Beruflich Dokumente
Kultur Dokumente
10 6.63 1034
75 = 7.5 kg or = 0.4 nm
1.67 1027 103
Mass of hydrogen =
100
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34 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
–13.6
19.6 10 18 4 n=
Eexcited state
ELi2 9
–13.6
9 = = 4 =2
ELi2 19.6 1018 –3.4
4
18. Answer (3)
= 4.41 × 10–17 J/atom
Kinetic energy of electron is = e × V
Energy of orbit of Li+2 is –4.41 × 10–17 J/atom
As per de-Broglie's equation
12. Answer (3)
h h
1 ⎡1 1⎤
RHZ2 ⎢ 2 – 2 ⎥ 2mEk 2meV
⎣⎢ n1 n2 ⎦⎥
h
2meV
2⎡ 1 1⎤ ⎡ 1 1 ⎤
(1) ⎢ 2 – 2 ⎥ (2)2 ⎢ 2 – ⎥
⎣⎢ n1 n2 ⎦⎥ ⎣ (2) (4)2 ⎦
19. Answer (2)
1 1
– 2
3 n2
r = a0 = 0.529 ×4
n12 n2 4 Z
n1 = 1, n2 = 2 = 2.12 Å
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 35
20. Answer (1) 2 2 2 2 2 2 2
N2: 1s *1s 2s * 2s 2p x 2p y 2pz
Na+ > Li+ > Mg2+ > Be2+
21. Answer (1) 2 2 2 2 2 2 2 1 1
O2: 1s *1s 2s * 2s 2pz 2p x 2p y *2p x *2py
2– – + 2+ 3+
O > F > Na > Mg > Al
2 2 2 2 2
S2: 1s *1s 2s * 2s 2p 2 22p *2p
z 2p
2 2
*2p y
x y x
Decreasing ionic radii with increasing effective
nuclear charge for isoelectronic species. *22pz 3s
2 2
*3s 2
3p 2 2 *13px *13py
z 3p x 3p y
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36 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
H2SO4 – Covalent bond between S and O and also van der Waal equation
between O and H.
a
Compound having no covalent bonds is KCl only. (P )(V b) RT
V2
41. Answer (3)
At low pressure
Structure of I3–
V b V
–
I ⎛ a ⎞
⎜ P 2 ⎟ V RT
⎝ V ⎠
I
a
PV RT
V
I
a
Number of lone pairs in I3 is 9. PV RT
V
42. Answer (1)
PV a
PV = nRT 1
RT VRT
3170 × 10–3 = n × 8.314 × 300
31.7 103 a
n= 1.27 103 So, Z 1
8.314 3 VRT
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 37
48. Answer (2) We know, efficiency of a fuel cell,
Let the mass of O2 = x
G
100
Mass of N2 = 4x H
x –702.6
Number of moles of O2 = 100
32 –726
4x x 97%
Number of moles of N2 =
28 7
53. Answer (3)
x x G = H – TS
Ratio : = 7 : 32
32 7 For equilibrium G = 0
49. Answer (4) For spontaneous reaction, G < 0
H-bond is one of the dipole-dipole interaction and T > Te
dependent on inverse cube of distance between the
54. Answer (3)
molecules.
50. Answer (2) 1 3
N2 H2 NH3
No. of moles initially = no. of moles finally. 2 2
pi V pi V pf V pf V HNH3 46 kJ
RT1 RT1 RT1 RT2
1 3
NH3 N2 H2
2pi ⎛1 1⎞ 2 2
pf ⎜ ⎟
T1 ⎝ T1 T2 ⎠
1 3
46 3HNH 712 436
2pi ⎛ T1T2 ⎞ 2 2
⎜ ⎟ pf
T1 ⎝ T1 T2 ⎠ HNH 352 kJ / mol
55. Answer (1)
⎛ T2 ⎞
p f 2pi ⎜ ⎟ rH = –111 – (2 × 54)
⎝ T1 T2 ⎠
= –219 kJ
51. Answer (1) 56. Answer (1)
I. H2O(l) H+(aq) + OH–(aq); H = 57.32 kJ From the data, it is clear that Pb+2 is more stable
than Pb+4 and Sn+2 is less stable than Sn+ 4.
