Beruflich Dokumente
Kultur Dokumente
January 2006
Principles of Radiation Protection Section 1 - Basic Radiation Physics
Section 1
The object of this section is to provide the fundamental concepts of physics that are
necessary to understand radioactive decay, radiation, and the interaction of radiation with
matter. These concepts will be brought together to allow an understanding of the physical
measurement of radioactivity, exposure, and absorbed dose. Some information is also
provided to describe the natural background radiation environment.
The atom is the smallest unit of matter that retains the chemical properties of an
element. Atoms consist of a nucleus and orbital electrons. The nucleus is a
heavy central mass with a positive charge. The nucleus accounts for most of the
mass of an atom, but is small in diameter compared to the overall size of the atom.
Particles within the nucleus are known as nucleons. Outside the nucleus is a
cloud of electrons - small, negatively charged particles that are attracted to the
atom by the opposing charge of the nucleus (coulomb forces).
3. Electrons
The charge of the electron (- 1) is equal in magnitude to the charge of the proton
but is negative instead of positive. In an uncharged atom, the number of orbital
electrons equals the number of protons within the nucleus. When the number of
orbital electrons does not equal the number of protons in the nucleus, an overall
imbalance of charge exists for the atom. A charged atom is known as an ion. Ions
readily form chemical bonds with other ions of opposing charge.
Although electrons exist in a cloud around the nucleus, it is useful to describe this
arrangement as a series of energy levels, called shells. Within each shell are
subgroups of electrons, called orbits. An atom may have a number of possible
energy states, which correspond to different arrangements of electrons in the
shells. Electrons normally occupy the lowest energy levels in the atom, with
successive shells and orbits filled in a complex manner. If an atom absorbs
energy, an electron can move to a higher-energy shell. Electrons occupying higher
energy levels can move back to vacancies in lower energy levels by releasing
energy. When the energy release is small (such as for transitions between outer
shells of an atom), the release occurs as visible or ultraviolet light. When the
difference in energy levels is large (such as when an electron moves to an inner
shell), an x-ray is emitted.
The total number of protons and neutrons in the nucleus of an atom is called the
atomic mass number (or, mass number). The symbol A is used to denote the
atomic mass number. Since atoms do not have “fractions” of protons or neutrons,
the atomic mass number is an integer.
The atomic mass number should not be confused with the atomic mass. Atomic
mass describes the relative mass of the atom (including orbital electrons). The
scale for atomic mass is fixed so that it equals 12.000 amu for an atom having 6
protons, 6 neutrons and 6 electrons. This atom (Carbon-12) also has an atomic
mass number of 12. For all other atoms, the atomic mass and atomic mass
numbers differ slightly in magnitude.
Hydrogen-1 1 0 1
Carbon-12 6 6 12
Iron-56 26 30 56
5. Nomenclature
symbol for the element is written with an upper left superscript before the symbol,
indicating the mass number (A). A lower left subscript before the symbol
indicates the atomic number (Z). This is illustrated by the examples from table 1:
Hydrogen-1 1
1 H
Carbon-12 12
6 C
Iron-56 56
26 Fe
Since both the atomic number and the chemical symbol uniquely identify the
element, it is acceptable to omit the atomic number. The designation of an atom is
often simply the chemical symbol followed by the atomic mass number, e.g. H-1,
C-12, Fe-56.
Isobars are defined as nuclides having the same mass number (A) but different
atomic numbers (Z). Example: I-131, Te-131 and Se-131 are isobars. This term is
rarely used.
7. Energy Units
The energies involved for individual reactions at the atomic level are small
compared to everyday electrical and mechanical processes requiring huge
numbers of atoms. The unit of energy used most frequently in atomic physics is
the electron volt, or eV. An electron volt is defined as the amount of energy
acquired by an electron when it falls through a difference in potential of 1 volt.
The eV unit is often used with a multiplier, either keV or MeV; 1 keV is equal to
1,000 eV, (1 keV = 103 eV) and 1 MeV is equal to a million eV, (1 MeV = 106 eV).
If it were possible to instantly turn on a light bulb, 1 MeV of energy would operate
a 100 watt light bulb for a duration of only 1.6 x 10-15 seconds. Most nuclear
interactions involve tens of keV up to several MeV of energy.
B. Radioactive Decay
1. General
The nucleus of an atom exists because the attractive force (strong nuclear force)
operating among protons and neutrons balances the coulomb force pushing the
nucleus apart. Some combinations of neutrons and protons are very successful in
holding the nucleus together. These nuclides remain intact indefinitely and are
said to be stable. For other atoms, the numbers of nucleons are less favorable
and the atom is unstable (radioactive).
To observe the pattern of stability among nuclides, the stable nuclides can be
plotted on a graph with the vertical axis indicating the N value (number of
neutrons) and the horizontal axis representing the Z value (number of protons).
This chart is shown in Appendix 1, Figure 1. These nuclides “cluster” in a small
area of the graph, indicating conditions that are favorable for stability.
The rules of stability are complex. Some of the factors influencing stability
include:
The optimum ratio of neutrons to protons varies from 1:1 for light nuclei to more
than 1.5:1 for heavy nuclei. Atoms lacking these ratios are not stable. If an atom
has an even number of protons and neutrons, it is more likely to be stable. Atoms
are particularly likely to be stable if the number of protons and/or neutrons
corresponds to one of the following integers: 20, 28, 50, 82 and 126. The region of
stability ends with Bi-209; all nuclides heavier than bismuth are radioactive.
Unstable atoms tend to decay in a manner that shifts the composition of the
daughter nucleus towards a more favorable combination of nucleons. The
direction of this shift determines the type of radioactive decay (this will be
discussed in subsequent sections). Some radionuclides can achieve stability
through a single decay (the daughter is stable). For other radionuclides, a series
of decays must occur before stability is reached.
3. Rate of Decay
a. Decay Constant
The process of decay is random for individual atoms. Although the exact
moment of an individual atomic decay cannot be predicted, the probability of
decay during a given time period can be measured (based on observations
from a large number of atoms). This quantity is known as the decay
constant (λ). The decay constant is expressed in units of probability per unit
time.
b. Half-Life (t½)
The rate of decay can also be described by the half-life of the atom. The half-
life (t½) is the amount of time required for 50% of the parent atoms to
undergo radioactive decay. The half-life and decay constant are related
through the simple expressions:
ln 2 0.693
t1 = =
2 λ λ
ln 2 0.693
λ = =
t1 t1
2 2
c. Activity
1 x 10-6 Ci = 1 microcurie, or
1 x 10-3 Ci = 1 millicurie.
Number of
Type of Disintegrations
Unit Abbreviation Multiple Unit per Second (dps)
curie Ci 1 Ci Traditional 37,000,000,000
millicurie mCi 10-3 Ci Traditional 37,000,000
microcurie :Ci 10-6 Ci Traditional 37,000
nanocurie nCi 10-9 Ci Traditional 37
becquerel Bq 1 Bq SI 1
kilobecquerel kBq 103 Bq SI 1000
megabecquerel mBq 106 Bq SI 1,000,000
gigabecquerel gBq 109 Bq SI 1,000,000,000
A = N ⋅λ
d. Exponential Decay
Stated as an equation:
⎛ ⎞
⎜ 0.693 ⋅ t ⎟
−⎜ ⎟
⎜ t1 ⎟
A(t ) = Ao ⋅ e −λ ⋅t = Ao ⋅ e ⎝ 2 ⎠
A(t) is the activity at time t, and A0 is the initial activity. Since the activity is
proportional to the number of radioactive atoms, the equation can also be
written:
⎛ ⎞
⎜ 0.693 ⋅ t ⎟
−⎜ ⎟
⎜ t1 ⎟
N (t ) = N o ⋅ e −λ ⋅t = No ⋅ e ⎝ 2 ⎠
N(t) is the number of radioactive atoms at time t, and N0 is the initial number
of radioactive atoms.
⎛ ⎞
⎜ 0.693 ⋅ t ⎟
−⎜ ⎟ ⎛ 0.693 ⋅ 30 days ⎞
⎜ t1 ⎟ − ⎜⎜ ⎟⎟
A(t ) = Ao ⋅ e ⎝ 2 ⎠
= (10 mCi ) ⋅ e ⎝ 8.05 days ⎠
= 0.76 mCi
The simple decay equation applies only when there is one radionuclide
present. If there is a mixture of radionuclides present (as for a parent mixed
with radioactive daughters), then a sum of exponential functions would apply.
