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UNIT – II
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UNIT – II
SERVICEABILITY AND DURABILITY OF CONCRETE
INTRODUCTION
• Maintenance of standards of quality of manufactured goods
• It is a management system
• Imprecise specification
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• Poor materials
• Poor workmanship
• Excess water to cement ratio – It should not exceed about 50% of the weight
of cement.
• poor or no supervision
• Poor maintenance
• Abrasion
• Corrosion of steel
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•
CONCRETE PROPERTIES
STRENGTH
The strength is usually specified as characteristic strength which is the
strength determined by testing at a fixed age samples of concrete.
1.Compressive Strength:
Prism: 100mmX100mmX500mm
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Compressive strengths given by different specimens for the same concrete mix
are different
(fck)cy = 0.8(fck)cube
ft = t/(a+bt) * f28
a=4.7,b=0.833
2.Flexural Strength
Flexural Strength=0.7(fck)1/2
• Casting
• Curing
• Moisture conditions
• Rate of loading
• Manner of loading
3.Tensile strength:
• Splitting tensile strength:
Direct compressive force is applied to a concrete specimen in such a way that the
specimen fails due to tensile stresses induced in the specimen.
σsp = 2P/(П*d*l)
Factors affecting strength of concrete
• Moisture conditions
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• Type of cement
• Degree of compaction
• Nature of loading
Permeability of Concrete
Permeability is the property that governs the rate of flow of a fluid through the
concrete. The rate of flow is higher when the permeability is higher.
The durability of concrete has proven to be a formidable obstacle in the service life
of new and existing structures.
The durability of concrete is a function of permeability. Permeability is governed by
the capillary pores in the cement paste. Pores that are too large will result in a high
permeability, while pores that are small will result in a low permeability.
The objective of this research is to study the permeability of concrete as the water-
to-cement ratio is changed. For this investigation, the AutoClam device will be used
to explore the permeability of different water-to-cement ratios respectively.
Results presented in this investigation will provide valuable knowledge of the
durability of concrete. Current research and or tests will study any relationships
between water permeability and the water-cement ratio of the concrete mix.
Our ultimate goal will be to show/prove an inverse relationship between water
permeability and concrete water-to-cement ratio. The test results show that by
increasing or decreasing of water-to-cement ratio and curing time, the permeability
of concrete changes.
The AutoClam was successful in measuring the permeability of concrete used for
this research. In the future the AutoClam can be tested side by side with a 16' head
of water and or the Rapid Chloride.
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Found on several ways, the water is the most important fluid on nature.
Among its properties, is noticeable the capacity to penetrate in small pores or
cracks, and the capacity of dissolve a large amount of substances.
Several researches refer and attest the great importance of the water
molecule on the concrete structure, especially on the first ages, caused by the
cement hydration and consequent hardness of the concrete.
However, the presence of water after the hardness of the concrete and after
the reduction, or the ceasing of the hydration reactions, may cause the
deterioration of the concrete or of the steel bar present on the structure.
The water take action as a direct agent (lixiviation) or transporting noxious
substances, such as chloride ions, sulfate ions and acid, or components that
can activate and propel many chemical reactions that speed up the
degradation process of the matrix, proportioning this way a substantial
reduction of the durability and the use life of the concrete and reinforced
concrete structures.
The permeability of the water is the most important factor to esteem the
durability under the most diverse conditions of service of a structure. The
permeability regulates the speed of aggressive water penetration for inside
of the concrete besides controlling the movement of the water during the ice-
thaw process.
Therefore concrete must be projected and manufactured for the environment
to which it goes to be displayed, because the permeability is related to the
porosity that varies in accordance to the composition of the concrete, its
factor water cement, its age and even though with its form of launching.
In this paper, will be evaluated permeability and the compressive strength of
the concrete with different compositions, water cement factor and ages,
making possible to generate correlation curves, suggesting a standard of
reference and analysis of the permeability in function of some variable of the
concrete.
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the concrete and react with the hydrated cement compounds forming
calcium carbonate.
