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HCl 0.02
HBS
Water 0.01
ETA
Diketone
IPA
HCl
Toluene
QTP-IV
NN Dimethyl Aniline
R-1638 POCl3
Toluene
QTP-VI Water
HCl
Pregablin
CO2
TBA
Bupropion BUP-1
Chloroform
ETA
Diketone
IPA
HCl
Toluene
QTP-IV
NN Dimethyl Aniline
R-1645 POCl3
TBA
Bupropion BUP-1
Chloroform
HCl
Pregablin
CO2
HCL
IPA
Celecoxib Water
Water 0.02
HBS HCl 0.03
IPA
Diketone Water
IPA
R-1677 Water
Hcl
QTP-VI Toluene
Toluene
QTP-IV Water
Toluene
Bupropion Water
HCl
Pregablin
Toluene
IPA
QTP--IV
HCl
Water
IPA
Water
QTP-VI
Hcl
Toluene
R-1671
HCl 0.1
HBS CO2 31
SO2 69
HCL
IPA
Celecoxib Water
Toluene
Bupropion
HCl
Toluene
QTP-IV Water
HCl 0.1
HBS CO2 31
R-1694 SO2 69
Methanol
Pregablin CO2
Toluene
Bupropion
HCl
QTP-IV Toluene
N Methyl Pyrollidone
QTP-VI Toluene
R-1666
CO2
Toluene
Bupropion TBA
QTP-IV Toluene
QTP-VI Toluene
R-1641 Bupropion Toluene
Toluene
Pregablin
Methanol
Bupropion Toluene
1.1
0.6
1.1
0.6
0.01
1.4
0.01
0.39
0.1
0.01
1.4
0.01
0.01
0.78
0.97
0.25
Bupropion Pregablin Total emission Pollutant Flow rate(Kg/hr)
Air flow rate(m3/hr) Air flow rate based on vent lines
0 0.00
Sl. No. Equipment Tag No MOC
1 Reactor R-1638 MSGL
10 m3/hr
Connected Pump Charging rate
Tank Capacity 20 KL
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 1.8
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
B) Charge POCl3 into the reactor containing Toluene and QTP-II at temperature 25-30°C fro
2 m3/hr
Connected Pump Charging rate
From Drum
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
2 QTP-II 227.29 0.45
Total
Mw
Kg/Kgmol
1 Toluene 92.14 0.895
2 POCl3 153.33 1.000
3 Nitrogen 28
Total
Summary
Toluene Emission Rate ER, ni =
POCl3 Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Volume qty
Mol. Weight
charged
S.No Component Name
Mw
Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
2 POCl3 153.33 0.2226
3 N,N Dimethyl aniline 121.19 0.149
Total
4 Nitrogen (Residual) 28
= 0.285381692
= 0.014841973
= 0.208568178
= 0.284005282
Total 329.75
Summary
Toluene Emission Rate ER, ni =
POCl3 Emission Rate ER, ni =
N,N Dimethyl aniline ER, ni =
Nitrogen Emission rate ER, N2 =
Distillate
Mol. Weight
S.No Component Name Volume
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
2 unreacted POCl3 153.33 0.2226
3 N,N Dimethyl aniline 121.19 0.149
4 PO2 Cl 98.4256
5 Hcl 36.45
6 QTP-III 245.73
Total
=
En-i, *Mw
=
En-i, *Mw/t
Summary
Toluene Emission Rate ER, ni =
POCl3 Emission Rate ER, ni =
N,N Dimethyl aniline ER, ni =
HCl ER, ni =
E) Distill out the POCL3 and Toluene below 115°C (Atm dist)
Distillate
Mol. Weight
S.No Component Name Volume
Mw
Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
2 POCl3 153.33 0.06
3 N,N Dimethyl aniline 121.19 0.149
Total
4 Nitrogen (Residual) 28
= 0.285381692
= 0.013237594
= 0.187176955
= 0.195097427
Total 295.96
Summary
Toluene Emission Rate ER, ni =
POCl3 Emission Rate ER, ni =
N,N Dimethyl aniline ER, ni =
Nitrogen Emission rate ER, N2 =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 0.615
2 POCl3 153 0.06
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
POCl3 Emission rate ER, N3 =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 3.3
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
H Charging of Toluene at temperature 25-30°C to Reactor-1666
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 5
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
I Heat the reaction mass to reflux temperature 80°C.
Volume qty
Mol. Weight
S.No Component Name charged
Mw Vi
Kg/Kgmol m3
1 Toluene 92 5
Total
4 Nitrogen (Residual) 28
= 0.194331154
= 0.050421674
= 0.068500796
= 0.065614744
1 Toluene 92 163.50
Total 396.50
Summary
Toluene Emission Rate ER, ni =
Filteration
J Charging of reaction mass into filter
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 4.7
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
K Charging toluene into filter
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 0.45
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
L Charging of reaction mass into Reactor R-1694
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 5.083
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
Total
Mw
Kg/Kgmol
1 Toluene 92.14 0.895
2 IPA 60 0.297
3 HCl 36.5 0.110
4 Water 18 0.594
Total
Nitrogen 28
Summary
Toluene Emission Rate ER, ni =
IPA Emission rate ER, ni =
HCl Emission rate ER, N2 =
Water emission rate ER, N3 =
Nitrogen Emission rate ER, N4 =
Second filteration
M Charging reaction mass into centrifuge
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 5.914
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 0.45
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
O Drying
kg
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92 0.108
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene ER, ni =
Nitrogen Emission rate ER, N2 =
Capacity
8 KL
1559 16.918
0.64 Kg/hr
3.86 Kg/hr
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.78 16.918 0.895
1000 450 0.22 1.980 0.105
2009 18.898
Pi pi
(mm Hg) (mm Hg) °C
T
1.00 0.9 36.7 32.80 30
1.00 1.0 45.32 45.32 30
681.88 30
760
0.04 Kg/hr
0.08 Kg/hr
0.22 Kg/hr
2067 20.479
7.877 m3
30
105
2.5 hrs
Average
Average
Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
1.000 0.28
8.9 Kg/hr
2.5 Kg/hr
0.1 Kg/hr
0.48 Kg/hr
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.75 16.918 0.826
1640 61 0.03 0.397 0.019
960 143 0.07 1.180 0.058
195 0.09 1.980 0.097
1180 72 0.03 1.983 0.097
487 0.24 1.980 0.097
2516 24.438
6 hrs
10.1279922444 0.138864574
933.1932053986 Kg 21.2921052
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.75 16.918 0.826
1640 98 0.05 0.642 0.031
960 143 0.07 1.180 0.058
1800 18.740
7.877 m3
30
105
2.5 hrs
Average
Average
Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
1.000 0.28
10.0 Kg/hr
0.7 Kg/hr
0.1 Kg/hr
0.37 Kg/hr
0.13 Kg/hr
0.07 Kg/hr
0.00 Kg/hr
2858 31.016
1.44 Kg/hr
1.20 Kg/hr
Weight qty Weight Mole
Density Moles
Charged Fraction Fraction
ρ Wi Xi
Kg/m3 Kg
866 4330 1.00 46.994 1.000
4330 46.994
0.48 Kg/hr
2.87 Kg/hr
ρ Wi Xi
Kg/m3 Kg Kg moles
866 4330 1.00 47.065 1.000
4330 47.065
5.2 m3
30
80
4 hrs
Average
Average
Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
1.000 0.15
1.5 Kg/hr
0.08 Kg/hr
Weight qty Weight Mole
Density Moles
Charged Fraction Fraction
ρ Wi Xi
Kg/m3 Kg
866 4070 1.00 44.174 1.000
4070 44.174
0.45 Kg/hr
2.70 Kg/hr
390 4.229
4402 47.774
0.49 Kg/hr
2.92 Kg/hr
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.78 16.918 0.895
1559 16.918
Pi pi
(mm Hg) (mm Hg) °C
T
1.00 0.9 37.0 33.10 30
1.00 0.3 58 17.21 30
1.00 0.1 21 2.30 30
1.00 0.6 31 18.40
760
688.99 30
0.07 Kg/hr
0.02 Kg/hr
0.00 Kg/hr
0.01 Kg/hr
0.46 Kg/hr
5122 55.584
rogen, and the vessel is vented to atmosphere
760 mm Hg
PT - Pi = 723 mm Hg
pnV/RT = 0.24 Kg moles
En, N2*Mw = 6.78 Kg
Ewt, N2 /t = 3.39 Kg/hr
0.57 Kg/hr
3.39 Kg/hr
390 4.229
0.04 Kg/hr
0.26 Kg/hr
