Real Gases/ Real Solutions

Real Gas Equations

• Van der Waals (a/b)
• Redlich-Kwong (a/b)
• Beattie-Bridgeman (a,b,c)
• Can be expressed in power series (virial
equations)
 Red line: IDG
Purple line: VDW
Blue line: RD
Dots: NIST Chemistry Webbook

Image from: Thermodynamics- Statistical Thermodynamics and Kinetics_Engel

Image from: Thermodynamics- Statistical Thermodynamics and Kinetics_Engel
http://atomsinmotion.com/book/chapter5/md
 Phase Diagram of CO2: Critical constants

Green chemistry: Designed to dissolve

Walter Leitner
Nature 405, 129-130(11 May 2000)
doi:10.1038/35012181
 Properties of Real Gases

Image from: Thermodynamics- Statistical Thermodynamics and Kinetics_Engel

Image from: Thermodynamics- Statistical Thermodynamics and Kinetics_Engel
Image from: Thermodynamics- Statistical Thermodynamics and Kinetics_Engel
Ball, Physical Chemistry, 2003
Determination of fugacity coefficient

Ball, Physical Chemistry, 2003

Ball, Physical Chemistry, 2003
Raoult’s Law in ideal solutions

Ball, Physical Chemistry, 2003

Henry’s Law: Gases dissolved in liquids

Ball, Physical Chemistry, 2003