This tends to neutralize the alkaline environment surrounding the steel
embedment, making the steel vulnerable to corrosion if moisture and
oxygen are available.
Unwanted excessive permeability can occur in all concrete because of
poor mix design, e.g., excessive water content, lack of fines or excessive
air entrapment, or because of inadequate or inconsistent consolidation or
due to poor finishing of the concrete.
In addition to being susceptible to corrosion of the steel embedment’s,
concrete having a high permeability tends to have a lower compressive
and tensile strength and lessened durability and abrasion resistance than
concretes of low permeability.
Corrosion problems also arise because of water and chloride ions leakage
through joints in the concrete. Leakage through joints, as opposed to
permeation through the concrete matrix, can occur in caulked joints such
as flexible joints located between slabs of concrete.
Leakage can also occur in cold joints which are joints between portions
of a concrete structure which are cast at different times so that the
concrete matrix loses continuity.
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It seems common for people to confuse size scales with respect to movement of
water and other elements through concrete. In order to better define and delineate
this movement let us review the size scales through which movement occurs.
MECHANISM OF TRANSPORT
One of the primary roles of all systems (even decorative coatings) is the
control of the movement of water and aggressive chemicals, whether this is
by keeping water in, out, off, or even letting it through.
A review is, therefore, in order of the scientific terms used to define these
movements. Foremost is an understanding of the difference between
porosity and permeability.
Porosity is the amount of holes and permeability is how well the holes are
connected. More specifically, the porosity is the volume of voids expressed as
a percentage of the total volume of a material
WATER FLOW AND WATER PERMEABILITY
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WATER PERMEABILITY
In OPC concrete during compaction water movement takes place
resulting in water reaching the place around aggregates and
creating a weak interface zone along with calcium hydroxide.
Micro cracks develop here, interconnecting the pores and creating
channels for the movement of moisture. In HVFAC, water content,
bleeding and collection of weak layer around aggregates are low,
resulting in a strong interface bond with no or minimum micro
cracks. Additional products of hydration due to reactive silica
refine the pores also.
Water permeability is therefore brought down. The permeability
in the three cases of fly ash absorption is given below as per DIN.
CHLORIDE PERMEABILITY
One of the adverse effects of permeability is chloride ion ingress into the
concrete which is responsible for chloride induced corrosion.
The total charge passing the concrete specimen , measured in Coulombs
should be less than 2000 in a good concrete from the point
CORROSION OF REINFORCEMENT
Corrosion of steel reinforcing bars inevitably weakens concrete members,
reducing load bearing capacity and safety factors.
In extreme cases failure of reinforced concrete members can occur, partly
because of loss of strength due to corrosion of the reinforcement itself, and
partly because of the breaking up of the concrete surrounding the
reinforcement.
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Experts have widely agreed for decades that the use of pozzolana, or
supplementary cementing materials, can reduce concrete
permeability by 7 to 10 times. In particular the mechanism of
pozzolana in this role can be viewed as having two principal aspects.
First, the use of a quality pozzolana will result in a denser pore
structure in the cement paste matrix. Second, the chemical reaction of
lime crystals to form binders has a direct effect of increased paste
density, reduced porosity over time, and will enhance the matrix
chemical resistance to many aggressive species.
EFFECT OF POWERPOZZ HRM ON POROSITY
The effect of High Reactivity Metkaolin in this regard is pronounced.
The engineered particle size of HRM serves as an effective micro-
packing additive.
Its average particle size being approximately one order of magnitude
smaller than the average cement particle, it will serve to fill the
interstitial spaces between cement grains, thus physically tightening
the particle arrangement. The alteration of lime is in a way a removal
by substitution reaction, where calcium hydroxide crystals are reacted
by HRM, in the presence of moisture, to form durable binding products
such as calcium silicate and calcium aluminate hydrates.
The physical and chemical effect of HRM is of particular significance
with regard to the paste-aggregate interfacial zones mentioned
previously.
CHLORIDE ION PERMEABILITY
The resistance of HRM concrete to chloride-ion penetration is significantly
higher than plain OPC of Fly Ash concrete, and similar to that of silica fume
concrete.