4. Types of Radiation
a. Subatomic Particles
Type of Greek
Radiation Symbol Description Charge Mass at Rest
Alpha α Combination of 2 +2 4.001 amu
protons and 2 neutrons (6.64 x 10-24 g)
Several kinds of interactions may create x-rays. They are related to the
energy balance (conservation of energy) that exists at the atomic level. For
example, when an orbital electron moves from an outer (higher energy) shell
to an inner (lower energy) shell, an x-ray must be emitted with an energy
equal to the difference between energy levels. When an unbound electron
traveling outside the atom suddenly slows down and changes direction (due
to the presence of an adjacent atom), an x-ray is emitted with an energy equal
to the decrease in electron energy.
a. Alpha (α ) Decay
Z daughter = Z parent − 2
Adaughter = A parent − 4
If the kinetic energy of the alpha particle is less than the energy released by
the decay process, the daughter nucleus is left with excess energy. The extra
energy is released in the form of one or more gamma rays. This occurs almost
simultaneously with the alpha decay.
226
88 Ra → 222
86Rn + 4
2α ++
+ 5 .59 MeV
(parent) (daughter) (alpha particle) (energy released by decay process)
For Ra-226, the 5.59 MeV decay energy is released entirely to the alpha
particle in 94.6% of all instances. In 5.4% of the decays, the decay energy is
divided between a 5.40 MeV alpha particle and 0.19 MeV gamma ray.
b. ( )
Beta β − Decay
Beta decay tends to occur when a nucleus has too many neutrons to achieve
stability. During beta decay, a neutron within the parent nucleus is
converted to a proton, an electron (e-) and a neutrino:
1
0 n → 1
1p + e− + ν
(neutron) (proton) (electron) (neutrino)
The proton remains in the daughter nucleus. The electron leaves the atom at
a high velocity (as a beta particle). Because it is charged, a beta particle can
interact and deposit energy in surrounding materials. The neutrino,
however, is chargeless and nearly massless. For all practical purposes, the
neutrino flies off into space without depositing energy or interacting with
other atoms.
The conversion of a neutron to a proton within the nucleus has the effect of
increasing the atomic number (Z) by one while keeping the same atomic mass
number (A). The loss of a slight amount of atomic mass does not change the
value of A, since the daughter has the same number of nucleons as the
parent.
Z daughter = Z parent + 1
Adaughter = Aparent
For any individual decay process, the beta energy may range from zero to the
maximum beta decay energy (Emax). This happens because the beta particle
randomly shares energy with the neutrino. When a sample contains many
atoms of a beta emitting radionuclide, the result is a beta spectrum with a
broad energy distribution between zero and Emax (a diagram of a
representative beta spectrum is shown below). The average beta energy is
about 1/3 of the maximum energy.
For most beta emitters, the decay energy is also shared by one or more
gamma rays. However, there are a few instances where no gammas are
emitted. These radionuclides are called pure beta emitters. Examples
include H-3 (tritium), C-14, P-32, P-33, and S-35. Pure beta emitters are
convenient for research applications where highly penetrating radiation is
not required, since the external hazard is greatly reduced. Coincidentally,
these elements are also components of important organic compounds. This
has led to use of these radionuclides in a wide variety of labeling procedures.
3
1 H → 3
2 He + β− + ν + 0 .0186 MeV
(beta) (neutrino) (kinetic energy of beta)
Average and maximum beta energies for selected nuclides are listed in Appendix 1,
Figure 2.
When an atom contains too many protons in the nucleus for stability, one of
these protons can combine with an inner-shell electron in the process of
electron capture. The result of this reaction is the conversion of a proton
and electron into a neutron.
1
1 p + e− → 1
0n + ν
(proton) (electron) (neutron) (neutrino)
Electron capture, therefore, has the effect of reducing the atomic number of
the parent by 1, with the parent and daughter having the same atomic mass
number.
51
24 Cr → 51
23 V + ν + 0.752 MeV
(parent) (daughter) (neutrino) (sum of decay energies)
d. ( )
Positron β + Emission
When the available decay energy is large and an atom has too many protons
in the nucleus, it may decay through positron emission instead of electron
capture. Positron emission is sometimes called beta (+) decay.
The process is similar to beta (-) decay, except that the type of radiation
emitted is an antimatter electron (positron). During positron emission, one of
the protons in the nucleus is converted to a neutron, a positron, and a
neutrino:
1
1 p → 1
0 n + e+ + ν
(proton) (neutron) (positron) (neutrino)
The neutron remains inside the daughter nucleus. The positron and neutrino
escape. This yields a daughter nucleus with one proton less than the parent
but with the same atomic mass number as the parent.
Positron emitters are rarely used because they are inconvenient to produce.
Most positron emitters decay after only a brief storage time (short half-life).
They are ordinarily produced using a particle accelerator (cyclotron). The
most common use of positron emitters is for positron emission tomography.
This technique takes advantage of the opposing directions of the two
annihilation gammas. Positron emission tomography is used to diagnose
some types of brain tumors and other brain disorders.
22
11 Na → 22
10 Ne + 00β + + ν + 1.02 MeV + 1.82 MeV
(parent) (daughter) (positron) (neutrino) (annihilation gammas) (remainder of decay energy)
The shape of the positron energy spectrum is similar to the beta spectrum.
e. Internal Conversion
f. Internal Transition
When a parent nuclide decays and the decay particles do not carry away all of
the energy, the daughter nucleus is left in an excited state (an excess of
energy). Normally, the energy is released immediately as a gamma ray or
internal conversion electron. However, for some daughter nuclides, the
excited state persists for minutes or hours. This is called internal
transition. The daughter nuclide is designated with the symbol “m” after
the atomic mass number to indicate a meta-stable state. Eventually, the
daughter nuclide releases the excitation energy through gamma emission.
The daughter nuclide can be chemically separated from the parent. By itself,
the daughter nuclide behaves like a pure gamma emitter. This can be useful
for some forms of medical imaging where highly penetrating radiation is
needed. When a radionuclide is injected for a nuclear medicine study (such
as a bone scan), any short-range alpha or beta radiation present in the decay
would be absorbed within the patient. This would cause unnecessary dose to
the patient and would not help the imaging process. If a pure gamma emitter
is available, the image quality is increased and the patient dose is decreased.
This can be achieved through use of an electron capture radionuclide or
internal transition radionuclide.
99
Mo → 99 m
Tc + β −
+ 1 .37 MeV
99 m
Tc → 99
Tc + γ ( 0 .14 MeV )
6. Decay Schemes and Energy Levels
Iodine-131 is typical of a complex beta decay scheme. There are five different
nuclear energy levels that correspond to different values of Emax (maximum
beta energy). Each beta (-) emission for I-131 has one or more corresponding
gamma emissions.
Table 4 – Energy Levels for I-131 Beta (-) Decay, (Q = 0.97 MeV)
The first two columns in Table 4 show the beta endpoint (maximum energy)
and the percentage of events in which this decay occurs. The third column
shows the possible gamma emission(s) associated with each beta decay.
Gamma rays are emitted either as a single photon, or as several photons
(shown in parenthesis). By adding the first and third columns, it is easy to
demonstrate that the total beta and gamma energies are always equal to the
Q value (total decay energy for I-131).
131
53
I (8.05d)
β − 1 1.6% 0.7229
β − 2 6.9%
0.6370
β − 3 0.5%
γ9 0.5030
Q β − = 0.970 MeV γ8
β − 4 90.4% γ7 0.3645
γ6 γ5
β − 5 0.6% γ4 0.1772
0.1639 131m
γ3 54 Xe (11.8 d)
γ2 0.0801
γ1 0.0
131
Stable 54
Xe
The parent nucleus, I-131, is shown at the top left corner. The half-life of
I-131 is equal to 8.05 days, as shown in parenthesis. The energy levels of the
Xe-131 daughter are shown as a series of horizontal lines. The daughter
nucleus is located to the right of the parent nucleus because it has a higher
atomic number (Z). Each line corresponding to the daughter nucleus is
shown with the energy level, in MeV, at the right side of the diagram. The
“ground state” (lowest energy state) of the daughter nucleus is indicated by
an energy of 0.0 MeV (bottom line of diagram). Since the Xe-131 nucleus does
not undergo radioactive decay, no half-life is shown.
