􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇􀪇

JOURNALOFIRON ANDSTEELRESEARCH,INTERNATIONAL􀆰２
０１３,２
０(９):２
１Ｇ２
５
􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉􀪉
􀪉

Ca
lcu
lat
ionandAna lys
isofSulf
ideCapac
iti
esf
or
CaOＧAl２O３Ｇ
SiO２ＧMgOＧTiO２S
las
g
RENZhong
Ｇshan１ ２ , 　HU Xi
aoＧun１ ２ , 　CHOU Kuo
Ｇch
ih１ ２
, , ,
j
(１．Sta
teKeyLabo r
atoryofAdvanced Metal
lurgy,Uni
versi
tyofSc
ienceandTechno
logyBei
jng,Be
i i
jng１０００８３,Ch
i na;
i
２．Departmen
tofPhy s
icalandChemis
try ,SchoolofMeta
llur
gic
alEcol
ogi
calEngi
neer
ing,Unive
rsi
tyo fSc
ienc
eand
Technol
ogyBeii
jng,Beii
jng１０００８３,China)

Abstr
act:Theemp ir
icalmode lsofsulf
idecapac
itycalcu
latedbyt radit
ionaloptic
alba s
ici
tydono tcons
iderthecharge
compensat
ionofa lkal
ineme talionstoAl３＋ inthemo lt
ens lags,sot hatthede v
iat
ionsbe tweent heca
lcula
tedvalues
andme asu
redone sofsu l
fidec apa
cityareinev
itabl
e ．Ther e
lationb e
t weensulfi
dec a ac
it
p ya ndt hecorr
ectedop l
t
ica
bas
ici
typ utfo
r wardb y Mill
sc onsi
deri
n gthechargecom pensati
onw asinvest
igated．Co mbinedw iththerel
ati
onbe Ｇ
tweensulf
idecapacityandt empe ra
tures,anove landa ccuratecalcu
lation modelofsu l
fidec apaci
ty waspropoed,
s
whichwa sappliedt ocalcu
lat
et hesul
fidecapaci
tie
so fCaOＧAl２O３ＧSiO２ＧMgOandCaOＧAl２O３ＧS iO２ＧMgOＧTiO２sysＧ
tems,whe rethesumo ftheCaOand MgOc oncentr
ationsi
ntheslagsmus tbenotlowerthantheAl２O３ c
oncent
raＧ
t
ion．Itwa salsof oundt ha
tthec al
cul
atedva l
ueswe reinagoodag reementwiththemeasuredval s,andt
ue hemean
devi
ati
onswe re２ 􀆰５７％ and２ 􀆰６５％ ,r espect
ivel
y．
Keywo rs:s
d ag;su
l lf
idecapaci
ty;char gecompensaton;c
i o
rre
ctedop t
ica
lbasi
ciy;me
t ande v
iat
ion

　　Wi thu ltraＧlowsu lphu rs teelus edmo r

ewi dely, semi Ｇemp iri
c aland emp iri
cal mode ls２－８ had be en
[ ]

thesme lt
i ngp roc essandt heo r
ieso fu ltra
Ｇlow sulＧ established f o rc alcu l
ating t he su lfide c apa citi
e s．
phu rs t ee
lbe comet hef ocuso fre search．CaF２ ba sed Bas edont he rmodynami csandcons ide r
i ngt hei n
terＧ
slagswh i
chwe rec ommon lyus edhaveabe tterdesＧ actionso fcomponen t sint hes l ,
ags goodr esultsc an
ulf uriz
a t
ione ffect,bu tt hee rosionf orr e
fractoryis beob tai
nedf ormanys l
ags yst emsby KTH ( KungＧ
seriousandt heyc ouldr elea ses omef luo rideswh ich l
i aT ekniska Hög skolan)mod el２－３ ．Howe ver,many
[ ]
g
areha rmf u ltot heenv ir
onmen tandhuman．Cons eＧ parame t
er sa re ne ededi nt hec a
lcu lation p rocess;
quen t
ly,t heapp licationandr esea rcho fCaO ba sed mo reove r,t herei sanoppos itet rendbe twe ent hee sＧ
slagsa ttracted mo r ea tt
en t
i on．Tor ealizet hede ep tima t
edva lue sandme asuredva l uesi nl owS iO２con Ｇ
de sulfurizati ,
on t hec orrects electiono fde sulfuri
zaＧ tents lags４ ．Thec
[]
alculat
ionp roce s so fIMCT ( Ion
tions l
agsi sver yimpo rtant．Asanimpo rtantpa r
amＧ and Mo leculeCoex is
t enceTheo ry)mode l５ ba sedon
[]

