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(1)
CHO
O
(2)
EN CHO
O
p
(1) DIBAL-H
+
OH x + y = (P1 + P2)2
O (2) H /H2O
Sol.
H Now total pressure
O O PT = P C + P B + P E
DIBAL-H will reduce cyanides & esters to = (P1 + P2) + P1 + P2 = 2(P1 + P2)
aldehydes. PT = 2 ( x + y )
3. In a chemical reaction, A + 2B
2C + D,
K
5. Freezing point of a 4% aqueous solution of X is
the initial concentration of B was 1.5 times of the equal to freezing point of 12% aqueous solution of
concentration of A, but the equilibrium Y. If molecular weight of X is A, then molecular
concentrations of A and B were found to be equal. weight of Y is :-
The equilibrium constant(K) for the aforesaid (1) A
chemical reaction is : (2) 3A
1 (3) 4A
(1) 16 (2) 4 (3) 1 (4) (4) 2A
4
Ans.(2) Ans. (2)
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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
Sol. For same freezing point, molality of both solution
OH
should be same.
8. CH3CH2 –C–CH3 cannot be prepared by :
mx = my
Ph
4 ´1000 12 ´ 1000
= (1) HCHO + PhCH(CH3)CH2MgX
96 ´ M x 88 ´ M y
(2) PhCOCH2CH3 + CH3MgX
96 ´ 12 (3) PhCOCH3 + CH3CH2MgX
or, My = M x = 3.27 A (4) CH3CH2COCH3 + PhMgX
4 ´ 88
Ans. (1)
Closest option is 3A.
6. Poly-b-hydroxybutyrate-co-b-
O
hydroxyvalerate(PHBV) is a copolymer of___.
Sol. (1) H–C–H + Ph–CH–CH2MgX
(1) 3-hydroxybutanoic acid and
CH3
4-hydroxypentanoic acid
(2) 2-hydroxybutanoic acid and
3-hydroxypentanoic acid
(3) 3-hydroxybutanoic acid and Ph–CH–CH2–CH2–OH
Ans. (4)
2-hydroxypentanoic acid
(4) 3-hydroxybutanoic acid and
3-hydroxypentanoic acid
EN 9.
CH3
OH PA VA 3 × PB × VB
(2)
OH =
n A RTA n B .RTB
O
2PA = 3PB
10. The element with Z = 120 (not yet discovered) will
CH3
be an/a :
O (1) transition metal
(3) O (2) inner-transition metal
CH3 (3) alkaline earth metal
(4) alkali metal
OH Ans. (3)
(4) Sol. Z = 120
Its general electronic configuration may be
Ans. (1) represented as [Nobal gas] ns2 , like other alkaline
Sol. M.P. of Napthalene ~ 80°C earth metals.
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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
11. Decomposition of X exhibits a rate constant of 0.05 14. For diatomic ideal gas in a closed system, which
mg/year. How many years are required for the of the following plots does not correctly describe
decomposition of 5 mg of X into 2.5 mg ? the relation between various thermodynamic
(1) 50 (2) 25 (3) 20 (4) 40 quantities ?
Ans.(1)
Sol. Rate constant (K) = 0.05 µg/year
means zero order reaction Cv Cp
(1) (2)
a0 5µg
t1/ 2 = =
2K 2 ´ 0.05 mg / year = 50 year T P
(3)
Ans. (4)
CH3O
Cl
(4)
CH3O
EN Cl
freedom becomes active.
CP =
7
2
5
R (Independent of P)
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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
16. The molecule that has minimum/no role in the O O
OH CH3
formation of photochemical smog, is : C
(1) CH2 = O H3C H H
(2) A = ; B=
(2) N2
H3C CH3 H3 C CH3
(3) O3
(4) NO O O
CH3 CH3
Ans. (2)
Sol. Chiefly NO2 , O3 and hydrocarbon are responsible (3) A = CH3 ; B = CH3
for build up smog. HO
17. In the Hall-Heroult process, aluminium is formed O O
CH3 CH3
at the cathode. The cathode is made out of : (4) A = CH3 ; B = CH3
(1) Platinum HO
(2) Carbon Ans. (4)
(3) Pure aluminium 19.
