JEE ( Main ) Examination–2019/Evening Session/11-01-2019

TEST PAPER OF JEE(MAIN) EXAMINATION – 2019

(Held On Friday 11th JANUARY, 2019) TIME : 02 : 30 PM To 05 : 30 PM
CHEMISTRY
1. The correct option with respect to the Pauling Ans. (1)
electronegativity values of the elements is :- Sol.
(1) Ga < Ge (2) Si < Al NH2 O
(3) P > S (4) Te > Se (P) Tyrosine Tyr OH CH–
2 –CH–C–OH
Ans. (1)
Sol. O NH2 O
B C (Q) Aspartic ASP H–O–C–CH–CH––C––OH
2
Al Si Acid
Ga < Ge NH2
(R) Serine Ser H O–CH–CH
Along the period electronegativity increases 2

COOH
2. The homopolymer formed from 4-hydroxy-
NH2
butanoic acid is :- (S) Lysine NH2–CH 2–CH 2–CH 2–CH 2 – CH

O
O
(1) —C(CH 2)3–O—
n

(2) —OC(CH 2)3–O—

EN (A) Ester test (Q) Aspartic acid (Acidic amino
acid)
(B) Carbylamine (S) Lysine [NH2 group present]
(C) Phthalein dye (P) Tyrosine {Phenolic group
present)
COOH

n 4. Taj Mahal is being slowly disfigured and

O O discoloured. This is primarily due to :-
(3) —C(CH2)2C–O— (1) Water pollution (2) Global warming
LL
n (3) Soil pollution (4) Acid rain
Ans. (4)
O O
Sol. Taj mahal is slowely disfigured and discoloured
(4) —C(CH 2)2C— due to acid rain.
n 5. The major product obtained in the following
Ans. (1) conversion is :-
Sol. O
A

O O O
Polymerisation
Br2(1 eqv.)
C (CH)
2 3 O MeOH
OH n
OH
O
3. The correct match between Item I and Item II is
CH3 O CH3 O
:- Br
Item I Item II O O OMe
(A) Ester test (P) Tyr (1) (2)
(B) Carbylamine test (Q) Asp Br
(C) Phthalein dye (R) Ser O O
test O CH3 O
(S) Lys CH3
O Br O
(1) (A)®(Q); (B)®(S); (C)®(P)
(2) (A)®(R); (B)®(Q); (C)®(P) (3) (4)
OMe Br
(3) (A)®(Q); (B)®(S); (C)®(R) O O
(4) (A)®(R); (B)®(S); (C)®(Q) Ans. (2)

E 1
JEE ( Main ) Examination–2019/Evening Session/11-01-2019
Sol. 9. The correct match between item I and item II is
:-
O O
O O Item I Item II
Br2 OMe (A) Allosteric (P) Molecule binding
MeOH Br effect to the active site
O O of enzyme
–H+
(B) Competitive (Q) Molecule crucial
Br2 O OH inhibitor for
O O communication in
O Me
+ MeOH + the body
Br
(C) Receptor (R) Molecule binding
Br
to a site other than
O O
the active site of
6. The number of bridging CO ligand (s) and Co- enzyme
Co bond (s) in CO2(CO)g, respectively are :- (D) Poison (S) Molecule binding
to the enzyme
(1) 0 and 2 (2) 2 and 0 covalently
(3) 4 and 0 (4) 2 and 1 (1) (A)®(P); (B)®(R); (C)®(S); (D)®(Q)
Ans. (4)
Sol.

CO CO CO
EN (2) (A)®(R); (B)®(P); (C)®(S); (D)®(Q)
(3) (A)®(P); (B)®(R); (C)®(Q); (D)®(S)
(4) (A)®(R); (B)®(P); (C)®(Q); (D)®(S)
CO Co Co CO Ans. (4)
CO CO CO
10. The radius of the largest sphere which fits
Bridging CO are 2 and Co – Co bond is 1. properly at the centre of the edge of body
centred cubic unit cell is : (Edge length is
LL
7. In the following compound,
represented by 'a') :-
a
NH2 (1) 0.134 a (2) 0.027 a
d
N Nb (3) 0.067 a (4) 0.047 a
N N Ans. (3)
e H c
Sol.
A

the favourable site/s for protonation is/are :- R r

a = 2(R + r)
(1) (b), (c) and (d) (2) (a)
(3) (a) and (e) (4) (a) and (d) a
= (R + r) ...(1)
2
Ans. (1)
Sol. Localised lone pair e–. a 3 = 4R ...(2)
8. The higher concentration of which gas in air
Using (1) & (2)
can cause stiffness of flower buds ?
(1) SO2 (2) NO2 a a 3
= =r
(3) CO2 (4) CO 2 4

Ans. (1) æ2- 3ö

Sol. Due to acid rain in plants high concentration aç ÷= r
è 4 ø
of SO2 makes the flower buds stiff and makes
them fall. r = 0.067 a