ete ro ft hede su lfurizati

ons lags,su lfidec apacit
ies thei on and mo lecule coex i
stenc et heo ryi s mo re
aret hes ign i
fican tba sisf orchoo singanapp ropri
ate comp lex,andt her esultsarea lsono ts at
isfied．The
de sulfurizations l ag．Thought hesu l f
idec apaci
tiesof est
ima ti
onmode lbas edonop tic alba sicit
yha sbe en
var i
ouss l ags had be eni nve stiga ted by many r eＧ deve l
opedobv iousl ,
y wh ichwa sf irs tp ropos edbyD
sea rche s,owi
r ngt ot hel imitationso fsl agsc ompo s
iＧ JSos inskyandIDSomme rvil
l e６ ,bu tt hec a
lcu l
atＧ
[]

tionandt empe rat ures,t heda tao fsu l

fidec apacit
ies edva lue sa r
eal itt
lel argerf orh ighsu l
fidec apa c
ity,
isa lsol imi ted．Henc ,
e t hes imu l
a ti
onr e
search of andt hen mod i
fiedby R W Young７ ．TheYoung
[]
′s
sul f
idec apa citi
e sbe come smo reandmo r eimpo rt
an t． mode lwa sd i
videdin
totwos ect
ionstaki
ngtheoptiＧ
　　S incet hesu lfidec apacity wa sf ir
stp roposedby calbasic
ityva lue０􀆰８a stheboundary,andthecalＧ
CJ B F incham and F D Ri char dson
[１]
, nume rous cula
tiona ccuracyisgre
atl
yimp roved．
InTaniguch
i′s

Foundati
onItem:
Item Sponso
redbyNa tiona
lNatur
alScienceFoundat
iono fCh
ina (
５１０９０３８４)
Bior
gaphy:RENZhong Ｇshan(
１９８６—),Ma le,Do
ctor; 　E Ｇmal:r
i enran１６３＠１６３􀆰com;　Re ce
ive
dDate:Febr
uay１３,２０１２
r
Corres
pondi
ngAuthor: HU Xi ao
Ｇjun(
１９７１—),Ma le,As soc
iat
eProfessr; 　E
o Ｇma
il:huxiao
jun＠us
tb􀆰edu
􀆰cn
 􀅰 ２２ 􀅰 　　　　　　　J
our
nalo
fIr
onandS
tee
lRe
sea
rch,I
nte
rna
tiona
l　　　　　　　　　　　　　　Vo
l􀆰２０　

mode l４ andShanka r′smode l８ ,t heop ticalba sici

t (１);a(O２－ )i st hea ctivit
yo foxygeni nt hes lag;
[] []
y
wa sa lsous edt oc a l
cu l atet hesu lfidec apa cities,and f(S２－ )ist hea c t
ivit y coeffi
ciento fs ulfur int hes lag;
bo tho ft he s emode lshavegoode ff ectsonc alcu lat
ing w (S)ist he ma s
spe rcento fsu l
f uri nt hes l ;
ag and
theh igha lumi nums l agsc on ta
i ning MnOandTiO２ ． pO２ andpS２ a ret hepa rt
ialp r essur eo fO２ andS２i n
Neve rthel ess,t he semode lsus i ngt het r aditiona lopＧ thes yste m , re spe cti
v el
y ．
ticalba sici tyigno ret hecha r gec ompens ationo falkaＧ 　 　Ba s edont heba lancer eac
tionbe twe ens lagsand
l
ine me talc ationst o Al２O３ i nt he mo lten s lags, me tal,E T Turkogan１２ p ropos edano thersu lf
ide
[ ]