1
II. H2(g) + O (g) H2O(l); H = –286.20 kJ 57. Answer (4)
2 2
H = E + ngRT
Adding I & II we get,
–1366.5 = E + (–1 × 8.314 × 300 × 10–3)
1
H2(g) + O (g) H+(aq) + OH–(aq) E = –1364 kJ
2 2
58. Answer (2)
H = 57.32 – 286.2
59. Answer (1)
= –228.88 kJ
For isothermal reversible expansion of an ideal gas,
52. Answer (3) the work done is given by
3 375
CH3OH(l) + O (g) CO2(g) + 2H2O(l) Wrev 0.04 8.314 310ln
2 2 50
Greaction = Gproducts – Greactant
–207.22 208 J
= [–394.4 – 2 × 237.2] – [–166.2]
q –Wrev 208J
= –702.6 kJ
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38 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
NO 2
2 G
NO
= –3263.9 + (–3.71)
⇒ G
NO 2
2 G
NO
RT ln K P = –3267.6 kJ mol–1
66. Answer (1)
2 86600 R 298ln K P
⇒ G
NO 2
2 [ CO32 ] = 10–4 M
– – 2 – + same.
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 39
70. Answer (3) 77. Answer (2)
Ksp = [Mg+2] [OH–]2
B + C, G° = 2494.2 J
2A
1 × 10–11 = 0.001 × [OH–]2
[OH–] = 10–4 M As we know G° = –2.303 RT logKC
pOH = 4, pH = 10 2494.2 = –2.303 × 8.314 × 300 log KC
71. Answer (4) –0.434 = log KC
KC = anti log (–0.434)
–
3
Cr 3OH
Cr(OH)3 KC = 0.367
– 1 1
K sp (Cr 3 )(OH)3 Now A , B 2 and C
2 2
Ksp = 27S4
⎛ ⎞ 1
–30 CB ⎜⎝ 2 ⎟⎠
2
K sp 1.6 10 Now QC 4
S= 4 4
27 27 A 2 ⎛ 1 ⎞2
⎜2⎟
⎝ ⎠
72. Answer (2)
as QC > KC, hence reaction will shift in backward
[H ] K a .C
direction.
A BCD
10 –5 K a .C
Initially : 1 1 11 [D]eq = 1.818 M
(10–5)2 = Ka.C
Q=1
10–10 Q < keq
Ka
C Equilibrium is forward shifted.
Ka = 1 × 10–10 C=1M A BCD
73. Answer (2)
Equilibrium : 1–x 1–x 1+x 1+x
74. Answer (3)
(1 x)2
75. Answer (4) 102
(1 x)2
[H+] of the given HCl solution = 0.1 M
Let x litre of water be added to 1 litre of the given 1 x
HCl solution to get pH = 2 or [H+] = 10–2 M = 10
1 x
0.1 1 + x = 10 – 10x
0.01⇒ x 9 litre
1 x 11x = 9
76. Answer (2)
9
x= = 0.818
1 11
SO2 (g) O2 (g) SO3 (g)
2 So, equilibrium concentration of 'D' = 1.818 M.
KP = KC(RT)x 79. Answer (4)
2 2MnO4 5C2O24 16H 2Mn2 10CO2 8H2O
2H S , K a 1 K a2 K eq
H2S
87. Answer (1)
H S
2
2
1 107 1.2 1013 a 361
H2S r= 127.6 pm
2 2 2 2
0.22 S2 88. Answer (1)
1.2 10 20
0.1
a
[S2–] = 3 × 10–20 In fcc crystal, R r
2
82. Answer (3) 508
110 r 254
2
[50 1]
Final concentration of [SO4– –] = = 0.1 M r = 144 pm
[500]
89. Answer (3)
Ksp of BaSO4,
Packing fractions of fcc and bcc lattices are 74%
[Ba2+][SO42–] = 1 × 10–10 and 68%
– Cl— 1 3
Cl Then, x + y = 550 ...(i)
Cl
—
–
4 4
Cl
1 4
+ and x + y = 560 ...(ii)
Cs 5 5
Solving (i) and (ii), we get
—
Cl –
Cl
— Cl x = 400 mm
Cl
and y = 600 mm
2rCl 2rCs 3 a 100. Answer (3)
Tf = i Kfm
3a
rCl rCs i for Na2SO4 is 3(100% ionisation)
2
95. Answer (1) 0.01
Tf = 3 × 1.86 ×
Edge length of BCC is 4.29 Å. 1
a W1 W2
Distance of closest approach = 2r = M1V1 M 2 V2
2
97. Answer (3) 5 1
=
342 100 M2 100
In Frenkel defect, cation is dislocated from its
normal lattice site to an interstitial site. M2 = 68.4
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42 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
Mg3 (PO4 )2 5 0.100 R T 0.5RT 0.527 = 1 –
2
KBr 2 0.250 R T 0.5 RT
= 0.473
2
