made of

1)polyamide polymer 2)polyethylene polymer

 3)polyvinyl polymer 4)polyester polymer

209. Which kind of isomerism is exhibited by CoBr2Cl.4 NH 3

1)Geometrical and ionization 2)Geometrical & optical

3)Optical and ionization 4)Geometrical only

210. Zwitter ion is formed by

1)sulphanilic acid 2)Glycine

3)Alanine 4)All of these

211. Which of the following statement is wrong regarding CH 2 F2

1) It has perfect tetrahedral structure 2) All bond angles are equal

3) All the hybrid orbitals have same s and p character 4) All are wrong

212. The interplanar distance between the closest packed layers in the face-centered cubic unit

cell is

1) equal to the edge length

2) equal to the half the edge length

3) equal to the one third of body diagonal

4) equal to the half of face diagonal.

213. Allegra, a common prescription drug with the structure shown below, is given for the
treatment of seasonal allergies. How many stereogenic carbon does allegra possess ?
CH 3

COOH

CH 3

N
H

OH
HO

1) 2 2) 1 3) 3 4) 5

214. The maximum number of 900 angles between bond pair of electrons is observed in

1) dsp 3 hybridization 2) sp3d 2 hybridization

3) dsp 2 hybridization 4) sp 3 d hybridization

215. An electron is allowed to move freely in a closed cubic box of length of side 10 cm. The

minimum uncertainty in its velocity will be:

1) 3.33´ 10- 4 m sec- 1 2) 5.8´ 10- 4 m sec- 1 3) 4´ 10- 5 m sec- 1 4) 4´ 10- 6 m sec- 1

216. Arrange the following compounds in the order of increasing tendency to undergo

electrophilic substitution

1) Nitrobenzene 2) Benzene 3) Phenol 4) Toluene

5) Trimethyl phenyl ammonium ion

1) 5<1<2<4<3 2) 3>2>1>4>5 3) 1>2>5>3>4 4)5<2<4<1<3

217. Which of the bonding conversions show minimum energy release

 -
1) C ® C 2) H ® H - 3) O ® O- 4) F ® F -

218. For a real gas PV>RT at all pressure ranges, then :

1) The gas is less compressible 2) The gas is highly compressible

3) The gas is not compressed at all 4) The gas is liquefied easily

219. CaC2 + H2O ® (A) ¾ H¾2SO¾ ¾¾

4 , HgSO4
® (B) Then A and B are

1) CH 4 and HCOOH 2) C2 H 4 and CH 3COOH

3) C2 H 2 and CH 3CHO 4) C2 H 2 and CH 3COOH

220. Which of the following is diamagnetic ?

2+ 3-
1) éêëFe (H 2O )5 (NO )ù
ú
û 2) éêëFe (CN )5 (NO )ù
ú
û

2- 3+
3) éêëFe (CN )5 (NO )ù
ú
û 4) éêëFe (H 2O )5 (NO )ù
ú
û

221. 20 ml of an H 2O2 solution on reaction with excess of acidified KMnO4 released 224 CC

of O2 . What is the volume strength of that H 2O2 ?

1) 5.6 vol 2) 11.2 vol 3) 22.4 vol 4) 2.8 vol

222. How many distinct alkene products are possible when the alkyl iodide below undergoes

E2 elimination ?

CH 3
base ,
CH 3 ?
I CH 3

1) 1 2) 2 3) 3 4) 5
223. The false statement among the following is

1) Metallic or interstitial hydrides can be considered as solid solutions

2) Hydrogen can be purified by occlusion process

3) H-H bond length is longer than D-D bond length and thus D2 has more bond energy

than H 2

4) High pure hydrogen is obtained by the electrolysis of warm Ba (OH )2 solution

224. I 2 (S )/ I - (0.1M ) half cell is connected to a H + (aq)/ H 2 (1bar)/Pt half cell and emf is

found to be 0.7714V. If EI0 / I - = 0.535V , find the P H of H + / H 2 half cell.

2

1) 5 2) 3 3) 4 4)6

225. In the reaction sequence Glycerol ¾ KHSO

¾ ¾4 / D¾
® X ¾ Zn
¾- Hg
¾/ concHCl
¾ ¾/ D¾® Y ¾ NBS
¾ /¾ ¾
CCl4
®Z

Z will be

1) 1,2-dibromopropane 2) 1-bromopropane

3) 2-bromopropane 4) 3-bromopropene

226. The wrong statement among the following is

1) With nitrogen lithium forms nitride but sodium forms azide

2) with sodium carbonate FeSO4 gives basic iron (II) carbonate precipitate but FeCl3

gives reddish brown Fe (OH )3 precipitate

3) Magnesium chloride gives white precipitate with Na2CO3 but not with NaHCO3 in
cold condition

4) Enthalpies of alkali metal chlorides decreases down the group

227. Equivalent conductivity of BaCl2 , H 2 SO4 and HCl. are x1 , x2 and x3 S - cm- 1 - eq- 1 at

infinite dilution. If conductivity of saturated BaSO4 solution is x S - cm- 1 , then K sp of

BaSO4 is

500 x 2.5´ 105 x 2 106 x 2 0.25x 2

1) 2 2) 2
3) 2
4) 2
(x1 + x2 - 2 x3 ) (x1 + x2 - 2 x3 ) (x1 + x2 - 2 x3 ) (x1 + x2 - x3 )

228. The major product of the reaction,

 H 3O
CH 2 C CH 2 CH 2 CH CH 2

CH 3 O
will be

CH 2OH CH 2OH

1) 2)
CH 3

OH CH 3

CH 3

CH 3 O
3) CH 3 C CH 2 CH 2 CH CH 2 4)
CH 3
OH
OH

229. Among (CH3 )3 N ® O and (CH3 )3 P ® O

1) N ® O bond has more dipole moment than P ® O

2) N ® O bond is stronger than P ® O bond

3) N ® O bond is shorter than P ® O bond

4) Amine oxides (R3 N ® O) are more stable than phosphine oxides (R3 P ® O)

230. Bredig’s arc method cannot be used for the preparation of colloidal sol of :

1) copper 2) gold 3) silver 4) sodium

231. Identify the product in the following reaction:

 CHO

1.con . N aO H
2H /

CHO

COOH

1) 2)
COOH

CH 2

COOH

O
3) 4)
C
OH
O

232. The molecule with zero dipole moment is

1) ClF3 2) Br F5 3) IF7 4) ClF

233. For an exothermic chemical process occurring in two steps as follows

(i) A + B ® X (slow) (ii) X ® AB ( fast )

The process of reaction can be best describe by

1) 2)
3) 4)

234 Which of the following is most acidic.

COOH COOH
H2C

1) COOH 2) COOH 3) CH 3COOH 4) HCOOH

235. An element of 3d-transition series shows two oxidation states x and y, differ by two units.
Then

1) compounds in oxidation state x are ionic if x  y

2) compounds in oxidation state x are ionic if x  y

3) oxidation state has no relation to the nature of bond

4) compounds in oxidation state y are covalent is y  x

236. The molal elevation constant of water is 0.52K kgmol 1 . The boiling point of 1.0 molal
aqueous KCl solution (assuming complete dissociation of KCl), should be

1) 98.96C 2) 100.52C 3) 101.04C 4) 107.01C

237. Which of the following can undergo Hoffmann reaction most easily?
 CONH 2 CONH 2 CONH 2 CONH 2

1) 2) 3) 4)

X CH 3 CN OCH 3

238. In which of the following the impure metal is not purified by the oxidation of impurities

1) silver containing lead

2) preparation of wrought iron from pig iron

3) zinc containing iron and cadmium

4) bessemerisation of pig iron

239. For a particular reversible reaction at temperature T, H and S were found be both +

ve. If Te is the temperature at equilibrium, the reaction would non-spontaneous when

1) T  Te 2) Te  T 3) Te  T 4) Te is 2 times T

240. The correct order of decreasing base strength among the amines given is

NH 2 NH 2 NHCH 3 NH 2

NO2

(I) (II) (III) CH 3

(IV)

1) III>I>IV>II 2) IV>III>I>II

3) I>IV>III>II 4)I>III>IV>II

CH 3
O
|
H 3O
CH 2 C CH 2 CH 2 CH CH 2
241. The major product for the reaction, will
be

CH2OH CH2OH

1) 2)
CH3
OH CH3

CH 3
| O CH3

3) CH 3 C CH 2 CH 2 CH CH 2 4)
CH3
| OH
OH

242. Which of the following statement is correct ?

 1) C-F bond is stronger than Si-F bond because C-F bond length is shorter than that of Si-
F

2) C-F bond is weaker than Si-F bond because of less difference in electronegativity

3) Si-F bond is stronger than C-F bond because of double bond character due to back
bonding from F to Si

4) Si-F bond is stronger than C-F bond due to more difference in electro negativities

243. 173.42´ 0.56 = 97.1152 . The correct answer to this problem in proper number of
significant digits is

1) 97.1152 2) 97.115 3) 97 4) 97.12

244. The correct acidic order of the following is

OH OH OH

(I) CH3 NO2

(II) (III)

1) I > II > III 2) III > I > II 3) II > III > I 4) I > III > II

245. Carborundum on heating with caustic soda in presence of air produces

1) Na2 SiO3 + H 2 2) Na2 SiO3 + Na2CO3

3) Na2 SiO2 + H 2 4) Na2 SiO4 + H 2

RH
246. The degeneracy of hydrogen atom that has the energy equal to is (where RH is
9
Rydberg constant )

1) 4 2) 6 3) 9 4) 12

247. Identify the major product, (Z) in the following reaction.

 Cl
Mg THF CO2
(Y) H+ (Z)
(X)
1 mole
Br

COOH

Cl COOH
COOH
1) 2) 3) 4) Br

COOH COOH

248. The standard oxidation potential value of lithium is greater than that of potassium. Yet
potassium is more reactive towards water than lithium because,

1) The m.pt of K is less than Li and the heat of the reaction is sufficient to melt K. So the
molten metal spreads out and exposes a larger surface to water

2)The m.pt of Li is less than K and the heat of reaction is sufficient to melt Li. So the
molten metal spreads out, and expose a larger surface to the water

3) The E 0 value is more negative and D G is more positive for Li + + e- ® Li

4) The E 0 value is more positive and D G is more negative for K + + e- ® K

249. The van der waals coefficient of the inert gases He, Ar and Xe are given below

Inert gas a (atm.dm 6 .mol - 2 ) b (10- 2 dm3mol - 1 )

He 0.34 2.38

Ar 1.337 3.20

Xe 4.137 5.16

Choose the appropriate pair to complete the following statement.

“The increase in the value of a signifies the increasing importance of _____ interaction

while increase in value in b is due to ______”

1) Ion-ion; increases atomic volume

 2) Induced dipole- induced dipole; increased atomic volume

3) Induced dipole- dipole; dipole- dipole interaction

4) Dipole- dipole ; decreasing ionization energies

250.

HNO3 Br2
A B
H 2 SO4 FeBr3

The compound B is

NO2
NO2 NO2 NO2
Br
1) 2) 3) 4)

Br Br Br
Br

251. An alkali metal hydride NaH reacts with diborane in solvent Y to give a tetrahedral
compound Z which is extensively used as reducing agent in organic synthesis . The Y and
Z in the above reactions are

1) C2 H 6 , C2 H 5 Na 2) C2 H5OC2 H5 , NaBH 4

3) NH3 , B3 N3 H 6 4) C3 H 8 , C3 H 7 Na

252. The equivalent weight of HCl in the given reaction is :

K2Cr2O7 + 14HCl ® 2KCl + 2CrCl3 + 7 H 2O + 3Cl2

1) 16.25 2) 85.1 3) 73 4) 36.5

253.

1% Hg So4 Dilute
CH CH A B
4% H 2 So4 , 600 C NaOH
The compound B is
 CH 3 - CH - CH 2 - CHO CH 3 - CH - CH 2 - COONa
1) | 2) |
OH OH

O OH O
|| | ||
3) CH 3 - CH - CH 2 - C - CH 3 4) CH 3 C CH 2 C CH 3
| |
OH CH 3

254. Sodium carbonate solution on adding to magnesium sulphate solution forms

1) Soluble magnesium bicarbonate

2) insoluble magnesium bicarbonate

3) insoluble basic magnesium carbonate

4)insoluble basic magnesium bicarbonate

255. An ideal solution contains two volatile liquids A(PA0 = 100 torr ) and B B (PB0 = 200 torr )
.

If mixture contains 1 mole of A and 4 moles of B, then total vapour pressure of the
distillate is

1) 150 torr 2) 180 torr 3) 188.88 torr 4) 198.88 torr

256. Among the following the least stable resonance structure is

O O
N N
1) 2)
O O

O O
N N
3) 4)
O O

257. The species present in solution when CO2 is dissolved in water are
 1) only H 2CO3 2) only H 2CO3 , HCO3

3) only CO2 , H 2CO3 4) only CO2 , H 2CO3 , HCO3 , CO32

258. For a hypothetical elementary reaction ,

2B
k1

k2 2C

k1 1
Where =
k2 2

Initially only 2 moles of A are present. The total no. of moles of A,B and C at the end of
75% reaction are :

1) 2 2) 3 3) 4 4) 3.5

259. Acid strength of the conjugate acids of the following are

(I) (II) (III) (IV)

N
N NH N NH
H N

1) II > III > I > IV 2) II > IV > I > III

3) II > I > III > IV 4) II > IV > III > I

260. Liquid oxygen and liquid nitrogen are allowed to flow between the poles of an
electromagnet. Choose the correct observation .

1) Both will be attracted but to opposing poles

2) Both will be attracted to the same poles

3) Liquid oxygen will be attracted and liquid nitrogen will be repelled

4) Liquid oxygen will be attracted but liquid nitrogen is unaffected

261. Solubility of AgCN is maximum in :

1) acidic buffer solution 2) basic buffer solution

3) in pure water 4) equal in all solution

262. Acyclic stereoisomers having the molecular formula C4H7Cl are classified and tabulated.
Find out the correct set of numbers.

Geometrical Optical

1) 6 2

2) 4 2

3) 6 0

4) 4 0

263. Which of the following pairs is expected to exhibit the same colour

1) 58 Ce3+ ,69 Ho3+ 2) 60 Nd 3+ ,68 Er 3+ 3) 61 Pm3+ ,69 Tm3+ 4) 63 Sm3+ ,70 Yb3+

æ 5 ö
264. When two mole on an ideal gas ççC p ,m = R÷
÷
÷ heated from 300 K to 600 K at constant
çè 2 ø
pressure. The change in entropy of gas (D S ) is :

3 3 5
1) R ln 2 2) - R ln 2 3) 5R ln 2 4) R ln 2
2 2 2

265. Identify the end product “B” here

NaNo2 / HCl D

00 - 50 C
A B
NH 2

1) phenanthrene 2) benzene

3) naphthalene 4) anthracene

266. In which of the following pairs find the pair in which first compound do not form
complex with NH 3 and second give coloured complex with NH 3

1) CoCl2 , ZnSO4 2) AgI , CuSO4 3) AlCl3 , ZnSO4 4) Cd (NO3 )2 , ZnSO4

267. In which of the following pairs of structures, tetrahedral as well as octahedral holes are
found

1) bcc and fcc 2) hcp and simple cubic

3) hcp and ccp 4) bcc and hcp

268. In the following reaction

Cellulose
( i )CS2 /NaOH

( ii )HCl/HOH
  P
Here the product [P] is

1) Rayon 2) Cellulose acetate

3) Gun cotton 4) Cellulose xanthate

269. Pure zirconium is obtained by

1) chromatographic method 2) Cupellation

3) Zone refining 4) Van arkel method

270. A graph was plotted between molar conductivity of various electrolytes (NaCl, HCl and
NH 4OH ) and C (in mol L- 1 ). Identify the Correct setting .

I
II
III

1) I(NaCl), II(HCl), III( NH 4OH ) 2) I (HCl ), II (NaCl ), III (NH 4OH )

3) I (NH 4OH ), II (NaCl ), III (HCl ) 4) I (NH 4OH ), II (HCl ), III (NaCl )

271. In simple cubic unit cell of a metal lattice, radius of cubic void is
1) 0.732 rmetal 2) 0.6 rmetal 3) 0.68 rmetal 4) 0.155 rmetal
272. Wavelength of high energy transition of H atom is 91.2 nm. Calculate the corresponding
wavelength of He+ ion.
1) 32.8 nm 2) 22.8 nm 3) 26.3 nm 4) 39.7 nm
273. Which of the following d orbitals is not involved in d 3 s hybridization ?