wh i chr esu ltsinpr oduc ingt hec alcu lationdev iat

ion capa c
ity (C ′ S ):
ofsu l
fidec apa c
itie s． 　　 [ S]＋ ( O２－ )＝ [ O]＋ ( S２－ ) (４)
　　I ngene rl,t
a heox ide si nt he mo l
t ens lagsc an a[O]
　　C′S＝w (S) (５)
bec lassif
i edi ntot hr eec atego ries:a c
i di
cox ide,e 􀆰g􀆰 a[S]
SiO２ ;ba si cox de,e
i 􀆰g 􀆰CaO,Na２O;andampho ter
Ｇ whe re,a[O]anda[S]a ret hea ctiv i
tieso foxygenand
icox de,e
i 􀆰g􀆰 Al２O３ ． Int hes ilica teme l ts,t hene t
Ｇ sulfuri nt he me t all
icso lu t
ion．Thed istributiono f
wo rks truc t ur
ei sf ormed by S iO４ un
４－
itst ha tare sulfurbe twe ens l agsand me tall
i cso lutioni salways
pol yme riz edt oget he rbyb ri dgingoxygeni ntol a
rger calculatedby Eqn 􀆰( ５),andi tc aneva lua tet hede Ｇ
comp lexan ions,s ucha sS i２O７ , Si ３O１０ a nds oon９ ． su l hur
i zatio na bilit ofs la sint h ea ctu al roducＧ
[]
p y g p
６－ ８－

Whent heba sicox idei sadded,t hec ati onssucha s tionp roc ess．
Ca２＋ and Mg２＋ c anb r eakt hene two rks truct ureand
rele asef re eoxygeni onswh ichpa rti c
i pate in th ed es
Ｇ １􀆰２　Tempe ra turede pendenc eo fs ulfidec apacity
ulf uri
z ationr e
ac t
i on．Howeve ,
r whenAl２O３i sp re
sＧ 　　I tc anbes eent hatt hede su l
f uri
z ationr ea c
tion
ent,t hecond i
tioni schanged．TheAl３＋ c ationsa l
so isanendo the rmi cr eactionf rom Eqn 􀆰( ２),soi tis
formt e trahed ronc oo r dinati ons truc tureAlO５－ ４ ,but be nef
icialf o r de su l
furization w ith an i ncrease in
theva lenc eo fAl３＋ c ationi sl owe rt hant hato fSi４＋ tempe rat ure． I nv iew o fdynami cs,t hei ncreaseo f
cati oni nt het etr ahed ron,s oa l kaline o ra l kal
ine tempe rat ure make st he mob il
ityo fs lagsbe tterand
ear thc ationssucha sCa２＋ and Na＋ a rene ededt o thed iffus ionr ateo foxygenandsu l
f urimpr oved,
ke epcha rgeba lanc ebyf ormi ng [ １/２Ca(AlO) ４]
４－
wh icha rea lsobene ficia
lf orde su lfurization．The reis
or [NaAlO４ ] ４－ [
１０]
,me anwh ilet hedeg r eeo fpo l
yＧ ad irect p ro p ortio nalr elat
i onship bet we ent h et emＧ
me riz
ationi senhanc edandmake st henumbe ro ffree pe r
atureandsu lf
i dec apa cityf rom manys tudiesa s
oxygende cline． Int hecu rr ents t udy,anewanda Ｇ showni
c nF i g􀆰１． Ino therswo rds,t hesu lfi
dec apa c
iＧ
cur ate mode lf orc al culati ng su lfide c apacitieso f ti
e so fs lagsi ncre asea st het empe ratur ei ncreases,
slagsi sp r opos ,
ed wh ichi sba sedont hec orr ec
ted wh ichiscons isten twi tht het heo re ti
calana lysis．
opti
calba s
icit
y ．Thesu l
fidecapa
cit
iesfor CaOＧ
１１ [ ]

