SEM-IV Code : A

Total marks: 50 Date : 06/02/2015

CHEM. – MARKS – 50
PART – A
 Select the proper choice from given Multiple Choices. (25)
1) If temperature of the reaction is increased from 300 to 310 K, the value of rate constant is almost doubled
because.
(A) Kinetic energy is doubled
(B) The fraction effective collision of molecules is almost doubled
(C) The number of molecular collision increases
(D) Energy of activation decreases.
2) R t graph of zero; order reaction is
(A) Straight line having positive slope (B) Curved lone having negative slope.
(C) Curved line having positive slope (D) Straight line having negative slope
3) What will be the order of reaction for Rate = Ka[H2][Br2]1/2 ?
(A) – 0.5 (B) 1 (C) 1.5 (D) 0.5
4) Which principle is known for study of chemical kinetics ?
(A) Molecular kinetic theory principle (B) Transition state principle
(C) Heisenberg’s principle (D) Pauli’s principle
5) t99.9 % = ...... times x t1/2.
(A) 5 (B) 10 (C) 99.9 (D) 2
6) The value of the rate constant of the reaction C2H5I + C2H5OH + at 300 and 600 C temperature
–1 –1
are 0.325 and 6.735 litre mole second than waht will be the value of activation energy ?
(A) 20260 cal (B) 20260 Kcal (C) 361.44 cal (D) 84773 cal
7) Mention the Freundlich’s adsorption isotherm.
(A) (B) (C) (D)
8) What is the correct effective coagulating order of ions for positively charged colloid of Fe(OH)3 ?
(A) (B)
(C) (D)
9) The particles of the colour are removed from the surface of charcoal when external force is applied, what
this phenomenon is called ?
(A) Desorption (B) Absorption
(C) Adsorption (D) All the given phenomenon
10) Which catalyst is used to obtain methanol from water gas ?
(A) Cu (B) ZnO + CrO3 (C) Pt (D) Cu – Zn
11) Fog is an example of what ?
(A) Dispersion of liquid in gas (B) Dispersion of gas in gas
(C) Dispersion of solid in gas (D) Dispersion of solid in liquid
12) In the Ostwald’s process for the manufacturing of HNO3 the catalyst used is :
(A) Fe (B) Pt (C) V2O5 (D) Mo
13) Which of the following electronic configuration, is possessed by ?
(A) [Ar] 3d54s2 (B) [Ar] 3d54s0 (C) [Ar] 3d34s2 (D) [Ar] 3d44s1
14) Which pair of the following transition ions shows 3d2 electronic configuration
(A) Ti+3, V2+, Cr3+, Mn4+ (B) Ti+, V4+, Cr6+, Mn7+
(C) Ti4+, V3+, Cr2+, Mn3+ (D) Ti+, V3+, Cr6+, Mn5+
15) What is the general electronic configuration of elements of lanthanide series ?
(A) [Xe] (B) [Xe]
(C) [Xe] (D) [Xe]
16) Which of the following is a lanthanide :
(A) Ta (B) Rh (C) Th (D) Gd
17) Which of the following complex ion does not possess tetrahedral shape ?
(A) (B) (C) (D)
18) What is theoretical magnetic moment of complex compound K2[NiF4] ?
(A) 1.73 BM (B) 2.83 BM (C) 3.87 BM (D) Zero
19) The co – ordination number, oxidation number, number of electrons in d- orbital and number of unpaired
electrons is respectively in complex [Co(NH3)4CO3]ClO4
(A) 6, 3, 6, 0 (B) 7, 2, 7, 1 (C) 5, 2, 6, 4 (D) 6, 2, 7, 3
20) The compounds [Co(SO4)(NH3)5]Cl represent
(A) Linkage isomers (B) Coordination isomers
(C) Ionisation isomers (D) Geometrical isomers
21) Pick up the incorrect statement :
(A) Cis – platin is a complex of platinum (B) Vitamin B12 is complex of cobalt
(C) Chlorophyll is complex of Manganese (D) Haemoglobin is a complex of iron
22) Match the complex ions given in Column – I with the colours given in Column – II and assign the correct
code :
Column – I Column – II
a 1 Violet
b 2 Green
c 3 Pale blue
d 4 Yellowish orange
Blue
a b c d
(A) 1 2 4 5
(B) 4 3 2 1
(C) 3 2 4 1
(D) 4 1 2 3
23) Which order from the following is true on the basis of sweetness values ?
(A) Aspartame > Sucrolose > Alitame > Saccharine
(B) Aspartame > Saccharine > Sucrolose > Alitame
(C) Alitame > Sucrolose > Saccharine > Aspartame
(D) Saccharine > Aspartame > Alitame > Sucrolose
24) Who is known as the father of chemotherapy ?
(A) Alexander Flemming (B) Howard Floor
(C) Paul Ehrlich (D) Ernest Borrischain
25) Which of the following two options are correct ?
(a) Antiseptic : Detol, Furacin, Soframycin
(b) Disinfectant : Aqueous solution of chlorine hacing 0.3 ppm concentration, aqueous solution of
phenol having 0.2 % concentration.
(c) Analgesic drugs : Asporon, Paracetamol, Quinine
(d) Sedative : Veranol, Amytal
(A) A and B (B) B and C (C) C and D (D) A and D
 PART - B
SECTION v A
 Questions Nos. 1 to 4 short questions. Each carries 2 marks (08)
1) Explain the adsorption of ammonia on the surface of nickel catalysts.
2) State the preparation, properties and uses of potassium dichromate.
3) Describe the mechanism of Micelle formation.
4) Explain Lyophilic colloid and Lyophobic colloid.
SECTION v B
 Questions Nos. 5 to 7 long questions. Each carries 3 marks (09)
5) Which four points are taken into consideration in classifying the drugs ? Explain.
6) Explain the geometrical structure, hybridization and magnetic properties of [Ni(CN)4]2- complex
7) The radioactive 90Sr that is formed due to nuclear explosion has half life period of 28.1 years. In the body
of a child born at this time 90Sr is found to be 1 (10–6 gram), then what will be 90Sr left in the body of the
child when the age of child will be 70 years. (90Sr is not lost in any other way)
SECTION v C
 Questions Nos. 8 & 9 are essay type questions. Each carries 4 marks (08)
8) Explain crystal field splitting in octahedral crystal.
9) Explain the theory of collision for a chemical reaction.