Beta emissions are indicated by arrows drawn from the parent nucleus (top
left corner) to the different energy levels of the daughter. The beta energy,
Emax, is obtained by subtracting the nuclear energy level from the decay
energy, Q. For example, the energy of the first beta (β-1) is 0.970 – 0.7229, or
0.247 MeV.
Gamma rays are depicted as vertical lines traveling from higher energy levels
to lower energy levels. They correspond to transitions where the daughter
nucleus looses some or all of the remaining decay energy. During the first
beta (β-1) decay the I-131 nucleus emits a 0.247 MeV beta to the 0.7229 MeV
energy level of Xe-131. All of the remaining 0.7229 MeV is emitted as a
single gamma ray. An example of multiple gamma emissions following beta
decay is found in the (β-4) decay to the 0.3645 MeV energy level. Here, the
remaining energy may be emitted as a single gamma ray of 0.3645 MeV, or as
two gamma rays (0.2845 MeV and 0.0801 MeV). The gamma ray energies are
equal to the difference in the nuclear energy levels.
The numbering of the beta particles and gamma rays is usually arbitrary;
this is done primarily so that additional notes can be included about relative
abundance and the probability of internal conversion. The diagrams show
only nuclear energy levels and do not include characteristic x-rays emitted
during transitions by electrons outside of the nucleus.
Nuclides that decay through electron capture may also decay through
positron emission if the Q value (available decay energy) is greater than
1.022 MeV. This amount of energy is necessary for the creation of two, 0.511
annihilation gammas. The decay scheme for Zn-65 is shown as an example of
this type of decay. The half-life of Zn-65 is 245 days (as shown in
parenthesis).
65
30
Zn (245 d)
1.115
EC1 49%
β +1 1.7%
0.0
65
Stable 29
Cu
* Maximum β + Energy = Q EC - 1.022 MeV
The daughter, stable Cu-65, is shown below and to the left of the parent.
This convention is followed because the atomic number (Z) of the daughter is
less than the Z of the parent for electron capture. The energy levels of the
Cu-65 daughter nucleus are much simpler than in the preceding example for
I-131 decay. There is only one level above ground state.
Electron capture transitions are shown as straight arrows from the parent to
the daughter. Two electron capture transitions are possible. In the first,
occurring 49% of the time, the daughter nucleus is left with an excitation
energy of 1.115 MeV. This is released as a 1.115 MeV gamma ray. In the
second electron capture transition (also occurring about 49% of the time), the
decay proceeds directly to the ground state of Cu-65. No gamma ray is
emitted. In both of these transitions, characteristic x-rays are emitted as
electrons fall into vacancies in electron shells. This occurs outside the
nucleus and is not depicted in the decay diagram.
During 1.7% of the decay events, the decay proceeds through positron
emission instead of electron capture. Positron emission is depicted by a
vertical line connected to a diagonal arrow. The vertical line symbolizes the
In this case, the energy level of the daughter is 0.0 (ground state), and the
maximum energy of the positron is equal to (1.35 – 1.022) MeV, or 0.33 MeV.
Alpha decay is symbolized by double lines within the decay scheme. The
decay energy, Q, tends to be very large. The daughter product is depicted to
the left of the parent because the Z of the daughter is less than the Z of the
parent. Radium-226 provides a straightforward example of alpha decay:
226
88 Ra (1602 y)
Q α = 4.894 MeV
α 1 5.4%
0.1857 α 2 94.6%
γ 0.0
222
86 Rn (3.82 d)
In 94.6% of all Ra-226 decays, an alpha particle with energy 4.894 MeV is
emitted. Since this corresponds to the ground state of Rn-222, no
corresponding gamma ray is released. In 5.4% of all decays, an alpha particle
with an energy equal to (4.894 – 0.1857) or 4.708 MeV is emitted. The
remaining 0.1857 MeV is emitted as a single gamma ray.
The types of radiation described in the preceding sections are ionizing radiation.
Ionizing radiation is distinguished from other types of energy by its ability to
produce ionization in materials. Ionization is the removal of orbital electrons
from an atom. Radiations that cannot produce ionization are known as
nonionizing radiation. Some familiar examples of nonionizing radiation
include ultraviolet and visible light, infrared light, radio waves, microwaves, and
electromagnetic fields from household wiring. Except where otherwise noted, this
discussion will apply only to ionizing radiation.
a. Ionization
These secondary electrons produce a track of damage along the path of the
radiation. In a biological system, this damage takes the form of broken
molecular bonds and free radicals (atoms that readily form chemical bonds).
b. Excitation
Excitation occurs when radiation deposits energy, but the energy is not
sufficient to produce ion pairs. Small amounts of kinetic energy are
transferred to atoms in the material. This increases the energy level of the
atom or molecule without actually breaking chemical bonds. The increase in
energy takes the form of molecular vibration or rotation. When this happens,
the result is a (small) rise in temperature triggered by the excitation process.
Collisions may impart enough energy to allow ionizations to occur from the newly-
released secondary electrons. Some of the energy may also be released as x-rays
(bremsstrahlung). The type and probability of these interactions is related to the
charge and velocity of the incident particle.
a. Beta Particles
Since the particle velocity is initially high, it has little chance to interact with
an orbital electron unless it passes very close to that electron. Interactions
are widely spaced (in terms of atomic dimensions) because the probability of
interaction is so low. However, when the particle does interact with an
As shown in the diagram, the net distance traveled by the beta particle is
shorter than the path length. This average depth represents the maximum
distance of travel in the material and is called the particle range. The range
differs according to the energy and charge of the particle. For electrons, the
range is approximated by the following equation:
where ∆ is the specific gravity of the material and E is the beta particle or
electron energy in MeV. Please note that the expression E{1.265-0.0954lnE} is the
beta energy (in MeV) raised to the power indicated in the brackets. It is not
the exponential function. For tissue and water, ∆ = 1.0. A further discussion
of beta particle range is provided in section D.3.
b. Bremsstrahlung
When a beta particle interacts with the electric field of the nucleus (instead of
the field surrounding an orbital electron), it looses energy by changing
directions and releasing an x-ray. The energy of the x-ray is equal to the
energy lost by the beta particle. These x-rays are called bremsstrahlung, or
braking radiation.
c. Annihilation
When a positron (β+) reaches the end of its range, it combines with a nearby
orbital electron in an annihilation reaction (as described previously). The
electron (matter) and positron (antimatter) disappear, and two 0.511 MeV
gamma rays are released. The annihilation gammas are emitted in opposite
directions from each other.
d. Alpha Particles
Alpha particles are approximately 7300 times more massive than beta
particles. Heavy charged particles such as alpha particles travel at velocities
much slower than the speed of light and have a high probability for
interactions with orbital electrons. They leave a dense path of ion pairs and
expend their energy in a short range. In addition to the slow speed, heavy
particles are barely deflected by each interaction; therefore their path is short
and straight.
Photons travel at the speed of light and have no charge. They cannot create
ion pairs by interacting directly with the electric fields of an orbital electron
or nucleus. Instead, photons produce ionization indirectly through reactions
that release energetic, charged particles (usually electrons). The reactions
that are most prominent for radiation protection issues are the photoelectric
effect, Compton scattering, and pair production. The probability of each
process varies with the photon energy and Z of the material.
b. Photoelectric Effect
Photoelectric absorption can occur for very low energy photons as well.
However, the resulting photoelectrons are not ionizing. This effect is the
basis for many electronic devices that detect light.
c. Compton Scattering
The photon may be scattered in any direction between 0 and 180 degrees.
The energy loss of the photon is related to the scattering angle. For high
energy photons, the scattering angle is usually low and little energy is
imparted in any one Compton event. For low energy photons, the scattering
angle can be much larger, and nearly all of the photon energy can be
transferred to the electron in a single scattering event.
Compton interactions are the most probable type of interaction for x-rays and
gamma rays in tissue. The probability of a Compton interaction decreases
slightly with increasing Z of the material.
d. Pair Production
When a photon has energy in excess of 1.022 MeV, it can interact with the
strong forces near the nucleus of an atom in a pair production reaction.
The photon disappears and is replaced by one electron and one positron,
emitted in opposite directions.
