FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

CPT - 5 CODE: 1221.1 PAPER - 2

SET-A
Time Allotted: 3 Hours • Maximum Marks: 216
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall be fore the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
BATCHES – 1719

sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into three sections: Section-A, & B.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) Section-A (01 – 04) contains 4 multiple choice questions which have only one correct answer. Each
question carries +4 marks for correct answer and – 1 mark for wrong answer.
Section-A (05 – 08) contains 4 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer. No negative marks for wrong answer.
Section-A (09 – 12) contains 2 paragraphs. Based upon paragraph, 3 and 2 multiple choice questions
have to be answered. Each question has only one correct answer and carries +4 marks for correct
answer and – 1 mark for wrong answer.
(ii) Section-B (01) contains 1 Matrix Match Type question containing statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. Each question
carries +8 marks for all correct answer. For each correct row +2 mark will be awarded. There may be
one or more than one correct choice. No marks will be given for any wrong match in any question.
(iii) Section-C (01 – 04) contains 4 Numerical based questions with single digit integer as answer, ranging
from 0 to 9 and each question carries +4 marks for correct answer. No negative marks for wrong
answer.

Name of the Candidate :__________________________________________

Batch :____________________ Date of Examination :__________________

Enrolment Number :_______________________________________________

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019, PH NO 020 46918686
PHASE TEST – 5 AIS/BPS/PCMC CLASS XII SET A (1221.1)
2

P
PAAR
RTT –– II :: P
PHHY
YSSIIC
CSS
SECTION – A
(Multiple Choice Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.

1. A potentiometer consisting of a uniform wire of length l and resistance R0 is connected to

a steady voltage source V0. The voltage supplied by it to a fixed load R as the function of
the distance ‘x’ of sliding contact from the higher potential end is (analyse the case when R
> > R0
V0 x 2 V0 x (l - x ) V0 x V0 x 2
A) B) C) D)
l2 l2 l l (l - x )

2. Two identical capacitors 1 and 2 are connected in series to a battery as shown in fig.
Capacitor 2 contains a di-electric slab of di-electric constant k as shown. Q1 and Q2 are
the charges stored in the capacitors. Now the di-electric slab is removed and the
corresponding charges are Q11 and Q12 . Then

1 2

Q 1
k +1 Q 1
k +1 Q12 k + 1 Q11 k
A) = 1
B) = 2
C) = D) =
Q1 k Q2 2 Q2 2k Q 1 2k

Space for rough work

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019 PH NO 020 46918686
PHASE TEST – 5 AIS/BPS/PCMC CLASS XII SET A (1221.1)
3

3. Electrically charged identical drops of mercury fall from altitude h

into a spherical metal vessel of radius R in the upper part of which
there is small opening . The mass of each drop is m and charge is
q . What is the number ‘n’ of last drop that can still enter the
sphere .

4 0 mg (h − R)2 4 0 mgR2
A) B)
q2 q2
4 0 mgh2 4 0 mg (h − R) R
C) D)
q 2
q2

4. The diagram shows a small bead of mass m carrying charge q. The

bead can freely move on the smooth fixed ring placed on a smooth
horizontal plane. In the same plane a charge +Q has also been fixed as
shown. The potential at the point P due to +Q is V. The velocity with
which the bead should projected from the point P so that it can
complete a circle should be greater than
6qV qV 3qV 4qV
A) B) C) D)
m m m m

Space for rough work

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019 PH NO 020 46918686
PHASE TEST – 5 AIS/BPS/PCMC CLASS XII SET A (1221.1)
4

(One or More than One Correct Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

5. In the circuit shown in the figure, switch S is closed at

Time t = 0. Select the correct statements
(A) rate of increase of charge is same in both the 2R
C
capacitors
(B) ratio of charge stored in capacitors C and 2C at any
time would be 1: 2 2C R
(C) time constant of both the capacitors are equal S

(D) steady state charge in capacitors C and 2C are in the E

ratio of 1 : 2

6. In the circuit shown, A and B are equal resistances.

C
When S is closed, the capacitor C charges from the cell
of emf  and reaches a steady state
B
(A) During charging, more heat is produced in A than in B
(B) In steady state, heat is produced at the same rate in + A S
A and B