Weight qty Weight Mole
Density Moles
Charged Fraction Fraction
ρ Wi Xi
Kg/m3 Kg
886 91 1.00 0.992 1.000
91 0.992
0.07 Kg/hr
0.03 Kg/hr
R = 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
0.5 36.7 30 36.65 0.0035
Inlet Stream Analysis:
1.00 1 POCl3
1.00
Total
Average
Average Emission Average Emission Emission Air velocity Flow
rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0004 0.04 0.04
0.0005 0.08 0.08
0.0080 0.22 0.22
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 105°C pi @ 105°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
35.60 624.18
724.40 135.82
mm Hg
Pi @ 105°C pi @ 105°C
(mm Hg) (mm Hg)
646.1 533.78
753.82 14.63
47.91 2.76
551.17
0.0262143443
3.1769163817
0.5294860636
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
31.76 560.16
728.24 199.84
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
5 291.0 80 261.863714 0.0073
5 343.0 80 34.3427701 0.0001
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
2 203.0 70 203 0.0313
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
2 37.0 10 37 0.0105
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 80°C pi @ 80°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
37.00 290.00
723.00 470.00
760
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
2 37.0 10 37 0.0099
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
2 37.0 10 37 0.0009
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
2 37.0 10 37 0.0107
Total
Average
Average Emission Average Emission Emission Air velocity Flow
rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0008 0.07 0.07
0.0004 0.02 0.02
0.0001 0.00 0.00
0.0005 0.01 0.01
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
2 37.0 10 37 0.0124
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
2 37.0 10 37 0.0009
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
2 291.0 80 291 0.0014
mm Hg/ (K. Kmol)
Mw Vi ρ Wi t Xi
365 0.007
Flow
(CFM)
Average Average Air
Flow Flow
Emission Emission rate velocity
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.67 0.13
0.01 0.00
Average Average Air
Flow Flow
Emission Emission rate velocity
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
2.89 1.44
Average Average Air
Flow Flow
Emission Emission rate velocity
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.97 0.48
Average Average Air
Flow Flow
Emission Emission rate velocity
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.91 0.45
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
60 - - 163 0.50 1.00 0.008
65 - - 65 0.20 1.00 0.003
18 - - 98 0.30 1.00 0.017
Flow
(CFM)
1.000 1.00
the inlet stream is in direct contact with the vessel headspace as it enters the
vessel.Therefore, the equilibrium vapor composition for the inlet stream will be
based on the exact composition ,of the inlet stream. A dilution factor ϕ for the
inlet stream will be assumed to be 1.0
162.5
97.5
A) Charging of Water at temperature 30°C to Reactor
Mw Vi
m3
1 Water 18 3
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Water Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
B) Charge Toluene into the reactor containing Water and NaoH at temperature 40°C from drum
Kg/Kgmol m3
1 Water 18 3
2 NaoH 40 0.077
Total
Mw
Kg/Kgmol
1 Water 18 0.976
2 Toluene 92 1.000
3 Nitrogen 28
Total
Summary
Water Emission Rate ER, ni =
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 3
2 Water 18 3
Total
4 Nitrogen (Residual) 28
= 0.0755185626
= 0.0044927324
= 0.0088129443
= 0.0009403177
Total 68.23
Summary
Toluene Emission Rate ER, ni =
Water Emission Rate ER, ni =
Mw Vi
m3
1 Toluene 92 2.8
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Mw
Vi
Kg/Kgmol m3
1 Toluene 92.14 2.8
2 N-Methyl pyrolidone 99 0.45
Total
4 Nitrogen (Residual) 28
= 0.2203493019
= 0.0107438611
= 0.1423580633
= 0.1437701229
Component Name Mol. Weight Avg pi
S.No
Mw
Kg/Kgmol (mm Hg)
Total 292.58
Summary
Toluene Emission Rate ER, ni =
N-methyl Pyrolidone ER, ni =
F Charging of Toluene at temperature 30°C to Reactor third reactor with reaction mass and w
Mw Vi
m3
1 Toluene 92 2.8
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Assuming QTP is not volatile
G Charging of Toluene at temperature 30°C to Reactor third reactor on top of reaction mass c
Mw Vi
m3
1 Toluene 92 2
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Mw
Vi
Kg/Kgmol m3
1 Toluene 92.14 2.8
Total
4 Nitrogen (Residual) 28
= 0.1591210348
= 0.0072319031
= 0.1022012192
= 0.1777195626
Total 289.83
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Mw Vi
m3
1 Toluene 92 1
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Filteration
J Charging of Toluene at temperature 10°C to Reactor second reactor
Mw Vi
m3
1 Toluene 92 4.7
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Mw Vi
m3
1 Toluene 92 1
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 4.5
Total
Mw
Kg/Kgmol
1 Toluene 92.14 1.000
2 IPA 60 0.297
3 HCl 36.5 0.110
4 Water 18 0.594
Total
Nitrogen 28
Summary
Toluene Emission Rate ER, ni =
IPA Emission rate ER, ni =
HCl Emission rate ER, N2 =
Water emission rate ER, N3 =
Nitrogen Emission rate ER, N4 =
Weight qty Mole
Density Weight Fraction Moles
Charged Fraction
ρ Wi Xi
Kg/m3 Kg
1000 3000 1.00 166.667 1.000
3000 166.667
0.09 Kg/hr
3.24 Kg/hr
Kg/m3 Kg Kg moles
1000 3000 0.95 166.667 0.976
2120 163 0.05 4.081 0.024
3163 170.748
Ẋi Partial System
ϕA, ϕB Vapor Pressure
Pressure Temp.
Pi pi
(mm Hg) (mm Hg) °C
T
0.93 0.9 31.7 28.81 40
1.00 1.0 59.6330512895 59.63 40
671.56 40
760
0.15 Kg/hr
1.57 Kg/hr
5.39 Kg/hr
ρ Wi Xi
Kg/m3 Kg Kg moles
866 2598 0.46 28.196 0.145
1000 3000 0.54 166.667 0.855
5598 194.863
1.923 m3
30
50
2 hrs
1.000 0.00
0.0059542595 Kg/hr
0.0072996658 Kg/hr
0.0052605296 Kg/hr
ρ Wi Xi
Kg/m3 Kg
866 2425 1.00 26.357 1.000
2425 26.357
0.51 Kg/hr
3.00 Kg/hr
System Pressure PT = 760
ρ Wi Xi
Kg/m3 Kg Kg moles
866 2425 0.84 26.316 0.849
1030 464 0.16 4.682 0.151
2888 30.998
6.082 m3
30
105
5 hrs
Fraction to Average Average
Average Emission
Total Emission Emission rate
1.000 0.14
2.6 Kg/hr
0.0413314584 Kg/hr
0.28 Kg/hr
ρ Wi Xi
Kg/m3 Kg
866 2425 1.00 26.357 1.000
2425 26.357
0.50 Kg/hr
3.00 Kg/hr
n top of reaction mass contatining toluene
Weight qty Mole
Density Weight Fraction Moles
Charged Fraction
ρ Wi Xi
Kg/m3 Kg
866 1732 1.00 18.826 1.000
1732 18.826
0.36 Kg/hr
2.14 Kg/hr
ρ Wi Xi
Kg/m3 Kg Kg moles
866 2425 0.84 26.316 0.849
2425 26.316
4.392 m3
30
105
5 hrs
1.000 0.14
2.6 Kg/hr
0.20 Kg/hr
stillation
Weight qty Mole
Density Weight Fraction Moles
Charged Fraction
ρ Wi Xi
Kg/m3 Kg
866 866 1.00 9.413 1.000
866 9.413
0.87 Kg/hr
0.73 Kg/hr
ρ Wi Xi
Kg/m3 Kg
866 4070 1.00 44.241 1.000
4070 44.241
0.18 Kg/hr
1.83 Kg/hr
ρ Wi Xi
Kg/m3 Kg
866 866 1.00 9.413 1.000
866 9.413
0.04 Kg/hr
0.39 Kg/hr
Weight qty Mole
Density Weight Fraction Moles
Charged Fraction
ρ Wi Xi
Kg/m3 Kg Kg moles
866 3897 1.00 42.294 1.000
3897 42.294
Ẋi Partial System
ϕA, ϕB Vapor Pressure
Pressure Temp.
