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Adhesion – Solid-Solid Contact

Adhesion is the phenomenon that Proximity of the asperities results in


occurs when two surfaces are pressed an adhesive joint caused by interatomic
together either under a pure normal force
together, attractions because of physical and
or under combined normal and shear chemical interactions. A chemical
forces. A normal tensile force must be interaction involves covalent bonds, ionic
exerted to separate the surfaces, Fig. or electrostatic bonds, metallic bonds,
4.1.1 The ratio of the normal tensile force y g bonds. Physical
and hydrogen y
W′ required for separation to the normal interaction involves the weak van der
compressive force initially applied is often Waals bonds.
referred to as the coefficient of adhesion,
µ′ For two solid surfaces in contact,
W′ the interfacial bond may be stronger than
µ′ = the cohesive bond in the cohesively
W
weaker of the two materials. In that
case, on separation of the two solids this
results in the transfer of the cohesively
weaker material to the cohesively
stronger.

Fig. 4.1.1 Schematic illustration of normal pull of


two solid bodies; W is the compression normal force
(load) applied for a certain duration and W′ is the
tensile normal force needed to separate surfaces.

1 Dr. M. M. Razzaque
Because of surface roughness
roughness, the real
area of contact is usually very much smaller
than the apparent area. Adhesion is
affected by the contact area which is a
function of normal load,, surface roughness
g
and mechanical properties. Materials with
higher roughness, modulus of elasticity
and/or hardness and lack of ductility exhibit
lower real area of contact which leads to
l
lower adhesion.
dh i

Any viscoelastic/ viscoplastic


deformation (creep) under load would
i
increase th
the reall area off contact
t t as a
function of duration of contact, leading to an
increase in adhesion.

W′ typically
t i ll iincreases lilinearly
l with
ith lload
d
and generally increases with duration of
static contact and separation rate.

Fig. 4.2.2 (a) Adhesive force as a function of


normal load, and (b) coefficient of adhesion
as a function of duration of contact for a clean
steel sphere on indium (From McFarlane and
Tabor,, 1950))

2 Dr. M. M. Razzaque

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