1 2
(C) In the steady state, energy stored in C is C
4
1
(D) In the steady state energy stored in C is C2
8

Space for rough work

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019 PH NO 020 46918686
PHASE TEST – 5 AIS/BPS/PCMC CLASS XII SET A (1221.1)
5

7. An ellipsodal cavity within a perfect conducter ( see figure). A positive charge q is placed
at the center of the cavity. The points A and B are on the cavity surface as shown in
figure. Then,
(A) electric field near A in the cavity = electric field near B
in the cavity.
(B) charge density at A = charge density at B
(C) potential at A = potential at B
(D) total electric flux through the surface of the cavity is
q
0

8. A conducting sphere of radius R, carrying charge Q, lies inside an uncharged conducting

shell of radius 2R. When joined by a metal wire.
Q
(A) amount of charge will flow from the sphere to the shell
3
2Q
(B) amount of charge will flow from the sphere to the shell
3
(C) Q amount of charge will flow from the sphere to the shell
Q2
(D) amount of heat will be produced
16 0 R

Space for rough work

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019 PH NO 020 46918686
PHASE TEST – 5 AIS/BPS/PCMC CLASS XII SET A (1221.1)
6

Comprehension Type

This section contains 2 paragraphs. Based upon each paragraph, 3 and 2 multiple choice
questions have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE is correct.

Paragraph for Questions 09 and 10

A solid conducting sphere of radius ‘a’ is surrounded by a thin uncharged concentric

conducting shell of radius 2a. A point charge q is placed at a distance 4a from common
centre of conducting sphere and shell. The inner
sphere is then grounded.

9. The charge on solid sphere is

q q
(A) − (B) −
2 4
q q
(C) − (D) −
8 16

10. Pick up the correct statement

(A) Charge on surface of inner sphere is non-uniformly distributed
(B) Charge on inner surface of outer shell is non-uniformly distributed.
(C) Charge on outer surface of outer shell is non-uniformly distributed
(D) All the above statements are false.
Space for rough work

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019 PH NO 020 46918686
PHASE TEST – 5 AIS/BPS/PCMC CLASS XII SET A (1221.1)
7

Paragraph for Q. Nos. 11 to 12

F F

Two small identical solid spheres of mass m each and charges Q, m m

-Q respectively are initially held at a separation of x0 on a rigid
fixed surface as shown. The balls and the surface are rough.
Consider only electrostatic interaction between the balls and Rigid surface
frictional interaction between the balls and rigid surface. Forces F as shown are normal to the
surface and act through the centres of spheres through out their motion. Radius of spheres is
much smaller compared to x0 . The system is released from rest. ‘x’ is the instantaneous
separation between the spheres

11. Acceleration ‘a’ of one sphere with respect to the other may be given by
5Q2 2Q2 Q2 5Q2
A) B) C) D)
14 0 mx 2 70 mx 2 280 mx 2 20 mx 2

12. It is found that slipping starts when the separation between the spheres reduces to half of
their initial separation . Then coefficient of friction is given by
2Q 2 Q2 5Q 2 Q2
A) B) C) D)
7F 0 x 2 7F 0 x 2 7F 0 x 2 14F 0 x 2

Space for rough work

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019 PH NO 020 46918686
PHASE TEST – 5 AIS/BPS/PCMC CLASS XII SET A (1221.1)
8

SECTION–B
Matrix−Match Type
p q r s t
This Section contains 1 question. Each question has four statements (A,
B, C and D) given in Column I and five statements (p, q, r, s and t) in A p q r s t

Column II. Any given statement in Column I can have correct matching B p q r s t
with ONE or MORE statement(s) given in Column II. For example, if for a C p q r s t
given question, statement B matches with the statements given in q and r,
D p q r s t
then for the particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.
1. Match the column:
In the circuit shown in fig, plates of capacitor C1 are gradually pulled apart.

Column – I Column – II
A) Potential difference across C2 p) will increase
B) charge on C2 q) will decrease
C) Potential energy stored in C2 r) will remains same
D) Electric field between plates of C1 s) some times will increase and
some times decrease.
t) Nothing can be said
Space for rough work

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019 PH NO 020 46918686
PHASE TEST – 5 AIS/BPS/PCMC CLASS XII SET A (1221.1)
9

PART – C
(Integer Type)
This section contains 4 questions. The answer to each question is a single-digit integer, ranging from 0
to 9. The correct digit below the question number in the ORS is to be bubbled.