Pi pi
(mm Hg) (mm Hg) °C
T
1.00 1.0 37.0 36.99 30
1.00 0.3 58 17.21 30
1.00 0.1 21 2.30 30
1.00 0.6 31 18.40
760
685.09 30
0.08 Kg/hr
0.02 Kg/hr
0.00 Kg/hr
0.01 Kg/hr
0.45 Kg/hr
R = 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1 31.7 30 31.740167271 0.0050
Total
Average
Average
Average Emission Emission Air velocity Flow
Emission
rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0041 0.07 0.15
0.0086 0.79 1.57
0.0963 2.70 5.39
mm Hg
44.15 92.32
715.85 667.68
Vapor System Partial
Time Average Emission
Pressure Temp. Pressure
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1 37.2 30 37.216055655 0.0055
mm Hg
33.38 551.77
726.62 208.23
Vapor System Partial
Time Average Emission
Pressure Temp. Pressure
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1 37.0 30 37 0.0055
Vapor System Partial
Time Average Emission
Pressure Temp. Pressure
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1 37.0 30 37 0.0039
mm Hg
31.11 548.55
728.89 211.45
Vapor System Partial
Time Average Emission
Pressure Temp. Pressure
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1 203.0 70 203 0.0095
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
3 22.0 10 22 0.0059
Vapor System Partial
Time Average Emission
Pressure Temp. Pressure
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
3 22.0 10 22 0.0012
1.00 1 IPA
2 HCl
3 Water
Total
Average
Average
Average Emission Emission Air velocity Flow
Emission
rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0009 0.08 0.08
0.0004 0.02 0.02
0.0001 0.00 0.00
0.0005 0.01 0.01
2425 26.357
Flow
6.577
(CFM)
Average Average Air
Flow Flow
Emission Emission rate velocity
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
60 - - 181 0.50 1.00 0.008 0.297
65 - - 72 0.20 1.00 0.003 0.110
18 - - 108 0.30 1.00 0.017 0.594
Flow
(CFM)
the inlet stream is in direct contact with the vessel
headspace as it enters the vessel.Therefore, the equilibrium
vapor composition for the inlet stream will be based on the
exact composition ,of the inlet stream. A dilution factor ϕ for
the inlet stream will be assumed to be 1.0
Dilution
factor for
the inlet
stream
1.00
the inlet stream is in direct contact with the vessel
headspace as it enters the vessel.Therefore, the equilibrium
vapor composition for the inlet stream will be based on the
exact composition ,of the inlet stream. A dilution factor ϕ for
the inlet stream will be assumed to be 1.0
325 65
Dilution
factor for
the inlet
stream 162.5
97.5
1.00
INPUT
QTP-II 450
Toluene 1558.8
POCl3 364.5
N,N Dimethyl aniline 143.55
Total 2517
OUTPUT
Mol. wt Component
Kg/Kmol
227.29 QTP-III
92.14 Toluene
153.33 Po2 Cl
121.19 Hcl
unreacted POCl3
N,N Dimethyl aniline
594 Total
Mass in qty Mol. wt
Kg Kg/Kmol
486.5 245.730
1558.8 92.140
194.9 98.426
72.3 36.5
60.9 153.33
143.6 121.19
2516.9 747
A Charge HCl into reactor containing water and solid 4-ABS
Mw Vi
Kg/Kgmol m3
1 water 18 1
2 4-ABS 178 0.463
Total
Mw
Kg/Kgmol
1 Water 18 0.952
2 HCl 36.5 1.000
3 Nitrogen 28
Total
Summary
Water emission rate ER, ni =
HCl Emission rate ER, ni =
Nitrogen Emission rate ER, N2 =
1 NaHCO3 CO2 84
2 NaHSO3 SO2 104
Mw Vi
Kg/Kgmol m3
1 water 18 1
Total
Mw
Kg/Kgmol
1 Water 18 0.952
2 HCl 36.5 1.000
3 Nitrogen 28
Total
Summary
Water emission rate ER, ni =
HCl Emission rate ER, ni =
Nitrogen Emission rate ER, N2 =
D Methanol Wash
Mw Vi
m3
1 Methanol 32 0.5
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitroge pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emissio Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Methanol Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Mw Vi
Kg/Kgmol m3
1 water 18 1.8
Total
Mw
Kg/Kgmol
1 Water 18 1.000
2 HCl 36.5 1.000
3 Nitrogen 28
Total
Summary
Water emission rate ER, ni =
HCl Emission rate ER, ni =
Nitrogen Emission rate ER, N2 =
F Methanol Wash
Mw Vi
m3
1 Methanol 32 0.5
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitroge pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emissio Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Methanol Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
G Drying
Methanol d 91.3 kg
Mw Vi
m3
1 Methanol 32 0.1155696203
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitroge pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emissio Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Methanol Emission Rate ER, ni =
Nitrogen Emission rate ER, N2 =
Mw
Vi
Kg/Kgmol m3
1 Water 18 5
2 HCl 36.5 2.5
Total
4 Nitrogen (Residual) 28
= 0.0388853873
= 0.0492520881
= 0.0851898831
1 Water 18 231.17
2 HCl 36.5 122.96
Total 396.50
Summary
Water ER, ni =
HCl ER, ni =
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 1000 0.67 55.556 0.952
1080 500 0.33 2.809 0.048
1500 58.365
Pi pi
(mm Hg) (mm Hg) °C
T
0.84 0.8 31.7 25.24 30
1.00 1.0 21 21.00 30
713.76 30
760
0.01 Kg/hr
0.02 Kg/hr
0.40 Kg/hr
Number of
Molecular
Weight Charged moles of gas Emission Time
weight of gas
generated
488.000 5.81 44.0 255.6190476 8
906.000 8.71 64.0 557.5384615 8
mass
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 1000 0.67 55.556 0.952
1000 55.556
Pi pi
(mm Hg) (mm Hg) °C
T
0.61 0.6 31.7 18.54 30
1.00 1.0 21 21.00 30
720.46 30
760
0.0055928413 Kg/hr
0.0128435096 Kg/hr
0.34 Kg/hr
Capacity
8 KL
ρ Wi Xi
Kg/m3 Kg
790 395 1.00 12.344 1.000
395 12.344
0.10 Kg/hr
1.12 Kg/hr
mass
Weight qty Weight Mole
Density Moles
Charged Fraction Fraction
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 1800 1.00 100.000 1.000
1800 100.000
Pi pi
(mm Hg) (mm Hg) °C
T
0.82 0.8 31.7 25.90 30
1.00 1.0 21 21.00 30
713.10 30
760
0.0156211497 Kg/hr
0.0256870193 Kg/hr
0.67 Kg/hr
Weight qty Weight Mole
Density Moles
Charged Fraction Fraction
ρ Wi Xi
Kg/m3 Kg
790 395 1.00 12.344 1.000
395 12.344
0.10 Kg/hr
1.12 Kg/hr
ρ Wi Xi
Kg/m3 Kg
790 91 1.00 2.853 1.000
91 2.853
0.02 Kg/hr
0.26 Kg/hr
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 5000 0.63 277.778 0.773
1190 2975 0.37 81.507 0.227
7975 359.285
2 m3
30
92
6 hrs
Average
Average Average
Fraction to Total Emission
Emission Emission
rate
(Kg moles) (Kg) (Kg/hr)
1.000 0.15
0.1 Kg/hr
0.2 Kg/hr
0.45 Kg/hr
R = 62.3636 m3. mm Hg/ (K. Kmol)
Compon Volume
Dilution factor for the
S.No ent Mol. Weight qty
initial vessel contents
Name charged
Mw Vi
Kg/Kgmol m3
0.84 1 HCl 36.5 0.75
0.84
Total
Average
Average Air
Average Emission Emissio Flow Flow
Emission velocity
n rate
(m3/hr) (CFM)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0010 0.02 0.01
0.0008 0.03 0.02
0.0283 0.79 0.40
Emission per hour
31.9523809524
69.6923076923
Compon Volume
Dilution factor for the
S.No ent Mol. Weight qty
initial vessel contents
Name charged
Mw Vi
Kg/Kgmol m3
0.61 1 HCl 36.5 2.533
Total
Average
Average Air
Average Emission Emissio Flow Flow
Emission velocity
n rate
(m3/hr) (CFM)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0025 0.04 0.01
0.0028 0.10 0.01
0.0966 2.70 0.34
