De completat aici cu datele din revistele de stiintifice.

Toate articolele le lucrati in document word, cate

un tabel pe fiecare pagina. Exemplu este in pagina 2.

Numele articolului

Link (website)

Metoda de obtinere

Cuvinte cheie

Informatii generale din articol

Exemplu: doar sa fie traduse in romana, am lasat in engleza sa nu pierd mult timp acum

Numele articolului Kaolinite-polymer compounds by grafting of 2-hydroxyethyl methacrylate

and 3-(trimethoxysilyl)propyl methacrylate

Link (website) https://ac-els-cdn-com.dbproxy.umfiasi.ro/S0169131717303046/1-s2.0-

S0169131717303046-main.pdf?_tid=2c2f2c1c-cea9-11e7-8761-
00000aab0f27&acdnat=1511261344_a4e4adafef787aa376496e866762c3e8
Metoda de obtinere The polymer formed was washed with toluene and dried at a
temperature of 80 °C until constant mass was reached. The polymer
yield or percent of HEMA or TMSPM monomer conversion (Y, %) was
calculated by the following equation: (Y) = mass of polymer initial
mass of monomer x100
Cuvinte cheie Kaolinite
Polymer
Functionalization
Methacrylate
Nanocomposites
Informatii generale din e. HEMA based composites exhibited a higher degree of monomer
incorporation into the kaolinite matrix, ca. 2.5 times, incorporated not only
articol into the interlayer space, but also on the external surface of kaolinite layers.
Preliminary adsorption studies using methylene blue as test molecule
revealed a higher affinity of both polymer-clay nanocomposites for this dye.

Numele articolului:

Link (website): Ex:

http://www.sciencedirect.com.dbproxy.umfiasi.ro/science/article/pii/S0169131717303046

Metoda de obtinere:ex: Obtinerea pHEMA prin polimerozare asistata de mirounde

Cuvinte cheie:

Informatii din articol: - obtinerea unui gel din pHema prin metoda....

-metoda de obtinere rezulta biocompatibiliate, natura elastica este oferita de...

- aplicatii in obtinerea de lentile de contact, eliberare de medicamente, etc...

Numele articolului
Hydrogel: Preparation, characterization, and
applications: A review

Link (website) http://www.sciencedirect.com/science/article/pii/S2090123213000969

Metoda de obtinere -

Cuvinte cheie Hidrogel, Preparare, caracterizare, Optimizare, Inovatie, Suspensie de

HEMA

Informatii generale din Conditiile care duc la o buna polimerizare a HEMA si optimizarea
suspensiei
articol Plus informatii generale despre hidrogeluri

Furthermore, Lee [61] studied the ranges of process parameters critical to the suspension
polymerization of hydrogel beads based on poly-2-hydroxyethyl methacrylate (PHEMA). The
PHEMA beads were prepared by free-radical suspension polymerization of 2-hydroxyethyl
methacrylate (HEMA) lightly cross-linked with ethylene glycol dimethacrylate (EGDMA) using
magnesium hydroxide as the suspension stabilizer.

The Suspension polymerization process flow sheet of Fig. 6 is very similar to the solution
polymerization process of Fig. 4, with the exception that water replaces the solvent and the
reactor operates adiabatically.
1. Download full-size image

Fig. 6. Suspension terpolymerization process with recycle loop.

Optimization of parameters affecting the polymerization process was carried out to maximize
bead yield, smoothness, sphericity, and clarity and to achieve a narrow size distribution while
reducing the amount of non-bead material. Suspension polymerization inherently produces size-
dispersed beads, but their particle size distribution can be controlled by stirring rpm. Parameters
found to influence polymer properties in a decreasing order of importance are as follows:
initiator type and purity, salt concentration, temperature of polymerization, suspending agent
type and concentration, rate and type of stirring, and ratio of dispersed to continuous phase.

Conditions that resulted in a good yield of quality PHEMA beads were found to consist of 0.85–
1.7% suspending agent, 18–20% dissolved salt, 3.5–5.25 continuous phase to monomer ratio,
0.2–0.4% initiator, and a stirring speed of 80–120 rpm. Suspension polymerization using a
typical setup yielded PHEMA beads of a diameter range between 75 μm and 1000 μm, but
largely (>50% by wt.) between 500 and 850 μm, depending on stirring rate. These beads have
equilibrium water swelling of 38–41% (w/w). The optimization of preparing conditions of
PHEMA hydrogel [61] can be summarized in Table 1.
Table 1. The optimized conditions for PHEMA hydrogel preparation.

Parameter Range

Suspending agent 0.85–1.7%

Dissolved salt 18–20%

Continuous phase/monomer ratio 3.5–5.25

Initiator 0.2–0.4%

Stirring speed 80–120 rpm

Preparation and process optimization of hydrogel based on grafted starch

Numele
Preparation of novel biodegradable pHEMA hydrogel for a
articolul
ui tissue engineering scaffold by microwave-assisted
polymerization.