N1. A capacitor stores 50 C charge when connected across a battery. When the gap
between the plates is filled with a dielectric, a charge of 100 C flows through the
battery. Find the dielectric constant of the material inserted.

N2. Two identical particles, each having a charge of 2.0  10–4 C and mass of 10g, are kept
at a separation of 10 cm and then released. The speeds of the particles when the
separation becomes very large, is 100 n. Find ‘n’

N3. A parallel-plate capacitor is filled with a dielectric material having resistivity  and
dielectric constant K. The capacitor is charged and disconnected from the charging
source. The capacitor is slowly discharged through the dielectric. This time constant of
n
discharging is 0 k. Find ‘n’
2

N4. A capacitor of capacitance 10 F is connected to a battery of emf 2 V. It is found that it

takes 50 ms for the charge on the capacitor to become 12.6 C. Find the resistance of
the circuit. (in k)
Space for rough work

FIITJEE PCMC CENTER, 4TH FLOOR, ABOVE VIJAY SALES, EMPIRE ESTATE, CHINCHWAD, PUNE – 411019 PH NO 020 46918686
1: An alkyl halide of formula C6H13Cl on treatment with potassium t-butoxide gives two isomeric
alkenes (C6H12). Both alkenes on hydrogenation give 2, 3, dimethyl butane. Isomeric alkenes are

H3C H3C

CH3 CH3

(A) H2C and H3C

CH3 CH3

H3C
H3C
CH3

(B) H2C and

CH3
CH3

H3C CH3
CH3 and
(C) H C
3
H3C CH3

H3C CH3

CH3
(D) H2C and H2C

CH3 CH3

Br

2:  i)  → A  CH
alc. KOH
ii) NaNH
  → B. A and B
NaNH 2
CH Cl
2 3 2

Br

CH 2 CH 3
(A) A≡ B≡

CH 2 CH 3
(B) A≡ B≡

CH
(C) A ≡
B ≡ CH 3

(D) None of these

3: Mononitration of phenyl benzoate gives:

(A) (B)

(C) (D)

C6H5 CH3
+

4: Identify the final product C6H5 CH3 →

H
∆
?
OH OH
CH3 C6H5
(A) C6H5 C C CH3 (B)C6H5 C C CH3
O CH3 CH3 O

C6H5 CH3
(C) C6H5 C C CH3 (D) None of these
5: Suggest appropriate structures for the missing compounds. (The number of carbon atoms remains
the same throughout the reactions). Compound (A), (B) & (C) can be

CH3
DilKmnO 4 HIO4 OH
–

(A ) (B) (C)
CH3

CH3
OH O O
(A) OH (B)
H3C CH3
CH3

OH HO CH3

(C) (D)
O O

6: An organic compound (A) reacts with H2 to give (B) and (C) successively. On ozonolysis of (A),
two
aldehydes (D) C2H4O and (E) C 2H2O2 and formed. On ozonolysis of (B) only propanal is formed.
Compound (A), (D) & (E) are

CHO
CH3
(A) H C (B)
3
CHO

CH3
(C) H C (D) CH3CHO
3
7. In the Dow process for the manufacture of phenol, chlorobenzene is fused with NaOH at high
temp and under pressure.

Cl
NaOH H 2O
Intermediate Phenol + (A) + (B)
0
360 C
High pressure Aromatic
Side products

Which of the following statements are correct for above reaction ?

(A) Phenol is formed via an intermediate that is aromatic.
(B) Diphenylether is also formed as by product.
(C) p-phenylphenol is also formed as by product.
(D) Biphenylene is also formed as by-product.