Na3PO4 4 0.125 RT 0.5RT
= 0.946
105. Answer (2)
% association = 94.6%
Vapour pressure of pure acetone P°A 185 torr
108. Answer (2)
Vapour pressure of solution, PS = 183 torr
o o
3+ E =? 2+ E = – 0.439 V
Molar mass of solvent, MA = 58 g/mole Fe Fe Fe
(1) (2)
Eo = – 0.036 V
P°A PS nB (3)
as we know
PS nA
Go1 + Go2 = Go3
185 183 WB MA – n1Eo1 – n2Eo2 = – n3Eo3
⇒
183 MB WA
– Eo + 2 × 0.439 = +3 × 0.036
2 1.2 58 Eo = +0.77 V
⇒
183 MB 100 109. Answer (4)
1.2 58 2 4
⇒ MB 183 Al2O3 Al O2
2 100 3 3
0.2 / 60 K 1.3 S m –1
0.45 = i(5.12) 1000 Cell constant 50
20 G 1S
i = 0.527 = 65 m–1
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 43
Case-II 1000
Now, m
K M
M
Molarity 2.5 103 1000
=
G cell constant 0.5
M
Molarity = 5 S cm2 mol–1
= 5 × 10–4 S m2 mol–1
1 S 65 m–1
1 = 10–3 m3
260 0.4 mol litre –1 114. Answer (3)
According to Debye-Huckel-Onsager equation,
1 S 65 m–1
260 0.4 mol 1000 m3 C A C
= 6.25 × 10–4 S m2 mol–1 Here A = B
111. Answer (3)
C B C
112. Answer (4)
Of the given values of standard reduction potential, 115. Answer (2)
On electrolysis only in case of Ca2+ salt aqueous
the value of EMnO4 /Mn2 is highest. Therefore,
solution H2 gas discharge at Cathode.
MnO4 is the strongest reducing agent. Case of Cr
113. Answer (1) At cathode : Cr3+ + 2e– Cr
For 0.2 M solution So, Cr is deposited.
R = 50 Case of Ag
= 1.4 S m–1 = 1.4 × 10–2 S cm–1 At cathode : Ag+ + e– Ag
1 1 So, Ag is deposited.
cm
1.4 10 2 Case of Cu
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44 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
12 96500
t second Ea ⎡ 1 1 ⎤
log2
2.303 8.314 ⎣ 300 310 ⎥⎦
⎢
100
12 96500
t hour 0.301 2.303 8.314 300 310
100 3600 Ea
10
t = 3.2 hours
121. Answer (2)
53600 Jmol1 or 53.6 kJmol1
127. Answer (4)
ln 2
t1/2 =
k 2A B C D
2.303 0.301 1d[A] d[B]
k= Rate of Reaction =
6.93 2 dt dt
2.303 ⎛ a ⎞ d[C] d[D]
log ⎜
⎝ a – 0.99a ⎟⎠
Also, t =
k dt dt
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 45
Let rate of Reaction = k[A]x[B]y
k Ea – Ea2
ln 2 = 1
d[C] k1 RT
Or, k[A]x [B]y
dt
Now from table, 10 103
= 4
1.2 × 10–3 = k [0.1]x[0.1]y ...(i) 8.314 300
⎡ 1⎤ ⎡ 1⎤
1 x x=2
⇒ ⎢2⎥ ⎢2⎥ 132. Answer (3)
⎣ ⎦ ⎣ ⎦
Physisorption is an exothermic process with H
⇒ x 1 –20 kJ/mol
133. Answer (4)
d[C]
Hence k[A]1[B]0 . 134. Answer (1)
dt
Number of moles of acetic acid adsorbed
128. Answer (1)
Higher order greater than 3 for reaction is rare ⎛ 50 50 ⎞
⎜ 0.06 0.042
because there is low probability of simultaneous ⎝ 1000 1000 ⎟⎠
collision of all the reacting species.
129. Answer (1) 0.9
moles
1000
0.693
Rate = K[H2O2] = 0.05 Weight of acetic acid adsorbed = 0.9 × 60 mg
25
= 54 mg
1 0.693
Rate of formation of H2O2 = 0.05
2 25 Hence, the amount of acetic acid adsorbed per g
k1 = k Pn
m
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46 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
x 1 O
log logP logk H H
m n
y = m·x + C O
H H H H
1 O
O
= n H
pe
slo H H
x O
log m
H
intercept = logk (in ice)
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 47
154. Answer (2) However, it dimerises at low temperature to become
diamagnetic.
