Beruflich Dokumente
Kultur Dokumente
www.elsevier.com/locate/solener
Received 12 September 2003; received in revised form 19 August 2004; accepted 25 August 2004
Available online 14 October 2004
Abstract
The thermal performance of a phase change thermal storage unit is analysed and discussed. The storage unit is a
component of a roof integrated solar heating system being developed for space heating of a home. The unit consists
of several layers of phase change material (PCM) slabs with a melting temperature of 29 C. Warm air delivered by
a roof integrated collector is passed through the spaces between the PCM layers to charge the storage unit. The stored
heat is utilised to heat ambient air before being admitted to a living space. The study is based on both experimental
results and a theoretical two dimensional mathematical model of the PCM employed to analyse the transient thermal
behaviour of the storage unit during the charge and discharge periods. The analysis takes into account the effects of
sensible heat which exists when the initial temperature of the PCM is well below or above the melting point during melt-
ing or freezing. The significance of natural convection occurring inside the PCM on the heat transfer rate during melting
which was previously suspected as the cause of faster melting process in one of the experiments is discussed. The results
are compared with a previous analysis based on a one dimensional model which neglected the effect of sensible heat. A
comparison with experimental results for a specific geometry is also made.
2004 Elsevier Ltd. All rights reserved.
Keywords: Phase change materials; Solar space heating; Thermal storage unit; Roof integrated heating systems
0038-092X/$ - see front matter 2004 Elsevier Ltd. All rights reserved.
doi:10.1016/j.solener.2004.08.017
342 W. Saman et al. / Solar Energy 78 (2005) 341–349
Nomenclature
heating and ventilation of a house. The results of this the validity of the model two sets of experimental results
work, according to the authors, were ‘‘very promising’’. from similar and different PCM geometry are compared
Recently Vakilaltojjar (2000) and Vakilaltojjar and with the model predictions.
Saman (2001) developed a mathematical model and de-
signed and tested a thermal storage unit using PCM for
a space heating and cooling system integrated with a re- 2. Mathematical model
verse cycle air conditioner. The model used by Vakilal-
tojjar was an extension of the one developed by The schematic of the thermal storage unit under anal-
Morrison and Abdel-Khalik (1978) for an air system. ysis is shown in Fig. 2. It consists of several layers of
In his work, Vakilaltojjar treated the thermal energy PCM slabs placed parallel to each other. Air flows
storage system model as a forced convection problem with through the passages between the PCM slabs.
variable wall temperature. In the model the sensible heat The most realistic model of the TSU under the study
was ignored and heat transfer was assumed to occur at a is a two dimensional model where a temperature gradi-
constant melting point temperature (Vakilaltojjar, 2000 ent exists and therefore heat transfer occurs in both ver-
and Vakilaltojjar and Saman, 2001). As a consequence tical and horizontal directions. In the vertical direction,
of this simplification, in the simulation the initial tem- heat transfer occurs due to the temperature difference
perature of PCM was set equal to the melting between the air flow along the surface of the PCM and
temperature. the layer of the PCM. In the horizontal direction, heat
In the model, the air inlet temperature was 40 C and transfer occurs due to the variation in the temperature
the melting temperature of the PCM was 29 C. It is ex- of the PCM along the horizontal plane. This scheme is
pected that the largest portion of sensible heat transfer shown in Fig. 3. In this scheme heat transfer between
occur on the initial instant after complete melting of the PCM and the fluid occurs along the left, right, lower
PCM; that is when the driving force (i.e. temperature and upper surfaces of the PCM.
difference) is the highest. The mathematical model employed in the current
As a rough estimate, when the PCM used in the mod- work is based on the enthalpy formulation where the
el reaches the equilibrium temperature or steady-state dependent variable is enthalpy. For a phase change
conditions, given the temperature difference between process involving either melting or freezing, energy con-
the melting point and the air flowing outside the PCM servation can be expressed in terms of total volumetric
containers, the maximum sensible heat convected by enthalpy and temperature as follows (Voller, 1990):
the flowing air to the PCM that can be stored is oH
23.43 kJ/kg (or 11% of the total) for CaCl2 Æ 6H2O and þ rðuH Þ ¼ rðkðrT ÞÞ ð1Þ
ot
40.48 kJ/kg kg (or 14.9% of the total) for KF Æ 4H2O.