The value of 1.022 MeV is the energy equivalent (E = mc2) of the mass of an
electron plus a positron. Any remaining kinetic energy (above 1.02 MeV) is
shared equally by the electron and positron, minus a very small amount of
energy shared with the atomic nucleus.
The electron and positron deposit energy as they travel through the
surrounding medium, creating ionization and excitation. However when the
The overall effect of pair production is the conversion of the incident photon
into two, 0.511 MeV annihilation photons emitted in opposite directions. The
only energy loss from the pair production interaction is the “left over” energy
(above 1.022 MeV) which is imparted to the secondary electron and positron.
The two, 0.511 MeV photons may subsequently deposit energy in the material
through Compton interactions.
Pair production is more prevalent for high Z materials than for low Z
materials. For lead, it becomes a significant interaction at photon energies
above 2 MeV, and the dominant interaction for photon energies above 10
MeV. For low Z materials such as tissue, it is rarely significant (unless
photon energies of tens of MeV are present).
1. Time
This principle is fairly simple. If you enter a radiation area, the amount of
occupational exposure will be proportional to the time spent in the area. Although
this sounds trivial, it is easily forgotten in the work environment. It is important
to work efficiently, without wasting time or making mistakes (which could
increase your radiation exposure).
Another facet of the “time” principle is exponential decay (section B.3). If you
have a source that is no longer needed, it can be allowed to decay in a well-
shielded area prior to disposal. This reduces the amount of radioactive material
disposed of as waste, and reduces any radiation exposure involved in the handling
of the material.
For any point source of radiant energy (including ionizing radiation), the intensity
of the radiation increases as you approach the source and decreases as you move
away from the source. The difference in intensity can be dramatic. Increasing the
distance from the source is an efficient method of reducing occupational dose.
Conversely, if you work unnecessarily close to a source of penetrating radiation, it
can lead to a great deal of unnecessary exposure.
The Inverse Square Law for a point source of radiation states that the dose rate
is inversely proportional to the distance from the source:
2
⎛d ⎞
I2 = I1 ⎜⎜ 1 ⎟⎟
⎝ d2 ⎠
Here, I is the radiation intensity and d is the distance from the source. As an
example, suppose that you measure a thousand counts per minute (cpm) on your
radiation detector placed one foot from a radiation source. If you moved back to a
distance of two feet, the count rate would be:
2 2
⎛d ⎞ ⎛ 1 foot ⎞
I2 = I1 ⎜⎜ 1 ⎟⎟ = (1000 cpm) ⋅ ⎜⎜ ⎟⎟ = 250 cpm
⎝ d2 ⎠ ⎝ 2 feet ⎠
Each time the distance from the source is doubled, the intensity is reduced by a
factor of four.
Note that the Inverse Square Law works to increase radiation exposure when the
distance is decreased. It can also be called the Inverse-r2 Effect. The r2
represents radius squared, which is the same as distance squared, in the
equations above. The following is an approximation of the increase in radiation
dose as you approach a small-diameter source.
Theoretically, the dose rate increases to infinity as the distance decreases to zero.
In reality, this does not happen. At very small distances, the point source
approximation no longer applies and the dose remains finite. However, the dose
rates can become extremely large at the point of contact with a radiation source.
For this reason, you should be extremely cautious about handling sources of
penetrating radiation. Normally, tongs or forceps must be used to provide some
distance between you and the source. If the radiation is easily attenuated
(particularly if it is a pure low-energy beta emitter), there may be enough
shielding around the material to permit holding the container in a gloved hand.
Otherwise, the source must not be handled directly.
3. Shielding
For radiation protection purposes, the thickness of the outer, “dead layer”
(stratum corneum) of skin is considered to be 0.007 cm. This value
underestimates the protection of the outer layer of skin for the hands.
Keep in mind that the shielding of the source container is not included in the
above diagram. Almost any added thickness from any container is sufficient
to stop beta particles from carbon-14 and sulfur-35 from reaching any
proliferating cells within the skin. For this reason, carbon-14 and sulfur-35
are not ordinarily considered to be external hazards.
For beta energies greater than 0.2 MeV, the incident betas can produce a dose
to the skin. Additional shielding is often beneficial (see section E.9.b. on Beta
Dose Rates). Although the standard approach is to provide shielding at least
as thick as the range of the maximum beta energy, this is not necessary
unless the dose rates near the source are high. Since most of the beta
particles have energies that are 1/3 of the maximum beta energy, even a
lesser amount of shielding can produce a noticeable benefit.
Two physical processes that decrease the effectiveness of beta shielding are
scattering and bremsstrahlung. These processes are more significant for
high-energy betas than for low-energy betas. In scattering, some of the beta
particles change direction and can be reflected back from the shield or to the
side of the shield. In extreme cases, multiple scattering can allow some of the
Unlike charged particles, x-rays and gamma rays do not have a fixed range.
X-rays and gamma rays interact with materials through photoelectric
absorption, Compton scattering, or pair-production (depending upon the
photon energy and Z of the material). When a single photon passes through a
thickness of material it has a certain probability of interaction. The
probability of interaction per unit thickness of material is called the linear
attenuation coefficient, :.
The attenuation equation for x-rays and gamma rays is similar to the
exponential equation for radioactive decay.
I = I0 ⋅ e −µ x
In this equation, I0 is the intensity without the shield, I is the intensity with
the shield in place, and x is the thickness of the shield. The attenuation
equation is an approximation, since x-rays and gamma rays scatter easily.
The contribution of scattered radiation depends upon the size and
arrangement of the shield, and is not included in this calculation.
I −1
= e −µ x = e −(88.7 cm )⋅ ( 0.1cm )
= 0.00014
I0
The intensity after shielding is only 0.01% of the original intensity (an almost
complete reduction).
I −1
= e −µ x = e −( 0.796 cm )⋅ ( 0.1 cm )
= 0.92
I0
Here, the intensity after shielding is 92% of the original intensity (only an 8%
reduction).
Note that the thickness, 1.0 mm, was converted to 0.1 cm to keep the same
units for : and x. This example illustrates the dramatic difference in
shielding effectiveness for different energies in high Z materials. It also
illustrates why lead shielding is more cost effective for x-rays than for high
energy emitters.
0.693 0.693
HVL = and µ=
µ HVL
2.30 2.30
TVL = and µ=
µ TVL
N HVL NTVL
I ⎛1⎞ I ⎛1⎞
= ⎜ ⎟ or = ⎜ ⎟
I0 ⎝2⎠ I0 ⎝ 10 ⎠
where NHVL is the number of half-value layers, and NTVL is the number of
tenth value layers. This can be a quick and easy approach to shielding
calculations. A graph of HVL vs. energy is shown in Appendix 1, Figure 5.
As a final shielding example, suppose you need to place a very intense Cs-137
source (0.67 MeV gamma rays) next to an existing office. It is necessary to
reduce the exposure rate so that the administrative personnel in the next
office receive less that 100 mrem in a year (based on a 40-hour week). If the
measured dose rate on the other side of the wall is 5.0 mrem/hour, what
thickness of concrete must be added? For this example, use a half-value layer
of 2.5 inches for Cs-137 gammas in concrete.
I0 = 5.0 mrem/hr
ln(I I 0 )
N HVL
I ⎛1⎞
= ⎜ ⎟ ⇒ N HVL =
I0 ⎝2⎠ ln( 12 )
ln(I I 0 ) ln(0.0096 )
N HVL = = = 6.7 half value layers
ln( 12 ) ln(0.5)
In any shield design (highly precise or otherwise), the user must always
measure the shield’s effectiveness under worst-case working conditions.
Never assume that the shielding is correct unless it is tested.
During the first few years after the discovery of x-rays, radiologists and scientists
struggled with a lack of available means for quantifying the amount of radiation
present. Since the hazards associated with high doses of radiation were not
recognized prior to the 1920’s, the first unit of dose was biological – the skin
erythema dose. This was the amount of radiation required to turn a person’s skin
red. Unfortunately, this required the assistance of individuals who received
considerably more radiation than modern occupational laws would allow. This
tragic method of detection was discontinued when the long-term hazards of such
exposures were recognized and other standard techniques for radiation detection
became available.
3. Exposure
1 R = 1000 mR
The original definition of the roentgen was the amount of x-ray or low energy
gamma radiation producing an ionization of one electrostatic unit (esu) of charge
in one cubic centimeter of dry air at standard temperature and pressure.