1) d xy 2) d yz 3) d x 2  y 2 4) d xz

274. One mole of N2O4 was found to decompose 80% at a particular temperature and a total
pressure of 1.5 atm. The K p for the reaction N 2O4 (g) ‡ˆ ˆ †ˆ 2NO 2 (g) is

æ64 ö æ64 ö æ8 ö æ1 ö
1) çç ÷ atm 2) çç ´ 1.5 ÷
´ 1.5 ÷ ÷ atm 3) çç ´ 1.5 ÷
÷atm 4) çç ´ 1.5 ÷
÷ atm
è 81 ø è9 ø è9 ø è9 ø

275. The percentage of dissociation of a weak acid HA is 0.3% when concentration of the acid
is 1 M. Hence % dissociation of 100 times diluted solution is

1) 0.3% 2) 3% 3) 30% 4) 100%

276. Which of the following metals can be purified by distillation?

1) Cu 2) Zn 3) Ag 4) Au

277. The cell potential of the given cell

Pt , H2(1 atm) HCl ( pH = 4) HCl ( pH = 3) H 2 (1atm), Pt is

(1) 0.0 V (2) 0.03V (3) 0.059V (4) 0.118V

278. The conductivity of pure water at 298K is ‘K’ Scm-1. Limiting molar conductivity of H+
and OH- ions are ‘x’ and ‘y’ Scm2mol-1 respectively. Degree of dissociation of water and
ionic product of water at 298K are respectively

18K 106 K 2 K K2
1) , 2) ,
 x  y  x  y 2 x  y  x  y 2

3) K  x  y  , K 2  x  y  4) 18k  x  y  ,106 k 2  x  y 
2 2

279. In blue vitriol, number of coordinated water molecules is/are

1) 5 2) 4 3) 2 4) 1

280. In which of the following octahedral complexes, D 0 magnitude is highest

+3 +3 - 3 - 3
1) éêëCo (H 2O )6 ù
ú
û 2) éêëCo (NH 3 )6 ù
ú
û 3) éëêCo (CN )6 ùûú 4) éêëCo (C2O4 )3 ù
ú
û
281. Colloid with which one of the following zeta potential is more stable

1)   25mV 2)   35mV 3)   45mV 4)   60mV

282. In CaMgSi2O6 , how many oxygens per each tetrahedron are shared by others

1) 4 2) 3 3) 2 4) 1

283. Treatment of cyclobutylmethanamine with nitrous acid doesn’t give

CH 2 OH
CH 2OH

I II III IV V

1) I, II, IV 2) II, V, I 3) I, II, IV, V 4) III only

284. Among the conjugate bases of oxoacids of chlorine, the correct bond angle order is

1) ClO3- < ClO4- < ClO2- 2) ClO2- < ClO3- < ClO4-

3) ClO2- < ClO4- < ClO3- 4) ClO4- < ClO3- < ClO2-

285. For dissolution of gases in liquids, correct statement(s) among the following is / are as
per Henry’s law.
a) At a certain temperature, the ratio of the molar concentrations of the gas in solution
and in the gas phase is constant.
b) The volume of a gas dissolved in a solvent at a given temperature is independent of the
pressure.
c) The mole fraction of the gas dissolved in the solution is proportional to the pressure of
a gas over a solution in which the gas is dissolved.
1) a, b and c 2) only c 3) only a, c 4) only a, b
286. Chlorine oxidizes iodine to
1) hypoiodite 2) iodite 3) iodate 4) periodate
287. The product formed in maximum proportion in the following reaction is

anhydrous
(CH 3 )3 CCOCl AlCl3
 OC CH 3 3

CHO
1) C6 H5COC ( CH3 ) 3 2) C6 H5C ( CH3 ) 3 3) C6 H5CH 2C ( CH3 ) 3 4)

288. Emerald is

1) Alumina with Cr3+ impurity 2) Silica with Cr3+ impurity

3) Alumina with Cu2+ impurity 4) Beryl mineral with Cr3+ impurity

289. Formation of yellow stains on fingers while working with conc. HNO3 in laboratory is
due to reaction of conc. HNO3 with

1) Carbohydrates 2) Nucleic acids

3) Proteins 4) Vitamins

290. Which one of the following complexes is optically inactive

é 2- ù
ë (
1) ê As CH3 )( C2H5) ( S ) ( C6H 4COO) ú
û
tetrahedral

2) é
ëPt py ( ) ( NH3) ( NO2) Cl Br I ùû
3+
3) éêCo ( en) NH 3 4 ù
( ú )
ë û

+
4) éêCo ( en) NH 3 4 Cl2 ù
( ) ú
ë û

291. For any gas  PVm  p0 value at 273.15K is (in dm3 bar)

1) zero 2) infinity 3) 22.711 4) 22.414

292. Each pair has been matched with the suitable reagent used for making distinction. Which
pair has been matched wrongly?

Pair Reagent
 1) R  C  CH and R  CH  CH 2 AgNO3 / NH 4OH

2) R  CHO and RCOOH 2, 4  DNP

3) RCOOH and RCONH 2 NaHCO3

4) R  NH 2 and Ph  NH 2 CHCl3 / NaOH

293. The entropy change at 373K for the transformation

H 2O  ,1.013225 bar   H 2O  g ,0.101325 bar  , Hvap of H2O is 40.6 KJ/mol

1) 109 J/K/mol 2) 19.15 J/K/mol

3) 128.17 J/K/mol 4) 150 J/K/mol

Cu,3000 C
294. Tertiary butyl alcohol  A .

A is subjected to ozonolysis. The products of ozonolysis are reduced with LiAlH 4 .

The final products is/are

1) 2-methylpropane-2-ol 2) mixture of methanol and ethanol

3) propan-2-ol and methanol 4) mixture of ethanol + formic acid

295. 12 g of AB (mol. mass = 60) is dissolved in 0.5 kg of water. The solution freezes at
0.74°C below the freezing point of water. What is the degree of dissociation of the
electrolyte is nearly? [ K f = 1.86 Km- 1]

1) 0 2) 0.25 3) 0.75 4) 1.0

296. Under the same reaction conditions initial concentration of 1.386 mol dm- 3 of a
substance becomes half in 40 seconds and 20 seconds through first order and zero order
kinetics respectively. Ratio (k1 / k0 ) of the rate constant for first order ( k1 ) and zero
order (k0 ) of the reaction is

1) 0.5 2) 1.0mol dm- 3 3) 1.5mol dm- 3 4) 0.5mol 1 dm+3

297. If phenol is heated with CCl4 and KOH a product is formed which on treatment with dil.
HCl gives the compound ‘X’, ‘X’ is
 1) Salicylaldehyde 2) Salicylic acid

3) Salol 4) Aspirin

298. Heat of combustion of ethane, ethene and ethyne are -1561kJ/mol, -1410kJ/mol and

-1326kJ/mol. Flame temperature of which fuel is highest when remaining conditions are
identical ( C p value of H 2O g  and CO2 g  are 33.5 J/k/ mol, 36.3 J/k/mol)

1) Ethane 2) Ethene 3) Ethyne 4) Equal for all

299. An aromatic compound having molecular formula C8 H10 ( A) on treatment with hot
KMnO4 gives (B) which can easily be converted to an anhydride by heating it . The
compound (A) is

1) Toluene 2) Ethyl benzene 3) Para - xylene 4) Ortho – xylene

300. Among the following solutions with given pH values, in which solution solubility of
CH3COO Ag is maximum.

1) 4 2) 6 3) 7 4) 9

301. Equimolal solutions of KCl and compound X in water shows depressions in freezing
point in the ratio of 4:1. Assuming KCl to be completely ionized

The compound X in the solution must

1) Trimerises to the extent of 50%

2) Dimerises to the extent of 80%

3) Dimerizes to the extent of 50%

4) Trimerizes to the extent of 75%

302. Which of the following gases always show positive deviation from ideal behaviour at all
pressures and 273 K

I. He II. CO2 III. H 2 IV. CH 4

1) I and II only 2) II and III only

 3) I and IV only 4) I and III only

303. An ionic compound A+ B- has ZnS(sphalarite) type structure If all the ions along one
body diagonal line in the unit cell are removed. Then the formula of remaining structure
is ?
(1) A12 B20 (2) A4 B5 (3) A8 B27 (4) A2 B3
304. In the precipitation of sulphides of second group of basic radicals, H2S is passed into the

acidified salt solution. If the solution is not acidified, then which is the correct statement?

1) Only the sulphides of second group get precipitated

2) Only the sulphides of fourth group get precipitated

3) Neither of the sulphides of second and fourth groups get precipitated

4) Sulphides of both second and fourth groups can get precipitated.

305. Consider the following compound :

1) It is cis-2-Chloro-3-methylpent-2-enal

2) It is (E)-2-Chloro-3-methylpent-2-enal

3) It is (Z)- 2- Chloro- 3- methylpent-2- enal

4) It is trans- 2- Chloro- 3- methylpent-2-enal

306. Circumference of Bohr’s orbit in a Hydrogen atom is 13.32A 0 .Calculate kinetic energy

of an electron in that orbit is (in ev/per atom)

(1) 13.6 (2) 27.2 (3) 6.8 (4) 3.4

307. Which of the following dienes is expected to be the least reactive towards electrophilic

addition?

1) 2) 3) 4)

308. Two flasks A and B have equal volumes. Flask A contains hydrogen at 600 K while
flask B has same mass of CH 4 as that of hydrogen at 300 K. Which of the following
statements are correct ?

(I) In flask A the molecules move faster than B

(II) In flask B the molecules move faster than A.

(III) Flask A contains greater number of molecules than B.

(IV) Flask B contains more molecules than A.

1) III and IV 2) I and II 3)II and IV 4) I and III

309. A mixture of benzaldehyde and formaldehyde are heated with NaOH solution then the
correct statements regarding the above reaction is

(I)The products are CH3 OH and C6 H5 COOH

(II) The products are formic acid and benzyl alcohol

(III) The reaction involves disproportionation

(IV) The order of the reaction depends on concentration of NaOH

 1) II ,IV only 2) I,III,IV only 3) II only 4) I,II,III only

310. Among the following the correct order of reactivity towards SN 2 reaction is

1) II  III  IV  I 2) III  II  I  IV

3) IV  III  I  II 4) I  II  III  IV

311. The hydrolysis product (A) of the reaction is

+
H 3 O18
O (A)

312. During the partial hydrolysis of XeF6 the hybridization of Xe changes from – to –

1) sp3d2 - sp3d 2) sp3d3 - sp3 3) sp3 - sp3d 4) sp3d3 - sp3d2

313. The correct reaction with respect to major product given

 2)
1)

3)

4)

314. P4  white  

Conc. NaOH / 
atmosphereof CO2
 A B 

Which of the following is wrong for the above reaction?

1) The compound A is NaH2 PO2

2) The compound B can be prepared by the hydrolysis of Ca3 P2

3) The compound A is Na2 H PO2

4) The above reaction involves disproportination

315. The conductivity of BaSO4 aqueous solution is 2 106 Ohm1cm1 . The conductivity of

water used to prepare above solution is 1106 ohm1cm1 at 250 C .

Ba
0
 60 ohm1cm2 mol 1
2
SO
0
2 is 20 ohm1cm2equivalent 1 then the solubility of
4

BaSO4 in pure water at 250 C is

 1) 5 106 moles/litre 2) 1105 moles/litre

3) 2 105 moles/litre 4) 11010 mole 2 /litre 2

316 I II

III IV

The correct relationship between above structures.

1) I and II are anomers; III and IV are epimers

2) I and III are epimers; II and IV are anomers

3) I and II are epimers; III and IV are anomers

4) I and III are anomers; I and II are epimers

317. Which of the following basic strength order given is incorrect :

1) (CH3)3N > (CH3)2NH > CH3NH2 > NH3 in vapour state.

2) (CH3)2NH > (CH3)3N > CH3NH2 > NH3 in water.

 NH 2 NH 2 NH 2

> >

OMe
OMe CH 3
3)

4) NH3 > C2 H5OH > H2O

318. Which of the following never undergo dispraportionation

I. F2 II. HNO2 III. H 2 S IV . SO2

1) III only 2) II,III,IV only

3) I,II,III only 4) I and III only

319. If A is the central atom of the molecule containing A and X atoms and E is the number of

lone pairs around it then VSEPR notation AX3E1 will be for the molecules:

1) PCl5 , ICl4 2) IClF  , ICl4  3) NF3 ,ClO3 4) ClF3 ,ClO3

320. Calcium amide Ca(NH 2 ) 2 on hydrolysis gives gas(B) which on oxidation by bleaching

powder gives gas(C). Gas (C) on reaction with magnesium gives compound (D) which on

hydrolysis gives again gas(B).Identify (B), (C) and (D) respectively

1) NH3 , N2 , Mg3 N2 2) N2 , NH3 , Mg ( NH 2 )2

3) N2 , N2O5 ,Mg(NH2 )2 4) NH3 , NO2 ,Mg (NO2 )2

321. Column I Column II

(A) Ortho-silicate (P) Formed by sharing two oxygen atoms by

each tetrahedral unit

(B) Pyro-silicate (Q) Three oxygen atoms of each tetrahedra are

shared with adjacent SiO 4 4 tetrahedral unit

(C) Single chain Silicate (R) Contains single descrete unit of SiO 4 4
tetrahedran

(D) Two dimensional sheet (S) Contain two units of SiO 4 4 joined along a
silicate corner containing oxygen atom.

The correct match is

A B C D

1) P Q R S

2) R S P Q

3) Q R S P

4 S R Q P

+ -
AB(S ) Aaq + Baq
for which K sp = 8´ 10 M and
- 12 2
322. AB dissolves as follows :

the standard entropy change of dissolution is 104 Jmol - 1 K - 1 ,then the enthalpy of

solution H 0 at 298K is nearly ( in KJ mol 1 )

1) 94.31 2) 3) 56 4)
 CH2 CH CH3
OH + I2/NaOH CHI 3 + X
323.
X would be

324. Which of the following is formed by condensation polymerisation?

1) Teflon 2)Polystyrene

3) PVC 4) Dacron

325 The compound formed during tailing of mercury is

1) Hg 2O 2) HgO 3) Hg Cl2 4) HgO.Hg Cl2
326 For the given three cells, which of the following is correct?

(i) Zn | Zn2 1M  Cu 2 1M  | Cu ; Ecell  E1

ii  Zn | Zn2 10M  || Cu 2 10M  | Cu ; Ecell  E2

iii  Zn | Zn2  0.1M  || Cu 2  0.1 M  | Cu ; Ecell  E3

1) E1  E2  E3 2) E3  E2  E1 3) E2  E1  E3 4) E1  E2  E3

327 Which of the following is correct with respect to the following graphs?
 1)I only represents zero order reaction

2) II only represents zero order reaction

3 ) III only represents Ist order reaction

4) All the three graphs represent zero order reaction

328 Incorrect statement regarding Cr2 O7- 2 is

1) All chromium oxygen bonds are not identical

2) It has Cr - Cr bond

3) One of the oxygen atom undergo sp3 hybridization

4) It oxidizes I - to I 2

329

CH2

1. NaNO / HCl /05C


2
2.  The major product is

H2N
 1) 2)

3) 4)

330 Sodium benzoate used as preservative for acidic food and soft drinks is metabolized

into……..which is excreted with urine.

1) Benzoic acid 2) Hippuric acid

3) Salicylic acid 4) CO2 and H 2O

331. Lemon juice normally has a pH of 2. If all the acid in the lemon juice is citric acid and
there are no citrate salts present, then what will be the citric acid(H.cit) concentration in
the lemon juice? (Assume that only the first hydrogen of citric acid is important).

