Beruflich Dokumente
Kultur Dokumente
By
Benito, Angelica Joyce Z.
Cauilan, Keicee
Mamauag, Alberto Jr. M.
Maquera, Kricel Mae
Pasicolan, Chrisitian D.
Singson, Mariella B.
June 2018
TABLE OF CONTENTS
I. INTRODUCTION ............................................................................................................ 1
II. REVIEW OF RELATED LITERATURE ..................................................................... 2
A. HYDROGEN SULFIDE IN BIOGAS....................................................................................... 2
B. SELECTIVE ABSORPTION OF HYDROGEN SULFIDE............................................................ 2
C. SELECTION OF SOLVENT .................................................................................................. 3
D. TYPES OF ABSORBERS ...................................................................................................... 4
E. REGENERATION OF SOLVENT USING STRIPPER ................................................................ 4
F. AIR AS A STRIPPING GAS ................................................................................................... 6
G. HEATING AND COOLING SYSTEM ..................................................................................... 6
III. METHODOLOGY ........................................................................................................... 7
A. GENERAL PROCEDURES ................................................................................................... 7
IV. DESIGN ......................................................................................................................... 8
A. DESIGN PROBLEM ............................................................................................................ 8
B. DESIGN INPUT .................................................................................................................. 9
C. DESIGN REQUIREMENTS................................................................................................... 9
D. DESIGN CALCULATIONS ................................................................................................... 9
1. Number of Contacting Trays of the Absorber ............................................................. 9
2. Number of Contacting Trays of the Stripper ............................................................. 13
3. Heating Load for the Heater ...................................................................................... 14
4. Cooling Load for the Cooling Tower ........................................................................ 15
5. Makeup Water for the Cooling Tower ...................................................................... 16
V. CONCLUSION ............................................................................................................... 17
VI. REFERENCES ............................................................................................................ 18
I. INTRODUCTION
Renewable energy derived from biomass sources has great potential for growth in
meeting future energy demands. Biogas is one of the most important renewable energy and
an indigenous source as it is widely available (Tippayawong &Thanompongchart, 2010).
It comprises of a flammable mixture of different gases that are produced by decomposition
of biodegradable organic matter by mechanical-biological treatment (MBT) process known
as anaerobic digestion (AD) (Chaundhary, 2008). The main gaseous products are methane
(CH4), carbon dioxide (CO2) and traces of small amounts of other contaminants like
hydrogen sulfide (H2S) (Hullu et al., 2008).
Biogas can be used for electricity production on sewage works, in a Combined Heat
and Power (CHP) gas engine, where the waste heat from the engine is conveniently used
for heating the digester; cooking; space heating; water heating; and process heating. If
compressed, it can replace compressed natural gas used in vehicles, where it can fuel
an internal combustion engine or fuel cells and is a much more effective displacer of carbon
dioxide than the normal use in on-site CHP plants (Wikipedia, 2015). However, the
corrosive nature of H2S alone is enough to destroy the machines. The presence of H2S in
the biogas contributes to formation of highly corrosive acid that attacks metal parts upon
combustion and interaction with water vapor. This result to corrosion and fouling of
burners and lowers the calorific value (CV) of the gas as well. According to Bobek et al.
(2016), when H2S undergoes combustion, it is converted into SO2 which poses health
hazards and also causes acid rain and smoke.
1
II. REVIEW OF RELATED LITERATURE
2
There are several process presented in literature (Bland and Davidson, 1967; Kohl
and Riesenfeld, 1985; Horikawa, 2001) that deal with means of removing
H2S. Nowadays, among the most effective and economic acid gas removal is by using
package blended amine. However, most of these requires high cost since it utilizes
chemical solvents. Due to this, a physical solvent is employed in the design. The solvent
used will be further discussed in the Chapter IIB. Aside from that, it was assumed that
there is no methane and carbon dioxide losses in the system. A stripper is also integrated
to recover this solvent, and a heat exchanger to maintain the temperatures of the inlet
feed of both the absorber and the stripper.
C. Selection of Solvent
The choice of solvent for absorption is very significant in the process industries.
The solvent is specified by the nature of the product. If the principal purpose is to
remove some constituent from the gas, some factors are considered. The Gas Solubility,
Volatility, Corrosiveness, Cost, Viscosity and Others.