R = 62.3636 m3. mm Hg/ (K. Kmol)
Antonie co efficients
Compon Volume
Dilution factor for the
S.No ent Mol. Weight qty
initial vessel contents
Name charged
Mw Vi
Kg/Kgmol m3
0.82 1 HCl 36.5 1.483
Total
Average
Average Air
Average Emission Emissio Flow Flow
Emission velocity
n rate
(m3/hr) (CFM)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0035 0.06 0.02
0.0028 0.10 0.03
0.0956 2.68 0.67
Antonie co efficients
Vapor Partial
Vapor Pressure Partial Pressure Pressur Pressur
e e
Pi @ pi @
Pi @ 30°C pi @ 30°C
80°C 80°C
(mm Hg) (mm Hg)
(mm Hg) (mm Hg)
29.50 560.56
730.50 199.44
760
the inlet stream is in direct contact with the vessel hea
it enters the vessel.Therefore, the equilibrium vapor co
for the inlet stream will be based on the exact compos
inlet stream. A dilution factor ϕ for the inlet stream will
assumed to be 1.0
ρ Wi t Xi
Kg/m3 Kg hr Kg moles
1180 885 1.00 2.00 24.247 1.000 1.00
885 24.247
Weight Dilution factor
Weight Mole
Density qty Time Moles for the inlet
Fraction Fraction
Charged stream
ρ Wi t Xi
Kg/m3 Kg hr Kg moles
1180 2989 1.00 8.00 81.889 1.000 1.00
2989 81.889
Air
Flow Flow
velocity
(m3/hr) (CFM)
Weight Dilution factor
Weight Mole
Density qty Time Moles for the inlet
Fraction Fraction
Charged stream
ρ Wi t Xi
Kg/m3 Kg hr Kg moles
1180 1750 1.00 4.00 47.944 1.000 1.00
1750 47.944
Air
Flow Flow
velocity
(m3/hr) (CFM)
Air
Flow Flow
velocity
(m3/hr) (CFM)
contact with the vessel headspace as
ore, the equilibrium vapor composition
based on the exact composition ,of the
or ϕ for the inlet stream will be
A) Charging of IPA
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 IPA 60 0.76
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
IPA ER, ni =
Nitrogen Emission rate ER, N2 =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
Kg/Kgmol m3
1 IPA 60 0.76
2 MAP 134 0.597
Total
Mw
Kg/Kgmol
1 IPA 60 0.690
2 ETA 142 1.000
3 Nitrogen 28
Total
Summary
IPA Emission ER, ni =
ETA Emissiom ER, ni =
Nitrogen Emission rate ER, N2 =
C) Heating to 45 °C
Volume qty
Mol. Weight
charged
S.No Component Name
Mw
Vi
Kg/Kgmol m3
1 IPA 60 0.76
2 ETA 142 0.637
Total
4 Nitrogen (Residual) 28
= 0.2555154397
= 0.0093887963
= 0.1159042075
= 0.0547058556
1 IPA 60 116.44
2 ETA 142 81.41
Total 197.86
Summary
IPA Emission ER, ni =
ETA Emission ER, ni =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 IPA 60 0.76
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
IPA ER, ni =
Nitrogen Emission rate ER, N2 =
Mw Vi
m3
1 IPA 60 0.6
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
IPA ER, ni =
Nitrogen Emission rate ER, N2 =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
Kg/Kgmol m3
1 IPA 60 0.6
2 Water 18 3.6
Total
Mw
Kg/Kgmol
1 IPA 60 0.545
2 Water 18 0.962
3 IPA 60 1.000
3 Nitrogen 28
Total
Summary
IPA Emission ER, ni =
Water emission ER, ni =
IPA Emission ER, ni =
Nitrogen Emission rate ER, N2 =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 IPA 60 1.5
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
IPA ER, ni =
Nitrogen Emission rate ER, N2 =
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 IPA 60 0.9
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
IPA ER, ni =
Nitrogen Emission rate ER, N2 =
H Drying
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 IPA 60 0.391
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
IPA ER, ni =
Nitrogen Emission rate ER, N2 =
Weight qty
Density Weight Fraction Moles Mole Fraction Time
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 597 1.00 9.956 1.000 0.3
597 9.956
0.49 Kg/hr
2.62 Kg/hr
Dilution factor
Weight qty for the initial
Density Weight Fraction Moles Mole Fraction
Charged vessel
contents
ρ Wi Xi
Kg/m3 Kg Kg moles
786 597 0.50 9.956 0.690 0.85
1005 600 0.50 4.478 0.310 0.85
1197 14.434
Ẋi Partial Average
ϕA, ϕB Vapor Pressure System Temp.
Pressure Emission
Pi pi
(mm Hg) (mm Hg) °C (Kg moles)
T piV/RT
0.85 0.6 61.0 35.79 30 0.0012
1.00 1.0 212 212.00 30 0.0071
512.21 30 0.0173
760
0.07 Kg/hr
1.01 Kg/hr
0.48 Kg/hr
Pi @ 30°C
(mm Hg)
ρ Wi Xi
Kg/m3 Kg Kg moles
786 597 0.44 9.956 0.651 8.0
1192 759 0.56 5.347 0.349 60.000600006
1357 15.303
6.22 m3
5
45
3 hrs
Average
Fraction to Average Average
Emission
Total Emission Emission
rate
(Kg moles) (Kg) (Kg/hr)
1.000 0.05
0.6 Kg/hr
1.1 Kg/hr
1.50 Kg/hr
Weight qty
Density Weight Fraction Moles Mole Fraction Time
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 597 1.00 9.956 1.000 0.3
597 9.956
0.49 Kg/hr
2.62 Kg/hr
Weight qty
Density Weight Fraction Moles Mole Fraction Time
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 472 1.00 7.860 1.000 0.3
472 7.860
0.39 Kg/hr
2.07 Kg/hr
Dilution factor
Weight qty for the initial
Density Weight Fraction Moles Mole Fraction
Charged vessel
contents
ρ Wi Xi
Kg/m3 Kg Kg moles
786 472 0.39 7.860 0.545 0.97
1000 3600 0.88 200.000 0.962 0.97
4072 207.860
Ẋi Partial Average
ϕA, ϕB Vapor Pressure System Temp.
Pressure Emission
Pi pi
(mm Hg) (mm Hg) °C (Kg moles)
T piV/RT
0.97 0.5 61.0 32.31 30 0.0011
0.97 0.9 32 29.86 30 0.0010
1.00 1.0 61 61.00 30 0.0021
636.83 30 0.0215
760
0.07 Kg/hr
0.02 Kg/hr
0.12 Kg/hr
0.60 Kg/hr
Weight qty
Density Weight Fraction Moles Mole Fraction Time
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 1179 1.00 19.650 1.000 0.3
1179 19.650
0.97 Kg/hr
5.18 Kg/hr
Weight qty
Density Weight Fraction Moles Mole Fraction Time
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 707 1.00 11.790 1.000 0.3
707 11.790
0.58 Kg/hr
3.11 Kg/hr
Weight qty
Density Weight Fraction Moles Mole Fraction Time
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 307 1.00 5.122 1.000 0.3
307 5.122
0.25 Kg/hr
1.35 Kg/hr
62.3636
Antonie co efficients
Vapor
Partial Average Average Average
Pressur System Temp.
Pressure Emission Emission Emission rate
e
mm Hg °C mm Hg (Kg moles) (Kg) (Kg/hr)
Pi T pi piV/RT ER, ni
61.0 30 61.0109060906 0.0025 0.15 0.49
Mw Vi
Kg/Kgmol m3
1 ETA 142 0.637
Total
Average
Average
Emissio Air velocity Flow Flow
Emission rate
n
(m3/hr) (CFM)
(Kg) (Kg/hr)
ER, ni
0.07 0.07
1.01 1.01
0.48 0.48
Partial
Partial
Pressur Vapor Pressure
Pressure
e
pi @
Pi @ 105°C pi @ 105°C
30°C
(mm Hg) (mm Hg)
(mm Hg)
733.83 390.46
62.3636
Antonie co efficients
Vapor
Partial Average Average Average
Pressur System Temp.
Pressure Emission Emission Emission rate
e
mm Hg °C mm Hg (Kg moles) (Kg) (Kg/hr)
Pi T pi piV/RT ER, ni
61.0 30 61.0109060906 0.0025 0.15 0.49
62.3636
Antonie co efficients
Vapor
Partial Average Average Average
Pressur System Temp.
Pressure Emission Emission Emission rate
e
mm Hg °C mm Hg (Kg moles) (Kg) (Kg/hr)
Pi T pi piV/RT ER, ni
61.0 30 61.0109060906 0.0019 0.12 0.39
Mw Vi
Kg/Kgmol m3
1 IPA 60 0.9
Total
Average
Average
Emissio Air velocity Flow Flow
Emission rate
n
(m3/hr) (CFM)
(Kg) (Kg/hr)
ER, ni
0.07 0.07
0.02 0.02
0.12 0.12
0.60 0.60
62.3636
Antonie co efficients
Vapor
Partial Average Average Average
Pressur System Temp.