 H .Cit H   Cit  .K a1  8.4 104 mol lit 1 

a) 8.4  104 M b) 4.2  104 M c) 16.8 104 M d) 12.0  102 M

332. One mole of an anhydrous salt AB dissolves in excess of water with the evolution of 21.0
J mol-1 of heat. If the heat of hydration of AB is -29.4 J mol-1, then the heat of dissolution
of the hydrated salt AB is

a) 50.4 J mol-1 b) 8.4 J mol-1 c) -50.4 J mol-1 d) -8.4 J mol-1

333. The number of isomers of [Co (NH3)3 Cl3] complex and secondary valency of the metal
ion in the complex respectively are.

a) 3 & 3 b) 2 & 3 c) 2 & 6 d) 3 & 6

334. The order of acidity of compounds I-IV, is-

 CH 2OH CO2 H OH SO3 H

I   II   III   IV 

a) I < III < II < IV b) IV < I < II < III

c) III < I < II < IV d) II < IV < III < I

335. A concentrated solution of copper sulphate, which is dark blue in colour, is mixed at
room temperature with a dilute solution of copper sulphate, which is light blue. For this process-

a) Entropy change is positive, but enthalpy change is negative

b) Entropy and enthalpy changes are both positive

c) Entropy change is positive and enthalpy does not change

d) Entropy change is negative and enthalpy change is positive

336. Increasing the temperature increases the rate of reaction but does not increase the-

a) number of collisions b) activation energy

c) number of fruitful collisions d) average velocity of the reactant molecules

337. From equations 1 and 2,

1
1). CO2( g ) CO( g )  O2( g )  K1  9.11012 at 10000 C  ;
2

1
2). H 2O(l ) H 2( g )  O2( g )  K 2  7.11012 at 10000 C 
2
 The equilibrium constant for the reaction CO2( g )  H 2( g ) CO( g )  H 2O(l ) at the same

temperature, is

a) 0.78 b) 2.0 c) 16.2 d) 1.28

338. Consider the reaction: 2 NO2  g   2NO  g   O2  g  , In the figure below, identify the

curves X, Y and Z associated with the three species in the reaction

Concentration Y

Time

a) X = NO, Y = O2, Z = NO2 b) X = O2, Y = NO, Z = NO2

c) X = NO2, Y = NO, Z = O2 d) X = O2, Y = NO2, Z = NO

339. Two isomeric compounds I and II are heated with HBr –

OH OH

CH 2OH OCH 3
I   II 

The products obtained are

OH OH Br Br

a) b)
CH 2 Br OH CH 2OH OCH 3
 OH OH
Br Br
Br

c) d)
CH 2OH OCH 3
CH 2 Br Br
Br

340. The number of possible enantiomeric pair(s) produced from the bromination (Br2/CCl4)

of I and II, respectively, are

H 3C CH 3 H 3C
CH 2
H 3C
H 3C CH 3
I   II 

a) 0,1 b) 1, 0 c) 0, 2 d) 1, 1

341. For the reaction A  B, H 0  7.5 KJ mol 1 and S 0  25 JK 1 mol 1 . The value of G 0

and the temperature at which the reaction reaches equilibrium are, respectively,

a) 0 KJ mol 1 and 400 K b) – 2.5 KJ mol 1 and 400 K

c) 2.5 KJ mol  and 200 K d) 0 KJ mol 1 and 300K

342. The solubility product of Mg  OH 2 is 1.0 1012 at 250C. Aqueous NaOH solution is

added to a 0.01 M aqueous solution of MgCl2 . The minimum pH at which precipitation

occurs at 250C is

a) 7.2 b) 7.8 c) 8.0 d) 9.0

343. Diborane is formed from the elements as shown in equation (1)

2B  s   3H 2  g   B2 H6  g  ............1
 Given that

H2O  l   H 2O  g  H10  44 kJ

2B  s   3/ 2O2  g   B2O3  s  H 20  1273 kJ

B2 H6  g   3O2  g   B2O3  s   3H 2O  g  H 30  2035 kJ

H 2  g   1/ 2O2  g   H 2O l  H 40  286 kJ

the H 0 for the reaction (1) is-

a) 36 kJ b) 509 kJ c) 520 kJ d) – 3550 kJ

344. The Crystal Field Stabilization Energy  CFSE  and the spin-only magnetic moment in

Bohr Magneton (BM) for the complex K 3  Fe  CN 6  are, respectively-

a) 0.0 0 and 35 BM b) 2.0  0 3 BM

c) 0.4  0 and 24 BM d) 2.4  0 and 0 BM

345. Conversion of Isopropyl chloride into Isopropyl alcohol can take place by both SN1 &
SN2 mechanism based on the conditions, from the following table

Mechanism No.of Intermediates No.of Transition states

SN1 P Q

SN2 R S

What is the value of (P + Q) - (R + S) is

a) 1 b) 2 c) 3 d) 4

346. 0
When 2 Moles of Zn(s) is oxidized at 298 K, in Daniel cell Ecell 
 1.1V , the standard 
 
Gibbs free energy change G 0 in kJ mol 1 , is closed to
 a) -212.3 b) -106.2 c) -424.6 d) -53.1

347. Number of P-O bonds in P4O6 molecule is

a) 6 b) 8 c) 12 d) 16

348. The adsorption isotherm for a gas is given by the relation x = ap/ (l + bp) where x is
moles of gas adsorbed per gram of the adsorbent, p is the pressure of the gas, a and b are
constants. Then correct statement is

a) x increases with p

b) x remains unchanged with p

c) x decreases with p

d) x increases with p at low pressures and then remains the same at high pressure

349. XeF6 on hydrolyses to give an oxide. The structures of XeF6 and the oxide,

respectively, are-

a) octahedral and tetrahedral

b) distorted octahedral andpyramidal

c) octahedral and pyramidal

d) distorted octahedral and tetrahedral

350. When MnO4 oxidizes separately (i) oxalate ion in acidic medium (ii) HCl. The ratios of

 MnO4 : C2O42  in (i) and  MnO4 : HCl  in (ii), in the respective balanced chemical

equations are respectively

a) 1:5 and 2:5 b) 2:5 and 1:8 c) 2:5 and 1:5 d) 5:2 and 1:8

351. The electron in hydrogen atom is in the first Bohr’s orbit (n=1). The ratio of electronic
transition energies,
 E  n  1  n  3 to E  n  1  n  2 , is

a) 32/27 b) 16/27 c) 32/9 d) 8/9

352. What is the major product of the following reaction sequence?

O
1SOCl2 (excess)
HO  CH 2 C OH 
 2CH3ONa1 eq 

O O
a) b)
Cl  CH 2 C Cl ClCH 2 C O  CH 3

O O
c) d)
CH 3  O  CH 2 C CH 3 CH3 O CH2 C Cl

353. 29.5 mg. of an organic compound containing nitrogen was digested according to

Kjeldahl’s method and the evolved NH 3 gas was absorbed in 20 mL of 0.1 M HCl solution. The

excess of acid required 15 mL of 0.1 M NaOH solution for complete neutralization. The

percentage of nitrogen in the compound is:

a) 29.5 b) 59.0 c) 47.4 d) 23.7

354. Which of the following statement(s) are correct.

(i) More number of oxidation states are exhibited by the actinoids than those by the
lanthanoids due to lesser energy difference between 5f – and 6d – in actinoids than 4f –
and 5d – orbitals in lanthanoids.
 (ii) There is a gradual decrease in the radii of the trivalent ions with the increasing atomic
number in the lanthanoids series.

(iii) The 5f-orbitals are deeply seated than the 4f-orbitals in the atom.

(iv) Zr and Hf have about the same raidus due to lanthanoid contraction

a) (i), (ii), (iv) b) (i), (ii), (iii)

c) (i), (ii) d) (i), (ii), (iii), (iv)

355. With reference the scheme given, which of the given statement(s) about T ,U ,V and W is
(are) correct?

O
T 
H 3C
LiAlH 4
  
 CrO3 / H 
V   
U  Excess of W 
  CH 3CO 2 O

(i) T is soluble in hot aqueous NaOH

(ii) U is optically active

(iii) Molecular formula of W is C10 H18O4

(iv) V gives effervescence with aqueous NaHCO3

a) (i), (ii), (iii) b) (i), (iii), (iv) c) (i), (ii), (iv) d) (i), (iii)

356. Choose the correct reason(s) for the stability of the lyophobic colloids.

i) Preferential adsorption of ions on their surface from the solution

ii) Perferential adsorption of solvent on their surface from the solution

iii) Attraction between different particles having opposite charges on their surface
 iv) Potential difference between the fixed layer and the diffused layer of opposite charges
around the colloidal particles.

a) (i), (ii), (iii) b) (i), (iii), (iv)

c) (i), (ii), (iv) d) (i), (iv)

357. Which of the following statement(s) are correct.

(i)   D      glucopyranose and   D      glucopyranose are anomers.

(ii) The change in optical rotaion of freshly prepared solution of fructose with time is

known as mutaroation

(iii) Sugars can be detected by Molish’s test.

(iv)Synthesis of each molecule of glucose in photosynthesis involves 10 molecules of

ATP.

(v) Biuret test is given by proteins.

a) (i), (ii), (iv), (v) b) (ii), (iii), (v)

c) (i), (ii), (iii), (v) d) (i), (ii), (iii), (iv), (v)

358. In which of the following arrangements, the sequence is not strictly according to the
property written against it?

a) HF  HCl  HBr  HI : increasing acid strength

b) NH 3  PH 3  AsH 3  SbH 3 : increasing basic strength

c) B  C  O  N : increasing 1st ionization enthalpy

d) GeO2  SnO2  PbO2 : increasing oxidizing power

359. Four coins of the same size are placed on the corners of a square in such a way that their
centre’s coincide with the corners of the square. Radius of coins is R and edge of square
is 2R . What is maximum radius of a coin that can be placed in the gap of the above
square?

a) 0.155 R b) 0.225 R c) 0.414 R d) 0.732 R

360. During the extraction of iron in the blast furnace,

a) Coke acts as reducing agent in the lower zone and CO acts as reducing agent in the
upper zone

b) CO acts as reducing agent in the lower zone and Coke acts as reducing agent in the
upper zone

c) Coke acts as reducing agent in the lower zone and CO acts as reducing agent in the
lower zone

d) CO acts as reducing agent in the upper zone and Coke acts as reducing agent in the
upper zone

361. When dry chlorine is passed through silver chlorate heated to 90°C then the oxide of
chlorine obtained is

1) ClO2 2) Cl2O 3) ClO3 4) Cl2O7

362. With limited supply of NH 3 , F2 gives:

1) N 2 2) N2 H 4 3) NF3 4) HN3

363. Relation between given pair is:

Cl H Cl
H

H H
OH HO

1) Enantiomer 2) Diastereomers 3) Identical 4)Structuralisomer

364. When sulphur dioxide is passed into acidified K 2Cr2O7 solution, the oxidation state of
sulphur changes from:
 1) +4 to +6 2) +6 to +4 3) +4 to 0 4) +4 to +2

365. A gas obeys the equation of state P(V–b) = RT, where ‘b’ is a constant. The slope of an
isochore will be

R
1) – ve 2) zero 3) 4) R / P
V- b

366. Which reaction can be used to prepare phosphoric acid?

1) P2O3  H 2O   2) P2O3  H 2O  

0 0
20 C 80 C

3) P2O3  H 2O   4) P4  conc.HNO3 

0
25 C

367. The correct order of stability of the following carbanions is

O CH3 NH CH3 S CH3

H3 C H3 C H3 C
CH3 CH3 CH3
P Q R

1) R>Q>P 2) R>P>Q 3)Q>P>R 4) P>Q>R

368. The figure depicts, the unit cell for a compound containing atoms A (filled circles) and B
(open circles). The empirical formula of the compound is

1) AB 3) AB2 3) A2B 4) A6B

369. The stability of dihalides of Si, Ge, Sn and Pb increases steadily in the sequence:

1) GeX 2  SiX 2  SnX 2  PbX 2 2) SiX 2  GeX 2  PbX 2  SnX 2

3) SiX 2  GeX 2  SnX 2  PbX 2 4) PbX 2  SnX 2  GeX 2  SiX 2

370. The order of acidity of positions X, Y and Z is

 F
z
NO 2

HO
x y

1) x>y>z 2) y>x>z 3) z>x>y 4) x>z>y

371. The correct Lewis acid order for boron halides is:

1) BF3  BCl3  BBr3  BI3 2) BCl3  BF3  BBr3  BI3

3) BI3  BBr3  BCl3  BF3 4) BBr3  BCl3  BI3  BF3

372. The correct relationship between the pH of equimolar solutions of (a)sodium oxide,
(b)sodium sulphide, (c)sodium selenide and (d)sodium telluride is

1) a >b >c >d 2) a <b <c = d 3) a <b <c <d 4) a >b =c >d

373. In a closed system: A(s) 2B(g) + 3C(g), if the partial pressure of C is doubled
keeping temperature same, then partial pressure of B will be:

1) dependent on KP of the reaction 2) Two times the original value

1
3) times the original value 4) 2 2 times its original value
2 2

374. The solubility of sulphates of alkaline earth metals in water shows the order:

1) Be  Ca  Mg  Ba  Sr 2) Mg  Be  Ba  Ca  Sr

3) Be  Mg  Ca  Sr  Ba 4) Mg  Ca  Ba  Be  Sr

375. Na2 S2O3 is oxidised by I 2 to :

1) Na2 S 2) Na2 SO4 3) Na2 HSO3 4) Na2 S4O6

376. The most stable canonical structure of given molecule is

 O

+ + +
O O O O
(A) (B) (C) + (D)

377. For a chemical reaction A  B  C , rate constant is found to be K  6 103 lit mol 1s 1
0.1M 5M

. Half life of the reaction will be

1) 23 s 2) 46s 3) 115 s 4) 23 min

378. For alkali metals, which one of the following trends is incorrect?

1) Hydration: Li  Na  K  Rb 2) ionization energy:

Li  Na  K  Rb

3) Density: Li  Na  K  Rb 4) atomic size: Li  Na  K  Rb

379. The O  O bond length in O2 , O2  AsF4  and K O2  is:

1) O2  AsF4   O2  K O2  2) O2  AsF4   K O2   O2

3) O2  O2  AsF4   K O2  4) K O2   O2  O2  AsF4 

380. The correct bond order for NO and NO  are respectively

1) 3,5/2 2) 3,2 3) 3,7/2 4) 5/2,3

381. The major product in the following reaction sequence is

 1) 2)

3) 4)

382. Half-life of an element is ‘t’ seconds. In t/2 seconds, the percentage of the element
decayed is ( Anti Log 0.1505 = 1.414 )

1) 29% 2) 25% 3) 21% 4) 17%

383. The order of SN1 reactivity of the following halides,

(i) (CH3)3C Br (ii) (C6H5)2CH Br

(iii) (C6H5)2C (CH3) Br (iv) (CH3)2 CH Br

1) iv > i > ii > iii 2) ii > i> iii > iv

3) i> iii > ii > iv 4) iii > ii > i> iv

384. Cleaning action of soap occurs because:

1) non-polar tails of soap molecules dissolve in grease

2) oil and grease dissolved into hydrophilic centres of soap micelles acid washed away

3) hydrophilic head dissolve in grease

4) grease dissolve in soap solution

385. Which of the following reagents converts both acetaldehyde and acetone to alkanes?
1) Ni / H 2 2) LiAlH 4

3) I 2 / NaOH 4) Zn  Hg / con  HCl

386. The freezing point of aq. Solution which contains 5% by mass urea (60), 1% by mass
KCl (74.5) and 10% by mass of glucose (180).  k f H O  1.86 K molal 1
2

1) 290.2 K 2) 285.5 K 3) 269.32 K 4) 250 K

387. Which will give positive isocyanide test

 NH2
H3C H3C NH

1) CH3 2) CH3

CH3
H3C H3C N

3) NH CH3 4) CH3

388. An ester used as medicine is

1) ethyl acetate 2) methyl acetate

3) methyl salicylate 4) ethyl benzoate

389. If Ksp of certain silver salts are as follows: AgI<AgBr<AgCl I II III

Then the cell constructed by dipping a silver rod in the above individual saturated
solutions, the reduction potential measured will be in the order of

1) I > II > III 2) II > III > I

3) III > II >I 4) III > I > II

390. Terylene is a condensation polymer of ethylene glycol and

1) benzoic acid 2) acetic acid

3)terephthalic acid 4) salicylic acid

391. Among the following hydroxides the one with lowest value of Ksp at ordinary
temperature.

A) Ba  OH 2 B) Mg  OH 2 C) Ca  OH 2 D) Be  OH 2

392. Which of the following pairs can be distinguished by action of heat

1) Na2CO3 and CaCO3 2) MgCl2 .6H 2O and CaCl2 .6H 2O 3) Ca  NO3 2 and NaNO3

A) 1 and 2 B) 1,2 and 3 C) 1 and 3 D) 1 only

B2 H6 .2 NH3   X  Y g 
0
200 C
393.
 Number of double bonds in X.

A) 3 B) 2 C) 4 D) 1

H3 PO4   X  Y . The hybridization of ‘P’in X and Y.

0
200 C
394.

A) sp 2 and sp 2 B) sp3 and sp C) sp and sp 2 D) sp3 and no

hybridization

395. H2SO4 is used to dry which of the following gases?

A) H2S B) CO2 C) NH3 D) all of these

396. Lowest boiling point is associated with

A) HF B) HCl C) HBr D) HI

397. SiO2  3H 2 F2  X  2H 2O . During the formation of ‘X’ an intermediate product ‘Y’ is

formed. Hybridization of central atom in X and Y respectively

A) sp3d 2 , sp 2 B) sp3d , sp3 C) sp3d 2 , sp3 D) sp3d , sp3d 2

398. The percentage by volume of C3H8 in a mixture of C3H8, CH4 and CO is 36.5. Calculate
the volume of CO2 produced when 100 ml of the mixture is burnt in excess of O2

A) 173 mL B) 253 mL C) 168 mL D) 223 mL

399. A complex is prepared by mixing CoCl3 and NH3. 0.1M solution of the complex was
found to freeze at 0.3720 C . The formula of the complex is (molal depression constant
of water = 1.86 0 C / m )

A) Co  NH 3 6  Cl3 B) Co  NH 3 5 Cl  Cl2

C) Co  NH 3 4 Cl2  Cl D) Co  NH 3 3 Cl3 

3
400. Magnetic moment of Cr  CN 6  ion if it is a inner orbital complex.