Al２O３ＧSiO２ＧMgO and CaOＧAl２O３ＧSiO２ＧMgOＧTiO２

sl
agsa r
ec alcula
ted,andc a
lcula
tedvalue
sc ou
l dbe
ingoodag reemen t wi
thalargenumbero fexper
iＧ
men tdata．
１　Ca
lcu
lat
ion Mod
el
１􀆰１　Su l
fidec apaci
ty
　　Thede sulphu r
iza
tionabil
ityofmo ltensl agsreＧ
f
l ect
edbysu lf
i decapaci
tyisclose
lyrelatedwi ththe
tempe rat
ur eands lagcompo s
iti
ons．Ac cord
ingt othe
balancer e
a ct
ionf orremovingt hegaseoussu lfurby
sl ,
ags CJBF inchamandFD Ri cha
rds on p
[１]
re
senＧ
F
ig􀆰１　Re
lat
ionbetweensu
lfi
dec apa
cit
yandtemp e
rat
urea
t
tedt heconc epto fsul
fidecapac
ityCS:
di
ffe
rentv
a l
uesofcorre
ctedopti
calba
sic
ity
１ １
　　 S２( g)＋ ( O２－ )＝ O２( g)＋ ( S２－ ) (１)
２ ２ １
􀆰３　Co rr
ectedopti
calbas
ici
tydependenc
eo fsul
fide
　　ΔGθ １ ＝１ １８５３５－５８ 􀆰８１５７T 　J /mol３
[]
(２) c
apa ci
ty
ö１/２
K１a(O２－ ) çpO２ ÷
æ
　　Theop t
ica
lba s
ici
tychar
act
eriz
edbyΛ wa sf
irst
　　CS＝ ＝w (S)çç (３)
f(S２－ ) am １５ ,wh
÷
èpS２ ø roposedbyJA Du ff
yand M DI ngr ich
[ ]
p
÷

whe
re,K１ i st heequilibr i
um c ons
tanto fr
eac
tion wasus edto measurethenumbero ffreeoxygeni n
I
ssue９　　　　　Ca
lcu
lat
ionandAna
lys
iso
fSu
lfi
deCapa
cit
iesf
orCaOＧAl２O３ＧS
iO２ＧMgOＧTiO２ S
lags　 􀅰 ２３ 􀅰

thes lag,andt heni twa swi delyapp li

edt od iscus s ti
vely;xi and Λi aret he mol
efract
ionandoptical
thes tructureande stima tethephys ic
alandchemi ca l basi
cit
y ofeachco mp onent,andt
h eval
ueso
f Λi a
re
prope rt
ieso fs l
ags．Howeve ,
ri nt hea luminabe aring showni nTable１１１ ．
[ ]

mo ltenslags,K C Mi l
ls１１ sugge stedt hatt heba si c
[ ]

oxide skep tcha rge bal

a nce wi
t h the Al３＋
in th e Tab
le１　Va
lue
sofop
tic
alba
sic
iti
eso
fpu
reox
ide
s
AlO４－４ first
ly,andt henb roket hene two rkst ructur e CaO Al２O３ S
iO２ MgO TiO２
tofo rmf reeoxygen．Henc e,Mi ll
smod ifi
edt heop Ｇ １
􀆰００ ０
􀆰６０ ０
􀆰４８ ０
􀆰７８ ０
􀆰６１
ti
calba sicit
y Λ to t
h ec orrec
te do pti
cal basi
cit yΛ co
rr
．
Int heCaOＧAl２O３ＧS iO２ＧMgOandCaOＧAl２O３ＧS iO２Ｇ
MgOＧTiO２s lags,t hec orrect
edop tica
lba sicityΛ
cor
r
　 　I nt hep resents tudy,t hes l
agsa rea lwayso f
canbec alculateda sf ol
lows． highba sici
ty andt hecompos it
ionsf ulf
ill( xCaO ＋
　　１)I nt hec aseo fxCaO ≥xAl２O３ xMgO )≥xAl２O３ i nt hea c
tualp roducti
on pr ocess,so
　Λcorr＝ [ ΛCaO × (xCaO －xAl２O３ )＋Λ MgO ×xMgO ＋ thec aseo f( xCaO ＋xMgO )＜xAl２O３ isno tt akeni nto
ΛAl２O３ ×３xAl２O３ ＋ΛSiO２ ×２xSiO２ ＋ΛTiO２ × account．Ac cordingt olotso fresearches,i ti salso
２xTiO２ ]/[(xCaO －xAl２O３ )＋xMgO ＋３xAl２O３ ＋ foundt hatt he reisal inearrela
tionbe tweent heco r
Ｇ
２xSiO２ ＋２xTiO２ ] (６) rectedop ti
ca lba sici
tyandsu lf
idec apaci
tya tac er
Ｇ
　　２ I ) nt hec aseofxCaO ＜xAl２O３ a (
nd xCaO ＋xMgO ≥) taintempe ra turea sshowni nF i􀆰２．
g
xAl２O３ 　 　 Comb in i
ng wi tht heana lyseso ft empe r
ature
　Λcorr＝ [Λ MgO × (
xCaO ＋xMgO －xAl２O３ )＋ΛAl２O３ × andco rrectedop ticalbasici
ty,t helinearr eg re
ssion
３xAl２O３ ＋ΛSiO２ ×２xSiO２ ＋ΛTiO２ × analysisoft her ela
tionbe tweensu lf
idec apa c
ityand
２xTiO２ ]
/[(xCaO －xAl２O３ )＋xMgO ＋ tempe rat
ur ,
e co rr
ected op ti
cal ba s
ici
tyi s made
３xAl２O３ ＋２xSiO２ ＋２xTiO２ ] (
７) basedont hecur rentda tao fCaOＧAl２O３ＧS iO２ＧMgO
whe rethecoe f
ficiens３,２and２a
t r
et henumbe rof andCaOＧAl２O３ＧS iO２ＧMgOＧTiO２s ags,andt
l hec al
Ｇ
oxygena tomsf orAl２O３ ,S iO２ ,and TiO２ ,r e spe
cＧ culati
onequa t
ioni sob ta
ined :