Thermal Properties:
Thermal Conductivity:
It is measure of the ability of concrete to conduct heat.
o The structural concrete of normal aggregate conduct heat more than light
weight concrete.
Lower the water content of the mix, the higher the conductivity.
It can be calculated from the conductivity of the coarse aggregate, the mix
proportions and the conductivity of the mortar.
K=Km(2M-M2) + (KmKa(1-M)2)/(KaM+Km(1-M))
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Ka – Conductivity of aggregate
Km - Conductivity of mortar
M = 1-(1-p)1/3
p – Volume of mortar per unit volume of concrete
Unit : WM-1K-1
Thermal Diffusivity:
It is a measure of the rate at which temp change within the mass takes place.
D=K/(cρ)
Where,
K- Thermal conductivity
D- Thermal diffusivity
C- Specific heat
ρ – Density of concrete
CRACKING
It can be defined as a separation of the individual components of concrete
resulting in a discontinuous material.
Classification of cracks:
A/c to location:
Bond cracks,
Mortar cracks,
Aggregate cracks
Fine: <0.1mm
Thin:0.1 to 0.3mm
Medium: 0.3 to 0.7mm
Wide: 0.7 to 2mm
Very wide:>2mm
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Cracks may be only at the surface or may extend to more than one layer. It
may be straight, toothed, stepped, map pattern.
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As the con is made up of two phases material namely paste and agg paste which has
dissimilar thermal con efficient but the coefficient of cone is a resultant of
these two phases.
In general form the coefficient of thermal expansion of cone is a function of the
quantity of aggregate in the mix and the coefficient of thermal expansion of
agg byitself.
Fire resistance:
Even cone is not a refractory material but a good combustible and has a good fire
resisting properties.
Fire resistance of concrete is determined by three factors.
The capacity of cone itself to with stand heat.
The subsequent action of water without losing strength unduly without cracking or
spelling.
And the conductivity of the concrete to heat and coefficient of thermal expansion of
concrete.
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Behavior of fire:
Failure in a fire occurs either through the spread of fire from the compartment or
through structural failure of a member or assembly of members.
Structural failure of a member most frequently occurs when the temperature of the
steel reduces the yield stress to the working stress.
The length of time of this fire occurs depend upon the severity of fire, the thermal
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Behavior of fire:
Failure in a fire occurs either through the spread of fire from the compartment or
through structural failure of a member or assembly of members.
Structural failure of a member most frequently occurs when the temperature of
the
steel reduces the yield stress to the working stress.
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The length of time of this fire occurs depend upon the severity of fire, the thermal
conductivity of the protecting concrete and weather spalling of the protection
covers.
VARIOUS CORROSION PROTECTION METHODS.
Methods of corrosion protection:
Corrosion inhibitors.
Corrosion resisting steels.
Coatings for steel and,
Cathode protection.
Corrosion inhibitors.
Corrosion inhibitor is an admixture that is used in concrete to prevent the metal
embedded in cone from corroding.
TYPES OF INHIBITORS:
Anodic inhibitors: (alkalis, phosphates, chromates, nitrates, benzoates).
Anodic inhibitors function by decreasing the reaction at the anode.
They may react with the existent corrosion product to form an extremely
insoluble
Adherent coating on the metal surface.
Organic inhibitors replace water at site on the inner plate, thus decrease
corrosion.
Cathode inhibitors (calcium carbonate):
Aluminum oxide and magnesium oxide.
Cathode inhibitors act to stifle the cathode reaction.
They are generally less effective since they do not form films on the anode.
MIXED INHIBITORS:
A mixed inhibitors may affect both and cathode processes.
DANGEROUS AND SAFE INHIBITORS:
A safe inhibitor is defined as one which reduces the total corrosion with out in
erecting area; while dangerous inhibitors produce increased rates can be due to the
lack of sufficient inhibitors to prevent complete protection or the presence of
crevices into which the inhibitor does not rapidly diffuse.
Anodic inhibitors are generally dangerous except sodium benzoate.
Cathode inhibitors are generally safe, but since sulphate is an exception.