A) 5.92 B.M B) 1.73 B.M C) 2.828 B.M D) 3.9 B.M

CH 3
H

X

401. O OH
 The product ‘X’ is

CH 3 CH 3

A) O OH B) HO OH

CH 3 CH 3

C) O D) O

N 
Br2
Fe
 The Major Product formed is
402.
O O
Br

N N Br

A) B)
O

Br
O
N

C) Br D)

CH 3

HOBr
'X '
403. . No. of atoms undergoing tetrahedral hybridization in X.

A) 7 B) 6 C) 8 D) 9

  A  . (A) is
2
404. Ph  C  C  CH 3 
Hg
H
 O
Ph Ph
O

H 3C H 3C
A) B)

OH
Ph Ph
OH
H 3C H 3C
C) D)

405. Which of the following readily undergo SN1 mechanism

Br CH 3
Br CH 2 CH 2 Br

A) CH 3 Br B) C) D)

406. The appropriate reagent for the following transformation

CH 3

HO
HO

NH 2  NH 2 / OH
A) Zn  Hg  / HCl B)

C) H 2 / Ni D) H 2 / Pd  BaSO4 / Quinoline

407. What is the shortest wavelength line in the Paschen series of Li 2  ion ?

R 9 1 9R
B) C) D)
A) 9 R R 4
408. A certain hydrate has the formula MgSO4 .xH2O .A quantity of 54.2 g of the compound is
heated in an oven to drive off the water .If the steam generated exerts a pressure of 24.8
atm in a 2.0 L container at 1200 C , calculate x.
 A) 2 B) 5 C) 6 D) 7
409. Poly caprolactum is

B) Perlon-L C) Dacron D)Glyptal

A) Nylon 6,6
410. Calculate H 0f for UBr4 from the G 0 of reaction and the S 0 values of U (s),
Br2 (l ) and UBr4 (s) are 50.3,152.3,242.6 (J / K – mol) respectively

U  S   2Br2  l   UBr4  s  ; G0  788.6kJ mole1;

A) -822.1 kJ/mol B) -841.2 kJ/mol

C) -775.6 kJ/mol D) -804.3 kJ/mol
411. The equilibrium constant Kc for the reaction

P4  g  ƒ 2P2  g  Is 1.4 at 4000C. Suppose that 3 moles of P4  g  and 2 moles of P2  g 

are mixed in 2 litre container at 4000 C . What is the value of reaction quotient (Q)?

3 2
A) B) C) 1 D) 4/3
2 3

412. 20 amino group is present in

A) Tyrosine B) Lysine C) Proline D) Serine

413. In the following reaction A  B  C , rate constant is 0.001 Ms 1 . If we start with 1 M

of A then conc.of A and B after 10 minutes are respectively:

A) 0.5 M , 0.5 M B) 0.6 M , 0.4 M

C) 0.4 M , 0.6 M D) 0.2M, 0.8 M

414. The radioactive decay 83 Bi 211 81 Tl 207 , takes place in 100 L closed vessel at 27 0 C .
Starting with 2 moles of 83 Bi 211  t1/ 2  130sec  , the pressure development in the vessel
after 520 sec will be :

A) 1.875 atm B) 0.2155 atm C) 0.4618 atm D) 4.618 atm

415. pK a of NH 4 is 9.26. Hence, effective range for NH4OH  NH4Cl buffer is about pH :

A) 8.26 to 10.26 B) 4.74 to 5.74

C) 3.74 to 5.74 D) 8.26 to 9.26

416. Which of the following is most soluble in water ?

 A) Ba3  PO4 2  K sp  6 1039  B) ZnS  K sp  7 1016 

C) Fe  OH 3  K sp  6 1038  D) Ag3  PO4   K sp  1.8 1018 

417. A 100.0 mL dilute solution of Ag  is electrolyzed for 15.0 minutes with a current of
1.25 mA and the silver is removed completely. What was the initial  Ag   ?

A) 2.32 101 B) 2.32 10 4 C) 2.32 103 D) 1.16 104

418. The Nernst equation E  E 0  RT / nF ln Q indicates that the Q will be equal to

equilibrium constant Kc when

A) E  E 0 B) RT / nF  1 C) E = zero D) E 0  1

419. Which of the following expressions is correct in case of a CsCl unit cell
(edge length, a)?

A) rc  ra  a B) rc  ra  a / 2 C) rc  ra  3a / 2 D) rc  ra  a / 2

420. On adding AgNO3 solution into KI solution , a negatively charged colloidal sol is
obtained when they are in :

A) 50 ml of 0.1 M AgNO3 + 50 ml of 0.1 M KI

B) 50 ML of 0.1 M AgNO3 + 50 ml of 0.2 M KI

C) 50 ML of 0.2 M AgNO3 + 50 ml of 0.1 M KI

D) 50 ML of 0.2M AgNO3  25 mL 0.4 M KI

+
OH O - Li

+
421. What is/are the product(s) of the above reaction?
+
O - Li OH

1) O 2)
+
 3) 4) HO OH

422. Identify the correct statement of the following

a) Hypo forms super saturated solutions

b) on thermal decomposition hypo gives H2S, SO2 and S.

c) Dilute sodium thio sulphate, on reaction with AgNO3 finally gives black ppt. of Ag2S

d) AgBr can be used in making photo graphic films.

1) A, B, C 2) B, C, D 3) A, C, D 4) A, B, C, D
423 Specify the coordination geometry around and hybridisation of N and B atomsina 1 : 1
complex of BF3 and NH3

1) N : tetrahedral, sp3 ; B–tetrahedral, sp 3

2) N–Pyramidal, sp3; B–pyramidal, sp 3

3) N–pyramidal, sp3; B–planar, sp2

4) N–pyramidal, sp3; B–tetrahedral – sp3

424 Two components A and B form an ideal solution. The mole fractions of A and B in ideal
solution are XA and XB, while that of in vapour phase, these components have their mole
1 1
fractions as YA and YB. Then, the slope and intercept of plot of vs will be :
YA xA

PA0 PB0  PA0 PB0 PA0  PB0 PB0 P0 PA0

1) , 2) . 3) , 0 B 0 4) PA0  PB0 ,
PB0 PB0 PA0 PA0 PA P3  PA
0
PB0

425. Which of the following compounds posses a chiral centre?

H OH H OH
H Br
Cl Br
1) 2) 3) 4)

CH2 CH2

426 Which of the following has the minimum heat of dissociation:

1) [(CH3)3N  BF3] 2) [(CH3)3N  B(CH3)F2]

3) [(CH3)3N  B(CH3)2F] 4) [(CH3)3N  B(CH3)3]

427 Which among the following is most soluble in water?

1) CsClO4 2) NaClO4 3) LiClO4 4) KClO4

428 For Adiabatic free expansion (Pext = 0) of an ideal gas

1) Ssurrounding = 0 2)Ssurrounding < 0 3)Ssurrounding > 0 4) Ssystem = 0

429 C6H5–CO–CH2–CH2 –CH2–COOH  C6H5–CO–CH2–CH2–CH2–CD2OH.

This conversion is done by

1) NaBH4 / H3O+ followed by LiAlD4 / H2O

2) LiAlD4 / H2O followed by NaBH4 / H3O+

3) (CH2OH)2 followed by LiAlD4 / H3O+

4) DMgBr / H3O+

430 On heating potassium ferrocyanide with conc. H2SO4 produces a neutral gas ‘A’. The gas
‘A’ on treatment with caustic soda under high pressure produced ‘B’, what are ‘A’ and
‘B’ respectively.

1) CO2, Na2CO3 2) SO2, Na2SO4 3) CO, HCOONa 4) NO2, NaNO3

431 Among the following statements, the incorrect one is :

1) Calamine and siderite are carbonates

2) Argentite and cuprite are oxides

3) Zinc blende and pyrites are sulphides

4) Malachite and azurite are ores of copper

432 Which of the following transition state is more stable in the nucleophilic substitution ?

Cl OH
Cl OH
Cl OH Cl OH
NO2 3)
2) 4)
1)
NO2
NO2 CH 3

433 An organic compound upon hydrolysis produces two compounds one product gave silver
mirror test, other product reacts with Hinsberg reagent to produce an alkali insoluble
product. The organic compound is
 O O
CH 3
1) || 2) H C N
CH 3  CH 2  C  NHCH 3 CH 3

O O
3) 4)
CH 3 CH 2 C NH 3 H C NH CH 2 CH 3

434 100 ml of a sample of hard water after passing through cation exchange resin, required
20ml of 0.05M NaOH for neutralisation. One litre of same sample of water on treatment
with sufficient lime gave 200mg of CaCO3. Assuming that the hardness is only due to
Ca+2 ions. Find the degree of permanent hardness of water.

1)300ppm 2)150ppm 3) 100ppm 4) 200ppm

435 Calculate the pH at which Mg(OH)2 begins to precipitate from solution containing
0.1 M Mg+2 ions. Ksp for Mg(OH)2 is 1.0 x 10–11

1) 4 2) 9 3) 5 4) 8

436 Arrange the following bromides in the increasing order of reactivity towards AgNO3

A) B) C)

Br Br Br

1) C  A  B 2) C  A  B 3) B  A  C 4) A  B  C

437 Shape of MnO 4 and hybridization of Mn in MnO 4 are respectively

1) Tetrahedral, sp3 2) Tetrahedral, d3s

3) Sq. planar, dsp2 4) sq. planar sp2d

438. Bond dissociation energy of XY, X2 and Y2 (all diatomic molecules) are in the ratio
1:1: 0.5 and Hf of XY is –200 kJ mol–1. The bond dissociation energy of X2 will be:

1) 800 kJ mol–1 2) 200 kJ mol–1

 3) 300 kJ mol–1 4) 400 kJ mol–1

439. Which of the following pairs of structures do not represent tautomers?

OH O

1) and

CHO CHOH

O O

C C
OH
2) and O

CHO
OH
H

O OH

3) and
N N
H

CHO CH 2OH

H OH C O
4) and
HO H H OH

CH 2OH CH 2OH

440. Consider a titration of potassium dichromate solution with acidified Mohr’s salt solution
using diphenylamine as indicator. The number of moles of Mohr’s salt required per mole
of dichromate is

1) 3 2) 4 3)5 4)6

441 The compound insoluble in acetic acid is

1) Calcium oxide 2) Calcium carbonate

3) Calcium oxalate 4) Calcium hydroxide

442

O O

OH- O + CHX 3

X2
 Which of the following is correct comparison of rate of haloform reaction with various
halogens ?

1) rCl2 > rBr2 > rI2 2) rI2 > rBr2 > rCl2

3) rBr2 > rCl2 > rI2 4) rCl2  rBr2  rI2

443. A complex of certain metal has the magnetic moment of 4.91 BM whereas another
complex of the same metal with same oxidation state has zero magnetic moment. The
metal ion could be…… and if that metal ion forms a complex with EDTA, then its EAN
would be……

1) Co2+,36 2) Mn2+,38 3) Fe2+,36 4) Ag+ ,36

444 Of the following metals, which one cannot be obtained by electrolysis of the aqueous
solution of its salt is

1) Ag 2)Mg 3) Cu 4)Au

445. The major product of the following reaction is

RCH2OH

+
O H (anhydrous)

(1) A hemiacetal (2) An acetal (3) An ether (4) An ester

446 The compressibility of a gas is less than unity at STP. Therefore,

1) Vm  22.4 L 2) Vm  22.4 L 3) Vm  22.4 L 4) Vm  44.8 L

447 Nitrogen dioxide cannot be obtained by heating

1) KNO3 2) Pb(NO3)2 3) Cu(NO3)2 4) AgNO3

CN

448. The IUPAC name of O is

 1) 2-methyl-3-(1-methylethyl)-4-oxopentanenitrile

2) 4-cyano–3-(1-methylethyl)–2–pentanone

3) 3-acetyl–2–cyano–4–methylpentane

4) 3–ethanoyl–2–methyl–3–(1–methylethyl) pentanenitrile

449. For the electrochemical cell, M |M+|| X–| X, E(M+|M) = 0.44 V and E
(X/X–) = 0.33 V. From this data one can deduce that

1) M + X  M+ + X– is the spontaneous reaction

2) M+ + X–  M + X is the spontaneous reaction

3) Ecell = 0.77 V

4) Ecell = –0.77 V

450. The exhausted permutit is generally regenerated by percolating through it a solution of:

1) Sodium chloride 2) Calcium chloride

3) Magnesium chloride 4) Potassium chloride

451. An organic compound X on treatment with pyridium dichromate in

dichloromethane gives compound Y. compound Y reacts with I 2 and alkali
to form idoform. The compound X is

1) C2 H 5OH 2) CH 3CHO 3) CH 3COCH 3 4) HCHO

452. In which pair the first atom or ion is not larger than the seconds?

1) N , F 2) Cl  , Cl 3) O, S 4) Fe2 , Fe3

453. Which of the following reagent can form a phenyl hydrazone with alkanone?


1) NH 3OHCl  2) PhNHNH 2 3) NH 2 NHCONH 2 4) HCN
454. Which of the following will give(s) cannizaro reaction ?

I) formaldehyde II) acetaldehyde III) benzaldehyde IV)benzophenone

1) I, III, IV only 2) I & IV only 3) I & III only 4) I only

455. A sudden jump between the values of second and third ionization energies of

an element would be associated with the electronic configuration:

1) 1s 2 , 2s 2 , 2 p 6 ,3s1 2) 1s 2 , 2s 2 , 2 p6 ,3s 2 ,3 p1

3) 1s 2 , 2s 2 , 2 p6 ,3s 2 ,3 p2 4) 1s 2 , 2s 2 , 2 p6 ,3s 2

456. Which gives maximum hydrated form?

1) HCHO 2) C6 H 5CHO 3) Cl3C  CHO 4) CH3 3 C  CHO

457. Electron affinity of:

1) Carbon is greater than oxygen 2) sulphur is lesser than oxygen

3) Iodine is higher than bromine 4) bromine is lesser than chlorine

NaBH4
458. 
H O 
HBr
 
Mg / Ether
CH 2O , H 3O 
 
PCC
CH Cl

 product
2 2 2

The product is

O
H O
OH
OH CH3
OH H
1) 2) (3) 4)
459. The correct stability order for N 2 and its given ions is:

1) N 2  N 2  N 2  N 22 2) N 2  N 2  N 2  N 22

3) N 2  N 2  N 2  N 22 4) N 2  N 2  N 2  N 22

460. In the following reaction,X and Y are respectively


CH 3COOH  NH 3  X   Y  H 2O

1) CH3CONH 2 , CH 4 2) CH3COONH 4 , CH3CONH 2

3) CH3CONH 2 , CH 3COOH 4) CH3 NH 2 , CH3CONH 2

461. The correct order for bond angles is:

1) NO2  NO2  NO2 2) NO2  NO2  NO2

3) NO2  NO2  N 02 4) NO2  NO2  NO2


462. Consider the following reactions CH 3COOH  A   B , the compound
CaCO3

B is

1) an ether 2) an alcohal 3) an aldehyde 4) a ketone.

463. The correct order of increasing bond angles is:

1) PF3  PCl3  PBr3  PI3 2) PF3  PBr3  PCl3  PI3

3) PI3  PBr3  PCl3  PF3 4) PF3  PCl3  PBr3  PI3

464. Which of the following compounds will dissolve in an alkali solution after it
has undergone reaction with Hinsberg reagent?
 NH2 CH3
H3C H3C NH H3C H3C N

1) CH3 2) CH3 3) NH CH3 4) CH3

465. Atomic hydrogen is obtained by:

1) Electrolysis of heavy water

2) reaction of water with heavy metals

3) Thermal decomposition of water

4) passing silent electric discharge through hydrogen at low pressure

466. Among the following the strongest base is

1) Acetanilide 2) Succinimide 3) Benzamide 4) Benzyl amine

467. Maximum concentration of Ortho  H 2 in ordinary hydrogen at Room
temperature is:

1) 75% ortho  H 2  25% para  H 2 2) 25% ortho  H 2  75% para  H 2

3) 50% ortho  H 2  50% para  H 2 4) 99% para  H 2  1% ortho  H 2

468. During the test for halogens, sodium extract is heated with conc HNO 3. The
reason for this is

1)To decompose NaCN and Na2S 2)Na2S is soluble in HNO3

3)NaCN is soluble in HNO3 4)Silver halides are insoluble in

HNO3

469. Calgon (a water softener) is

 1) Na2  Na4  PO3 6  2) Na4  Na2  PO3 6  3) Na2  Na4  PO4 6  4) Na4  Na2  PO4 6 

470. A disaccharide which gives only glucose on hydrolysis is

1)Lactose 2)Fructose 3)Sucrose 4)Maltose

471. Na2CO3  Fe2O3  A  CO2 ; A is

1) NaFeO2 2) Na3 FeO3 3) FeO4 4) Na2 FeO2

472. In Lassiagnes test, the organic compound is fused with a piece of sodium
metal in order to

1)Increase the ionization of the compound

2)Decrease the melting point of the compound

3)Convert the ionic compound into a mixture of covalent compounds

4)Convert the covalent compound into a mixture of ionic compounds

473. The stability of the following alkali metal chlorides follows the order:

1) LiCl  KCl  NaCl  CsCl 2) CsCl  KCl  NaCl  LiCl

3) NaCl  KCl  LiCl  CsCl 4) KCl  CsCl  NaCl  LiCl

474. Which amino acid doesn’t evolve nitrogen gas on react with nitrous acid
(HNO2) ?
1) cysteine 2) proline 3) histidine 4) arginine
475. The magnetic moment of KO2 at room temperature is

1) 1.41 B.M 2) 1.73 B.M 3) 2.23 B.M 4) 2.64 B.M

476. Which alkaline earth metal nitride is volatile?

 1) Be3 N 2 2) Mg3 N2 3) Ca3 N2 4) none of these

477. A drug that is antipyretic as well as analgestic is

1) chloropromazine hydrochloride 2) para-Acetamidophenol

3) chloroquin 4) penicillin

H3C O

478. The compound OH is used as

1) antiseptic 2) antibiotic 3) analgestic 4) pesticide

479. BeF2 is soluble in water whereas fluorides of other alkaline earth metals

insoluble because of

1) Ionic nature of BeF2

2) covalent nature of BeF2

3) Greater hydration energy of Be2 ion as compared to its lattice energy

4) None of these

480. Which of the following gives propyne on hydrolysis:

1) Al4C3 2) CaC2 3) B4C3 4) Mg 2C3

481.