8. Which of the following gives p-tert butyl phenol ?

OH
H
+
(A) + CH 3 − C = CH 2 →
H +
(B) Phenol + Tert butyl alcohol→
H

(C) Phenol + Isobutyl chloride 

AlCl3
∆
→ (D) Phenol + Tert butyl chloride 
AlCl3
→
 Although chlorobenzene is inert to nucleophilic substitution, it gives quantitative yield of phenol
when heated with aq. NaOH at high temperature and under high pressure. Phenol, so formed, is
a weaker acid than the cabroxylic acid; hence it dissolves only in strong bases like NaOH, but
not in weak bases like NaHCO3. It reacts with acid chlorides and acid anhydrides in the absence
of AlCl3 to form esters. As far as electrophilic substitution in phenol is concerned, the –OH is an
activating group, hence its presence enhances the electrophilic substitution in the o- and p-positions.
Condensation with formaldehyde is one of the important property of phenol. The condensation
may take place in presence of acids or alkalis and leads to the formation of bakelite, an important
industrial polymer.

9: The product (B) in the following sequence of reaction is:


C6 H5 CO3 H
→ A →
HCl
B
CH2

OH
O
(A) (B)
Cl

Cl O

(C) (D)
OH OH

O +
Mg − dust
10: 
Et 2 O
→ 
H 3O
→ A 
H 2SO 4
→B

OH
OH O
O

(A) (B) (C) (D)

 According to following reaction steps find out the product. A Compound is a carbonyl compound
with lowest Molecular mass & can show positive Iodoform Test. D is acid with optical activity. F is

an alcohol with molecular formula C3 H 6O and G is a yellow colour compound.

11: Compound A is
(A) Methanal (B) Ethanal
(C) Propanone (D) Propanal
12: Compound D is
(A) Lactic Acid (B) Aspartic Acid
(C) Tataric Acid (D) Succinic Acid
 CH3
CH2  
→
LiAlH4
(A) H3C C H+ (p)
O

CH2OH CH3

(B)  
H2 SO4
→ (q) H3C CH3
∆
OH

CH2OH

(C) (r)

O CH3

+
(D) + CH3MgI 
H3 O
→ (s)
1. Number of possible isomers for C2H2 Cl2

2. Total number of isomers formed when 2-methyl butane is subjected to monochlorination

3. 9.2 mg of an organic compound (A) reacts with excess CH3CH2MgBr to give 6.72 mL of a gas
at STP. What is the number of active hydrogen present in the compound (A) if its mol.wt. is 92.

4. What is the number of compounds having a benzene nucleus can have the molecular formula
C 7H 8O?
 SECTION – A
(Multiple Choice Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.

1. If 𝑓(𝑥). 𝑓(𝑦) = 𝑓(𝑥) + 𝑓(𝑦) + 𝑓(𝑥𝑦) − 2∀ 𝑥, 𝑦 ∈ 𝑅 and 𝑖𝑓 𝑓(𝑥) is not a constant function,
then the value of 𝑓(1) is equal to

(A) 1 (B) 2 (C) 0 (D) -1

2. where [.] denotes greates integer function, is equal to

(A) 0 (B) 1 (C) does not exist (D) sin 1

𝑥+2 𝑥<0
3. 𝑓(𝑥) = {−𝑥 2 − 2 0≤𝑥<1
𝑥 𝑥≥1

Then the number of points of discontinuity of |𝑓(𝑥)| is

(A) 1 (B) 2 (C) 3 (D) none of these

4. 𝐼𝑓 𝑓(𝑥) = log 𝑥, then 𝑓 ′ (log 𝑥) equals :

𝑥 log 𝑥 1 1
(A) log 𝑥 (B) 𝑥 (C) 𝑥 𝑙𝑜𝑔 𝑥 (D) log 𝑥

Space for rough work

 (One or More than One Correct Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

5. 𝐼𝑓: 𝑅 → 𝑅, 𝑓(𝑥) = 𝑒 −|𝑥| − 𝑒 𝑥 is a given function, then which of the following are correct:
(A) f is many – one into function (B) f is many one onto function
(C) range of f is [0, ∞] (D) range of f is (−∞, 0]

6. Which of the following limits tend to unity ?

sin(cos 𝑥)
(A) sin(tan 𝑡) (B) lim (B)
lim sin 𝑡
𝑡→𝜋/2 cos 𝑥
𝑡→0
1−cos 𝑥
(C) √𝑥 2 (D) lim ( 𝑥2
)
lim 𝑥→𝜋/2
𝑥→0 𝑥