These figures may justify Vakilaltojjars claim for low where H = total volumetric enthalpy, J/m3; t = time, s;
differences between the air temperatures and melting/ u = velocity; k = thermal conductivity, W/m C;
freezing temperatures. T = temperature, C.
The inclusion of the sensible heat term(s) in a model
that describes the heat transfer between PCM and air,
however, is useful when this term cannot be neglected.
For example, Bruno and Saman (2001) have shown that L
for PCM fibreboards used as heat storage, the sensible Air Flow
heat is significant in the overall heat transfer; and the
model involving only the latent heat is not valid. The ef-
fect of the sensible heat is also important in relation to
thermal comfort consideration. Since the unit being ana-
lysed is used for delivering air to a living space to main- PCM slab
tain the required level of thermal comfort, any factors
Fig. 2. Schematic of the thermal storage unit (TSU).
that affect the thermal comfort need to be considered
carefully.
In the present work, the sensible heat term is included
in the analysis while maintaining the effects of varying
wall temperature on the air temperature. The model con- y
siders both the melting and freezing processes and the ef-
W
H q1 k S
T ¼ Tm þ H > q1 k ðliquidÞ ð8cÞ
ql cl
Fig. 4. Two dimensional domain of the PCM internal nodes
Substituting Eq. (5) into (2) we obtain: notation.
W. Saman et al. / Solar Energy 78 (2005) 341–349 345
is assumed at a certain value above the melting point. used to determine the sensible enthalpy, hs, at the slab
The value of this temperature depends on the final con- surface as follows:
dition of melting during the charge period. These two hs ¼ qs cs ðT PCM T Melt Þ T PCM < T Melt
situations can be used to calculate the initial sensible
enthalpy of the PCM, hinit, as follows: hs ¼ 0 T PCM ¼ T Melt ð16Þ
hs ¼ ql cl ðT PCM T Melt Þ T PCM > T Melt
qs cs ðT m T init Þ
hinit ¼ ð11Þ
ql cl ðT init T m Þ
Eqs. (12)–(15) are used to calculate the fluid, wall and 40°C
5.0 37.5°C
PCM surface node temperatures at any distance from
35°C
the entrance. The surface node temperature, TPCM, is
2.5
T air q T PCM
T Wall
0.0
∆ywall 0 120 240 360 480 600 720 840
1 Time, minutes
hc A k wA
Fig. 6. Effect of the inlet temperature on the heat transfer rate
Fig. 5. Thermal circuit of the air-wall-PCM heat transfer. and melting time (flat slabs).
346 W. Saman et al. / Solar Energy 78 (2005) 341–349
Temperature, °C
fer rates and the melting time during a melting process 35
for three different air flow rates. As seen, a higher flow 15°C 17.5°C
30 20°
rate increases heat transfer rate and shortens the melting
time. The effect of the air flow rate is similar to that of 25
inlet temperature.
As the charge period is limited by the period of solar 20
energy availability, this parameter is an important factor 0 120 240 360 480 600 720 840
Time, minutes
in determining the effectiveness of the TSU. Individual
or combined effect of the inlet temperature and air flow Fig. 9. Effect of air inlet temperature on the air outlet
rate may be the only practical factors that can control temperature and freezing time (flat slabs).
the range of the melting time.
3.2.3. Outlet air temperature profile approaches that of the PCM initial temperature and
For heating, the useful commodity of a TSU is the drops linearly and sharply during the period of the first
outlet air which should be warm enough to provide ther- hour. This is desirable as it delivers warming effect dur-
mal comfort when it is delivered to a living space. Figs. 8 ing the initial period of the system operation.
and 9 show the outlet air temperature resulting from a When the PCM surface temperature reaches the melt-
discharge (freezing) process. Air entering the TSU at a ing point, the outlet temperature drops gradually be-
constant temperature of 20 C is heated as it passes the cause some of the heat is used to freeze the PCM. The
air passages in the TSU having initial temperature of outlet temperature suitable for heating must be limited
40 C. by that necessary for achieving thermal comfort.
Initially, due to the high temperature difference be- The effect of the air flow rate on the outlet air temper-
tween the air and the PCM, the outlet air temperature ature is also worth noting. As the flow rate increases the
outlet air temperature curve shifts downwards which re-
sults in a lower air temperature supply to the living space
10.0 (Fig. 8). Conversely, increasing the air inlet temperature
Inlet temp. = 40°C results in higher air temperature of the air leaving the
Heat Transfer Rate, kW
35
the heat transfer rates reported are within ±0.35 kW.