O O

X 2 OH O
  CHX 3
Which of the following is
correct comparison of rate of haloform reaction with various halogens?

a) rCl  rBr  rI
2 2 2
b) rI  rBr  rCl
2 2 2
c) rCl  rBr  rI
2 2 2
d) rBr  rCl  rI
2 2 2


Br2 / CH 3COOH
 A 
Li2CO3
DMF
B
482.

Which of the following statement is not correct about the above reaction

a) Br  is attacking group in the reaction

b) Recemisation takes place in the formation of A

c) Formation of ‘B’ involves an elimination reaction

d) Enolisation does not takes place in the reaction

483. The following is not an anti depressant drug

a) Seldane b) Iproniazid c) phenelzine d) equanil

484. Non-narcotic analgesic among the following

a) Morphine b) heroin c) aspirin d) codeine

485. Which of the following undergoes cannizaro reaction?

 I) HCHO II) C6 H 5CHO III) H 3C CHO IV) CH3 3 C CHO

a) Only I and II b) Only II and III c) Only III and IV d) I,II and IV

486. A substance C4 H10O on oxidation yields compound C4 H 8O . Which gives an

oxime and a positive iodoform test. The original substance on treatment with
conc. H 2 SO4 gives C4 H 8 . The compound is

a) CH3CH 2CH 2CH 2OH b) CH3CHOHCH 2CH3

c)  CH3 3 COH d) CH3CH 2  O  CH 2CH3

487. Identify the product of the following condensation reaction.

a) b) c) d)

488. Which is the best hydride donor?

H H H R C  O
| | | |
a) R  C  O  b) R  C  O  c) R  C  Cl d) H
| | |
OH O H

489. The following is a bacteriostatic antibiotic

a) Penicillin b) erythromycin c) Aminoglycosides d) Ofloxacin

490. The following is a narrow spectrum antibiotic

a) Penicillin-G b) ampicillin c) amoxycillin d) vancomycin

491. The following is not an antiseptic

a) Furacine b) soframicine c) bithionol d) salvarsan

492. The following is a cationic detergent

a) Sodium laurylsulphate b) sodium dodecylbenzene sulphonate

c) cetyltrimethyl ammonium bromide d) sodium stearate

493. On vigorous oxidation by permanganate solution CH3 2 C  CH  CH2CHO

gives

a) CH3 2 CO and OHC  CH2  CHO

 CH3 2 C  CH  CH 2  CHO
| |
b) OH OH

c) CH3 2 CO and OHC  CH2  COOH d)  CH3 2 CO and CH 2 COOH 2

OH O
| K1
||
494. A. CH 3  C  CN CH 3  C  CH 3  HCN
|
CH 3
 OH O
| K2
||
B. CH 3  C  CN CH 3  C  H  HCN
|
H

Relation between K1 and K2 is

a) K1  K2 b) K1  K 2 c) K 2  K1 d) K 2  2 K1

495. How many hydrogens are replaced by deuterium in the following reaction?

a) 1 b) 2 c) 3 d) 4

i  x  moles PCl5
496. 
  y moles NaNH 2  CH
ii 3  C  C  CH 3 , the sum, x + y is

a) 2 b) 3 c) 4 d) 5

497.
 How many molecules of RMgX will be consumed in the above given
reaction?

a) 2 b) 4 c) 5 d) 6

498.

a) b) c) d)

+ C Cl 
AlCl3

( X );
499.

O
a) C
b)

H C
c) d)
O

500. The high potency sweetener among the following

a) Aspartame b) Saccarin c) Sucrolose d) Alitame

501. The following is not a food preservative

a) Sodium benzoate b) salt of sorbic acid

 c) sodium stearate d) salt of propanoic acid

502 The following is not an anti septic

a) mixture of chloroxylenol & terpineol(dettol)

b) 2-3% I 2 in alcohol –water mixture (tincture of iodine)

c) boric acid on dilute aqueous solution

d) 0.2-0.4 ppm Cl2 in aqueous solution

503. Which of the following reagents is best used for the conversion shown
below?

a) 1.NaBH 4 / 2. D3O  b) 1.NaBD4 / 2. H 3O 

c) 1.LiAlH 4 / 2. D3O  d) 1.LiAlH 4 / 2. H 3O 

504.

a) Cyclic acetal b) Cyclic hemiacetal

c) Open chain acetal d) Open chain hemiacetal

505.
a) b) c) d)

506.

(B); Product of the Clemmensen reduction is :

a) b) c) d)

507. CH3  C  CH 

HgSO
dil . H SO
  A
2
4
4

 2 H O / HO  
1BH3 .THF
CH3  C  CH   B
2 2

Product (A) and (B) is differentiated by :

a) 2-4-DNP b) NaOI c) Na-metal d) NaHSO3

508.  A 
ii  Zn, H O   B  
i  O
3
2
NaOH

 the reactant (A) will be :

a) b) c) d)
509. An organic compound with the molecular formula C9 H10O forms a 2,4-DNP
derivative, reduces Tollen’s reagent and undergoes Cannizaro reaction, on
vigorous oxidation it gives 1,2-benzenedicarboxylic acid. Structure of
organic compound is:

a) b) c) d)

510. End product (C) of the reaction is :

 A    B    C 

2 PhMgBr HO
3

a) b) c) d)

511. Arrange the given alkyl halides in the increasing reactivity towards nucleophilic
substitution reactions

I) Cl II) Br

III) Cl IV) Br

1) II  III  I  IV 2) I  III  IV  II 3) II  I  III  IV 4) IV  I  II  III


512. The rate for the substitution reaction of 2-bromobutane and OH in 75% enthanol 25% water at
300 C is rate  3.2  10 5 [ 2-bromobutane] [ OH  ]+ 1.5  106 [2-bromobutane] what percent of
the reaction takes place by the SN mechantism, when OH   1.00M ?
2 1

1)96% 2) 94 % 3) 92 % 4) 93 %
513. What are the probable products formed in this reaction.
Br
NaC  CH
Product

C CH
I) II)

C CH

III) IV)

1) I, III, IV 2) II, III, IV 3) II, IV 4) III, IV

CH2-CH2-COOH
514. C7 H10 by ozonolysis from HOOC the degree of
unsaturation of C7 H10 is

1) 7 2) 3 3) 4 4) 5

515. The number of alkyl halides can be produced from monochlorination of the methyl cyclohexane
is ( excluding stereo isomers)

1) 7 2) 5 3) 8 4) 9

516. Arrange the following compounds in the order of leaving group ability


I) CH 3COO  II) OMe

O O
O S Me O S CF3

III) O IV) O

1) I  II  III  IV 2) IV  III  II  I

3) III  IV  I  II 4) IV  III  I  II
 CH 3COCl CH 3COOK 
A B C
517. O . The degree of unsaturation in compound ‘C’
is

1) 3 2) 4 3) 2 4) 5

518. 0.1 mol of a hydroxyl compound reacts with 62.5 g of PCl5 determine the number of OH
groups

1) 3 2) 4 3) 5 4) 6

519. Identify the set of reagent /reaction conditions ‘X’ and ‘Y’ in the following set of transformations

Br X Y
Product
Br
0 0
1) X = dil aq NaOH, 20 C ; Y = HBr/acetic acid 20 C

0 0
2) X = conc. alcoholic NaOH, 80 C ; Y = HBr/acetic acid 20 C

3) X = dil aq NaOH, Y = Br2 / CHCl3 , 00 C

0
4) X = concentrated alcoholic NaOH, 80 C ; Y = Br2 / CHCl3 , 00 C

 HCl  X

520. O ,’X’ will be

OH OH

Cl

1) OH 2) OH
 OH OH
Cl

OH Cl

3) OH 4) OH

521. Which of the following alcohol shows fastest reaction with H 

OH OH
OH

OH
1) 2) 3) 4)

OH

522. on reaction with PCl5 and then on reduction with LiAlH 4 forms

OTS

1) 2) 3) 4) None of these

H
Copper
HO
CH3 Chromate

523. HO ,

H
O
H CH3
O
1) CH3 2) O

O
O

3) O 4)

524. CH 3  Cl 
M1
 X 
M2I
 Y 
C2 H 5Cl
 C3 H 8 what are M1 and M 2 respectively?

1) Na, Mg 2) Li, Mg 3) Li, Cu 4) Na, Ag

 O CH2
525. when treated with HI produces

CH2I OH CH2OH I

1) 2)

I OH I

CH2 OH
3) 4)

SH SH
H
NaOH in
A(major)
Aq EtOH
C6H10S
526. H Cl H Major product of the above
reaction is

SH

S
1) H 2)

HO SH
3) 4)

OH

1. one Eq NaOH
OH A
2. MeBr
527. ,product (A) is
 OMe OH

OH OMe
1) 2)

OH

3) 4) None of these

528. Which of the following statements is correct regarding the rate of hydrolysis of the compounds
(A) and (B) by SN  reaction?

Br O Br

(A) (B)

1) A reacts faster than B 2) B reacts faster than A

3) Both A and B at the same rate 4) Neither A nor B reacts

529. Which describes the best product of the following reaction

CH3
K  t BuO 
CD 3
Major Product
Ph Br

1) Absolute configuration has been inverted 2) Absolute configuration has been

retained

3) Racemisation has occurred 4) Loss of chirality has occurred

530.

S C CH3 RO 

O C CH3

O
 SH SH

1) OH 2) OH

S O
3) 4)

531.

PBr3 Mg, ether

(A) (C) Grignard reagent H3O
(D) 3,4-dimethyl
Na2Cr2O7 3-Hexanol
(B)
H2SO4

When Grignard reagent reacts with (B) product (D) will obtained. Reactant (A) of the above reaction
is

1) OH 2) OH

OH

3) OH 4)

532. Which of the following would not rearrange to a more stable form

1) 2) 3) 4)

533. In which of the following reactions, two products will be formed other than phosphoniumylide
 POPh3 
O

 Ph3 P  CH 2
1) 2) CH3CHO  Ph3 P  C  CH3 2
 O
Ph  C  H  Ph3 P  CH  Ph 
3) 4) HCHO  Ph3 P  CH  CH 3

534.

Ph  CH 2  CH  CH 3 
Br2 / hv

D Product of the above reaction will be
.

1) racemic mixture 2) diastereomers 3)Mesocompounds 4) constitutional isomers

O O

O O O
(I) (II) (III) Among the given compounds, the correct order of enol
535.
content is

1) I  II  III 2) III  II  I 3) II  I  III 4) II  III  I

536. The synthesis of 3-octyne is achieved by adding a bromoalkane in to a mixture of sodium amide
and alkyne. The bromoalkane and alkyne, respectively are

1) BrCH 2CH 2CH 2CH 2CH 3 and CH 3CH 2C  CH

2) BrCH 2CH 2CH 3 and CH3CH 2CH 2C  CH

3) BrCH 2CH 2CH 2CH 2CH 3 and CH 3C  CH

4) BrCH 2CH 2CH 2CH3 and CH 3CH 2C  CH

537. Alkyl halides can be obtained by all methods except

1) CH 3CH 2OH  HX / ZnCl2  2) CH 2  CH  CH3 

SO2Cl2
475 K


3) C2 H 5OH  NaCl  4) CH3COOAg  Br2 / CCl4 

538. The no. of moles of HI required to convert glycerol to 2-Iodo propane is/are

1) One 2) Four 3) Three 4) Five

HBr(Excess)
OCH3
539. In the reaction the products are
 Br OCH3 Br
1) and H 2 2) and CH 3 Br

Br OH
3) and CH 3OH 4) and CH 3 Br

OH

NaOH(aq)/Br2

540. In the reaction an intermediate is not

O
O
O
H

Br H
1) 2) Br 3) Br 4) all the above

541. The number of alkynes that are possible with the formula C5 H8 is

1) 2 2) 3 3) 4 4) 5

542. The smallest alkyne which can exhibit optical isomerism is

1) 4-methyl-1-pentyne 2) 3-methyl-1-butyne 3) 3-methyl-1-pentyne 4) 4-methyl-2-pentyne

543. Consider the following sequence of reactions. CH3CH  CH2 

Br2 NaNH2
CCl4  
excess
H2O
 
H

The major end product formed is

1) propadiene 2) propyne 3) 3-chloropropene 4) 2-chloropropene

544. 1, 2-Dibromopropane is heated with one mole of alcoholic KOH. The reaction is expected to
produce

1) 1-bromopropene 2) 2-bromopropene 3) 3-bromopropene 4) all of these

545. Acetylide ion possesses

1) two  bonds, one  bond and one lone pair of electrons

 2) one  bond, two  bonds and one lone pair of electrons

3) one  bond, two  bonds and two lone pairs of electrons

4) one  bond, one  bond, one lone pair of electrons

546. Consider the following reaction sequence CH3C  CH 

CH3MgBr Ch3CH2Br
 I   II The
final product (II) formed is

1) CH3C  CCH3 2) CH3C  CCH2CH3

CH3
|
3) CH3C  CMgBr 4) CH  C  CHCH CH
3 2 3

547. Which of the following molecule is not linear?

1) OCCCO 2) CH 2  C  O 3) HC  C  C  CH 4) HC  CH

H3C
H H
C C
Pd  CaCO 3
C C CH3 + H 2   
PbO

C
H
CH3
548. Consider above reaction.

The IUPAC name of the product formed is

1) (2Z,4R,5E)–4–methyl-2, 5-heptadiene 2) (2E,4R,5Z)–4–methyl-2, 5-heptadiene

3) (2Z,4S,5E)–4–methyl-2, 5-heptadiene 4) (2E,3S,5Z)–3–methyl-2, 5-heptadiene

549. Acetylene is allowed to react with an excess of HCl in the presence of HgCl2 . The product formed
is

1) ethylene chloride 2) acetylene dichloride 3) ethylidene chloride 4) vinyl chloride

550. Consider the following reaction sequence. CH3C  CCH3   I   II The final
2 2Cl 4 Br /CCl
1 mole 1 mole

product (II) formed is

 1) 2, 2-dibromo-3, 3-dichlorobutane 2) 2-bromo-3-chloro-2-butene

3)     2,3  dibromo-2 3-dichlorobutane 4) meso-2, 3-dibromo-2, 3-dichlorobutane

551. Which of the following statements is correct?

1) Alkynes are more reactive than alkenes in both electrophilic and nucleophilic addition
reactions.

2) Alkynes are more reactive than alkenes in electrophilic addition reactions but less reactive in
nucleophilic addition reactions.

3) Alkynes are less reactive than alkenes in electrophilic addition reactions but more reactive in
nucleophilic addition reactions.

4) Alkynes and alkenes both have low reactivity in electrophilic addition reactions but both have
high reactivity in nucleophilic addition reactions.

552. Consider the following two reaction sequences.


1.BH 3
2.H O /OH 
P
2 2

PhC CH

 Aq
 
.H 2 SO 4
HgSO 4
Q

The two products (P) and (Q) are, respectively.