The SI unit for exposure is coulombs of charge per kilogram of air and the
conversion between the international system and the traditional system is:
1 R = 2.58 x 10 − 4 C / kg
Exposure units are defined only for x-rays and low energy gamma rays when
measured in air. Exposure should not be used when describing radiation dose in
materials other than air, and it should not be used for beta or alpha radiation (or
other charged particles).
4. Absorbed Dose
The traditional unit of absorbed dose was originally called the radiation absorbed
dose. Now the unit is known entirely by the acronym: rad. The rad is defined as
an energy deposition of 100 ergs per gram of absorbing material.
The rad has been replaced in the SI system by the gray, Gy, which is defined as
one joule of energy departed per kilogram of absorbing material.
In many low-Z materials, the absorbed dose is fairly close to the measured
exposure in air. An amount of radiation producing an exposure of one R in air will
produce an absorbed dose of 0.87 rad in air or approximately 0.92 rad in a small
volume of tissue.
The absorbed dose in a material varies with the energy and type of radiation as
well as the depth of penetration in the material. For this reason, it is necessary to
define a set of standard measurement depths. For radiation protection purposes,
standard reference depths are 0.007 cm for skin, 0.3 cm for lens of the eye and
1 cm for “total body” or deep dose. A measurement device, such as an “optically
stimulated luminescent” (OSL) dosimeter or “thermoluminescent dosimeter”
(TLD), can be used to detect the dose at these reference depths.
Some types of radiation (heavy particles, alphas and neutrons) have a heightened
ability to produce biological damage. These particles tend to leave dense trails of
ionization rather than diffuse ionization. The concept of quality factor was
developed to account for the differing degrees of hazard for various radiations.
The quality factor, Q, is defined as the relative effectiveness for producing
biological damage from a particular type of radiation.
Alphas and heavy particles are approximately 20 times more efficient (per unit
dose) in producing biological damage than betas or gammas. So, alphas and heavy
particles are assigned a quality factor of 20. Neutrons are approximately 10 times
more efficient than betas or gammas in producing biological damage (although
this varies with energy). Neutrons are assigned a quality factor of 10 (unless
specific corrections are made for energy). Betas and gammas are assigned a
quality factor of 1.
It must be emphasized that the potential for biological damage varies with both
the quality factor and the absorbed dose. For example, alpha particles outside the
body have a quality factor of 20 but produce zero dose in tissue (because they
cannot penetrate the outer, protective layer of the skin). On the other hand, if an
alpha emitter is taken internally, it comes in close contact with various tissues in
the body. Then, the high quality factor for alpha emitters is important. For this
reason, greater care is taken in handling alpha emitters to prevent ingestion or
inhalation of these materials.
6. Dose Equivalent
The dose equivalent includes both the energy absorbed from a specific type of
radiation (i.e., the dose in rad or Gy) and the ability of that radiation to produce
biological damage (the quality factor, Q). The relationship between dose
equivalent and absorbed dose is as follows:
Since 100 rad = 1 Gy, it is also true that 100 rem = 1 Sv.
As a sample calculation, compare the dose equivalent from a 0.1 rad dose of alpha,
beta and gamma radiations:
7. Rate Units
It is often useful to know the rate at which the exposure to radiation is occurring.
Most measurement instruments are calibrated in terms of dose rate, exposure
rate or count rate. The most common radiation units of rate are:
The accrued dose (mrad), for example, would be the dose rate (mrad/hr) times the
total duration of the exposure. Keep in mind that the shorter the exposure time,
the lower the total dose:
Also keep in mind that a person often moves around in the workplace. The
average amount of radiation received may be much lower than what you expect
based on measurements close to the source. For example, suppose that you have
a source that produces an exposure rate of 30 mR/hr at a distance 3 inches from
the source and a rate of 0.2 mR/hr at a distance of 3 feet from the source. If you
spend 6 minutes holding the source (using forceps) and 1 hour standing 3 feet
from the source, your total exposure would be (30 mR/hr x 0.1 hr) + (0.2 mR/hr
x 1 hour), or 3.2 mR.
The units of counts per minute, cpm, can be related to the amount of radioactive
material present. This usage is appropriate for searching out trace amounts of
contamination in a lab or facility. Most detectors that are calibrated in counts per
minute are extremely sensitive to radiation. Users of these survey instruments
are sometimes deceived into believing that a high dose rate is present because
they have a measurable count rate. This is usually not true. If it is necessary to
determine an external dose rate, it better to use an ionization chamber
(measuring absorbed dose in air) than to try to convert from counts per minute to
dose. If you require information about dose rates and do not have an instrument
designed for dose measurements, you may contact the Radiation Safety Office to
arrange for this type of radiation measurement.
It can be extremely useful to anticipate radiation levels around a source before the
source is purchased or used. This can be the basis for evaluating shielding
requirements and the need for personnel monitors (radiation badges), as well as
for planning other safety precautions.
The external radiation exposure rate (R/hr) from a gamma emitter can be
predicted from the specific gamma ray constant, Γ, for that radionuclide.
The specific gamma ray constant is defined as the exposure rate per curie of
activity at a fixed distance. The units may include distance-squared instead
of distance. At first glance, this may appear to be a misprint but it is actually
a more precise way of specifying the conversion factor. The equation for
exposure rate is:
Γ⋅ A
X =
d2
Here, X is the exposure rate, Γ is the specific gamma ray constant, A is the
source activity, and d is the distance from the source. Note that the distance
term is squared in the denominator. This reflects inverse-r2, the decrease in
intensity with the square of the distance from the source.
The specific gamma ray factor, Γ, has been calculated for most commonly
used radionuclides. Many of these are provided in Appendix 1, Figure 7. For
radionuclides not shown in Figure 7, the specific gamma ray constant can be
determined based on the energy and the number of gammas emitted per
disintegration. A graph of specific gamma ray constant versus energy is
provided in Appendix 1, Figures 8 and 9.
From Appendix 1, Figure 7, Γ = 2.2 R cm2 per hr per mCi. To apply this
factor, convert the source activity and distance into the same units used for
the specific gamma ray constant.
1 mCi
A (mCi ) = A( µCi ) ⋅
1000 µCi
10 µCi
here, A (mCi ) = or 0.010 mCi
1000 µCi / mCi
1 cm
D (cm) = D ( ft ) ⋅
0.0328 ft
6 ft
here, D (cm) = = 183 cm
0.0328 ft / cm
Note that the source strength would decrease with time as radioactive decay
occurs; I-131 has a half-life of 8 days. Even if new source material were
added frequently to replace the material “lost” to radioactive decay, the
worker at the desk would only receive 0.011 R in a year. Since the limit for a
radiation worker is 5 rem per year to the “whole body” (roughly the same as
5 R), this would be only 0.2% of the annual limit for radiation exposure.
Additional shielding is clearly unnecessary for this purpose.
Now, suppose that the worker is handling the 10 µCi I-131 source, which is
contained in a thick vial of plastic, 3 mm (0.3 cm) in thickness. This amount
of plastic would absorb the incident beta particles but would not stop the
gamma emissions. At contact with the vial, what would be the maximum
exposure rate to the person’s hand (assuming no beta dose)?
The limit for occupational exposure to the extremities and skin is 50 rem per
year (about the same as 50 R per year). In this instance, it is unlikely that
the worker would receive a significant fraction of this limit unless the source
was a much higher activity or the shielding was thin enough to allow beta
particles to reach the hand. However, it is far preferable to use forceps or
tongs when holding a source (unless that radiation cannot penetrate the
source container).
Note that this example would not apply if the source material were spilled
directly on bare skin, or if the container were very thin (minimal reduction in
beta particle intensity). Calculations of skin dose from beta particles are
included in the next section.
Unfortunately, those beta particles that are capable of reaching the 0.007 cm
depth in skin are very efficient in depositing their energy (thus, producing a
dose). This is because the beta energy is deposited over a few millimeters
depth of tissue. Compare this situation to x-rays and gamma rays, which
deposit their energy in a much more diffuse manner (over many centimeters
of tissue depth). Since dose is energy deposited per unit mass of material, it
is easy to see that the less concentrated energy deposition produces a lower
dose. For unshielded beta-gamma emitters, the skin dose from the gamma
component is less than a few percent of the skin dose from the beta
component.