Link http://www.sciencedirect.com/science/article/pii/S1995764514600092?via%3Dihub
https://www.ncbi.nlm.nih.gov/m/pubmed/24461527/?i=4&from=pHEMA%20hydrogel%20pr
(website) eparation

Metoda Hidrogelul Phema a fost sintetizat de catre polimerizarea asistata

de la microunde.
obtinere A fost utilizat 2-hidroxietil metacrilat ca material de baza, ca
initiator: persulfatul de potasiu, iar PCLX a fost utilizat drept aditiv
de incrucisare.
Hidrogelurile au fost caracterizate cu FTIR si spectroscopie NMR.
Proprietatile fizice si chimice ale hidrogelului a fost evaluate si s-au
testat performantele degradarii.
Pentru testarea citotoxicitatii s-a folosit MTT.
Cuvinte Poly(2-hydroxyethylmethacrilate)
cheie Biodegradabil hidrogel
Polimerizare asistata la microunde

Informat Scopul lucrarii consta in realizarea unui hydrogel pe baza de pHEMA cu proprietati extraordinare,
astfel incat, acesta sa fie utilizat cu success in regenerarea tesutului cutanat.
ii In urma cercetarii, se demonstreaza faptul ca hidrogelul poate fi utilizat cu success in aplicatiile
generale ingineriei tisulare.
din
articol
Numele
Controlled drug release from hydrogels for
articolului
contact lenses: Drug partitioning and diffusion

Link http://www.sciencedirect.com.dbproxy.umfiasi.ro/science/article/pii/S0378517316310146
http://www.sciencedirect.com.dbproxy.umfiasi.ro/science/article/pii/S0378517316310146
(website)

Metoda de Two types of HEMA based hydrogels were prepared:

obtinere HEMA/PVP (98/2, w/w) and TRIS/NVP/HEMA (40/40/20,
w/w/w).
The obtained hydrogel sheets were washed over 5 days, with
DD water renewed three times a day, to remove unreacted
monomers and to facilitate the cutting of the samples. The
hydrated samples (10 mm in diameter and 0.25 mm and
0.30 mm in thickness for TRIS/NVP/HEMA and HEMA/PVP,
respectively) were then dried, overnight, in an oven at 40 °C
and stored dried.
Dry samples of each composition (three replicates each) were
placed in DD water at 37 °C after determination of their dry
weight, W0.
Drug loading and drug release
The hydrogel samples were loaded with the drugs by soaking
in the drug dissolved in PBS or water (Vload = 1 mL) with
concentration of 1 mg/mL, until equilibrium was attained, at
ambient temperature and under light protection.

Determination of bulk diffusion coefficients using PGSE-NMR

Diffusion coefficients of the studied drugs in water and PBS
were determined by the PGSE method in a NMR Bruker
Avance III 500 MHz spectrometer with a 5 mm BBO probe with
a z-gradient shielded coil.

Cuvinte cheie Drug release

Contact lens
Hydrogel membrane
Partition coefficient
 Diffusion coefficient

Informatii
generale din
articol

Numele
Cryogels: Morphological, structural and
articolului
adsorption characterisation
Link http://www.sciencedirect.com.dbproxy.umfiasi.ro/science/article/pii/S000186861200142X
(website)

Metoda de This PHEMA cryogel was modified by anti-human β-lipoprotein

obtinere antibody molecules immobilised and oriented through protein A
onto the cryogel to remove cholesterol from
hypercholesterolaemic human blood plasma.
Cuvinte Cryogel
cheie Structural characteristics
Microscopic image treatment
Cryoporometry
Thermoporometry
Adsorption
Diffusion
Interfacial phenomena

Informatii
generale din
articol
Numele
Study of the calcification of PHEMA hydrogels
articolului
using a two compartment permeation cell

Link http://www.sciencedirect.com.dbproxy.umfiasi.ro/science/article/pii/S0022286004007471
(website)

Metoda de To simulate the process of calcification in hydrogel implants,

obtinere particularly calcification inside hydrogels, in vitro experiments
using two compartment permeation cells have been
performed. PHEMA hydrogel membranes were synthesized by
free radical polymerization in bulk. The permeability and
diffusion coefficient for Ca2+ ions at 37 °C were determined
using Fick's laws of diffusion. It was evident that Ca2+ ions
either from CaCl2 or SBF solutions may diffuse through
PHEMA hydrogel membranes.
Cuvinte cheie Calcification
Diffusion
Permeation
Hydrogel

Informatii There are two approaches commonly used for the

generale din investigation of biomaterial calcification, that is in vitro or in
articol vivo experimental studies and analysis of clinical evidence.
Most hypotheses on the mechanism of calcification have relied
on the participation of dead cells or the incidence of
necrosis [1–4], where the calcium deposits originate from the
cells or tissues that have degenerated or become necrotic as a
result of surgical trauma or the toxicity of implants
Numele articolului
pHEMA hydrogels

Link (website) https://rd.springer.com/article/10.1007/s10973-016-5329-6

Metoda de obtinere To simulate the process of calcification in hydrogel

implants, particularly calcification inside hydrogels,
in vitro experiments using two compartment
permeation cells have been performed. PHEMA
hydrogel membranes were synthesized by free
radical polymerization in bulk. The permeability and
diffusion coefficient for Ca2+ ions at 37 °C were
determined using Fick's laws of diffusion. It was
evident that Ca2+ ions either from CaCl2 or SBF
solutions may diffuse through PHEMA hydrogel
membranes.
Cuvinte cheie pHEMA Hydrogel Biomaterial Calorimetry Kinetic In
vitro tests
Informatii generale din Hydrogels of poly (2-hydroxyethyl methacrylate)
articol (pHEMA) are suitable materials for medical
applications. Synthesis, structural characterization,
kinetic, physical properties and cell viability of these
materials are reported in this article.