7. A function f (x) satisfies the realtion 𝑓(𝑥 + 𝑦) = 𝑓(𝑥) + 𝑓(𝑦) + 𝑥𝑦(𝑥 + 𝑦)∀ 𝑥, 𝑦 ∈ 𝑅. if
𝑓 ′ (0) = −1, then
(A) f(x) is a polynomial function (B) f(x) is an exponential function
(C) f (x) is twice differentiable for all 𝑥 ∈ 𝑅 (D) f’(3)= 8

8. if 𝑓(𝑥) = 𝑥 3 − 𝑥 2 + 100𝑥 + 1001, then

1 1
(A) 𝑓(2000) > 𝑓(2001) (B) 𝑓 (1999) > 𝑓 (2000)
(C) 𝑓(𝑥 + 1) > 𝑓(𝑥 − 1) (D) 𝑓(3𝑥 − 5) > 𝑓(3𝑥)
Space for rough work
 Comprehension Type
This section contains 2 paragraphs. Based upon each paragraph, 3 and 2 multiple choice
questions have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE is correct.

Paragraph for Questions 09 and 10

1
[𝑥] , −2 ≤ 𝑥 − 2
Let a function is defined as 𝑓(𝑥) = { , where [.] denotes greatest integer
2 1
2𝑥 − 1 , −2 <𝑥≤2

function. Answer the follwing question by using the above information.

9. The number of points of discontinuity of f(x) is

(A) 1 (B) 2 (C) 3 (D) None of these

10. Number of points where |f(x)|is not differentiable is

(A) 1 (B) 2 (C) 3 (D) 4
for rough work
 Paragraph for Q. Nos. 11 to 12

If a continuous function f defined on the real line R, assumes positive and negative values in the
R then the equation f (x) =0 has a root in R. For example, if it is known that a continoues
function f on R is positive at some point and its minimum value is negative then the equation f
(x) =0 has a root in R consider f (x) 𝑘𝑒 𝑥 − 𝑥 for all real X where k is a real constant.

11. The line 𝑦 = 𝑥 meets 𝑦 = 𝑘𝑒 𝑥 for 𝑘 ≤ 0 at

(A) no point (B) one point (C) two points (D) more than two ponts

12. The positive value of k for which 𝑘𝑒 𝑥 − 𝑥 = 0 has only one roots is
1
(A) 𝑒 (B) 1 (C) e (D) log e 2

Space for rough work

 SECTION–B
Matrix−Match Type
p q r s t
This Section contains 1 question. Each question has four statements (A, B,
C and D) given in Column I and five statements (p, q, r, s and t) in Column A p q r s t

II. Any given statement in Column I can have correct matching with ONE or B p q r s t
MORE statement(s) given in Column II. For example, if for a given question, C p q r s t
statement B matches with the statements given in q and r, then for the
D p q r s t
particular question, against statement B, darken the bubbles corresponding
to q and r in the ORS.

Match the columns.

Column I Column II
(A) √3
Value of x satisfying sin−1 𝑥 − cos−1 𝑥 = 𝑐𝑜𝑠 −1 ( ) 𝑖𝑠 (p) <0
2

(B) Value of sec 2(tan−1 2) + 𝑐𝑜𝑠𝑒𝑐 2 (cot −1 3) 𝑖𝑠 (q) <1

(C) Greatest value of x, satisfying sin−1 𝑥 − (r) ≥1

cos−1 x = sin−1 (3𝑥 − 2) is
(D) Value of sin−1(sin 5) is (s) >0
(t) >2

Space for rough work

 PART – C
(Integer Type)
This section contains 4 questions. The answer to each question is a single-digit integer, ranging from 0
to 9. The correct digit below the question number in the ORS is to be bubbled.