Pressure Emission Emission Emission rate
e
mm Hg °C mm Hg (Kg moles) (Kg) (Kg/hr)
Pi T pi piV/RT ER, ni
61.0 30 61.0109060906 0.0048 0.29 0.97
62.3636
Antonie co efficients
Vapor
Partial Average Average Average
Pressur System Temp.
Pressure Emission Emission Emission rate
e
mm Hg °C mm Hg (Kg moles) (Kg) (Kg/hr)
Pi T pi piV/RT ER, ni
61.0 30 61.0109060906 0.0029 0.17 0.58
62.3636
Antonie co efficients
Vapor
Partial Average Average Average
Pressur System Temp.
Pressure Emission Emission Emission rate
e
mm Hg °C mm Hg (Kg moles) (Kg) (Kg/hr)
Pi T pi piV/RT ER, ni
61.0 30 61.0109060906 0.0013 0.08 0.25
Air velocity Flow Flow
(m3/hr) (CFM)
Dilution
factor
Weight qty Weight Mole
Density Time Moles for the
Charged Fraction Fraction
inlet
stream
ρ Wi t Xi
Kg/m3 Kg hr Kg moles
1192 759 1.00 1.00 5.347 1.000 1.00
759 5.347
Air velocity Flow Flow
(m3/hr) (CFM)
Air velocity Flow Flow
(m3/hr) (CFM)
Dilution
factor
Weight qty Weight Mole
Density Time Moles for the
Charged Fraction Fraction
inlet
stream
ρ Wi t Xi
Kg/m3 Kg hr Kg moles
786 707 1.00 1.00 11.790 1.000 1.00
707 11.790
(m3/hr) (CFM)
Air velocity Flow Flow
(m3/hr) (CFM)
Air velocity Flow Flow
(m3/hr) (CFM)
nters the vessel.Therefore, the
composition for the inlet stream will be
t composition ,of the inlet stream. A
r the inlet stream will be assumed to be
nters the vessel.Therefore, the
composition for the inlet stream will be
t composition ,of the inlet stream. A
r the inlet stream will be assumed to be
Sl. No. Equipment Tag No MOC Capacity
1 Reactor R-1638 MSGL 8 KL
Volume qty
S.No Component Name Mol. Weight Density
charged
Mw Vi ρ
m3 Kg/m3
1 IPA 60 2.8 789
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atmos
System Pressure PT = 760
Partial Pressure of Nitrogen pN2 = PT - Pi
Moles of Nitrogen Emission En, N2 = pnV/RT
Weight of Nitrogen Emission Ewt, N2 = En, N2*Mw
Nitrogen Emission rate ER, N2 = Ewt, N2 /t
Summary
IPA Emission Rate ER, ni = 0.60
Nitrogen Emission rate ER, N2 = 2.87
Volume qty
Mol. Weight Density
charged
S.No Component Name
Mw
Vi ρ
Kg/Kgmol m3 Kg/m3
1 IPA 60 2.8 789
Total
4 Nitrogen (Residual) 28
= 0.251434422
= 0.0249743813
= 0.0524919362
= 0.004195114
Fraction to
Component Name Mol. Weight Avg pi Total
S.No
Mw
Kg/Kgmol (mm Hg)
1 IPA 60 109.00 1.000
Summary
Toluene Emission Rate ER, ni = 0.1
Volume qty
S.No Component Name Mol. Weight Density
charged
Mw Vi ρ
Kg/Kgmol m3 Kg/m3
1 IPA 60 2.8 789
2 CXB-1 230 0.76 921
3 Water 18 1.4 1000
Total
Mw
Kg/Kgmol
1 IPA 60 0.313 0.98
2 HCl 36.5 1.000 1.00
3 Water 18 0.661 0.98
3 Nitrogen 28
Total
Summary
IPA Emission Rate ER, ni = 0.02
HCl Emission Rate ER, ni = 0.01
Nitrogen Emission rate ER, N2 = 0.13
Volume qty
Mol. Weight Density
charged
S.No Component Name
Mw
Vi ρ
Kg/Kgmol m3 Kg/m3
1 IPA 60 2.8 789
Total
4 Nitrogen (Residual) 28
= 0.1154030236
= 0.0238028996
= 0.0800434058
= 0.0679240162
Fraction to
Component Name Mol. Weight Avg pi Total
S.No
Mw
Kg/Kgmol (mm Hg)
Summary
IPA Emission Rate ER, ni = 1.4
Volume qty
S.No Component Name Mol. Weight Density
charged
Mw Vi ρ
m3 Kg/m3
1 IPA 60 5.4 789
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atmos
System Pressure PT = 760
Partial Pressure of Nitrogen pN2 = PT - Pi
Moles of Nitrogen Emission En, N2 = pnV/RT
Weight of Nitrogen Emission Ewt, N2 = En, N2*Mw
Nitrogen Emission rate ER, N2 = Ewt, N2 /t
Summary
Toluene Emission Rate ER, ni = 0.78
Nitrogen Emission rate ER, N2 = 3.69
Volume qty
S.No Component Name Mol. Weight Density
charged
Mw Vi ρ
m3 Kg/m3
1 IPA 60 0.7 789
2 Water 18 0.7 1000
Total 1.4
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atmos
System Pressure PT = 760
Partial Pressure of Nitrogen pN2 = PT - Pi
Moles of Nitrogen Emission En, N2 = pnV/RT
Weight of Nitrogen Emission Ewt, N2 = En, N2*Mw
Nitrogen Emission rate ER, N2 = Ewt, N2 /t
Summary
IPA ER, ni = 0.04
Nitrogen Emission rate ER, N2 = 1.00
Water Emission rate ER, H2O = 0.02
R
Antonie co efficients
Wi Xi t mm Hg
Kg hr Pi
2209 1.00 36.820 1.000 1 68.0
2209 36.820
Kg/hr
Kg/hr
Mole Partial
Weight qty Charged Moles Vapor Pressure
Fraction Pressure
pi @
Pi @ 30°C
30°C
(mm Hg)
(mm Hg)
Wi Xi
Kg Kg moles
2209 36.820 1.000 68.0 68.00
692.00
m3
hrs
Average Average
Average Emission
Emission Emission rate
0.00
Kg/hr
Kg/hr
Dilution factor
Weight Mole
Weight qty Charged Moles for the initial
Fraction Fraction
vessel contents
Wi Xi
Kg Kg moles
2209 0.51 36.820 0.313 0.98
700 0.16 3.043 0.026 0.98
1400 0.32 77.778 0.661 0.98
4309 117.641
Average
Ẋi Vapor Partial System Average
Emissio
Pressure Pressure Temp. Emission
n
Pi pi
(mm Hg) (mm Hg) °C (Kg moles) (Kg)
T piV/RT
0.3 150.0 46.07 45 0.0003 0.02
1.0 53 53.00 45 0.0004 0.01
0.6 31 20.09 45 0.0001 0.00
660.93 45 0.0046 0.13
760
Kg/hr
Kg/hr
Kg/hr
pi @
Pi @ 45°C
45°C
(mm Hg)
(mm Hg)
Wi Xi
Kg Kg moles
2209 1.00 36.820 1.000 150.0 150.00
610.00
m3
hrs
Average Average
Average Emission
Emission Emission rate
0.07
Kg/hr
Kg/hr
Antonie co efficients
Wi Xi t mm Hg
Kg hr Pi
4261 1.00 71.010 1.000 1.5 68.0
4261 71.010
Kg/hr
Kg/hr
Antonie co efficients
Wi Xi t mm Hg
Kg hr Pi
552 0.44 9.205 0.191 1.5 68.0
700 0.56 38.889 0.809 1.5 31.0
1252 48.094
sel is vented to atmosphere
mm Hg
= 721.918331042 mm Hg
= 0.05 Kg moles
= 1.50 Kg
= 1.00 Kg/hr
Kg/hr
Kg/hr
Kg/hr
= 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
Vapor Partial
Pressure Pressure
Pi @ 45°C pi @ 45°C
(mm Hg) (mm Hg)
150.0 150.00
150.00
610.00
Inlet Stream Analysis:
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
1 HCl 36.5 0.139 1180 164 1.00 1.00 4.494
(m3/hr) (CFM)
(Kg/hr)
ER, ni
0.02
0.01
0.00
0.13
Vapor Partial
Pressure Pressure
Pi @ 75°C pi @ 75°C
(mm Hg) (mm Hg)
552.0 552.00
552.00
208.00
Antonie co efficients
Antonie co efficients
Dilution
factor
Mole
for the
Fraction
inlet
stream
Kg moles
1.000 1.00
pH adjustment
B Evolution of CO2
1 NaHCO3
R-1677
D Charge HCl into reactor containing water and r
S.No
S.No
1
2
3
Summary
CO2 may also be released
B) Charge Methanol
1 methanol
Total
Summary
Toluene Emission Rate
Nitrogen Emission rate
Mw
Kg/Kgmol
1 Methanol 32
Total
4 Nitrogen (Residual) 28
1 Methanol 32
Total
Summary
Methanol ER, ni
B Evolution of CO2
1 NaHCO3 CO2 84
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 Methanol 32
Total
4 Nitrogen (Residual) 28
1 Methanol 32
Total
Summary
Toluene Emission Rate ER, ni
B) Charge Methanol
Mw
1 Toluene 92
Total
The empty vessel was previously made inert with nitrogen, and the vessel
System Pressure PT
Partial Pressure of Nitrog pN2
Moles of Nitrogen Emissio En, N2
Weight of Nitrogen Emissi Ewt, N2
Nitrogen Emission rate ER, N2
Summary
Toluene Emission Rate ER, ni
Nitrogen Emission rate ER, N2