155. Answer (3)
2NO
N2O2
ClO4 H
HClO4
Its bond order is 2.5 and it combines with O2 to
give nitrogen dioxide.
ClO3 H
HClO3
157. Answer (4)
Because of polarity and weak bond interhalogen
ClO2 H
HClO2
compounds are more reactive.
158. Answer (4)
ClO H
HOCl
Down the group strength of van der Waal's force of
Resonance produced conjugate base. attraction increases hence Xe have highest boiling
point.
–
O O O
159. Answer (1)
Cl Cl Cl N2 + O2 2NO
(i) O O
–
O O
–
O O
O O O Required temperature for above reaction is around
–
(ClO4 ) 3000°C which is a quite high temperature. This
O reaction is observed during thunderstorm.
Cl
160. Answer (4)
O O The phosphorous atoms of orthophosphorous acid
–
O
H3PO3 and pyrophosphorous H4P2O5 have a formal
–
O O O oxidation state +3.
Cl Cl Cl 161. Answer (4)
(ii) –
O O O
–
O O O
4Zn + 10HNO3(dil) 4Zn(NO3)2 + N2O + 5H2O
(ClO3–)
O O
–
Zn + 4HNO3(conc.) Zn(NO3)2 + 2NO2 + 2H2O
Cl Cl 162. Answer (3)
(iii) –
O O
Xe is oxidised from +4(in XeF4) to +6(in XeF6)
(ClO2–)
Oxygen is reduced from +1 (in O 2F2) to zero
(iv) ClO– is not resonance stabilized. (in O2)
As per resonance stability order of conjugate base 163. Answer (1)
is
Cl2 2NaOH NaCl NaOCl H2 O
Cold & dilute Sodium
ClO4 ClO3 ClO2 ClO
hypochlorite
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48 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
Among all the given compounds, only (NH4)2SO4 These reactions correspond to the production of Fe
do not form dinitrogen on heating, it produces by reduction of Fe3O4 in blast furnace.
ammonia gas. 177. Answer (2)
166. Answer (2) TiCl3 - Ziegler-Natta polymerisation
V2O5 - Contact process
= 4e–, non-planar = non-aromatic
PdCl2 - Wacker process
167. Answer (3) CuCl2 - Deacon's process
168. Answer (4) 178. Answer (3)
In Hall-Heroult process Al 2 O 3 (molten) is Charge transfer spectra from ligand (L) to metal (M)
electrolyte. is responsible for color of KMnO4.
169. Answer (2) 179. Answer (1)
Sulphide ores are concentrated by froth floatation. CrO2 is strongly attracted towards magnetic field
Galena (PbS) is concentrated by froth floatation. so it is ferromagnetic.
170. Answer (1) 180. Answer (1)
In the highest oxidation states, the transition Identical the number of unpaired electrons higher
metals show acidic character. the magnetic moment
171. Answer (2) Metal ion Unpaired electrons
Ln (III) compounds are generally coloured. [Cr(H2O)6]2+ Cr2+ 4
172. Answer (2)
[Fe(H2O)6]2+ Fe2+ 4
Mn > Cr > Fe > Co
[Cr(H2O)6]2+ and [Fe(H2O)6]2+ have identical
o
EMn 2
/Mn
1.18 magnetic moment.
181. Answer (2)
EoCr 2 /Cr 0.91
In (a), ZnO acts as acidic oxide as Na2O is basic
o oxide.
EFe 2
/Fe
0.44
In (b), ZnO acts as basic oxide as CO2 is acidic
EoCO2 /CO 0.28 oxide.
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 49
182. Answer (3) 190. Answer (2)
en en B
V G
Co en en Co R Y
O
NH3 NH3
NH3 NH3 The energy of red light is less than that of violet
light.
So energy order is
183. Answer (1)
Red < Yellow < Green < Blue
SCN– is an ambidentate ligand.
The complex absorbs lower energy light lower will
184. Answer (3) be its strength. So order of ligand strength is
N 3+
N 3+
L1 < L3 < L2 < L4
N N N N
191. Answer (2)
Co Co
The complex
N N N N [CoCl(NH3)5]+ decomposes under acidic medium,
N N so
Optically active [CoCl(NH3)5]+ + 5H+ Co2+ + 5NH4+ + Cl—.