The gas solubility should be high, thus increasing the rate of absorption and
decreasing the quantity of solvent required. Generally solvent with a chemical nature
similar to the solute to be absorbed will provide good solubility. A chemical reaction
of the solvent with the solute will frequently result in very high gas solubility, but if the
solvent is to be recovered for re-use, the reaction must be reversible. In regards with
volatility the solvent should have a low vapor pressure to reduce loss of solvent in the
gas leaving an absorption column.
The materials of construction required for the equipment should not be unusual or
expensive. The solvent should be inexpensive, so that losses are not costly, and should
be readily available. Low viscosity is preferred for reasons of rapid absorption rates,
improved flooding characteristics in packed column, low pressure drops on pumping,
and good heat transfer characteristics. Further, the solvent should be non-toxic, non-
flammable and chemically stable.
In this design the water is utilized as a solvent for H2S removal in biogas. This
removes a significant proportion of the acid gas contaminants including carbon dioxide,
which can be released from the wash water in an air- or steam stripping tower. The
resulting regenerated water can be recirculated for further use or just used one time.
3
The H2S solubility in water is not as high as in other liquids, but it has the advantages
of availability and low cost. H2S has a slightly higher solubility than CO2, nevertheless
cost associated with selective removal of H2S.
D. Types of Absorbers
Packed column absorbers and tray column absorbers have very high efficiencies for
the removal of an unwanted solute in the gas stream. However, the advantages inherent
to trayed columns become clear when one needs the solvent to have a high
concentration of the component to be removed from the gas stream. This is most
important in the case where there is a very low concentration of the component in the
gas stream. The specification states the major disadvantage of a trayed column is when
compared to a packed column is the pressure drop. The pressure drop in a packed
column is generally very low, whereas in between each tray of a trayed column pressure
drop can be quite large, solvent must contain a high concentration of that component.
In this case the flow rate of the solvent may not be high enough for a packed column,
however in a trayed column the solvent flow rate can be near zero for operation
(Schmidt, 2012). In addition, it is difficult to estimate the packed tower efficiency.
Plate columns can be designed to handle a wider range of liquid and gas flow rates than
packed columns. Plate columns can be designed with more assurance than packed
columns. There is always some doubt that good liquid distribution can be maintained
throughout a packed column under all operating conditions, particularly in large
columns.
Trays are much better for handling solids and fouling applications, offer greater
residence time for slow absorption reactions, can better handle high L/G ratios and
intermediate cooling, give better liquid turndown, and are more robust and less prone
to reliability issues such as those resulting from poor distribution. As a rule of thumb,
plates are always used in columns of large diameters and towers that have more than
20 to 30 stages.
4
It also has variety of applications in the industry. If sufficient attention is paid to
pre-purification, stripping is a robust technique that can be easily implemented in a wide
variety if sectors and in a wide volume range.
Stripping is cheaper and more reliable and provides relatively good substance
transfer. If the established condition for the Henry coefficient is met, air stripping can
be used to realize high removal yield per placed unit. If necessary, multiple units can
be placed in a series to further increase total performance (VITO, 2015).
Stripping is used when you want to minimize the expenses of your industry,
absorbent liquid is regenerated as many times as possible, instead of using a completely
fresh batch of absorbent liquid for every run. Regeneration is done by removing the
H2S dissolved in water, and then reuse the water for subsequent feeds. Stripping is
mainly removing dissolved gases from a liquid (Quora, 2016).
The main set-up types are the stripping tower or stripping column and the plate
stripper. The stripping tower is based on the counter-flow principle, where a vertical
column is filled with packing material. The plate stripper is based on the cross-flow
principle, where the liquid flow is intensively aerated via a perforated plate.
Depending on the application, these trays and packing are the same as those used in
distillation and absorption columns. Tray types include sieve, valve and bubble cap.
The geometry of the trays affects the extent and type of contact between the vapor and
liquid streams. Down comers channel the liquid flowing from one tray down to the tray
below. The air strippers of environmental systems are used in a groundwater treatment
plant. These units purify the incoming water through the use of trays rather than packing
(ChE University of Michigan, 2015).
The advantage of tray/plate column over the packed column are significant. Tray
column favor variable liquid and vapor load rather than packed column. It is also
reliable for low liquid rates and significant on large number of stages. It has high liquid
residence time and plate columns are easier to clean. The presence of thermal or
mechanical stress due to large temperature changes might lead to cracked packings
which gives another advantage for tray columns.