ontents Analysis
Volume qty
Component Name Mol. Weight Density
charged
Mw Vi ρ
Kg/Kgmol m3 Kg/m3
water 18 5.2 1000
Total
Mw
Kg/Kgmol
Water 18 0.056 0.97
HCl 36.5 1.000 1.00
Nitrogen 28
Total
2534
sel was previously made inert with nitrogen, and the vessel is vented to atmosphere
PT = 760 mm Hg
pN2 = PT - Pi =
En, N2 = pnV/RT =
Ewt, N2 = En, N2*Mw =
ER, N2 = Ewt, N2 /t =
System Pressure PT
Weight qty
Volume qty charged Density Weight Fraction
Charged
Vi ρ Wi
m3 Kg/m3 Kg
3.2 792 2534 1.00
2534
= 5.6 m3
= 30
= 58
= 4 hrs
0.2157168911
0.0619420505
0.1584407078
0.1496884204
Avg pi Average
Fraction to Total Average Emission
Emission
(Kg moles) (Kg)
(mm Hg)
En-i, *Mw
396.50 1.000 0.15 4.8
396.50 1.000 0.15
= 1.2 Kg/hr
= 0.25 Kg/hr
System Pressure PT
Weight qty
Volume qty charged Density Weight Fraction
Charged
Vi ρ Wi
m3 Kg/m3 Kg
4.1 792 3247 1.28
3247
= 5.6 m3
= 30
= 58
= 4 hrs
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Avg pi Average
Fraction to Total Average Emission
Emission
(Kg moles) (Kg)
(mm Hg)
En-i, *Mw
508.02 1.281 0.19 6.1
= 1.5 Kg/hr
= #DIV/0! Kg/hr
Vapour Pressure
Operating pressure Time Partial pressure
of methanol at 10
Por P Pi
mm Hg Kg mm hg
100 97 16.00 3.000
Weight qty
Volume qty charged Density Weight Fraction
Charged
Vi ρ Wi
m3 Kg/m3 Kg
2.1 886 1861 1.00
1861
= 0.12 Kg/hr
= 0.74 Kg/hr
Vapour Pressure
Operating pressure Time Partial pressure
of Toluene at 20
Por P Pi
mm Hg Kg mm hg
50 22 16.00 28.000
Molecular weight of
Emission Time Emission per hour
gas
Weight
Weight qty Charged Moles Mole Fraction
Fraction
Wi Xi
Kg Kg moles
5200 1.00 288.889 0.056
5200 288.889
Ẋi Vapor Partial
System Temp.
Pressure Pressure
Pi pi
(mm Hg) (mm Hg) °C
T
0.1 31.7 1.71 30
1.0 21 21.00 30
737.29 30
760
Kg/hr
Kg/hr
Kg/hr
Mole
Weight Fraction Moles Time
Fraction
Xi t
hr
1.00 79.200 1.000 1
79.200
551 mm Hg
0.09 Kg moles
2.57 Kg
2.57 Kg/hr
= 760 mm Hg
Vapor
Moles Mole Fraction Partial Pressure
Pressure
Pi @ 30°C pi @ 30°C
Xi (mm Hg) (mm Hg)
Kg moles
79.200 1.000 209.0 209.00
79.200 209.00
551.00
Average Emission
rate
(Kg/hr)
En-i, *Mw/t
1.2
Time Emission per hour
2 139.595238095
= 760 mm Hg
Vapor
Moles Mole Fraction Partial Pressure
Pressure
Pi @ 30°C pi @ 30°C
Xi (mm Hg) (mm Hg)
Kg moles
101.475 1.281 209.0 267.78
101.475 267.78
492.22
Average Emission
rate
(Kg/hr)
En-i, *Mw/t
1.5
Displacement Vleakage Leakage Totol
m3
Antonie co efficients
Xi t mm Hg
hr Pi
20.224 1.000 3 37.0
20.224
mm Hg
Kg moles
Kg
Kg/hr
Displacement Vleakage Leakage Totol
m3
0.97 1
Average Average
Average Emission Air velocity
Emission Emission rate
Antonie co efficients
Average
Vapor Pressure System Temp. Partial Pressure
Emission
mm Hg °C mm Hg (Kg moles)
Pi T pi piV/RT
209.0 35 209 0.0348
Vapor Pressure Partial Pressure
Pi @ 58°C pi @ 58°C
(mm Hg) (mm Hg)
584.0 584.00
584.00
176.00
Vapor Pressure Partial Pressure
Pi @ 58°C pi @ 58°C
(mm Hg) (mm Hg)
584.0 748.25
748.25
11.75
Total emission
En
Kg
24.17
Average Average
System Temp. Partial Pressure
Emission Emission
En
Kg
0.38
Volume Weight
Component Weight
Mol. Weight qty Density qty Time Moles
Name Fraction
charged Charged
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
HCl 36.5 0.5 1180 590 1.00 1.00 16.164
Flow Flow
(m3/hr) (CFM)
m3. mm Hg/ (K. Kmol)
1.000 1.00
Sl. No. Equipment Tag No
1 Reactor R-1638
0.555
Vacuum transfer/ Lutz pump transfer
From drum
Mw
1 Bup-1 247
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to
System Pressure PT
Partial Pressure of Nitrogen pN2
Moles of Nitrogen Emission En, N2
Weight of Nitrogen Emission Ewt, N2
Nitrogen Emission rate ER, N2
Summary
Bup-1 Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 Bup-1 247
2 Chloroform 119.38
Total
4 Nitrogen (Residual) 28
1 BUP-1 247
2 Chloroform 73.2
Total
Summary
BUP-1 Emission Rate ER, ni
Chloroform Emission Rate ER, ni
Nitrogen Emission rate ER, N2
C) Charge TBA into the reactor containing BUP-1 and Chloroform at temperature 15-25°C fr
Mw
Kg/Kgmol
1 Bup-1 247
Total
Mw
Kg/Kgmol
1 Bup-1 247
2 TBA 73.2
3 Nitrogen 28
Total
Summary
TBA Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 BUP-1 247
2 TBA 73.2
Total
4 Nitrogen (Residual) 28
=
Component Name Mol. Weight
S.No
Mw
Kg/Kgmol
1 BUP-1 247
2 TBA 73.2
Total
Summary
BUP-1 Emission Rate ER, ni
TBA Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Mw
1 Bup-1 247
2 TBA 73.2
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to
System Pressure PT
Partial Pressure of Nitrogen pN2
Moles of Nitrogen Emission En, N2
Weight of Nitrogen Emission Ewt, N2
Nitrogen Emission rate ER, N2
Summary
TBA Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 TBA 73.2
Total
4 Nitrogen (Residual) 28
G) Charge Toluene into the reactor containing reaction mass(TBA) and purified water at 25
Mw
Kg/Kgmol
1 TBA 73.2
2 Purified water 18
Total
Mw
Kg/Kgmol
1 TBA 73.2
2 Purified water 18
3 Toluene 92.1
4 Nitrogen 28
Total
Summary
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 TBA +Toluene 82.65
Total
4 Nitrogen (Residual) 28
Filled volume
Volume of Head Space Available in Reactor
Initial Temperature (T1)
Final Temperature (T2)
time for Heating (t)
Calculate the average gas space molar volume
1 TBA+Toluene 82.65
Total
Summary
TBA + Toluene Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Mw
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to
System Pressure PT
Partial Pressure of Nitrogen pN2
Moles of Nitrogen Emission En, N2
Weight of Nitrogen Emission Ewt, N2
Nitrogen Emission rate ER, N2
Summary
Toluene Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Mw
Kg/Kgmol
1 Aq. Layer (Water) 18
Total
Calculation of the average batch and vapor-phase compositions
Mw
Kg/Kgmol
1 Aq. Layer (Water) 18
2 Toluene 92.1
3 Nitrogen 28
Total
Summary
Water Emission Rate ER, ni
Toluene Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 Organic layer(Toluene) 92.1
2 Purified water 18
Total
4 Nitrogen (Residual) 28
1 Toluene 92.1
2 Purified water 18
Total
Summary
Toluene Emission Rate ER, ni
Purified water Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Mw
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to
System Pressure PT
Partial Pressure of Nitrogen pN2
Moles of Nitrogen Emission En, N2
Weight of Nitrogen Emission Ewt, N2
Nitrogen Emission rate ER, N2
Summary
Toluene Emission Rate ER, ni
Nitrogen Emission rate ER, N2
M) Heat the reaction mass(toluene) to 40 -45°C
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 Organic layer(Toluene) 92.1
Total
4 Nitrogen (Residual) 28
1 Toluene 92.1
Total
Summary
Toluene Emission Rate ER, ni
Nitrogen Emission rate ER, N2
N) Charge HCl into the reactor containing Organic layer(Toluene) at temperature 40-45°C .