3 192. Answer (2)
Exist as enantiomeric pair ⎡⎣Co en3 ⎤⎦
a b a c a b
185. Answer (2)
Pt Pt Pt
2.675 d c d b c d
Moles of complex = 0.01
267.5 as per question a = Cl, b = py, c = NH 3 and
d = NH2OH are assumed.
4 78
Moles of AgCl precipitated = 0.033 193. Answer (1)
143.5
It means 3Cl– are released by one molecule of Cl
complex Cl
en Co
[Co(NH3)6]Cl3
186. Answer (3)
en
NH3 enCN– CO
Field strength
Strong field ligand has no plane of symmetry, so it is optically active.
194. Answer (2)
187. Answer (4)
[ Co(NH 3 ) 2 (en) 2 ] 3 + will exhibit geometrical 1.2 1022
isomerism ( [ Ma2(A – A)2 ] ± n type complex ). Millimoles of AgNO3 = 1000 = 20
6 1023
188. Answer (1)
Millimoles of CoCl3·6H2O = 0.1 × 100 = 10
189. Answer (3)
Each mole of CoCl3·6H2O gives two chloride
[Co(NH3)3Cl3) has two geometrical isomers, namely ions.
fac. and mer. Both of them have a plane of
symmetry. So, they are not expected to show [Co(H2O)5Cl]Cl2·H2O
optical isomerism. 195. Answer (4)
NH3 NH3 The solution which shows maximum freezing point
Cl NH3 Cl NH3 must have minimum number of solute particles.
Co Co
Cl NH3 Cl Cl (1) [Co(H2O)6]Cl3 [Co(H2O)6]3+ + 3Cl–, i = 4
Cl NH3 (2) [Co(H2O)5Cl]Cl2 H2O
fac. mer. [Co(H2O)5Cl]2+ + 2Cl–, i = 3
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50 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
x 3 H2 C2 O 4
2 4 Conc. H SO
CO CO2
–H2O (effervescence)
⎡⎣Cr C6H6 2 ⎤⎦ ⇒ x 2 0 0
Na2 C2 O 4 CaCl2 CaC2 O 4 2NaCl
x0 ( X) white ppt.
2
2MnO4– 5C2O2–
4 16H 2Mn 10CO2 8H2O
K 2 ⎡⎣Cr CN2 O2 O2 NH3 ⎤⎦
⇒ 1 2 x – 1 2 – 2 2 – 2 1 0 201. Answer (3)
⇒x – 6 0 4– 1 3–
[Fe(CN) 6] + H O + H+ [Fe(CN)6] + H2O
2 2 2
x 6
3– 1
197. Answer (2) [Fe(CN)6] + H O + OH
2 2 2 1
4–
Br [Fe(CN)6] + H2O + O 2
NH3 2
Br
202. Answer (3)
Excess
NH3 NH3 Al3
NaOH
Al OH 3
NaOH
NaAlO2
White gelatinous ppt. Sodium meta
NH3 alu minate
(so lub le)
cis-isomer
–
+Br
2Al OH3
Strong heating
Al2O3 3H2O
Br Br Al2O3 is used in column chromatography.
NH3 Br NH3 Br 203. Answer (1)
+
CH3
NH3 Br NH3 NH3 1 2 3
CH3 – C – CH3
NH3 Br
fac- mer- CH3
(2 isomer)
IUPAC name : 2, 2-dimethylpropane
Br Br
NH3 NH3
204. Answer (2)
NH3 NH3
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 51
206. Answer (1)
1 60 1 20
(ngeq )NH3
Θ 5 1000 10 1000
R COO HC CΘ NH2 R
increasing basic strength 6 1
(ngeq )NH3
500 500
As sp3 C is less electronegative than sp3 N alkyl
5 1
carbanion R is more basic than NH . However
Θ
(ngeq )NH3
2 500 100
sp hybridized carbon is more electronegative than
Θ 1
Θ (nmol )N (nmol )NH3 (ngeq )NH3
sp3 N. Hence NH2 is more basic than HC C 100
207. Answer (4) 14
(Mass)N 0.14 g
1.4 NV 100
%N
W
0.14
Percentage of "N" 100 = 10%
1.4 0.1 (20 15) 1.4
29.5 103 211. Answer (1)
Percentage of Br
700
23.7
29.5 Weight of AgBr Mol. mass of Br
= Mol. mass of AgBr Weight of O.C. 100
208. Answer (4)
Benzyl carbocation (III) is more stable than allyl
carbocation (I) as it has more number of resonating 141 80
= 100
structures. n-propyl carbocation (II) is least stable 188 250
as it is stabilised by +I and +H effects of ethyl
group. = 24%
Normality Volume
N 214. Answer (2)
H2SO4 60mL
5 Kjeldahl method is not applicable for compounds
N containing nitrogen in nitro, and azo groups and
NaOH 20mL
10 nitrogen in ring, as N of these compounds does
not change to ammonium sulphate under these
conditions. Hence only aniline can be used for
(ngeq )H2SO4 (ngeq )NaOH (ngeq )NH3
estimation of nitrogen by Kjeldahl’s method.