5
F. Air as a stripping gas
Desorption involves the removal of solutes component from a liquid stream into a
gas stream when in contact with an inert gas or steam but since steam condense, it is
preferred in solute recovery than inert gas. In an exceptional case, air is used besides
steam or inert gas to desorb certain amount of compound such as organic solvents or
ammonia gas from water and it cost less to provide air especially when the need for the
recovery of concentrated solute is unnecessary. The height of the column is also
reduced in the use of air stripping. Desorption, alternatively called stripping due to the
nature of its operation requires certain factors for operational efficiency which includes
reduction, in total pressure or temperature increase or otherwise. If absorption is carried
out under high pressure, a large fraction of the solute can sometimes be removed simply
by flashing to atmospheric pressure (McCabe et al. 2005, 590.)
6
III. METHODOLOGY
A. General Procedures
The problem presented to the designer of a gas absorption system usually specifies the
following quantities:
(1) gas flow rate;
(2) gas composition of the component or components to be absorbed;
(3) operating pressure and allowable pressure drop across the absorber;
(4) minimum recovery of one or more of the solutes; and, possibly;
(5) the solvent to be employed.
7
IV. DESIGN
A. Design Problem
A floating-drum type biodigester produces a biogas with a composition of 5 kmol%
H2S, 60 kmol% CH4 and 35 kmol% CO2 is to be purified of its H2S content by scrubbing
with water as an absorbent (Bujoczek et al.,2010). Design an absorber-stripper system
that will reduce the concentration of H2S in the biogas to 0.2 mol% to meet fuel
specifications.
Absorber:
The average production rate of the biogas is determined to be 40 kmol/h and the
water recovered by stripping with air contains 1104 kmol% H2S. The
absorption process operates at 1.5 times the minimum L/G and will be constant
at 25 ⁰C and 1 atm pressure.
Stripper:
The water with H2S from the absorber and stripping air is to be heated at 60 ⁰C
and will enter the stripper at 1 atm pressure. The treated water containing 1104
kmol% H2S is to be cooled to 25 ⁰C and returned to the absorber.
Heater:
The target heating temperature will be from 25 0C to 60 0C before entering the
stripper.
Cooler:
The target cooling temperature will be from 600C to 250C before entering the
absorber.
8
B. Design Input
G1 LO G’1 L’O
Y1 = 0.002 XO = 1 x 10-6 Y’1 X’O
S
A
T
B
R
S
I
O
P
R
COOLER P
B
E
E
R
R
HEATER
C. Design Requirements
D. Design Calculations
Assumption:
9
Inert Balance:
Inert (1 y 1 )G 1
38 (1 0.002)G 1
kmol
G 1 38.0761523
hr
Overall Mass Balance:
L o G N 1 L N G 1
40 L o L N G 1
L N 40 L 0 38.0761523
L N L 0 1.9238477
H2S Balance:
L o x o G N 1 y N 1 L N x N G 1 y1
(40)(0.05) L 0 (110 6 ) L N x N (38.076)(0.002)
2 0.002(38.0761523) 1 106
xN
LN
1.9238477 1 106 L0
xN
L0 1.92338477
i. Equilibrium Equation
At T = 25 ⁰C,
H P = 545 atm
545 atm
HC = 545
1 atm
Equilibrium Equation:
y HC x
y 545x
10
ii. Minimum Liquid-to-Gas Ratio
At y Yn 1 0.05 ,
0.05
x
545
9.174 10 5
Since the absorption process operates at 1.5 times the minimum L/G,
L L
1.5
G actual G min
1.5528.9657
793.4486
L y y1
n 1
G actual x n x o
y y
793.4486 N 1 1