(
a)CaOＧAl２O３ＧS
iO２ＧMgOs
ysem; 　 (
t b)CaOＧAl２O３ＧS
iO２ＧMgOＧTiO２s
yst
em．
F
ig􀆰２　Re
lat
ionb
etwe
ens
ulf
idec
apa
cit
yandc
orr
ect
edop
tic
alba
sic
ityo
ftwos
yst
emsa
tdi
ffe
ren
ttemp
era
tur
es

－４７２３６􀆰６＋５２２７３ 􀆰７Λcorr whe re,l gCSmea andl gCScal aretheme asur

edandc a
lＧ
　　l
gCS＝ －
T culatedsu lf
idec apacit
iesr, espe
c t
i vel ;
y andN i sthe
１９􀆰４６Λcorr＋１６􀆰８９ (
８) numbe ro fsulfidec apacity．
　　Fo rCaOＧAl２O３ＧS iO２ＧMgOs ys tem,expe r
imenＧ
２　App
lic
ati
ono
fMod
el ,
talda t
af rom Y Tan iguch ie ta l A Shanka ret
[４]

　　Thep resentmode lhasbe enemp l

oyedt oesti
Ｇ al８ ,H Hayakawae ta l１４ and YANG Xue Ｇminet
[] [ ]

matethesu lfidecapaci
tieso f molt
en sl
agsi nthe al１６ we
[ ]
reemp loyedt oa ssesst her el
iab
ili
ty ofthe
CaOＧAl２O３ＧSiO２ＧMgO and CaOＧAl２O３ＧS iO２ＧMgOＧ cal
cu la
tedva lue s．Asc anbes eenf r om Fig􀆰３ (a),
TiO２ syst
ems．The me an devi
ati
ons ofe st
imat
ion thec al
cu lat
edva luesa rei ngoodag reemen twiththe
werecalcul
ateda sfo
llows: experimen talda ta．Theme andev ia t
i onfort hi
ssysＧ
１N | l
gCScal －l
gCSmea| temi s２ 􀆰５７％．
　　Δ＝ Σ ×１００％ (
９)
Nn＝１ l gCSmea 　 　Fo r CaOＧAl２O３ＧS iO２ＧMgOＧTiO２ s ystem,ex Ｇ
 􀅰 ２４ 􀅰 　　　　　　　J
our
nalo
fIr
onandS
tee
lRe
sea
rch,I
nte
rna
tiona
l　　　　　　　　　　　　　　Vo
l􀆰２０　

per
imentaldatafrom A Shankaretal８ and Tang thecal
culated val
uesf i
t we l
l withthe measur
ed
[]

Xinetal we reusedf
orac ompar
isonwit
hthec a
lＧ ones,thoughsomes ca
tteredresu
ltsoccur
red．The
[
１８]

cu
latedvalues．I
tc anbeseenfrom Fig ( )
􀆰３ b t hat meandeviationfo
rt h
iss ys
t emis２􀆰６５％．