CLASSIFICATION OF INHIBITORS:
Somewhat a different classification based on the actions of such as,
Barrier layer formation.
Neutralization and,
Savaging.
These represent processes by way of which the passivation is achieved it is
interested to note that the barrier layer formation is generally best achieved by
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simply completely coating steel with a well curved low water cement paste which
needs to extra admixture at all.
CORROSION RESISTING STEEL:
In mid steel, the corrosion is not sufficiently or corrosion is not sufficiently or
significantly affected by composing, grade or level or stresses. Hence substitute
steels for corrosion resistance will have a significantly different compaction.
Based on some atmosphere, corrosion weathering, steels of correct type were
tested in concrete. They did not perform well in most content containing chloride it
is observed that the weathering steel corrode in similar concrete to those can
corrosion at high yield strength steel. Although the total amount of corrosion less
than would occur on high yield steel under similar conditions, deep localized pitting
developed, which could be more structurally weakened.
Stainless steel pipe has been used special applications especially as flames in
precast members, but generally not expect use as a substitute for wild steel any
case, stainless steel should not concrete involving under corrosion resistant.
Stainless steels contains relatively lower content of chloride levels, there was a
based in a delayed time to cracking relative to that for high strength steels, but this
was offset by irregular pitting corrosion. Very high corrosion resistance was shown
by austenitic stainless steels in all the environments in which they were tested, but
the observation of some very high pitting in the preserve of chlorides lead to the
warming the corrosion susceptibility was not evaluated in the test programme.
COATING OF STEEL:
Coatings are sometimes considered as for mild steel is to be embedded in concrete
exposed to advise corrosive condition.
There are both benefits and disadvantages to their use and any benefit can only be
optimized by carefully considering the specific job. The more obvious of those
considerations are,
Do the expected service life and structure exposure warrant coating of the steel.
If coating is desirable, is a field of job read or may the coating be applied prior to
fabrications of the reinforcing, for the structure.
Do transportation and subsequent lubrication pose a significant danger to the
coating.
In view of the exposure conditions, is the choice of coating dictated by these
condition rather than adoption of other measures.
GROUPS OF COATING:
ORGANIC COATING:
Organic coatings include coal tar enamel epoxy, asphalt, chlorinated rubber, vinyl,
phenolic, neoprene and methane.
Out of these, epoxy group is appeared to have the best potential for use.
EPOXY COATINGS:
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OTHER COATINGS:
Zinc coating.
Zinc coating is used where longer life protection is desired than can be provide by
usual methods of coating it is not a permanent protection, however and in moist,
tropical climates the galvanized coating itself is usually protected with a goodquality
paint. Galvanizing is also useful for subaqueous exposure, where it gives
fairly good protection.
For structural work, it is customary to specify zinc coating by the hot-dip process
(galvanizing), because the resulting coating is thicker than that applied by there
processes such as the radioing, electroplating or spraying.
CATHODIC PROTECTION:
Corrosion in equals environments or in damp soil is primarily electro chemical in
nature and is due is a current passing from anodic areas of the metal into solution
and returning to the metal at cathode areas. This type of corrosion can be
prevented by impressing a countercurrent on the metal in a sufficient amount to
neutralize the aggressive electric currents.
Cathode protection, which consists of the electrical connections of the soon finial
anode to the structure to be protected, serves this function by neutralizing the
corroding current and forming layers of insoluble reaction products on the new
cathode areas.
In structural applications, cathode application of buried steel (pipe or piling) for
protection of the submerged portions of mass structure such as piling and bracing
for protecting lock and gates, for the interior of water tanks and for the exterior of
burried tanks.
Cathode protection however will not prevent corrosion of structure unless the metal
to
be protected is sorrows by an electrolyte such a swatter or damp soil and is
ineffective
in protecting structural elements above the water line or in very dry soil in cathode
protection, the effects of the induced currents on adjacent structures may be
damaged
unless they are adequately bonded to the new system or other means of protections
are provided.
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PART – A
TWO MARKS QUESTION AND ANSWERS
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PART – B
SIXTEEN MARKS QUESTIONS
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