1) PhCOCH3 and PhCH 2CHO 2) PhCH 2CHO and PhCH 2CHO

3) PhCH 2CHO and PhCOCH3 4) PhCOCH3 and PhCOCH3

553. Consider the following reactions.

C H3

C H  C  C Na
O  H   A  Lindlar
2 B  
2
 4
C
H H SO
O
C H3 3
heat
catalyst

The products (A), (B) and (C), respectively, are

 OH OH CH 3
| | |
1)  CH  CC  CH,  CH  CC  CH and CH C  C  CH
3 2 3 2 3 2

OH OH CH3
| | |
2)  CH  CC  CH,  CH  C. HC  CH and CH  CCH  CH
3 2 3 2 2 2

O OH
|| |
3) CH  CHCH CCH , CH CH CH CHCH and CH CH CH  CHCH
2 2 3 3 2 2 3 3 2 3

4) HC  COCH  CH3 2 ,CH2  CHOCH  CH3 2 and  CH3CHO,CH3CH  CH2 

554. Which of the following is aromatic?

1) 10  Annulene 2) [6]-Annulene 3) [8]-Annulene 4) [4]-Annulene

555. In the nitration of benzene with a mixture of concentrated HNO3 and concentrated H2SO4 , the
active species involved is

1) NO 3 2) NO 2 3) NO 3 4) NO 2

556. Benzene reacts with n-propyl chloride in the presence of anhydrous AlCl3 to give predominantly

1) isopropylbenzene 2) n-propylbenzene

3) propiophennone 4) 1-chloro-3-propylbenzene

557. By which of the following sets of reagents can benzene be formulated to benzaldehyde in the
presence of anhydrous AlCl3 ?

1) HCHO and HCN 2) HCOOCH3 and HCl

3) CO and HCl 4) HCONH 2 and HCl

558. The correct order of decreasing reactivity of anisole (I), benzene (II) and nitrobenzene (III) towards
aromatic substitution with a given electrophile is
 1) II > III > I 2) III > II > I 3) II > I > III 4) I > II > III

559. Benzene is a resonance hybrid of the following reasonance contributors

I) II) III)

IV) V)

Which of the following statements is correct about the resonance?

1) All the above structures contribute equally

2) All the above structures represent real molecules

3) Structures III, IV and V are not planar

4) Structures I and II contribute equally and to the highest extent for resonance hybrid

560. Which of the following compounds is the most reactive towards aromatic substitution with a given
electrophile

1) Nitrobenzene 2) Aniline 3) Anilinium chloride 4) Acetanilide

561. Aromatic compounds burn with a sooty flame because

1) they have a ring structure

2) they are reluctant to react with atmospheric oxygen

3) they have a relatively high percentage of carbon

4) they have a relatively high percentage of hydrogen

562. Toluene, when treated with Br2 / Fe gives p-bromotoluene as the major product because the –CH3
group of toluene is

1) a meta-directing group

2) an ortho-directing group
 3) a para-directing group

4) an ortho-, para-directing group but o-bromotoluene suffers steric hindrance

563. The number of possible dichloronitrobenzene isomers is

1) 3 2) 4 3) 6 4) 8

564. Which of the following is an o-, p-directing but deactivating substituent in an electrophilic aromatic
substitution?

1) CCl3 2) Cl 3)  NHCOCH3 4) OCH3

565. Which of the following is the powerful meta-directing group?

1)  NO 2 2) SO3H 3) CHO 4) COOH

 HNO 3  conc.H
 2SO
4

566. is

NO2

NO2

NO2
NO2
1) 2) 3) 4)

 FeBr
Br2

3

567. The major product of the reaction

Br
1) 2) Br
 3) Br 4) Br

CCl 3

 Cl
2 / Fe

568. The major product formed in the reaction

C C l3 Cl C C l3

1) Cl 2)

C C l3

3) Cl 4) all in equal amounts

C O 
conc.HNO 3 /conc.H 2SO 4
 mononitration  
569. The major product formed in the reaction is

C O O

O2N C O
O2N
1) 2)

O
O
C O
C O O2N
O2N
3) 4)

570. Which of the following substituent deactivates the benzene ring towards electrophilic substitution?

1)  NHCH3 2) OH 3) OCH3 4) COOCH3

KEY & SOLUTIONS

1) 1 2) 2 3) 3 4) 1 5) 2 6) 2 7) 4 8) 3 9) 4 10) 1
11) 2 12) 4 13) 4 14) 1 15) 3 16) 2 17) 3 18) 4 19) 3 20) 4
21) 2 22) 3 23) 4 24) 2 25) 4 26) 2 27) 2 28) 4 29) 3 30) 4
31) 3 32) 4 33) 1 34) 3 35) 4 36) 3 37) 4 38) 3 39) 1 40) 4
41) 3 42) 1 43) 3 44) 3 45) 3 46) 1 47) 3 48) 2 49) 3 50) 3
51) 3 52) 2 53) 2 54) 4 55) 3 56) 2 57) 2 58) 3 59) 3 60) 1
61) 1 62) 1 63) 1 64) 4 65) 3 66) 2 67) 4 68) 2 69) 3 70) 1
71) 1 72) 3 73) 1 74) 4 75) 3 76) 1 77) 1 78) 3 79) 2 80) 1
81) 4 82) 1 83) 3 84) 1 85) 3 86) 1 87) 2 88) 2 89) 1 90) 1
91) 2 92) 2 93) 2 94) 3 95) 1 96) 1 97) 2 98) 3 99) 2 100) 3
101) 1 102) 1 103) 2 104) 3 105) 1 106) 3 107) 4 108) 3 109) 2 110) 1
111) 3 112) 3 113) 3 114) 2 115) 3 116) 4 117) 3 118) 4 119) 3 120) 3
121) 3 122) 1 123) 2 124) 4 125) 1 126) 1 127) 2 128) 2 129) 4 130) 2
131) 4 132) 3 133) 3 134) 3 135) 3 136) 4 137) 1 138) 2 139) 3 140) 4
141) 1 142) 1 143) 1 144) 3 145) 4 146) 1 147) 2 148) 4 149) 2 150) 4
151) 3 152) 2 153) 3 154) 4 155) 3 156) 1 157) 3 158) 1 159) 2 160) 4
161) 1 162) 1 163) 3 164) 2 165) 1 166) 2 167) 4 168) 2 169) 3 170) 2
171) 1 172) 3 173) 2 174) 3 175) 2 176) 3 177) 2 178) 1 179) 3 180) 1
181) 2 182) 3 183) 1 184) 2 185) 1 186) 4 187) 1 188) 1 189) 1 190) 1
191) 3 192) 3 193) 1 194) 1 195) 1 196) 3 197) 3 198) 1 199) 1 200) 2
201) 3 202) 3 203) 2 204) 3 205) 4 206) 1 207) 2 208) 1 209) 1 210) 4
211) 4 212) 3 213) 2 214) 2 215) 1 216) 1 217) 2 218) 1 219) 3 220) 3
221) 1 222) 4 223) 3 224) 2 225) 4 226) 4 227) 2 228) 1 229) 4 230) 4
231) 4 232) 3 233) 3 234) 1 235) 2 236) 3 237) 4 238) 3 239) 3 240) 4
241) 1 242) 3 243) 3 244) 2 245) 2 246) 3 247) 1 248) 1 249) 2 250) 1
251) 2 252) 4 253) 1 254) 3 255) 3 256) 1 257) 4 258) 4 259) 2 260) 3
261) 1 262) 1 263) 2 264) 3 265) 1 266) 2 267) 3 268) 1 269) 4 270) 2
271) 1 272) 2 273) 3 274) 2 275) 2 276) 2 277) 3 278) 1 279) 2 280) 3
281) 4 282) 3 283) 4 284) 1 285) 1 286) 3 287) 2 288) 4 289) 3 290) 3
291) 3 292) 4 293) 3 294) 3 295) 1 296) 4 297) 2 298) 3 299) 4 300) 1
301) 4 302) 4 303) 2 304) 4 305) 3 306) 4 307) 1 308) 4 309) 1 310) 3
311) 3 312) 4 313) 3 314) 3 315) 2 316) 4 317) 2 318) 4 319) 3 320) 1
321) 2 322) 1 323) 1 324) 4 325) 1 326) 4 327) 4 328) 2 329) 3 330) 2
331) 4 332) 4 333) 3 334) 1 335) 1 336) 2 337) 4 338) 1 339) 1 340) 1
341) 4 342) 4 343) 1 344) 2 345) 4 346) 3 347) 3 348) 4 349) 2 350) 2
351) 1 352) 2 353) 4 354) 1 355) 2 356) 4 357) 2 358) 2 359) 3 360) 1
361) 1 362) 1 363) 1 364) 1 365) 3 366) 4 367) 2 368) 1 369) 3 370) 1
371) 3 372) 1 373) 3 374) 3 375) 4 376) 2 377) 1 378) 3 379) 1 380) 4
381) 3 382) 1 383) 4 384) 4 385) 4 386) 3 387) 1 388) 3 389) 3 390) 3
391) 4 392) 2 393) 1 394) 4 395) 2 396) 2 397) 3 398) 1 399) 3 400) 4
401) 3 402) 2 403) 3 404) 1 405) 3 406) 2 407) 3 408) 4 409) 2 410) 1
411) 2 412) 3 413) 3 414) 3 415) 1 416) 4 417) 4 418) 3 419) 3 420) 2
421) 2 422) 4 423) 1 424) 2 425) 2 426) 4 427) 3 428) 1 429) 3 430) 3
431) 2 432) 1 433) 2 434) 1 435) 2 436) 3 437) 2 438) 4 439) 4 440) 4
441) 3 442) 4 443) 3 444) 2 445) 2 446) 2 447) 1 448) 1 449) 2 450) 1
451) 1 452) 3 453) 2 454) 3 455) 4 456) 3 457) 4 458) 3 459) 1 460) 2
461) 1 462) 4 463) 1 464) 1 465) 4 466) 4 467) 1 468) 1 469) 1 470) 4
471) 1 472) 4 473) 4 474) 2 475) 2 476) 1 477) 2 478) 3 479) 3 480) 4
481) 3 482) 4 483) 1 484) 3 485) 4 486) 2 487) 3 488) 2 489) 2 490) 1
491) 4 492) 3 493) 4 494) 2 495) 3 496) 2 497) 2 498) 4 499) 2 500) 4
501) 3 502) 4 503) 2 504) 2 505) 1 506) 3 507) 2 508) 1 509) 2 510) 2
511) 1 512) 1 513) 2 514) 2 515) 2 516) 4 517) 3 518) 1 519) 2 520) 2
521) 2 522) 3 523) 2 524) 3 525) 1 526) 2 527) 1 528) 2 529) 4 530) 3
531) 1 532) 3 533) 3 534) 2 535) 3 536) 4 537) 3 538) 4 539) 4 540) 3
541) 2 542) 3 543) 2 544) 4 545) 3 546) 2 547) 2 548) 3 549) 3 550) 4
551) 3 552) 3 553) 2 554) 2 555) 4 556) 1 557) 3 558) 4 559) 4 560) 2
561) 3 562) 4 563) 3 564) 2 565) 1 566) 2 567) 3 568) 2 569) 4 570) 4
HINTS

1. 4th complex cannot show geometrical isomerism due to presence of symmetrical ligand.

2. 25  N1  40  0.4

16
N1   0.64 N
25

Volume strength  0.64  5.6  3.584

3.   icRT
4.92  i  0.1 0.0821 300

i  1.99

i  1 1.99  1
   0.49
n 1 3 1

% of   49%

G 965 103
4. G  nFE  E     2.5
nF 4  96500
 The potential difference needed for the reduction = 2.5V

5. NaCl  aq   AgNO3  aq  
 AgCl  s   NaNO3  aq 

143.5 g of AgCl is got from 58.5 g of NaCl

58.5
 0.287 g of AgCl is got from  0.287  0.117 g
143.5

0.117
 % purity of sample  100  5.85%
2

 
3
 a3  N A 2.75  660 1010  6.023 10 23
6. Z  4
M 119

 Number of formula units per unit cell = 4

23.8
No.of unit cells   6.023 10 23  0.05  6.02310 23  3.01110 22
119  4

1
7. m eq of NaOH  16   3.2
5

20ml of acid requires 3.2m eq of NaOH

3.2  500
500ml acid requires  80m eq of NaOH
20

m.eq. of NH 3  m eq of H 2 SO4  m eq of NaOH

 100  80  20

1.4 m eq of NH 3
%N
wt of O.C

1.4  20
 wt of O.C   2g
14

10.

PCl 5 PCl 3  Cl 2
1 0 0
1  x  x x
 Total no.of moles  1  x  x  x  1  x 

 x   x 
  P P x2
 1 x   1 x 
Kp   P
 1 x  1  x 2
 P
 1 x 

Kp
x
Kp  P

18.  2Li O  4 NO  O
4LiNO3  2 2 2

22. t 93.75%  4  t 50%  120 min

 t 50%  120  30 min

4

 K  0.693  0.693  2.3110 2 min 1

t1 30
2

2 3
Rate at the end of 120 min  2.3110  0.125  2.88 10 M min 1

26.

31. Meq of salt = Meq of Na 2SO3

50  0.1 n  25  0.1 2
 n 1 changein  O.N.
 M3  e 
 M2
32. Allotropes of an element have the same chemical properties but have different
arrangement of atoms and physical properties.
33. It undergoes dehydration easily as the product obtained is conjugated, and is more stable.
34. Polarity in a molecule gives rise to an increase in forces of attraction among molecules
and thus, the boiling point increases.
35. Being amphoteric , Al  OH 3 is soluble in NaOH solution whereas Fe  OH 3 is
insoluble.
36. CaC2 
H2 O
 C2 H2  H2 O
Hg 2  catalyst 
 CH3CHO 
H2
Ni
 CH3CH2 OH

w w
37. Let w g of each be taken, then initial mole of P  ;molof Q 
10 20
w1 4w1
Final mole of P  Final mole of Q 
5  10 20  5
PN0 Q N0
For P  e1t For Q  e2 t
PN QN
w  5 10 1 20
 For P e
10  w 2
w  20  5
For Q  e2 20
20  w1  4
By Eqs. (i) and (ii) 4  e   1 2 20

 20  1   2   loge 4
 0.693 0.693 
or 20     loge 4
 10 t1/ 2 
 t 

38. FeSO4  7H2O 
 FeSO4  7H2O;

2FeSO4   Fe2O3  SO2  SO3
39.
  

KOH aq
C3 H 6 O
B
C3 H 6Cl2 or
 A KOH ( alc )

 C3 H 4
C 

CH3C  CH 
CH3COCH3 
H2 O
Br2
H .Hg2
 NaOH
CHBr3  CH3COONa
Since, B and D are different, thus B is CH 3CH 2 CHO and so A is CH3CH 2 CHCl2 .
40. Higher vapour pressure of H 2 O in atomosphere will drive H 2 O vapours to the solute
particles.
41. HOSO2OH  PCl5 
Cl SO2Cl  POCl3  2HCl
42. must be a tertiary alcohol as it gives alkene on treatment with Cu. Thus, C 4 H 8 O is a
ketone.
43. phenomenon of conversion of freshly precipitated mass into colloidal state by the action
of solute or solvent is called peptization.
44. The solubility of noble gases increases with increase in molecular weight due to increase
in van der Waals’ forces. However, these are sparingly soluble.
45. Follow applications of inductive effect. The negative charge on carboxylate ion is
dispersed more due to IE of F atom.

F C C O

O
F
The carboxylate ion thus becomes more stable and the acid becomes more
reactive.
d  N 2 O 5 1 d  NO 2  2d O 2 
46.  
dt 2 dt dt
k
 k1  N2O5   2  N2O5   2k 3  N2O5 
2
47. According to Werner’s theory, only those ions are precipitated which are attached to the
metal atoms with ionic bonds and are present outside the coordination sphere.
48.

OCH 2CH  CH 2
O
H


 CH 2 CH  CH 2

OH
CH 2CH  CH 2

 NO2 
2
2
 2  103 / 2
49. Kc    1 105
 N 2 O4   0.2 
 2 

50. PbS is black and S2  reacts with K 2 Cr2 O7 to give Cr2  SO 4 3 solution which is green.
51.
 H 3C
CH 3

CH

AlCl O .
CICH 2CH 2CH 3 
3

2 

CH3
CH 3  CH  OH
OH

 CH COCH 3
H O

2 
3

Q
52. For NaX,
X  H2O HX OH 
1 h h h

Kh Kw 1014
h  
C Ka  C 105  0.1

 108  104
 %H  104 100  102  0.01
2
0.059  H    p H2   LHS
53. E cell = log RHS
2
2 p H2  RHS   H  
LHS

Thus, for positive E cell , PH2  LHS  PH2  RHS

54.
HO H
CHO C

(CHOH)3 (CHOH)3 O

CHOH CH

CH2OH CH2OH

55. Conceptual

56.
 Cl
CH2 
R eplacement of one Hatom 
2

C6 H 5  CHCl  C6 H 5
Cl

CH2

Cl

CH2

Cl CH2

57. DNA has deoxyribose sugar; RNA has ribose sugar with three bases common as adenine,
guanine and cytosine, DNA has fourth base thymine; RNA has uracil
58. This gives rise to higher e nuclear charge in Na  and the size of Na  becomes smaller
due to more effective pull of valence shells towards nucleus.
59. In D-(+)-tartaric acid, the (+) is due to positive optical rotation and is derived from
D    glyceraldehyde.
60. Bakelite is a step-growth polymer i.e., the condensation involving the reaction of
functional group e.g., terylene, Bakelite etc.
61. P4  N2O  P4O10  N2
( A) ( B) (C )

the electronic configuration of the given ion is as

64.