(
a)CaOＧAl２O３ＧS
iO２ＧMgOs
ysem; 　 (
t b)CaOＧAl２O３ＧS
iO２ＧMgOＧTiO２s
yst
em．
F
ig􀆰３　Compa
ris
onb
etwe
enl
gCSmea andl
gCScalf
ortwos
yst
ems

desulfur
izationabil
ityofCaOi salsost
rongerthan
３　Di
scu
ssi
on
thatofMgO．Th isresu
ltha sbeenconf
irmedby K
　　I tc anbes eenf rom F i 􀆰１andF i 􀆰２t ha ttemＧ Karsrud１９ andJ D Seo２０ ．I nt hei
rresea
rch,by
[ ] [ ]
g g
pe ratureandt hec orre ctedop ti
calba sic
ityhavet he keepingt hecon t
entofSiO２andAl２O３cons t
ant,the
samee ffectont hesu lfidec apa ci
ties．Ifoneo ft hem repl
ac emento fCaO by MgOl eadstoade cr
eas
ei n
isf xed,t
i hesu l
fidec apa citieso fslagsinc reasewi th sulf
idec apacit
ya sshowni nF i
g􀆰４．
ano the rris e．Thes truc tu r
eo fslagsi srelatedt ot he
op ti
calba sici
t y．Be c aus et hei ncreaseo fop t i
calba Ｇ
sicity me ansmo reba sicox ide saddedi ntos l ,
ags ex Ｇ
pe ctfo rcha rgeba lanc eou tside,t herewou ldbeex Ｇ
traa lka l
ineme tali onst opa rtic
ipate inb reaking e
th
netwo ,
rk r elea s
ing mo ref re eoxygen and mak ing
the mob ilityo f mo ltens l
agsbe t
ter,wh ich havea
goode ffe c
tonde su l
f urization．
　 　 Howeve ,
r t hei ncreasingsu lf
idec apa ci
tie
sa s
theox ide saddeddono tme ant hatt heox ide shave
thes ame ab ili
tyo f de su lfurizat
ion．I nt he CaOＧ
Al２O３ＧS iO２ＧMgOs yst em,t hema inox idesus edf or
de sulfurizationa r e MgO and CaO,andt her eacＧ
tions８ a rea sf o
ll ows:
[]
F
ig􀆰４　Ef
fec
tso
fMgOc
ont
entons
ulf
idec
apa
cit
y
１ １
　MgO( s)＋ S２( g)＝MgS( s)＋ O２( g) 　 　I nt hes t
udy o f CaOＧAl２O３ＧS iO２ＧMgOＧTiO２
２ ２
system,AShanka re ta l８ andTangXi neta l１８ had
[] [ ]
　　ΔGθ＝１８５５５６－１１ 􀆰９７T 　J /mo l (１０)
１ １ f
oundt hatthesu l
fidec apa c
itiesde c
r eased witht he
　CaO( s)＋ S２( g)＝CaS( s)＋ O２( g) i
nc r
e a
seo f TiO２ conc entrat
ioni nsl agsa ta g iven
２ ２
　　ΔGθ＝９６６８４－５ 􀆰２５T /mo
J l (１１) t
empe rat
ure．TiO２ wit ht hecon tentr angeo f０－７％
Ac cord ingt oΔG ＝－RTl
θ
nK ,t heequ i
libriumc onＧ i
nShanka r′sworkha ss li
gh teffectonsu l
fidecapa ciＧ
stan to fr eaction ( １０)i ssma l
lert hant hato fr eacＧ ty．InTang ′swo ,
rk t hecon tento fTiO２i nthes lags
ti (
on １１ a ) taf i xedt empe ratur ,
e wh ichsugge s
ts i
sa sh igha s２５％ ,wh i
chbe longst oh ight i
tani um
tha tt hede su lfuriza tion deg r eeo f MgO i s weake r s
l ,
ag wh ilethereisas i
gn i
ficantde clinei nsu lfide
thant hato fCaO．Fu rthe rmo re,duet ot hel arger capaci
ty withtheinc r
e aseo fTiO２con tent．IDSomＧ
fCaO,t me rvi
lleandH BBe l
l２１ sugge stedt hatTiO２ a c ted
[ ]
op ti
calba sicity va lueo herea re mo ref ree
oxygeni onsc ontri bu tedbyCaOi nthes lags,s ot he asacidicox i
deint heba sicslagsandex is
tedi nt he
I
ssue９　　　　　Ca
lcu
lat
ionandAna
lys
iso
fSu
lfi
deCapa
cit
iesf
orCaOＧAl２O３ＧS
iO２ＧMgOＧTiO２ S
lags　 􀅰 ２５ 􀅰