(4) Copper Ans. 4 O O
Sol. O OH
–
O
Ans. (2) C– H C–H + H 2O
17. Ans.(2) Carbon
Sol. In the Hall-Heroult process the cathode is made
of carbon.
18. Water samples with BOD values of 4 ppm and 18
ppm, respectively, are :
EN HO
O
H2O
O–
H
O
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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
Sol. hn = f + hn° Sol. ppm of CaCO3
(10 –3 × 103) × 100 = 100 ppm
1 æ1 1 ö
mv 2 = hc ç – ÷ 24. The correct order for acid strength of compounds
2 è l l0 ø CHºCH, CH3–CºCH and CH2=CH2
is as follows :
1
hn =f + mv 2 (1) CH º CH > CH2 = CH2 > CH3–C º CH
2
(2) HC º CH > CH3 –C º CH > CH2 = CH2
6.626 ´ 10 –34 ´ 3 ´ 10 8 1 (3) CH3–C º CH > CH2 = CH2 > HC º CH
– ´ 9 ´ 10 ´ (6 ´10 )
–31 5 2
f=
4000 ´ 10 –10 2 (4) CH3–C º CH > CH º CH > CH2 = CH2
f = 3.35 × 10–19 J Þ f ~ 2.1 eV Ans. (2)
21. Among the following compounds most basic amino Sol. CHºCH > CH3–CºCH > CH2=CH2
acid is : (Acidic strength order)
(1) Lysine 25. Mn2(CO)10 is an organometallic compound due
(2) Asparagine to the presence of :
(3) Serine (1) Mn – Mn bond (2) Mn – C bond
(4) Histidine (3) Mn – O bond (4) C – O bond
Ans. (4) Ans. (2)
Sol. Histidine
O O
eg
A
dx2y2 dz2 NH
NH 2
t2g
dxy dyz dxz (A) O
(B)
2 3
d sp
CN
23. The hardness of a water sample (in terms of NH2 NH2
equivalents of CaCO3) containing 10–3 M CaSO4
is :
(C) (D)
(molar mass of CaSO4 = 136 g mol–1)
(1) 100 ppm (1) (B) < (A) < (D) < (C)
(2) 50 ppm (2) (B) < (A) < (C) < (D)
(3) 10 ppm (3) (A) < (C) < (D) < (B)
(4) 90 ppm (4) (A) < (B) < (C) < (D)
Ans. (1) Ans. (2)
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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
Sol. Nucleophilicity order Me
O OH :O OH Me
H
CN Sol. H–C–H + H + O
O O C+ rds
C +H
:
NH2 NH2 H H H H
NH < NH2 < <
O
B A C D OH
H OMe
MeOH +
27. The pair of metal ions that can give a spinonly C +
CH2–OMe + H
magnetic moment of 3.9 BM for the complex H OMe H
[M(H2O)6]Cl2, is : acetal
(1) Cr 2+ and Mn2+ (2) V2+ and Co2+ 1
rate µ
(3) V2+ and Fe2+ (4) Co2+ and Fe2+ steric crowding of aldehyde
Ans. (2) t-butanol can show formation of carbocation in
27. Ans.(2) V2+ and Co2+ acidic medium.
29. 50 mL of 0.5 M oxalic acid is needed to
Sol. V2+ ® [V(H2O)6]Cl2 ; [Ar]18
3
neutralize 25 mL of sodium hydroxide solution.
3d The amount of NaOH in 50 mL of the given
3 unpaired e– , spin only sodium hydroxide solution is :
magnetic moment
= 3.89 B.M.
3d 50 × 0.5 × 2 = 25 × MNaOH × 1
3 unpaired e–, spin only
\ MNaOH = 2 M
magnetic moment
Now 1000 ml solution = 2 × 40 gram NaOH
= 3.89 B.M.
LL
\ 50 ml solution = 4 gram NaOH
28. In the following reaction
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