Ca 2  1s 2 2s 2 2 p6 3s 2 3 p6 Mn2  1s 2 2s 2 2 p6 3s 2 3 p6 3d 5 Zn2  1s 2 2s 2 2 p6 3s 2 3 p6 3d 10

Thus the size of Zn 2 ion is smallest and of Ca 2  is largest among the three due to increase
in effective nuclear charge with increase in atomic number.Smaller the size of ion ,lighter
is the hydration enthalpy.Thus ,the order of hydration enthalpy is
Zn 2  Mn 2 1  Ca 2 1 .
 2047 kJ mol  1841kJ mol  1577 kJ mol 
1

67. K2Cr2O7  4 NaCl  6H 2 SO4  2 CrO2Cl2  2KHSO4  4NaHSO4  3H 2O

red vapor ' p '

CrO2Cl2  2 NaOH  Na2CrO4  HCl

yellowsolution

Na2CrO4  2 AgNO3  Ag2CrO4

red solid 'Q '
70. Conceptual

72. A  2B  C

t=0 Pi 0 0

at t Pi -x 2x x

if t   0 2Pi Pi

 Pt  Pi  2x

Pt  Pi
x
2

P
and P  3pi  Pi 
3

2.303  P 
K  log  i 
t  Pi  x 

73. The base in which lone pairs are more available for donation,forms most stable adduct
with the lewis acid, B(CH 3 )3 .
Presence of electron releasing groups like ,Me makes the electron more available for
donation,where as an electron withdrawing group decreases the electron releasing
tendency of the base.
CH3

Thus N forms the most stable adduct with B(CH 3 )3 .

N and both are crowded molecules so do not form adduct

with Lewis Acids.

75. H3PO4  PO34  H 2 PO4  HPO 42

Initial milli moles : 20  0.1 20  0.1 - -

 After reaction: - - 2 2

Buffer solution of H 2 PO 4 (acid) and HPO 24 (Conjugate base) is formed

 HPO24 
P  P  log
H Ka2

 H 2 PO4 

ka2
=P

76. Due to lanthanide contraction, left to right atomic size decreases

78. 0.1 F Liberates 0.1 equivalents of O2 at anode and 0.1 equivalents of Ag at Cathode

 Total loss = (0.1)8 + (0.1) 108 = 11.6g

 Wt. of final solution = 108  11.6  96.4g

79. X is borazine.it is iso electronic with benzene.it reacts with hydrogen chloride to give an
addition product. B3 N3 H 6  3HCl  B3 N3 H9Cl3

81. Tf  K f .m

36 1
 0.93  1.86x x
M 1.2

 M  60

60
n  2
30

 m.f   CH2O2

82. [Cu ( NH 3 ) 4 ](ClO4 ) 2 or [Cu ( NH 3 ) 4 ]2 contains Cu 2  ion

3d 4s 4p

Cu 2  [ Ar ]3d 9
3d 4s 4p

   
NH3

[Cu ( NH 3 ) 4 ]2  [ Ar ] dsp2 square planar

NH 3 being a strong field ligand transfer the unpaired electron to 4d orbital.In

[Cu ( NH 3 ) 4 ](ClO4 ) or [Cu ( NH 3 ) 4 ] ,Cu is present as Cu  ion.
 4s 4p

[Cu ( NH 3 ) 4 ]  [ Ar ]3d 10    

sp3 tetra hedral

Completely filled orbitals are highly stable, so NH 3 ligand occupy 4s and 4p orbitals.

85. Conceptual

x
87. log    tan(45o ) log p  log 2
m

x
    2p
m

 4, at P  2 atm

88. Due to emulsification surface tension decreases.

91. Volume strength  5.6  Normality

92.

Br MgBr COOMgBr COOH

Mg

 CO

2 H O

2 

93. 5 f 14 , 6d 3  Total 17e

5 f 14  (n  l )  5  3  8

6d 3  ( n  l )  6  2  8

95.
 CH 3 CH 3
CH 3
Br
Br
Br2
 Sn / HCl
  

 HBr

NO2
NO2 NH 2
(A) (B)

COOH CH 3
CH 3
Br Br Br
H O
KMnO
 4 
2 
 OH
H 3 PO2

(E) (D)

N 2Cl 
2-bromobenzic acid
(C)

1 1
96. V H 2  V He  
H 2 
He

 1 1   1 1 
R  2  2   Rz 2  2  2 
n  2 4 
 1 n2 

 n1  1 & n2  2

 a
99. Vender wall's equation for 1 mole gas is  p   (v  b)  RT
v2  

AT low p, volume is High. so (V-b)=V

 a 
  p  2  v  RT
 V 

a
(or) PV +  RT
V
 a
 PV  RT 
V

1
100. Work done  (4 P1  P1 )(3V1  2V1 )
2

= 3 P1V1

104. It is a basic buffer

pH = 8.65

 pOH  14  8.65  5.35

[ NH 4 ]
P = p  log
OH kb
[ NH 4OH ]

[ NH 4 ]
5.35 = 4.75  log
[ NH 4OH ]

[ NH 4 ]
  anti log(5.35  4.75)
[ NH 4OH ]

4

[ NH 4 ] 0.2  30
  4
[ NH 4OH ] 0.3  V1

 V= 5 ml

105. 1°-alkyl halides follows SN2 path and walden Inversion takes place

106. B2H6+6H2O  2H3BO3+6H2 

above
3B2H6+6NH3   2B3N3H6+12H2 
200C

107. A2B3 2A3+ + 3B2-

  K sp  108 x5

108. 4  58.5g - No. of unit cells  6 1023

1 gram = ?

1
  6 1023  2.56 1021
4  58.5

110. Al2 ( SO4 )3 2 Al 3  3SO42

Initially let 1 0 0

After 1 2 3

1    2  3
i  4.2
1

 1  4  4.2

3.2
 4  3.2     0.8  80%
4

T fA 2 1
112. Given   e
T fB 1 1/ 2

B should associate to show lower in T

114. Cell reaction : 2Fe3++Fe  3Fe2+

0
Ecell  0.77  (0.44)  1.21  spon tan eous

 Fe3 & Fe will reduce

115. Al3++3e-  Al

1 mol Al = 27g = 3F

13.5 gr of Al = ? F= 1.5F
x
 0.03  45
117. Order with respect to A  
 0.01  5
 3x  32 x  2

x
 0.02  5
Order with respect to B   
 0.01  2.5

2 y  21 y = 1

Rate = K  A  B 
2 1

t H
119. I order 100% 
1/2  50% 
2  25%

Given 2t1/2  1hr

1
 t1/2  hr
2

28  VN2 at STP 100

120. %N 
22400  WoC

28  22.4  100
  11.2%
22400  0.25

121. Phenolphthalein gives the end point corresponding to the reactions

NaOH + HCl ® NaCl + H2O

Na 2CO3 + HCl ® NaHCO3 + NaCl

millimoles of NaOH + millimoles of Na 2CO3 = millimoles of HCl = 2.5

Methyl orange gives the end point corresponding to the reactions

NaOH + HCl ® NaCl + H2O

Na 2CO3 + 2HCl ® 2NaCl + CO2 + H 2O

Millimoles of NaOH + millimoles of Na 2 CO3 ´ 2 = millimoles of HCl = 3

millimoles of Na 2CO3  0.5

millimoles of NaOH = 2.5 – 0.5 = 2

 Ratio of mole of NaOH and Na 2CO3

122. Energy absorbed 13.6 1.5  20.4 eV

20.4 – 13.6 = 6.8 ev

this 6.8 ev is converted KE

1
KE = mv 2
2

1
6.8´ 1.6´ 10- 19 = ´ 9.11´ 10- 31 ´ v 2
2

2´ 6.8´ 1.6´ 10- 19

v= = 1.54´ 106 m / sec
9.11´ 10 - 31

rmx 4 10 Mx
124. = ´ = 2=
rx 5 4 M mx

M mix = 9 \ M x = 36

Mmix = MH2 XH2 + MCH4 XCH4 = 2X H 2 + 16(1- X H2 ) = 9 XH2 = 0.5

125. In CsBr

3  4.3
2  re  ra   3a re  ra   3.72Pm
2
126. In 2,3 and 4 conbanion is stabilised by resonance, but in (1) it is not stabilized. Moreover
(+I) effect of Me group destabilises the carbanion in (1)
128. Step 2 in wrong because friedel - crofts reaction will not take palce in the presence of e- -
with drawing, m- directing group

Me
MgBr
H O OH
+ CH3-CH = O 
3

 
+
H
130.
 Me
+ Me
+ 1 2 3 Me + Me
ring Br - Br
expansion
5 4

1.000  k f  
132. Tf 
M

1000  5.12  0.2

0.45 
20  M

Mobs  113.78

Now for 2CH3COOH  CH3COOH 2

Before assosiation 1 0


after association 1 
2

Where X is degree os association

M normal 
 1  
M observed 2

60 
 1     0.948
113.78 2

135. 0m BaSO4  2 eq BaSO4

0eq BaSO4  eq

0
Ba 2  eq
0
SO42

0eq BaCl2  eq

0
H2SO4  eq
0
HCl

0eq BaSO4  x1  x 2  x3

0m BaSO4  2  x1  x 2  x3 

For sparingly soluble salts

k
 0m   1000
M
 x
M 1000
2  x1  x 2  x 3 

kp2 H0  1 1 
139. n    
kp1 R  T1 T2 

104 H0  25 
 n 
106 8.314  298  323 

 r H 0  147.41 kJ / mol

142. The units of rate of reaction and rate constant are same for a zero order reaction
143. PhCOOH  B  , PhCOCl  C ,  phCO2 O  D

Br2  KOH NaNO2  HCl

PhCONH 2   PhNH 2    ph  N 2 Cl
(x) y  Phenol
azodye
2
145. k sp  Fe2  OH 

PH=13 POH = 1

OH    101

2
8 1016   Fe2  101 

 Fe2   8 1014  solibility

146. The monomers are

NH2
N NH2

N N

NH2
and HCHO

2,4,6 – triamino 1,3,5 – triazine

148. G  H  TS
 40, 000
at eqm 0 = -40000 + T50 T   800k
50

Len than 800k spontaneous

More than 800k non spontaneous

149.

CH2OH CH2OH
HO H
5 5 OH
4
H H
OH H1 4 H1
OH
H 3 2 H 3 2 H
H OH H OH
  D  Galatose   D  Glu cos e

151. BP directly proportional to MW

152. To avoid elimination 10 alkyl halides preferred

153. Jones reagent produce Carboxylic acid

KMnO4 oxidises alkyl group on benzene to Carboxylic acid

alc . KCN produces alkyl cyanide

154. Monomer of natural rubber is Isoprene

Monomer of Neoprene is chloroprene

155. C6H 5 - CH = CH - CH 3

156. H 2 is reducing agent

157. Number of un paired e - = 5

158. 120 - Ubn

0.693
159.
36
160. 1010 ® 1 sec

6.02 ´ 1023 ® ?

161. HCl produced by PCl 3 responsible for fumes

162. D G 0 = - 2.303 RT log K C

163. Ka ´ Kb = K w

K w 11014
 Kb  
K a 1109

164. Ptotal = PA0 X A + PB0 X B

165. Both are true for ideal solution

166. N4 : M 1
8´
3

hc
167. = KE + W
l

6.625 1034  3 108

 K .E  2.31
4 107 1.6 1019

K .E  0.97 eV
.

a
168. PV + = RT
V

PV
Z =
RT

169. In solid state dihedral angle is less

170. éCo (en ) Cl 2 ùCl ® Both Geometrical and Optical

êë 2 úû

éCo (en ) ùCl 3 ® Only Optical

êë 3ú
û

171. XeO3 on complete hydrolysis

XeOF4 and XeO2F2 on partial hydrolysis

172. Un saturation not effected

173. Acidic nature of CH3COOH > CH3CH2COOH

174. - CHO protected by ethylene glycol

175. 3 molecules required

176. Gem dihalide is produced. During hydrolysis it produces acetone

177. Br2 /CS2 produces mainly para product

178. Gaunine is Purine base, remaing are Pyrimidine bases

179. Saturation attained at high pressure

180. 30 carbocation attached to benzene rings stabilized through resonance

181. One mole of any substance contains Avogadro number of molecules.

h
182. D x.mD v = since D x = mD v
4p

2 h
(mD v) =
4p

2 h
(D v) = 2
m 4p

1 h
Dv =
2m p

æ ö
183. çç p + a ÷÷V = RT
çè v ø
2 ÷

a
PV + = RT
V

PV a RT
+ =
RT RTV RT

a PV
Z = 1- \ Z=
RTV RT
184. Ionic character is more if size of cation is more and charge is less.

3a
185. In bcc of ionic solids rc + ra =
2

3 ´ 4.3
= = 3.72 pm
2

186. O2- 2 is peroxide ion with bond order = 1 & diamagnetic

187. Among isoelectronic specices size is less when atomic number is more.

188. Less substituted alkene is least stable and its heat of hydrogenation is more.

189. D H = D E + D nRT

D H - D E = D nRT D nRT = - 3´ 8.314´ 10- 3 ´ 298 =-7.43KJ

( D n = 12 - 15 , R = 8.314´ 10- 3 KJ mA- 1 , T = 298 )

190. Order of acidic nature

CH3OH < H 2O < PhOH < AcOH

\ the order of nucleophilic nature is

CH 3- O > OH - > PhO- > ACO-

1
191. X pen tan e =
5

4
X hexane =
5

Ptotal = PA0 ´ X A + PBo ´ B

æ 1ö æ 4ö
= çç440´ ÷
÷
÷+ çç120´ ÷÷
÷
çè 5ø è ç 5ø

= 88 + 96 = 184

88
X 1pen tan e = = 0.478
184
 i- 1
192. a =
n- 1

i- 1
0.3 =
2- 1

i = 1.3

D T f = i.K f .m = 1.3´ 1.85´ 0.2

= 0.48

\ Tf = - 0.480 C

[C ][D ] 3´ 4
193. Q= = =6
[A][B ] 1´ 2

Kc = 10 sin ce Q < Kc ,

The system moves from left to right.

194
Br

CH3 C C H + 2HBr CH3 C CH3

Br

195. BaCO3 ƒ Ba + 2 + CO3- 2

K sp = éêëBa + 2 ùé - 2ù
ûëCO3 úû
úê

éBa+ 2 ù=
K sp 5.1´ 10- 9
û éCO- 2 ù= 1´ 10- 4 = 5.1´ 10 M
- 5
êë ú
êë 3 ú û

196. The change in oxidation state of both oxidized and reduced species is 6 units

M
\ Eq wt =
6
197.

1) CH 3CHO
CH 3CH 2OH ¾ PCl
¾¾ 3
® CH 3CH 2Cl ¾ Mg
¾® CH 3CH 2 MgCl ¾ 2)¾H 2¾
O
¾® CH 3 - CH - CH 2 - CH 3
|
OH

0 0 0
198. ECell = Ecathode - Eanode

0 0
= EFe+3
/ Fe+ 2
- EFe+2
/ Fe

= 0.771- (- 0.441)

= 0.771+ 0.441

= 1.212V

a - (a - x)
200. k=
t

a - 0.5
2´ 10- 2 =
25

a = 1.0M

201. AgNO3 + KI ® KNO3 + AgI

AgI becomes –ve sol when excess KI is added

206. Paracetamol is nonnarcotic analgesic

208. Nylon is a polyamide

211. Fluorine being more electronegative than carbon bond pairs mole towards fluorine In C-
H bonds bond pairs move towards carbon. Hence all bond angles are not equal. As bond
angle decreases (in F-C-F) s- character of hybrid orbitals also decreases . The molecule
has obstorted tetrahedral shape.

213. Second carbon from nitrogen is only chiral.

214. (2) sp3d 2 is octahedral 6 bond angle are with 900

215. Dx = 3a

216. Hydration reaction.

217. Conceptual (The electron affinity values are in the order fluorine > oxygen > carbon.)

218. Conceptual

219. CaC2 + H 2O ® C2 H 2

¾ H¾2SO¾ ¾¾
4 , HgSO4
® CH 3 + CHO

220.

eg eg

eg eg

t2 g t2 g
2 3
Fe H 2O 5 NO Fe H 2 O 5
NO
t2 g t2 g
2
[ Fe CN NO]3 Fe CN 5
NO
5

2+ 3+
In éêëFe (H 2O)5 NO ù é ù , the unpaired electron present in higher
û and êëFe (H 2O)5 NO ú
ú û
energy anti bonding MO of NO transfers to lower energy t2 g orbital of Fe Still these
3-
contain unpaired electrons and are paramagnetic In éêëFe (CN )5 NOù û , the unpaired
ú
electron in higher. Energy anti bonding MO of NO cannot go into the higher energy eg
orbital of Fe as there is no vacancy in lower energy t2 g orbital. So it remain in NO and as
2-
a whole the complex is paramagnetic. In éêëFe (CN )5 NOù û the electron from NO can be
ú
transferred to vacant lower energy t2 g orbital. Since all the electrons are paired in this
complex it is diamagnetic .