1. Find the number of solution of the equation |𝑥 − 1| = 2[𝑥] − 3{𝑥}

(𝑤ℎ𝑒𝑟𝑒 [𝑥]& {𝑥} denotes integral and fractional part of x)

2. 𝑖𝑓 lim (√𝑥 4 + 𝑎𝑥 3 + 3𝑥 2 + 𝑏𝑥 + 2 − √𝑥 4 + 2𝑥 3 − 𝑐𝑥 2 + 3𝑥 − 𝑑) = 4, then (a + c )

𝑥→∞

𝑥𝑒 𝑎𝑥 ,𝑥 ≤ 0
3. 𝐿𝑒𝑡 𝑓(𝑥) = { 2 3 where a is positive constant and the interval in which
𝑥 + 𝑎𝑥 − 𝑥 , 𝑥 > 0
𝜆 𝑎
f ’ (x) is increasing is (− 𝑎1 , 𝜆 ), then find (𝜆1 + 𝜆2 )
2

5𝜋2
4. Find number of solution of the equation (tan−1 𝑥)2 + (cot −1 𝑥)2 = .
8

Space for rough work

 ANSWER KEY

PHYSICS

ANSWER KEY

Single choice 4 question

1. C

2.C

3. D
4. A

More than one choice 4 question

1. B,C,D

2. A,B,D

3. C,D

4. C,D

Passage – I
1.B

2.C

Passage – II
1. A
2. D

Integer type 4 question

1. 3

2. 6

3. 2
4. 5

Match the column

A–Q,B–Q
C–Q,D–Q

Hint and Solutions

Single choice

3.

Knq2 Knq2
+mgh = +mg2R
h -R R
40mg( h -R ) R
solving we will get n =
q2

4. Applying conservation of energy

1
V.q + mu 2 = 4V.q + 0
2
6Vq
u=
m
More than one

3. C, D

Charge density at A < Charge density at B. Since field inside cavity is zero, hence potential at
A=

potential at B = a constant value

1
By Gauss theorem total electric flux =
0

Passage I

The inner sphere is grounded, hence its potential is zero. The net charge on isolated
outer

sphere

is zero. Let the charge on inner sphere be q  .

 Potential at centre of inner sphere is

1 q 1 q q
+0+ =0  q = −
4 0 a 4 0 4a 4

The region in between conducting sphere and shell is shielded from charges on and outside
the

outer surface of shell. Hence charge distribution on surface of sphere and inner sueface of
shell is uniform.The distribution of induced charge on outer surface of shell depends only
on point charge q. hence is non-uniform.

passageII

KQ 2 2
− f r = ma ; f r = ma
x2 5
KQ 2 7 5KQ 2 5Q 2
so = ma ; a= =
x2 5 7mx 2 28 0 mx 2
5Q 2
so relative acceeptence is
14 0 mx 2
2 2 5Q 2 2Q 2
fr = ma =   m =
5 5 28 0 mx 2 28 0 x 2
Q2
= when slipping occurs f r =F
14 0 x 2
 CHEMISTRY

HINTS & SOLUTIONS

PART - A

1.

2. C6 H 5 − C ≡ C − C − C

3. Mono Nitration (Any Electrophylic substitution) reaction determine by +M group present in Benzene
nucleus.

4. Pinacolone
 5. (A), (B), (D)

CH3
OH O O
(A) =
OH (B) =
H3C CH3
CH3

HO
CH3

(C) =

O
Aldol

6. (B), (C), (D)

CH3 CH3
A =H C B=H C
3 3

CH3
C=H C D = H3C — CHO
3

CHO

E=
CHO

7. BC

8. BCD

COMPREHENSIONS

H
+ OH
O O
9 B (A)
H+ Cl−
→ Cl−

→
Cl

10. B pinacool- Pmacolone rearrangement

11. B Conceptual

12. A
MATRIX-MATCH TYPE QUESTIONS

MATRIX-MATCH TYPE QUESTIONS

 INTEGER TYPE QUESTIONS

H Cl Cl Cl H Cl

1. C C C C C C
H Cl H H Cl H

C| C|
2. C l2 / h υ
C − C − C − C → C − C − C − C − Cl
C| *
C − C − C| − C
Cl
C|
C|
Cl − C − C − C − C C − C| − C − C
*
Cl

3. 3

9.2
Number of moles = X 10−3
92
= 10−4 mol

Coresponding volume of gas

= n X 10−4 X 22.4 X 103

⇒n=3
4. 5
(i) Anisole
(ii) Benzyl aleohol
(iii) 2 Methyl phenol
(iv) 3 Methyl phenol
(v) 4 Methyl phenol