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52 ANSWERS AND SOLUTIONS ARCHIVE - JEE (Main)
221. Answer (2) Excess nitrate in drinking water can cause blue
baby syndrome.
5-keto-2-methylhexanal is
The prescribed limit for fluoride is 10 ppm.
O O
The prescribed limit for lead is 50 ppb.
H The prescribed limit for iron is 0.2 ppm.
228. Answer (1)
O3 Zn
O O –
+
Permissible limit of F in drinking water is upto 1
H –
H ppm. Excess concentration of F 10 ppm
causes decay of bones.
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229. Answer (3) 234. Answer (3)
F– ions make the teeth enamel harder by On moving down a group basicity decreases but
converting nucleophilicity increases.
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OH OH
NBS/h COOH
CO2
NaOH
Salicylic acid
248. Answer (3)
More stable
Alcohols which give more stable carbocation is
Br –H more reactive with Lucas reagent
O
NBS H2O/K2CO3 (Anhy. ZnCl2 + conc. HCl)
OH
|
Anhy. ZnClHCl
CH3 C CH2 CH3 CH3 C CH2CH3
244. Answer (4) | |
CH3 CH3
Rate of SN1 reaction stability of carbocation More reactive More stable tertiary
carbocation
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ARCHIVE - JEE (Main) ANSWERS AND SOLUTIONS 55
250. Answer (4) 255. Answer (1)
100°C-110°C
C2H5HSO4 OH OH
140°C CO2, NaOH
COOH
C2H5OH + H2SO4 C2H5OC2H5
Acidification
180°C
CH2 = CH2 (Major)
251. Answer (3) O
OH O–C–CH3
The acidic strength of the given derivatives of
COOH COOH
phenol is decided by the stability of their conjugate (CH3CO)2O
bases. p-nitrophenol is most acidic as –I and –R H2SO4
effects of NO2 group stabilises its conjugate base Acetyl salicylic acid
most effectively. This is followed by p-chlorophenol (Aspirin)
due to –I effect of Cl group, p-cresol due to +I and
+H effects of CH3 group which destabilises its 256. Answer (4)
conjugate base. p-methoxphenol is least acidic due
to +R effect of OCH3 group. O HI I
+
252. Answer (2) Heat I
O OH
Tertiary alcohol gives instant turbidity with Lucas + OH
reagent and the reaction follows SN1 mechanism Hence, option (4) is correct.
due to stability of tertiary carbocation.
257. Answer (3)
253. Answer (1)
H
— Liquid + ethanol Fruity smell compound
O O O
H O—
— O=C=O
C
O Carboxylic acid Must be ester
H
OH CH3COOH + C2H5OH CH3COOC2H5
OH
COOH COO— 258. Answer (3)
+
(CH3CO)2O H
OH
aq. KOH
(B) CH3CHCl2 CH3CH
gem-dihalide OH
OCOCH3
unstable
COOH
–H2O
CH3CHO
(C)
259. Answer (1)
254. Answer (3) In Cannizzaro reaction, the transfer of hydride to
the carbonyl group is the rate determining step.
O O
260. Answer (1)
[Ag(NH3)2]+OH– CH3 – OH/H+
CH3 H
Esterification
O3
CH3 C C CH2 CH3
C=O C=O Zn/H2O
H HO
CH3 O
O (i) CH3MgBr HO CH3
(3 moles)
CH3 C O + CH3 CH2 C H
(ii) H2O acetone
261. Answer (4)
CH3 262. Answer (3)
C – OCH3 HO – C
O CH3 263. Answer (4)
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+ +
NH2 NH2 NH2 278. Answer (3)
Protonation
+ NH NH2
NH2 NH2 (b) 2
sp
+
NH2 NH2 NH2
Protonation
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