221. (1) 2MnO4  5H 2O2  6 H   2 Mn 2  5O2  8 H 2O

22,400 ml of O2  34 g of H2O2

224 ml of O2  0.34 g of H2O2

0.34 1000
Normality  
17 20

=1
 Volume strength = (5.6) (N) = 5.6 Vol

222. Two E and two Z isomers, one from methyl groups (Total Five)

223. Atomic sizes of both H and D are equal and hence H-H and D-D bond lengths are equal.
The difference in H-H and D-D bond energies is not due to difference in bond lengths but
due to difference in vibrational energies.

224. H2 / H + / I - / I2

H 2 + I 2 ® 2H + + 2I -

0.059
0.7714 = 0.533 - 10 g (H + )(0.1)
1

225. Zn  Hg / HCl with non polar solvent reduces double bond.

226. Magnesium slats gives precipitate with sodium bicarbonate only on boiling because
Mg (HCO3 )2 is soluble but on heating it decomposes to insoluble MgCO3 and CO2

227. Ùeq = X 1 + X 2 - X 3

Ùm = 2(x1 + x2 - x3 )

K 1000
Ùm =
m

103 x
S=
2 (x1 + x2 - x3 )

2.5 x 2105
K sp = S 2 = 2
(x1 + x2 - x3 )

CH 3 O
H
CH 2 C CH 2 CH 2 CH CH 2
228.

CH 3 O
CH 2 C CH 2 CH 2 CH CH 2
 CH 3 O H
1
SN
CH 2 C CH 2 CH 2 CH CH 2

CH 2OH
CH 2OH

CH 3
CH 3
O
H H

CH 2OH

H
CH 3
OH

229. Among (CH3 )3 N ® O and (CH3 )3 P ® O P ® O bond is stronger and shorter due to
back bonding from oxygen to phosphorous P ‡ˆ ˆ †ˆ O thus polarity also decreases

230. Conceptual

231. This is an example of intermolecular cannizzaro reaction.

232. IF7 has zero dipolemoment

233. Conceptual

234. (1) Due to –I effect of -COOH ; oxalic acid is more acidic

235. Transition metals form ionic compounds in lower oxidation states while they form
covalent compound in higher oxidation states .

236. (3) i  2 ( KCl  K   Cl  )

Tb  iKb m

 2  0.52 1

 1.04
 Tb  101.04C

237. Rearrangement (In RDS migration is easy when donating groups present)

238. Except in the case of zinc, remaining three cases impurities are oxidized during the
purification

239. (3) G  H  T S

At equilibrium G  0

For a reaction to be non spontaneous G should be positive

T  Te

240. Resonance decreases basicity.

241.

CH 3

| O
H
CH 2 C CH 2 CH 2 CH CH 2

H
|
CH 3 O
|
CH 2 C CH 2 CH 2 CH CH 2

CH 3 O H
| |
SN 1
CH 2 C CH 2 CH 2 CH CH 2
 CH2OH CH2OH

H CH3
O CH3
H O
H H
CH2OH

+
CH3
-H
OH

244. p – nitrophenol (III) > phenol (I) > p – cresol (II).

 O2 2
245. SiC  4 NaOH   Na2 SiO3  Na2CO3  2H 2O

247.

O
O
Cl THF C
Br Mg Cl Mg Br Cl C O M gBr

1 mole O
X
H

O
Cl C OH

250. - NO2 is a meta – directing group. As it is also a deactivating group so no chance of

introduction of second – Br atom.

CH 2 O CH 2 CH 3
251 2 NaH  B2 H 6   2 NaB2 H 4

253. A is CH3 – CHO, which then undergo aldol condensation to give compound B.

O OH
|| |
NaOH
.CH 3 C H CH 2CHO CH 3CCH 2CHO
| |
H H
 X 1A 100 1
255. 1
= ´
1- X A 200 4

8 x1 A = 1- x1A

1
x1A =
9

1 8
Pm = 100´ + 200´
9 9

= 188.8 Torr

256. As same charges are present at nearest position (less stable)

257. CuSO4  4 NH 3  Cu  NH 3 4  SO4

258.

K1 2B
K1 1
A Where 
K2 2
K2
2C

A  2B  2C
2 0 0

1
Finally 0.5 2 1.5 
3

 0.5  2  0.5  2

 0.5  1  2

 3.5

259. Conjugate base is week conjugate acid strong

262. 3 cis & 3 trans isomers

H Cl
C C
CH 3
CH 3
i)
 H H
C C
CH 2 Cl
CH 3
ii)

H H
C C
Cl
C2 H 5
iii)

H H

C2 H 3 C Cl Cl C C2 H 3

CH 3 CH 3

i ii
iv)

264. For isobaric process

T2
S  nCP log
T1

265.

NaNO2 /HCl
0 5 C

NH2 N 2 Cl

268. Condensation polymerization

271.

3a  2  rvoid  rmetal   3  2rmetal  2  rvoid  rmetal    

3  1 rmetal  rvoid  rvoid  0.732rmetal

l 1 Z 22
272. =
l 2 Z12

274.
 N 2O4 g
2 NO 2 g

1 0
1-0.8=0.2 1.6

nTotal = 1.8

0.2 1.6
PN 2 O4 = ´ 1.5 , PNO2 = ´ 1.5
1.8 1.8

1.6 1.6
´ 1.5´ ´ 1.5
kp = 1.8 1.8
0.2
´ 1.5
1.8

277. E = - 0.0591´ 3 +0.0591´ 4 = 0.0591

H 2O H   OH 
278. C C  C C


 H    OH   C  

Conductivity of water k H 2O  k H   KOH 

C C
k  x.  y.
1000 1000

C 1000  k  18 k 2106
k  x  y    x  y   , kw  C.C 
1000 18 1000  x  y  x  y 2

281. Colloid with high zeta potential (negative or positive) are electrically more stable.

283. It is diazotization reaction and initially formed carbonation is


CH 2
 CH 2  OH


and forms , or expands to new carbo cation

OH
which forms

286. I 2  6H 2O  5Cl2  2HIO3  10HCl

291. When P  0 ,all real gases come near to ideal behaviour. At least S.T.P i.e., 1 bar,

273.15KVm = 22.711 dm3

292. Both R  NH 2 and Ph  NH 2 gives positive iso-cynide test with CHCl3 / NaOH . So

given reagents not useful to distinguish

H vap P1
293. S   2.303R log
Tb P2

ozonolysis LiAlH 4
294. A[CH 2  C (CH 3 )2 ]  HCHO  CH 3  CO  CH 3 

OH
CH 3OH  CH 3  CH  CH 3

12 1 0.74´ 5´ 0.5
295. 0.74 = 1.86´ ´ ´ i Þ i= =1
60 0.5 1.86

0.693 1.386 k1 1
296. K1 = , k0 = =
40 2´ 20 k0 2

298. Flame temperature is directly proportional to the amount of heat released per mole of

products
300. The ubility of salts of weak acids like phosphates, acetates increases with decreasing the

pH. This is because at lower pH, concentration of the anion decreases due to its

protonation.

T f  KCl  4 i  KCl  2
301   
T f  X  1 i  x i  x

2
 ix   0.5
4

 1
for association of 3 molecules i  x   1  1   
 n

 1
 1  1     0.5
 3

   0.75

302 The boyle’s temperature of both H 2 and He is very low.

303 Along the body diagonal two B - ions and one A+ are removed

304 At high concentration of sulphide ions the cations of both II and IV groups are
precipitated.

305 Follow CIP rules.

306 2p r = n l Þ 2p rn = n 2 l 1

307 Depends on stability of carbocations

T
308 (i) Molecules move faster for which greater. obviously H 2 molecule move faster.
M

309 Cannizzarrows reaction

310 Rate of reaction depends on leaving ability of the group

311 Nucleophilic substitution

312 In the partial hydrolisys of Xe F6 different products formed or XeO F4 and XeO2 F2

313 Tollen’s reagent oxidizes aldehyde group only

314 B = PH 3 A = NaH 2 PO2

315 Conductivity BaSO4  2 106  1106  1106

BaSO
0
4
 Ba
0
 SO
2
0
2 Molar conductivities = 60  2  20  100ohm1cm2 mol 1
4

1000  K 1000 106

In the case of sparingly soluble salt  0
BaSO4  V    100
C C

103
C  105 moles / litre
100

316 C1 epimers are called anomers

317 a) basic strength in vapour state depends on +I –effect

c) +R group increase basic strength at para and decrease the basic strength at meta due to –
I.

d) Lesser the surface volume more the basic strength, hence NH3 is more basic. R–OH >
H2O due to +I – effect of ‘R’ group

320 B = NH 3 C = N2 D = Mg3 N2

322

323 Iodoform reaction

324 Teflon, polystyrene and PVC are formed by addition polymerization

325 Conceptual

326 Ratio of concentration of reactants and products is same in all three.

327 Kt = C0 - Ct

328 Follow the structure of dichromate ion.

329

CH 2
 
NaNO2 / HCl
0.50 C
 .........
N2
H2 N NN
H

H 

or

330 Sod. Benzoate is metabolized to hippuric acid C6 H5  CO  NH  CH 2COOH .

2
 H  
331. ka 1 
C

332. (b)

(i) AB S   aq  AB aq ; H  21 J

(ii) AB S   xH 2O  AB.xH 2O s  ; H  29.4 J

AB.xH2O S   aq  AB aq ; H  ?

Equation (i) is equivalent to

AB S   xH2O  AB.xH 2O s  ; H  H1

AB.xH 2O S   aq  AB aq ; H  H 2

H1  H2  21

 29.4  H2  21

H 2  21  29.4  8.4 J mol 1

333. It is MA3 B3 type complex therefore it shows fac. & mer. isomers

334.

CH 2  O   CH 3 O 

Number of resonance less stable less acidic nature

O
||
 S  O
||
O

More stable more acidity

1
337. (i) CO2 CO  O2 K1  9.11013
2

1
(ii) H 2O H 2  O2 K 2  7.11012
2

object CO2  H2 CO  H2O

equation (i) – (ii)

K1
 K  2  1.28
1

K
 1 d  NO2  1 d  NO  d O2 
338. r  
2 dt 2 dt dt

 NO2 is reactant so (Z)

Rate of disappearance of NO2  rate of formation of NO

So NO is (X)

OH OH


H Br
 

  H 2O


 CH 2  Br
CH 2  OH

OH OH

 


H Br

 CH 3  Br

 
OH
O C H3
339.

340.

CH 3 CH 3
H 3C CH 3
C

Br2
 CH 3 C Br Br

H 3C CH 3 CH 3 C Br Br C

CH 3 CH 3

Meso

(Not enantiomer’s)

CH 3
H 3C *
Br C CH 2
CH 2  Br2

H 3C CH 2

CH 3
 Chiral center present

341. At equation G 0  0

H 7.5 1000
T    300 K
S 25

342. MgCl2  Mg 2  2Cl 

0.01 M
2
K sp  Q   Mg 2  OH  

1012  0.01 OH  

2

2
OH    1010

OH    105

pOH  5  pH  9

343.

H 2O  H 2O
(1) H  44 kJ
(l ) (g)

1
(2) 2 B  O2  B2O3   1273kJ
3

(3) B2 H 6  3O2  B2O3  3H 2O

(g)

H  2035 kJ

(4) H 2  1 / 2 O2  H 2O H  286 kJ
l 

Equation  2   4  3  1  3   3
 H   1273   286  3   44  3   2035  36 kJ

345. P = 2, Q = 3, R = 0, S = 1

346. Zn  Cu 2  Zn 2  Cu

2Zn  2Cu 2  2Zn 2  2Cu

For 2 moles of Zn, n =4

G 0  nFECell
0
 4  96500  1.1  424.6 kJ

348. According to Lagmuir curve

ap
x
1  bp

a
p x
b

p0 x p

349.
XeF6 XeO3
 3H 2O   6 HF
 

Sp3d 3 Hybridisation Sp 3 Hybridisation

(distorted octahedral) (Pyramidal)

350. 16H   2MnO4  5C2O42  2Mn2  10CO2  8H 2O

MnO4 : C2O42  2 : 5

2K MnO4  16 HCl  2KCl  2MnCl2  5Cl2  8H 2O

MnO4 : HCl  2 :16  1: 8

1 1

 1 1 E13 1 3 2
32 2
351. E  13.6  2  2  eV / atom ;  
 n1 n2  E12 1  1 27
12 22

353. 15 mL 0.1 N NaOH = 15 mL 0.1 N HCl

Vol. of HCl used with NH3 = 20-15 = 5 mL

1.4 NV 1.4  0.1 5

%N= 
w 29.5 103

700
  23.7
29.5

356. Lyophobic colloids have charge of adsorbed ions on surface whose repulsion stabilizes
them.

Higher the zeta potential between fixed and diffused layers, higher is the stability.

359. It is octahedral void

391. Be  OH 2 which is least soluble in H2O


392. Na2CO3   No effect


CaCO3   CaO  CO2


MgCl2 .6H2O   Mg  OH  Cl  HCl  5H 2O


CaCl2 .6 H 2O   CaCl2  6 H 2O

1
Ca  NO3 2 

 CaO  2 NO2  O2
2
  1
NaNO3   NaNO2  O2
2

393. X  B3 N3 H 6

394. X  H 3 PO4 ; Y  PH 3

395. Acidic oxide

397. X  H 2 SiF6 , Y  SiF4

399. Tf  i  Kf  m  0.372  0.186  i  0.1

i2

400. It has 3 unpaired electrons.

Cr  3d 5 4s1

Cr 3  3d 3

401. Dehydration leading to conjugation

O
P
402.  C  N is group is o, p directing.

Br CH 3
OH

403.

404. Product is formed through the formation of stable C  ion.

405. 30 alkyl halide

2
n  1
407.    1 
 z1  R

W
408. PV  RT , find molecular wt.
M
410. G0f  H 0f  T S 0f

411. QC 
 P at any time in the reversible reaction
 R
2.303 a
413. k log
t ax

414. Find the no. of moles of ‘He’ gas and use PV=nRT

415. pK a  1

416. Find the solubility using the expression for KSp

Mct
417. Find the mass of ‘Ag’ deposited by using the formula m 
ZF

418. At equilibrium E=0

419. 2d  3a

420. Excess ‘KI’ is needed

421. R – OH < Ph – OH (Acidic Strength)

425. 1, 3, 4  contains plane of symmetry

H OH
* Chiral center

CH2

428. Free explanation Ssurr  0

S sys  0

429.
 O
O O
OH OH
Ph-C-CH2-CH2-CH2-COOH Ph-C-CH2-CH2-CH2-COOH

O LiAlD4/H3O+

Ph-C-CH2-CH2-CH2-CD2OH

433.

O
CH3
H3O+ O
H-C-N Ph-SO2Cl
H-COOH + CH3-N-H CH3 - N - S - Ph
CH3
CH3 O
CH3 NaOH

Silver mirror test

434

2
435.  Mg 2  OH    1011

2 1011
OH     1010  POH  5
0.1

PH=9

O  

  Stability order of C 

436. 

438. X 2  Y2 2 xy

1 1
x2  y2  xy H  200
2 2

1 1
BEX 2  BEY2  B.EXY  200
2 2
 6e
3
Cr2O7 2  Fe2  Cr  Fe3
440. le

442. formation of enol is rate determining step.

445.

O-CH2-R Acetal

VR
446. z
Vi

449. M  X M  X E oCell  0.11V .

481. Rate of the reaction is independent of halogen

482. Enolisation takes place in acidic medium

485. CH 3CHO gives aldol condensation

 
CH 3CHOHCH 2CH 3  CH 3 CO CH 2CH 3   Iodoform
O I 2 / NaOH

486.  conc H 2 SO4  NH 2OH

CH 3CH  CHCH 3 Oxime

487.
488. More the number of O  ions, greater will be the H  donating tendency

493.  CH3 2 C  CHCH 2CHO 

O
 CH 3COCH 3  CH 2  COOH 2

1 1
494. For the formation of cyanohydrins   K1  K 2
K 2 K1

495. 3  H’s are replaced by D’s

496. 1 mole PCl5 and 2 moles NaNH 2

O
497. 2 moles of RMgX for || gp
C  Cl

O
1 molecule each for || and CHO gps.
C 

498.

499.
C C


C C C  C C + CO

C O C

503.
504.

505. NO2 gp and acetal links are not affected in wolf kishner reduction

506.
H 
 NO2  NH 2 ( in acidic medium)

507. A is CH3COCH3 ; B isCH3CH 2CHO

508.

( intramolecular aldol condensation)

509. ‘b’ gives cannizaro’s reaction

‘c’ gives internal aldol condensation

510.