2
⎛ 10 cm ⎞
Dose rate (mrad / hr ) ≈ (0.010 mCi) ⋅ (2800 mrad / hr per mCi at 10 cm) ⋅ ⎜⎜ ⎟⎟
⎝ 0.5 cm ⎠
≈ 11,200 mrad / hr
If beta emitters are allowed to come in contact with bare skin (from
contamination of laboratory surfaces or equipment), high skin doses may be
produced. For this reason, the primary means of protection in most
laboratory environments is the use of gloves, lab coats, and good
contamination control measures (surveys and cleanliness). Appendix 1,
Figure 10 shows the skin doses produced by an even distribution of
1 microcurie per cm2 over the surface of the skin. The protection provided by
ordinary laboratory gloves is also illustrated in the graph. Additional
information concerning contamination on skin and clothing is provided in
Appendix 1, Figure 11. Maximum beta particle ranges in selected materials
are shown in Appendix 1, Figure 12.
A lab coat and gloves are required when working with radioactive materials
(along with any additional precautions mandated by the chemical or physical
hazards present in the environment). Although it is rare, direct skin
contamination can occur through tearing of a glove or transfer of material
from a contaminated surface. If a microcurie quantity of a beta (or beta
gamma) emitter comes in contact with skin, it should be washed off as soon
as possible. The skin dose will not exceed the allowable limits unless the
material is allowed to remain for several hours. Please contact Radiation
Safety if you have any questions about potential skin doses.
In summary, beta emitters are much more easily shielded than gamma
emitters. Beta particles are not capable of penetrating tissue to reach any
internal organs (other than the skin). This makes them safer to work with
than gamma emitters in many respects. However, beta emitters greater than
0.2 MeV in energy are very efficient in producing a superficial dose to the
skin. Particular care should be taken to avoid contamination of bare skin,
since this greatly increases the dose rate.
1. Uptake
or transfer coefficients are estimated from animal studies and some human data.
These coefficients have been determined for the hypothetical "standard man," but
it must be recognized that in the real situation this will vary from individual to
individual. Variation in breathing rates, for example, are very dependent on a
person's physical condition and activity level. Eating habits may also provide
competing elements for uptake.
2. Interorgan Transfer
Materials that are taken into the body will move from one organ to another with
generally predictable transfer coefficients. This may be as simple as the transfer
of insoluble material through the G.I. tract or as complicated as the deposition of
radium or calcium in bones. An important interorgan transfer is the
concentration of radioiodine in the thyroid. As noted above, parameters for the
standard person are available, but actual individual variations may be
substantial.
3. Residence Time
The time that a radioactive material is in the body is dependent on both the
physical decay constant of the radionuclide and the biological removal mechanism
related to the chemical and physical forms. The combination of biological
elimination and physical decay is referred to as the effective decay constant and
can be easily converted to an "effective" half-life.
4. Energy Deposition
However, for most organs and for most radionuclides, not all of the
electromagnetic radiation energy (x- and gamma rays) will be absorbed in the
organ. The absorbed fraction is related to the size of the organ and the energy of
the radiation. The absorbed fractions have been calculated for standard size
organs. Fractions are also calculated for energy absorbed in nearby organs.
Geometric computer models provide these parameters.
are expressed in units of Bq or µCi. A list of ALIs is given in Appendix 1, Figure 13 for
many radionuclides in common use.
The annual limit for “whole body” dose is 0.05 Sv (5 rem) based on the sum of
the external deep dose at 1 centimeter depth plus the effective dose
equivalent from any internally deposited radionuclide. For most workers,
there is no significant ingestion or inhalation of radionuclides. In these cases,
the total effective dose equivalent is equal to the deep dose recorded by the
dosimeter.
The annual limit to the lens of the eye is 0.15 Sv (15 rem).
The annual external dose limit at 0.007 cm depth is 0.5 Sv (50 rem) to the
skin or to any extremity.
d. Other Organs
The annual limit for all other organs is 0.5 Sv (50 rem) based on the sum of
the external dose at one centimeter depth and the dose to that organ from
internally deposited radionuclides (as determined by a bioassay).
The occupational dose limit for minors is 10% of the above limits.
The total effective dose equivalent to individual members of the public must not
exceed 1 mSv (0.1 rem) in a year. The dose to any unrestricted area from external
sources of radiation must not exceed 0.02 mSv (0.002 rem) in any one hour.
1. Cosmic Radiation
Cosmic radiation comes from deep space and from the sun. Before entering our
atmosphere it consists mainly of high energy protons and heavier particles. These
particles interact in the upper atmosphere and cause "spallation" showers of
lighter particles and protons which reach the earth.
Cosmic radiation varies with the earth's latitude because of the effect of the
earth's magnetic field. Doses are lowest at the equator and increase toward the
poles. The atmosphere is a very effective shield, so cosmic doses increase with
increasing altitude. Persons who live in the mountains or fly in airplanes receive
a significant increase in cosmic radiation. Cosmic radiation increases following
solar flare activity.
The sea level whole body dose equivalent is about 30 millirem per year and
increases to about 40 mrem/yr at 1 kilometer. A jet flight across the country at
12 km altitude will result in a dose equivalent of 2.5 mrem. A polar route flight to
Europe would result in nearly 10 mrem.
Cosmic radiation also produces radioactivity which becomes part of our food and
air. Tritium, carbon-14, beryllium-7, and sodium-22 are the principle cosmogenic
radionuclides, but more than twenty others have been identified. The dose
equivalent from C-14 is about 1 mrem/year, with the others being rather
insignificant.
2. Terrestrial Radiation
There are many primordial radionuclides in the earth's crust. The most well
known are uranium and thorium. These are actually part of a whole family of
radionuclides, where one decays to the next. A total of 39 different radionuclides
are included in these families.
Uranium and thorium and their daughter products are found in nearly all
materials, although in different concentrations. One of the most important
daughters is radon, an inert gas which is released to the atmosphere. Radon in
soils tends to be drawn into the structures of most buildings. This radon can
subsequently pose an exposure problem in the building. Humans receive a
natural radiation dose from two processes: a) the external radiation emitted from
decay outside of the body, and b) the internal dose from inhalation and ingestion.
Because of this, natural background radiation is higher when living in certain
structures that are conducive to buildup of radon gas, and in certain areas of the
country that have porous soil or high concentrations of primordial radionuclides in
the surrounding materials.
The average annual natural background radiation exposure in the United States
is about 300 millirem per year. This includes cosmic radiation, terrestrial
radiation, and naturally occurring radionuclides. The actual effective dose
equivalent varies widely from location to location, primarily from fluctuations in
radon concentration and building materials. Elevated natural background
radiation levels are present in areas where there are naturally high uranium
concentrations in the soil (e.g., some areas of Colorado and eastern Washington
State).
5. Medical Radiations
6. Miscellaneous Dose
Many common materials and equipment emit radiation. These include smoke
detectors, luminescent watch dials, mantles for gas lanterns, aircraft exit signs,
some tableware, and anti-static devices. This generally accounts for an average
population effective dose equivalent of about 10 millirem per year. Appendix 1,
Figure 14 lists the radioactivity in many of these devices.
Other activities such as the occupational use of radiation, the nuclear fuel cycle,
and radioactive fallout account for 1 to 2 millirem per year to the average
population.
The total average effective dose equivalent to the U.S. population resulting for
both manmade exposures and natural background radiation is about 360 millirem
per year.
c velocity of light
Ci curie
E energy
EC electron capture
eV electron volt
GBq Gigabecquerel
h Planck’s constant
kCi kilocurie
MBq Megabecquerel
Q quality factor
R roentgen
rem traditional unit of dose equivalent = absorbed dose (rad) times a quality factor (Q)
t½ half-life
v velocity
λ wavelength
Glossary
absorbed dose: The amount of energy absorbed per unit mass of material at the place of
interest. The unit of absorbed dose is the rad. One rad equals 100 ergs per gram.
activity: The rate of decay; the number of atoms that decay per unit of time.
alpha particle: A charged particle consisting of two protons and two neutrons (same as a
helium nucleus).
annihilation radiation: Radiation produced when a particle unites with its antimatter
equivalent, such as an electron and a positron. The particles disappear and two
gamma rays are emitted (in opposing directions).
atom: The smallest subdivision of matter which retains the chemical properties of an
element.
atomic mass: The mass of an uncharged atom of a nuclide, usually expressed in terms of
“atomic mass units.” The “atomic mass unit” is one-twelfth the mass of one neutral
atom of carbon-12; equivalent to 1.66 x 10-24 gram.
atomic mass number (A): The total number of protons and neutrons in the nucleus of an
atom.
becquerel: The international system of unit for activity, equal to one disintegration per
second.
beta particle: An energetic electron which has been emitted from the nucleus of an atom,
during radioactive decay.