2 E
 JEE ( Main ) Examination–2019/Evening Session/11-01-2019
11. Among the colloids cheese (C), milk (M) and
DH
smoke (S), the correct combination of the Sol. Teq =
DS
dispersed phase and dispersion medium,
respectively is :- 491.1 ´ 1000
(1) C : solid in liquid; M : solid in liquid; =
198
S : solid in gas
(2) C : solid in liquid; M : liquid in liquid; = 2480.3 K
S : gas in solid 14. Given the equilibrium constant :
(3) C : liquid in solid; M : liquid in solid;
KC of the reaction :
S : solid in gas
(4) C : liquid in solid; M : liquid in liquid; Cu(s) + 2Ag + (aq) ® Cu 2+ (aq) + 2Ag(s) is
S : solid in gas 10 × 1015, calculate the E0cell of this reaction at
Ans. (4)
298 K
Sol.
Dispersed Dispersion é RT ù
Phase Medium êë 2.303 F at 298K = 0.059V úû
Cheese Liquid Solid

12.
Milk
Smoke
Liquid
Solid
Liquid
Gas
EN
The reaction that does NOT define calcination is:-
D
(1) ZnCO3 ¾¾ ® ZnO + CO2
(1) 0.04736 V
(3) 0.4736 mV
Ans. (2)
(2) 0.4736 V
(4) 0.04736 mV

D
(2) Fe2O3·XH2O ¾¾ ® Fe2O3 + XH2O 0.059
Sol. Ecell = E ocell – log Q
D n
(3) CaCO3·MgCO3 ¾¾
® CaO + MgO + 2 CO2
LL
(4) 2 Cu2S + 3 O2 ¾¾
D
® 2 Cu2O + 2 SO2 At equilibrium
Ans. (4)
E°Cell = 0.059 log1016
Sol. Calcination in carried out for carbonates and 2
oxide ores in absence of oxygen. Roasting is = 0.059×8
carried out mainly for sulphide ores in presence = 0.472 V
of excess of oxygen. 15. The hydride that is NOT electron deficient is:-
A

13. The reaction,

(1) B2H6 (2) AlH3
MgO(s) + C(s)®Mg(S) + CO(g), for which DrHº
= + 491.1 kJ mol–1 and DrSº = 198.0 JK–1 mol– (3) SiH4 (4) GaH3
1, is not feasible at 298 K. Temperature above
Ans. (3)
which reaction will be feasible is :-
Sol. (1) B2H6 : Electron deficient
(1) 1890.0 K (2) 2480.3 K
(2) AlH 3 : Electron deficient
(3) 2040.5 K (4) 2380.5 K (3) SiH4 : Electron precise
Ans. (2) (4) GaH3 : Electron deficient

E 3
JEE ( Main ) Examination–2019/Evening Session/11-01-2019
16. The standard reaction Gibbs energy for a 19. The reaction 2X ® B is a zeroth order reaction.
chemical reaction at an absolute temperature T If the initial concentration of X is 0.2 M, the
is given by half-life is 6 h. When the initial concentration
DrGº = A – Bt of X is 0.5 M, the time required to reach its final
Where A and B are non-zero constants. Which concentration of 0.2 M will be :-
of the following is TRUE about this reaction ? (1) 18.0 h (2) 7.2 h (3) 9.0 h (4) 12.0 h
(1) Exothermic if B < 0 Ans. (1)
(2) Exothermic if A > 0 and B < 0 Sol. For zero order
[A0]–[At] = kt
(3) Endothermic if A < 0 and B > 0
0.2 – 0.1 = k×6
(4) Endothermic if A > 0
Ans. (4) 1
k= M/hr
Sol. Theory 60
17. K2HgI4 is 40% ionised in aqueous solution. The 1
value of its van't Hoff factor (i) is :- and 0.5–0.2 = ´t
60
(1) 1.8 (2) 2.2 (3) 2.0 (4) 1.6
t = 18 hrs.
Ans. (1) 20. A compound 'X' on treatment with Br2/NaOH,
Sol. For K2[HgI4] provided C 3 H 9 N, which gives positive
i = 1+ 0.4 (3–1) carbylamine test. Compound 'X' is :-

18.
= 1.8 EN
The de Broglie wavelength (l) associated with
a photoelectron varies with the frequency (v)
of the incident radiation as, [v 0 is thrshold
(1) CH3COCH2NHCH3
(2) CH3CH2COCH2NH2
(3) CH3CH2CH2CONH2
(4) CH 3CON(CH3)2
frequency] : Ans. (3)
Sol.
1
1 1 Br2 CHCl3
(1) lµ 3 (2) lµ [X] C3H 9N CH3CH2CH2–NC
(v - v0 )2 NaOH KOH
LL
(v - v0 )2 Hoff mann's Carbylamine
1 Bromaide Reaction
1
1 degradation
(3) lµ (4) lµ (v - v )
(v - v0 )4 0 Thus [X] must be aride with oen carbon more
Ans. (2) than is amine.
Sol. For electron Thus [X] is CH3CH2 CH2CONH2
21. Which of the following compounds will
A

l
lDB = (de broglie wavelength) produce a precipitate with AgNO3 ?
2mK.E.
By photoelectric effect Br
Br
hn = hn0 + KE
(1) (2)
KE = hn –hn0 N
h
l DB = Br Br
2m ´ (hn - hn 0 )
(3) (4)
1
l DB µ 1
(n – n 0 ) 2 Ans. (4)