x N x0
0.05 0.002
793.4486
1.9238477 1 10 6 L0
1 10 6
L0 1.92338477
kmol
L 0 31798.80266
hr
LN 31798.80266 1.9238477
kmol
L N 31800.72651
hr
1.9238477 1 10 6 (31798.80266)
xN
31798.80266 1.9238477
x n 6.1502573 10 5
11
v. Number of Contacting Trays
N
ln (1 A 1 )(Y1 Y2 )/(Y 2 Y2 ) A 1
o o
ln(A)
Where,
L m1, ave
A
mG m1ave
L1 L 2
L m, ave
2
31798.80266 31800.2651
L m, ave
2
31799.76459
Solving for A
31799.76459
A
39.038(545)
1.49465
y 2 5.45 10 3
o
N
ln (1 A 1 )(Y1 Y2 )/(Y 2 Y2 ) A 1
o o
ln(A)
N
ln (1 1.49465 1 )(0.0051 5.45 10 4 )/(0.002 5.45 10 4 ) 1.49465 1
ln(1.49465 )
N 6.1578611stages
12
2. Number of Contacting Trays for the Stripper
Assumption:
ln
1 A x 2 x1o
A
x1 x1o
N
ln A 1 (1)
in which
L1 L2
Lm,ave
2
31800 .72651 31798 .80266
Lm,ave
2
Lm,ave 31799 .76459 mol
k
hr
and
13
G1 G 2
G m,ave
2
3851 .8715 3849 .94765
G m,ave
2
G m,ave 3850 .909575 k mol
hr
In getting xo,
y1
x1o 0
m
T1 25o C 298K
T2 60o C 333K
14
QH m
Cp(T2 T1 )
kmol
333K 298K
J
31800.72651 75280
h kmol K
J 1h
8.3790 1010
h 3600s
J
2.3274 107
s
Q H 23274.598 kW
T1 25o C 298K
T2 60o C 333K
QC m
Cp(T2 T1 )
333K 298K
kmol J
31798.80266 75280
h kmol K
J 1h 1kJ
8.378 1010
h 3600s 1000 J
QC 23273.190 kW
15
5. Makeup Water for the Cooling Tower
From Perry 2008, M = E + D + B
Where,
M = makeup water
E = evaporatio n loss
D = drift loss
B = blowdown loss
Since the cooling load and the change in temperature is given
kmol 18 kg 1 m3 m3
ṁ = 31798.80266 x x = 574.1 ,
h kmol 997 kg h
∆T = 350 C
Evaporation Loss
E = (0.00085)ṁ(1.8)∆T
m3 ⁰F
E = (0.00085) (574.1 ) (1.8 ) (350 C)
h ⁰C
3
m
E = 30.743
h
Drift Loss
D = 0.0002ṁ
m3
D = 0.0002 x 574.1
h
m3
D = 0.11482
h
Blowdown Loss
For better quality of our fluid, cycles of concentration, CoC was set to 4
E − (CoC − 1)D
B=
CoC − 1
m3 m3
30.743 − (4 − 1)0.11482
B= h h
4−1
m3
B = 10.1328
h
Makeup Water
M= E+D+B
m3 m3 m3
M = 30.743 + 0.11482 + 10.1328
h h h
3
m
M = 40.99062
h
𝐤𝐦𝐨𝐥
𝐌 = 𝟐𝟐𝟕𝟎. 𝟒𝟐𝟒𝟗
𝐡
16
V. CONCLUSION
A S
B T
S R
O I
R P
B P
COOLER
E E
R R
17
23273.19 kW and a make-up water of 2270. 42 kmol/h. Lastly, the stripper will have an air
discharge containing only 0.005 kmol% H2S (50 ppm) which is considered safe to humans
and can be discharged to the environment.
VI. REFERENCES
[1] Bobek, J., & al, e. (2016). SELECTIVE HYDROGEN SULPHIDE REMOVAL FROM
ACID GAS BY ALKALI CHEMISORPTION IN A JET REACTOR. HUNGARIAN
JOURNAL OF INDUSTRY AND CHEMISTRY, 51-54.
[2] ChE University of Michigan. (2015). Retrieved from Visual Encyclopedia of Chemical
Engineering:
http://encyclopedia.che.engin.umich.edu/Pages/SeparationsChemical/Strippers/Stripp
ers.html
[3] Perry, R. H. (2008). Perry’s Chemical Engineers’ Handbook. New York, Chicago, San
Francisco, Lisbon, London, Madrid, Mexico City, Milan, New Delhi, San Juan, Seoul,
Singapore, Sydney, Toronto: McGraw-Hill.
[4] Quora. (2016). Retrieved from Quora website: https://www.quora.com/What-is-
difference-between-distillation-and-stripping-columns
[5] VITO. (2015). Retrieved from emis: https://emis.vito.be/en/techniekfiche/air-stripping
[6] Wikipedia. (2015, May 15). Biogas CHP – Alfagy – Profitable Greener Energy via
CHP, Cogen and Biomass Boiler using Wood, Biogas, Natural Gas, Biodiesel,
Vegetable Oil, Syngas and Straw. Retrieved from Wikipedia:
https://en.wikipedia.org/wiki/Biogas#Applications
18