Compton scattering: Scattering of a photon by a loosely bound electron. Part (or all) of
the energy and momentum of the incident photon is transferred to the electron and the
remaining part is carried away by the scattered photon.
coulomb: A quantity of charge equaling one ampere per second. One coulomb is
equivalent to the charge of 1.60 x 1019 electrons.
curie (Ci): The traditional unit of activity. One curie equals 3.700 x 1010 disintegrations
per second. Several fractions of the curie are in common usage.
decay constant: The probability of decay per unit time for a given radionuclide.
dose equivalent: Includes both the energy absorbed from a specific type of radiation and
the general effectiveness of that radiation to cause biological damage.
dosimeter: A small device used to detect and measure accumulated radiation exposure.
electron capture (EC): A mode of radioactive decay involving the capture of an orbital
electron by the nucleus followed by the emission of characteristic x-rays.
electron volt (eV): A unit of energy equivalent to the energy gained by an electron in
passing through a potential difference of one volt. Larger multiple units of the electron
volt are frequently used: keV for thousand or kilo electron volts; MeV for million or
mega electron volts. One electron volt equals 1.6 x 10-12 erg.
erg: Unit of energy equal to 10-7 joules or 2.4 x 10-8 thermal calories.
gamma ray: Short wavelength electromagnetic emitted from the nucleus during
radioactive decay; a photon.
gray: The international system of units for absorbed dose defined as one joule of energy
absorbed per kilogram of material.
half-life (biological): The time required for the body to eliminate one-half of an
administered dosage of any substance by regular processes of excretion. It is
approximately the same for both stable and radioactive isotopes of a particular
element.
half-life (radioactive): Time required for 50% of the atoms to undergo radioactive decay
within a sample of a given radionuclide.
half-value layer (HVL): The thickness of a specified substance which, when introduced
into the path of a given beam of radiation, reduces the gamma ray intensity by 50%.
internal conversion: A form of radioactive decay where the decay energy normally seen
as a gamma ray is imparted directly to an orbital electron. The electron is emitted
with a discreet kinetic energy equal to the decay energy minus the binding energy of
the electron.
inverse square law: For a point source of radiation, the dose rate is inversely
proportional to square of the distance from the source.
ion chamber: Gas-filled radiation detection device with a relatively low voltage, which
can be calibrated to measure dose or dose rate directly.
ion pair: An electron and positively charged ion created by the interaction of ionizing
radiation with the atom.
ionization: The formation of one or more ions by the addition of electrons to or the
removal of electrons from electrically neutral atoms. Ionization may be produced by
radiation or through other physical and chemical interactions.
isobar: Nuclides having the same mass number but different atomic numbers, such as
I-131 and Xe-131.
isotopes: Atoms having the same number of protons but different numbers of neutrons.
Isotopes always share the same element name and atomic number.
mass absorption coefficient (µ/ρ): The linear absorption coefficient divided by the
density of the material. It is frequently expressed in cm2 per gram.
neutrino: An electrically neutral particle of very small (probably zero) mass emitted
during beta decay.
nucleon: Major categories of particles (protons and neutrons) within the nucleus of an
atom.
nucleus: The dense, positively charged core of an atom, which accounts for most of the
mass in an atom.
nuclide: A term used to denote any species of atom without reference to a particular
element or grouping.
photoelectron: An electron ejected from an atom when all the energy of a photon is
deposited in an inner shell electron.
photon: The basic packet of electromagnetic energy, generally regarded as having the
properties of a wave as well as a particle. It has a discrete frequency but no charge or
rest mass.
positron: A particle of the same mass (Me) as an electron, but has a positive (+1) charge.
It is an antimatter electron.
proton: Elementary nuclear particle with a positive electric charge equal numerically to
the charge of the electron and a mass of 1.67 x 10-24 grams (1.007 amu).
quality factor (Q): A factor expressing the relative effectiveness of a particular kind of
radiation in producing biological damage.
rad: An energy deposition of 100 ergs per gram (or 0.01 joule per kilogram) of absorbing
material
radionuclide: An atom having a combination of neutrons and protons which cause the
nucleus to be unstable.
rem: Unit of dose equivalent equal to the number of rads (absorbed dose) times the quality
factor (Q).
roentgen (R): A radiation unit, expressing ionization in air by x-rays or gamma rays. It is
equal to the charge per unit mass produced in air. One roentgen equals 2.58 x 154
coulombs per kilogram of dry air.
sievert (Sv): Unit of dose equivalent equal to the number of gray (absorbed dose) times
the quality factor (Q). One sievert is equal to 100 rem.
specific gamma ray constant (Γ): The external radiation exposure rate per unit of
activity at a fixed distance. It is often expressed in R/hr per mCi at one centimeter or
in R/hr per Ci at one meter.
wavelength (λ): Distance between any two similar points of two consecutive waves. For
electromagnetic radiation, the wavelength is equal to the velocity of light (c) divided by
the frequency of the wave (λ), λ= c/v.
work function (W): The average energy required to produce an ion pair in a material.
For air, it is about 33.7 eV.
x-rays: Photons similar to gamma rays which are produced by interactions outside the
nucleis of atoms. These may be produced by transitions between orbital electron shells
or by angular deceleration of electrons in a material.
Energy Units
Multiply # of by to obtain # of
To obtain # of by divide # of
Radiological Units
Multiply # of by to obtain # of
To obtain # of by divide # of
Hydrogen-3 (Tritium):
External Concerns
Internal Concerns
ALI 80 mCi
Note: Many tritium compounds are volatile or can penetrate the skin. Tritiated
DNA precursors are considered more toxic than tritiated water, however,
they are less volatile.
Carbon-14:
External Concerns
Internal Concerns
ALI 2 mCi
Note: Many C-14 compounds are rapidly metabolized and exhaled as CO2.
Some compounds are eliminated via the urine.
Sulfur-35:
External Concerns
Half-life 88 days
Internal Concerns
ALI 10 mCi
Phosphorus-32:
External Concerns
Note: High energy betas can produce a substantial skin dose. Large quantities
of P-32 can present a significant bremsstrahlung hazard.
Internal Concerns
Phosphorus-33:
External Concerns
Internal Concerns
Iodine-125:
External Concerns
Half-life 60 days
Internal Concerns
Note: Elemental iodine and some iodine compounds are volatile. 25% to 30% of
ingested or inhaled iodine is taken up by thyroid.
Iodine-131:
External Concerns
Internal Concerns
Note: Elemental iodine and some iodine compounds are volatile. 25% to 30% of
ingested or inhaled iodine is taken up by the thyroid.