６ ,w
fo
rmo fTiO８－ h
ichenhanc
edthedegr
eeofpol Ｇ [
６] 　So nskyDJ,Somme
y si rvil
leID．TheCompo s
iti
onandTemperＧ
atur
eDependenceo
ftheSu l
fideCapaci
tyofMe tal
lur
gic
alS
lags
meriza
tionanddecre
asedthenumberoff
reeoxygen [J]．Meta
llur
gic
aland Mate
rial
sTr ansa
ctons,１９８６,１７B(
i ２):
i
onsi nt hes
lags,andthenreduc
edthesulf
idecaＧ ３３１．
paci
ty． [
７] 　YoungR W,Du f
f yJA,Ha s salGJ,e
l ta l．Us eo fOp ticalBa Ｇ
sicityConc eptf o rDe termi ni ngPho spho rusandSu lphurS l agＧ
４　Conc
lus
ion
s Me talPa rtitions [ J]． Ironmak ingandS teelmak ing,１９９２,１９
(３):２０１．
　　１)Ac cordingt ot her elationamongsu lfidec aＧ
[
８] 　Shanka rA,Go rne rupM,Lah iriA K,e ta l． SulfideCapa ci
t yo f
pacit ,
yt empe ratu r ,
e andc o rrectedop ticalbasicity, Hi ghAl umi naB la stFur naceS lags [J]．Me t al
l urg i
caland Ma Ｇ
anewanda ccu r
at emode lf orc a
l culatingsulfidec aＧ te rial
sTr ans actions,２００６,３７B( ６):９４１．
pacit
ieso fm oltens lag sis r
p po os ed． T hecalculated [
９] 　ZhangG H,XueQ G,ChouK C．S tudyonRe lationBe twe en
valuesf orCaOＧAl２O３ＧS iO２ＧMgO and CaOＧAl２O３Ｇ Vi s cosityandEl ec tricalConduc tivi
tyo fAl umi no si
licate Me lts
[J]． Ironmak ingandS te elmak ing,２０１１,３８( ２):１４９．
SiO２ＧMgOＧTiO２ sys tems a rei n good ag reemen t [
１０] 　ShuQ F．A Vi scosityEs tima t
ion Mode lf or Mo l
tenS lagsi n
witht heexpe rimen talr esults． Al２O３ＧCaOＧMgOＧS iO２ Sys t em [ J]．S teelRe s earchI nter naＧ
　　２)Wi tht her iseo ft hec or rectedop t
icalba sic
iＧ t ional,２００９,８０( ２):１０７．
ty,t hemob ili
t yo fmo lt
ens lagsbe come sbe tt
e rand [
１１] 　 Mi lls K C,Sr idha rS．Vi s cositi
eso fI ronmak i
ngandS t eelＧ
ags [ J]．I ng,１９９９,２６
thenumbe ro ffre eoxygeni onsi ncr e
a ses,wh ichr eＧ mak ingS l ronmak ingand S te elmak i
(４):２６２．
sultint hei ncreas eo fsu lf
idec apa ci
ties． [
１２] 　TurkoganET． SlagsandF luxe sforFe rrousLad leMe tallur gy
　　３)I nt hea lumi no s
ilica
t eme lts,t headd itiono f [J]． I ronmak ingandS teelmak ing,１９８５,１２( ２):６４．
MgOandCaOc ani nc reaset hesu lfidec apaci
tie sof [
１３] 　Go rn erup M,Wi jk O．Su lph ideCa paci
tieso fCaOＧAl ２O３ ＧS iO２
t１５５０,１６００and１６５０ ℃ [ J]．
mo lt
en s lags;howeve r,i nt he CaOＧAl２O３ＧS iO２Ｇ Sl agsa Scand inav ianJ our na lo f
Me tallur gy,１９９６,２５( ３):１０３．
MgOs ystem,r ep lac
i ng CaO by MgO wou ld make [
１４] 　HayakawaH,Ha segawaM,Oh ＧNuk iK,e ta l． Sulph i
deCa Ｇ
thesu lf
idec apa ci
t yde cli
nea tac onstan tlevelo fsil
iＧ pa ci
tieso fCaOＧS iO２ＧAl２O３ＧMgO S ags [
l J]．S t eelRe s ear ch