4 E
 JEE ( Main ) Examination–2019/Evening Session/11-01-2019
Sol. 24. Match the following items in column I with the
corresponding items in column II.
Br
AgNO3 Column I Column II
AgBr + (i) Na2 CO3 ·10 H2O (P) Portland cement
aromatic cation ingredient
(ii) Mg(HCO3 )2 (Q) Castner-Keller
as it can produce aromatic cation so will process
produce precipitate with AgNO3 . (iii) NaOH (R) Solvay process
22. The relative stability of +1 oxidation state of (iv) Ca3Al2 O6 (S) Temporary
group 13 elements follows the order :- hardness
(1) Al < Ga < Tl < In (2) Tl < In < Ga < Al
(1) (i)®(C); (ii)®(B); (iii)®(D); (iv)®(A)
(3) Al < Ga < In < Tl (4) Ga < Al < In < Tl
Ans. (3) (2) (i)®(C); (ii)®(D); (iii)®(B); (iv)®(A)
Sol. Due to inert pair effect as we move down the (3) (i)®(D); (ii)®(A); (iii)®(B); (iv)®(C)
group in 13 th group lower oxidation state
(4) (i)®(B); (ii)®(C); (iii)®(A); (iv)®(D)
becomes more stable.
Ans. (2)
Al < Ga < In < Tl

bromide and
decolourizes bromine water solution :-
EN
23. Which of the following compounds reacts with
ethylmagnesium also
Sol. Na2CO3.10H2O ® Solvay process

Mg(HCO3)2 ® Temporary hardness

CN O NaOH ® Castner-kellner cell

(1) Ca3Al2O6 ® Portland cement

25. 25 ml of the given HCl solution requires 30 mL

LL
CN of 0.1 M sodium carbonate solution. What is
CH2–CO2CH3 the volume of this HCl solution required to
(2)
titrate 30 mL of 0.2 M aqueous NaOH solution?

OCH3 (1) 25 mL (2) 50 mL (3) 12.5 mL(4) 75 mL

CH Ans. (1)
(3)
A

CH2
Sol. HCl with Na2CO3
OH Eq. of HCl = Eq. of Na2CO3
(4)
25 30
´ M ´1 = ´ 0.1 ´ 2
1000 1000
Ans. (4)
Sol.
6
M= M
25
OH OMgBr
EtMgBr Eq of HCl = Eq. of NaOH
+ CH3–CH3

6 V 30
´1´ = ´ 0.2 ´ 1
25 1000 1000
declolourizes Bromin water
V = 25 ml

E 5
JEE ( Main ) Examination–2019/Evening Session/11-01-2019
4 KOH, O2 Sol.
26. A 2B + 2 H2O
(Green)
4 HCl COOH CH–OH
3B 2 C + MnO 2 + 2 H 2O 2

(Purple) LiAlH4
C–CH excess
H O, KI
2B 2 2 A + 2KOH + D 3 C–CH3
NO2 NH2
In the above sequence of reactions, O OH
A and D respectively, are :-
LiAlH4 will not affect C=C in this compound.
(1) KIO3 and MnO2 (2) KI and K2MnO4
29. The major product of the following reaction
(3) MnO2 and KIO3 (4) KI and KMnO4
is :-
Ans. (3)
HO (1) HCl
Sol. MnO2(A) ¾¾¾¾
4KOH, O2
® 2K2MnO4(B) + 2H2O
(2) AlCl3 (Anhyd.)
(Green)
3K2MnO4(B) ¾¾¾
4HCl
® 2KMnO4(C) + 2H2O Cl HO
(Purple) (1) (2)
2KMnO4(C) ¾¾¾ ¾
H 2 O, KI
® 2MnO2(A) + 2KOH +

27.
A ® MnO2
D ® KIO3
The coordination number of Th in
KIO3(D)
EN (3)
Cl
(4)
HO

Ans. (2)
K4[Th(C2O4]4(OH2)2] is :-
Sol.
(C O 2
2-
4 = Oxalato )
LL
(1) 6 (2) 10 (3) 14 (4) 8 HO C=C
HCl
Ans. (2) AlCl3
H+ OH
Sol. C 2O 42- (oxalato) : bidentate
Cl +
H2O (aqua) : Monodentate HO HO
–AlCl3
28. The major product obtained in the following
–AlCl4
reaction is :-
A

O OH
Li AlH4 30. For the equilibrium,
(excess)
CH3 2H2O H3O+ + OH–, the value of DGº at 298
K is approximately :-
NO 2 O
O OH OH (1) –80 kJ mol–1 (2) –100 kJ mol–1
(3) 100 kJ mol–1 (4) 80 kJ mol –1
CH3 CH3 Ans. (4)
(1) (2)
NO 2 OH NH 2 OH Sol.
OH OH 2H2O = H3O+ + OH– K = 10–14
DG° = –RT ln K
(3) CH3 (4) CH3
-8.314
= ´ 298 ´ln10 -14
NH 2 OH NO 2 OH 1000
Ans. (2)
= 80 KJ/Mole

6 E