600 l/s 400 l/s 300 l/s
30
3.3.1. Flat slabs
25 Fig. 10 shows the inlet temperature of the air flowing
into the TSU, the actual outlet temperature from the
20 previous experiment (Vakilaltojjar, 2000) and the outlet
0 120 240 360 480 600 720 840 temperatures predicted by Vakilaltojjars model and the
Time, minutes
present model. The PCM and the thermophysical prop-
Fig. 8. Effect of air flow rate on the air outlet temperature and erties are the same as in the simulation (Section 3.2). The
freezing time (flat slabs). data used in both the models and the experiment were as
W. Saman et al. / Solar Energy 78 (2005) 341–349 347
40 3.0
Inlet
35 2.0
Vakilaltojjar's
1.5
0.0
25 0 120 240 360 480 600 720 840
0 0.25 0.5 0.75 1 1.25
Time, minutes
Time, hrs
Fig. 11. Comparison of the experimental heat transfer rates
Fig. 10. Inlet and outlet air temperature profiles of the TSU with those predicted by the models (conical capsules, melting).
from the two models and the experiment (flat slabs, melting).
Temperature, °C
35
The PCM initial temperature was 25 C.
The figure shows a close agreement between the pre- 30
sent model, Vakilaltojjars model and the experimental Vakilaltojjar's
results. Similar results were found with the experiments 25
Present model
involving freezing. Due to the small mass of PCM used Experiment
in the experiments, the sensible heat effect only appears
20
during the very short time at the beginning of the melt- 0 120 240 360 480 600 720
ing process. Time. minutes
Fig. 12. Inlet and outlet air temperature from the experiment
3.3.2. Conical capsules
and those predicted by the models (conical capsules, melting).
The model also has been used to predict the heat
transfer rate and the outlet temperature profile of a
TSU containing PCM encapsulated in conical capsules. the PCM is at the melting point, the outlet temperature
Due to the difference in the geometry, while keeping increases gradually and finally approaches the inlet tem-
other parameters constant, the equivalent thickness of perature at the end of melting.
a slab and the air gap need to be estimated. Estimation Since the heat transfer rate and air temperature are
was based on the actual heat transfer surface that results coupled, underestimate of heat transfer rate at the begin-
from the arrangement of the conical capsule in the TSU. ning of melting (Fig. 10) is reflected in the rather high
The data of the experiment are as follows (Bruno and outlet air temperature at the same period. Since Vakilal-
Saman, 2002): TSU dimensions = 1.3 m · 0.9 m · 0.6 m, tojjars model ignored the sensible heat, it predicts high-
PCM weight = 253.5 kg, container: conical capsule, air er outlet temperature at the initial period of melting.
flow rate = 264 l/s with varying air inlet temperature. Finally, Figs. 13 and 14 show the heat transfer rate
Fig. 11 shows the heat transfer rates predicted by and air outlet temperature from the actual experimental
both the models and the actual experimental results. results and the models prediction for freezing. As
As can be seen the prediction of the present model shown, the present model predicts accurately both the
underestimates the heat transfer rates during half of heat transfer rate and the air outlet temperature.
the time, however it predicts accurately the melting time
and the total heat stored during the melting. 3.4. Natural convection
Fig. 12 shows the inlet temperature and the outlet
temperatures from the experiment and from both Previously it was suspected that natural convection,
models. occurring inside the PCM during the melting, speeds
As can be seen, in the initial period of melting where up the melting process (Bruno and Saman, 2002). In
the sensible heat is predominant, the actual outlet tem- the present model, natural convection effect has not been
perature and that predicted by the present model rise included; yet it is able to predict quite accurately the
sharply by some degrees above the initial temperature melting time and the heat transfer rate during the melt-
(about 22 C) to a value above the melting point ing. This suggests that for the geometry being consid-
(28 C). In the later period, where the whole surface of ered, the effect of natural convection is rather
348 W. Saman et al. / Solar Energy 78 (2005) 341–349
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