caanda lumi nai nt hes lag． I nter nationa l,２００６,７７( １):１４．
　 　４) Whent herea re mo re TiO２ i nt he CaOＧ [
１５] 　Du ffyJA,I ng ram M D．AnI n t
erpretationo fGl assChemi sＧ
t ryi nTe rmso ft heOp ticalBa sic
ityConc ep t[ J]． Jour na lo f
Al２O３ＧS iO２ＧMgOＧTiO２ sys t ,
em TiO２ ex istsa sb ig Non ＧCr yst al
lineSo lids,１９７６,２１( ３):３７３．
comp lexan ions,e 􀆰g􀆰 TiO８－ ６ ,w hichha sa ma rked [
１６] 　YANGXue Ｇmi n,J IAOJ inＧsha,DINGRu Ｇ cai,e ta l．A The rＧ
eff
e c
tonde creasingt hesu l
fidec apa c
i t
y． modynami cMode lf orCa lcu lat
ingSu lphurDi stribution Ra tio
Be twe en CaOＧAl２O３ＧS iO２ＧMgO I ronmak ing S lagsand Ca rＧ
Re
fer
enc
es:
bonSa tur atedHo tMe t alBa sedont heI onand Mo leculeCo Ｇ
[
１] 　Fincham CJB,Ri char
dsonFD．TheBehav iouro fSulphurin ex i
stenc eTheo ry[ J]．I SIJI nternational,２００９,４９ ( １２):
Si
licat
eandAl uminateMe ls[
t J]． Proceedi
ngso ftheRoya lSoＧ １８２８．
c
ietyo fLondonSe ries,１９５４,２２３A( １１５２):４０． [
１７] 　Ot a M,KuboT,Mo r
it aK．Ef fect
so fCaF２,MgOandS iO２
[
２] 　Nz ot
ta M M,S chenDu,Se
i etharamanS．Su lphideCapa c
iti
es Add itionon Su lfide Capa citieso ft he CaOＧAl２O３ S lag [ J]．
i
nSomeMu l
tiComponen tS lagSys tems [J]． IS
IJI n
ternati
onＧ Te tsu ＧtoＧHagane,２００３,８９( ７):７４２ ( inJ apane s e)．
al,１９９８,３８( １１):１１７０． [
１８] 　TangXi n,XuChushao．Su lphurDi stri
bu tionBe twe enCaOＧ
[
３] 　DrakaliyskyE,S ichen Du,Se etharamanS．AnExpe r
imen ta
l SiO２ＧTiO２ＧAl ２O３ＧMgO S lagandCa rbon ＧSa tur atedI rona t
Studyo ft heSulphide Capacit
iesi nt heSys tem Al２O３ＧCaOＧ １７７３K [ J]． ISIJI n t
er nationa l,１９９５,３５( ４):３６７．
SiO２ [J]．Canad ian Me t
allurgic
a l Quart
erly,１９９７,３６( ２): [
１９] 　Ka rsr udK． Su lfideCapa ci
tie sofSyn the t
icB lastFur na ceS lags
１１５． at１５００ ℃ [ J]． Sc and inavianJ ournalo fMe t
all urgy,１９８４,１３
[
４] 　Tan i
guchiY,Sano N,Se e
tharamanS．Su lphideCapaci
tiesof (３):１４４．
CaOＧAl２O３ＧSiO２ＧMgOＧMnOS l
agsi ntheTempe rat
ureRange [
２０] 　SeoJD,Kim S H．TheSu lphideCapa cityo fCaOＧAl２O３Ｇ
１６７３－１７７３K [ J]．I
S IJInte
rnati l,２００９,４９(
ona ２):１５６． SiO２ＧMgO ( ＧFeO)Sme ltingReduc tionS lags [ J]．S tee lRe Ｇ
[
５] 　SHICheng Ｇbin,YANG Xue Ｇmin,J IAOJ i
nＧsha,etal．ASu l
Ｇ se archI nte rnationa l,１９９９,７０( ６):２０３．
phide Capac
ity Predi
c t
ion Mode lo f CaOＧSiO２ＧMgOＧAl２O３ [
２１] 　Somme r villeID,Be l
lH B．TheBehav ioro fTi tan i
ai n Me talＧ
Ir
onmak ingSlagsBa sedont heI onand Mo l
eculeCoexis
tenc
e l urgic alS lags [ J]．Canad ian Me tall
ur gical Qua rt
erly,１９８２
Theo ry[J]．ISI
JI n
ternati
onal,２０１０,５０( １０):１３６２． (２):１４５．