Vessel capacity 2
Mw
Kg/Kgmol
1 Organic layer(Toluene) 92.1
Total
Mw
Kg/Kgmol
1 Organic Layer (Toluene) 92.1
2 HCl 36.5
3 Nitrogen 28
Total
Summary
Toluene Emission Rate ER, ni
HCl Emission Rate ER, ni
Nitrogen Emission rate ER, N2
O) Charge HCl into the reactor containing Organic layer(Toluene) at temperature 40-45°C .
Vessel capacity 2
Mw
Kg/Kgmol
1 Organic layer(Toluene) 92.1
Total
Mw
Kg/Kgmol
1 Organic Layer (Toluene) 92.1
2 HCl 36.5
3 Nitrogen 28
Total
Summary
Toluene Emission Rate ER, ni
HCl Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Pump transfer
Mw
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to
System Pressure PT
Partial Pressure of Nitrogen pN2
Moles of Nitrogen Emission En, N2
Weight of Nitrogen Emission Ewt, N2
Nitrogen Emission rate ER, N2
Summary
HCl Emission Rate ER, ni
Nitrogen Emission rate ER, N2
Pump transfer
Mw
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to
System Pressure PT
Partial Pressure of Nitrogen pN2
Moles of Nitrogen Emission En, N2
Weight of Nitrogen Emission Ewt, N2
Nitrogen Emission rate ER, N2
Pump transfer
Mw
1 Acetone 58
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to
System Pressure PT
Partial Pressure of Nitrogen pN2
Moles of Nitrogen Emission En, N2
Weight of Nitrogen Emission Ewt, N2
Nitrogen Emission rate ER, N2
m3/hr
1300 5.263
= 0.00 Kg/hr
= 0.63 Kg/hr
Vi ρ Wi
m3 Kg/m3 Kg Kg moles Xi
0.833 1560 1300 0.98 5.263 0.965
0.015 1490 22.5 0.02 0.188 0.035
= 7.652 m3
= 30
= 85
= 2.5 hrs
0.284
0.003
0.018
0.032
Average
Average
Avg pi Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
(mm Hg)
En-i, *Mw En-i, *Mw/t
0.00 0.000 0.000 0.0 0.0
31.11 1.000 0.032 2.3 0.94
m3/hr
kL
Vi ρ Wi Xi
Kg moles
m3 Kg/m3 Kg
0.833 1560 1300 1.00 5.263 1.000
1300 5.263
Pi pi
(mm Hg) (mm Hg) °C
T
1.000 0.35 0.4 0.00 25
1.000 1.00 1.0 369 369.00 25
391.00 25
760
= 4.19 Kg/hr
= 1.70 Kg/hr
Vi ρ Wi
m3 Kg/m3 Kg Kg moles Xi
0.833 1560 1300 0.39 5.263 0.161
2.882 696 2006 0.61 27.403 0.839
= 4.79 m3
= 25
= 32
= 2.5 hrs
0.193
0.080
0.102
0.024
Average
Average
Avg pi Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
(mm Hg)
En-i, *Mw En-i, *Mw/t
0.00 0.000 0.000 0.0 0.0
358.20 1.000 0.024 1.8 0.7
b
358.20 1.000 0.024
= 0.0 Kg/hr
= 0.7 Kg/hr
= 0.05 Kg/hr
Kg/hr
Vi ρ Wi Xi
m3 Kg/m3 Kg Kg moles
1.25 0.7 3306 1.00 45.164 1.000
= 7.377 m3
= 30
= 105
= 8 hrs
m3/hr
kL
Vi ρ Wi Xi
m3 Kg/m3 Kg Kg moles
1.6 696 1300 0.43 17.76 0.158
1.17 1000 1700 0.57 94.44 0.842
3000 112.204
Pi pi
(mm Hg) (mm Hg) °C
T
0.158 0.93 0.15 369 54.55 25
0.842 0.93 0.79 23.69 18.62 25
1.000 1.00 1.00 28.49 28.49 25
686.83 25
760
= 0.69 Kg/hr
= 0.03 Kg/hr
= 0.49 Kg/hr
= 3.57 Kg/hr
Vi ρ Wi Xi
m3 Kg/m3 Kg Kg moles
0.528 0.8 2500 1.00 30.248 1.000
2500 30.248
= 5.368 m3
= 4.632 m3
= 30
= 55
= 2 hrs
0.179
0.060
0.135
0.132
Average
Average
Avg pi Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
(mm Hg)
En-i, *Mw En-i, *Mw/t
420.30 1.000 0.132 10.9 5.5
= 5.5 Kg/hr
= 0.21 Kg/hr
°C to another Reactor(Reactor-4)
Kg/hr
Volume qty Weight qty Weight Mole
Density Moles
charged Charged Fraction Fraction
Vi ρ Wi Xi
m3 Kg/m3 Kg
3.7 960 3543 1.00 38.469 1.000
3.7
3543 38.469
= 0.52 Kg/hr
= 4.08 Kg/hr
at temperature 50-55°C .
m3/hr
kL
Vi ρ Wi
m3 Kg/m3 Kg Kg moles Xi
1.14 1000 1140 1.00 63.333 1.000
1140 63.333
Vapor Partial
Ẋi System
Xi ϕA, ϕB Pressure Pressure @
Temp.
@ 55°C 55°C
Pi pi
(mm Hg) (mm Hg) °C
T
1.000 0.92 0.9 117.78 108.60 55
1.000 1.00 1.0 113.57 113.57 55
537.83 55
760
= 0.224 Kg/hr
= 0.598 Kg/hr
= 0.861 Kg/hr
Vi ρ Wi
m3 Kg/m3 Kg Kg moles Xi
4.83 940 4516 0.76 49.034 0.382
1.43 1000 1430 0.24 79.444 0.618
= 4.24 m3
= 25
= 45
= 1 hrs
0.168
0.006
0.016
0.037
Average
Average
Avg pi Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
(mm Hg)
En-i, *Mw En-i, *Mw/t
19.57 0.399 0.015 1.4 1.4
29.49 0.601 0.022 0.4 0.4
= 1.4 Kg/hr
= 0.4 Kg/hr
= 0.01 Kg/hr
°C to another Reactor(Reactor-5)
Kg/hr
Volume qty Weight qty Weight Mole
Density Moles
charged Charged Fraction Fraction
Vi ρ Wi Xi
m3 Kg/m3 Kg
4.815 930 4502 1.00 48.882 1.000
4.815
4502 48.882
= 0.45 Kg/hr
= 3.54 Kg/hr
Vi ρ Wi
m3 Kg/m3 Kg Kg moles Xi
4.815 930 4502 1.00 48.882 1.000
= 5.69 m3
= 25
= 45
= 1 hrs
0.225
0.009
0.021
0.035
Average
Average
Avg pi Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
(mm Hg)
En-i, *Mw En-i, *Mw/t
51.28 1.000 0.035 3.2 3.2
= 3.2 Kg/hr
= 0.01 Kg/hr
e) at temperature 40-45°C .
m3/hr
kL
Volume qty Weight qty Weight Mole
Density Moles
charged Charged Fraction Fraction
Vi ρ Wi
m3 Kg/m3 Kg Kg moles Xi
4.815 930 4502 1.00 48.882 1.000
4502 48.882
Vapor Partial
Ẋi System
Xi ϕA, ϕB Pressure Pressure @
Temp.