Appendix 1
Figure 1
Figure 2
Figure 2 continued
Figure 2 continued
Figure 2 continued
Figure 2 continued
Figure 3
Decay Schemes
Hydogen-3 3
1H (12.3 y)
Carbon-14 14
C (5730y)
6
Q β− = 0.1561 MeV
0.0
β − 100%
14
Stable 7
N
15
Oxygen-15 8O (124 s)
β + 100%
0.0
15
Stable 7
N
* Maximum β + Energy = QEC - 1.022 MeV
Figure 3 continued
18
Fluorine-18 F (109.7 m)
9
β + 97%
0.0
18
Stable O
8
Sodium-24 24
(15.0 h)
11 Na
β - 99+% 4.122
γ2
Q β = 5.51 MeV
−
1.37
γ1
0.0
24
Stable 12 Mg
Figure 3 continued
32
Phosphorus-32 P (14.3 d)
15
Q β− = 1.710 MeV
β − 100%
0.0
32
Stable 16
S
Phosphorus-33 33
15
P (25.4d)
Q β− = 0.248 MeV
β − 100% 0.0
33
Stable 16
S
Sulfur-35 35
S (88 d)
16
Q β− = 0.167 MeV
β− 100% 0.0
35
Stable 17
Cl
Figure 3 continued
45
Calcium-45 Ca (165 d)
20
Chromium-51 51
Cr (27.8 d)
24
0.3198 EC1 9%
QEC = 0.752 MeV
γ1
EC2 91%
0.0
51
Stable 23 V
Iron-55 55
26
Fe (2.6 y)
Figure 3 continued
Cobalt-60 60
Co (5.26y)
27
2.5057
β 1− 99+%
γ1
Q β− = 2.819 MeV
1.3325
β 2− 0.1%
γ2
0.0
60
Stable 28 Ni
Copper-64 64
29 Cu (12.8 h)
β - 38%
EC1 0.5%
Qβ = 0.573 MeV
−
1.34
64
Stable 30
Zn
EC2 43% QEC = 1.678 MeV *
γ1
β + 19%
0.0
64
Stable 28 Ni
Figure 3 continued
Zinc-65 65
Zn (245 d)
30
1.115
EC1 49%
β +1 1.7%
0.0
65
Stable 29
Cu
* Maximum β + Energy = QEC - 1.022 MeV
Strontium-90 90
Sr (28.8 y)
38
Yttrium-90 90
39 Y (64 h)
β1− 99+%
0.0
90
Stable 40 Zr
Figure 3 continued
99
42 Mo (67h)
β −1 0.3% 1.11
γ11 0.922
β −2 17%
γ10
γ9
γ8 γ
Q β− = 1.37 MeV 7
0.513
β − 3 1.0%
IT
γ6 0.1811
β −4 82%
0.1427 99m
43
Tc (6.04h)
γ5 γ 0.1405
4 γ
3 γ2 γ1
0.0
99
43
Tc (2.12x105 y)
Indium-111 111
49
In (2.81 d)
EC 99+%
0.419 QEC = 1.1 MeV
γ1
0.247
γ2
0.0
111
Stable 48 Cd
Figure 3 continued
Iodine-125 125
53 I (60 d)
0.0355
γ1 EC 100%
QEC = 0.149 MeV
0.0
125
Stable 52Te
Iodine-131
131
53
I (8.05d)
β −1 1.6% 0.7229
β −2 6.9%
0.6370
β −3 0.5%
γ9 0.5030
Q β− = 0.970 MeV γ8
β −4 90.4% γ7 0.3645
γ6 γ5
β −5 0.6% γ4 0.1772
0.1639 131m
γ3 54 Xe (11.8 d)
γ2 0.0801
γ1 0.0
131
Stable 54
Xe
Cesium-137 137
55 Cs (30.0y)
β −1 93.5%
0.6616 137m
Q β− = 1.176 MeV 56
Ba (2.55 m)
β −2 6.5% γ
0.0
137
Stable 56
Ba
Figure 3 continued
Thallium-201 201
81 Tl (73 h)
EC1 34%
0.1674 QEC = 0.41 MeV
γ5 γ4 γ 0.0321 EC2 8.0%
3 γ2 γ 0.0016
1
0.0 EC3 58%
201
Stable 80 Hg
Radium-226 226
88 Ra (1602 y)
Q α = 4.894 MeV
α 1 5.4%
0.1857 α 2 94.6%
γ 0.0
222
86 Rn (3.82 d)
Figure 4
Figure 4 continued
Figure 5
Figure 5 continued
Figure 6
Figure 6 continued
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11
Beta Emitters
Column 2: The contamination level maintained on the skin for a 24 hour day
to deliver 0.5 rem/year to the basal layer. Multiply by 17.52 to get level which
gives 1 mrem/hour. For a single event during the year, the initial level required
to deliver 0.5 rem in the following year can be higher by a factor of 17 [1 +
(15/T1/2)] where T1/2 is the radioactive half-life of the radionuclide in days.
Figure 11 continued
Figure 12
Figure 13
65
Zn 300 (10) All forms Y 400 (10) All forms
(243.9 d)
67
Ga 10,000 (400) Oxide, hydroxide, W 7000 (300) All forms
(78.26 h) carbides, halides,
nitrates
10,000 (500) All others D
85
Sr 2000 (60) SrTiO3 Y 3000 (90) Soluble salts
(64.84 d) 3000 (100) All others D 4000 (100) SrTiO3
Figure 13 continued
Average Average
No. of Annual Dose Annual
People Equivalent to Population
Exposed in the Exposed Dose
Source the United Population Remarks Equivalent Remarks
States
Unwanted Byproduct X Rays
Television Receivers 100,000,000 0.7-1.5 mrem 0.5 mrem Gonadal dose equivalent
(male)
0.2-0.4 mrem
(female)
Cold Cathode Gas Discharge < 500,000 < 1 mrem Primarily high school students < 2.5 urem Gonadal dose equivalent
Tubes
Electron Microscopes 4,400 50 mrem Ranges from 50-200 mrem/y 2-10 urem Whole-body dose
Whole-body dose equivalent equivalent
Figure 14
Intentional X Rays
Airport Inspection Systems 10,000,000 22 :rem Gonadal dose equivalent 1 u:rem Gonadal dose equivalent
Personnel Scanning Unknown 0.25-800 mrem Gonadal dose equivalent Unknown
Systems Very small 30-170 mrem Pelvic exposure Unknown
Shoe-Fitting Fluoroscopes per exposure
Processed Radioactive Materials
Radioluminous Products
Luminous Wristwatches 10,000,000 3 mrem 226Ra gonadal dose equivalent 150 :rem 226Ragonadal dose
16,000,000 0.6 mrem 3H whole-body dose equivalent 50 :rem equivalent
2,000,000 < 1 mrem 147Pm gonadal dose equivalent < 10 urem 3H whole-body dose
Pocket Watches 20,000 6 mrem 226Ra gonadal dose equivalent ~ 0.5 urem equivalent
147Pm gonadal dose
Clocks 20,000,000 < 1 mrem 3H or 147Pm whole-body dose < 100 urem equivalent
10,000,000 < 7-9 mrem equivalent 226 Ra whole-body
dose ~ 0.3-0.5 Gonadal dose equivalent
January 2006
Page Phy-97
aircraft, Whole-body dose
whole-body Unknown equivalent
Figure 14
continued
Check Sources 100,000 1 µrem Whole-body dose equivalent <<< 1 µrem Whole-body dose equivalent
Static Eliminators Very small < 0.1 mrem Gonadal and whole-body dose < 10 µrem Whole-body dose equivalent
Spark Gap- equivalent to user Whole-body dose equivalent
Irradiators 10,000,000 0.03-1.5 mrem Whole-body dose equivalent 1-45 µrem
Natural
Radioactive
Materials 50,000,000 0.25-4 mrem Lung dose equivalent 0.5-1 mrem Lung dose equivalent
Combustible Fuels 18,000,000 2-40 :rem Lung dose equivalent to people < 4 :rem Lung dose equivalent
Coal exposed within a radius of 10
Oil miles of an oil-burning plant
Principles of Radiation Protection
Average Avg Annual
No. of People Annual Dose Population
Exposed in Equivalent to Dose
Source the United the Exposed Remarks Equivalent Remarks
States Population
Natural Radioactive Materials
Natural Gas
Cooking Ranges 125,000,000 6-9 mrem Bronchial epithelial dose 5 mrem Bronchial epithelial dose
equivalent equivalent
Unvented Heaters 16,000,000 22 mrem Bronchial epithelial dose
Bronchial epithelial dose 2 mrem equivalent
equivalent
Natural Gas (Nuclear None < 1 mrem This whole-body dose equivalent is 0 mrem Whole-body dose
Stimulated) (projected) in addition to that received from equivalent
non-nuclear stimulated natural
Figure 14 continued
gas
Glass and Ceramics
Uranium in Dental Porcelain 45,000,000 60 rem Delivered to the superficial layers 10-15 rem Basal mucosal dose
of tissue in contact with these equivalent
teeth and subject to alpha
(Dentures and Crowns) << 1 rem radiation
Delivered from the uranium beta <<0.25 rem Basal mucosal dose
~ 0.1 rem radiation equivalent
Delivered from the potassium-40 ~ 0.02 rem
Unknown 1-4 rem beta radiation Basal mucosal dose
Delivered to germinal cells of the Unknown equivalent
cornea, assuming glass is in
compliance with federal
January 2006
Page Phy-99
of rem
Aircraft Transport of 6,000,000 0.2 mrem Whole-body dose equivalent 7 :rem Whole-body dose
Radioactive Materials equivalent