@ 45°C 45°C
Pi pi
(mm Hg) (mm Hg) °C
T
1.000 0.68 0.7 74.12 50.75 45
1.000 1.00 1.0 0.00 45
709.25 45
760
= 0.138 Kg/hr
= 0.000 Kg/hr
= 1.172 Kg/hr
e) at temperature 40-45°C .
m3/hr
kL
Vi ρ Wi
m3 Kg/m3 Kg Kg moles Xi
3,686 890 3271 1.00 35.516 1.000
3271 35.516
Vapor Partial
Ẋi System
Xi ϕA, ϕB Pressure Pressure @
Temp.
@ 45°C 45°C
Pi pi
(mm Hg) (mm Hg) °C
T
1.000 0.81 0.8 74.12 59.96 45
1.000 1.00 1.0 0.00 45
700.04 45
760
= 0.163 Kg/hr
= 0.000 Kg/hr
= 1.156 Kg/hr
another Reactor
Kg/hr
= 0.00 Kg/hr
= 3.94 Kg/hr
entrifuge
Kg/hr
= 0.00 Kg/hr
= 4.22 Kg/hr
Kg/hr
= 0.52 Kg/hr
= 2.48 Kg/hr
R = 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1.5 - 30 0.0 0.000
518
51800
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 85°C Pi @ 85°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
242.5 8.38 1557 53.83
8.38 53.83
751.62 706.17
Inlet Stream Analysis:
0.35 1 TBA
Total
Average
Average Emission Average Emission Air velocity Flow
Emission rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0000 0.00 #DIV/0!
0.0572 4.19 4.19
0.0606 1.70 1.70
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 25°C Pi @ 25°C Pi @ 32°C Pi @ 32°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
309.55 406.86
450.45 353.14
R = 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
0.0 25 0 0.0000
0.5
369 25 309.55 0.048
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 55°C Pi @ 55°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
449.00 1082.00
311.00 -322.00
0.93 1 Toluene
Total
Average
Average Emission Average Emission Air velocity Flow
Emission rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.0047 0.34 0.69
0.0008 0.02 0.03
0.0026 0.24 0.49
0.0638 1.79 3.57
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 55°C Pi @ 55°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
517.18 162.22
R = 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1 28.4 25 28.43 0.0057
0.92 1 Toluene
Total
Average
Average Emission Average Emission Air velocity Flow
Emission rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.006 0.11 0.224
0.006 0.60 0.598
0.0308 0.86 0.861
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 25°C Pi @ 25°C Pi @ 45°C Pi @ 45°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
25.50 72.62
734.50 687.38
R = 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1.5 28.4 25 28.43 0.0074
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 25°C Pi @ 25°C Pi @ 45°C Pi @ 45°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
28.43 74.12
731.57 685.88
Inlet Stream Analysis:
Dilution factor for the Component
S.No
initial vessel contents Name
0.68 1 HCl
Total
Average
Average Emission Average Emission Air velocity Flow
Emission rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.003 0.28 0.138
0.000 0.00 0.000
0.0418 1.17 1.172
Total
Average
Average Emission Average Emission Air velocity Flow
Emission rate
(m3/hr)
(Kg moles) (Kg) (Kg/hr)
piV/RT ER, ni
0.004 0.33 0.163
0.000 0.00 0.000
0.0413 1.16 1.156
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1 25 0 0.0000
R = 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
1 5 0 0.0000
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
0.25 70.1 5 70.14 0.0023
m Hg/ (K. Kmol)
Average Average
Air velocity Flow Flow
Emission Emission rate
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.000 0.0000
Volume qty Weight qty Weight
Mol. Weight Density Time Moles
charged Charged Fraction
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
73.2 2.882 696 2006 1.00 1.00 27.404
2006 27.404
Flow
(CFM)
m Hg/ (K. Kmol)
Average Average
Air velocity Flow Flow
Emission Emission rate
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.00 0.00
3.51 7.03
Volume qty Weight qty Weight
Mol. Weight Density Time Moles
charged Charged Fraction
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
92.1 1.727 866 1496 1.00 0.50 16.239
1496 16.239
Flow
(CFM)
m Hg/ (K. Kmol)
Average Average
Air velocity Flow Flow
Emission Emission rate
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.52 0.52
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
92.1 1.17 866 1013 1.00 0.500 10.999
1013 10.999
Flow
(CFM)
m Hg/ (K. Kmol)
Average Average
Air velocity Flow Flow
Emission Emission rate
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.68 0.45
Volume qty Weight qty Weight
Mol. Weight Density Time Moles
charged Charged Fraction
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
36.5 1.709 1.09 1863 1.00 2.000 51.041
1863 51.041
Flow
(CFM)
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles
36.5 0.6 1.09 657 1.00 2.000 18.000
657 18.000
Flow
(CFM)
m Hg/ (K. Kmol)
Average Average
Air velocity Flow Flow
Emission Emission rate
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.00 0.00
m Hg/ (K. Kmol)
Average Average
Air velocity Flow Flow
Emission Emission rate
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.00 0.00
m Hg/ (K. Kmol)
Average Average
Air velocity Flow Flow
Emission Emission rate
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.13 0.52
Mole Dilution factor for the
Fraction inlet stream
1.000 1.00
Mole Dilution factor for the
Fraction inlet stream
1.000 1.00
Mole Dilution factor for the
Fraction inlet stream
1.000 1.00
Mole Dilution factor for the
Fraction inlet stream
1.000 1.00
A
2-propanol 8.88
acetic acid 8.02
acetic acid 8.27
acetone 7.63
acetone 7.12
chloroform 6.95
ethyl acetate 7.10
ethylene glycol 7.25
methanol 8.08
toluene 6.95
water 8.07
Tertiary butyl amine 7.16
Phosphorus oxychloride (POCl3) 4.28
N,N Dimethyl aniline 7.43
From Elliot and Lira, Introductory Chemical Engineering Thermodynam
Diphyl Temp
References
HCL data
https://terpconnect.umd.edu/~nsw/chbe301/chap02.pdf
Yaws handbook
https://books.google.co.in/books?id=MevHBQAAQBAJ&pg=PA61&dq
Calculation of Psat Calculation of Tb
T [ C] =
o
92 Psat [kg/cm2] =
Psat [mmHg] =
d=MevHBQAAQBAJ&pg=PA61&dq=nn+dimethyl+aniline+vapour+pressure+antoine+constants&hl=en&sa=X&ved=0ahUKEwj1s_bg39DfAhXPSH0K
2.2 absolute
1672
Toluene
TemperatureVP
20 22.372368
25 28.998303
30 37.216056
35 47.318081
40 59.633051
45 74.527741
50 92.408742
55 113.72397
60 138.96396
65 168.66294
log10(P) = A - (B / (T + C)) 70 203.39965
80 290.52712
90 405.88297
100 555.72838
108 705.09798
110.6 759.99386
UKEwj1s_bg39DfAhXPSH0KHSEMCFQQ6AEIKjAA#v=onepage&q=7647-01-0&f=false
TemperatureVP TEMPERATUVP TEMPERATUVP
20 33173.222 20 38.22282 20 22.372368 20
25 37045.333 25 51.414714 25 28.998303 25
30 41212.186 30 68.335704 30 37.216056 30
35 45682.326 35 89.807533 35 47.318081 35
40 50463.766 40 116.77986 40 59.633051 40
45 55563.981 45 150.34076 45 74.527741 45
50 60989.9 50 191.72684 50 92.408742 50
55 242.33291 55 113.72397 55
60 303.72099 60 138.96396 60
65 377.62864 65 168.66294 61
70 465.97642 70 203.39965 5
80 694.62861 80 290.52712
82.349592 759.99996 90 405.88297
100 555.72838
108 705.09798
110.6 759.99386
132.93757 17723.742
168.70745 22492.719
212.42572 28321.404
265.48036 35394.85
329.43195 43921.119
406.02505 54132.803
497.1993 66288.499
605.10001 80674.233
732.08837 97604.803
760.00011 101326.1
61.782423 8237.06743